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1.
Granular activated carbon produced from palm kernel shell was used as adsorbent to remove copper, nickel and lead ions from a synthesized industrial wastewater.Laboratory experimental investigation was carried out to identify the effect of pH and contact time on adsorption of lead, copper and nickel from the mixed metals solution. Equilibrium adsorption experiments at ambient room temperature were carried out and fitted to Langmuir and Freundlich models. Results showed that pH 5 was the most suitable, while the maximum adsorbent capacity was at a dosage of 1 g/L, recording a sorption capacity of 1.337 mg/g for lead, 1.581 mg/g for copper and 0.130 mg/g for nickel. The percentage metal removal approached equilibrium within 30 min for lead, 75 min for copper and nickel, with lead recording 100 %, copper 97 % and nickel 55 % removal, having a trend of Pb2+ > Cu2+ > Ni2+. Langmuir model had higher R2 values of 0.977, 0.817 and 0.978 for copper, nickel and lead respectively, which fitted the equilibrium adsorption process more than Freundlich model for the three metals.  相似文献   

2.
The objective of the present study is to evaluate the absorption efficacy of H. fusiformis biochar (HFB) for the removal of phenol and heavy metals from single and mixed solute systems of these species under different experimental conditions. The effects of contact time, pH change, initial phenol concentration, and heavy metal concentration on the adsorption capacity of HFB were investigated. The kinetics and equilibrium models of sorption of the components of the single and mixed solute systems on HFB were also studied. The experimental data were fitted to kinetic and equilibrium models. The batch experiments revealed that 360 min of contact time was sufficient to achieve equilibrium for the adsorption of both phenol and heavy metals. The adsorption of phenol and nickel by HFB followed the pseudo-second-order kinetic model, which was quite adequate for describing the adsorption mechanism. The equilibrium data for the adsorption of phenol and heavy metals fit well to the Langmuir model with regression coefficients of R 2 > 0.819. The maximum Langmuir adsorption capacities were 10.39, 12.13, 22.25, 2.24, 2.89, and 22.03 mg/g for phenol, Ni2+, Zn2+, Cu2+, Pb2+, and Cd2+, respectively. Moreover, HFB exhibited optimal sorption under slightly acidic conditions at pH 6. The HFB used in the present study exhibited higher adsorption capacity for the removal of phenol and heavy metals from aqueous solutions compared to documented sorbents. These results demonstrate that HFB is potentially useful for alleviating the harmful effects of phenol and heavy metal in wastewater treatment systems.  相似文献   

3.
A binary mixture of humic acid and geothite was prepared and used to modify kaolinite to produce geothite–humic acid (GHA)-modified kaolinite adsorbent useful for the adsorption of Pb2+, Cd2+, Zn2+, Ni2+ and Cu2+ from Single and Quinary (5) metal ion systems. The cation exchange capacity (CEC) and specific surface area of GHA-modified kaolinite clay adsorbent were found to be 40 meq/100 g and 13 m2/g, respectively, with the CEC being five times that of raw kaolinite clay (7.81 meq/100 g). The Langmuir–Freundlich equilibrium isotherm model gave better fit to experimental data as compared with other isotherm models. In Quinary metal ion system, the presence of Zn2+ and Cu2+ appears to have an antagonistic effect on the adsorption of Pb2+, Cd2+ and Ni2+, while the presence of Pb2+, Cd2+ and Ni2+ shows a synergistic effect on the adsorption of Zn2+ and Cu2+. The GHA-modified kaolinite showed strong preference for the adsorption of Pb2+ in both metal ion systems. Brouers–Weron–Sotolongo (BWS) kinetic model gave better fit to kinetic data compared with other kinetic models used. Data from BWS kinetic model indicate that adsorption of metal ions onto GHA-modified adsorbent in both metal ion systems followed strictly, diffusion-controlled mechanism with adsorption reaction proceeding to 50 % equilibrium in <2 min in the Single metal ion system and <1 min in the Quinary metal ion system. Adsorption of metal ions onto GHA-modified kaolinite is fairly spontaneous and endothermic in nature in both metal ion systems although the rate of metal ion uptake and spontaneity of reaction are reduced in the Quinary metal ion system.  相似文献   

4.
Nile Rose Plant was used to study adsorption of several cations (Cu2+, Zn2+, Cd2+ and Pb2+) from wastewater within various experimental conditions. The dried leaves of Nile Rose Plant were used at different adsorbent/ metal ion ratios. The influence of pH, contact time, metal concentration, and adsorbent loading weight on the removal process was investigated. Batch adsorption studies were carried out at room temperature. The adsorption efficiencies were found to be pH dependent, increasing by increasing the pH in the range from 2.5 to 8.5 exept for Pb. The equilibrium time was attained within 60 to 90 min. and the maximum removal percentage was achieved at an adsorbent loading weight of 1.5 g/50 mL mixed ions solution. Isothermal studies showed that the data were best fitted to the Temkin isotherm model. The removal order was found to be Pb2+> Zn2+> Cu2+> Cd2+. The surface IR-characterization of Nile rose plant showed the presence of many functional groups capable of binding to the metal cations.  相似文献   

5.
This paper investigates the potential of alginate-immobilised Chlorella sorokiniana for removing Cu2+, Ni2+ and Cd2+ ions from drinking water solutions. The effects of initial metal concentrations, contact times and temperatures on the biosorptions and removal efficiencies of the tested metals were investigated at initial pH values of 5, and pH effects were studied within the range of 3–7. When studying the effects of initial metal concentrations, the highest experimental removal yields achieved for Cu2+, Ni2+ and Cd2+ ions were 97.10, 50.94 and 64.61 %, respectively. The maximum biosorption capacities obtained by the Langmuir isotherm model for the biosorptions of Cu2+, Ni2+ and Cd2+ ions by alginate-immobilised C. sorokiniana were found to be 179.90, 86.49 and 164.50 mg/g biosorbent, respectively. The experimental data followed pseudo-second-order kinetics. At an initial metal concentration of 25 mg/L, immobilised algae could be used in at least 5 successive biosorption–desorption cycles. SEM and EDS analyses revealed that the metals bonded to the biosorbent. Bi- and multi-metal systems of Cu2+, Ni2+ and Cd2+ were investigated at initial metal concentrations of 30, 50 and 100 mg/L. The removal of Cd2+ as well as Ni2+ in such systems was negatively affected by the presence of Cu2+. The removal efficiency for Cu2+ in multi-metal systems decreased by 5–7 %, whilst in the cases of Cd2+ and Ni2+ the efficiencies decreased by up to 30 %. Nevertheless, the results obtained show that alginate-immobilised C. sorokiniana can efficiently remove the metals tested from polluted drinking water sources.  相似文献   

6.
Adsorption of copper and zinc by oil shale   总被引：8，自引：0，他引：8  
 Oil shale is able to remove appreciable amounts of copper and zinc ions from aqueous solutions. It was noted that an increase in the adsorbent concentration with constant copper or zinc concentration resulted in greater metal removal from solution. An increase in the copper or zinc concentration with a constant sorbent concentration resulted in higher metal loading per unit weight of sorbent. For both metals, copper and zinc, equilibrium was attained after 24-h contact time. Increase in the initial pH or temperature of the metal solution resulted in an increase in the metal uptake per unit weight of the sorbent. Freundlich isotherm model was found to be applicable for the experimental data of Cu2+ and Zn2+. The results showed that oil shale could be used for the adsorption of the Cu2+ and Zn2+ with higher affinity toward Zn2+ ions. Addition of sodium salt to the metal solution influenced copper removal positively, but inhibited zinc removal. Received: 3 January 2000 · Accepted: 27 June 2000  相似文献   

7.
The removal of Pb2+ from aqueous solution by two Brazilian rocks that contain zeolites—amygdaloidal dacite (ZD) and sandstone (ZS)—was examined by batch experiments. ZD contains mordenite and ZS, stilbite. The effects of contact time, concentration of metal in solution and capacity of Na+ to recover the adsorbed metals were evaluated at room temperature (20°C). The sorption equilibrium was reached in the 30 min of agitation time. Both materials removed 100% of Pb2+ from solutions at concentrations up to 50 mg/L, and at concentrations larger than 100 mg/L of Pb2+, the adsorption capacity of sandstone was more efficient than that of amygdaloidal dacite due to the larger quantities and the type of zeolites (stilbite) in the cement of this rock. All adsorbed Pb2+ was easily replaced by Na+ in both samples. The analysis of the adsorption models using nonlinear regression revealed that the Sips and the Freundlich isotherms provided the best fit for the ZS and ZD experimental data, respectively, indicating the heterogeneous adsorption surfaces of these zeolites.  相似文献   

8.
邵坤  赵改红  赵朝辉 《岩矿测试》2019,38(6):715-723
磁铁矿是一种绿色廉价的矿物材料,对水体中重金属离子具有良好的吸附性,但吸附容量低,选择性差,易团聚,通过改性可以克服该缺点并提高其吸附性能。本文以腐植酸为改性剂,采用常温水相反应制备了腐植酸改性磁铁矿吸附材料。通过傅里叶红外光谱(FTIR)、扫描电镜(SEM)和X射线光电子能谱(XPS)表征研究其表面形貌和微观结构。采用静态平衡实验考察了pH、吸附时间等因素对铅、镉吸附性能的影响,探讨了吸附动力学规律,拟合了吸附等温线。结果表明:腐植酸上的羧基、羟基被成功地接枝到了磁铁矿表面。在室温下,溶液初始pH对Pb~(2+)的吸附率几乎无影响,对Cd~(2+)的影响较大,当pH=7时,Pb~(2+)和Cd~(2+)吸附率均达到了95%。对初始质量浓度为10mg/L的Pb~(2+)、Cd~(2+)最佳吸附平衡时间为360min,吸附过程符合准二级动力学方程。吸附等温线实验得到的竞争吸附顺序为Pb~(2+)Cd~(2+),由Langmuir等温吸附模型得到Pb~(2+)、Cd~(2+)饱和吸附容量分别为39.27mg/g、28.95mg/g,显著大于磁铁矿的饱和吸附容量,表明磁铁矿经腐植酸改性后增强了对水中铅镉的吸附能力。  相似文献   

9.
The interaction between minerals and heavy metals has been a hot object of study in environmental science,mineralogy and soil science,Through the selective adsorption experiment of Ca-montomorillonite,illite and kaolinite to Cu2 ,Pb^2 ,Zn^2 ,Cd^2 ,and Cr^3 ions at certain conditions,it could be concluded that Cr^3 is most effectively sorbed by all the three minerals.Also,it can be found that Pb^2 shows a strong affinity for illite and kaolinite while cu^2 for montmorillonite .Based on the adsorption experiment at varying pH of solution,it can be found that the amount of heavy etals sorbed by minerals increases with increasing pH of the solution.  相似文献   

10.
Adsorption of divalent metal ions, including Cu2+, Pb2+, Zn2+, Cd2+ and Ni2+, on quartz surface was measured as a function of metal ion concentration at 30°C under conditions of solution pH= 6. 5 and ion strength I = 0. 1mol/L. Results of the experimental measurements can be described very well by adsorption isotherm equations of Freudlich. The correlation coefficients (r) of adsorption isotherm lines are > 0. 96. Moreover, the experimental data were interpreted on the basis of surface complexation model. The experimental results showed that the monodentate-coordinated metal ion surface complex species (SOM+) are predominant over the bidentate-coordinated metal ion surface complex species [(SO)2M] formed only by the ions Cu2+, Zn2+ and Ni2+. And the relevant apparent surface complexation constants are lgKM = 2.2–3.3 in order of KCd≥KPb > KZn > KNi≥KCu, and lgβM = 5.9-6.8 in order of βNi > βZn > βCu. Therefore, the reactive ability of the ions onto mineral surface of quartz follows the order of Cd > Pb > Zn > Ni> Cu under the above-mentioned solution conditions. The apparent surface complexation constants, influenced by the surface potential, surface species and hydrolysis of metal ions, depend mainly on the Born solvation coefficient of the metal ions. This project was financially supported by the National Natural Science Foundation of China (No. 49572091).  相似文献   

11.
In this study, sepiolite-nano zero valent iron composite was synthesized and applied for its potential adsorption to remove phosphates from aqueous solution. This composite was characterized by different techniques. For optimization of independent parameters (pH = 3–9; initial phosphate concentration = 5–100 mg/L; adsorbent dosage = 0.2–1 g/L; and contact time = 5–100 min), response surface methodology based on central composite design was used. Adsorption isotherms and kinetic models were done under optimum conditions. The results indicated that maximum adsorption efficiency of 99.43 and 92% for synthetic solution and real surface water sample, respectively, were achieved at optimum conditions of pH 4.5, initial phosphate concentration of 25 mg/L, adsorbent dosage of 0.8 g/L, and 46.26 min contact time. The interaction between adsorbent and adsorbate is better described with the Freundlich isotherm (R 2 = 0.9537), and the kinetic of adsorption process followed pseudo-second-order model. Electrostatic interaction was the major mechanisms of the removal of phosphates from aqueous solution. The findings of this study showed that there is an effective adsorbent for removal of phosphates from aqueous solutions.  相似文献   

12.
本文首先分析了江西德兴铜矿区周围土壤的微量元素和矿物组成特征,结果显示该地区重金属元素富集,且表层土中重金属元素含量与粘土矿物相对含量变化具有较好的一致性。室内土柱淋滤实验结果表明,当总淋滤时间为451 h时,土壤对Pb2+的总吸附量为2 584.75 mg/kg,淋滤实验的前半期存在多种竞争吸附机制,后半期土壤对Pb2+的吸附基本达到动态平衡。淋滤后土壤矿物的相对质量分数发生了改变,粘土矿物有所减少。粘土矿物在不同土壤层对Pb2+的吸附能力也各异。  相似文献   

13.
In this study, the speciation of Zn2+, Pb2+, and Cu2+ ions sorbed at the calcite surface was monitored during a 2.5-year reaction period, using extended X-ray absorption spectroscopy to characterize metal speciation on the molecular scale. Experiments were performed using pre-equilibrated calcite-water suspensions of pH 8.3, at metal concentrations below the solubility of metal hydroxide and carbonate precipitates, and at constant metal surface loadings. The EXAFS results indicate that all three metals remained coordinated at the calcite surface as inner-sphere adsorption complexes during the 2.5-year ageing period, with no evidence to suggest slow formation of dilute metal-calcite solid solutions under the reaction conditions employed. All three divalent metals were found to form non-octahedral complexes upon coordination to the calcite surface, with Zn2+ adsorbing as a tetrahedral complex, Cu2+ as a Jahn-Teller distorted octahedral complex, and Pb2+ coordinating as a trigonal- or square-pyramidal surface complex. The non-octahedral configurations of these surface complexes may have hindered metal transfer from the calcite surface into the bulk, where Ca2+ is in octahedral coordination with respect to first-shell O. The use of pre-equilibrated calcite suspensions, with no net calcite dissolution or precipitation, likely prevented metal incorporation into the lattice as a result of surface recrystallization. The results from this study imply that ageing alone does not increase the stability of Zn2+, Pb2+, and Cu2+ partitioning to calcite if equilibrium with the solution is maintained during reaction; under these conditions, these metals are likely to remain available for exchange even after extended sorption times.  相似文献   

14.
Various soil zones such as Bw, C1, and C3 are developed on spilite. Montmorillonite, vermiculite and chlorite is moderately occurred in the C1 and C3 soil zones, in contrast montmorillonite and vermiculite are absent in Bw soils whereas illite and sesquioxide are relatively increased. The high cation exchange capacity (CEC) of montmorillonite and vermiculte and moderate CEC of chlorite and illite resulted in the high adsorption of heavy metals. The adsorption of the heavy metals on spilite soil zones was studied at different concentrations and pH levels. Heavy metals like lead, cadmium, and copper were selected for adsorption studies considering their contribution as toxic metals in the environment. The initial solute concentrations ranged from 7.0 × 10−3 to 1.0 × 102 mg/L. The sorption behavior of Cd2+, Pb2+, and Cu2+ on soil zones of spilite was investigated using the batch equilibrium technique at 25°C. The characteristics of the adsorption process were investigated using Scatchard plot analysis (q/C vs. q) by the batch equilibrium technique at 25°C. In the adsorption of heavy metals, deviation from linearity in the plot of q/C versus q was observed, indicating the presence of multi-model interaction and non-Langmuirean behavior. When the Scatchard plot showed a deviation from linearity, greater emphasis was placed on the analysis of the adsorption data in terms of the Freundlich model, in order to construct the adsorption isotherms of the metal(s) at particular concentration(s) in solutions. The adsorption behavior of these metal ions on spilite soil zones is expressed by the Freundlich isotherms. Adsorption constants and correlation coefficients for the Cd, Pb, and Cu on spilite soil zones were calculated from Freundlich plots.  相似文献   

15.
The impacts of common ions on the adsorption of heavy metal   总被引：1，自引：0，他引：1  
Researches on the impact of common ions onto sediments are of great importance for the study of the heavy metal adsorption mechanisms. Considering the surface sediments from the relatively clean reach in the Baotou section of the Yellow River as the adsorbent, this work presents the impacts of common ions (Na+, Mg2+, K+, Ca2+, Cl−, SO4 2−, and NH4 +) on heavy metals (Cu2+, Zn2+, Cd2+, and Pb2+) adsorption. The experimental results reveal that the adsorptive capacities of the heavy metals are controlled by different adsorption mechanisms in different ion concentration ranges. With the increase of the ionic strength, the adsorption of the heavy metals increases for the compression of the electric double layer, whereas decreases for the decreasing of the ionic activities of the heavy metals. The competitive adsorption and complexations between the heavy metals and common ions are also important factors controlling the heavy metal adsorption. According to the experimental results and the real concentration of common ions in the Baotou section of the Yellow River, the increase of the concentrations of Na+, Mg2+, K+, and Ca2+ would cause the increase of Zn2+ adsorption and reduce the Zn pollution. The NH4 + from the industrial discharge of the tributaries has a strong impact on the heavy metal adsorption.  相似文献   

16.
Tetraethylenepentamine-modified sugarcane bagasse (SCB) was prepared to improve its adsorption capacity and selectivity toward Cu2+. Adsorption performances of the modified sorbent for Cu2+ were studied in batch system. Separation of Cu2+ from Pb2+ by the modified sorbent fixed-bed column were studied under dynamic system with initial molar concentration ratio \(\left( {C_{0}^{\text{Cu}} /C_{0}^{\text{Pb}} } \right)\) ranging from 1:1 to 1:100. The amount of Cu2+ and Pb2+ adsorbed on the saturated column was calculated by the elution curve. Batch experimental results showed that the adsorption capacity of the sorbent for Cu2+ increased from 0.12 to 0.21 mmol g?1 after modification. Dynamic adsorption results showed that the modified SCB had higher adsorption affinity toward Cu2+ than Pb2+. 0.07 mmol g?1 of adsorbed Pb2+ was pushed off by Cu2+ during the competitive adsorption process at \(C_{0}^{\text{Cu}} /C_{0}^{\text{Pb}} = {\text{1:1}}.\) The breakthrough curves and adsorption kinetics of Cu2+ in the column could be fitted well by the Yoon–Nelson and modified Yoon–Nelson model, respectively. According to the elution curve, the amount of Cu2+ adsorbed on the fixed-bed column were 0.16, 0.16 and 0.15 mmol g?1, while that of Pb2+ were 0.0016, 0.0051 and 0.0094 mmol g?1 when \(C_{0}^{\text{Cu}} /C_{0}^{\text{Pb}}\) increased from 1:1 to 1:10 and 1:100. Cu2+ could be selectively adsorbed and separated from Pb2+ by using the modified sorbent fixed-bed column.  相似文献   

17.
The limitation of plant growth in the polluted mediums can be used as a factor to determine of plant tolerance and the toxic effect of these mediums. In this work, the effect of Pb2+, Cd2+, Ni2+and Znsu2+ (individually) on Azolla filiculoides growth in the aqueous solution and using this method to water post treatment were studied. During 15 days the biomass the fresh Azolla with initial mass of 20 g was grown on the nutrient solution containing these metal ions, each in a concentration 4 mg/l. The presence of these ions, caused about 25%, 42%, 31% and 17% inhibition of biomass growth, respectively, in comparison to Azolla control weight which had not heavy metals. The water salinity of 1, 2 and 4 g. NaCl/l decreased the removal of these heavy metals about 4–7%, 20–24% and 40–55%, respectively. The addition of total dissolved solids (TDS) from 50 to 300 ppm. (as CaCO3) into the samples of containing heavy metals increased Azolla growth, but decreased the control Azolla growth.  相似文献   

18.
Heavy metal ions (Pb2+, Cd2+, Ni2+, and Zn2+) were biosorbed by brown seaweed (Hizikia fusiformis), which was collected from Jeju Island of South Korea. The metal adsorption capacity of H. fusiformis improved significantly by washing with water or by base or acid treatments. The maximum sorption by NaOH-pretreated biomass was observed near a slightly acidic pH (pH 4?6) for Pb2+, Cd2+, Ni2+, and Zn2+. This result suggests that the treatment of H. fusiformis biomass with NaOH helped increase the functional forms of carboxylate ester units. Kinetic data showed that the biosorption occurred rapidly during the first 60 min, and most of the heavy metals were bound to the seaweed within 180 min. The maximum metal adsorption capacities assumed by a Langmuir model were on the order of Pb2+ > Cd2+ > Ni2+ > Zn2+. Equilibrium adsorption data for the heavy metal ions could fit well in the Langmuir model with regression coefficients R 2 > 0.97.  相似文献   

19.
The ability of light expanded clay aggregate to remove lead and cadmium from paint industry’s effluents was studied at different levels of adsorbent, contact time and pH in April 2008. For this purpose, lead and cadmium removal from paint industry effluents were studied in batch reactors. lead and cadmium measurements have been taken with non-flame atomic absorption techniques and test methods were adapted from 19th. Ed. of standard methods for the examination of water and wastewater. In this study, different amounts of Leca (1, 2, 3, 4, 5, 6, 7, 8, 9 and 10 g/L) were investigated. The amount of adsorbed lead and cadmium exposure to Leca increased from 1.41 to 3 mg/g and 0.22 to 0.75 mg/g, respectively. The maximum removal efficiency for Pb was 93.75 % at pH = 7 and exposure to 10 g/L of Leca, while for cadmium, it was nearly 89.7 % at the same condition. In this study, adsorption process of lead and cadmium was fitted with Freundlich adsorption isotherm (R2 Pb = 0.97 and R2 Cd = 0.98). The sufficient contact time was deemed 1–2 h for lead and cadmium. According to the results, Leca is recommended as a low cost and available adsorbent to remove lead and cadmium from industrial wastewater.  相似文献   

20.
This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO4=) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO4= anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb2+, Zn2+, Cu2+, Cd2+, Mn2+, Co2+, Ni2+) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10−1) of the SO 4= ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.  相似文献   

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