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1.
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2.
The mineralogy and petrology of pumice exposed in two small outcrops at the top of two hills in western Spain suggest that these rocks are of impact genesis. Ringwoodite, which was identified in the rocks, can crystallize from melt under pressures of 10?C11 GPa in static regime or at the relief of pressure of a shock wave under pressures of 15?C17 GPa and more. The other minerals crystallizing from the melt at a pressure decrease are ferrous hortonolite (unit cell parameters of ringwoodite and hortonolite are reported), minerals belonging to the spinel group and having variable Fe mole fractions, clinopyroxene, orthopyroxene, anorthite, and corundum. Hollow, skeleton, dendritic, and whisker crystals of these minerals suggest that they crystallized at the cooling and strong undercooling of the melt. The crystallization temperature of the hercynite is 1780°C. The temperature of the melt that produced the pumice is estimated at 1900?C2700°C. Our find of ringwoodite is the first discovery of this mineral in natural impact rocks.  相似文献   

3.
陈鸣 《地学前缘》2005,12(1):23-27
橄榄石高压多形林伍德石被认为是地幔过渡带的主要矿物。天然产状林伍德石主要在发生强烈冲击变质的球粒陨石冲击脉体中出现。目前还没有在地球岩石中发现林伍德石的报告。陨石冲击脉体的温度压力历史和矿物组合特征研究表明,林伍德石形成后,高压下淬火是使林伍德石不发生退变作用的重要条件。陨石中有利于林伍德石保存的淬火时间仅为数秒到十多秒。在地球上任何地质事件中,均难以实现在如此短的时问内使位于地幔过渡带的林伍德石被带往地球表层。寻找地球产状的林伍德石,关键是要在岩石和矿物中存在有利于林伍德石保存的条件,特别是当这些岩石和矿物仍处于高温的环境时。  相似文献   

4.
The products of shock metamorphism in the Jänisjärvi astrobleme in Karelia, Russia, are compared with the results of experiments in which spherical converging shock waves affected a spherical rock sample. The sample was loaded by a broad spectrum of shock pressures, which increased from ～20 GPa at the periphery of the rock sphere to > 200 GPa at its center. Experiments with rocks metamorphosed under the effect of spherical converging shock waves imitate collisions of cosmic bodies with the Earth’s surface, when transformations in rocks and minerals are induced by a single impact event. The shock-thermal decomposition of mafic minerals occurs in the same succession in nature and the experiments, with some differences between natural and experimentally produced shock-thermal aggregates likely accounted for by the smaller sizes of the experimental impact rock sample and, correspondingly, its more rapid quenching. Our shock experiments were the first to synthesize ringwoodite that was rich in Al2O3 and should be referred to as aluminous ringwoodite. The mineral was produced not via the martensite transition of olivine but by means of biotite replacement coupled with the migration of elements. The transformations of minerals by shock waves (amorphization and shock-thermal decomposition) were determined to be controlled mainly by the crystal structures of these minerals. The experimental products provide evidence of the migration of chemical elements within the crystal structure. The structural setting of ions in a mineral determines the onset of element migrations and the intensity of this process.  相似文献   

5.
The sequential growth of biotite, garnet, staurolite, kyanite, andalusite, cordierite and fibrolitic sillimanite, their microstructural relationships, foliation intersection axes preserved in porphyroblasts (FIAs), geochronology, P–T pseudosection (MnNCKFMASH system) modelling and geothermobarometry provide evidence for a P–T–t–D path that changes from clockwise to anticlockwise with time for the Balcooma Metamorphic Group. Growth of garnet at ～530 °C and 4.6 kbar during the N–S‐shortening event that formed FIA 1 was followed by staurolite, plagioclase and kyanite growth. The inclusions of garnet in staurolite porphyroblasts that formed during the development of FIAs 2 and 3 plus kyanite growth during FIA 3 reflect continuous crustal thickening from c. 443 to 425 Ma during an Early Silurian Benambran Orogenic event. The temperature and pressure increased during this time from ～530 °C and 4.6 kbar to ～630 °C and 6.2 kbar. The overprinting of garnet‐, staurolite‐ and kyanite‐bearing mineral assemblages by low‐pressure andalusite and cordierite assemblages implies ～4‐kbar decompression during Early Devonian exhumation of the Greenvale Province.  相似文献   

6.
Ailaoshan orogenic belt located at the northeastern margin of the Indochina block, southeastern Tibet, was formed by subduction and collision between the Indochina and South China blocks in Triassic and slip shearing resulted from the extrusion of the Indochina block in Cenozoic. The high‐pressure pelitic granulite is located at the southeastern margin of the Ailaoshan metamorphic belt, occurs as a slice of about 500～700m in thickness, consists of garnet, sillimanite, feldspar, biotite and quartz with accessory of kyanite, sapphirine, spinel, rutile, ilmenite, zircon and apatite. The petrography and mineral chemistry show that the high‐pressure pelitic granulite had suffered three stages of metamorphism: 1) the prograde metamorphism recorded by the mineral assemblage of garnet, kyanite, feldspar, biotite and rutile; 2) the peak metamorphism shown by the mineral assemblage of garnet, sillimanite, sapphirine, ternary feldspar, K‐feldspar, plagioclase, biotite, spinel, quartz, rutile and zircon mantle; 3) the retrograde metamorphism recorded by the mineral assemblage of biotite, muscovite, plagioclase, quartz and zircon rim. Zircon SHRIMP U‐Pb dating indicates that the protolith of the pelite granulite was deposited before 336 Ma, the prograde to peak metamorphism occurred at P‐T conditions of ≥10.4 kbar at 850～919 °C in 235 Ma, and the retrograde metamorphism occurred at the P‐T condition of 3.5～3.9 kbar at 572～576 °C until to 33 Ma. They are consistent with the times of Indochina separated from Gondwanaland during late Paleozoic, the amalgamation of the south China and Indochina blocks during the Triassic, and the sinistral slip‐shearing since the Early Cenozoic respectively. It is inferred that that the sedimentary rock was subducted to the lower continental crust (30 km) and suffered granulite‐facies metamorphism due to the collision during Indosinian, then exhumed quickly to middle‐upper crust (10–12km) and superimposed retrograde metamorphism since the Cenozoic.  相似文献   

7.
The migmatitic rocks exposed in Hafafit and Feiran areas exhibit some migmatitic structures as the banded, agmatic, boudinage and schlieren structures. The dominant type of these structures is the stromatic migmatites. Electron microprobe analyses of plagioclases, biotites and amphiboles from Hafafit and Feiran areas, in the Eastern Desert and Sinai, Egypt, are carried out and the metamorphic conditions are discussed. The present study revealed marked differences in the composition of plagioclases, biotites and amphiboles from Hafafit and Feiran localities. The obtained data indicated that plagioclases of the Feiran migmatites are of andesine and oligoclase composition, and display anorthite content from An20 to An38; whereas the Hafafit migmatites show a wider range of plagioclases from An10 to An60, and therefore plagioclases have labradorite, andesine and oligoclase composition. This may be due to the slow rate of the crystallisation processes. The analyses indicated that biotites of the studied areas are of metamorphic origin showing significant variation in Fe–Mg. It is worth mentioning that biotites from Hafafit migmatites have Mg–biotite composition while that of Feiram migmatites have Fe–biotite composition. High Mg and low Fe contents in biotite suggest higher crystallisation temperature. The composition of amphiboles in Hafafit migmatites is ferro-tschermakitic hornblende, while amphiboles from Feiram migmatites are magnesio-hornblende. High Ti content in the hornblende of Feiran migmatites suggests that they were formed at slightly higher temperatures and lower pressure than the Hafafit migmatites (i.e. Feiram migmatites and Hafafit migmatites were formed at granulite and amphibolite facies, respectively). Discrimination diagrams show that the muscovite is of secondary origin. Moreover, the present study confirmed that these migmatites are mainly formed by metamorphic differentiation via partial melting.  相似文献   

8.
The gneisses and metabasites of the Sierra de Limón Verde were investigated by P–T–t determinations. The rocks are unique in the Central Andes because of their high pressure metamorphic conditions with P≈13±1 kbar at T≈660–720°C. Their age of metamorphism is ≈270 Ma, based on Sm–Nd mineral isochrons. Final uplift of the isolated basement block occurred in the Triassic with a K–Ar age of biotite at ca 235 Ma. In our interpretation, the protolith of the Permian metamorphic rocks is the crust that formed and stabilized during Early Paleozoic. The Sierra de Limón Verde rocks give insight into the lowermost part of the crust in Early Mesozoic. Its Sm–Nd isotopic composition is indistinguishable from the composition of the crust that formed in the Early Paleozoic metamorphic–magmatic cycle (ca 500 Ma) in northern Chile and NW Argentina. The tectonic-geodynamic setting that triggered the high P (∼45 km depth) metamorphism and the locally restricted exhumation of the rocks remains speculative. Continental collision or a subduction related accretionary complex is unlikely considering the regional geological situation. Transpression–transtension in a strike slip system along the continental margin is suggested as a hypothesis for future investigations.  相似文献   

9.
The minor intrusions of the Edel'veis alkaline–carbonatite complex are bounded by the spurs of the North Chuya Ridge in southeastern Gorny Altai. According to Ar–Ar isotope data, the complex formed in the Middle Cambrian (～507 Ma). All of its components (alkali clinopyroxenite–melanogabbro–alkali syenite + Ca-carbonatite) occur in only one pluton. Silicate igneous rocks are equivalent in silica content and alkalinity to potassic alkaline and subalkalic mafic rocks. Apatite-phlogopitic Ca-carbonatites are enriched in P2O5 (up to 3.6 wt.%), Sr (～2500–5500 ppm), and REE (up to ～2000 ppm) and are, presumably, of liquation genesis. A PREMA-type plume component was a predominant magma source for the complex (?Nd(T) = +6.56 to +6.85). According to isotope data (87Sr/86Sr(T) ～ 0.7032–0.7039; δ18O ～ 7.5–14.9‰; δ13C ～ –2.7 to –8.4‰), the fractionation of the melts was accompanied by their crustal contamination. The trace-element composition of the rocks suggests that the complex developed on a continental margin and its development was accompanied by late-collisional rifting and the mixing of moderately depleted (PREMA) and enriched suprasubductional lithospheric mantle (EM I or EM II) with continental crust. It is presumed that the alkaline and carbonatite complexes in the western Central Asian Fold Belt are of primary plume origin and form a LIP within this belt together with other associations produced by Early Paleozoic (510–470 Ma) magmatism.  相似文献   

10.
The chemical compositions of rock-forming minerals have been determined for both altered and least-altered igneous rocks spatially associated with numerous mineralized zones (Nucleus Au–Bi–Cu–As deposit, Revenue Au ± Cu and Stoddart Cu–Mo ± W mineral occurrences, and Laforma Au–Ag deposit) across the Freegold Mountain area, Yukon, Canada. Within the study area, K-feldspar has a narrow compositional range (89.4–91% Or), whereas plagioclase spans a wide range (4.4–70.07% An). In all of the investigated samples, T Ab = T An = T Or, suggesting that magmatic equilibrium between the coexisting plagioclase and K-feldspar was maintained. Igneous amphibole phenocrysts from hypabyssal dikes are typically calcic, whereas the Stoddart Cu–Mo ± W, Laforma Au–Ag, and Goldy Au mineralization are associated with Mg-enriched primary amphibole of edenite composition, and Au–Bi–Cu–As mineralization from Nucleus is related to Al-enriched primary amphibole of ferropargasite composition. Primary biotite phenocrysts across the Freegold Mountain area re-equilibrated with oxidized magma (f(O2) values between 10–13 and 10–11.5 bars, lying between the Ni/NiO and the magnetite/haematite buffers). However, biotite and amphibole phenocrysts from Stoddart, Goldy, Laforma, and the Highway zones crystallized from a more oxidized magma, as indicated by their elevated X Mg up to 0.65, relative to biotite and hornblende from Nucleus and Revenue characterized by a lower X Mg (typically < 0.50). This suggests that various sources and (or) rapid emplacement were involved in magma genesis, as further supported by the considerable variation of pressure (1.8–7.3 kb) of amphibole crystallization and of the total Al content in least-altered biotite (2.6–2.9 afu) within the Freegold Mountain area. Biotite and apatite equilibrated within the T range of 520–780°C, consistent with temperatures of equilibration between ilmenite and magnetite, and their compositions indicate that they formed from an oxidized I-type magma. Magma differentiated by fractional crystallization (indicated by the presence of normally zoned plagioclase with Ca-rich cores and Na-enriched outer rims) and multiple magma mixing (supported by the presence of reversed zoned plagioclase and coexistence of normally and reversely zoned plagioclase). Lower X Mg biotite associated with the mineralized (Cu–Mo ± W) potassic alteration incorporated more F and Cl relative to least-altered biotite with higher X Mg. In both Nucleus and Revenue Au–Cu mineralizations, secondary biotite composition varies with respect to the associated alteration mineral assemblages. Although secondary biotite in the skarn re-equilibrated with F-poor fluids, secondary biotite from the pervasive biotitization is related to F- and Cl-enriched fluids, and secondary biotite from the phyllitic zone is related to F-, Cl-, and Mg-depleted fluids, thus consistent with a change in mineralizing fluid composition during mineralization.  相似文献   

11.
Detailed electron microprobe analyses of phyllosilicates in crenulated phyllites from south‐eastern Vermont show that grain‐scale zoning is common, and sympathetic zoning in adjacent minerals is nearly universal. We interpret this to reflect a pressure‐solution mechanism for cleavage development, where precipitation from a very small fluid reservoir fractionated that fluid. Multiple analyses along single muscovite, biotite and chlorite grains (30–200 μm in length) show zoning patterns indicating Tschermakitic substitutions in muscovite and both Tschermakitic and di/trioctahedral substitutions in biotite and chlorite. Using cross‐cutting relationships and mineral chemistry it is shown that these patterns persist in cleavages produced at metamorphic conditions of chlorite‐grade, chlorite‐grade overprinted by biotite‐grade and biotite‐grade. Zoning patterns are comparable in all three settings, requiring a similar cleavage‐forming mechanism independent of metamorphic grade. Moreover, the use of 40Ar/39Ar geochronology demonstrates this is true regardless of age. Furthermore, samples with chlorite‐grade cleavages overprinted by biotite porphyroblasts suggest the closure temperatures for the diffusion of Al, Si, Mg and Fe ions are greater than the temperature of the biotite isograd (>～400 °C). Parallel and smoothly fanning tie lines produced by coexisting muscovite–chlorite, and muscovite–biotite pairs on compositional diagrams demonstrate effectively instantaneous chemical equilibrium and probably indicate simultaneous crystallization. These results do not support theories suggesting cleavages form in fluid‐dominated systems. If crenulation cleavages formed in systems in which the chemical potentials of all major components are fixed by an external reservoir, then the compositions of individual grains defining these cleavages would be uniform. On the contrary, the fine‐scale chemical zoning observed probably reflects a grain‐scale process consistent with a pressure‐solution mechanism in which the aqueous activities of major components are defined by local dissolution and precipitation. Thus the role of fluids was probably limited to one of catalysing pressure‐solution and fluids apparently did not drive cleavage development.  相似文献   

12.
We report here rare evidence for the early prograde P-Tevolution of garnet-sillimanite-graphite gneiss(khondalite)from the central Highland Complex,Sri Lanka.Four types of garnet porphyroblasts(Grt_1,Grt_2,Grt_3 and Grt_4)are observed in the rock with specific types of inclusion features.Only Grt_3 shows evidence for non-coaxial strain.Combining the information shows a sequence of main inclusion phases,from old to young:oriented quartz inclusions at core,staurolite and prismatic sillimanite at mantle,kyanite and kyanite pseudomorph,and biotite at rim in Grt_1;fibrolitic sillimanite pseudomorphing kyanite±corundum,kyanite,and spinel+sillimanite after garnet+corundum in Grt_2;biotite,sillimanite,quartz±spinel in Grt_3;and ilmenite,rulite,quartz and sillimanite in Grt_4.The pre-melting,original rock composition was calculated through stepwise re-integration of melt into the residual,XRF based composition,allowing the early prograde metamorphic evolution to be deduced from petrographical observations and pseudosections.The earliest recognizable stage occurred in the sillimanite field at around 575℃ at 4.5 kbar.Subsequent collision associated with Gondwana amalgamation led to crustal thickening along a P-T trajectory with an average dP/dT of ~30 bar/℃ in the kyanite field,up to ~660℃ at 6.5 kbar,before crossing the wet-solidus at around 675 ℃ at 7.5 kbar.The highest pressure occurred at P 10 kbar and T around 780℃ before prograde decompression associated with further heating.At 825℃ and 10.5 kbar,the rock re-entered into the sillimanite field.The temperature peaked at 900℃ at ca.9-9.5 kbar.Subsequent near-isobaric cooling led to the growth of Grt_4 and rutile at T ~880℃.Local pyrophyllite rims around sillimanite suggest a late stage of rehydration at T400℃,which probably occurred after uplift to upper crustal levels.U-Pb dating of zircons by LAICPMS of the khondalite yielded two concordant ~(206)Pb/~(238)U age groups with mean values of 542±2 Ma(MSWD=0.24,Th/U=0.01-0.03)and 514±3 Ma(MSWD=0.50,Th/U=0.01-0.05)interpreted as peak metamorphism of the khondalite and subsequent melt crystallization during cooling.  相似文献   

13.
A petrological and thermobarometric study of the Lago Teleccio hornfelses was undertaken to reconstruct the polymetamorphic evolution and constrain the P–T conditions of Permian contact metamorphism. The Lago Teleccio metasedimentary rocks record a Variscan regional metamorphism characterized by amphibolite facies mineral assemblages including quartz, plagioclase, K‐feldspar (Kfs 1), biotite, garnet (Grt 1) and staurolite; this was followed by a late‐Variscan mylonitization event. Metamorphism of the Variscan metamorphic rocks at the contact with a Permian granitic intrusion produced static recrystallization and/or new growth of quartz, garnet (Grt 2), plagioclase, K‐feldspar (Kfs 2), cordierite, green spinel, biotite and prismatic sillimanite (Contact 1). This thermal event, which occurred at a peak pressure of 0.23–0.35 GPa, temperature of 670–700 °C and aH2O of 0.75–1, was followed either during post‐contact metamorphism cooling or, more likely, during the early‐Alpine metamorphism by the breakdown of cordierite into an anhydrous kyanite + orthopyroxene + quartz assemblage. The poorly developed early‐Alpine eclogite facies metamorphism (Alpine 1) was characterized by relatively anhydrous mineral associations and low strain, which locally produced coronitic and pseudomorphous microstructures in metasedimentary rocks, with scanty formation of jadeite, zoisite and a new high‐pressure garnet (Grt 3). Greenschist facies retrogression (Alpine 2) was characterized by the local development of a chlorite‐ and muscovite‐bearing mineral association, suggestive of aqueous fluid incursion. In the hornfelses, the limited extent of metamorphic overprinting is suggested by the fine grain size of the Alpine mineral associations, which formed at the expense of the Permian contact metamorphic associations, and was favoured by the anhydrous mineralogy of the hornfelses.  相似文献   

14.
高栋  吴才来  郜源红  吴迪  郑坤  徐楠  陈红杰 《中国地质》2022,49(5):1636-1655
【研究目的】 玉苏普阿勒克塔格花岗岩体位于阿尔金造山带南部茫崖蛇绿混杂岩带内,主要由中粗粒似斑状黑云二长花岗岩及中细粒含斑黑云二长花岗岩组成。玉苏普阿勒克塔格岩体的形成时代、成因类型和岩浆物质来源尚不明确,制约了我们进一步认识该岩体形成的地球动力学背景以及南阿尔金造山带早古生代构造演化过程。【研究方法】 因此,本文对玉苏普阿勒克塔格岩体进行了岩石学、锆石U-Pb年代学、全岩地球化学、黑云母矿物化学及Hf同位素组成等方面的研究。【研究结果】 锆石U-Pb年代学研究结果表明该岩体中粗粒似斑状黑云二长花岗岩的锆石U-Pb加权平均年龄为451~447 Ma。结合前期工作获得该岩体中细粒含斑黑云二长花岗岩的年龄（430~423 Ma）,笔者认为玉苏普阿勒克塔格花岗岩体属于早古生代岩浆活动的产物。黑云母矿物化学研究结果表明,玉苏普阿勒克塔格岩体形成于温度较低压力较高环境。根据玉苏普阿勒克塔格岩体两期花岗岩的矿物组成、全岩地球化学特征及形成的物理化学环境,认为该岩体属于I型花岗岩。Hf同位素组成研究结果表明,玉苏普阿勒克塔格岩体两期花岗岩具有相似的Hf同位素组成,暗示它们具有相似的物质来源：源岩以新生地壳的部分熔融为主,在侵位过程中经历了部分古老地壳物质的混染。【结论】 综合玉苏普阿勒克塔格花岗岩体的形成时代、成因类型、物质来源,结合区域构造演化资料,本文认为玉苏普阿勒克塔格岩体形成于与南阿尔金洋北向俯冲有关的活动大陆边缘环境。  相似文献   

15.
The Oligocene Yao’an syenite porphyry, associated with gold mineralisation, and the Machangqing alkali granite porphyry–monzonite porphyry, associated with Cu mineralisation, belong to the Red River–Jinshajiang alkaline igneous belt that formed in a continental setting in southwestern China. A study of the mineral chemistry of major silicate minerals in these two mineralised intrusions provides insights into their overall crystallisation conditions. The temperature and pressure conditions, derived from amphibole–plagioclase and perthite–plagioclase geothermometry and Al-in-amphibole barometry, suggest that the Yao’an intrusion crystallised at around 820?±?50°C and 0.9–1.3 kbar, whereas the Machangqing intrusion crystallised at around 730?±?50°C and 2.2–2.8 kbar. The higher temperature and lower pressure of crystallisation for the Yao’an intrusion relative to the Machangqing intrusion indicates that it was emplaced at a shallower crustal level. Based on biotite composition, the two intrusions formed under imposed oxygen fugacities above the Ni–NiO buffer (NNO), and the Yao’an intrusion crystallised under more oxidising conditions than the Machangqing intrusion. The results show that the intrusions associated with Cu–Au mineralisation in the Red River–Jinshajiang alkaline igneous belt were emplaced at a relatively high fO2, which, together with the weakly fractionated magma, favoured Au enrichment relative to Cu in the belt.  相似文献   

16.
The metamorphic evolution of a granulitized eclogite from the Phung Chu Valley (Eastern Himalaya) was reconstructed combining microstructural observations, conventional thermobarometry and quantitative pseudosection analysis. The granulitized eclogite consists of clinopyroxene, plagioclase, garnet, brown amphibole, and minor orthopyroxene, biotite, ilmenite and quartz. On the basis of microstructural observations and mineral relationships, four metamorphic stages and related mineral assemblages have been recognized: (i) M1 eclogite‐facies assemblage, consisting of garnet, omphacite (now replaced by a clinopyroxene + plagioclase symplectite) and phengite (replaced by biotite +plagioclase symplectite); (ii) M2 granulite‐facies assemblage, represented by clinopyroxene, orthopyroxene, garnet, plagioclase and accessory ilmenite; (iii) M3 plagioclase + orthopyroxene corona developed around garnet, and (iv) M4 brown amphibole + plagioclase assemblage in the rock matrix. Because of the nearly complete lack of eclogitic mineral relics, M1 conditions can be only loosely constrained at >1.5 GPa and >580 °C. In contrast, assemblage M2 tightly constrains the peak granulitic stage at 0.8–1.0 GPa and >750 °C. The second granulitic assemblage M3, represented by the plagioclase + orthopyroxene corona, formed at lower pressures (～0.4 GPa and ～750 °C). During the subsequent exhumation, the granulitized eclogite experienced significant cooling to nearly 700 °C, marked by the appearance of brown amphibole and plagioclase (M4) in the rock matrix. U‐Pb SHRIMP analyses on low‐U rims of zircon from an eclogite of the same locality suggest an age of 13–14 Ma for the M3 stage. The resulting decompressional clockwise P–T path of the Ama Drime eclogite is characterized by nearly isothermal decompression from >1.5 GPa to ～0.4 GPa, followed by nearly isobaric cooling from ～775 °C to ～710 °C. Modelling of phase equilibria by a calculated petrogenetic grid and conventional thermobarometry on a biotite‐garnet‐sillimanite metapelite hosted in the country rock granitic orthogneiss extends the inferred P–T trajectory down to ～630 °C and ～0.3 GPa.  相似文献   

17.
The evolution of the mineral assemblages and P–T conditions during partial melting of upper‐amphibolite facies paragneisses in the Orue Unit, Epupa Complex, NW Namibia, is modelled with calculated P–T–X phase diagrams in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O system. The close concordance of predictions from the phase diagrams to petrographic observations and thermobarometric results documents that quantitative phase diagrams are suitable to explain the phase relationships in migmatitic upper‐amphibolite facies low‐ and medium‐pressure metapelites, which occur in many high‐grade metamorphic terranes worldwide. Different mineral assemblages in the migmatitic metapelites of the Orue Unit reflect regional discrepancies in the metamorphic grade: in a Northern Zone, early biotite–sillimanite–quartz assemblages were replaced via melt‐producing reactions by cordierite‐bearing assemblages. In a Southern Zone, they were replaced via melt‐producing reactions by garnet‐bearing assemblages while cordierite is restricted to rare metapelitic granofelses, which preserve Grt–Sil–Crd–Bt peak assemblages. Peak‐metamorphic conditions of 700–750 °C at 5.5–6.7 kbar in the Southern Zone and of ～750 °C at 4.5 kbar in the Northern Zone are estimated by integrating thermobarometric calculations with data from calculated mineral composition isopleths. Retrograde back‐reactions between restite and crystallizing melt are recorded by the replacement of garnet by biotite–sillimanite and/or biotite–muscovite intergrowths. Upper‐amphibolite facies metamorphism and partial melting (c. 1340–1320 Ma) in the rocks of the Southern Zone of the Orue Unit, which underwent probably near‐isobaric heating–cooling paths, are attributed to contact metamorphism induced by the coeval (c. 1385–1319 Ma) emplacement of the Kunene Intrusive Complex, a huge massif‐type anorthosite body. The lower‐pressure metapelites of the Northern Zone are interpreted to record contact metamorphism at an upper crustal level.  相似文献   

18.
Biotite dissolution experiments were carried out to better understand the dissolution kinetics and Fe behavior under low O2 conditions, and to give an insight into the Precambrian weathering. Mineral dissolution with a continuous flow-through reactor was employed at 25 °C for up to 65 days varying partial pressure of atmospheric oxygen (PO2), pH (6.86 and 3.01) and Fe content in mineral (1.06 and 0.11 mol of Fe per O10(OH,F)2 for biotite and phlogopite, respectively) independently for the examination of their effects on biotite dissolution. Low PO2 conditions were achieved in a newly developed glove box (PO2 ? 6 × 10−4 atm; referred to as anoxic conditions), which was compared to the present, ambient air conditions (0.2 atm of PO2; oxic conditions). The biotite dissolution rate was slightly faster under anoxic conditions at pH 6.86 while it was not affected by PO2 at pH 3.01. There was no direct effect of Fe content on dissolution rate at pH 6.86 while there was a small difference in dissolution rate between biotite and phlogopite at pH 3.01. The 1.5 order-of-magnitude faster release rate of Fe under anoxic conditions for biotite dissolution at pH 6.86 resulted from the difference in ratio of Fe3+ precipitates remaining in the reactor to Fe dissolved (about 60% and 100% under anoxic and oxic conditions, respectively), which is caused mainly by the difference in PO2. The results infer that the Fe2+ and Fe3+ contents in the Paleoproterozoic paleosols, fossil weathering profiles, are reflected by atmospheric oxygen levels at the time of weathering.  相似文献   

19.
The mechanism of the high pressure transformation of olivine in the presence of aqueous fluid was investigated by high pressure experiments conducted nominally at the wadsleyite + ringwoodite stability field at 14.5 GPa and 700 and 800°C. The microstructures of recovered samples were observed using an analytical transmission electron microscope (ATEM) for which foils were prepared using a focused ion beam technique. Glass films approximately 1 μm in width always occupied the interface between olivine and hydrous ringwoodite. ATEM measurements showed that the chemical compositions of the glass films had approximately the same Mg/Fe ratio as that of olivine, but a higher Si content. Micro-structural and -chemical observations suggest that these glass films formed as quenched glass from the aqueous fluid dissolving olivine and that hydrous ringwoodite was crystallized from the fluid. This indicates that the transformation of olivine to hydrous ringwoodite was prompted by the dissolution–reprecipitation process. The dissolution–reprecipitation process is considered an important mineral replacement mechanism in the Earth’s crust by which one mineral is replaced by a more stable phase or phases. However, this process has not previously been reported for deep mantle conditions.  相似文献   

20.
文章主要通过电子探针、扫描电镜、激光拉曼光谱、透射电镜等微区微分析技术研究GRV 022115球粒陨石的基础矿物学特征和冲击变质矿物学特征，探讨陨石冲击熔融脉的形成机制和界定其母体的冲击条件。陨石主岩主要由橄榄石、辉石、熔长石、铁镍金属和硫化物等矿物组成。根据主岩的硅酸盐矿物学特征，确定GRV 022115是风化程度较低（W1） 的L6型普通球粒陨石，与前期分类结果一致。根据熔融脉内含有大量林伍德石的现象，修正GRV 022115陨石的冲击级别为S6，比原定的S5高一个级别。GRV 022115球粒陨石中有多条冲击熔融脉，熔融脉由基质和主岩碎块包裹体两类岩相组组成。熔融脉基质的主要组成是微米级粒状镁铁榴石与纳米级的含铁方镁石，是在平衡冲击压力下结晶的产物。冲击熔融脉主岩碎块包裹体中的橄榄石、低钙辉石、长石碎块已部分或全部转为相对应的高压相。橄榄石相变为林伍德石；个别低钙辉石相变为钙钛矿结构布里奇曼石微晶的集合体；长石主要相变为熔长石与玲根石。几乎所有的主岩碎块都有高温熔融的圆滑边界。熔融脉内外同类矿物的主量和微量元素具有一定的差异性，该差异性可以反映高温高压下混溶作用和扩散作用的影响。结合陨石冲击熔融脉形成机制和结晶模型，根据熔脉基质中镁铁榴石+方镁石矿物组合及静态高温高压实验相图，界定该陨石经受的冲击压力为23~27 GPa。  相似文献   

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