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1.
This paper contributes to the understanding of the genesis of epigenetic, hypogene BIF-hosted iron deposits situated in the eastern part of Ukrainian Shield. It presents new data from the Krivoy Rog iron mining district (Skelevatske–Magnetitove deposit, Frunze underground mine and Balka Severnaya Krasnaya outcrop) and focuses on the investigation of ore genesis through application of fluid inclusion petrography, microthermometry, Raman spectroscopy and baro-acoustic decrepitation of fluid inclusions. The study investigates inclusions preserved in quartz and magnetite associated with the low-grade iron ores (31–37% Fe) and iron-rich quartzites (38–45% Fe) of the Saksaganskaya Suite, as well as magnetite from the locally named high-grade iron ores (52–56% Fe). These high-grade ores resulted from alteration of iron quartzites in the Saksaganskiy thrust footwall (Saksaganskiy tectonic block) and were a precursor to supergene martite, high-grade ores (60–70% Fe). Based on the new data two stages of iron ore formation (metamorphic and metasomatic) are proposed.The metamorphic stage, resulting in formation of quartz veins within the low-grade iron ore and iron-rich quartzites, involved fluids of four different compositions: CO2-rich, H2O, H2O–CO2 N2–CH4)–NaCl(± NaHCO3) and H2O–CO2 N2–CH4)–NaCl. The salinities of these fluids were relatively low (up to 7 mass% NaCl equiv.) as these fluids were derived from dehydration and decarbonation of the BIF rocks, however the origin of the nahcolite (NaHCO3) remains unresolved. The minimum P–T conditions for the formation of these veins, inferred from microthermometry are Tmin = 219–246 °C and Pmin = 130–158 MPa. The baro-acoustic decrepitation analyses of magnetite bands indicated that the low-grade iron ore from the Skelevatske–Magnetitove deposit was metamorphosed at T = ~ 530 °C.The metasomatic stage post-dated and partially overlapped the metamorphic stage and led to the upgrade of iron quartzites to the high-grade iron ores. The genesis of these ores, which are located in the Saksaganskiy tectonic block (Saksaganskiy ore field), and the factors controlling iron ore-forming processes are highly controversial. According to the study of quartz-hosted fluid inclusions from the thrust zone the metasomatic stage involved at least three different episodes of the fluid flow, simultaneous with thrusting and deformation. During the 1st episode three types of fluids were introduced: CO2–CH4–N2 C), CO2 N2–CH4) and low salinity H2O–N2–CH4–NaCl (6.38–7.1 mass% NaCl equiv.). The 2nd episode included expulsion of the aqueous fluids H2O–N2–CH4–NaCl(± CO2, ± C) of moderate salinities (15.22–16.76 mass% NaCl equiv.), whereas the 3rd event involved high salinity fluids H2O–NaCl(± C) (20–35 mass% NaCl equiv.). The fluids most probably interacted with country rocks (e.g. schists) supplying them with CH4 and N2. The high salinity fluids were most likely either magmatic–hydrothermal fluids derived from the Saksaganskiy igneous body or heated basinal brines, and they may have caused pervasive leaching of Fe from metavolcanic and/or the BIF rocks. The baro-acoustic decrepitation analyses of magnetite comprising the high-grade iron ore showed formation T = ~ 430–500 °C. The fluid inclusion data suggest that the upgrade to high-grade Fe ores might be a result of the Krivoy Rog BIF alteration by multiple flows of structurally controlled, metamorphic and magmatic–hydrothermal fluids or heated basinal brines.  相似文献   

2.
Volcanic rocks preserved in the Lampang–Den Chai area in NW Thailand are important components of the giant Paleotethyan igneous belt. Constraining their age and petrogenesis is critical for better understanding their temporal-spatial relationship with the Lancangjiang igneous zone and the Paleotethyan tectonic evolution in SE Asia. The volcanic suite is constituted by intermediate to acid rocks with zircon U–Pb ages of 240.4 ± 1.7 Ma and 240.6 ± 1.9 Ma for the representative andesitic and rhyolitic samples, respectively. Volcanic sequence is dominated by calc-alkaline andesites, dacites and rhyolites. The andesitic and dacitic samples are characterized by high Mg# (37–57) and TiO2 (0.91–1.59 wt%), and can be classified as high-Mg series. They are enriched in LILEs and LREEs and depleted in HFSEs. Representative andesitic samples have 87Sr/86Sr (i) ratios of 0.70398–0.70567, εNd (t) values of +3.6–+3.9, zircon εHf (t) values of +2.8–+8.0 and δ18O values of 7.01–8.11‰, respectively. The rhyolitic samples are characterized by high Mg# (38–70) and low TiO2 (0.25–0.61 wt%). They are enriched in LILEs and LREEs, along with 87Sr/86Sr (i) = 0.70468–0.70645, εNd (t) = +2.0–+4.3 and zircon εHf (t) = +5.7–+13.6. Geochemical signatures suggest that the andesitic and dacitic samples might originate from a newly modified mantle source by slab-derived fluids and recycled sediments, and rhyolitic samples were derived from juvenile mafic crust. It is proposed that the Middle Triassic high-Mg volcanic rocks in the Lampang–Den Chai area formed in response to slab roll-back during transition of tectonic regime from subduction to continental collision between the Sibumasu and Indochina blocks. These rocks constitute part of the Chiang Khong–Lampang–Tak igneous zone, and can northerly link with the Lancangjiang igneous zone and southerly extend to the Chanthaburi, Malaysia and Singapore areas.  相似文献   

3.
The combination of ion microprobe dating and cathodoluminescence (CL) imaging of zircons from a high-grade rock from the Central Zone of the Limpopo Belt were used to constrain the age of metamorphic events in the area. Zircon grains extracted from an orthopyroxene-gedrite-bearing granulite were prepared for single crystal CL-imaging and ion microprobe dating. The grains display complex zoning when using SEM-based CL-imaging. A common feature in most grains is the presence of a distinct core with a broken oscillatory zoned structure, which clearly appears to be the remnant of an original grain of igneous origin. This core is overgrown by an unzoned thin rim measuring about 10–30 μm in diameter, which is considered as new zircon growth during a single metamorphic event. Selected domains of the zircon grains were analysed for U, Pb and Th isotopic composition using a CAMECA IMS 1270 ion microprobe (Nordsim facility). Most of the grains define a near-concordant cluster with some evidence of Pb loss. The most concordant ages of the cores yielded a weighted mean 207Pb/206Pb age of 2689 ± 15 (2σ) Ma, interpreted as the age of the protolith of an igneous origin. The unzoned overgrowths of the zircon grains yielded a considerably younger weighted mean 207Pb/206Pb age of ∼2006.5 ± 8.0 Ma (2σ), and these data are interpreted to reflect closely the age of the ubiquitous high-grade metamorphic event in the Central Zone. This study shows clearly, based on both the internal structure of the zircons and the data obtained by ion microprobe dating, that only a single metamorphic event is recorded by the studied 2.69 Ga old rocks, and we found no evidence of an earlier metamorphic event at ∼2.5 Ga as postulated earlier by some workers.  相似文献   

4.
Compared to the extensively documented ultrahigh-pressure metamorphism at North Qaidam, the pre-metamorphic history for both continental crust and oceanic crust is poorly constrained. Trace element compositions, U–Pb ages, O and Lu–Hf isotopes obtained for distinct zircon domains from eclogites metamorphosed from both continental and oceanic mafic rocks are linked to unravel the origin and multi-stage magmatic/metamorphic evolution of eclogites from the North Qaidam ultrahigh-pressure metamorphic (UHPM) belt, northern Tibet.For continental crust-derived eclogite, magmatic zircon cores from two samples with U–Pb ages of 875–856 Ma have both very high δ18O (10.6 ± 0.5‰) and mantle-like δ18O (averaging at 5.2 ± 0.7‰), high Th/U and 176Lu/177Hf ratios, and steep MREE-HREE distribution patterns (chondrite-normalized) with negative Eu anomalies. Combined with positive εHf (t) of 3.9–14.3 and TDM (1.2–0.8 Ga and 1.3–1.0 Ga, respectively), they are interpreted as being crystallized from either subduction-related mantle wedge or recycled material in the mantle. While the metamorphic rims from the eclogites have U–Pb ages of 436–431 Ma, varying (inherited, lower, and elevated) oxygen isotopes compared with cores, low Th/U and 176Lu/177Hf ratios, and flat HREE distribution patterns with no Eu anomalies. These reflect both solid-state recrystallization from the inherited zircon and precipitation from external fluids at metamorphic temperatures of 595–622 °C (TTi-in-zircon).For oceanic crust-derived eclogite, the magmatic cores (510 ± 19 Ma) and metamorphic rims (442.0 ± 3.7 Ma) also show distinction for Th/U and 176Lu/177Hf ratios, and the REE patterns and Eu anomalies. Combined with the mantle-like δ18O signature of 5.1 ± 0.3 ‰ and two groups of model age (younger TDM close to the apparent ages and older > 700 Ma), two possible pools, juvenile and inherited, were involved in mixing of mantle-derived magma with crustal components. The relatively high δ18O of 6.6 ± 0.3‰ for metamorphic zircon rims suggests either the protolith underwent hydrothermal alteration prior to the ~ 440 Ma oceanic crust subduction, or external higher δ18O fluid activities during UHP metamorphism at ~ 440 Ma.Therefore, the North Qaidam UHPM belt witnesses multiple tectonic evolution from Late Mesoproterozoic–Neoproterozoic assembly/breakup of the Rodinia supercontinent with related magmatic emplacement, then Paleozoic oceanic subduction, and finally transition of continental subduction/collision related to UHP metamorphism.  相似文献   

5.
The precise constraints on the timing of metamorphism of the Changhai metamorphic complex is of great importance considering the prolonged controversial issue of the north margin and the extension of the Sulu–Dabie HP–UHP Belt. While the monazite U–Th–Pb and muscovite 40Ar/39Ar techniques are widely accepted as two of the most powerful dating tools for revealing the thermal histories of medium–low grade metamorphic rocks and precisely constraining the timing of metamorphism. The Changhai metamorphic complex at the SE Jiao–Liao–Ji Belt, North China Craton consists of a variety of pelitic schist and Grt–Ky-bearing paragneiss, and minor quartzite and marble. Analyses of mineral inclusions and back-scattered electric (BSE) images of monazites, combined with LA–ICP–MS U–Th–Pb ages for monazites and 40Ar/39Ar ages for muscovites, provide evidence of the origin and metamorphic age of the Changhai metamorphic complex. Monazites separates from various Grt–Mus schists and Grt–Ky–St–Mus paragneisses exhibit homogeneous BSE images from cores to rims, and contain inclusion assemblages of Grt + Mus + Qtz ± Ctd ± Ky in schist, and Grt + Ky + St + Mus + Pl + Kfs + Qtz inclusions in paragneiss. These inclusion assemblages are very similar to matrix minerals of host rocks, indicating they are metamorphic rather than inherited or detrital in origin. LA–ICP–MS U–Th–Pb dating reveals that monazites of schist and paragneiss have consistent 206Pb/238U ages ranging from 228.1 ± 3.8 to 218.2 ± 3.7 Ma. In contrast, muscovites from various schists show slightly older 40Ar/39Ar plateau ages of 236.1 ± 1.5 to 230.2 ± 1.2 Ma. These geochronological and petrological data conclude that the pelitic sediments have experienced a metamorphic event at the Mid–Late Triassic (236.1–218.2 Ma) rather than the Paleoproterozoic (1950–1850 Ma), commonly regarded as the Precambrian basement for the Jiao–Liao–Ji Belt. Hence, the Changhai metamorphic complex should be considered as a discrete lithotectonic group.This newly recognized Mid–Late Triassic metamorphic event (236.1–218.2 Ma) for the Changhai metamorphic complex is coeval with the HP–UHP metamorphic event (235–220 Ma) for Sulu–Dabie rocks. This leads us to speculate that the metamorphism of the Changhai complex belt along the SE margin of the North China Craton was genetically related to the Mid–Late Triassic collision of the North China and South China cratons. By the same token, the Sulu–Dabie HP–UHP Belt may have extended through Yantai, and the southern Yellow Sea, and to the southern side of the Changhai metamorphic complex.  相似文献   

6.
《Gondwana Research》2014,25(3):1272-1286
The Mejillonia terrane, named after the Mejillones Peninsula (northern Chile), has been traditionally considered an early Paleozoic block of metamorphic and igneous rocks displaced along the northern Andean margin in the Mesozoic. However, U–Pb SHRIMP zircon dating of metasedimentary and igneous rocks shows that the sedimentary protoliths were Triassic, and that metamorphism and magmatism took place in the Late Triassic (Norian). Field evidence combined with zircon dating (detrital and metamorphic) further suggests that the sedimentary protoliths were buried, deformed (foliated and folded) and metamorphosed very rapidly, probably within few million years, at ca. 210 Ma. The metasedimentary wedge was then uplifted and intruded by a late arc-related tonalite body (Morro Mejillones) at 208 ± 2 Ma, only a short time after the peak of metamorphism. The Mejillones metamorphic and igneous basement represents an accretionary wedge or marginal basin that underwent contractional deformation and metamorphism at the end of a Late Permian to Late Triassic anorogenic episode that is well known in Chile and Argentina. Renewal of subduction along the pre-Andean continental margin in the Late Triassic and the development of new subduction-related magmatism are probably represented by the Early Jurassic Bólfin–Punta Tetas magmatic arc in the southern part of the peninsula, for which an age of 184 ± 1 Ma was determined. We suggest retaining the classification of Mejillonia as a tectonostratigraphic terrane, albeit in this new context.  相似文献   

7.
The newly discovered Yuanlingzhai porphyry molybdenum (Mo) deposit in southern Jiangxi province belongs to the group of Mo-only deposits in the Nanling region. The mineralization developed at contact zones between the Yuanlingzhai granite porphyry and Neoproterozoic metamorphic rocks of the Xunwu Formation. Precise LA–MC–ICPMS zircon U–Pb dating of the Yuanlingzhai porphyry, as well as the adjacent western Keshubei and eastern Keshubei granites, yielded ages of 165.49 ± 0.59 Ma, 159.68 ± 0.43 Ma, and 185.13 ± 0.52–195.14 ± 0.63 Ma, respectively. Molybdenite Re–Os isochron ages of the ores are 160 ± 1–162.7 ± 1.1 Ma, which is consistent with the age of large-scale W–Sn deposits in South China. The Yuanlingzhai porphyry is characterized by high K2O, P2O5, and A/CNK (1.33–1.59), and low CaO and Na2O. The rock shows relatively enriched LREE without significant Eu anomalies (Eu/Eu* = 0.80–0.90). Geochemical and mineralogical characteristics indicate that the ore-hosting porphyry is a typical S-type granite generated from the partial melting of crustal material with only minor mantle contribution. Both Harker and evolutionary discrimination diagrams indicate that the Yuanlangzhai and western Keshubei granites are not products of co-magmatic evolution. The Keshubei granites and Xunwu Formation were not significant sources for the components in the porphyry mineralization, but the Yuanlangzhai granite may have supplied some ore-forming material. However, the main ore-forming material was carried by fluids from deep sources, as demonstrated by fluid inclusion and stable isotope data from the molybdenum deposit. The Mo porphyry deposit formed in an extensional setting, and was possibly associated with Jurassic subduction of the Izanagi Plate.  相似文献   

8.
In eastern Thailand the Klaeng fault zone includes a high-grade metamorphic rock assemblage, named Nong Yai Gneiss, which extends about 30 km in a NW–SE direction along the fault zone. The rocks of this brittle-fault strand consist of amphibolite to granulite grade gneissic rocks. Structural analysis indicates that the rocks in this area experienced three distinct episodes of deformation (D1–D3). The first (D1) formed large-scale NW–SE-trending isoclinal folds (F1) that were reworked by small-scale tight to open folds (F2) during the second deformation (D2). D1 and D2 resulted from NE–SW shortening during the Triassic Indosinian orogeny before being cross-cut by leucogranites. D1 and D2 fabrics were then reworked by D3 sinistral shearing, including shear planes (S3) and mineral stretching lineations (L3). LA–MC–ICP–MS U–Pb zircon dating suggested that the leucogranite intrusion and the magmatic crystallization took place at 78.6 ± 0.7 Ma followed by a second crystallization at 67 ± 1 to 72.1 ± 0.6 Ma. Both crystallizations occurred in the Late Cretaceous and, it is suggested, were tectonically influenced by SE Asian region effects of the West Burma and Shan-Thai/Sibumasu collision or development of an Andean-type margin. The sinistral ductile movement of D3 was coeval with the peak metamorphism that occurred in the Eocene during the early phases of the India–Asia collision.  相似文献   

9.
The Eastern Ghats Frontal Thrust (EGFT) demarcates the boundary between the Archaean/Paleoproterozoic cratonic rocks to the west, and the Meso/Neoproterozoic granulites of the Eastern Ghats Mobile Belt (EGMB) to the east. At Jeypore (Orissa, India), mafic schists and granites of the cratonic domain document a spatial increase in the metamorphic grade from greenschist facies (garnet, clinozoisite – absent varieties) in the foreland to amphibolite facies (clinozoisite- and garnet-bearing variants) progressively closer to the EGFT. Across the EGFT, the enderbite–charnockite gneisses and mafic granulites of EGMB preserves a high-grade granulite facies history; amphibolite facies overprinting in the enderbite–charnockite gneisses at the cratonic fringe is restricted to multi-layered growth of progressively Al, Ti – poor hornblende at the expense of pyroxene and plagioclase. In associated mafic granulites, the granulite facies gneissic layering is truncated by sub-centimeter wide shear bands defined by synkinematic hornblende + quartz intergrowth, with post-kinematic garnet stabilized at the expense of hornblende and plagioclase. Proximal to the contact, these granulites of the Eastern Ghats rocks are intruded by dolerite dykes. In the metadolerites, the igneous assemblage of pyroxene–plagioclase is replaced by intergrown hornblende + quartz ± calcite that define the thrust-related fabric and are in turn mantled by coronal garnet overgrowth, while scapolite is stabilized at the expense of recrystallized plagioclase and calcite. Petrogenetic grid considerations and thermobarometry of the metamorphic assemblages in metadolerites intrusive into granulites and mafic schists within the craton confirm that the rocks across the EGFT experienced prograde heating (Tmax value ∼650–700 °C at P  6–8 kbar) along the prograde arm of a seemingly clockwise PT path. Since the dolerites were emplaced post-dating the granulite facies metamorphism, the prograde heating is correlated with renewed metamorphism of the granulites proximal to the EGFT. A review of available age data from rocks neighboring the EGFT suggests that the prograde heating of the cratonic granites and the re-heating of the Eastern Ghats granulites are Pan – African in age. The re-heating may relate to an Early Paleozoic Pan-Gondwanic crustal amalgamation of older terrains or reactivation along an old suture.  相似文献   

10.
We report SHRIMP U–Pb age of zircons in four samples of eclogite and one sample of orthogneiss from Sulu ultrahigh-pressure (UHP) zone in Yangkou area, eastern China. UHP rocks are distributed along the Sulu orogenic belt suturing North China Block with South China Block. In Yangkou area, UHP unit is well exposed for about 200 m along Yangkou beach section and consists mainly of blocks or lenses of ultramafic rocks and eclogite together with para- and orthogneiss which are highly sheared partly. Zircon grains examined in this study from eclogite show oscillatory zoning and overgrowth texture in CL images, and most of the grains have high Th/U ratio ranging from 0.8 to 2.1 indicating an igneous origin. The weighted mean 206Pb/238U ages of zircons from the four samples range from 690 to 734 Ma. These ages can be correlated to the magmatic stage of the protoliths. In rare cases, zircon grains possess a narrow rim with very low Th/U ratio (< 0.02). EPMA U–Th-total Pb dating of such rim yields younger ages that range from 240 to 405 Ma marking the metamorphic stage. On the other hand, zircons from the orthogneiss show irregular shape and zoning with inclusion-rich core and inclusion-free rim. These grains of zircon yield U–Pb discordia intercept ages of 226 ± 63 Ma and 714 ± 110 Ma (MSWD 0.78). Bulk of the areas of the rims rim of the zircons demonstrate younger 206Pb/238U ages close to the upper intercept, with low Th/U ratio (< 0.20) indicating their metamorphic origin. In contrast, the cores show older 206Pb/238U ages close to lower intercept and high Th/U ratio of (0.14–5.25) indicating their igneous origin. The upper intercept age is also commonly noted in zircons from eclogite. Our results suggest a bimodal igneous activity along this zone during the Neoproterozoic, probably related to the rifting of the Rodinia supercontinent.  相似文献   

11.
The NW–SE trending Longshoushan is in the southwestern margin of the Alxa Block, which was traditionally considered the westernmost part of the North China Craton (NCC). Precambrian crystalline basement exposed in the Longshoushan area was termed the “Longshoushan Complex”. This complex's formation and metamorphism are significant to understand the geotectonics and early Precambrian crustal evolution of the western NCC. In this study, field geology, petrology, and zircon U–Pb and Lu–Hf isotopes of representative orthogneisses and paragneisses in the Longshoushan Complex were investigated. U–Pb datings reveal three Paleoproterozoic magmatic episodes (ca. 2.33, ca. 2.17 and ca. 2.04 Ga) and two subsequent regional metamorphic events (ca. 1.95–1.90 Ga and ca. 1.85 Ga) for metamorphic granitic rocks in the Longshoushan Complex. U–Pb dating of the detrital magmatic zircons from two paragneisses yields concordant 207Pb/206Pb ages between 2.2 Ga and 2.0 Ga, and a small number of metamorphic zircon rims provide a ca. 1.95 Ga metamorphic age, suggesting that the depositional time of the protolith was between 2.0 and 1.95 Ga and that the sedimentary detritus was most likely derived from the granitic rocks in the Longshoushan Complex itself. Zircon Lu–Hf isotopic analyses indicate that nearly all magmatic zircons from ca. 2.0 Ga to ca. 2.17 Ga orthogneisses have positive εHf(t) values with two-stage Hf model ages (TDMC) ranging from 2.45 to 2.65 Ga (peak at ca. 2.5 Ga), indicating that these Paleoproterozoic granitic rocks were derived from the reworking of the latest Neoarchean–early Paleoproterozoic juvenile crust. Detrital magmatic zircons from two paragneisses yield scattered 176Hf/177Hf ratios, εHf(t) and TDMC values, further indicating that the sedimentary detritus was not only derived from these plutonic rocks but also from other unreported or denuded Paleoproterozoic igneous rocks. The ca. 2.15 Ga detrital magmatic zircons from one paragneiss have negative εHf(t) values with TDMC ranging from 2.76 to 3.04 Ga, indicating another important crustal growth period in the Longshoushan region. These data indicate that the Longshoushan Complex experienced Neoarchean–Early Paleoproterozoic crustal growth, approximately ca. 2.3–2.0 Ga experienced multiphase magmatic events, and approximately ca. 1.95–1.90 Ga and ca. 1.85 Ga experienced high-grade metamorphic events. The sequence of tectonothermal events is notably similar to that of the main NCC. Together with the datasets from an adjacent area, we suggest that the western Alxa Block was most likely an integrated component of the NCC from the Neoarchean to the Paleoproterozoic.  相似文献   

12.
Eclogites are high-pressure/low-temperature metamorphic rocks and are regularly considered as an indicator of ancient subduction zones. Eclogites have recently been found in the North Shahrekord metamorphic complex (NSMC) of the Sanandaj–Sirjan zone and represent the only ones within the Zagros orogen. Their occurrence and timing are important for the reconstruction of convergence history and geodynamic evolution of the Neo-Tethys Ocean and Zagros orogen. White mica from the eclogites and an associated paragneiss give 40Ar/39Ar ages ranging from 184.3 ± 0.9 to 172.5 ± 0.8 Ma and represent the age of cooling through the closure temperature for phengitic white mica. The NSMC also comprises the ductile NW–SE trending North Shahrekord Shear Zone (NSSZ), which is located in the northeast of the Main Zagros Reverse Fault. The NSMC consists mainly of various metasedimentary rocks, orthogneiss and small-sized bodies of metabasic rocks containing also the eclogites. Furthermore, pre-metamorphic granitoids represent part of the NSMC. The North Shahrekord eclogites are composed of garnet, omphacite, zoisite, Ca–Na amphibole, phengite and rutile. The highly deformed and metamorphosed granitoids yield hornblende and biotite 40Ar/39Ar ages 170.1 ± 0.9 Ma and 110.7 ± 0.3 Ma, respectively. According to the new age dating results of eclogites, the rocks are the oldest high-pressure metamorphic rocks in the Zagros orogenic belt testifying the Neo-Tethys Ocean subduction. Our new data indicate that the eclogites formed during Early Jurassic subduction of a Panafrican microcontinental piece from the northern margin of the Neo-Tethyan Ocean under the Central Iranian microplate. We suggest that initiation of subduction in Neo-Tethyan Ocean occurred a few million years prior to 184 Ma (Pliensbachian stage).  相似文献   

13.
With the aim of constraining the Early Mesozoic tectonic evolution of the eastern section of the Central Asian Orogenic Belt (CAOB), we undertook zircon U–Pb dating and geochemical analyses (major and trace elements, Sr–Nd isotopes) of volcanic rocks of the Luoquanzhan Formation and Daxinggou Group in eastern Heilongjiang and Jilin provinces, China. The analyzed rocks consist mainly of dacite and rhyolite, with SiO2 contents of 68.52–76.65 wt%. Three samples from the Luoquanzhan Formation and one from the Daxinggou Group were analyzed using laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) U–Pb zircon techniques. Three zircons with well-defined oscillatory zoning yielded weighted mean 206Pb/238U ages of 217 ± 1, 214 ± 2, and 208 ± 1 Ma, and one zircon with oscillatory zoning yielded a weighted mean 206Pb/238U age of 201 ± 1 Ma. These ages are interpreted to represent the timing of eruption of the volcanic rocks. The Triassic volcanic rocks are characterized by high SiO2 and low MgO concentrations, enrichment in large ion lithophile elements (LILEs) and light rare earth elements (LREEs), depletion in high field strength elements (HFSEs) and heavy rare earth elements (HREEs), (87Sr/86Sr)i = 0.7040–0.7050 (Luoquanzhan Formation) and 0.7163–0.7381 (Daxinggou Group), and εNd (t) = 1.89–3.94 (Luoquanzhan Formation) and 3.42–3.68 (Daxinggou Group). These geochemical features indicate an origin involving the partial melting of juvenile lower crust (Nd model ages (TDM2) of 651–821 Ma) and that compositional variation among the volcanic rocks arose from mineral fractionation and minor assimilation. These volcanic rocks formed within an extensional environment following collision of the NCC and Jiamusi-Khanka Massif during the Late Paleozoic–Early Triassic.  相似文献   

14.
The Elu Link connecting the Neoarchean Hope Bay and Elu granite-greenstone belts in the Bathurst block of the northeast Slave craton consists of volcano-sedimentary and gabbro–granite rocks. Laser ablation ICP-MS zircon and titanite U-Pb dating was combined with mineral 40Ar-39Ar age data to date the Elu Link rocks and D1–D3 tectono-metamorphic events, as well as characterize the response to the Thelon Orogeny in the area. The volcanic rocks are correlated with the ca. 2716 Ma Flake Lake suite in the adjacent Hope Bay belt, whereas the sedimentary units have a minimum depositional age of 2684 ± 11 Ma nearly coinciding with the onset of D1 deformation. Most gabbro–granite bodies were emplaced between 2651 ± 14 Ma and 2577 ± 13 Ma coeval with the D2 deformation whose accompanying metamorphism culminated at 2632 ± 7 Ma. Older ages (up to 3042 ± 22 Ma) retained by either the gabbro–granite or their hosts are indicative of crustal contamination. A few gabbro–granites were also emplaced during the 2577 ± 13 Ma to 2494 ± 21 Ma D3 deformation event. However, the 2494 ± 21 Ma intrusions are unusual and mark the Archean–Paleoproterozoic transition. The D3 deformation was followed by erosional exhumation and localized thermal pulses associated with the emplacement of diabase dikes at 2228 ± 8 Ma, 2128 ± 11 Ma, and 802 ± 75 Ma. The Thelon Orogeny imprint, inferred from the 2054 ± 11 Ma to 1919 ± 5 Ma biotite ages, corresponds to nearly isobaric, low-temperature (< 350 °C) metamorphic re-equilibration.  相似文献   

15.
The Ebrahim-Attar (EBAT) leucogranite body is intruded within the Jurassic metamorphic complex of the Ghorveh area, located in the northern part of the Sanandaj Sirjan zone (SaSZ) of northwest Iran. The granite comprises alkali feldspar, quartz, Na-rich plagioclase and to a lesser extent, muscovite and biotite. Garnet and beryl are also observed as accessory minerals. Additionally, high SiO2 (71.4–81.0wt %) and Rb (145–440 ppm) content; low MgO (<0.12wt %), Fe2O3 (< 0.68 wt.%), Sr (mainly < 20 ppm), Ba (<57 ppm), Zr (10–53 ppm) and rare earth elements (REEs) low content (3.88–94.9 ppm with an average = 21.2 ppm); and flat REE patterns with a negative Eu anomaly characterize these rocks. The chemical composition and mineral paragenesis indicate that the rocks were formed by the partial melting of siliciclastic to pelitic rocks and can be classified as per-aluminous leucogranite or strongly per-aluminous (SP) granite. The Rb-Sr whole rock and mineral isochrons confirm that crystallization of the body occurred at 102.5 ± 6.1 Ma in Albian. The 87Sr/86Sr(i) and 143Nd/144Nd(i) ratios are 0.7081 ± 0.009 and 0.51220 ± 0.00005, respectively, and εNd(t) values range from −5.8 to −1.6. These values verify that the source of this body is continental crust. The Nd model ages (TDM2) vary between 1.0 and 1.3 Ga and are more consistent with the juvenile basement of Pan African crust. Based on these results, we suggest that the upwelling of the hot asthenospheric mantle in the SaSZ (likely during the Neo-Tethys rollback activity) occurred after the late Cimmerian orogeny. Consequently, we suggest that this process was responsible for a thinning and heating of the continental crust, from which the SP granite was produced by the partial melting of muscovite rich in pelitic or felsic-metapelitic rocks in the northern SaSZ.  相似文献   

16.
《Ore Geology Reviews》2011,41(1):27-40
Diyadin mineralization is the first reported gold deposit located in a collisional tectonic environment in Eastern Anatolia. The mineralization is related to N–S and N10–20°W-trending fault systems and hosted within the Paleozoic metamorphic basement rocks of the Anatolide–Toride microcontinent. Calc-schist, dolomitic marble and Miocene and Quaternary volcanic rocks comprise the exposed units in the mineralized area. Geochemical signatures, alteration types and host rock characteristics of the Diyadin gold deposit resemble those of Carlin-type deposits. Mineralization is constrained by alteration of overlying volcanic rocks to younger than ~ 14 Ma (K–Ar).Carbon and oxygen stable isotope measurements of carbonate rocks were made on six drill holes (n = 81) with an additional four samples of fresh carbonate rocks from surface outcrops. Background carbonate rocks have δ13CV-PDB ~ 1.8‰ and δ18OV-SMOW ~ 27‰. Isotopically-altered host rock samples have decreased δ18O (down to ~+11.4‰) and variable δ13C (from − 3.6 to + 4.8‰). Postore carbonate veins and cave-fill material have distinctly different isotopic signatures, particularly carbon (from δ13C = + 8.4 to + 9.8‰). Whether this post-ore carbonate is simply very late in mineralization associated with the gold system, or is a completely different, younger system utilizing the same pathways, is unclear at present. Within the host rock sample set, there is no correlation between gold and δ13C, and a weak correlation between gold and δ18O, indicative of water–rock interaction and isotopic alteration. Both the isotopic data and structural mapping suggest that the main upflow zone for the deposit is near the northern portion of the drill fence. Additional data at multiple scales are required to clarify the relationship(s) between fluid flow and mineralization.  相似文献   

17.
Zircon is the best mineral to record the complex evolution history of ultrahigh-pressure (UHP) metamorphic rocks as mineralogical and geochemical tracers of UHP metamorphism are almost obliterated in matrix assemblages resulted from subsequent retrogression during exhumation. Zircons from Dabie–Sulu UHP rocks, including outcrop and core samples from drill holes ranging from 432 to 5158 m in depth contain abundant mineral inclusions of protolith, prograde, peak (UHP) and retrograde minerals in different domains; these minute inclusions were identified by laser Raman spectroscopy and/or electronic microprobe analysis. Systematic studies on inclusions in zircons from previous and present studies indicate that the Dabie–Sulu UHP terrane extends for >2000 km, is about 50 km wide, and has at least 10 km thick, probably the largest UHP terrane recognized in the world thus far. The internal structure of zircon revealed by cathodoluminescence (CL) imaging displays a distinct zonation, which comprises an inherited (magmatic or detrital) core, prograde, peak (UHP), and outmost retrograde domains, each with distinctive mineral inclusion assemblages. Low-pressure, igneous mineral inclusions are common in the inherited (magmatic or detrital) zircon cores. In contrast, quartz eclogite-facies inclusion assemblages occur in prograde domains, coesite eclogite-facies inclusion assemblages are preserved in UHP domains, and amphibolite-facies inclusion assemblages are enclosed in outmost retrograde rims. Parageneses and compositions of inclusion minerals preserved in distinct zircon domains were used to constrain the metamorphic PT path of many Dabie–Sulu UHP rocks. The results indicate that Neoproterozoic supracrustal rocks together with minor mafic-ultramafic rocks were subjected to a prograde subduction-zone metamorphism at 570–690 °C and 1.7–2.1 GPa, and UHP metamorphism at 750–850 °C and 3.4–4.0 GPa, following by rapid decompression to amphibolite-facies retrograde metamorphism at 550–650 °C and 0.7–1.05 GPa. Sensitive high-resolution ion microprobe (SHRIMP) U–Pb spot analyses of the zoned zircons show four discrete and meaningful ages of the Dabie–Sulu metamorphic evolution: (1) Neoproterozoic protolith ages (800–750 Ma); (2) 246–244 Ma for early-stage quartz eclogite-facies prograde metamorphism; (3) 235–225 Ma for UHP metamorphism; and (4) 215–208 Ma for late-stage amphibolite-facies retrogression. This indicates that Neoproterozoic voluminous igneous protoliths of orthogneiss in response to the breakup of Rodinia supercontinent, together with various sedimentary rocks, and minor mafic-ultramafic intrusive and extrusive rocks, were subjected to coeval Triassic subduction to mantle depths and exhumation during the collision between the South China Block and North China Block. The estimated subduction and exhumation rates for the Dabie–Sulu UHP terrane would be up to 4.7–9.3 km Myr?1 and 5.0–11.3 km Myr?1, respectively. The zonal distribution of mineral inclusions and the preservation of index UHP minerals such as coesite imply that zircon is the best mineral container for each metamorphic stage, particular for supracrustal rocks as their metamorphic evolution and UHP evidence have been almost or completely obliterated. Similar conclusions have been documented elsewhere for other UHP terranes.  相似文献   

18.
The age and composition of the 14 × 106 km2 of Antarctica's surface obscured by ice is unknown except for some dated detrital minerals and erratics. In remedy, we present four new analyses (U–Pb age, TDMC, εHf, and rock type) of detrital zircons from Neogene turbidites as proxies of Antarctic bedrock, and review published proxies: detrital hornblendes analysed for Ar–Ar age and bulk Sm–Nd isotopes; Pb isotope compositions of detrital K-feldspars; erratics and dropstones that reflect age and composition; and recycled microfossils that reflect age and facies. This work deals with the 240°E–0°–015°E sector, and complements Veevers and Saeed's (2011) analysis of the 70°E–240°E sector. Each sample is located in its ice-drainage basin for backtracking to the potential provenance. Gaps in age between sample and upslope exposure are specifically attributable to the provenance. The major provenance of detritus west of the Antarctic Peninsula (AP) is West Antarctica, and of detritus east of the AP East Antarctica. We confirm that the Central Antarctic provenance about a core of the Gamburtsev Subglacial Mountains (GSM) and the Vostok Subglacial Highlands (VSH) contains a basement that includes igneous (mafic granitoids) and metamorphic rocks with peak U–Pb ages of 0.65–0.50, 1.20–0.9, 2.1–1.9, 2.8–2.6, and 3.35–3.30 Ga, TDMC of 3.6–1.3 Ga, and mainly negative εHf. The potential provenance of zircons of 650–500 Ma age with TDMC ages of 1.55 Ga, and of zircons of 1200–900 Ma age with positive εHf lies beneath the ice in East Antarctica south and southeast of Dronning Maud Land within the Antarctic part of the East African–Antarctic Orogen. Zircons with the additional ages of 1.7–1.4 Ga, 2.1–1.9 Ga, and 3.35–3.00 Ga have a potential provenance in the GSM.  相似文献   

19.
Isotopic compositions of He (27 samples) and Ar (7 samples) as well as major and trace elements have been determined in Cenozoic effusive rocks and hosted olivine and pyroxene phenocrysts from northern and central Mongolia. The R = 3He/4He values are within (0.1–13)⋅10−6. Abnormally high R value, 13⋅10−6, atypical of Cenozoic basaltic-volcanism areas in Mongolia, has been first revealed at one of the sites of the Hangayn upland. In composition the rocks under study correspond to tephrites, trachybasalts, and subalkalic andesite-basalts. Analysis of their REE patterns and spidergrams shows that the elements participating in the formation of basalt fields of the Hangayn upland were supplied from the enriched mantle (EM1). These patterns are similar to the OIB ones; (La/Yb)n = 9–53. The R values in the olivine phenocrysts are higher as compared with the pyroxene phenocrysts and the bulk rock compositions of the same samples. Based on the elemental composition of the rocks, their contents of radiogenic 4He and 3He were calculated. The rate of 3He formation is 5.65⋅10−2 at/(g⋅year). The calculated and measured R values in the rock samples point to the presence of trapped mantle helium.  相似文献   

20.
The metamorphic belt in the Basongco area, the eastern segment of Lhasa terrane, south Tibet, occurs as the tectonic blocks in Paleozoic sedimentary rocks. The Basongco metamorphic rocks are mainly composed of paragneiss and schist, with minor marble and orthogneiss, and considered previously to be the Precambrian basement of the Lhasa terrane. This study shows that the Basongco metamorphic belt experienced medium-pressure amphibolite-facies metamorphism under the conditions of T = 640–705 °C and P = 6.0–8.0 kbar. The inherited detrital zircon of the metasedimentary rocks yielded widely variable 206Pb/238U ages ranging from 3105 Ma to 500 Ma, with two main age populations at 1150 Ma and 580 Ma. The magmatic cores of zircons from the orthogneiss constrain the protolith age as ca. 203 Ma. The metamorphic zircons from all rocks yielded the consistent metamorphic ages of 192–204 Ma. The magmatic cores of zircons in the orthogneiss yielded old Hf model ages (TDM2 = 1.5–2.1 Ga). The magmatic zircons from the mylonitized granite yielded a crystallization age of ca. 198 Ma. These results indicate that the high-grade metamorphic rocks from the Basongco area were formed at early Jurassic and associated with coeval magmatism derived from the thickening crust. The Basongco metamorphic belt, together with the western and coeval Sumdo and Nyainqentanglha metamorphic belts, formed a 400-km-long tectonic unit, indicating that the central segment of the Lhasa terrane experienced the late Paleozoic to early Mesozoic collisional orogeny.  相似文献   

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