首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 326 毫秒
1.
Soil samples collected from various places in and around Mysore were analyzed for the total trace elements such as Fe, Mn, Cu, Zn, Pb, and Cd. The results of the analysis indicate that the concentration of lead and cadmium in soils is below 2.5 g ml–1 and 0.2 g ml–1, respectively, which are the minimum detection levels, whereas the concentration of iron, manganese, copper, and zinc in most of the samples is within the global average ranges of 3%, 500–1000 g g–1, 15–40 g g–1, and 50–100 g g–1, respectively. The investigated area has the presence of gneisses and schists, in which partly there are igneous intrusions and pegmatitic intrusions. There are amphibolite enclaves in gneisses that account for the higher concentration of trace elements. The lower concentration may be attributed to the presence of silicic type of rock.  相似文献   

2.
Lake Suwa, located in the center of the largest Japanese island of Honshu was a typical hypertrophic lake with a dense scum Microcystis species in summer during the 1970's. However, due to the introduction of a sewage treatment plant and the awareness of environmental pollution by local residents, a decrease in the concentration of nutrients in lake water since 1981 has been observed (from 1600 g l–1 and 160 g l–1 in 1977 to 990 g l–1 and 110 g l–1 in 1984 for total nitrogen and phosphorus respectively).  相似文献   

3.
The distribution of some trace metals (Cu, Zn, Ni, Co,Fe, Mn) and of DOC over a particulate (> 1 m),a colloidal (size < 0.45 m and molecular weight > 10 kD) and an ultrafiltered fraction (< 10 kD)was determined at several sites on the Thur River,Switzerland, at various times of the year. Thecomplexation of Cu by strong ligands in theultrafiltrate and in the conventional filtrate (<0.45 m) was compared using a ligand-exchange/CSV method.The <0.45 m concentrations of Cu (from anaverage of 7 nM to 24 nM), Zn (<5–23 nM), Ni (5–13 nM),Co (1.5–3 nM) and Mn (7–92 nM)increased downstream. The major part of Cu, Zn, Niand Co usually occurred in the ultrafiltratefraction at all sites, whereas Fe and Mn were mostlyin the particulate fraction, under conditions of lowsuspended matter content (< 10 mg L-1) in theriver. The percentage of metal in the colloidalfraction, with respect to the 0.45-m filtrate,decreased in the order: Cu (median 11%) > Zn Ni(median 5–6%) > Mn Co (median < 5%). DOCalso consisted mostly of molecules in the < 10 kDrange.Cu was strongly complexed by natural organic ligandsin all filtrate and ultrafiltrate samples. A largepart of the strong Cu binding ligands consisted ofcompounds in the < 10 kD range, but colloidalligands with similar properties also occurred. Cu wasdistributed among the dissolved and the colloidalligands, roughly in proportion to organic carbon.The colloidal fraction (as defined here) did notincrease in its proportional amount downstream and wasonly of limited significance in transporting traceelements in the Thur River under low discharge conditions.  相似文献   

4.
Gediz Graben is an important area for geothermal activity in Turkey. Menderes Massif rocks consisting of gneisses, schists, marbles and granodiorite, comprise the aquifers of the geothermal systems. Neogene terrestrial sediments made up mainly of sandy and clayey conglomerates cap the systems. Gediz Graben geothermal areas are physically divided into seven main groups: Turgutlu-Urganl, Sart-Çamur, Caferbeyli, Üfürük, Kurunlu, Kavakldere-Sazdere and Alaehir geothermal areas. The third highest aquifer in Turkey temperature (182 °C) after Kzldere (242 °C) and Germencik (232 °C) was discovered in the Kavakldere-Sazdere area. The thermomineral waters of the Gediz Graben geothermal areas have outlet temperatures of 25–95 °C and an electrical conductivity of 874–6020 S/cm. Mineralization is mostly dominated by Na+ (188–2027 ppm) and HCO3– (544–2950 ppm). Kavakldere-Sazdere area shows the highest boron content among the entire geothermal aquifers of Turkey. Major geochemical processes for thermomineral waters are carbonate and silicate dissolution and mixing.  相似文献   

5.
Divariant oxide plus metal assemblages potentially make useful redox sensors for use in hydrothermal and other high pressure experiments. Here we report the calibration of the (Ni, Mn)O/Ni redox sensor in which the Ni/NiO (NNO) oxygen buffer is displaced to lower oxygen chemical potentials (O2), by the solid solution of MnO in the oxide phase. This assemblage was chosen because: (1) it covers a useful range of O2; (2) the system can be calibrated very accurately. Values of O2 defined by the (Ni, Mn)O/Ni assemblage were determined electrochemically, from 900 to 1300 K, using calcia-stabilized zirconia solid electrolytes. The oxide compositions (8 in total, ranging from 0.1X NiO0.8) were analysed afterwards by electron microprobe, and were checked for internal consistency by measuring the lattice parameters (a0), using powder XRD. The accuracies of the measurements, both assessed theoretically and established empirically, are (1): ±80J/mol in O2, ±0.0002 Å in a0 and ±0.002 to 0.005 in X NiO. Activity-composition relations were fitted to the Redlich-Kister formalism. There is a slight asymmetry (corresponding to a subregular model) across the solution with A 0 G =9577(±45) J/mol, and A 1 G =–477(±80) J/mol. The experimental data were also used to derive the parameters Vex, Hex and Sex. There is no obvious relationship between excess volumes and enthalpies of mixing, nor between excess volumes and excess entropies. The experimental data from this study have been used to formulate the (Ni, Mn)O/Ni redox sensor expression: O2 = 2(NNO) + 2RTlnX NiO + 2(1 – X NiO)2[11483 – 1.697T] – 477(4X NiO – 1)(900 < T(K) < 1300) where O2(NNO)=–478967+248.514T–9.7961 T In T, from O'Neill and Pownceby(1993a).  相似文献   

6.
The Brixen Quartzphyllite, basement of the Southern Alps (Italy), consists of metasediments which had suffered progressive deformation and low grade metamorphism (p max4 kbar, T max375±25° C) during the Palaeozoic. It has been excavated by pre-Permian erosion, buried again beneath a pile of Permo-mesozoic to Cainozoic sediments (estimated T max150° C), and is now exposed anew due to late Alpine uplift and erosion. The behavior of the K-Ar system of white micas is investigated, taking advantage of the narrow constraints on their thermal history imposed by the geological/stratigraphic reference systems.The six structurally and petrographically differing samples come from a single outcrop, whose position is roughly two kilometers beneath the Permian land-surface. White mica concentrates from five grain size fractions (<2 , 2–6 , 6–20 , 20–60 , 60–75 ) of each sample have been analyzed by the conventional K-Ar method, four selected concentrates additionally by the 40Ar/39Ar stepwise heating technique; furthermore, Ar content and isotopic composition of vein quartz were determined.The conventional ages of the natural grain size fractions (20–60 , 60–75) are in the range 316±8 Ma, which corresponds to the 40Ar/39Ar plateau age of 319.0±5.5 Ma within the error limits. The finer grain size fractions yield significantly lower ages, down to 233 Ma for fractions <2 . Likewise low apparent ages (down to 83 Ma) are obtained for the low temperature 40Ar/39Ar degassing steps.There is no correlation between microstructural generation of white mica prevailing in the sample and apparent age. This favours an interpretation of the 316±8 Ma values as cooling age; progressive deformation and metamorphism must be respectively older and their timing cannot be resolved by these methods. The data preclude any significant influence of a detrital mica component as well as of excess argon.The lower ages found for the fine grain-size fractions (respectively the low-T degassing steps) correspond to a near-surface period (p-T-minimum); the values are geologically meaningless. The effect is interpreted to result from partial Ar loss due to reheating during Mesozoic-Cainozoic reburial. A model based on diffusion parameters derived from the outgassing experiments and Dodson's (1979) equation yields a closure temperature of 284±40 °C for a cooling rate of 18° C/Ma. Furthermore, this model suggests that the observed argon loss of up to 5% may in fact have been induced by reheating to 150 °C for 50 Ma.  相似文献   

7.
The carbon isotopic fractionation between CO2 vapour and sodamelilite (NaCaAlSi2O7) melt over a range of pressures and temperatures has been investigated using solid-media piston-cylinder high pressure apparatus. Ag2C2O4 was the source of CO2 and experimental oxygen fugacity was buffered at hematite-magnetite by the double capsule technique. The abundance and isotopic composition of carbon dissolved in sodamelilite (SM) glass were determined by stepped heating and the 13C of coexisting vapour was determined directly by capsule piercing. CO2 solubility in SM displays a complex behavior with temperature. At pressures up to 10 kbars CO2 dissolves in SM to form carbonate ion complexes and the solubility data suggest slight negative temperature dependence. Above 20 kbars CO2 reacts with SM to form immiscible Na-rich silicate and Ca-rich carbonate melts and CO2 solubility in Na-enriched silicate melt rises with increasing temperature above the liquidus. Measured values for carbon isotopic fractionation between CO2 vapour and carbonate ions dissoived in sodamelilite melt at 1200°–1400° C and 5–30 kbars average 2.4±0.2, favouring13C enrichment in CO2 vapour. The results are maxima and are independent of pressure and temperature. Similar values of 2 are obtained for the carbon isotopic fractionation between CO2 vapour and carbonate melts at 1300°–1400° C and 20–30 kbars.  相似文献   

8.
Groundwaters from crystalline and metamorphic rocks (hardrocks) and from Quaternary deposits, i.e., alluvial and glacial deposits (softrocks) from the counties of Nord-Trøndelag and Sør-Trøndelag were analyzed for major and minor elements and ions including fluoride. The median concentration of F– in water from the hardrock aquifers is 0.28 mg/l (14.7 eq/l) in contrast to water from softrock aquifers in which it is found to be 0.05 mg/1 (2.6 eq/l). More importantly, ca. 15% of the locations where water was abstracted from hardrock wells contain 1.5 mg/l (78.9 eq/l) F– or more. Thus, 15% of all hardrock wells returned F– results that are at or above the maximum recommended value for drinking water. Of the softrock wells, none are above 1 mg/l. Geologists would normally expect higher F–contents in groundwaters derived from acid rocks, e.g., in granitic or gneissic areas. When comparing the host lithology with the observed F–contents, however, no clear relationship between F– content and lithology is visible. The highest observed F– values actually occur in gneissic host rocks. However, wells drilled in amphibolites/greenstones, mica schists, calcareous rocks, and sedimentary rocks all returned some analytical results above 1.5 mg/l F–. These results suggest that all hardrock wells drilled should be tested for F– and the users informed about the results and advised to take any necessary precautions. When applying the recently proposed Norwegian drinking water limits to our data, 51% of all softrock well waters and 56% of all hardrock well waters are unfit for consumption without prior treatment, although we analyzed only for about half of the proposed elements/parameters. This result seriously questions the concept of fixed action levels—many of them with totally unproven health implications—for so many parameters/elements for hardrock groundwaters.  相似文献   

9.
The Oso Bay, Texas, sediments from nine sites were analyzed by GC-MS for organics to measure contamination in the bay. In most of the sites sediments contained tetrachloroethene (87–1433 g/kg), bis (2-ethylhexyl)phthalate (40–193 g/kg), and aliphatic hydrocarbons, C8-C13 (720–2491 g/kg). Sources of these contaminants include a landfill, military facilities, and municipal and industrial discharges. Size analysis of the sediments indicates they contain a high percentage of muddy sand (50–75 percent), which suggests that Oso Bay consists of common bay margin sediments.  相似文献   

10.
This paper refers to the morphometric and hydrological conditions, as well as to the physical and chemical characteristics of the Kerkini reservoir (N Greece) and determines the trophic status. The flushing rate, and the residence time of the water show clearly the dominance of the riverine system upon the lacustrine circulation pattern. The shallowness of the reservoir, the inflow of river Strimon, and the nearly continuous functioning of the dam throughout the year should be considered as the factors influencing the circulation of the water in the reservoir. Phosphorous mean annual value, mean annual and maximum values of chlorophyll-a were found 106.6 g P 1–1, 18.4 g 1–1, 29.7 g 1–1 respectively. There is a tendency of the reservoir to decline into a hypertrophic state from a eutrophic one. River Strimon contributes significantly to the overloading of the reservoir by nitrogenous agricultural effluents.  相似文献   

11.
Summary The mineral trigonite crystallizes in the monoclinic space groupPn–C s 2 witha 0=7.26,b 0=6.78,c 0=11.09Å; =91.5°,Z=2. The structure was determined from 1250 X-ray intensities collected on an automatic two circle Weissenberg-type diffractometer. The final residual isR=6.5% using anisotropic temperature factors for Pb, Mn and As, and isotropic temperature factors for O.The structure consists of MnO6 octahedra, sharing all six oxygens with arsenite groups to form a framework. The Pb atoms are attached to this framework with Pb–O distances2.23Å. One oxygen, bound only to an As atom, is interpreted as the donor for a hydrogen bond of 2.75Å.
Die Kristallstruktur des Trigonits, Pb3Mn(AsO3)2(AsO2OH)
Zusammenfassung Das Mineral Trigonit kristallisiert monoklin, RaumgruppePn–C s 2 ,a 0=7,26,b 0=6,78,c 0=11,09Å; =91,5°;Z=2. Die Strukturermittlung erfolgte anhand von 1250 Röntgenintensitäten, die auf einem automatischen Zweikreis-Weissenbergdiffraktometer gesammelt wurden. Mit anisotropen Temperaturfaktoren für Pb, Mn und As sowie isotropen für die O-Atome ergibt sich einR-Wert von 6,5%.Die MnO6-Oktaeder werden über die sechs Sauerstoffe mit Arsenitgruppen zu einem dreidimensionalen Gerüst verknüpft. Über Pb-O-Abstände2,23 Å sind die Pb-Atome in dieses Gerüst eingebaut. Ein Sauerstoff, nur an ein As-Atom gebunden, wird als Donator einer H-Brücke von 2,75 Å interpretiert.

With 2 Figures  相似文献   

12.
Northern Brazil contains remnants of Mesozoic flood basalts and hypabyssal rocks that were apparently emplaced during tectonism related to opening of the Atlantic Ocean. Analyses and new K-Ar ages reveal that this 700x250 km Maranhão province (5°–8°S) has low-Ti basalts (1.1 wt% TiO2) in the western part that range about 160 to 190 Ma, and high-Ti basalts (3.4–4.4 wt% TiO2) in the eastern part about 115–122 Ma. Low-Ti basalt compositions are less evolved and have a smaller range, Mg# 62-56, than the high-Ti basalts, Mg# 44–33. General characteristics of the least evolved members of low- and high-Ti groups include, respectively, Zr 100 and 250 ppm, Sr 225 and 475 ppm, Ba 200 and 500 ppm, Nb 10 and 26 ppm, Y 29 and 36 ppm, La/Yb(n) 4.2 and 8.8, where La(n) is 30 and 90. Overall compositions resemble the low- and high-Ti basaltic rocks of the Mesozoic Serra Geral (Paraná) province in southern Brazil. The Maranhão low-Ti basalts have more radiogenic Sr and Pb and higher 18O than the high-Ti basalts. Respectively, low- vs high-Ti: Sr26–54 vs 15–18; 206Pb/204Pb=18.25–.78 vs 18.22–.24; and 18O 8.9–12.6 vs 6.5–8.6. Nd isotopes overlap: Nd–1.6 to –3.8 vs –2.1 to –3. Ages, compositions, and isotopes indicate that the low- and high-Ti groups had independent parentages from enriched subcontinental mantle. However, both groups can be modeled from one source composition if low-Ti basalt isotopes reflect crustal contamination, and if the parentages for each group were picritic liquids that represent either higher (for low-Ti) or lower (for high-Ti) percentages of melting of that single source. When comparing Pb isotopes of Maranhão and Serra Geral high-Ti basalts (uncontaminated) to evaluate the DUPAL anomaly, Maranhão has Pb 7/4=4.6–11, and Pb 8/4=72–87; Serra Geral has Pb 7/4=10–13, and Pb 8/4=95–125. The small difference is not enough to conform to DUPAL contours, and is inconsistent with large-scale isotopic heterogeneity of mantle beneath Brazil prior to rifting of South America from Africa. Maranhão low-Ti magmas probably relate to the opening of central North Atlantic, and high-Ti magmas to the opening of equatorial Atlantic. The proposed greater percentage of source melting for low-Ti basalts may reflect a Triassic-Jurassic hotspot, while lesser melting for high-Ti magmas may relate to Cretaceous decompressional (rifting) melting.  相似文献   

13.
The lead isotopic compositions of galena in Early Proterozoic gold deposits have been determined for three districts in northern Sweden and central Finland. The deposits are hosted by a variety of 1870–1890 Ma Svecofennian host rocks including the volcanosedimentary succession within the Skellefte District island arc in Sweden as well as I-type tonalites at Jörn (Sweden) and Pohjanmaa (Finland). The deposits are epigenetic in relation to these Svecofennian rocks and are part of a goldbearing metallogenetic belt, which can be followed for 600 km parallel to the southwestern margin of the Archaean Domain. In spite of these epigenetic relationships, the lead isotopic data indicate that the deposits are not dramatically younger than the 1870–1890 Ma Svecofennian host rocks (probably not exceeding 10–20 million years). Two principal lead sources were activated when the gold deposits were formed. The most significant source is represented by the I-type tonalites, which constitute a relatively primitive ( = 9.3) and widely distributed source in the entire metallogenic belt. In addition, the volcanic components in the westernmost part of the Skellefte District constitute an extremely primitive ( <9.0) source, which only locally was an important contributor to the epigenetic deposits in this metallogenetic belt. The significantly different lead isotopic composition estimated for these sources indicates that the volcanic rocks in the western part of the Skellefte District were not comagmatic with the I-type tonalites recognized at Jörn and central Finland.  相似文献   

14.
Zusammenfassung Mikroskopisch Einschluß-freie Disthene aus der Schweiz zeigen im nahen UR-Spektralbereich eine scharfe Absorptionsbande mit einem Doppelmaximum bei 2,96 und 3,06 , das der OH-Streckschwingung zuzuordnen ist. In Kristallplatten parallel (100) zeigt das Doppelmaximum einen starken, in Platten parallel (010) einen nur schwachen Pleochroismus. Der Pleochroismus kann unter der Annahme zweier kristallographisch verschiedener OH-Gruppen erklärt werden, deren wahrscheinliche Orientierung abgeleitet wird.
Measurement of the infrared-pleochroism in minerals. XII. The pleochroism of the OH-stretching frequency in kyanite
Summary Inclusion-free kyanites from Switzerland show in the near IR-absorption spectrum a sharp absorption band with a double maximum at 3378 cm–1 and 3268 cm–1 which belongs to the OH-stretching frequency. Crystal-plates parallel to (100) show a strong pleochroism for the double masimum, plates parallel to (010) only a weak pleochroism. This pleochroism can be explained by assuming two crystallographically different kinds of OH-groups; their probable orientation could be derived.

Mit 3 Abbildungen  相似文献   

15.
In the Montes de Toledo area, located in the axial part of the Central Hercynian zone, a long-term thermo-tectonic evolution can be deduced from apatite fission-track (AFT) data in conjunction with tight geological constraints derived from the knowledge of regional geology and other independent chronometers. The area is composed of two different blocks separated by the Toledo Shear Zone (TSZ). The northern block is a granulite facies anatectic terrane. The southern block is composed of greenschist facies Paleozoic sediments intruded by a late Hercynian granitic pluton. A total of 13 samples have been recovered for AFT analysis. AFT ages in both blocks cluster around 189–221 Ma, with mean confined track lengths between 11.4 m and 12.4 m. Modeling of the AFT data indicates that the thermal history is broadly similar in both blocks, which constrains the main movement of the TSZ, as essentially before the Upper Permian. AFT ages in the TSZ cluster around 124–164 Ma, and the track lengths vary between 11.4 m and 12.4 m. These data reveal that the fault must have been affected by a later thermal overprint as AFT ages are significantly younger than those of the footwall and hangingwall blocks. This differential thermal resetting is likely related to the advection of localized hydrothermal fluids that are responsible for the widespread Pb–Zn mineralization along the TSZ. These results give an example of resetting AFT data by hydrothermal events. The long-term evolution suggests a lack of important Alpine tectonism in the Montes de Toledo block, in clear contrast to other nearby Hercynian areas such as the Sierra de Guadarrama, where the important effect of Alpine tectonism has almost totally erased the previous thermal signal in the AFT system.  相似文献   

16.
Zusammenfassung Der primare klastische Anteil des mittleren Muschelkalks besitzt ein Maximum in den Korngrößen von 6–20, Ø , das über weite Strecken konstant bleibt. Der Mineralgehalt besteht aus Quarz, Feldspat, Glimmer und vielleieht Kaolinit.Bei der Diagenese warden Quarz und Feldspat teils korrodiert, teils wurden Quarz und Albit neu gebildet. In Randgebieten entstand Glaukonit vermutlich aus Glimmern.Durch Grundwassereinwirkung bildete rich ein zweites Maximum zwischen 0–2 Ø aus. Dabei ist in diesen Korngrößen eine Zunahme an Illit und Kaolinit und das Neuauftreten von Montmorillonit zu verzeichnen.Bei der Verwitterung verschwand das Maximum zwischen 6–20 Ø zugunsten eines Maximums zwischen 0–2 Ø . Damit verschwand auch der primäre Mineralgehalt fast völlig. Die Fraktionen unter 2 Ø setzen sich aus einem illitähnlichen Mineral zusammen.Durch Grundwassertätigkeit und Oberflächenverwitterung wurde also nicht nur der lösliche Anteil des mm ausgelaugt, sondern es sind auch deutliche Veränderungen des klastischen Anteils wahrzunehmen.Herrn Professor Dr.Carl W. Correns zum 60. Geburtstag gewidmet.  相似文献   

17.
The chemical and microbiological characteristics of groundwater from two provinces of central Spain were studied. In some zones of this area, the concentrations of As in groundwater exceed the guideline concentrations, set internationally between 10 g/l and 50 g/l, reaching levels over 100 g/l. A narrow correlation between the contents of arsenic and HCO3– was observed. These data suggest a possible mechanism of the As mobilization from aquifer sediments to groundwater: the bicarbonate ions could displace HAsO42– adsorbed on aquifer oxyhydroxides. Sediments containing relatively high contents of adsorbed arsenic are deposited in surface water environments with low carbonate concentrations. Subsequently, the sediments become exposed to groundwater with highly dissolved carbonate content, and arsenic can be mobilized by displacement from mineral surfaces. In addition, the presence of Pseudomonas genera bacteria, which secrete siderophores (Fe chelating agents) could mobilize As adsorbed on Fe oxides through their dissolution. These combined microbiological and chemical processes might have increased the natural mobility of As.  相似文献   

18.
White mica bearing fractions ranging in grain size from 0.4 m to 6.3–20 m were separated from metapelites and intercalated metatuffs of the eastern Rheinisches Schiefergebirge (FRG). The stratigraphic age of these rocks is Middle Devonian (Eifelian), and they contain detrital material of northwestern provenance (Old Red Continent, probably mainly derived from the Caledonian Orogen). Folding in the Carboniferous was associated with cleavage formation and an apparently synkinematic anchizonal metamorphism. Apparent K-Ar ages of metapelite fractions display a marked positive correlation with grain size illustrating the detrital influence which is diminished with decreasing grain size and increasing metamorphism (determined by illite crystallinity). Contrasting grain morphologies observed by SEM enable the interpretation of apparent age/ grain size relationship for coarse fractions. The anticipated lack of detrital mica in metatuffs is confirmed by the fairly consistent apparent K-Ar ages determined for the coarser than 0.63 m size fractions which date the anchizonal metamorphism at ca. 330 Ma. Comparison of metatuff and metapelite apparent ages suggests that the extent of rejuvenation in the latter was largely dependent on grain size. Rejuvenation was also somewhat controlled by the degree of anchizonal metamorphism as suggested by differences in K-Ar results of metapelites which were metamorphosed at variable anchizonal conditions. Fractions <0.63 m from upper anchizonal metapelites record ca. 330 Ma ages similar to those of the 0.63–20 m sizes in metatuffs. Together those results confirm the limited applicability of conventional K-Ar dating on bulk clay fractions (<2 m) of very-low grade (anchizonal) metamorphic rocks in dating metamorphic events and concomitant cleavage formation.  相似文献   

19.
Heavy metals distribution in core sediments, different size fractions of bed sediments (>212 urn, 90-212 jam, 63–90 urn, 53–63 urn, < 53 urn), and suspended sediments (>30 urn, 20–30 m, 10–20 urn, 2–10 urn, <2 m) have been discussed. Pb, Zn, and Cr have been accumulating in recent years in the sediments. Si, Al, Fe, Ca, and Mg dominate the bed and suspended sediment composition. Metals show increasing concentrations in finer sediments. Applying multivariate analysis to sediment composition, metals have been grouped into different factors depending upon their source of origin. Chemical fractionation studies on suspended and bed sediments show Fe, Zn, Cu, and Pb are associated with the residual fraction and Mn with the exchangeable fraction.  相似文献   

20.
This paper deals with barite from stratiform, karst, and vein deposits hosted within Lower Paleozoic rocks of the Iglesiente-Sulcis mining district in southwestern Sardinia. For comparison sulfates from mine waters are studied. Stratiform barite displays 34S=28.8–32.1, 18O=12.7–15.6, and 87Sr/86Sr=0.7087, in keeping with an essentially Cambrian marine origin of both sulfate and strontium. Epigenetic barite from post-Hercynian karst and vein deposits is indistinguishable for both sulfur and oxygen isotopes with 34S=15.3–26.4 and 18O=6.6–12.5; 87Sr/86Sr ratios vary 0.7094–0.7140. These results and the microthermometric and salinity data from fluid inclusions concur in suggesting that barite formed at the site of mineralization by oxidation of reduced sulfur from Cambrian-Ordovician sulfide ores in warm, sometimes hot solutions consisting of dilute water and saline brine with different 18O values. The relative proportion of the two types of water may have largely varied within a given deposit during the mineralization. In the karst barite Sr was essentially provided by carbonate host rocks, whereas both carbonate and Lower Paleozoic shale host rocks should have been important sources for Sr of the vein barite. Finally, 34S data of dissolved sulfate provide further support for the mixed seawater-meteoric water composition of mine waters from the Iglesiente area.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号