首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 25 毫秒
1.
Abstract Paragonite in textural equilibrium with garnet, omphacite and kyanite is found in two eclogites in the ultrahigh-pressure metamorphic terrane in Dabie Shan, China. Equilibrium reactions between paragonite, omphacite and kyanite indicate a pressure of about 19 kbar at c . 700° C. However, one of the paragonite eclogites also contains clear quartz pseudomorphs after coesite as inclusions in garnet, suggesting minimum pressures of 27 kbar at the same temperature. The disparate pressure estimates from the same rock suggest that the matrix minerals in the ultrahigh-pressure eclogites have recrystallized at lower pressures and do not represent the peak ultrahigh-pressure assemblages. This hypothesis is tested by calibrating a garnet + zoisite/clinozoisite + kyanite + quartz/coesite geobarometer and applying it to the appropriate eclogite facies rocks from ultrahigh- and high-pressure terranes. These four minerals coexist from 10 to 60 kbar and in this wide pressure range the grossular content of garnet reflects the equilibrium pressure on the basis of the reaction zoisite/clinozoisite = grossular + kyanite + quartz/coesite + H2O. The results of the geobarometer agree well with independent pressure estimates from eclogites from other orogenic belts. For the paragonite eclogites in Dabie Shan the geobarometer indicates pressures in the quartz stability field, confirming that the former coesite-bearing paragonite-eclogite has re-equilibrated at lower pressures. On the other hand, garnets from other coesite-bearing but paragonite-free kyanite-zoisite eclogites show a very wide variation in grossular content, corresponding to a pressure variation from coesite into the quartz field. This wide variation, partly due to a rimward decrease in grossular component in garnet, is caused by partial equilibration of the mineral assemblage during the exhumation.  相似文献   

2.
Coesite is typically found as inclusions in rock‐forming or accessory minerals in ultrahigh‐pressure (UHP) metamorphic rocks. Thus, the survival of intergranular coesite in UHP eclogite at Yangkou Bay (Sulu belt, eastern China) is surprising and implies locally “dry” conditions throughout exhumation. The dominant structures in the eclogites at Yangkou are a strong D2 foliation associated with tight‐to‐isoclinal F2 folds that are overprinted by close‐to‐tight F3 folds. The coesite‐bearing eclogites occur as rootless intrafolial isoclinal F1 fold noses wrapped by a composite S1–S2 foliation in interlayered phengite‐bearing quartz‐rich schists. To evaluate controls on the survival of intergranular coesite, we determined the number density of intergranular coesite grains per cm2 in thin section in two samples of coesite eclogite (phengite absent) and three samples of phengite‐bearing coesite eclogite (2–3 vol.% phengite), and measured the amount of water in garnet and omphacite in these samples, and also in two samples of phengite‐bearing quartz eclogite (6–7 vol.% phengite, coesite absent). As coesite decreases in the mode, the amount of primary structural water stored in the whole rock, based on the nominally anhydrous minerals (NAMs), increases from 107/197 ppm H2O in the coesite eclogite to 157–253 ppm H2O in the phengite‐bearing coesite eclogite to 391/444 ppm H2O in the quartz eclogite. In addition, there is molecular water in the NAMs and modal water in phengite. If the primary concentrations reflect differences in water sequestered during the late prograde evolution, the amount of fluid stored in the NAMs at the metamorphic peak was higher outside of the F1 fold noses. During exhumation from UHP conditions, where NAMs became H2O saturated, dehydroxylation would have generated a free fluid phase. Interstitial fluid in a garnet–clinopyroxene matrix at UHP conditions has dihedral angles >60°, so at equilibrium fluid will be trapped in isolated pores. However, outside the F1 fold noses strong D2 deformation likely promoted interconnection of fluid and migration along the developing S2 foliation, enabling conversion of some or all of the intergranular coesite into quartz. By contrast, the eclogite forming the F1 fold noses behaved as independent rigid bodies within the composite S1–S2 foliation of the surrounding phengite‐bearing quartz‐rich schists. Primary structural water concentrations in the coesite eclogite are so low that H2O saturation of the NAMs is unlikely to have occurred. This inherited drier environment in the F1 fold noses was maintained during exhumation by deformation partitioning and strain localization in the schists, and the fold noses remained immune to grain‐scale fluid infiltration from outside allowing coesite to survive. The amount of inherited primary structural water and the effects of strain partitioning are important variables in the survival of coesite during exhumation of deeply subducted continental crust. Evidence of UHP metamorphism may be preserved in similar isolated structural settings in other collisional orogens.  相似文献   

3.
Abstract In the Su-Lu ultrahigh- P terrane, eastern China, many coesite-bearing eclogite pods and layers within biotite gneiss occur together with interlayered metasediments now represented by garnet-quartz-jadeite rock and kyanite quartzite. In addition to garnet + omphacite + rutile + coesite, other peak-stage minerals in some eclogites include kyanite, phengite, epidote, zoisite, talc, nyböite and high-Al titanite. The garnet-quartz-jadeite rock and kyanite quartzite contain jadeite + quartz + garnet + rutile ± zoisite ± apatite and quartz + kyanite + garnet + epidote + phengite + rutile ± omphacite assemblages, respectively. Coesite and quartz pseudomorphs after coesite occur as inclusions in garnet, omphacite, jadeite, kyanite and epidote from both eclogites and metasediments. Study of major elements indicates that the protolith of the garnet-quartz jadeite rock and the kyanite quartzite was supracrustal sediments. Most eclogites have basaltic composition; some have experienced variable 'crustal'contamination or metasomatism, and others may have had a basaltic tuff or pyroclastic rock protolith.
The Su-Lu ultrahigh- P rocks have been subjected to multi-stage recrystallization and exhibit a clockwise P-T path. Inclusion assemblages within garnet record a pre-eclogite epidote amphibolite facies metamorphic event. Ultrahigh- P peak metamorphism took place at 700–890° C and P >28 kbar at c . 210–230 Ma. The symplectitic assemblage plagioclase + hornblende ± epidote ± biotite + titanite implies amphibolite facies retrogressive metamorphism during exhumation at c . 180–200 Ma. Metasedimentary and metamafic lithologies have similar P-T paths. Several lines of evidence indicate that the supracrustal rocks were subducted to mantle depths and experienced in-situ ultrahigh- P metamorphism during the Triassic collision between the Sino-Korean and Yangtze cratons.  相似文献   

4.
The Eclogite Zone, of the Tauern Window is an exhumed subduction channel comprising eclogites with different grades of retrogression in a matrix of high-pressure metasediments. The rocks were exposed to 600 °C and 20–25 kbars, and then retrogressed during their exhumation, first under blueschist facies and later under amphibolite facies metamorphism. To gain insights into the deformation within the subduction channel during subduction and exhumation, both fresh and retrogressed eclogites, as well as the surrounding metasediments were investigated with respect to their deformation microstructures and crystallographic preferred orientations (CPOs). Pristine and retrogressed eclogites show grain boundary migration and subgrain rotation recrystallization microstructures in omphacite. A misorientation axes analysis reveals the activity of complementary deformation mechanisms including grain boundary sliding and dislocation creep. The omphacite CPOs of the eclogites correspond to dominant SL-fabrics characteristic of plane strain deformation, though there are local variations towards flattening or constriction within the paleosubduction channel. The glaucophane CPOs in retrogressed eclogites match those of omphacite, suggesting that a constant strain geometry persisted during exhumation at blueschist facies conditions. Plastic deformation of the host high-pressure metasediments outlasted that of the eclogites, as indicated by white mica fabrics and quartz CPO. The latter is consistently asymmetric, pointing to the operation of non-coaxial deformation. The microstructures and CPO data indicate a continuous plastic deformation cycle with eclogite and blueschist facies metamorphism related to subduction and exhumation of the different rock units.  相似文献   

5.
都兰榴辉岩地体位于柴北缘—南阿尔金超高压变质带的东端,是唯一确定含柯石英的超高压变质地体,约700 km,其特点是含有两个特征不同的变质亚带,并经历了不同的折返过程。柯石英假像和温压计算表明两带榴辉岩峰期变质的压力都在柯石英的稳定域（2.8~3.3 GPa）,但它们退化变质的p–T 轨迹具有明显不同的特征。北带榴辉岩经历了两个阶段的折返：早期从地幔深度快速折返到中部地壳层次,伴随岩石的等温降压,并发生角闪岩相退化变质;晚期抬升到地壳浅部。都兰南带榴辉岩折返过程中经历了高压麻粒岩相变质的改造,高压麻粒岩阶段的p–T条件为p＝1.9~2.0 GPa,T＝873~948℃, 并进一步经历了角闪岩相退化变质,说明都兰南带榴辉岩折返速率较慢,发生了壳幔过渡带（或加厚的深部地壳）层次的强烈热松弛。这种热松弛发生在许多大陆俯冲带的超高压岩石的折返过程中,并且是榴辉岩发生深熔作用的主要机制。都兰两个变质带不同的变质演化轨迹反映了俯冲的大陆地壳具有差异折返的特征。  相似文献   

6.
安徽省大别山区含柯石英榴辉岩主要分布在太湖县、潜山县及霍山县一带。根据其地质特征、物质成分和矿物组合等可分分为三种类型:赋存在蛇纹岩、滑石片岩中,具斜方辉石岩外壳的榴辉岩;赋存在黑云斜长片麻岩中的榴辉岩;赋存在造辉透门大理岩中的榴辉岩。主要矿物组合为石榴石、绿辉石、柯石英及副矿物金红石和榍石。它属于华中高压变质带的一部分。  相似文献   

7.
The Chinese western Tianshan high-pressure/low-temperature (HP–LT) metamorphic belt, which extends for about 200 km along the South Central Tianshan suture zone, is composed of mainly metabasic blueschists, eclogites and greenschist facies rocks. The metabasic blueschists occur as small discrete blocks, lenses, bands, laminae or thick beds in meta-sedimentary greenschist facies country rocks. Eclogites are intercalated within blueschist layers as lenses, laminae, thick beds or large massive blocks (up to 2 km2 in plan view). Metabasic blueschists consist of mainly garnet, sodic amphibole, phengite, paragonite, clinozoisite, epidote, chlorite, albite, accessory titanite and ilmenite. Eclogites are predominantly composed of garnet, omphacite, sodic–calcic amphibole, clinozoisite, phengite, paragonite, quartz with accessory minerals such as rutile, titanite, ilmenite, calcite and apatite. Garnet in eclogite has a composition of 53–79 mol% almandine, 8.5–30 mol% grossular, 5–24 mol% pyrope and 0.6–13 mol% spessartine. Garnet in blueschists shows similar composition. Sodic amphiboles include glaucophane, ferro-glaucophane and crossite, whereas the sodic–calcic amphiboles mainly comprise barroisite and winchite. The jadeite content of omphacite varies from 35–54 mol%. Peak eclogite facies temperatures are estimated as 480–580 °C for a pressure range of 14–21 kbar. The conditions of pre-peak, epidote–blueschist facies metamorphism are estimated to be 350–450 °C and 8–12 kbar. All rock types have experienced a clockwise P–T path through pre-peak lawsonite/epidote-blueschist to eclogite facies conditions. The retrograde part of the P–T path is represented by the transition of epidote-blueschist to greenschist facies conditions. The P–T path indicates that the high-pressure rocks formed in a B-type subduction zone along the northern margin of the Palaeozoic South Tianshan ocean between the Tarim and Yili-central Tianshan plates.  相似文献   

8.
Abstract Crystal-chemical relationships between coexisting sodic and calcic amphiboles have been studied in eclogitic metagabbros from the Aosta Valley, Western Alps. Textural analysis gives evidence of three successive high-pressure parageneses:
1. Pre-kinematic high-grade blueschist assemblages, preserved as polymineralic inclusions in garnet cores and made of glaucophane and actinolite (stage A).
2. Synkinematic eclogite assemblages, composed of garnet + omphacite + glaucophane ± actinolite ± white mica ° Clinozoisite + quartz + rutile (stage B).
3. Post-kinematic epitactic overgrowths of barroisitic amphibole on glaucophane and actinolite (stage C).
P–T conditions of the eclogitic metamorphism have been estimated at around 500–550°C, 16 kbar.
Glaucophane and actinolite coexist as discrete grains in stage A and B assemblages. This texture and the chemistry of the amphiboles unambiguously denotes the existence of a miscibility gap between sodic and calcic amphiboles (from NaM4= 0.80 in actinolite to NaM4= 1.70 in glaucophane at T = 500–550°C). A comparison with published analyses allows a new solvus along the glaucophane–actinolite join to be drawn.
The later barroisitic amphibole (stage C) exhibits strong chemical zonation indicating disequilibrium growth. This amphibole cannot either be used to define a miscibility gap with glaucophane or actinolite or be considered as an intermediate stage between these two end-members.  相似文献   

9.
根据花岗岩类资料，分析了大别造山带自古生代以来的岩石隆升－剥露历史。认为北淮阳地块、大别地块西段及大悟地块的岩石隆升－剥露主要发生于侏罗纪之前，而大别地块东段在白垩纪之后还发生了强烈岩石隆升－剥露．本文指出，含超高压变质岩的大别地块东段自海西期以来的岩石隆升－剥露幅度达２０ｋｍ．这一深度的负荷压力与大陆碰撞过程中超过压和高应变条件的结合，有可能形成柯石英榴辉岩，但高压变质地体中的金刚石，更可能是早期慢源岩浆挟带到地壳中的捕虏晶。  相似文献   

10.
Pseudosections calculated with thermocalc predict that lawsonite‐bearing assemblages, including lawsonite eclogite, will be common for subducted oceanic crust that experiences cool, fluid‐saturated conditions. For glaucophane–lawsonite eclogite facies conditions (500–600 °C and 18–28 kbar), MORB compositions are predicted in the NCKMnFMASHO system to contain glaucophane, garnet, omphacite, lawsonite, phengite and quartz, with chlorite at lower temperature and talc at higher temperature. In these assemblages, the pyrope content in garnet is mostly controlled by variations in temperature, and grossular content is strongly controlled by pressure. The silica content in phengite increases linearly with pressure. As the P–T conditions for these given isopleths are only subtly affected by common variations in bulk‐rock compositions, the P–T pseudosections potentially present a robust geothermobarometric method for natural glaucophane‐bearing eclogites. Thermobarometric results recovered both by isopleth and conventional approaches indicate that most natural glaucophane–lawsonite eclogites (Type‐L) and glaucophane–epidote eclogites (Type‐E) record similar peak P–T conditions within the lawsonite stability field. Decompression from conditions appropriate for lawsonite stability should result in epidote‐bearing assemblages through dehydration reactions controlled by lawsonite + omphacite = glaucophane + epidote + H2O. Lawsonite and omphacite breakdown will be accompanied by the release of a large amount of bound fluid, such that eclogite assemblages are variably recrystallized to glaucophane‐rich blueschist. Calculated pseudosections indicate that eclogite assemblages form most readily in Ca‐rich rocks and blueschist assemblages most readily in Ca‐poor rocks. This distinction in bulk‐rock composition can account for the co‐existence of low‐T eclogite and blueschist in high‐pressure terranes.  相似文献   

11.
The Flatraket Complex, a granulite facies low strain enclave within the Western Gneiss Region, provides an excellent example of metastability of plagioclase‐bearing assemblages under eclogite facies conditions. Coesite eclogites are found <200 m structurally above and <1 km below the Flatraket Complex, and are separated from it by amphibolite facies gneisses related to pervasive late‐orogenic deformation and overprinting. Granulites within the Flatraket Complex equilibrated at 9–11 kbar, 700–800°C. These predate eclogite facies metamorphism and were preserved metastably in dry undeformed zones under eclogite facies conditions. Approximately 5% of the complex was transformed to eclogite in zones of fluid infiltration and deformation, which were focused along lithological contacts in the margin of the complex. Eclogitisation proceeded by domainal re‐equilibration and disequilibrium breakdown of plagioclase by predominantly hydration reactions. Both hydration and anhydrous plagioclase breakdown reactions were kinetically linked to input of fluid. More pervasive hydration of the complex occurred during exhumation, with fluid infiltration linked to dehydration of external gneisses. Eclogite facies shear zones within the complex equilibrated at 20–23 kbar, 650–800°C, consistent with the lack of coesite and with the equilibration conditions of external HP eclogites. If the complex experienced pressures equivalent to those of nearby coesite eclogites (> 28 kbar), unprecedented metastability of plagioclase and quartz is implied. Alternatively, a tectonic break exists between the Flatraket Complex and UHP eclogites, supporting the concept of a tectonic boundary to the UHP zone of the Western Gneiss Region. The distribution of eclogite and amphibolite facies metamorphic overprints demonstrates that the reactivity of the crust during deep burial and exhumation is strongly controlled by fluid availability, and is a function of the protolith.  相似文献   

12.
Abstract Sodic amphiboles are common in Franciscan type II and type III metabasites from Cazadero, California. They occur as (1) vein-fillings, (2) overgrowths on relict augites, (3) discrete tiny crystals in the groundmass, and (4) composite crystals with metamorphic Ca–Na pyroxenes in low-grade rocks. They become coarse-grained and show strong preferred orientation in schistose high-grade rocks. In the lowest grade, only riebeckite to crossite appears; with increasing grade, sodic amphibole becomes, first, enriched in glaucophane component, later coexists with actinolite, and finally, at even higher grade, becomes winchite. Actinolite first appears in foliated blueschists of the upper pumpellyite zone. It occurs (1) interlayered on a millimetre scale with glaucophane prisms and (2) as segments of composite amphibole crystals. Actinolite is considered to be in equilibrium with other high-pressure phases on the basis of its restricted occurrence in higher grade rocks, textural and compositional characteristics, and Fe/Mg distribution coefficient between actinolite and chlorite. Detailed analyses delineate a compositional gap for coexisting sodic and calcic amphiboles. At the highest grade, winchite appears at the expense of the actinolite–glaucophane pair. Compositional characteristics of Franciscan amphiboles from Ward Creek are compared with those of other high P/T facies series. The amphibole trend in terms of major components is very sensitive to the metamorphic field gradient. Na-amphibole appears at lower grade than actinolite along the higher P/T facies series (e.g. Franciscan and New Caledonia), whereas reverse relations occur in the lower P/T facies series (e.g. Sanbagawa and New Zealand). Available data also indicate that at low-temperature conditions, such as those of the blueschist and pumpellyite–actinolite facies, large compositional gaps exist between Ca- and Na-amphiboles, and between actinolite and hornblende, whereas at higher temperatures such as in the epidote–amphibolite, greenschist and eclogite facies, the gaps become very restricted. Common occurrence of both sodic and calcic amphiboles and Ca–Na pyroxene together with albite + quartz in the Ward Creek metabasites and their compositional trends are characteristic of the jadeite–glaucophane type facies series. In New Caledonia blueschists, Ca–Na pyroxenes are also common; Na-amphiboles do not appear alone at low grade in metabasites, instead, Na-amphiboles coexist with Ca-amphiboles throughout the progressive sequence. However, for metabasites of the intermediate pressure facies series, such as those of the Sanbagawa belt, Japan and South Island, New Zealand, Ca–Na pyroxene and glaucophane are not common; sodic amphiboles are restricted to crossite and riebeckite in composition and clinopyroxenes to acmite and sodic augite, and occur only in Fe2O3-rich metabasites. The glaucophane component of Na-amphibole systematically decreases from Ward Creek, New Caledonia, through Sanbagawa to New Zealand. This relation is consistent with estimated pressure decrease employing the geobarometer of Maruyama et al. (1986). Similarly, the decrease in tschermakite content and increase in NaM4 of Ca-amphiboles from New Zealand, through Sanbagawa to New Caledonia is consistent with the geobarometry of Brown (1977b). Therefore, the difference in compositional trends of amphiboles can be used as a guide for P–T detail within the metamorphic facies series.  相似文献   

13.
北秦岭官坡地区高压—超高压榴辉岩岩相学及变质作用研究   总被引：19，自引：2，他引：19  
北秦岭官坡地区的榴辉岩及含柯石英榴辉岩产在帮岭岩群的北侧，主要由绿辉石和石榴石组成，部分石榴石和绿辉石中含柯石英包体。此外还含有退变质的多硅白云母、角闪石、黝帘石和纳长石等矿物，根据变质矿物之间的替代关系及共生组合规律，榴辉岩退变质作用可划分为四个阶段，各阶段代表性矿物组合依次为：柯石英＋绿辉石＋石榴石；石英＋绿辉石＋石榴石；多硅白云母＋绿辉石＋石榴石＋石英；角闪石＋斜长石＋白云母＋黑云母。这四个  相似文献   

14.
Eclogites from the Onodani area in the Sambagawa metamorphic belt of central Shikoku occur as layers or lenticular bodies within basic schists. These eclogites experienced three different metamorphic episodes during multiple burial and exhumation cycles. The early prograde stage of the first metamorphic event is recorded by relict eclogite facies inclusions within garnet cores (XSps 0.80–0.24, XAlm 0–0.47). These inclusions consist of relatively almandine‐rich garnet (XSps 0.13–0.24, XAlm 0.36–0.45), aegirine‐augite/omphacite (XJd 0.08–0.28), epidote, amphiboles (e.g. actinolite, winchite, barroisite and taramite), albite, phengite, chlorite, calcite, titanite, hematite and quartz. The garnet cores also contain polyphase inclusions consisting of almandine‐rich garnet, omphacite (XJd 0.27–0.28), amphiboles (e.g. actinolite, winchite, barroisite, taramite and katophorite) and phengite. The peak P–T conditions of the first eclogite facies metamorphism are estimated to be 530–590 °C and 19–21 kbar succeeded by retrogression into greenschist facies. The second prograde metamorphism began at greenschist facies conditions. The peak metamorphic conditions are defined by schistosity‐forming omphacites (XJd ≤ 49) and garnet rims containing inclusions of barroisitic amphibole, phengite, rutile and quartz. The estimated peak metamorphic conditions are 630–680 °C and 20–22 kbar followed by a clockwise retrograde P–T path with nearly isothermal decompression to 8–12 kbar. In veins cross‐cutting the eclogite schistosity, resorbed barroisite/Mg‐katophorite occurs as inclusions in glaucophane which is zoned to barroisite, suggesting a prograde metamorphism of the third metamorphic event. The peak P–T conditions of this metamorphic event are estimated to be 540–600 °C and 6.5–8 kbar. These metamorphic conditions are correlated with those of the surrounding non‐eclogitic Sambagawa schists. The Onodani eclogites were formed by subduction of an oceanic plate, and metamorphism occurred beneath an accretionary prism. These high‐P/T type metamorphic events took place in a very short time span between 100 and 90 Ma. Plate reconstructions indicate highly oblique subduction of the Izanagi plate beneath the Eurasian continent at a high spreading rate. This probably resulted in multiple burial and exhumation movements of eclogite bodies, causing plural metamorphic events. The eclogite body was juxtaposed with non‐eclogitic Sambagawa schists at glaucophane stability field conditions. The amalgamated metamorphic sequence including the Onodani eclogites were exhumed to shallow crustal/surface levels in early Eocene times (c. 50 Ma).  相似文献   

15.
Z.V. Spetsius   《Lithos》2004,77(1-4):525-538
Highly aluminous xenoliths include kyanite-, corundum- and coesite-bearing eclogites, grospydites and alkremites. These xenoliths are present in different kimberlites of Yakutia but have most often been found in Udachnaya and other pipes of the central Daldyn–Alakitsky region. Kimberlites of this field also contain eclogite-like xenoliths with kyanite and corundum that originate in the lower crust or the lower crust–upper mantle transition zone. Petrographic study shows that two rock groups of different structure and chemistry can be distinguished among kyanite eclogites: fine- to medium-grained with mosaic structure and coarse-grained with cataclastic structure. Eclogites with mosaic structure are characterized by the occurrences of symplectite intergrowths of garnet with kyanite, clinopyroxene and coesite; only in this group do grospydites occur. In cataclastic eclogites, coarse-grained coesite occurs, corresponding in size to other rock-forming minerals. Highly aluminous xenoliths differ from bimineralic eclogites in their high content of Al2O3 and total alkali content. Coesite-bearing varieties are characterized by low MgO content and higher Na/K and Fe2+/Fe3+ ratios, as well as high contents of Na2O. Geochemical peculiarities of kyanite eclogites and other rocks are exhibited by a sloping chondrite-normalized distribution of rare earth elements (REE) in garnets and low Y/Zr ratio, in contrast to bimineralic rocks. Coesite is found in more than 20 kyanite eclogites and grospydites from Udachnaya. Grospydites with coesite from Zagadochnaya pipe are described. Three varieties of coesite in these rocks are distinguished: (a) subhedral grains with size of 1.0–3.0 mm; (b) inclusions in the rock-forming minerals; (c) sub-graphic intergrowths with garnet. The presence and preservation of coesite in eclogites indicate both high pressure of formation (more than 30 kbar) and set a number of constraints on the timing of xenolith cooling during entrainment and transport to the surface. Different ways of formation of the highly aluminous eclogites are discussed. Petrographic observations and geochemistry suggest that some highly aluminous rocks have formed as a result of crystallization of anorthosite rocks in abyssal conditions. δ18O-estimations and other petrologic evidence point out the possible origin of some of these xenoliths as the result of subduction of oceanic crust. Diamondiferous samples have been found in all varieties except alkremites. Usually these eclogites contain cubic or coated diamonds. However, two sample corundum-bearing eclogites with diamonds from the Udachnaya pipe contain octahedra that show evidence of resorption.  相似文献   

16.
A coesite-bearing eclogite breccia is reported here for the first time at Yangkou in the Chinese Su–Lu ultrahigh-pressure (UHP) metamorphic belt. It is thrusted over a coesite-bearing coronitic eclogite and is gradational to a foliated eclogite at the contact. The coronitic eclogite is characterized by garnet coronas between fine-grained high-pressure mineral aggregates forming pseudomorphs after plagioclase, ilmenite, biotite, and pyroxene in a gabbroic protolith. The breccia consists of fine-grained cataclastic eclogite fragments (garnet + omphacite + coesite/quartz ± phengite ± kyanite) and a coarser-grained matrix schist (garnet + quartz + phengite + kyanite). The foliated eclogite consists of intercalating bands of the cataclastic eclogite and a schist similar to the fragments and the matrix, respectively, in the breccia. The igneous fabric of the eclogitized gabbro is increasingly obliterated from the coronitic eclogite through the foliated eclogite to the breccia. Micropoikilitic amoeboid garnet containing numerous inclusions of omphacite and other high-pressure minerals is characteristic of eclogite facies pseudotachylytes and suggests flash melting and rapid crystallization. In the breccia and foliated eclogite, quartz + K-feldspar ± albite aggregates are included in garnet or form strings cutting across the cataclasites. In some aggregates, quartz grains are cemented by K-feldspar and vesicular albite, also implying crystallization from melts in a rapid cooling and decompression process from the UHP condition. The field context, the locally preserved igneous fabric in the breccia, the similar whole-rock compositions, as well as the complementary mineral assemblages in the fragments and the matrix with respect to the coronitic eclogite, suggest that the breccia was formed by cataclasis and segregation of minerals in a former coronitic eclogite in response to a sudden pressure release. Intergranular coesite is found only in the eclogite cataclasites and may have survived via the rapid cooling event, as coesite converts to quartz completely in a few years when being cooled slowly at lower pressures. Such rate information is incompatible with the presumed deep subduction/exhumation process but implies transient UHP metamorphism coeval with the seismic event.  相似文献   

17.
The chemistry and phase relations of calcic and sodic amphiboles in the Ouégoa blueschists are investigated. The first appearance of sodic amphiboles is controlled by bulkrock chemistry. Sodic amphibole appears first in weakly-metamorphosed pumpellyite metabasalts prior to the crystallization of lawsonite but does not crystallize in pelitic schists until the middle of the lawsonite zone; sodic amphibole continues as an apparently stable phase in rocks of all bulk compositions into, and throughout, the highest-grade rocks in the district. Calcic amphibole is widespread in metabasalts of the lawsonite and epidote zones and also occurs in metasediments of appropriate composition. Coexisting pairs of calcic and sodic amphiboles are common in metabasalts but they have also been found in some metasediments. A grunerite-riebeckite pair is described.Electron-probe analyses of 120 amphiboles from representative rock-types are presented in graphical form. Sodic amphiboles show an increased Mg/(Mg+Fe) ratio with increasing metamorphic grade. Sodic amphiboles in pelitic schists are ferroglaucophane in the lawsonite zone and crossite and glaucophane in the epidote zone. Sodic amphiboles in metabasalts are iron-rich crossites in weakly-metamorphosed rocks and more-magnesian crossites and glaucophanes in the lawsonite and epidote zones. The abrupt increase in Mg/(Mg+Fe) ratio in sodic amphiboles at the epidote isograd is attributed to the crystallization of epidote and almandine which take the place of lawsonite and spessartine of the lawsonite zone. Calcic amphiboles are fibrous actinolites in the lawsonite zone and grade with increasing Al and Na/Ca ratio into prismatic blue-green hornblendes (barroisites) in the upper epidote zone. In calcic amphiboles, increasing metamorphic grade effects the coupled substitution of (Na+Al) for (Ca+Mg) and a small increases in Fe/Mg ratio; octahedrally and tetrahedrally coordinated Al increases in an approximately 11 ratio. Both the calcic and the sodic amphiboles show an increase in A-site occupancy with increasing metamorphic grade. In two-amphibole assemblages Ti, Mn and K are concentrated in the calcic amphibole.The textural and chemical relations between coexisting calcic and sodic amphiboles are discussed. If the calcic and sodic amphiboles are an equilibrium pair then the data collected from the Ouégoa amphiboles gives a picture of a very asymmetric solvus in the system glaucophane-actinolite-hornblende, i.e. steep-sided to glaucophane and with a gentle slope to the calcic amphibole field; there is no indication of any termination of the solvus under the pressure-temperature conditions of crystallization of the Ouégoa schists.  相似文献   

18.
Eclogites from the south Tianshan, NW China are grouped into two types: glaucophane and hornblende eclogites, composed, respectively, of garnet + omphacite + glaucophane + paragonite + epidote + quartz and garnet + omphacite + hornblende (sensu lato) + paragonite + epidote + quartz, plus accessory rutile and ilmenite. These eclogites are diverse both in mineral composition and texture not only between the two types but also among the different selected samples within the glaucophane eclogite. Using thermocalc 3.1 and recent models of activity–composition relation for minerals, a P–T projection and a series of P–T pseudosections for specific samples of eclogite have been calculated in the system Na2O–CaO–FeO–MgO–Al2O3–SiO2–H2O (NCFMASH) with quartz and water taken to be in excess. On the basis of these phase diagrams, the phase relations and P–T conditions are well delineated. The three selected samples of glaucophane eclogite AK05, AK11 and AK17 are estimated to have peak P–T conditions, respectively, of 540–550 °C at c. 16 kbar, c. 560 °C at 15–17 kbar and c. 580 °C at 15–19 kbar, and two samples of hornblende eclogite AK10 and AK30 of 610–630 °C and 17–18 kbar. Together with H2O‐content contours in the related P–T pseudosections and textural relations, both types of eclogite are inferred to show clockwise P–T paths, with the hornblende eclogite being transformed from the glaucophane eclogite assemblage dominantly through increasing temperature.  相似文献   

19.
Coesite inclusions are found in kyanite from the Lanshantou eclogite in the Sulu ultrahigh-pressure (UHP) metamorphic belt. This discovery extends the stable region of kyanite to over 2.4 GPa. As an important UHP metamorphic belt in China, the Sulu eclogite belt is the product of A-subduction induced by strong compression of the Yellow Sea terrane to the Jiaodong-northereastern Jiangsu terrane during the interaction of the Eurasian plate and Palaeo-Pacific plate in the Indosinian. It stretches about 350 km and contains over 1000 eclogite bodies. Most eclogites in this belt belong to Groups B and C in the classification of Coleman et al., and commonly contain kyanite, while the Lanshantou eclogite belongs to Group A and contains coesite. The MgO, CaO and FeO contents in garnet and pyroxene show regular variation from the core to the rim, which reveals the PTt paths of progressive metamorphism during the Early Mesozoic (240-200 Ma) and retrogressive metamorphism during the Late Mesozoic and Cenozoic exhum  相似文献   

20.
Glaucophane‐bearing ultrahigh pressure (UHP) eclogites from the western Dabieshan terrane consist of garnet, omphacite, glaucophane, kyanite, epidote, phengite, quartz/coesite and rutile with or without talc and paragonite. Some garnet porphyroblasts exhibit a core–mantle zoning profile with slight increase in pyrope content and minor or slight decrease in grossular and a mantle–rim zoning profile characterized by a pronounced increase in pyrope and rapid decrease in grossular. Omphacite is usually zoned with a core–rim decrease in j(o) [=Na/(Ca + Na)]. Glaucophane occurs as porphyroblasts in some samples and contains inclusions of garnet, omphacite and epidote. Pseudosections calculated in the NCKMnFMASHO system for five representative samples, combined with petrographic observations suggest that the UHP eclogites record four stages of metamorphism. (i) The prograde stage, on the basis of modelling of garnet zoning and inclusions in garnet, involves P–T vectors dominated by heating with a slight increase in pressure, suggesting an early slow subduction process, and P–T vectors dominated by a pronounced increase in pressure and slight heating, pointing to a late fast subduction process. The prograde metamorphism is predominated by dehydration of glaucophane and, to a lesser extent, chlorite, epidote and paragonite, releasing ～27 wt% water that was bound in the hydrous minerals. (ii) The peak stage is represented by garnet rim compositions with maximum pyrope and minimum grossular contents, and P–T conditions of 28.2–31.8 kbar and 605–613 °C, with the modelled peak‐stage mineral assemblage mostly involving garnet + omphacite + lawsonite + talc + phengite + coesite ± glaucophane ± kyanite. (iii) The early decompression stage is characterized by dehydration of lawsonite, releasing ～70–90 wt% water bound in the peak mineral assemblages, which results in the growth of glaucophane, j(o) decrease in omphacite and formation of epidote. And, (iv) The late retrograde stage is characterized by the mineral assemblage of hornblendic amphibole + epidote + albite/oligoclase + quartz developed in the margins or strongly foliated domains of eclogite blocks due to fluid infiltration at P–T conditions of 5–10 kbar and 500–580 °C. The proposed metamorphic stages for the UHP eclogites are consistent with the petrological observations, but considerably different from those presented in the previous studies.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号