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The goal of this study was to explore prebiotic chemistry in a range of plausible early Earth and Mars atmospheres. To achieve this laboratory continuous flow plasma irradiation experiments were performed on N2/H2/CO/CO2 gas mixtures chosen to represent mildly reducing early Earth and Mars atmospheres derived from a secondary volcanic outgassing of volatiles in chemical equilibrium with magmas near present day oxidation state. Under mildly reducing conditions (91.79% N2, 5.89% H2, 2.21% CO, and 0.11% CO2), simple nitriles are produced in the gas phase with yield (G in molecules per 100 eV), for the key prebiotic marker molecule HCN at G∼1×10−3 (0.1 nmol J−1). In this atmosphere localized HCN concentrations possibly could approach the 10−2 M needed for HCN oligomerization. Yields under mildly oxidizing conditions (45.5% N2, 0.1% H2, 27.2% CO, 27.2% CO2) are significantly less as expected, with HCN at G∼3×10−5 (). Yields in a Triton atmosphere which can be plausibly extrapolated to represent what might be produced in trace CH4 conditions (99.9% N2, 0.1% CH4) are significant with HCN at G∼1×10−2 (1 nmol J−1) and tholins produced. Recently higher methane abundance atmospheres have been examined for their greenhouse warming potential, and higher abundance hydrogen atmospheres have been proposed based on a low early Earth exosphere temperature. A reducing (64.04% N2, 28.8% H2, 3.60% CO2, and 3.56% CH4), representing a high CH4 and H2 abundance early Earth atmosphere had HCN yields of G∼5×10−3 (0.5 nmol J−1). Tholins generated in high methane hydrogen gas mixtures is much less than in a similar mixture without hydrogen. The same mixture with the oxidizing component CO2 removed (66.43% N2, 29.88% H2, 0% CO2, and 3.69% CH4) had HCN yields of G∼1×10−3 (0.1 nmol J−1) but more significant tholin yields. 相似文献
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This work presents model calculations of the diurnal airglow emissions from the OH Meinel bands and the O2 IR atmospheric band in the neutral atmosphere of Mars. A time-dependent photochemical model of the lower atmosphere below 80 km has been developed for this purpose. Special emphasis is placed on the nightglow emissions because of their potential to characterize the atomic oxygen profile in the 50-80 km region. Unlike on Earth, the OH Meinel emission rates are very sensitive to the details of the vibrational relaxation pathway. In the sudden death and collisional cascade limits, the maximum OH Meinel column intensities for emissions originating from a fixed upper vibrational level are calculated to be about 300 R, for transitions v′=9→v′?8, and 15,000 R, for transitions v′=1→v′=0, respectively. During the daytime the 1.27 μm emission from O2(), primarily formed from ozone photodissociation, is of the order of MegaRayleighs (MR). Due to the long radiative lifetime of O2(), a luminescent remnant of the dayglow extends to the dark side for about two hours. At night, excited molecular oxygen is expected to be produced through the three body reaction O + O + CO2. The column emission of this nighttime component of the airglow is estimated to amount to 25 kR. Both nightglow emissions, from the OH Meinel bands and the O2 IR atmospheric band, overlap in the 50-80 km region. Photodissociation of CO2 in the upper atmosphere and the subsequent transport of the atomic oxygen produced to the emitting layer are revealed as key factors in the nightglow emissions from these systems. The Mars 5 upper constraint for the product [H][O3] is revised on the basis of more recent values for the emission probabilities and collisional deactivation coefficients. 相似文献
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A global solution for the Mars static and seasonal gravity, Mars orientation, Phobos and Deimos masses, and Mars ephemeris 总被引：2，自引：0，他引：2
Alex S. Konopliv Charles F. Yoder E. Myles Standish Dah-Ning Yuan William L. Sjogren 《Icarus》2006,182(1):23-50
With the collection of six years of MGS tracking data and three years of Mars Odyssey tracking data, there has been a continual improvement in the JPL Mars gravity field determination. This includes the measurement of the seasonal changes in the gravity coefficients (e.g., , , , , , ) caused by the mass exchange between the polar ice caps and atmosphere. This paper describes the latest gravity field MGS95J to degree and order 95. The improvement comes from additional tracking data and the adoption of a more complete Mars orientation model with nutation, instead of the IAU 2000 model. Free wobble of the Mars' spin axis, i.e. polar motion, has been constrained to be less than 10 mas by looking at the temporal history of and . A strong annual signature is observed in , and this is a mixture of polar motion and ice mass redistribution. The Love number solution with a subset of Odyssey tracking data is consistent with the previous liquid outer core determination from MGS tracking data [Yoder et al., 2003. Science 300, 299-303], giving a combined solution of k2=0.152±0.009 using MGS and Odyssey tracking data. The solutions for the masses of the Mars' moons show consistency between MGS, Odyssey, and Viking data sets; Phobos GM=(7.16±0.005)×10−4 km3/s2 and Deimos GM=(0.98±0.07)×10−4 km3/s2. Average MGS orbit errors, determined from differences in the overlaps of orbit solutions, have been reduced to 10-cm in the radial direction and 1.5 m along the spacecraft velocity and normal to the orbit plane. Hence, the ranging to the MGS and Odyssey spacecraft has resulted in position measurements of the Mars system center-of-mass relative to the Earth to an accuracy of one meter, greatly reducing the Mars ephemeris errors by several orders of magnitude, and providing mass estimates for Asteroids 1 Ceres, 2 Pallas, 3 Juno, 4 Vesta, and 324 Bamberga. 相似文献
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Brian M. Cudnik 《Planetary and Space Science》2005,53(6):653-658
Hale-Bopp (C/1995 O1) was the most productive recent comet observed in terms of gas and dust output. Since its discovery in 1995 at a distance of 7.14 AU from the Sun, the comet has been well observed, revealing the dynamics of a rare and large comet. Hale-Bopp showed strong emissions of the principle cometary gases CN, C3, and C2, as well as an abundance of dust. The production rates of these gases were found to be 1.45×1028, 1.71×1028, and , respectively, with dust production, in terms of Afρ, , as measured in the green continuum (5260 Å). The observations for this paper are presented in two groups spanning 10 days each, one group centered near 32 days prior to and the other 21 days after perihelion. The averages of dust and gas production rates show a slightly higher value for each prior to perihelion than after perihelion, consistent with a possible peak in production a few weeks prior to perihelion passage. 相似文献
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We develop a parametric fit to the results of a detailed magnetohydrodynamic (MHD) study of the response of ion escape rates (O+, and ) to strongly varied solar forcing factors, as a way to efficiently extend the MHD results to different conditions. We then use this to develop a second, evolutionary model of solar forced ion escape. We treat the escape fluxes of ion species at Mars as proportional to the product of power laws of four factors - that of the EUV flux Reuv, the solar wind particle density Rρ, its velocity (squared) Rv2, and the interplanetary magnetic field pressure RB2, where forcing factors are expressed in units of the current epoch-averaged values. Our parametric model is: , where ?(i) is the escape flux of ion i. We base our study on the results of just six provided MHD model runs employing large forcing factor variations, and thus construct a successful, first-order parametric model of the MHD program. We perform a five-dimensional least squares fit of this power law model to the MHD results to derive the flux normalizations and the indices of the solar forcing factors. For O+, we obtain the values, 1.73 × 1024 s−1, 0.782, 0.251, 0.382, and 0.214, for ?0, α, β, γ, and δ, respectively. For , the corresponding values are 1.68 × 1024 s−1, −0.393, 0.798, 0.967, and 0.533. For , they are 8.66 × 1022 s−1, −0.427, 1.083, 1.214, and 0.690. The fit reproduces the MHD results to an average error of about 5%, suggesting that the power laws are broadly representative of the MHD model results. Our analysis of the MHD model shows that by itself an increase in REUV enhances O+ loss, but suppresses the escape of and , whereas increases in solar wind (i.e., in , and RB2, with Reuv constant) favors the escape of heavier ions more than light ions. The ratios of escaping ions detectable at Mars today can be predicted by this parametric fit as a function of the solar forcing factors. We also use the parametric model to compute escape rates over martian history. This second parametric model expresses ion escape functions of one variable (per ion), ?(i) = ?0(i)(t/t0)−ξ(i). The ξ(i) are linear combinations of the epoch-averaged ion escape sensitivities, which are seen to increase with ion mass. We integrate the and oxygen ion escape rates over time, and find that in the last 3.85 Gyr, Mars would have lost about mbars of , and of water (from O+ and ) from ion escape. 相似文献
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We present the results of additional calculations involving the collisions of km-scale rubble piles. In new work, we used the Open Dynamics Engine (ODE), an open-source library for the simulation of rigid-body dynamics that incorporates a sophisticated collision-detection and resolution routine. We found that using ODE resulted in a speed-up of approximately a factor of 30 compared with previous code. In this paper we report on the results of almost 1200 separate runs, the bulk of which were carried out with 1000-2000 elements. We carried out calculations with three different combinations of the coefficients of friction η and (normal) restitution ?: low (η=0,?=0.8), medium (η=0,?=0.5), and high (η=0.5,?=0.5) dissipation.For target objects of ∼1 km in radius, we found reduced critical disruption energy values in head-on collisions from 2 to 100 J kg−1 depending on dissipation and impactor/target mass ratio. Monodisperse objects disrupted somewhat more easily than power-law objects in general. For oblique collisions of equal-mass objects, mildly off-center collisions (b/b0=0.5) seemed to be as efficient or possibly more efficient at collisional disruption as head-on collisions. More oblique collisions were less efficient and the most oblique collisions we tried (b/b0=0.866) required up to ∼200 J kg−1 for high-dissipation power-law objects. For calculations with smaller numbers of elements (total impactor or 200 elements) we found that collisions were more efficient for smaller numbers of more massive elements, with values as low as for low-dissipation cases. We also analyzed our results in terms of the relations proposed by Stewart and Leinhardt [Stewart, S.T., Leinhardt, Z.M., 2009. Astrophys. J. 691, L133-L137] where where QR is the impact kinetic energy per unit total mass mi+mT. Although there is a significant amount of scatter, our results generally bear out the suggested relation. 相似文献
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We have observed (66652) 1999 RZ253 with the Hubble Space Telescope at seven separate epochs and have fit an orbit to the observed relative positions of this binary. Two orbital solutions have been identified that differ primarily in the inclination of the orbit plane. The best fit corresponds to an orbital period, days, semimajor axis a=4660±170 km and orbital eccentricity e=0.460±0.013 corresponding to a system mass m=3.7±0.4×1018 kg. For a density of the albedo at 477 nm is p477=0.12±0.01, significantly higher than has been commonly assumed for objects in the Kuiper belt. Multicolor, multiepoch photometry shows this pair to have colors typical for the Kuiper belt with a spectral gradient of 0.35 per 100 nm in the range between 475 and 775 nm. Photometric variations at the four epochs we observed were as large as 12±3% but the sampling is insufficient to confirm the existence of a lightcurve. 相似文献
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In July of 2005, the Deep Impact mission collided a 366 kg impactor with the nucleus of Comet 9P/Tempel 1, at a closing speed of 10.2 km s−1. In this work, we develop a first-order, three-dimensional, forward model of the ejecta plume behavior resulting from this cratering event, and then adjust the model parameters to match the flyby-spacecraft observations of the actual ejecta plume, image by image. This modeling exercise indicates Deep Impact to have been a reasonably “well-behaved” oblique impact, in which the impactor-spacecraft apparently struck a small, westward-facing slope of roughly 1/3-1/2 the size of the final crater produced (determined from initial ejecta plume geometry), and possessing an effective strength of not more than . The resulting ejecta plume followed well-established scaling relationships for cratering in a medium-to-high porosity target, consistent with a transient crater of not more than 85-140 m diameter, formed in not more than 250-550 s, for the case of (gravity-dominated cratering); and not less than 22-26 m diameter, formed in not less than 1-3 s, for the case of (strength-dominated cratering). At , an upper limit to the total ejected mass of 1.8×107 kg (1.5-2.2×107 kg) is consistent with measurements made via long-range remote sensing, after taking into account that 90% of this mass would have stayed close to the surface and then landed within 45 min of the impact. However, at , a lower limit to the total ejected mass of 2.3×105 kg (1.5-2.9×105 kg) is also consistent with these measurements. The expansion rate of the ejecta plume imaged during the look-back phase of observations leads to an estimate of the comet's mean surface gravity of (0.17-0.90 mm s−2), which corresponds to a comet mass of mt=4.5×1013 kg (2.3-12.0×1013 kg) and a bulk density of (200-1000 kg m−3), where the large high-end error is due to uncertainties in the magnitude of coma gas pressure effects on the ejecta particles in flight. 相似文献
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The relationship between the organic and D/H ratios in small Solar System bodies (meteorites, interplanetary dust and comets) suggests that isotopic exchange reactions taking place at various temperatures are at the origin of the observed variations. These relationships are used to determine the exothermicity (ΔE) of ion-molecule reactions that fractionated the nitrogen isotopic ratio in the presolar molecular cloud; that is ΔE=43±10 K. Comparison with current models of interstellar chemistry suggests that such a value could be achieved by condensation of 15N-rich gas-phase precursors onto grain surfaces and their further isolation from the gas by incorporation into large macromolecular structures. 相似文献
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Gravity field and interior of Rhea from Cassini data analysis 总被引：1，自引：0，他引：1
Luciano Iess Nicole J. Rappaport Jonathan Lunine Sami W. Asmar Francesco Zingoni 《Icarus》2007,190(2):585-593
The Cassini spacecraft encountered Rhea on November 26, 2005. Analysis of the Doppler data acquired at and around closest approach yields the mass of Rhea and the quadrupole moments of its gravity field with unprecedented accuracy. We obtained which corresponds to a density of . Our results for J2 and C22 are (7.947±0.892)×10−4 and (2.3526±0.0476)×10−4, respectively. These values are consistent with hydrostatic equilibrium. From the value of C22, we infer the non-dimensional moment of inertia C/MR2=0.3721±0.0036. Our models of Rhea's interior based on the gravity data favor an almost undifferentiated satellite. A discontinuity between a core and a mantle is possible but not required by the data. Models with a constant silicate mass fraction throughout the body cannot account for the determined quadrupole coefficients. The data exclude fully differentiated models in which the core would be composed of unhydrated silicates and the mantle would be composed of pure ice. If the mantle contains 10% in mass of silicates, the core extends to 630 km in radius and has a silicate mass fraction of 40%. A continuous model in which the silicates are more concentrated toward the center of the body than in the outer layers is allowed by the gravity data but excluded by thermal evolution considerations. The one model that fits the gravity data and is self-consistent when energy transport and ice melting are qualitatively considered is an “almost undifferentiated” Rhea, in which a very large uniform core is surrounded by a relatively thin ice shell containing no rock at all. 相似文献
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We present thermal infrared photometry and spectrophotometry of six Near-Earth Asteroids (NEAs) using the 3.8 m United Kingdom Infrared Telescope (UKIRT) together with quasi-simultaneous optical observations of five NEAs taken at the 1.0 m Jacobus Kapteyn Telescope (JKT). For Asteroid (6455) 1992 HE we derive a rotational period P=2.736±0.002 h, and an absolute visual magnitude H=14.32±0.24. For Asteroid 2002 HK12 we derive . The Standard Thermal Model (STM), the Fast Rotating Model (FRM) and the Near-Earth Asteroid Thermal Model (NEATM) have been fitted to the measured fluxes to derive albedos and effective diameters. The derived geometric albedos and effective diameters are (6455) 1992 HE: pv=0.26±0.08, Deff=3.55±0.5 km; 1999 HF1: pv=0.18±0.07, ; 2000 ED104: pv=0.18±0.05, Deff=1.21±0.2 km; 2002 HK12: , Deff=0.62±0.2 km; 2002 NX18: pv=0.031±0.009, Deff=2.24±0.3 km; 2002 QE15: , Deff=1.94±0.4 km. The limitations of using the NEATM to observe NEAs at high phase angles are discussed. 相似文献
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The J = 3-2 rotational line of CO in Neptune has been measured using the heterodyne receiver B3 at the JCMT. The spectral resolution was 1.25 MHz and 25 tunings were used to cover a frequency range of almost 20 GHz. The measured line shape, encompassing both the broad absorption feature arising in the lower atmosphere and a narrow emission core from the upper stratosphere, indicates that the CO mole ratio is not uniform with altitude, with best-fit values of in the upper stratosphere and 0.6±0.4×10−6 in the lower stratosphere and troposphere. The higher stratospheric abundance indicates that a dual, internal and external, origin of CO is most likely. 相似文献