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1.
In terms of environmental mineralogy, the environmental properties of metallic minerals, including chemical activation, adsorption, pore effect and nanometer effect, have been analyzed. On the basis of the analysis of environmental properties of metallic minerals, the applications of iron-bearing sultides, iron and manganese oxides in the purification of wastewaters containing heavy metal ions （Cr^6＋ ,Hg^2＋ , Pb^2＋ , etc. ） have been summarized. Moreover, research on the application of metallic minerals in environmental protection has been anticipated. It should be a piece of dominating work for environmental mineralogie researchers in the future to lucubrate systematically the physical and chemical characteristics of the metallic mineral surfaces, further reveal the reciprocity process between metallic minerals and water surface, perfect the theory and model of the metallic minerals to remove contaminants, intensify study on the facilities and techniques of metallic minerals to remove contaminants, and entail well the extension and propagation of achievements. 相似文献
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《地学前缘(英文版)》2022,13(2):101316
Mössbauer spectroscopy has been used widely to characterize the ferric (Fe3+) and ferrous (Fe2+) proportions and coordination of solid materials. To obtain these accurately, the recoilless fraction is indispensible. The recoilless fractions (f) of iron-bearing minerals, including oxides, oxyhydroxides, silicates, carbonates, phosphates and dichalcogenides, and silicate glasses were evaluated from the temperature dependence of their center shifts or absorption area with the Debye model approximation. Generally, the resolved Debye temperature (θD) of ferric iron in minerals, except dichalcogenides, through their center shifts ranging from 400 to 550 K, is significantly larger than ferrous iron ranging from 300 to 400 K, which is consistent with the conclusion from previous work. The resolved f (Fe3+)RT with the center shift model (CSM) ranges from 0.825 to 0.925, which is larger than that obtained for f(Fe2+)RT, which ranges from 0.675 to 0.750. Meanwhile, the θD and f resolved from temperature-dependence of absorption are generally lower than from center shifts, especially for ferric iron. The significant difference between f(Fe3+) and f(Fe2+) indicates the necessity of recoilless fraction correction on the Fe3+/(Fe3++Fe2+) resolved from Mössbauer spectra. 相似文献
4.
《Applied Geochemistry》2001,16(1):85-93
An experimental study has been undertaken concerning the adsorption of radioelements on mixtures of minerals. The question is whether the adsorption of trace elements by rocks and soils can be easily predicted from the properties of the constituent minerals. The goal of these experiments was the comparison between the measurements of distribution coefficients of some radioelements for pure minerals and for binary mixtures according to the Doehlert’s uniform shell designs and to test an additive law of combination of Kd. The results showed that when one of the constituents acts as a dilutant in the mixture, i.e. it presents a very low adsorption capacity with respect to some trace element, then the relations of additivity of Kd are fulfilled. Otherwise, these relations are not satisfied and this is probably caused, in the present cases, by interactions from solubilized species. 相似文献
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The fluorine (F) and chlorine (Cl) contents of arc magmas have been used to track the composition of subducted components, and the F and Cl contents of MORB have been used to estimate the halogen content of depleted MORB mantle (DMM). Yet, the F and Cl budget of the Earth’s upper mantle and their distribution in peridotite minerals remain to be constrained. Here, we developed a method to measure low concentrations of halogens (≥0.4 µg/g F and ≥0.3 µg/g Cl) in minerals by secondary ion mass spectroscopy. We present a comprehensive study of F and Cl in co-existing natural olivine, orthopyroxene, clinopyroxene, and amphibole in seventeen samples from different tectonic settings. We support the hypothesis that F in olivine is controlled by melt polymerization, and that F in pyroxene is controlled by their Na and Al contents, with some effect of melt polymerization. We infer that Cl compatibility ranks as follows: amphibole > clinopyroxene > olivine ~ orthopyroxene, while F compatibility ranks as follows: amphibole > clinopyroxene > orthopyroxene ≥ olivine, depending on the tectonic context. In addition, we show that F, Cl, Be and B are correlated in pyroxenes and amphibole. F and Cl variations suggest that interaction with slab melts and fluids can significantly alter the halogen content of mantle minerals. In particular, F in oceanic peridotites is mostly hosted in pyroxenes, and proportionally increases in olivine in subduction-related peridotites. The mantle wedge is likely enriched in F compared to un-metasomatized mantle, while Cl is always low (<1 µg/g) in all tectonic settings studied here. The bulk anhydrous peridotite mantle contains 1.4–31 µg/g F and 0.14–0.38 µg/g Cl. The bulk F content of oceanic-like peridotites (2.1–9.4 µg/g) is lower than DMM estimates, consistent with F-rich eclogite in the source of MORB. Furthermore, the bulk Cl budget of all anhydrous peridotites studied here is lower than previous DMM estimates. Our results indicate that nearly all MORB may be somewhat contaminated by seawater-rich material and that the Cl content of DMM could be overestimated. With this study, we demonstrate that the halogen contents of natural peridotite minerals are a unique tool to understand the cycling of halogens, from ridge settings to subduction zones. 相似文献
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《地学前缘(英文版)》2022,13(2):101337
Geo-electric anomalies are generated during the process of stress accumulation and release associated with earthquakes. However, the mechanism of these anomalies remains equivocal. Based on the analysis of thermoelectric characteristics of semiconductor minerals of the earth’s deep crust such as graphite, ferrosilicon alloy, magnetite etc., we perform finite element analysis to evaluate the principles governing the thermoelectric power generated by minerals and rocks. The results show that graphite, ferrosilicon alloy and magnetite all exhibit Seebeck effect and can be superimposed. And the thermo-electric field can be enhanced with the activation temperature increases, the content of thermoelectric minerals increases, the size of aggregates increases, and the spacing of thermoelectric minerals grains decreases. Seismogenic processes would generate a similar thermal gradient. The natural semiconductor minerals in this thermal field show a thermoelectric effect, forming a thermoelectric field that interferes with the background electric field. This study indicates that thermoelectric effect may have an important influence on the formation of geoelectric field. 相似文献
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Adsorption of dissolved copper and phosphate by natural and peroxide-treated marine sediments was compared. A three-fold increase in copper adsorption and a six-fold increase in phosphate adsorption was caused by the peroxide treatment. Indigenous organic matter evidently interferes with adsorption.Clay minerals coated with heptadecanoic acid adsorbed somewhat less copper, phosphate, and hexadecane than uncoated clays, but slightly more nonadecanoic acid and anthracene. 相似文献
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《International Geology Review》2012,54(8)
Two new varieties of sulfate minerals, zincobotryogen and zincocopiapite, belonging to the botryogen group and the copiapite group, respectively, were found in the oxidation zone of a lead-zinc deposit, situated on the northern border of the extremely arid Tsadam basin. – Authors. 相似文献
9.
《中国地球化学学报》2006,(Z1)
Background:The combustion of bituminous coal resulted in the high incidence of lung cancer of peasants in Xuanwei and Fuyuan counties of Yunnan Province because of particulate matter (PM) absorbing a great deal of heavy metal elements and organic matter s… 相似文献
10.
The study of re-homogenized melt inclusions in the same growth planes of quartz of pegmatites genetically linked to the Variscan
granite of the Ehrenfriedersdorf complex, Erzgebirge, Germany, by ion microprobe analyses has determined high concentrations
of Be, up to 10,000 ppm, in one type of melt inclusion, as well as moderate concentrations in the 100 ppm range in a second
type of melt inclusion. Generally, the high Be concentrations are associated with the H2O- and other volatile-rich type-B melt inclusions, and the lower Be concentration levels are connected to H2O-poor type-A melt inclusions. Both inclusion types, representing conjugate melt pairs, are formed by a liquid–liquid immiscibility
separation process. This extremely strong and very systematic scattering in Be provides insights into the origin of Be concentration
and transport mechanisms in pegmatite-forming melts. In this contribution, we present more than 250 new analytical data and
show with ion microprobe and fs-LA-ICPMS studies on quenched glasses, as well as with confocal Raman spectroscopy of daughter
minerals in unheated melt inclusions, that the concentrations of Be may achieve such extreme levels during melt–melt immiscibility
of H2O-, B-, F-, P-, ± Li-enriched pegmatite-forming magmas. Starting from host granite with about 10 ppm Be, melt inclusions with
10,000 ppm Be correspond to enrichment by a factor of over 1,000. This strong enrichment of Be is the result of processes
of fractional crystallization and further enrichment in melt patches of pegmatite bodies due to melt–melt immiscibility at
fluid saturation. We also draw additional conclusions regarding the speciation of Be in pegmatite-forming melt systems from
investigation of the Be-bearing daughter mineral phases in the most H2O-rich melt inclusions. In the case of evolved volatile and H2O-rich pegmatite systems, B, P, and carbonates are important for the enrichment and formation of stable Be complexes. 相似文献
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Bin LIAN Bin WANG Congqiang LIU 《中国地球化学学报》2006,25(B08):175-175
Potassium fertilizer is in short supply in China. However, there is a considerable resource of insoluble potassium resources in the soil mineral or potassium-baring low-degrade rocks. Most of these kinds of potassium exist in aluminous silicate minerals from which potassium cannot be absorbed directly by plants. So it is very important to study how to release potassium from soil minerals or rocks by using biological action. Recently, a large number of researches on degradation of potassic mineral by bacterial but few by fungi have been reported. In order to study the degradation of potassic mineral by fungi, we isolated a strain of thermophilic fungi TH003, which can use potassic rock as nutrient source. The strain was identified as Aspergillus fumigatus based on its morphological characters and molecular biology. In this paper, the direct and indirect processes of mineral powder degradation with the strain of TH003 were studied： mineral powder was added in medium directly for cultivation so as to investigate the direct process. For the purpose of studying indirect process, mineral powder was wrapped up in a parcel using membrane with pore size of 0.22 μm, and then the parcels were added in the medium. The interaction between mineral granules and mycelia was observed by using TEM and AFM at different stages during the whole experimental procedure. The results showed that the effect of direct process is stronger than that of indirect process. For instance, the content of K^＋ is higher in both culture media and mycelia. Direct process includes mechanical demolishment, adsorption, parceling, phagocytosis, erosion and comprehensive effect, while indirect process only refers to erosion on the surface of mineral granules by metabolic products of mycelia. The technology of fermentation engineering was employed to study the biological effects of the strain of Aspergillus fumigatus TH003 on the minerals bating low-grade potassium. Nutrition factors and culture conditions that affect the process of mineral powder degrading with the strain of TH003 were studied in this paper. The results showed that glucose and corn steep are the optimal carbon and nitrogen resources in the strain culture medium, and that pH values range from 3.0 to 9.0. 相似文献
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In the Noril’sk ore field, parkerite is a characteristic mineral of sulfide ore that metamorphosed under conditions of zeolite and prehnite-pumpellyite facies and of arsenide-calcite veins. The mineral occurs in ores containing bornite, anhydrite, magnetite, mackinawite (3–5 wt % Ni), valleriite, calcite, ankerite, native silver, native bismuth, violarite, Te-rich bismutohauchecornite, cupropentlandite enriched in Fe, Pd-rich breithauptite (1.5–2.5 wt % Pd), galena enriched in Cu (3.8 wt % Cu), and Ni arsenides and antimonides. Parkerite occurs in those place, where the primary ores have contained pockets and veins of graphic galena and chalcopyrite aggregates with associated Pt-Pd-Au-Ag minerals. Parkerite metacrysts in galena and Fe-Cu-Ni sulfides contain 6–16 and up to 5 wt % Pb, respectively. Parkerite rims replacing PGM aggregates and galena contain 1–3 wt % Pb. In calcite veins hosted in metamorphosed sulfide ores, parkerite is associated with native silver and bismuth, maucherite, cobaltite, chalcocite, and uraninite. Parkerite from these veins contains up to 0.5 wt % Pb. Thus, the Pb and Bi contents in parkerite basically depend on those of replaced minerals. Rare bismutohauchecornite is associated with parkerite. 相似文献
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A. P. Khomyakov V. V. Korovushkin Yu. D. Perfiliev V. M. Cherepanov 《Physics and Chemistry of Minerals》2010,37(8):543-554
A representative collection of structurally characterized eudialyte-group minerals (EGM) with varying relative concentrations of Fe2+ and Fe3+ ions from several localities was investigated at room temperature by 57Fe Mössbauer spectroscopy coupled with magnetometric, optical, and X-ray powder diffraction methods. To refine the Mössbauer parameters of isomer shift and quadrupole splitting for Fe2+ and Fe3+ in different types of coordination polyhedra (planar quadrangle, square pyramid, and distorted octahedron) in EGM structures, we also collected Mössbauer parameters for gillespite and labuntsovite. The main purpose of this work is to determine the location of Fe3+ in different sites in typical eudialyte, rastsvetaevite, georgbarsanovite, and some of their naturally hydrated and heat-treated analogs, and investigate the kinetics and oxidation mechanisms of iron ions in their structures. Our study has confirmed the presence of Fe2+ ions in the planar quadrangle and square pyramid in primary eudialytes, as well as the presence of Fe3+ ions in the square pyramid and distorted octahedron in primary, naturally hydrated, and heat-treated eudialytes. According to this study, hydrated eudialytes are characterized by the location of Fe3+ ions mainly in octahedra with OH groups and/or water molecules at trans vertices, while heat-treated eudialytes are characterized by their location in square pyramids with an O2? anion at the apical vertex. 相似文献
14.
《中国地球化学学报》2006,(Z1)
Potassium fertilizer is in short supply in China. However, there is a considerable resource of insoluble potassium resources in the soil mineral or potassium-baring low-degrade rocks. Most of these kinds of potassium exist in aluminous silicate minerals f… 相似文献
15.
Models of geochemical controls on elements of concern (EOCs; e.g., As, Se, Mo, Ni) in U tailings are dominated by ferrihydrite. However, the evolution of aqueous concentrations of Al and Mg through the Key Lake (KL) U mill bulk neutralization process indicates that secondary Al and Mg minerals comprise a large portion of the tailings solids. X-ray diffraction, Al K-edge XAS, and TEM elemental mapping of solid samples collected from a pilot-scale continuous-flow synthetic raffinate neutralization system of the KL mill indicate the secondary Al–Mg minerals present include Mg–Al hydrotalcite, amorphous Al(OH)3, and an amorphous hydrobasaluminite-type phase. The ferrihydrite present contains Al and may be more accurately described as Al–Fe(OH)3. In the final combined tailings sample (pH 10.5) collected from the model experiments using raffinate with Al, Mg, and Fe, solid phase EOCs were associated with Al–Fe(OH)3 and Mg–Al hydrotalcite. In model experiments using raffinate devoid of Fe, aqueous EOC concentrations decreased greatly at pH 4.0 (i.e., where ferrihydrite would precipitate) and largely remained in the solid phase when increased to the terminal pH of 10.5; this suggests Al–Mg minerals can control aqueous concentrations of EOCs in the raffinate in the absence of Fe. Maximum adsorption capacities for individual and mixtures of adsorbates by Mg–Al hydrotalcite were determined. A revised model of the geochemical controls in U mill tailings is presented in which Al and Mg minerals co-exist with Fe minerals to control EOC concentrations. 相似文献
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Maoxu ZHU Haihua WANG Xin JIANG 《中国地球化学学报》2006,25(B08):94-95
Phosphate is one of the important nutrients for plant growth. In acidic and highly weathered soils, phosphate is ready to adsorb on Al and Fe oxides and transform into sparsely soluble Fe-P and Al-P solid phases, greatly reducing phosphate bioavailability. Aluminum and iron oxides in soils are important sinks for both phosphate and fluoride. In acidic soils, fluoride adsorption can dramatically facilitate dissolution of Al- and Fe-containing phases, which may influence the distribution and migration of both pollutants and nutrients including phosphate. To date, little information is available on mutual effects of fluoride and phosphate in fluoride-contaminated acidic soils. The objective of this study is to evaluate mutual effects of fluoride and phosphate on their adsorption/desorption in red soil, collected fi＇om Yingtan, Jiangxi Province, China, using a batch equilibrium method. The following results and conclusions were obtained. In heavily fluoride-contaminated soils, the adsorption of both fluoride and phosphate decreases with an increase in solution pH. Phosphate adsorption decreases progressively with increasing concentration of fluoride, suggesting that fluoride competes with phosphate for adsorption sites. 相似文献
18.
The character of solubility of 61 metamorphic and metasomatic minerals in an aqueous fluid was analyzed as a function of temperature, pressure, and fluid acidity by means of computer simulation of mineralfluid equilibria. Depending on the behavior of minerals in solutions of varying acidity, six main types of solubility diagrams were distinguished. The solubility of the majority of minerals is controlled mainly by fluid acidity rather than by P–T conditions. The analysis of model results provided insight into the mobility of chemical elements composing the minerals. The highest mobility in solutions of any acidity was established for Si, K, and Na. Ca and Mg are mobile in acidic solutions and inert in neutral and alkaline solutions. Fe(II) and Mn(II) are mobile in acidic and alkaline solutions but inert in neutral solutions. Fe(III) is mobile only in strongly acidic solutions and practically immobile in solutions of other compositions, which suggests that ferrous iron species must prevail in solutions. Al is mobile in alkaline and ultra-acidic solutions but inert in neutral and slightly acidic solutions. Correspondingly, a change in acidity must lead to the migration of some component into the solution and precipitation of other components. These conclusions are in agreement with the sequences of element mobility deduced from the experimental investigation of metasomatism. Most metamorphic fluids must be rich in silica and alkalis, which may result in the appearance of aggressive silica-alkali fluids responsible for regional metasomatism and granitization. In general, the solubility of Fe-, Mg-, Mn-, and Ca-bearing minerals in alkaline solutions is low compared with acidic solutions. Therefore, only acidic initial solutions could produce fluids enriched in these elements at the expense of leaching from metamorphic rocks during fluid migration. Fluids enriched mainly in Fe could initially be both acidic and alkaline. 相似文献
19.
《中国地球化学学报》2006,(Z1)
Phosphate is one of the important nutrients for plant growth. In acidic and highly weathered soils, phosphate is ready to adsorb on Al and Fe oxides and transform into sparsely soluble Fe-P and Al-P solid phases, greatly reducing phosphate bioavailability… 相似文献
20.
Abdel-Aal M. Abdel-Karim Waheed I. Elwan Hassan Helmy Shymaa A. El-Shafey 《Arabian Journal of Geosciences》2014,7(2):693-709
Spinels, Fe–Ti oxide minerals, apatites, and carbonates hosted in ophiolitic serpentinites and metagabbros of Gabal Garf (southern ED) and Wadi Hammariya (central ED) of Egypt are discussed. Microscopic and electron probe studies on these minerals are made to evaluate their textural and compositional variations. Alteration of chromites led to form ferritchromite and magnetite; rutile–magnetite intergrowths and martite are common in serpentinites. Fine trillis exsolution of ilmenite–magnetite and ilmenite–hematite and intergrowth of rutile–magnetite and ilmenite–sphene are recorded. Composite intergrowth grains of titanomagnetite–ilmenite trellis lamellae are common in metagabbros. The formation of ilmenite trellis and lamellae in magnetite and titanomagnetite indicate an oxidation process due to excess of oxygen contained in titanomagnetite; trapped and external oxidizing agents. This indicates the high P H2O and oxygen fugacity of the parental magma. The sulfides minerals include pyrrhotite, pyrite and chalcopyrite. Based on the chemical characteristics, the Fe–Ti oxide from the ophiolitic metagabbros in both areas corresponds to ilmenite. The patites from the metagabbros are identified as fluor-apatite. Carbonates are represented by dolomites in serpentinites and calcite in metagabbros. Spinel crystals in serpentinites are homogenous or zoned with unaltered cores of Al-spinel to ferritchromit and Cr-magnetite toward the altered rims. Compared to cores, the metamorphic rims are enriched in Cr# (0.87–1.00 vs. 0.83–0.86 for rims and cores, respectively) and impoverished in Mg# (0.26–0.48 vs. 0.56–0.67) due to Mg–Fe and Al (Cr)–Fe3+ exchange with the surrounding silicates during regional metamorphism rather than serpentinization process. The Fe–Ti oxides have been formed under temperature of ~800 °C for ilmenite. Al-spinels equilibrated below 500–550 °C, while the altered spinel rims correspond to metamorphism around 500–600 °C. Geochemical evidence of the podiform Al-spinels suggest a greenschist up to lower amphibolite facies metamorphism (at 500–600 °C), which is isofacial with the host rocks. Al-spinel cores do not appear to have re-equilibrated completely with the metamorphic spinel rims and surrounding silicates, suggesting relic magmatic composition unaffected by metamorphism. The composition of Al-spinel grains suggest an ophiolitic origin and derivation by crystallization of boninitic magma that belonging to a supra-subduction setting could form either in forearcs during an incipient stage of subduction initiation or in back-arc basins. 相似文献