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1.
Experiments [T. Irifune (1994) Nature 370, 131–133; E. Ito et al. (1998) Geophys. Res. Lett. 25, 821–824; A. Kubo, M. Akaogi (2000) Phys. Earth Planet. Int. 121, 85–102] indicate that (Mg,Fe)SiO3 perovskite, commonly believed to be the most abundant mineral in the Earth, is the preferred host phase of Al2O3 in the Earth’s lower mantle. Aiming to better understand the effects of Al2O3 on the thermoelastic properties of the lower mantle, we use atomistic models to examine the chemistry and elasticity of solid solutions within the MgSiO3(perovskite)–Al2O3(corundum)–MgO(periclase) mineral assemblage under conditions pertinent to the lower mantle: low Al cation concentrations, P=25–100 GPa, and T=1000–2000 K. We assess the relative stabilities of two likely substitution mechanisms of Al into MgSiO3 perovskite in terms of reactions involving MgSiO3, MgO, and Al2O3, in a manner similar to the 0 Kelvin calculations of Brodholt [J.P. Brodholt (2000) Nature 407, 620–622] and Yamamoto et al. [T. Yamamoto et al. (2003) Earth Planet. Sci. Lett. 206, 617–625]. We determine the equilibrium composition of the assemblage by examining the chemical potentials of the Al2O3 and MgO components in solid solution with MgSiO3, as functions of concentration. We find that charge coupled substitution dominates at lower mantle pressures and temperatures. Oxygen vacancy-forming substitution accounts for 3–4% of Al substitution at shallow lower mantle conditions, and less than 1% in the deep mantle. For these two pressure regimes, the corresponding adiabatic bulk moduli of aluminous perovskite are 2% and 1% lower than that of pure MgSiO3 perovskite.  相似文献   

2.
The elastic moduli of ScAlO3 perovskite, a very close structural analogue for MgSiO3 perovskite, have been measured between 300 and 600 K using high precision ultrasonic interferometry in an internally heated gas-charged pressure vessel. This new capability for high temperature measurement of elastic wave speeds has been demonstrated on polycrystalline alumina. The temperature derivatives of elastic moduli of Al2O3 measured in this study agree within 15% with expectations based on published single-crystal data. For ScAlO3 perovskite, the value of (∂KS/∂T)P is −0.033 GPa K−1 and (∂G/∂T)P is −0.015 GPa K−1. The relative magnitudes of these derivatives agree with the observation in Duffy and Anderson [Duffy, T.S., Anderson, D.L., 1989. Seismic velocities in mantle minerals and the mineralogy of the upper mantle. J. Geophys. Res. 94, 1895–1912.] that |(∂KS/∂T)P| is typically about twice |(∂G/∂T)P|. The value of (∂KS/∂T)P for ScAlO3 is intermediate between those inferred less directly from V(P,T) studies of Fe-free and Fe- and Al-bearing MgSiO3 perovskites [Wang, Y., Weidner, D.J., Liebermann, R.C., Zhao, Y., 1994. P–V–T equation of state of (Mg,Fe)SiO3 perovskite: constraints on composition of the lower mantle. Phys. Earth Planet. Inter. 83, 13–40; Mao, H.K., Hemley, R.J., Shu, J., Chen, L., Jephcoat, A.P., Wu, Y., Bassett, W.A., 1991. Effect of pressure, temperature and composition on the lattice parameters and density of (Mg,Fe) SiO3 perovskite to 30 GPa. J. Geophys. Res. 91, 8069–8079; Zhang, Weidner, D., 1999. Thermal equation of state of aluminum-enriched silicate perovskite. Science 284, 782–784]. The value of |(∂G/∂T)|P for ScAlO3 is similar to those of most other mantle silicate phases but lower than the recent determination for MgSiO3 perovskite [Sinelnikov, Y., Chen, G., Neuville, D.R., Vaughan, M.T., Liebermann, R.C., 1998. Ultrasonic shear wave velocities of MgSiO3 perovskite at 8 GPa and 800K and lower mantle composition. Science 281, 677–679].

Combining the results from the previous studies and current measurements on ScAlO3 perovskite, we extracted the parameters (q and γ0) needed to fully specify its Mie–Grüneisen–Debye equation-of-state. In this study, we have demonstrated that acoustic measurements of KS(T), unlike V(P,T) data, tightly constrain the value of q. It is concluded that ScAlO3 has ‘normal’ γ0 (1.3) and high q (3.6). The high value of q indicates that ScAlO3 has very strong intrinsic temperature dependence of the bulk modulus; similar behaviour has been observed in measurements on Fe- and Al-bearing silicate perovskites (Mao et al., 1991; Zhang and Weidner, 1999).  相似文献   


3.
We investigated the physical properties in the upper mantle beneath the Philippine Sea using a theoretical relation derived by Karato [Mapping water content in the upper mantle. Subduction factory, AGU Monograph, in press]. From the attenuation model of Shito and Shibutani [Phys. Earth Planet. Interact., in press] and the velocity model of Widiyantoro et al. [Earth Planet. Sci. Lett. 173 (1999) 91], observed attenuation and velocity anomalies were evaluated to explain the temperature, water content, and chemical heterogeneities in the target area. The results indicate that the observed anomalies in the shallower regions (50–200 km) may be due to chemical composition effects (e.g., concentration of iron), in addition to the temperature and water content anomalies. In contrast, for the deep upper mantle (300–400 km), the observations can be explained by only the effects of high water content (10–50 times higher than the average mantle). These inferred properties of the mantle are consistent with the tectonic history of the Philippine Sea region, which has had a long history of subduction and active magmatism.  相似文献   

4.
Fresh basalt glasses from the North Chile Ridge (NCR) in the southeastern Pacific have Ne isotopic compositions distinctly different from typical mid-ocean ridge basalts (MORB). In a three-isotope plot of 20Ne/22Ne vs. 21Ne/22Ne, the NCR data define a correlation line with a slope smaller than that of the MORB correlation line, i.e. their Ne composition is more nucleogenic than that of MORB. 3He/4He ratios are slightly lower than the MORB average, whereas in a few stepwise heating fractions very high 40Ar/36Ar ratios up to 28,000 are found. One model to explain the data assumes contamination of the NCR mantle source by material from the continental or oceanic crust, but in addition to difficulties with quantitatively reconciling the noble gas patterns with such a model it seems unable to account for some geochemical characteristics of NCR basalts reported earlier [Bach et al., Earth Planet. Sci. Lett. 142 (1996) 223–240], such as depletions in highly incompatible elements and unradiogenic Sr isotope compositions. Therefore we favor the scenario of a mantle source which was depleted and degassed previously, possibly as a residue from mantle melting beneath the southern East Pacific Rise that was transported to the NCR and melted again. The time during which such a depleted reservoir would have to be separated from the MORB mantle is estimated at 10–100 Ma based on U/Th–Ne systematics, in reasonable agreement with the time scale deduced from the formation history of the NCR and the temporal evolution of the southeast Pacific.  相似文献   

5.
Glacial–interglacial variation in the marine Sr/Ca ratio has important implications for coral Sr thermometry [J.W. Beck et al., Science 257 (1992) 644–647]. A possible variation of 1–3% was proposed based on ocean models [H.M. Stoll and D.P. Schrag, Geochim. Cosmochim. Acta 62 (1998) 1107–1118]. Subsequently, studies have used fossil foraminifera to test this prediction [P.A. Martin et al., Geochem. Geophys. Geosyst. 1 (1999); H.M. Stoll et al., Geochim. Cosmochim. Acta 63 (1999) 3535–3547; H. Elderfield et al., Geochem. Geophys. Geosyst. 1 (2000)]. But whether some component of foraminiferal Sr/Ca variation can be uniquely ascribed to seawater Sr variation is still not clear. To address this question, we developed cleaning and analysis techniques and measured Sr/Ca ratios on individual shells of the modern benthic foraminifer Cibicidoides wuellerstorfi. We showed that different size shells have different Sr/Ca ratios; however, samples with shell sizes of 355–500 μm appear to have normally distributed Sr/Ca ratios (1σ=1.8%). For multi-shell measurements (with estimated errors of 0.12–0.39%), the ratio varied by as much as 7.2±0.5% during the last glaciation for two Caribbean records at the same site and by 3.7±0.5% over the past 40,000 yr for one record from the Sierra Leone Rise in the eastern equatorial Atlantic. The two Caribbean records are very similar indicating that the behavior of shell Sr uptake was identical locally and that the shell Sr/Ca ratio faithfully reflects the local environment. The Atlantic record differs from the Caribbean records by as much as several percent. Thus, the foraminiferal Sr/Ca changes cannot be solely due to changes in seawater Sr/Ca unless the glacial deep ocean had spatial variation in Sr/Ca well in excess of the modern ocean. Certain similarities between the three records do exist. Notably, the rate of change of Sr/Ca is similar between 9 and 0 ka (−0.25%/kyr) and between 25 and 16 ka (+0.16%/kyr). This suggests that during these intervals, benthic foraminiferal Sr/Ca was affected by similar large-scale variables. One of these variables may be the average marine Sr/Ca ratio; however, comparison with model predictions [H.M. Stoll and D.P. Schrag, Geochim. Cosmochim. Acta 62 (1998) 1107–1118] suggests other factors must also be considered. The discrepancies between the two sites may be related to the different water mass histories for the Caribbean and eastern Atlantic. Our results suggest that variation of the seawater Sr budget only partially contributed to C. wuellerstorfi Sr/Ca records, while other significant factors still need to be quantified. At present we cannot confidently determine past seawater Sr/Ca variation from our foraminiferal records.  相似文献   

6.
Nine new intermediate water ages estimated with coupled uranium-series and radiocarbon measurements on deep-sea corals from the northeastern Atlantic are presented. Together with six intermediate and deep-water ages from the western North Atlantic [Adkins et al., Science 280 (1998) 725-728] and one from the equatorial Atlantic [Mangini et al., Nature 392 (1998) 347-348] they span the time period from 15?400 to 560 yr ago and show abrupt variations of intermediate and deep-water ages from 270 up to 2320 yr. Both major pulses of meltwater discharge MWP 1A, following Heinrich Event 1 and MWP 1B after the Younger Dryas cold event are followed by enhanced supply of southern source water at intermediate depths in the North Atlantic, together with reduced formation of well-ventilated glacial North Atlantic intermediate water (1000-2000 m). This result gives strong support to numerical models, predicting fast and sharp increase of bottom water age in the Atlantic triggered by pulses of freshwater discharge into the North Atlantic [Rahmstorf, Nature 372 (1994) 82-85; Stocker and Wright, Radiocarbon 40 (1998) 359-366].  相似文献   

7.
Previous studies have shown that the Pacific geoid and gravity fields exhibit lineated anomalies, trending approximately in the direction of absolute plate motion over the underlying mantle. Because the undulations obliquely cross fracture zones they have often been attributed a convective origin. Recently, lithospheric boudinage caused by diffuse extension has been proposed as a possible mechanism. We have examined the undulations in the free-air anomalies, geoid and bathymetry over a portion of the Pacific Plate to determine quantitatively how the undulations are related to plate motion. We compare the observed data to an axisymmetric, sinusoidal undulation defined in an arbitrary frame of reference; in particular, we seek the north pole of this reference frame that maximizes the correlation between data and model. Poles that are close to the Pacific hotspot pole represent copolar undulations possibly related to plate motion. The distance between the best-fitting poles and the hotspot pole is determined as a function of undulation wavelength and reveals several minima (with distance < 10°) for discrete geoid wavebands centered on wavelengths of 160 km, 225 km, 287 km, 400 km, 660 km, 850 km, 1000 km and 1400 km. Bathymetry data have copolar bathymetric expressions as well, giving an implied admittance of 2–3 m/km. The most co-polar geoid/bathymetry undulations (with poles within 2–3° of the average Pacific Euler pole) have wavelengths of 280 km and 1050 km, respectively. The latter could have a convective origin or be related to the spacing of hotspot swells. The former may reflect lithospheric boudinage formed in response to diffuse extension, but could also have a dynamic origin since flexural dampening may only have attenuated the bathymetric amplitude by 50% or less. Radiometric dating of volcanic ridges found in the troughs of prominent gravity lineations gives ages that correlate well with documented changes in Pacific and Indo/Australian Plate motion, suggesting the ridges formed in response to intermittent plate boundary stresses and not as a direct consequence of small-scale convection or diffuse extension.  相似文献   

8.
In Forte and Claire Perry (2000) models of mantle viscosity (by using the data on tectonic plate velocities, of global free-air gravity anomalies, of surface topography corrected for crustal isostasy, and the excess of dynamic ellipticity of the core-mantle boundary in accordance with Herring et al., 1986 and Mathews et al., 1999) have been constructed. In the following investigation we reconsider the results which are obtained from the presently available data on core-mantle boundary flattening (abbreviated by CMBF). In contrast with the aforementioned work, we use below the value of CMBF (Molodensky and Groten, 1998) which is based on a new approach to the theory of diurnal Earth tides and nutation which takes into account the second-order terms of expansions of a small parameter (for a detailed discussion of this subject see (Molodensky and Groten, 1998)). Below we find the area of admissible values of mantle viscosity which does not contradict the following data sets: (a) the numerical value on CMBF; (b) the value of the whole Earth's dynamical flattening, and (c) the data on the secular deceleration of the Earth's rotation. Our estimations show, that the maximal viscosity at depth 2000 km may be of the order of 1027 Poise. This value is consistent with the distribution obtained by Trubitsin (2000) who adopted the viscosity dependence on temperature and pressure by an exponential function with olivine parameters under the assumption that the activation energy varies only weakly with pressure, and the activation volume varies in inverse proportion to temperature. Under these assumptions, his solution of convection equations gave the depth dependence of temperature and thereby the viscosity distribution.  相似文献   

9.
We report on new paleomagnetic results obtained from 27 sites sampled in the Plio–Pleistocene sequences at the external front of the central–northern Apennines. Previous analyses of Miocene (Messinian) sediments indicated that the present shape of the northern Apenninic arc is due to the oroclinal bending of an originally straight belt oriented around N320° and that vertical axis rotations accompanied the migration of the thrust fronts toward the Adriatic foreland [F. Speranza et al., J. Geophys. Res. 102 (1997) 3153–3166]. We tried to provide new paleomagnetic constraints for the timing and rates of the oroclinal bending process during the Pliocene and the Pleistocene. The results suggest that CCW rotations observed in the northern part of the studied area are possibly younger than 3 Ma. No regional rotation is recorded in the Pliocene and Pleistocene sediments from the southern part of the study area, analogously to the Messinian sediments of the ‘Acquasanta’ domain of Speranza et al. [F. Speranza et al., J. Geophys. Res. 102 (1997) 3153–3166]. A local significant CCW rotation (23°±10°) is identified in the Early Pleistocene sediments that crop out along the Adriatic coast between Ascoli and Pescara, indicating differential motion of the thrust sheets. This rotation must be younger than 1.43 Ma.  相似文献   

10.
We investigated the upper mantle anelastic structure beneath the northern Philippine Sea region, including the Izu-Bonin subduction zone and the Shikoku Basin. We used regional waveform data from 69 events in the Pacific and the Philippine Sea slabs, recorded on F-net and J-array network broadband stations in western Japan. Using the S–P phase pair method, we obtained differential attenuation factors, δt*, which represent the relative whole path Q. We conducted a tomographic inversion using 978 δt* values to invert for a fine-scale (50–100 km) three-dimensional anelastic structure.

The results shows two high-Q regions (QP>1000) which are consistent with the locations of the Pacific and the Philippine Sea slabs. Also there is a low-Q (QP110) area extending to the deeper parts (350–400 km) of the model just beneath the old spreading center and the Kinan Seamount Chain in the Shikoku Basin. A small depth dependence of the laterally averaged QP was found, with values of 266 (0–250 km), 301 (250–400 km), and 413 (400–500 km).  相似文献   


11.
Low-velocity structure beneath Africa from forward modeling   总被引：1，自引：0，他引：1  
Seismic waveforms observed in South Africa containing the first arrival crossover of S to SKS (70° to 110°) are analyzed. The data consist of analog records from the World Wide Seismographic Station Network (WWSSN) of deep events beneath South America. The S-waves arrive 2 to 3 s early relative to PREM at ranges from 70° to 95° and then become increasingly delayed, becoming 5 to 6 s late at 110°. The SKS phase is late by 3 to 5 s over the entire range. This pushes crossover between S and SKS, normally observed at about 81°, out about 2° to 3°, which is the most anomalous shift ever reported. To model such features, we modified Grand's tomography model [Grand et al., GSA Today 7 (1997) 1–7], and generated 2D synthetics to match the data. The overall shape and position of the lower mantle low-velocity anomaly proposed by Grand predicts good results if lower mantle anomalies are enhanced to a level of about 4%. This results in a complex tabular structure extending upward from the core–mantle boundary about 1500 km into the mantle. These features appear to be consistent with a large young plume which is erupting off the CMB.  相似文献   

12.
We examine the micro-earthquake seismicity recorded by two temporary arrays of ocean bottom seismometers on the outer rise offshore southern Chile on young oceanic plate of ages 14 Ma and 6 Ma, respectively. The arrays were in operation from December 2004–January 2005 and consisted of 17 instruments and 12 instruments, respectively. Approximately 10 locatable events per day were recorded by each of the arrays. The catalogue, which is complete for magnitudes above 1.2–1.5, is characterized by a high b value, i.e., a high ratio of small to large events, and the data set is remarkable in that a large proportion of the events form clusters whose members show a high degree of waveform similarity. The largest cluster thus identified consisted of 27 similar events (average inter-event correlation coefficient > 0.8 for a 9.5 s window), and waveform similarity persists far into the coda. Inter-event spacing is irregular, but very short waiting times of a few minutes are far more common than expected from a Poisson distribution. Seismicity with these features (high b value, large number of similar events with short waiting times) is typical of swarm activity, which, based on empirical evidence and theoretical considerations, is generally thought to be driven by fluid pressure variations. Because no pronounced outer rise bulge exists on the very young plate in the study region, it is unlikely that melt is accessible from decompression melting or opening of cracks. A fluid source related to processes at the nearby ridge is conceivable for the younger segment but less likely for the older one. We infer that the fluid source could be seawater, which enters through fractures in the crust. Most of the similar-earthquake clusters are within the crust, but some of them locate significantly below the Moho. If our interpretation is correct, this implies that water is present within the mantle. Hydration of the mantle is also indicated by a decrease of Pn velocities below the outer rise seen on a refraction profile through one of the arrays [Contreras-Reyes, E., Grevemeyer, I., Flueh, E.R., Scherwath, M., Heesemann, M., 2007. Alteration of the subducting oceanic lithosphere at the southern central Chile trench-outer rise. Geochem., Geophys. Geosyst. 8, Q07003.]. The deepest events within the array on the 6 Ma old plate occur where the temperature reaches 500–600 °C, consistent with the value observed for large intraplate earthquakes within the mantle (650 °C), suggesting that the maximum temperature at which these fluid-mediated micro-earthquakes can occur is similar or identical to that of large earthquakes.  相似文献   

13.
Up to now, tests of thermal models of the oceanic lithosphere as it cools and moves away from the ridge crest have been based mainly on topography and heat flow data. However, large areas of the ocean floor deviate from the normal subsidence due to thermal contraction and heat flow data are not very sensitive to the form of the model.

Cooling of the lithosphere causes a short-wavelength step in the geoid across fracture zones that can also be used to constrain thermal models. We have analyzed geoid data at fracture zones from the SEASAT altimeter measurements in the entire Pacific Ocean and redetermined parameters of the cooling models. We find that the data reveal two distinct regimes of cooling; one for seafloor ages in the range 0–30 Ma, the other beyond 30 Ma; this does not appear to be correlated with particular fracture zones but rather it is representative of the whole area studied, i.e., the entire south Pacific and northeast Pacific Ocean. These two trends may be interpreted in terms of two different (asymptotic) thermal thicknesses of the plate model. The smaller thermal thickness ( 65 km) found for ages <30 Ma—compared to 90 km in the age range 30–50 Ma—calls for some kind of thermal perturbation in the vicinity of the ridge crest.

From the results obtained in this study, we conclude that the half-space cooling model is unable to explain the data, that beyond 30 Ma, a simple plate model gives a satisfactory fit to the data but in the younger plate portion (ages < 30 Ma) the cooling history of the oceanic lithosphere is much more complex than predicted by the usual cooling models. Furthermore, the depth-age relationship obtained from the geoid-derived thermal parameters departs significantly beyond 30 Ma from the widely used Parsons and Sclater's depth-age curve, predicting a lesser subsidence.  相似文献   


14.
The island chains of French Polynesia form subparallel line segments whose southeasterly extensions are perpendicular to the East Pacific Rise, the site of present sea-floor spreading in the eastern Pacific Ocean. Samples collected from island members of the Society and Austral Islands chains are used, together with previously reported age determinations for the Marquesas and Pitcairn-Gambier Islands, in a geochronological study of the southeastward migration of volcanism in each of those four lineaments. The suggestion from geomorphologic evidence that island ages increase to the northwest within each island chain, is confirmed by K---Ar whole-rock ages. The linear volcanism which built the islands of French Polynesia began in the Miocene and continues today.Rates of migration of volcanism are calculated from the nearly linear relationship between average island ages and distance from the southeast ends of the four island lineaments. The four rates are indistinguishable, within limits of detection, at 11 ± 1 cm/year. These rates are consistent with the model of rigid Pacific plate movement over four fixed sources of volcanism, be they dynamic as in the hot spot/plume models or passive as in models of propagating lithospheric fractures. If it is accepted that these volcanic sources trace the motion of the lithosphere over the mantle and thus define the “absolute” frame of reference for plate movement, Pacific plate motion may be fixed to the geometry and volcanic migration rates of French Polynesia. This allows calculation of the absolute motion of all other plates, providing an accurate relative motion model is known (Minster et al., 1974). Such a calculation predicts that Africa is virtually stationary and that the Mid-Atlantic Ridge and East Pacific Rise are moving slowly to the west.  相似文献   

15.
Basalts from young seamounts situated within 6.8 m.y. of the East Pacific Rise, between 9° and 14°N latitude, display significant variations in 143Nd/144Nd (0.51295–0.51321), 87Sr/86Sr (0.7025–0.7031), and(La/Sm)N (0.415–3.270). Nd and Sr isotope ratios are anti-correlated and form a trend roughly parallel to the “mantle array” on a143Nd/144Nd vs.87Sr/86Sr variation diagram. Nd and Sr isotope ratios display negative and positive correlations, respectively, with(La/Sm)N. The geochemical variations observed at the seamounts are nearly as great or greater than those observed over several hundred kilometers of the Reykjanes Ridge, or at the islands of Iceland or Hawaii.

Samples from one particular seamount, Seamount 6, display nearly the entire observed range of chemical variations, offering an ideal opportunity to constrain the nature of heterogeneities in the source mantle. Systematics indicative of magma mixing are recognized when major elements, trace elements, trace element ratios, and isotope ratios are compared with each other in all possible permutations. The source materials required to produce the end-member magmas are: (1) a typical MORB-source-depleted peridotite; and (2) a relatively enriched material which may represent ancient mantle segregations of basaltic melt, incompletely mixed remnants of subducted ocean crust, or metasomatized peridotite such as that found at St. Paul's Rocks or Zabargad Island. Due to the proximity of the seamounts to the East Pacific Rise (EPR), the source materials are thought to comprise an intimate mixture in the mantle immediately underlying the seamounts and the adjacent EPR. Lavas erupted at the ridge axis display a small range of isotopic and incompatible trace element compositions because the large degrees of melting and presence of magma chambers tend to average the chemical characteristics of large volumes of mantle.

If the postulated mantle materials, with large magnitude, small-scale heterogeneities, are ubiquitous in the upper mantle, chemical variations in basalts ranging from MOR tholeiites to island alkali basalts may reflect sampling differences rather than changes in bulk mantle chemistry.  相似文献   


16.
Chemical and isotopic ratio (He, C, H and O) analysis of hydrothermal manifestations on Pantelleria island, the southernmost active volcano in Italy, provides us with the first data upon mantle degassing through the Sicily Channel rift zone, south of the African–European collision plate boundary. We find that Pantelleria fluids contain a CO2–He-rich gas component of mantle magmatic derivation which, at shallow depth, variably interacts with a main thermal (100°C) aquifer of mixed marine–meteoric water. The measured 3He/4He ratios and δ13C of both the free gases (4.5–7.3 Ra and −5.8 to −4.2‰, respectively) and dissolved helium and carbon in waters (1.0–6.3 Ra and −7.1 to −0.9‰), together with their covariation with the He/CO2 ratio, constrain a 3He/4He ratio of 7.3±0.1 Ra and a δ13C of ca. −4‰ for the magmatic end-member. These latter are best preserved in fluids emanating inside the active caldera of Pantelleria, in agreement with a higher heat flow across this structure and other indications of an underlying crustal magma reservoir. Outside the caldera, the magmatic component is more affected by air dilution and, at a few sites, by mixing with either organic carbon and/or radiogenic 4He leached from the U–Th-rich trachytic host rocks of the aquifer. Pantelleria magmatic end-member is richer in 3He and has a lower (closer to MORB) δ13C than all fluids yet analyzed in volcanic regions of Italy and southern Europe, including Mt. Etna in Sicily (6.9±0.2 Ra, δ13C=−3±1‰). This observation is consistent with a south to north increasing imprint of subducted crustal material in the products of Italian volcanoes, whose He and C (but also O and Sr) isotopic ratios gradually evolve towards crustal values northward of the African–Eurasian plate collision boundary. Our results for Pantelleria extend this regional isotopic pattern further south and suggest the presence of a slightly most pristine or ‘less contaminated’, 3He-richer mantle source beneath the Sicily Channel rift zone. The lower than MORB 3He/4He ratio but higher than MORB CO2/3He ratio of Pantelleria volatile end-member are compatible with petro-geochemical evidence that this mantle source includes an upwelling HIMU–EM1-type asthenospheric plume component whose origin, according to recent seismic data, may be in the lower mantle.  相似文献   

17.
This paper presents a new perturbation solution of the non-linear Boussinesq equation for one-dimensional tidal groundwater flow in a coastal unconfined aquifer. Built upon the work of Parlange et al. [Parlange, J.-Y., Stagnitti, F., Starr, J.L., Braddock, R.D., 1984. Free-surface flow in porous media and periodic solution of the shallow-flow approximation, J. Hydrol., 70, 251–263], the solution adopts a new perturbation parameter that is by definition less than unit, and thus is applicable to a wider range of physical conditions within the constraint of the Boussinesq approximation. This approach avoids a secular term in the third-order perturbation equation of Parlange et al. (1984), enabling the derivation of the third- and higher-order solutions. In comparison with a numerical (“exact”) solution, the new perturbation solution is shown to be slightly more accurate than that of Parlange et al. (1984) with the second-order approximation. The obtained third-order solution exhibits considerable improvement in accuracy. In relatively simple analytical forms, the present perturbation solution will help to understand better the non-linear characteristics of tidal water table fluctuations in as modeled by the non-linear Boussinesq equation coastal unconfined aquifers.  相似文献   

18.
There are three cases of variation of trench location possible to occur during subduction: trench fixed, trench advancing, and trench retreating. Retreat of trench may lead to back-arc extension. The Pacific plate subducts at low angle beneath the Eurasia plate, tomographic results indicate that the subducted Pacific slab does not penetrate the 670 km discontinuity, instead, it is lying flat above the interface. The flattening occurred about 28 Ma ago. Geodynamic computation suggests: when the frontier of the subducted slab reaches the phase boundary of lower and upper mantle, it may be hindered and turn flat lying above the boundary, facilitates the retreat of trench and back-arc extension. Volcanism in northeastern China is likely a product of such retreat of subduction, far field back-arc extension, and melting due to reduce of pressure while mantle upwelling. Foundation item: National Natural Science Foundation of China (40234042 and 40174027).  相似文献   

19.
Despite a spreading rate of 65–70 km Ma−1, the East Scotia Ridge has, along most of its length, a form typically associated with slower rates of sea floor spreading. This may be a consequence of cooler than normal mantle upwelling, which could be a feature of back-arc spreading. At the northern end of the ridge, recently acquired sonar data show a complex, rapidly evolving pattern of extension within 100 km of the South Sandwich Trench. New ridge segments appear to be nucleating at or near the boundary between the South American and Scotia Sea plates and propagating southwards, supplanting older segments. The most prominent of these, north of 56°30′S, has been propagating at a rate of approximately 60 km Ma−1 for at least 1 Ma, and displays a morphology unique on this plate boundary. A 40 km long axial high exists at the centre of this segment, forming one of the shallowest sections of the East Scotia Ridge. Beneath it, seismic reflection profiles reveal an axial magma chamber, or AMC, reflector, similar to those observed beneath the East Pacific Rise and Valu Fa Ridge. Simple calculations indicate the existence here of a narrow (<1 km wide) body of melt at a depth of approximately 3 km beneath the sea floor. From the topographic and seismic data, we deduce that a localised mantle melting anomaly lies beneath this segment. Rates of spreading in the east Scotia Sea show little variation along axis. Hence, the changes in melt supply are related to the unique tectonic setting, in which the South American plate is tearing to the east, perhaps allowing mantle flow around the end of the subducting slab. Volatiles released from the torn plate edge and entrained in the flow are a potential cause of the anomalous melting observed. A southward mantle flow may have existed beneath the axis of the East Scotia Ridge throughout its history.  相似文献   

20.
A phase transition in pure CaSiO3 perovskite was investigated at 27 to 72 GPa and 300 to 819 K by in-situ X-ray diffraction experiments in an externally-heated diamond-anvil cell. The results show that CaSiO3 perovskite takes a tetragonal form at 300 K and undergoes phase transition to a cubic structure above 490–580 K in a pressure range studied here. The transition boundary is strongly temperature-dependent with a slightly positive dT / dP slope of 1.1 (± 1.3) K/GPa. It is known that the transition temperature depends on Al2O3 content dissolved in CaSiO3 perovskite [Kurashina et al., Phys. Earth Planet. Inter. 145 (2004) 67–74]. The phase transition in CaSiO3(+ 3 wt.% Al2O3) perovskite therefore could occur in a cold subducted mid-oceanic ridge basalt (MORB) crust at about 1200 K in the upper- to mid-lower mantle. This phase transition is possibly ferroelastic-type and may cause large seismic anomalies in a wide depth range.  相似文献   

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