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1.
A detailed water quality analysis was carried out in the quaternary aquifer system of the marginal alluvial plain (Ganga Plain) in Bah Tahsil, Agra district, India. The electrical conductivity of 50 samples each from dug wells, hand pumps and tube wells was analysed for the study of salinity levels in shallow, intermediate and deep aquifers. Out of 50, 20 samples of each were also analysed for other chemical constituents such as Na+, K+, Cl−, F− and TDS. The analyses show drastic changes in the salinity levels of shallow, intermediate and deep aquifers. The deep aquifers are more saline compared to the shallow and intermediate aquifers. On the contrary, the concentration of chemical constituents such as Na+, K+, Cl− and F− was more in the shallow aquifers compared to the deep aquifers. Moreover, there is an indication that the salinity and concentration of the above chemical constituents also escalate with time in each aquifer. The chemical constituents such as Na+, K+, Cl−, F− and TDS range from 51 to 165 mg/l, 1 to 14 mg/l, 224 to 1,459 mg/l, 0 to 1.5 mg/l and 750 to 2,650 mg/l, respectively. Over a 3-year period, the salinity levels have sharply increased and the average F level has increased by 0.1–0.3 mg/l. An attempt has been made here to discuss the factors causing the variation and escalation of chemical constituents and salinity in the water of the three aquifers.  相似文献   

2.
Land subsidence in Bangkok, Thailand   总被引：9，自引：0，他引：9  
Land subsidence from deep well pumping has been affecting Bangkok for the past 35 years. Its impact is particularly critical because of the flat low-lying topography and the presence of a thick soft clay layer at the ground surface that augment flood risk and foundation engineering problems, respectively. The subsidence reached its most critical state in the early 1980s when it occurred at a rate as high as 120 mm/year. The rate decreased in the subsequent period but the subsidence-affected area expanded following the growth of the city. Despite various attempts implemented to remedy the crisis, groundwater pumping from the thick aquifer system underneath the city continued to increase from 1.2 million m3/day in the early 1980s to more than 2.0 million m3/day at the turn of the century. Piezometric levels in the main aquifer layers had been drawn down by as much as 65 m. Monitoring data showed a clear correlation between the subsidence and piezometric drawdown. The data suggested that for 1 m3 of groundwater pumped out in Bangkok Plain, approximately 0.10 m3 of ground loss occurred at the surface. Significant development has been made in numerical methods for prediction of differential settlements between building foundations caused by the piezometric drawdown in the aquifers. The strict mitigation measures adopted recently, comprising a pricing policy for groundwater management, an expansion of tap water supply, and strict enforcement of groundwater laws, have resulted in a marked drop in groundwater use. However, the land subsidence will continue for a long while owing to the time-dependent consolidation behavior of the soft clay layer and clay aquitards.  相似文献   

3.
The Wilcox aquifer is a major groundwater resource in the northern Gulf Coastal Plain (lower Mississippi Valley) of the USA, yet the processes controlling water chemistry in this clastic aquifer have received relatively little attention. The current study combines analyses of solutes and stable isotopes in groundwater, petrography of core samples, and geochemical modeling to identify plausible reactions along a regional flow path ～300 km long. The hydrochemical facies evolves from Ca-HCO3 upgradient to Na-HCO3 downgradient, with a sequential zonation of terminal electron-accepting processes from Fe(III) reduction through SO4 2? reduction to methanogenesis. In particular, decreasing SO4 2? and increasing δ34S of SO4 2? along the flow path, as well as observations of authigenic pyrite in core samples, provide evidence of SO4 2? reduction. Values of δ13C in groundwater suggest that dissolved inorganic carbon is contributed both by oxidation of sedimentary organic matter and calcite dissolution. Inverse modeling identified multiple plausible sets of reactions between sampled wells, which typically involved cation exchange, pyrite precipitation, CH2O oxidation, and dissolution of amorphous Fe(OH)3, calcite, or siderite. These reactions are consistent with processes identified in previous studies of Atlantic Coastal Plain aquifers. Contrasts in groundwater chemistry between the Wilcox and the underlying McNairy and overlying Claiborne aquifers indicate that confining units are relatively effective in limiting cross-formational flow, but localized cross-formational mixing could occur via fault zones. Consequently, increased pumping in the vicinity of fault zones could facilitate upward movement of saline water into the Wilcox.  相似文献   

4.
228Ra, 226Ra, and 222Rn activities were determined on over 150 ground water samples collected from drilled, public water supply wells throughout South Carolina. A wide range of aquifer lithologies were sampled including the crystalline rocks of the Piedmont and sedimentary deposits of the Coastal Plain. A significant linear relationship between log 228Ra and log 226Ra (n = 182, r = 0.83) was indistinguishable between Piedmont and Coastal Plain ground water. Median 228Ra226Ra activity ratios for the Piedmont, 1.2, and Coastal Plain, 1.3, ground water are close to estimated average crustal 232Th238U activity ratios of 1.2 to 1.5 corresponding to Th/U weight ratios of 3.5 to 4.5. A linear correlation was also found between log 222Rn and log 226Ra for Piedmont (n = 68, r = 0.62) and Coastal Plain (n = 89, r = 0.64) ground water. However, the median 222Rn226Ra activity ratio for Piedmont ground water, 6100, was much higher than for Coastal Plain ground water, 230. Higher excess 222Rn activities may be due to greater retention of 226Ra by the chemically active Piedmont aquifers compared to the more inert sand aquifers sampled in the Coastal Plain. The relationship between log 228Ra and log 226Ra was used to predict total Ra (228Ra + 226Ra) distributions in Appalachian and Atlantic and Gulf Coastal Plain ground water. Predictions estimate that 2.4% of Appalachian and 5.3% of Atlantic and Gulf Coastal Plain ground water supplies contain total Ra activities in excess of the 5 pCi/l limit established by the U.S. Environmental Protection Agency. These predictions also indicate that 40–50% of these ground water wells may be overlooked using the presently suggested screening activity of 3.0 pCi/l of 226Ra for 228Ra analysis.  相似文献   

5.
The city of Scarborough lies on the eastern margin of the Greater Toronto Area of southern Ontario, Canada, along the northern coastline of Lake Ontario. The City has a population of 500,000 and is presently one of the fastest growing communities in Canada. The City is expanding northwards onto rural land on the south slope of the large Pleistocene glacial Oak Ridges Moraine system. The moraine system is underlain by a thick (150 m) succession of tills, sands and gravels and is a regionally-significant recharge area for three principle aquifer systems that discharge to numerous watercourses that flow to Lake Ontario. Protection of deeper aquifers from surface-generated urban contaminants is a particular concern. A groundwater flow model using Visual MODFLOW was developed for the 350-km2 Rouge River–Highland Creek (RRHC) drainage basin using an extensive GIS-based collection of subsurface geological, geophysical and hydrogeological data, maps of land use and surficial geology. The RRHC model was calibrated against point water level data, known potentiometric surfaces of the principal aquifers and baseflow measurements from streamflow gauging stations and determined to be within acceptable limits. Water balance calculations indicate that 70% of the basin recharge (106,000 m3/day) enters the Upper Aquifer along the crest and immediate flanks of the Oak Ridges Moraine. To the south, Upper Aquifer water moving through fractured till aquitards accounts for more than 75% of recharge to deeper aquifers. Water quality data confirm previous observations that urban- and rural-sourced contaminants (chlorides and nitrates) present in Upper Aquifer waters are moving rapidly into deeper aquifers. Some 83% of total RRHC recharge water is ultimately discharged as baseflow to creeks draining to Lake Ontario; the remainder discharges to springs and along eroding lakeshore bluffs. Model results demonstrate that deeper aquifers are poorly protected from urban contaminants and that long-term protection of ground and surface water quality has to be a priority of municipal planners if the resource is not to be severely degraded. Electronic Publication  相似文献   

6.
A semi-distributed groundwater recharge model is presented, which estimates water-table fluctuation and water-balance variables. The model is expressed by the water-balance concept linking atmospheric and hydrogeological parameters to different water uses (industrial, agricultural, domestic, etc). It was calibrated and validated using 5 years of data collected in the Dogo Plain in Japan. A 3-year dataset, from 2000 to 2002, was used in the calibration, while a 2-year dataset, from 2003 to 2004, was used for the validation. Calibration of the model was achieved by the shuffled complex evolution automatic optimization of model parameters to match simulated results with measured water-table depth. Square roots of relative error (R2) are 0.88 and 0.90 for calibration and validation processes, respectively. Monthly evolution of water storage change was then estimated and the water-table drawdown in different pumping scenarios was simulated. Finally, the groundwater-pumping amount planned by the government for future sustainable groundwater utilization was evaluated. The government-planned groundwater-pumping amount is feasible in most regions while the midstream region should be paid more attention. This study offers a scientific basis to control and prevent depletion of groundwater resources.  相似文献   

7.
Cretaceous strata in Alabama and Mississippi (USA) represent one of the most complete records of shallow marine deposition worldwide for the Upper Cretaceous. The age assignment of these strata in the eastern Gulf Coastal Plain is difficult due to the comparative lack of radiometrically datable beds and sometimes conflicting results of biostratigraphy using different taxonomic groups. Numerical age dating using strontium isotope ratios (87Sr/86Sr) preserved in diagenetically resistant fossil shark tooth enameloid had been proposed by previous researchers as a solution to dating some geologic units. Here we apply this methodology to the whole Upper Cretaceous, using teeth of two fossil shark genera (Scapanorhynchus and Squalicorax) collected from variable facies. Shark teeth collected from a bentonite mine in Monroe County, Mississippi, were also analyzed and compared with the radiometric date of the bentonite layer. Results indicate a strong correlation between stratigraphic position of the fossil teeth and numerical age determination based on 87Sr/86Sr content. Furthermore, this method is equally effective for both of the fossil shark genera analyzed in the study. Because of the nearly uniform distribution of strontium in ocean water, numerical age dating using strontium isotope ratios preserved in fossil shark tooth enameloid can be a useful method to employ in the correlation of marine geological strata on both regional and global scales.  相似文献   

8.
The Beijing-Tianjin-Hebei Plain (BTHP) is the political, economic and cultural center of China, where groundwater is the main source of water supply to support social and economic development. Continuous overdraft of the resources has caused a persistent decline of groundwater level and formed a huge cone of depression at a regional scale. This paper addresses current groundwater situation over the BTHP area. The paper also delineates the groundwater flow field, using groundwater level data, in order to provide an effective method for the restoration of groundwater level and associated water resources management. Based on the analysis of multiple factors, such as groundwater level, soil salinization, ground subsidence, groundwater recharge and storage, urban underground space security, formation of fractures, and seawater intrusion, the threshold for groundwater level restoration is defined, and some measures for groundwater over-exploitation management are accordingly proposed. The study shows that: (i) Since the 1980s to 2020, shallow groundwater level in the western part of the BTHP area has dropped by 25 m to 60 m, while the cumulative decline of deep groundwater in the central and eastern regions is in the range of 40–80 m; (ii) The water table of the shallow groundwater within the depression zone over the Western Piedmont Plain should be controlled in the range of 15–30 m below ground level (mbgl), while the depth of groundwater level in large and medium-sized urban areas should be controlled within 20–30 mbgl. The groundwater level in the resource preservation area should be controlled within 10–15 mbgl, and the groundwater level in the area with identified soil salinization in the central and eastern plain should be controlled within 3–10 mbgl. However, for the deep groundwater in the central and eastern plainwater, the main focus of the resources management is to control the land subsidence. The water level in the severe land subsidence area should be controlled within 45–60 mbgl, and in the general subsidence area should be controlled within 30–45 mbgl; (iii) Based on the water level recovery threshold and proposed groundwater overdraft management program, if the balance of abstraction and recharge is reached in 2025, the shallow groundwater abstraction needs to be gradually reduced by about 2×108 m3. Meanwhile, the ecological water replenishment of rivers through the South-to-North Water Transfer Project should be increased to 28.58×108 m3/a, and the deep groundwater abstraction needs to be gradually reduced by 2.24×108 m3. To reach the target of shallow groundwater level in 2040, surface water replacement is recommended with a rate of 25.77×108 m3/a and the ecological water replenishment of rivers in the South-to-North Water Diversion Project should reach 33.51×108 m3/a. For deep groundwater recovery, it is recommended to replace the deep freshwater extraction with the utilization of shallow salt water by 2.82×108 m3 , in addition to the amount of 7.86×108 m3 by water diversion. The results are of great significance to the remediation of groundwater over-exploitation, the regulation of water resources development and utilization, and ecological protection in Beijing-Tianjin-Hebei plain.  相似文献   

9.
 Quaternary alluvial aquifers in the paleo Pennar delta region of Andhra Pradesh (Long. 80°0′ and 80°12′; Lat. 14°40′ and 14°20′) constitute an important coastal strip, with potential fresh groundwater resources and several well fields in operation. The lineament patterns and traces of paleo channels provide basic information on the configuration and boundaries of paleo delta and the possible neotectonic movements in the region. The paleo delta region is essentially characterized by freshwater aquifer systems at the near-surface depths, (up to 50 m from ground level) with transmissivity values in the system ranging from 1200 to 2500 m2/day. This groundwater system has been subjected to heavy draft situation over the last two decades, parlicularly near the outer rim of the delta where an unlined brackish-water canal runs parallel to the coast imparting chloride contamination to the adjoining fresh aquifers. A two-dimensional solute transport model solution was applied to assess chloride migration rates inland under different hydraulic stresses, combining finite difference solution of flow equation and the method of characteristic solution of solute transport equation. Groundwater flow and chloride migration patterns/rates were obtained for different simulated stress events in the delta system, and measures required to protect the freshwater resources ara outlined. Received: 2 January 1997 · Accepted: 4 November 1997  相似文献   

10.
As groundwater becomes an increasingly important water resource worldwide, it is essential to understand how local geology affects groundwater quality, flowpaths and residence times. This study utilized multiple tracers to improve conceptual and numerical models of groundwater flow in the Middle San Pedro Basin in southeastern Arizona (USA) by determining recharge areas, compartmentalization of water sources, flowpaths and residence times. Ninety-five groundwater and surface-water samples were analyzed for major ion chemistry (water type and Ca/Sr ratios) and stable (18O, 2H, 13C) and radiogenic (3H, 14C) isotopes, and resulting data were used in conjunction with hydrogeologic information (e.g. hydraulic head and hydrostratigraphy). Results show that recent recharge (<60 years) has occurred within mountain systems along the basin margins and in shallow floodplain aquifers adjacent to the San Pedro River. Groundwater in the lower basin fill aquifer (semi confined) was recharged at high elevation in the fractured bedrock and has been extensively modified by water-rock reactions (increasing F and Sr, decreasing 14C) over long timescales (up to 35,000 years BP). Distinct solute and isotope geochemistries between the lower and upper basin fill aquifers show the importance of a clay confining unit on groundwater flow in the basin, which minimizes vertical groundwater movement.  相似文献   

11.
Fluoride contamination in groundwater resources of Alleppey,southern India   总被引：1，自引：0，他引：1  
Alleppey is one of the thickly populated coastal towns of the Kerala state in southern India.Groundwater is the main source of drinking water for the 240,991 people living in this region.The groundwater is being extracted from a multi-layer aquifer system of unconsolidated to semi-consolidated sedimentary formations,which range in age from Recent to Tertiary.The public water distribution system uses dug and tube wells.Though there were reports on fluoride contamination,this study reports for the first time excess fluoride and excess salinity in the drinking water of the region.The quality parameters,like Electrical Conductivity(EC) ranges from 266 to 3900 μs/cm,the fluoride content ranges from 0.68 to2.88 mg/L,and the chloride ranges between the 5.7 to 1253 mg/L.The main water types are Na-HC03,NaCO_3 and Na-Cl.The aqueous concentrations of F~- and CO_3~(2-) show positive correlation whereas F~- and Ca~(2+) show negative correlation.The source of fluoride in the groundwater could be from dissolution of fluorapatite,which is a common mineral in the Tertiary sediments of the area.Long residence time,sediment-groundwater interaction and facies changes(Ca-HCO_3 to Na-HCO_3) during groundwater flow regime are the major factors responsible for the high fluoride content in the groundwater of the area.High strontium content and high EC in some of the wells indicate saline water intrusion that could be due to the excess pumping from the deeper aquifers of the area.The water quality index computation has revealed that 62%of groundwater belongs to poor quality and is not suitable for domestic purposes as per BIS and WHO standards.Since the groundwater is the only source of drinking water in the area,proper treatment strategies and regulating the groundwater extraction are required as the quality deterioration poses serious threat to human health.  相似文献   

12.
The Oramiriukwa River is within the sandy coastal plain strata of the Benin formation (Miocene–Recent). The base flow is very high ranging from 79.13–98.56%, which is caused by the excellent hydraulic interconnection between the river and the adjacent unconfined aquifer. Recharge rates are high, estimated to range from 1.8×1012–2.5×1012 m3/year. Coastal sands are medium-to-coarse grained, moderately-to-poorly sorted, angular to subangular, with lenses of clay and clayey fine-grained sands. The coastal sands and clay lenses form aquifer and aquitard systems, which are unconfined to semi-confined. Groundwater recharge potential is high. Runoff from precipitation is low. Groundwater and surface water are fairly acidic; pH ranges from 5.5–6.1 (groundwater) and 5.8–6.5 (surface water), and hardness is generally low. Chemical analysis and percentage sodium show that groundwater and surface water are somewhat potable after some pH modification of the surface water. The waters are good for agricultural use, especially for irrigation and poultry water supply. However, pollution from landfill leachate is serious. Electronic Publication  相似文献   

13.
Recharge to the Quaternary aquifers beneath the Northern Adelaide Plains was estimated to be 3.9 x 106 m3/year using the environmental tritium concentration of water samples taken from suitably sited boreholes. Recharge to the Tertiary aquifers was estimated to be 0.4 x 106m3/year, by the same isotopic techniques. These results may be compared with a total recharge by leakage through the beds of streams which cross the plain, estimated by the South Australian Department of Mines to be 6.4 x 106 m3/year.  相似文献   

14.
Hydrology of the coastal sabkhas of Abu Dhabi, United Arab Emirates   总被引：2，自引：0，他引：2  
Water fluxes were estimated and a water budget developed for the land surface and a surficial 10-m-deep section of the coastal sabkhas that extend from the city of Abu Dhabi, United Arab Emirates, west to the border with Saudi Arabia. The fluxes were estimated on the basis of water levels and hydraulic conductivities measured in wells and evaporation rates measured with a humidity chamber. In contrast with conceptual models proposed in earlier studies, groundwater inflow is estimated to be small, whereas the largest components of the water budget are recharge from rainfall and evaporation from the water table. Estimates within a rectilinear volume of sabkha, defined as 1 m wide by 10 km long by 10 m deep, indicate that about 1 m3/year of water enters and exits by lateral groundwater flow; 40–50 m3/year enters by upward leakage; and 640 m3/year enters by recharge from rainfall. Based on the water and solute fluxes estimated for the upward leakage into the sabkha, 7–8 pore volumes of brine have entered the sabkha from below since the time the sabkha became saturated (7,000 years ago) as a result of the last global sea-level rise.
Ward E. SanfordEmail:
  相似文献   

15.
Most faulting in the Coastal Plain is high angle and generally normal, but the faults in the Livingston Fault Zone are all medium-angle reverse, forming a series of parallel horsts and grabens. Parallel to the fault zone are a number of phenomena all leading to the conclusion that the faults result from the solution of a late Cretaceous salt anticline by fresh groundwater, which then migrated up to the Eutaw and perhaps Tuscaloosa aquifers, causing an anomalous elongated area of highly saline water. The origin of the Livingston Fault Zone and the association of salt water in underlying aquifers is of particular importance at this time in relation to environmental concerns associated with hazardous waste management in the area.  相似文献   

16.
Long-trend trends in dissolved oxygen (DO) and total coliform bacteria concentrations are used to evaluate the impact of almost 60 yr of sewage abatement and treatment in the lower Hudson River near New York City. Although some water pollution control plants have been in operation in the region since the 1930s, the most significant abatement of untreated sewage in the lower Hudson River has occurred since the late 1970s, when most of the existing plants were upgraded to secondary treatment, and additional plants were constructed. From at least 1922 through the early 1960s, average summer DO percent saturation varied between 35% and 50% in surface waters and 25% and 40% in bottom waters. Beginning in the late 1970s, DO concentrations generally increased through the 1980s and especially into the 1990s, coinciding with the upgrading of the 7.4 m3 s?1 (170 million gallons per day, mgd) North River plant to secondary treatment in the spring of 1991. Average summer percent saturation in the early 1990s exceeded 80% in surface waters and 60% in bottom waters. In addition, summer DO minima have increased from less than 1.5 mg 1?1 in the early 1970s to greater than 3.0 mg 1?1 in the 1990s, and the duration of hypoxia during summer months has been reduced. Total coliforms also display strong declining trends from the 1970s into the 1990s, with declines attributed to plant upgrades, construction of two New York City plants (North River and Red Hook) in the mid 1980s, and improved operation of the sewer system.  相似文献   

17.
长江河口地区地下水咸、淡水界面的动态变化研究   总被引：1，自引：0，他引：1  
本文对长江河口地区1960～1985年间78口钻井中的各层承压水进行了245个水化学样品测试，分析内容包括K+、Na+、Ca2+、Mg2+、NH4+、Al3+、Cl-、HCO3-、CO32-、SO42-离子含量以及酸碱性、温度等项目。其中第I层有样品24个；II层有63个；III层有53个；IV层有70个；V层有35个。测试时采用平行双样进行精度控制，水质分析的结果，按阴阳离子毫克当量总和的平衡关系进行检查，超出允许误差及时进行复检。
为了研究各承压含水层咸、淡水界面分布的变化，我们将矿化度作为水质指标，并利用人工神经网络技术进行了计算机模拟。结果表明，本区第四纪地层中各含水层水质的时空分布格局主要受第四纪海平面波动控制；IV、V含水层中的微咸水、咸水的分布可能受上层咸水通过越流污染下层淡水所致。对II、III含水层在二十世纪六十年代和八十年代两阶段水质分布的分析发现，含水层内淡水区在上海市区有向东南和西北方向明显扩展的趋势。造成这种现象的主要原因在于二十世纪七十和八十年代，上海市区地下水开采量逐年压缩，并开展了人工回灌（均为淡水），从而阻止了由于二十世纪六十年代市区过量抽取地下水而引起的地面沉降等问题。  相似文献   

18.
A regional lithostratigraphic and hydraulic interpretation is presented for the upper 0–300 m of the Benin Formation where groundwater is abstracted in the Rivers State, Nigeria.The aquifers are predominantly sand beds with minor clays, lignite, and conglomerate intercalations. The sands are very fine to coarse grained, subangular to subrounded, poor to fairly well sorted and mostly lithic arenites. A maximum thickness greater than 50 m is developed in places and vertical stacking is common. Most of the conglomerate beds have a matrix support fabric and appear restricted to the east as the lignite beds. An east-west trending belt, about central to the state, seems to contain more clay interbeds.The transmissivity values for the aquifers range from 1.05 × 10–2 to 11.3 × 10–2 m2/sec, while the coefficient of storage varies between 1.07 × 10–4 and 3.53 × 10–4 and specific capacity values lie between 19.01 and 139.8 m3/h/m drawdown. These values suggest that the aquifers have very good capacity to transmit groundwater. The static water level map shows a north-to-south regional groundwater flow pattern except in the northeast (Imo River catchment area) where the flow is northeast to southwest. The groundwater quality is very good and compares favorably with WHO standards for drinking water. However, relatively high iron and chloride values are localized in time and space.Deposition of the aquifer materials is thought to have occurred in alluvial fan, fluvial channel, tidal channel, intertidal flat, beach, and related microenvironments.  相似文献   

19.
The semi-arid Sahel regions of West Africa rely heavily on groundwater from shallow to moderately deep(100 m b.g.l.)crystalline bedrock aquifers for drinking water production.Groundwater quality may be affected by high geogenic arsenic(As)concentrations(10μg/L)stemming from the oxidation of sulphide minerals(pyrite,arsenopyrite)in mineralised zones.These aquifers are still little investigated,especially concerning groundwater residence times and the influence of the annual monsoon season on groundwater chemistry.To gain insights on the temporal aspects of As contamination,we have used isotope tracers(noble gases,~3H,stable water isotopes(~2 H,~(18)O))and performed hydrochemical analyses on groundwater abstracted from tube wells and dug wells in a small study area in southwestern Burkina Faso.Results revealed a great variability in groundwater properties(e.g.redox conditions,As concentrations,water level,residence time)over spatial scales of only a few hundred metres,characteristic of the highly heterogeneous fractured underground.Elevated As levels are found in oxic groundwater of circum-neutral pH and show little relation with any of the measured parameters.Arsenic concentrations are relatively stable over the course of the year,with little effect seen by the monsoon.Groundwater residence time does not seem to have an influence on As concentrations,as elevated As can be found both in groundwater with short(50 a)and long(10~3 a)residence times as indicated by ~3He/~4He ratios spanning three orders of magnitude.These results support the hypothesis that the proximity to mineralised zones is the most crucial factor controlling As concentrations in the observed redox/pH conditions.The existence of very old water portions with residence times10~3 years already at depths of50 m b.g.l.is a new finding for the shallow fractured bedrock aquifers of Burkina Faso,suggesting that overexploitation of these relatively low-yielding aquifers may be an issue in the future.  相似文献   

20.
A total of 1270 raw-water samples (before treatment) were collected from 15 principal and other major aquifer systems (PAs) used for drinking water in 45 states in all major physiographic provinces of the USA and analyzed for concentrations of the Ra isotopes 224Ra, 226Ra and 228Ra establishing the framework for evaluating Ra occurrence. The US Environmental Protection Agency Maximum Contaminant Level (MCL) of 0.185 Bq/L (5 pCi/L) for combined Ra (226Ra plus 228Ra) for drinking water was exceeded in 4.02% (39 of 971) of samples for which both 226Ra and 228Ra were determined, or in 3.15% (40 of 1266) of the samples in which at least one isotope concentration (226Ra or 228Ra) was determined. The maximum concentration of combined Ra was 0.755 Bq/L (20.4 pCi/L) in water from the North Atlantic Coastal Plain quartzose sand aquifer system. All the exceedences of the MCL for combined Ra occurred in water samples from the following 7 PAs (in order of decreasing relative frequency of occurrence): the Midcontinent and Ozark Plateau Cambro-Ordovician dolomites and sandstones, the North Atlantic Coastal Plain, the Floridan, the crystalline rocks (granitic, metamorphic) of New England, the Mesozoic basins of the Appalachian Piedmont, the Gulf Coastal Plain, and the glacial sands and gravels (highest concentrations in New England).  相似文献   

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