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羌塘高原典型矿区水系沉积物地球化学特征与区域化探扫面方法 总被引：3，自引：0，他引：3
羌塘高原是目前区域化探全国扫面工作最大的空白区和地质找矿工作的新区,这里的化探扫面和地质找矿工作正在推进中。水系沉积物测量是该区主要区域化探扫面方法。在羌塘高原上,风成沙广布,其粒级主要集中在–40目,比例高达90%以上,是影响区域化探找矿效果的最大因素。通过四个矿区水系沉积物地球化学特征研究发现:1)水系沉积物不同粒级中,大部分矿化指示元素含量都呈不对称的"反S"型或"U"型分布,富集在+40目粒级和–160目粒级中。以–10~+40目为采样粒级,很大程度上可以消除风成沙的干扰。2)大型矿床形成的指示元素异常沿水系迁移距离为4~8 km,异常面积25 km2;小型矿床形成的异常迁移距离1 km左右,异常面积1 km2左右。3)确定区域化探扫面最佳技术指标为:采样粒级–10~+40目;采样密度1点/4 km2(勘查目标定位到大型以上矿床时)或1点/km2(勘查目标定位到小型以上矿床时)。 相似文献
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森林沼泽景观区区域化探异常追踪方法技术 总被引：3，自引：2，他引：1
在森林沼泽景观区中低山亚景观条件下,通过4个研究区的试点工作认为：①以找寻小型以上规模矿床为目的的区域化探异常查证工作方法,以水系沉积物加密测量为佳,采样粒级-10～＋60目,采样密度3—4点／km^2。②采用B层残坡积土壤测量可以达到同样的目的;采样粒级-20目,采样密度4点／km^2左右;采样布局为沿山脚和山脊的不规则测网。③在倒石堆发育区,可以采用采样密度6—7点／km^2渗湿土测量方法进行异常追踪。④泥炭测量难以获得比较全面和客观的测区找矿前景信息,在区域化探异常追踪阶段最好不要选用。 相似文献
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在广东北市地区选择310 km2试验区开展1∶5万水系沉积物测量粒级试验。在同一采样点位分别采集-10~+80目和-60目两种粒级的样品,进行多元素含量测试,从水系沉积物粒级分布特征、元素含量分布特征、富集倾向性和地球化学特征4方面对上述两种粒级试验效果进行综合评价。结果表明:(1)水系沉积物中-10~+80目粒级段样品占全部样品的86.59%,质量上占有绝对优势;(2)除W、Sn、Pb外,试验区多数元素在两种粒级总体上具有相似的含量分布特征,且在高背景区或矿(化)区均不同程度富集于-10~+80目粗粒级,在低背景区或非矿(化)区则正好相反;(3)包括Au、Ag、Zn、Mo、Sb在内,多数元素-10~+80目粗粒级显示的区域地球化学分布与区域地质吻合度更高,地球化学分布界线与地质界线更为接近;(4)多数元素-10~+80目粗粒级显示的地球化学高背景-正异常区的规模和强度整体上大于-60目细粒级,Mo、Sb等尤为明显。因此,广东北市地区1∶5万水系沉积物的最佳采样粒级为-10~+80目。 相似文献
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1:20万区域化探方法核心技术"取样粒级"的讨论 总被引：2，自引：0，他引：2
内蒙古区域化探扫面采用水系沉积物测量(或土壤测量),取粗粒级样品,取得了较好的地质找矿效果,但局部景观区找矿效果受到了一些影响.我国南北方水系沉积物中元素含量呈"U"形分布,反映了南北方不同的风化类型,以及所取不同粒级样品的物质成分也不同;取粗粒级和细粒级样品均可能有化探异常显示,采用-5～+20目(0.9 mm≤A＜4 mm)和-120目(A＜-0.125 mm)组合粒级作为采样粒级.为提高工效,取样时可以采用-5目(或-20目)全粒级物质,也能获取更多的找矿信息.这种取样粒级技术,也适宜于全国各种不同的景观区的不同尺度的水系沉积物测量和土壤测量的化探工作. 相似文献
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大兴安岭北部富克山地区勘查地球化学工作方法探索 总被引：1，自引：0，他引：1
大兴安岭北部为典型的森林沼泽景观区,勘查地球化学找矿方法在该区找矿工作中起到了重要作用,这一特定的景观内大区自然环境相同,而局部地质、地貌条件、植被发育程度、风化程度等各有差异,必将影响工作方法的选择及其应用效果.通过富克山地区1/5万水系沉积物测量及后期查证的工作,以生产与试验相结合,对水系沉积物测量及后期土壤地球化学测量工作方法进行了探索研究,取得了较好的应用效果.认为富克山地区应属中低山森林沼泽亚景观区,水系沉积物测量采样介质可以采用细砂、粉砂、岩屑,野外样品初加工方法为水筛,野外样品初加工粒级为-10~+60目.二级查证1/万土壤地球化学（剖面）测量,采样层位为B层,介质以褐黄色、土黄色土壤为主,初加工粒级为-40目,初加工方法为干燥后过筛. 相似文献
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通过研究皖东南地区1∶25万水系沉积物测量成果,系统总结了该地区元素地球化学背景特征。利用新采样方法技术开展的1∶25万区域化探数据更新成果与以往1∶20万化探资料进行对比研究,认为采用1∶25万截取粒级(-10~+80目)获取的区域化探数据更能客观、准确地反映研究区成矿地质背景的地球化学特征。依据异常分布规律和区域成矿地质背景划分出6个找矿远景区,并对各区找矿前景进行了分析,为皖东南地区下一步矿产资源勘查选区提供重要的地球化学依据。 相似文献
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高频红外碳硫仪测定重晶石和黄铁矿中的硫 总被引：2，自引：2，他引：0
硫酸盐矿石和硫化物矿石大部分是低电磁性的物质,利用高频红外碳硫仪测定这类矿石中的硫时,在燃烧过程中难以产生较大的电磁感应涡流,导致矿石中的硫释放不完全,造成硫的测定结果偏低。本文采用二氧化硅将重晶石精矿和黄铁矿精矿稀释成不同硫含量的重晶石和黄铁矿样品,通过优化称样量及助熔剂等测试条件,建立了使用高频红外碳硫仪测定重晶石和黄铁矿中硫含量的分析方法。结果表明:当样品中的硫含量高于2%时确定称样量为0.07 g,当硫含量低于2%时确定称样量为0.1 g,加入助熔剂0.4 g锡粒+0.4 g铁粒+1.5 g钨粒,可使重晶石和黄铁矿中的硫完全释放进入仪器红外吸收区域,硫的回收率提高至95.8%~104.2%(重晶石)和95.3%~105.1%(黄铁矿),分别高于常规红外碳硫仪的回收率(83.39%~91.1%和91.5~97.5%)。本方法精密度高(RSD5%),实现了硫含量的准确测定。 相似文献
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《International Geology Review》2012,54(6):565-576
In the Eastern Pontide Region of northeastern Turkey, volcanogenic Cu-Zn-Pb deposits of the Kuroko type are widespread within the dacitic series of the Liassic-Eocene volcano-sedimentary succession. Sulfide mineralization within the studied deposits shows four different depositional styles: disseminated ore; polymetallic stockwork ores; polymetallic massive ores; and disseminated pyrite in the hanging-wall tuff units. Only the stockwork and massive ores are economically important, and usually one or the other dominates in each ore body. The δ34S of sulfide minerals belonging to the various styles of mineralization are in the range from ?2.6 to +5.2% (VCDT): pyrite has the highest values and the galena lowest values in agreement with the usual isotopic-fractionation trends. Massive ores have heavier sulfur-isotope composition among the mineralization styles and the heaviest values are recorded in barite- and gypsum-rich deposits. The close similarity of the δ34S among the various mineralization episodes in some deposits indicates a single sulfur source having a stable and homogenous composition. The δ34S of sulfates fall into three groups: barites and primary gypsum (15.4 to 20.4%), close to coeval seawater sulfate; one value of barite (25.4%) heavier than coeval sea water; and values of secondary gypsum (2.2 to 8.0%) either very light compared to coeval seawater sulfate, or within the range recorded from sulfide minerals. The δ34S values of pyrite disseminated in the brecciated dacite tuff units are very close to zero and similar to the ones reported for magmatic rocks, suggesting a magmatic source for the sulfur of the earliest sulfide mineralization episode. These δ34S data are not sufficient to calculate the fraction of the reduced sulfur derived from seawater sulfate, as the associated fractionation factor cannot be constrained. 相似文献
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大河边重晶石矿床是一个世界级的超大型重晶石矿床。最近在该区重晶石矿床下部的震旦系陡山沱组碳酸盐岩(白云岩)和碎屑岩中,新发现一套规模较大、层位产出稳定的铅锌矿化。铅锌矿体和重晶石矿床具有"上部为重晶矿,下部为铅锌硫化物矿床"的矿化特征。铅锌矿段矿石矿物主要为闪锌矿、黄铁矿及方铅矿,含少量白铁矿、黄铜矿及磁黄铁矿;脉石矿物主要为石英和重晶石,少量白云石、热液磷灰石、炭沥青及钡冰长石。成矿流体特征类似于形成沉积喷流型铅锌矿床的流体特征。铅锌矿化中的硫源自局限海盆内早寒武世海水经硫酸盐还原作用提供。此种类似于喷流沉积型铅锌矿床在南华裂谷盆地一带矿化层位稳定、分布范围较广泛,体现早寒武世时在裂谷盆地内存在一次大规模的热液事件。天柱大河边铅锌矿床的发现具有重要的资源意义及区内该种矿床的勘查意义。 相似文献
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红外碳硫仪测定矿石中高含量硫的探讨 总被引：4，自引：3，他引：1
探讨了用红外碳硫测定仪测定矿石中高含量硫需注意的一些影响因素,包括标样的选择、减少天平误差、称样量、样品的充分燃烧以及仪器的稳定性,说明了用红外碳硫仪测定矿石中高含量硫的可行性。 相似文献
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The stable enrichment of pyrite from magnesite ores in δ34S isotope (from 5.4 to 6.9‰) compared with pyrite from the host (sedimentary and igneous) rocks was established in the classical Satka sparry magnesite ore field. Concretionary segregations of fine-grained pyrite in dolomite are depleted in the heavy sulfur isotope (δ34S, from–9.1 to–5.8‰). Pyrite from dolerite is characterized by δ34S values (–1.1 and 1.7‰) close to the meteorite sulfur. The δ34S values in barite from the underlying dolomite horizon vary in the range of 32.3–41.4‰. The high degree of homogeneity of the sulfur isotope composition in pyrite from magnesite is a result of thermochemical sulfate reduction during the syngenetic crystallization of pyrite and magnesite from epigenetic brines, formed during dissolution of evaporite sulfate minerals at the stage of early catagenesis of the Riphean deposits.
相似文献16.
硫同位素研究在喀拉通克岩体的地壳物质混染过程中有重要意义。通过对块状和浸染状矿石、斑点状和脉状矿石以及围岩中硫化物进行硫同位素测试,分析了黄铜矿、黄铁矿、磁黄铁矿的硫同位素在硫化物中的富集状态,探讨了喀拉通克铜镍矿床硫同位素组成特征及其地质意义。结果表明：块状矿石的同位素测定值与标准值之间的千分偏差δ（34S）为（-1.30～1.84）×10-3,浸染状矿石的δ（34S）为（-2.50～0.85）×10-3,脉状矿石的δ（34S）为（-1.54～3.00）×10-3,围岩中黄铁矿的δ（34S）为（-7.8～-3.3）×10-3;硫同位素在硫化物中的富集从大到小依次为黄铁矿、磁黄铁矿、黄铜矿,说明硫化物之间基本达到了硫同位素平衡;喀拉通克铜镍矿床的硫主要来自于地幔,只在岩浆熔离作用形成的浸染状矿石和岩浆后期热液阶段形成的脉状矿石以及晚期黄铁矿中有少量或局部地壳硫混染的痕迹;地壳硫的加入没有在岩浆源区发生,可能发生在岩浆上升并发生硫化物就地熔离的局部过程中,几乎不对硫饱和及硫化物的熔离产生影响;岩浆在地壳深部发生的橄榄石、铬铁矿等矿物的分离结晶作用,有可能是促使硫饱和与硫化物熔离的主要因素。 相似文献
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Zahra Badrzadeh Timothy J. Barrett Jan M. Peter Domingo Gimeno Mossaieb Sabzehei Mehraj Aghazadeh 《Mineralium Deposita》2011,46(8):905-923
The Sargaz Cu–Zn massive sulfide deposit is situated in the southeastern part of Kerman Province, in the southern Sanandaj–Sirjan Zone of Iran. The stratigraphic footwall of the Sargaz deposit is Upper Triassic to Lower Jurassic (?) pillowed basalt, whereas the stratigraphic hanging wall is andesite. Mafic volcanic rocks are overlain by andesitic volcaniclastics and volcanic breccias and locally by heterogeneous debris flows. Rhyodacitic flows and volcaniclastics overlie the sequence of basaltic and andesitic rocks. Based on the bimodal nature of volcanism, the regional geologic setting and petrochemistry of the volcanic rocks, we suggest massive sulfide mineralization in the Sargaz formed in a nascent ensialic back-arc basin. The current reserves (after ancient mining) of the Sargaz deposit are 3 Mt at 1.34% Cu, 0.38% Zn, 0.08%Pb, 0.24 g/t Au, and 7 g/t Ag. The structurally dismembered massive sulfide lens is zoned from a pyrite-rich base, to a pyrite?±?chalcopyrite-rich central part, and a sphalerite–chalcopyrite-rich upper part, with a sphalerite-rich zone lateral to the upper part. The main sulfide mineral is pyrite, with lesser chalcopyrite and sphalerite. The feeder zone, comprised of a vein stockwork consists of quartz–sulfide–sericite pesudobreccia and, in the deepest part, chlorite–quartz–pyrite pesudobreccia. Footwall hydrothermal alteration extends at least 70–80 m below the massive sulfide lens and more than a hundred meters along strike from the massive sulfide lens. Jasper and Fe–Mn bearing chert horizons lateral to the sulfide deposit represent low-temperature hydrothermal precipitates of the evolving hydrothermal system. Based on mineral textures and paragenetic relationships, the growth history of the Sargaz deposit is complex and includes: (1) early precipitation of sulfides (protore) on the seafloor as precipitation of fine-grained anhedral pyrite, sphalerite, quartz, and barite; (2) anhydrite precipitation in open spaces and mineral interstices within the sulfide mound followed by its subsequent dissolution, formation of breccia textures, and mound clasts and precipitation of coarse-grained pyrite, sphalerite, tetrahedrite–tennantite, galena and barite; (3) replacement of pre-existing sulfides by chalcopyrite precipitated at higher temperatures (zone refining); (4) continued “refining” led to the dissolution of stage 3 chalcopyrite and formation of a base-metal-depleted pyrite body in the lowermost part of the massive sulfide lens; (5) carbonate veins were emplaced into the sulfide lens, replacing stage 2 barite. The δ34S composition of the sulfides ranges from +2.8‰ to +8.5‰ (average, +5.6‰) with a general increase of δ34S ratios with depth within the massive sulfide lens and underlying stockwork zone. The heavier values indicate that some of the sulfur was derived from seawater sulfate that was ultimately thermochemically reduced in deep hydrothermal reaction zones. 相似文献
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海洋天然气水合物系统硫同位素研究进展 总被引：2，自引：2，他引：0
在海洋天然气水合物的地质系统中,甲烷的渗漏作用形成了独特的地球化学微环境。渗漏的甲烷在硫酸根-甲烷氧化还原界面与硫酸根之间发生厌氧氧化反应,同时硫酸盐发生还原反应,形成具有特殊同位素组成的自生碳酸盐、硫化物（AVS、黄铁矿等）和硫酸盐（重晶石、石膏）等。反应过程中硫酸盐还原菌的作用使得产物中硫的同位素发生了强烈分馏,具体表现为低δ34S值的硫化物矿物和高δ34S值的硫酸盐矿物的形成。沉积物中这种独特的硫同位素特征与海洋天然气水合物系统中独特地球化学微环境有关,是硫酸盐还原反应过程中细菌控制的硫酸盐分馏和厌氧细菌对硫的歧化反应（disproportionation）的共同作用结果。 相似文献
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电感耦合等离子体发射光谱法测定含重晶石的银铅矿中的铅 总被引：5，自引：5，他引：0
测定银铅矿中的铅,常规分解方法是采用酸溶法（王水和四酸）处理样品。当银铅矿中重晶石含量为40%~80%时,酸溶法不能完全分解样品,造成铅的测定结果偏低;且样品中大量硫酸钡的存在易与铅生成铅钡复盐沉淀而影响铅的准确测定。本文采用过氧化钠碱熔法分解样品,在试液中加入氯化钡,应用电感耦合等离子体发射光谱法测定重晶石含量高的银铅矿中铅的含量,通过优化取样量与稀释倍数等参数,配合高盐雾化器的使用有效避免了基体干扰。方法检出限为0.013%,相对标准偏差（RSD）为1.1%~1.6%,回收率为97.9%~102.9%,标准样品的测定结果可靠。本法采用过氧化钠碱熔,可完全彻底地分解样品;氯化钡的加入使重晶石含量高的银铅矿样品中硫酸钡对铅的干扰被消除,而对不含重晶石的铅矿样品中铅的测定无影响。本法解决了银铅矿与高含量重晶石共生时样品难分解的问题,同时解决了硫酸钡干扰测定铅的问题。 相似文献
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Alexandre Raphael Cabral Nikola Koglin Harald Strauss Helene Brätz Rogerio Kwitko-Ribeiro 《Mineralium Deposita》2013,48(7):805-816
The distribution of mineral deposits, characterised as barite deposits, hematite-rich auriferous deposits and auriferous tourmaline–sulfide deposits, displays a regional sulfate–hematite–sulfide zoning along the thrust-delineated limbs of the Mariana anticline, in the south-eastern part of the Quadrilátero Ferrífero of Minas Gerais, Brazil. Cross-cut relationships of barite veins and sulfide lodes indicate that sulfidation occurred in a late-tectonic context, which is here attributed to the collapse of the ～0.6-Ga Brasiliano thrust front. Reconnaissance S-isotopic data from barite and pyrite (Antônio Pereira barite deposit and its adjacent gold deposit, respectively), and arsenopyrite (Passagem de Mariana gold deposit), suggest a new interpretation for the hydrothermal fluid overprint in the Mariana anticline. The Antônio Pereira barite has Δ33S values that are near zero, constraining the sulfate source to rocks younger than 2.45 Ga. The barite-δ34S values are between +19.6 and +20.8?‰. The Passagem arsenopyrite and tourmaline have Co/Ni ratios that define a positive linear trend with the Antônio Pereira pyrite. The latter has homogenous δ34S values, between +8.8 and +8.9?‰, which are compatible with thermochemical reduction of aqueous sulfate with the S-isotopic composition of the Antônio Pereira barite. 相似文献