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1.
Petrochronology of magmatic monazite and apatite from a single paragneiss leucosome derived by in situ partial melting documents the thermal evolution of the Allochthonous Belt of the central Grenville Province. Monazite records suprasolidus metamorphism from ca. 1080 to 1020 Ma under high temperature up to 850°C. Apatite from the same leucosome yields an age of 960 Ma, consistent with cooling of this crustal segment down to subsolidus conditions of ca. 450°C. A pegmatitic granite dyke, with lobate contacts, previously dated at ca. 1005 Ma (Turlin et al., 2017 ) is interpreted to intrude the paragneisses at a temperature of ca. 650°C close to the wet‐solidus. These data document slow cooling at a rate of 2–6°C/Ma for the middle crust of this part of the Grenville hinterland marked by protracted suprasolidus conditions for at least 70 Ma. It supports the definition of the Grenville Orogen as a large, hot, long‐duration orogen.  相似文献   

2.
Annually resolved June–July–August (JJA) temperatures from ca. 570 BC to AD 120 (±100 a; approximately 690 varve years) were quantified from biogenic silica and chironomids (Type II regression; Standard Major Axis calibration‐in‐time) preserved in the varved sediments of Lake Silvaplana, Switzerland. Using 30 a (climatology) moving averages and detrended standard deviations (mean–variability change, MVC), moving linear trends, change points and wavelets, reconstructed temperatures were partitioned into a warmer (+0.3°C; ca. 570–351 BC), cooler (?0.2°C; ca. 350–16 BC) and moderate period (+0.1°C; ca. 15 BC to AD 120) relative to the reconstruction average (10.9°C; reference AD 1950–2000 = 9.8°C). Warm and variable JJA temperatures at the Late Iron Age–Roman Period transition (approximately 50 BC to AD 100 in this region) and a cold anomaly around 470 BC (Early–Late Iron Age) were inferred. Inter‐annual and decadal temperature variability was greater from ca. 570 BC to AD 120 than the last millennium, whereas multi‐decadal and lower‐frequency temperature variability were comparable, as evident in wavelet plots. Using MVC plots of reconstructed JJA temperatures from ca. 570 BC to AD 120, we verified current trends and European climate model outputs for the 21st century, which suggest increased inter‐annual summer temperature variability and extremes in a generally warmer climate (heteroscedasticity; hotspot of variability). We compared these results to MVC plots of instrumental and reconstructed temperatures (from the same sediment core and proxies but a different study) from AD 1177 to AD 2000. Our reconstructed JJA temperatures from ca. 570 BC to AD 120 showed that inter‐annual JJA temperature variability increased rapidly above a threshold of ～10°C mean JJA temperature. This increase accelerated with continued warming up to >11.5°C. We suggest that the Roman Period serves with respect to inter‐annual variability as an analogue for warmer 21st‐century JJA temperatures in the Alps. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

3.
Impacts of subsurface heat storage on aquifer hydrogeochemistry   总被引：3，自引：3，他引：0  
The use of shallow aquifers for subsurface heat storage in terms of energy management and building climatisation can lead to a temperature rise in the aquifer to 70 °C and above. The influence of temperature changes on individual mineral and sorption equilibria, reaction kinetics and microbial activity is largely known. However, the impact of heating to temperatures as high as 70 °C on the aquifer overall system has not been quantified yet. Temperature-related changes in sediment ion exchange behaviour, dimension and rates of mineral dissolution and precipitation as well as microbially enhanced redox processes were studied in column experiments using aquifer sediment and tap water at 10, 25, 40, and 70 °C. At 70 °C, a change in sediment sorption behaviour for cations and organic acids was postulated based on temporal changes in pH, magnesium, and potassium concentration in the experimental solution. No clear changes of pH, TIC and major cations were found at 10–40 °C. Redox zoning shifted from oxic conditions towards nitrate and iron(III) reducing conditions at 25 and 40 °C and sulphate reducing conditions at 70 °C. This was attributed to (a) a temperature-related increase in microbial reduction activity, and (b) three times higher release of organic carbon from the sediment at 70 °C compared to the lower temperatures. The findings of this study predict that a temperature increase in the subsurface up to 25 °C and above can impair the usability of ground water as drinking and process water, by reducing metal oxides and thus possibly releasing heavy metals from the sediment. Generally, at 70 °C, where clear cation and organic carbon desorption processes were observed and sulphate reducing conditions could be achieved, a site-specific assessment of temperature effects is required, especially for long-term operations of subsurface heat storage facilities.  相似文献   

4.
Aquifer thermal energy storage in urban and industrial areas can lead to an increase in subsurface temperature to 70 °C and more. Besides its impacts on mineral and sorption equilibria and chemical reaction kinetics in an aquifer, temperature sensitively influences microbial activity and thus redox processes, such as sulphate reduction. Microorganism species can only operate within limited temperature ranges and their adaptability to temperature is a crucial point for the assessment of the environmental consequences of subsurface heat storage. Column experiments with aquifer sediment and tap water at 10, 25, 40, and 70 °C showed that under the constant addition of acetate sulphate reduction could be initiated after 26–63 pore volumes exchanged at all temperatures. Fastest initiation of sulphate reduction with the highest reduction rates was found at 40 °C. Maximum rate constants during experimental run-time were 0.56 h?1 at 40 °C and 0.33, 0.36, and 0.25 h?1 at 10 and, 25, and 70 °C, respectively. Hence, microbial activity was enhanced by a temperature increase to 40 °C but was significantly lowered at 70 °C. At 25 °C methane was found in solution, indicating the presence of fermenting organisms; at 10, 40, and 70 °C no methane production was observed. It could be shown that redox processes in an aquifer generally can adapt to temperatures significantly higher than in situ temperature and that the efficiency of the reduction process can be enhanced by temperature increase to a certain limit. Enhancement of sulphate reduction in an aquifer due to temperature increase could also allow enhanced degradation of organic ground water contaminants such as BTEX, where sulphate is an important electron acceptor.  相似文献   

5.
 The speciation of water dissolved in glasses along the join NaAlSi3O8-KAlSi3O8 has been investigated using infrared spectroscopy. Hydrous melts have been hydrothermally synthesized by chemical equilibration of cylinders of bubble-free anhydrous start glasses with water at 1040° C and 2 kbar. These melts have been isobarically and rapidly (200° C/s) “drop”-quenched to room temperature and then subsequently depressurized. The speciation of water in the quenched glasses reflects the state of water speciation at a temperature (the so-called fictive temperature) where the quenched-in structure of the glasses closely corresponds to the melt structure at equilibrium. This fictive temperature is detectable as the macroscopically measureable glass transition temperature of these melt compositions. A separate set of experiments using vesicular samples of the same chemistry has precisely defined the glass transition temperature of these melts (±5° C) on the basis of homogenization temperatures for water-filled fluid inclusions (Romano et al. 1994). The spectroscopic data on the speciation of water in these quenched glasses has been quantified using experimentally determined absorptivities for OH and H2O for each individual melt composition. The knowledge of glass transition temperatures, together with quantitative speciation data permits an analysis of the temperature dependence of the water speciation over the 113° C range of fictive temperatures obtained for these water-saturated melts. The variation of water speciation, cast as the equilibrium constant K where K = [H2O] [O m ]/[OH]2 is plotted versus the fictive temperature of the melt to obtain the temperature dependence of speciation. Such a plot describes a single linear trend of the logarithm of the equilibrium constant versus reciprocal temperature, implying that the exchange of K for Na has little influence on melt speciation of water. The enthalpy derived from temperature dependence is 36.5(±5) kJ/mol. The results indicate a large variation in speciation with temperature and an insensitivity of the speciation to the K–Na exchange. Received: 8 March 1995/Accepted: 6 June 1995  相似文献   

6.
Core P1‐003MC was retrieved from 851 m water depth on the southern Norwegian continental margin, close to the boundary between the Norwegian Current (NC) and the underlying cold Norwegian Sea Deep Water. The core chronology was established by using 210Pb measurements and 14C dates, suggesting a sampling resolution of between 2 and 9 yr. Sea‐surface temperature (SST) variations in the NC are reconstructed from stable oxygen isotope measurements in two planktonic Foraminifera species, Neogloboquadrina pachyderma (d.) and Globigerina bulloides. The high temporal resolution of the SST proxy records allows direct comparison with instrumental ocean temperature measurements from Ocean Weather Ship (OWS) Mike in the Norwegian Sea and an air temperature record from the coastal island Ona, western Norway. The comparison of the instrumental and the proxy SST data suggests that N. pachyderma (d.) calcify during summer, whereas G. bulloides calcify during spring. The δ18O records of both species suggest that the past 70 yr have been the warmest throughout the past 600 yr. The spring and summer proxy temperature data suggest differences in the duration of the cold period of the Little Ice Age. The spring temperature was 1–3°C colder throughout most of the period between ca. AD 1400 and 1700, and the summer temperature was 1–2°C colder throughout most of the period between ca. AD 1400 and 1920. Fluctuations in the depth of the lower boundary of the NC have been investigated by examining grain size data and benthic foraminiferal assemblages. The data show that the transition depth of the lower boundary of the NC was deeper between ca. AD 1400 and 1650 than after ca. AD 1750 until present. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

7.
Chironomids and pollen were studied in a radiocarbon-dated sediment sequence obtained from a former lake near the Maloja Pass in the Central Swiss Alps (1865 m a.s.l.) to reconstruct the Lateglacial environment. Pollen assemblages imply a vegetation development around the Maloja Pass from shrub tundra at the beginning of the Allerød to coniferous forest during the early Holocene with a lowering of the timberline during the Younger Dryas. Chironomid assemblages are characterized by several abrupt shifts in dominant taxa through the Lateglacial. The occurrence of taxa able to survive hypoxia in the second part of the Allerød and during the Preboreal, and their disappearance at the onset of the Younger Dryas cold phase suggest summer thermal stratification and unfavourable hypolimnetic oxygen conditions in the palaeo-lake during the warmer periods of the Lateglacial interstadial and early Holocene. Mean July air temperatures were reconstructed using a chironomid-temperature transfer function from the Alpine region. The pattern of reconstructed temperature changes agrees well with the Greenland δ18O record and other Lateglacial temperature inferences from Central Europe. The inferred July temperatures of ca 10.0 °C during most of the Allerød were slightly lower than modern values (10.8 °C) and increased up to ca 11.7 °C (i.e., above present-day values) at the end of the Allerød. The first part of the Younger Dryas was colder (ca 8.8 °C) than the second part (ca 9.8 °C). During most of the Preboreal, the temperatures persisted within the limits of 13.5–14.5 °C (i.e., ca 3 °C above present-day values). The amplitudes of temperature changes at the Allerød–Younger Dryas–Preboreal transitions were ca 3.5–4.0 °C. The temperature reconstruction also shows three short-lived cooling events of ca 1.5–2.0 °C, which may be attributed to the centennial-scale Greenland Interstadial events GI-1d and GI-1b, and the Preboreal Oscillation.  相似文献   

8.
A chironomid–July air temperature inference model based on chironomid assemblages in the surface sediments of 81 Swiss lakes was used to reconstruct Late Glacial July air temperatures at Lac Lautrey (Jura, Eastern France). The transfer‐function was based on weighted averaging–partial least squares (WA‐PLS) regression and featured a leave‐one‐out cross‐validated coefficient of determination (r2) of 0.80, a root mean square error of prediction (RMSEP) of 1.53 ° C, and was applied to a chironomid record consisting of 154 samples covering the Late Glacial period back to the Oldest Dryas. The model reconstructed July air temperatures of 11–12 ° C during the Oldest Dryas, increasing temperatures between 14 and 16.5 ° C during the Bølling, temperatures around 16.5–17.0 ° C for most of the Allerød, temperatures of 14–15 ° C during the Younger Dryas and temperatures of ca. 16.5 ° C during the Preboreal. The Lac Lautrey record features a two‐step July air temperature increase after the Oldest Dryas, with an abrupt temperature increase of ca. 3–3.5 ° C at the Oldest Dryas/Bølling transition followed by a more gradual warming between ca. 14 200 and 13 700 BP. The transfer‐function reconstructs a less rapid cooling at the Allerød/Younger Dryas transition than other published records, possibly an artefact caused by the poor analogue situation during the earliest Younger Dryas, and an abrupt warming at the Younger Dryas/Holocene transition. During the Allerød, two centennial‐scale 1.5–2.0 ° C coolings are apparent in the record. Although chronologically not well constrained, the first of these cold events may be synchronous with the beginning of the Gerzensee Oscillation. The second is inferred just before deposition of the Laachersee tephra at Lac Lautrey and is therefore coeval with the end of the Gerzensee Oscillation. In contrast to the Greenland oxygen isotope records, the Lac Lautrey palaeotemperature reconstruction lacks a clearly defined Greenland Interstadial (GI) event 1d and the decreasing temperature trend during the Bølling/Allerød Interstadial. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

9.
The melting of two basic granite varieties in the Voznesenka Complex such as Yaroslavka biotite granite and Voznesenka Li–F granite was subject to experimental studies to analyze and to compare the conditions of their physicochemical formation. The experiments were conducted at 550–700°C and 50–500 MPa in pure water and in 0.1 and 1 m HF aqueous fluorine-bearing solutions. The melting temperature of Voznesenka Li–F granites was 60–70°C lower than that of Yaroslavka biotite granites. The temperature decreased by almost 100°C from the completion of biotite granite crystallization to the completion of Li–F granite crystallization.  相似文献   

10.
This paper studies the variation of mass, density, wave velocity and thermal conductivity of concrete after high-temperature heat treatment. The range of temperature to which the concrete specimens are exposed is 25–900 °C, in a heating furnace. The results are summarized as follows: three temperature ranges (20–300 °C, 300–600 °C and above 600 °C) corresponding to the moisture vaporization (i.e., adhered water, combined water or crystal water), decomposition of some minerals (i.e., Ca-hydroxide, Mg-hydroxide) and Ca-carbonate are obviously evident. The physical properties of concrete specimens change most significantly within the temperature range above 300 °C, which may be attributed to the transformation of concrete minerals. Moreover, within the temperature range of 300–900 °C, especially between 400 and 600 °C, the concrete structure has significant chemical changes basing on the variations of surface features, ultimately making the number and width of cracks and mass loss level increased, as well as the wave velocity and thermal conductivity changed.  相似文献   

11.
Geothermal water sources located within The Erzurum province were identified and hot water samples were taken from four different geothermal areas. The results of in situ and hydrogeochemical analyses of these hot water samples were interpreted and the properties of hot water, water–rock associations, estimated reservoir temperature and hot water usage areas were determined. The temperatures of the samples collected from the study area vary between 26.2 and 57.7 °C, while pH values change from 6.09 to 7.33, EC values obtained from in situ measurements are between 1829 and 9480 µS/cm and Eh values are (??190) to (26.3) mV. Total dissolved solids of the hot waters have a range from 838.7 to 3914.1 mg/l. The maximum estimated reservoir temperature is calculated as 250 °C by applying chemical geothermometers. However, considering the actual temperatures of Pasinler, Köprüköy, Horasan and Il?ca thermal waters and wells, the most reliable temperature range depending on the applied geothermometers’ results indicate minimum and maximum reservoir temperatures 85–158.9 °C, respectively, taking in account the errors. According to the isotope analysis, the waters circulating within the geothermal system are of meteoric origin and modern waters. In addition, two samples taken from clayey levels observed in the field were analyzed and the mineralogy of the clays was evaluated.  相似文献   

12.
Few well-dated, quantitative Holocene temperature reconstructions exist from high-altitude sites in the Central Eastern Alps. Here, we present a chironomid-based quantitative reconstruction of mean July air temperatures (TJuly) throughout the Holocene for a remote high-mountain lake, Schwarzsee ob Sölden, situated above the treeline at 2796 m a.s.l. in the Austrian Alps. Applying a chironomid-temperature inference model developed from lakes of the Alpine region to a high-resolution chironomid record from the lake provides evidence for early Holocene (ca 10000–8600 cal yr BP) TJuly of up to 8.5 °C, i.e. >4 °C above the modern (1977–2006) mean July temperature. The reconstruction reveals the so-called ‘8.2-ka cold event’ centered at ca 8250–8000 cal yr BP with temperatures ca 3 °C below the early-Holocene thermal maximum. Rather warm (ca 6 °C) and productive conditions prevailed during ca 7900–4500 cal yr BP. The chironomid record suggests a climate transition between ca 5200 and 4500 cal yr BP to cooler TJuly. A distinct cooling trend is evident from ca 4500 until ca 2500 cal yr BP. Thereafter, the study site experienced its coldest conditions (around 4 °C or less) throughout the rest of the Holocene, with the exception of the warming trend during the late 20th century. Beside other factors, the Northern Hemisphere summer insolation seems to be the major driving force for the long-term trends in TJuly at high altitudes in the Eastern Alps. Due to the extreme location of the lake and the limited temperature range represented by the applied calibration data set, the chironomid-based temperature reconstruction fails to track phases of the late-Holocene climatic history with TJuly cooler than 4 °C. Further chironomid-based palaeoclimate model and down-core studies are required to address this problem, provide more realistic TJuly estimates from undisturbed high-altitude lakes in the Alps, and extract a reliable regional temperature signal.  相似文献   

13.
《Quaternary Science Reviews》2007,26(19-21):2420-2437
Lateglacial environments at Hijkermeer, northwest Netherlands, were reconstructed by means of chironomid, diatom and pollen analyses. Diatom assemblages indicate that Hijkermeer was a shallow, oligo- to mesotrophic lake during this period. Pollen assemblages reflect the typical northwest European Lateglacial vegetation development and provide an age assessment for the record from the beginning of the Older Dryas (ca 14 000 calibrated 14C yr BP) into the early Holocene (to ca 10 700 calibrated 14C yr BP). The chironomid record is characterized by several abrupt shifts between assemblages typically found in mid-latitude subalpine to alpine lakes and assemblages typical for lowland environments. Based on the chironomid record, July air temperatures were reconstructed using a chironomid-temperature transfer-function from central Europe. Mean July air temperatures of ca 14.0–16.0 °C are inferred before the Older Dryas, of ca 16.0–16.5 °C during most of the Allerød, of ca 13.5–14.0 °C during the Younger Dryas, and of ca 15.5–16.0 °C during the early Holocene. Two centennial-scale decreases in July air temperature were reconstructed during the Lateglacial interstadial which are correlated with Greenland Interstadial events (GI)-1d and -1b. The results suggest that vegetation changes in the Netherlands may have been promoted by the cooler climate during GI-1d, immediately preceding the Older Dryas biozone, and GI-1b. The Hijkermeer chironomid-inferred temperature record shows a similar temperature development as the Greenland ice core oxygen isotope records for most of the Lateglacial and a good agreement with other temperature reconstructions available from the Netherlands. This suggests that chironomid-based temperature reconstruction can be successfully implemented in the Northwest European lowlands and that chironomids may provide a useful alternative to oxygen isotopes for correlating European lake sediment records during the Lateglacial.  相似文献   

14.
《International Geology Review》2012,54(15):1873-1883
Mt Sanqingshan, a global Geopark and world natural heritage site located in Jiangxi Province, China, is famous for its eroded granite peaks. The uplift and denudation history of the area has been reconstructed using fission track methods for the first time. Apatite fission track ages (AFTAs) cluster into three groups at ca. 25 Ma, 45–55 Ma, and 70 Ma. These ages can be related to ancient multilevel denudation planes at about 900, 1200, and 1500 m above sea level, respectively. The apatite data also reveal four cooling stages for the Mt Sanqingshan region, from ca. 90 to 65–60 Ma, 65–60 to 45 Ma, 45 to 20–15 Ma, and 20–15 Ma to the present, with cooling rates of 1.96°C, 1.18°C, 0.37°C, and 3.78°C per million years, respectively, and an average cooling rate of 1.80°C per million years. Calculated uplift rates are 0.055, 0.034, 0.011, and 0.11 mm year?1 in the four stages, yielding uplifts of 4140, 570, 290, and 1940 m, respectively. The uplift rate of the last stage was significantly faster than that of the other three preceding stages, reflecting rejuvenation of Mt Sanqingshan, as a result of new tectonism. The average uplift rate at Mt Sanqingshan is 0.053 mm year?1, and the average denudation rate is 0.048 mm year?1, resulting in 3550 m of uplift and 2540 m of denudation relative to eustatic sea level. The 1010 m difference is very close to the average elevation of about 1000 m at present. A comparison of uplift–denudation histories for Mt Sanqingshan and Mt Huangshan shows that fission track results can be useful for defining geomorphological development stages.  相似文献   

15.
We describe the structure, microstructures, texture and paleopiezometry of quartz-rich phyllites and marbles along N-trending Moutsounas shear zone at the eastern margin of the Naxos metamorphic core complex (MCC). Fabrics consistently indicate a top-to-the-NNE non-coaxial shear and formed during the main stage of updoming and exhumation between ca. 14 and 11 Ma of the Naxos MCC. The main stage of exhumation postdates the deposition of overlying Miocene sedimentary successions and predates the overlying Upper Miocene/Pliocene conglomerates. Detailed microstructural and textural analysis reveals that the movement along the Moutsounas shear zone is associated with a retrograde greenschist to subgreenschist facies overprint of the early higher-temperature rocks. Paleopiezometry on recrystallized quartz and calcite yields differential stresses of 20–77 MPa and a strain rate of 10−15–10−13 s−1 at 350 °C for quartz and ca. 300 °C for calcite. Chlorite geothermometry of the shear zone yields two temperature regimes, 300–360 °C, and 200–250 °C. The lower temperature group is interpreted to result from late-stage hydrothermal overprint.  相似文献   

16.
We have compiled what we believe is the longest coherent coastal sea surface temperature record in North America. Near-surface water temperature measurements have been made almost daily at Great Harbon, Woods Hole, Massachusetts, since 1886 with remarkably few gaps. The record shows that there was no significant trend in water temperature at this site for the first 60 yr of observation. There was some cooling during the 1960s that was followed by a significant warming from 1970–2002 at a rate of 0.04°C yr?1. During the 1990s annual mean temperatures averaged approximately 1.2°C warmer than they had been on average between 1890 and 1970; winter (December, January, and February) temperatures were 1.7°C warmer and summer (June, July, and August) temperatures were 1.0°C warmer. There has not been a statistically significant decrease in the annual number of winter days below 1°C or an increase in the annual number of winter days above 5°C. The number of summer days each year with water temperature above 21°C has not increased significantly. The dates of first observations of 10°C and 20°C water in the spring have not changed sufficiently to be statistically significant. There is a weak positive correlation between annual and winter water temperature and the annual and winter North Atlantic Oscillation index, respectively, during the period of record.  相似文献   

17.
We present a Lateglacial and early Holocene chironomid‐based July air temperature reconstruction from Foppe (1470 m a.s.l.) in the Swiss Southern Alps. Our analysis suggests that chironomid assemblages have responded to major and minor climatic fluctuations during the past 17 000 years, such as the Oldest Dryas, the Younger Dryas and the Bølling/Allerød events in the Lateglacial and the Preboreal Oscillation at the beginning of the Holocene. Quantitative July air temperature estimates were produced by applying a combined Norwegian and Swiss temperature inference model consisting of 274 lakes to the fossil chironomid assemblages. The Foppe record infers average July air temperatures of ca. 9.9 °C during the Oldest Dryas, 12.2 °C during most of the Bølling/Allerød and 11.1 °C for the Younger Dryas. Mean July air temperatures during the Preboreal were 14 °C. Major temperature changes were observed at the Oldest Dryas/Bølling (+2.7 °C), the Allerød/Younger Dryas (?2 °C) and the Younger Dryas/Holocene transitions (+3.9 °C). The temperature reconstruction also shows centennial‐scale coolings of ca. 0.8–1.4 °C, which may be synchronous with the Aegelsee (Greenland Interstadial 1d) and the Preboreal Oscillations. A comparison of our results with other palaeoclimate records suggests noticeable temperature gradients across the Alps during the Lateglacial and early Holocene. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

18.
Geomorphological mapping of northern Arran provides evidence for two advances of locally nourished glaciers, the younger being attributable to the Loch Lomond Stade (LLS) of ca. 12.9–11.5 k yr BP, primarily through the mutually exclusive relationship between glacial limits and Lateglacial periglacial features. The age of the earlier advance is unknown. Inferred LLS glacier cover comprised two small icefields and eight small corrie or valley glaciers and totalled 11.1 km2. ELAs reconstructed using area–altitude balance ratio methods range from 268 m to 631 m for individual glaciers, with an area‐weighted mean ELA of 371 m. ELAs of individual glaciers are strongly related to snow‐contributing areas. The area‐weighted mean ELA is consistent with a north–south decline in LLS ELAs along the west coast of Great Britain. This decline has an average latitudinal gradient of 70 m 100 km?1, equivalent to a mean southwards ablation‐season temperature increase of ca. 0.42°C 100 km?1. Mean June–August temperatures at the regional climatic ELA, estimated from chironomid assemblages in SE Scotland, lay between 5.7 ± 0.1°C and 4.1 ± 0.2°C. Empirical relationships between temperature and precipitation at modern glacier ELAs indicate equivalent mean annual precipitation at the ELA lay between 2002 ± 490 mm and 2615 ± 449 mm. These figures suggest that stadial precipitation on Arran fell within a range between +8% and ?33% of present mean annual precipitation. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

19.
The magma storage conditions of the 6.62 Ma Blacktail Creek Tuff eruption, belonging to the Heise volcanic field (6.62–4.45 Ma old) of the Yellowstone hotspot system, have been investigated by combining thermobarometric and experimental approaches. The results from different geothermometers (e.g., Fe–Ti oxides, feldspar pairs, apatite and zircon solubility, and Ti in quartz) indicate a pre-eruptive temperature in the range 825–875 °C. The temperature estimated using two-pyroxene pairs varies in a range of 810–950 °C, but the pyroxenes are probably not in equilibrium with each other, and the analytical results of melt inclusion in pyroxenes indicate a complex history for clinopyroxene, which hosts two compositionally different inclusion types. One natural Blacktail Creek Tuff rock sample has been used to determine experimentally the equilibrium phase assemblages in the pressure range 100–500 MPa and a water activity range 0.1–1.0. The experiments have been performed at fluid-present conditions, with a fluid phase composed of H2O and CO2, as well as at fluid-absent conditions. The stability of the quartzo-feldspathic phases is similar in both types of experiments, but the presence of mafic minerals such as biotite and clinopyroxene is strongly dependent on the experimental approach. Possible explanations are given for this discrepancy which may have strong impacts on the choice of appropriate experimental approaches for the determination of magma storage conditions. The comparison of the composition of natural phases and of experimentally synthesized phases confirms magma storage temperatures of 845–875 °C. Melt water contents of 1.5–2.5 wt% H2O are required to reproduce the natural Blacktail Creek Tuff mineral assemblage at these temperatures. Using the Ti-in-quartz barometer and the Qz–Ab–Or proportions of natural matrix glasses, coexisting with quartz, plagioclase and sanidine, the depth of magma storage is estimated to be in a pressure range between 130 and 250 MPa.  相似文献   

20.
The paper reports data on the mineralogy, geochemistry, phase composition of comendites and pantellerites from Nemrut volcano, eastern Turkey; estimates of the crystallization conditions of minerals, composition of matrix glasses and melt inclusions in anorthoclase, fayalite, hedenbergite phenocrysts. LA-ICP-MS was applied to analyze the matrix glasses and phenocryst minerals. The distribution coefficients between phases and glass were calculated for P, B, Li, Rb, Cs, Ba, Sr, Zr, Hf, Ta, Nb, Sc, V, Cr, Ni, Cu, Pb, Th, U, Y, REE. Mass balance simulations of the comenditic and pantelleritic compositions, experimental data, data on melt inclusions are utilized to analyze the processes responsible for the derivation of the magmas, accumulation of components in them and to elucidate genetic links between the trachyte-comenditic, comenditic and pantelleritic melts. The origin of the residual comenditic and pantelleritic melts is explained by variations in the crystallization conditions of anorthoclase (dominant phase), hedenbergite, fayalite, Fe and Ti oxides in the parental trachyte-comenditic magma depending on the pressure and concentration of water dissolved in the melts. The accessory phases (REEand Sr-bearing fluorapatite and zircon) were likely involved in the fractionation of the melts. The following crystallization parameters were obtained by QUILF calculations for the hedenbergite, fayalite, and ilmenite phenocrysts (minimum values for quartz-free melts): 3 kbar, 763°C, ΔFMQ = ?1.27 for the Fe-comendites; 3.3–3.8 kbar, 715°C, ΔFMQ = ?1.8 for the pantellerites; 2.3 kbar, 748°C, ΔFMQ = ?1.16 for the low-Fe comendites. The equilibrium crystallization of anorthoclase phenocrysts in the comenditic melts proceeded at temperature ～750°C. Data on glasses of melt inclusions indicate that the comenditic and pantelleritic melts contained 1–3 wt % H2O. Analysis of literature data and estimates of the conditions under which the Nemrut magmas were derived suggest that the local chambers with H2O-undersaturated comenditic and pantelleritic melts could occur at centers of alkaline volcanism at depths within the range of 5 to 10–15 km (lithostatic pressure of 1–4 kbar), at temperatures <750°C and oxygen fugacity below the FMQ buffer.  相似文献   

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