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1.
Horizontal and vertical distributions of organochlorine compounds (OCs) were determined in sediments from Masan Bay. The concentrations of polychlorinated biphenyls (PCBs), dichlorodiphenyltrichloroethanes (DDTs), HCB, hexachlorocyclohexanes (HCHs) and chlordane related compounds (CHLs) in sediments were in the range of 1.24-41.4, 0.28-89.2, 0.02-0.59, nd-1.03, and nd-2.56 ng/g, respectively. The spatial distribution of OCs showed a negative gradient from the inner of the bay to outer part of the bay, indicating that the source of OCs was probably located inside the bay. Compositional pattern of PCB congeners showed a relatively high concentration of high-chlorinated congeners in the inner part of the bay and a relatively low concentration of low-chlorinated congeners in the outer part. In sediment core from Masan Bay maximum concentrations of PCBs and DDTs are observed in the subsurface samples and correspond to an age of early 1980s and late 1960s. The concentration profiles of PCBs and DDTs in sediments of Masan Bay appear to correspond to use of PCBs and DDTs in Korea.  相似文献   

2.
This study evaluated the contamination status and distribution of organochlorine pesticides (OCPs) between Xinghua Bay and adjacent watersheds in Putian region, southeast China. Twenty-five surface soil samples and two sediment cores were collected from two watersheds and the Xinghua Bay, respectively. Results showed that the concentrations of OCPs in samples of the Mulan River Watershed (MRW), the Qiulu River Watershed (QRW), the inner bay core (IBC) and the open bay core (OBC) were in the range of 4.96-38.20 ng/g, 4.62-22.80 ng/g, 1.84-80.46 ng/g and 1.87-23.43 ng/g, respectively. The mean concentration of OCPs was in an order: IBC > MRW > QRW > OBC. The higher concentration of OCPs in recent periods may suggest that a certain amount of OCPs were still input to this area.  相似文献   

3.
Persistent organochlorine compound concentrations were determined for 23 surface sediment samples collected from Alexandria Harbor, Egypt. Total PCB concentrations ranged from 0.9 to 1210 ng/g with four to seven Cl-substituted biphenyls being the most prevalent PCBs congeners. Different PCB congener distribution patterns were observed, probably reflecting different inputs and attenuation at various locations. Total DDT concentrations varied from <0.25 ng/g to 885 ng/g. The ratios of DDTs (2,4′- and 4,4′-DDT)/total DDTs (DDTs plus metabolites) in sediment samples from certain sites were 0.86 or higher, indicating little attenuation or recent input of DDT. Total chlordane (the sum of heptachlor and its epoxide, oxy-, γ- and -chlordane and cis+trans-nonachlor) ranged from <0.25 to 44 ng/g with the highest concentration found in the Arsenal Basin. The geographic distributions of PCBs, total DDTs and total chlordane were similar. Chlorinated benzenes (CBs), hexachlorocyclohexanes (HCHs), aldrin, dieldrin, endrin, chloropyrifos, endosulfan, mirex and pentachloroanisole were below detection limits or detected at low concentrations in most of the samples. Sites that were contaminated with high concentrations of organochlorine compounds were associated with dense population and low energy environment. The contamination levels of PCBs, total DDTs and total chlordane were in high range compared to other locations worldwide.  相似文献   

4.
During August-September 1993, a joint Russian-United States expedition to the Bering and Chukchi Seas took place. Surface water samples were collected from 21 sites and separated into dissolved (duplicates) and suspended solids; 19 sediment and 6 air samples were also collected. These samples were analysed for 19 organochlorine pesticides, 11 chlorobenzenes and 113 PCB congeners. The report provides data on selected compounds which occured in > or = 75% of the water samples. Highest water concentrations were observed for HCH in open waters north and south of the Bering Strait, both regions being similar (alpha-HCH; 2.2 ng/L and lindane: 0.35 ng/L). Air levels observed were also constant (alpha-HCH; 0.041 ng/m3, lindane: 0.0093 ng/m3). Suspended solids and air particulares contributed little to the concentrations in their respective media, an observation common to all analytes except for the PCBs and the DDT residues. The sum of PCB concentrations in water were higher in the Bering Sea area compared to the Chukchi Sea (1.0 vrs 0.67 ng/L) and lower for air (0.46 vrs 0.23 ng/m3). Sum of DDT in water was higher in the Bering Sea than in the Chukchi Sea (0.23 vrs 0.15 ng/L) while in sediments and air, the Bering Sea concentrations were lower (0.95 vrs 1.6 ng/g and 36 vrs 56 pg/m3, respectively). Other organochlorine compounds for which data are presented include: pp'-DDE, pp'-DDT, dieldrin, HCB, 3 chlorobenzenes and 3 PCB congeners. Fluxes of all these chemicals through the Berin Strait are estimated; they ranged from 57 t/a (alpha-HCH) through 26 t/a (for sum of PCBs) to 0.2 t/a (pp'-DDE, dieldrin and 1,2,3-trichlorobenzene). Fugacity ratios for the HCHs and PCBs indicate the alpha-HCH is degassing in both the Bering and Chukchi Seas and that the gamma-isomer is degassing in the Bering Sea and is close to equilibrium (weakly absorbing) in the Chuchi Sea; the sum of PCBs are strongly absorbing in both areas.  相似文献   

5.
Water from the Susquehanna River was collected and analyzed for polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyl (PCB) congeners to estimate seasonal and annual riverine loads to the Chesapeake Bay. Temporal variations in the chemical loads resulted from the large changes in the water flow rates and in the particle-associated contaminant concentrations. Concentrations of PCBs and PAHs in river particles (ng/g) were twice as great as those in the northern Chesapeake Bay, indicating that the Susquehanna River is an important source of these contaminants to the bay. The river carries a majority of its hydrophobic organic contaminants (HOCs) in the particulate phase. During periods of high flow, large amounts of suspended particles in the river result in elevated HOC levels and increased loadings of these contaminants to the bay. From 1997 to 1998, 60% of the total annual HOC loading occurred in the early spring coincident with high river flows. The total PCB and PAH annual loadings from the Susquehanna River to the Chesapeake Bay were 76 and 3160 kg/year, respectively and 75% of the loaded organic contaminants were in the particulate phase. Principal component analysis of PAH and PCB congener patterns in the particles reveals that the river suspended particles were dominated by autochthonous production in the summer and by resuspended sediment and watershed erosion during the winter and early spring.  相似文献   

6.
Very little information is available on the contamination of coastal sediments of Taiwan by PBDEs and PCBs. In this study, we determined the concentrations of 19 PBDE and 209 PCB congeners in 57 surface sediment samples to identify the possible sources of PBDEs and PCBs. The total PBDE and PCB concentrations ranged from below detection limit to 7.73 ng/g and 0.88-7.13 ng/g, respectively; these values are within the ranges observed for most coastal sediments worldwide. The PBDE congeners were dominated by BDE-209 (50.7-99.7%), with minor contributions from penta- and octa-BDEs. The signatures of PCB congeners suggested that PCB residues in Kaohsiung coast may be the legacy of past use or the result of ongoing inputs from the maintenance, repair and salvage of old ships. Principal component analysis of the congener-specific composition of PBDEs and PCBs revealed distinct regional patterns that are related to the use of commercial products.  相似文献   

7.
Trace organic (chlorinated pesticides, PCBs, PAHs and dioxins/furans) and trace metal concentrations were measured in surficial sediment and biological tissues (i.e., worms, crustaceans, bivalve molluscs, and fish livers) collected from the Russian Arctic. Total DDT, chlordane, PCB and PAH concentrations ranged from ND to 1.2, ND to <0.1, ND to 1.5 and <20-810 ng g(-1), respectively, in a suite of 40 surficial sediment samples from the Kara Sea and the adjacent Ob and Yenisey Rivers. High sedimentary concentrations of contaminants were found in the lower part of the Yenisey River below the salt wedge. Total dioxins/furans were analysed in a subset of 20 sediment samples and ranged from 1.4 to 410 pg g(-1). The highest trace organic contaminant concentrations were found in organisms, particularly fish livers. Concentrations as high as 89 ng g(-1) chlordane; 1010 ng g(-1) total DDTs; 460 ng g(-1) total PCBs; and 1110 ng g(-1) total PAH, were detected. A subset of 11 tissue samples was analysed for dioxins and furans with total concentrations ranging from 12 to 61 pg g(-1). Concentrations of many trace organic and metal contaminants in the Kara Sea appear to originate from riverine sources and atmospheric transport from more temperate areas. Most organic contaminant concentrations in sediments were low; however, contaminants are being concentrated in organisms and may pose a health hazard for inhabitants of coastal villages.  相似文献   

8.
Persistent organochlorine pollutants (POPs) are analyzed for the dropping-amended soils from the habitats of Antarctic seabirds and seals in Fildes Peninsula and Ardley Island. The concentration ranges are 0.21 to 3.85 ng/g for polychlorinated biphenyls (ΣPCBs),0.09 to 2.01 ng/g for organochlorine pesticides (ΣDDT),and 0.06 to 0.76 ng/g for hexachlorocyclohexanes (HCHs). Among these,hepata-chlorobiphenyls,hexachlorobiphenyls,p,p′-DDE and α-HCH compounds are dominant. The concentra-tion ranges of ΣPCB,DDT and HCH in the eggs of skuas were 91.9―515.5 ng/g,56.6―304.4 ng/g and 0.5―2.0 ng/g respectively; those in the eggs of penguins were 0.4―0.9 ng/g,2.4―10.3 ng/g and 0.1― 0.4 ng/g; and those in the eggs of giant petrel were 38.1―81.7 ng/g,12.7―53.7 ng/g and 0.5―1.5 ng/g respectively. The dominant POP compounds in the eggs are PCB180,PCB153,p,p′-DDE and hexa-chlorobenzene (HCB). The present study shows that the concentration of POPs in the sea-bird-inhabited-dropping-amended soil varies with the extent of predation and nest occupancy of dif-ferent seabird populations. Statistical analysis on the POP concentrations from the different seabird eggs implies that the difference in the bio-concentration levels of the birds depends on the bio-habits of the species,such as the range of activity,distance of immigration,feeding pattern,and nest occupation. Among these,the most important factor is the location of the seabirds in the food chain and their feeding pattern. This shows that POPs accumulated in the seabirds resulted from the bio-concentration through the food chain. In addtion,210Pb dating for the dropping-amended soils (AD1-a and AD2) was performed,which provided the POP accumulation rate and the historic record for the soil profile. It indicates that POP will continuously affect the Antarctic ecosystem for a long time.  相似文献   

9.
Concentrations of PCBs in coastal mangrove sediments of Hong Kong   总被引：6，自引：0，他引：6  
The concentrations of polychlorinated biphenyls (PCBs) in surface sediments of ten mangrove sites in Hong Kong were determined by Congener-specific and Arcolor methods. Spatial variations were found between mangrove sites and within the same site, indicating that the sediment samples were heterogeneous and total PCBs concentrations in mangrove sediments should be normalised to compensate for natural variability and for identifying serious anthropogenic contamination. In addition to total organic carbon, Al, Fe and Mn were possible normalisers. Based on PCB/normaliser ratio and 95% prediction limits of scatter plots between total PCB and normaliser, all mangrove sites were not seriously contaminated by human activities. The estimated total PCBs concentrations (quantified by Congener-specific method) for most sediment ranged from 0.5 to 5.8 ng g(-1) (dry weight, n = 92). However, very high concentrations of PCB were found in sub-samples from Yi O, Tolo Pond and Lai Chi Wo, suggesting that these samples represented the PCB contaminated "hot spots".  相似文献   

10.
Various benthic invertebrates (flying crab, common shrimp, and red starfish), small fish (sand goby), benthic flatfish (dab, plaice, and sole) and gadoids (bib and whiting) were collected in the Belgian North Sea and along the Scheldt Estuary, both representing areas impacted by various contaminants to different degrees. The levels of 25 polychlorinated biphenyls (PCBs) and 15 organochlorine pesticides (OCPs), which included penta- and hexachlorobenzene, alpha-, beta-, and gamma-hexachlorocyclohexane isomers, chlordanes, and DDT and metabolites, were determined. Sum of PCBs and OCPs in benthic invertebrates and goby ranged from 1.5 to 280 ng/g wet weight (ww) and from 0.27 to 23 ng/g ww, respectively. The fish livers revealed total PCB and OCP levels ranging from 20 to 3200 ng/g ww and from 6.0 to 410 ng/g ww, respectively. Levels of both contaminant groups were significantly higher in samples from the Scheldt Estuary compared to the Belgian North Sea. For most species a highly inverse correlation was found between the concentration of contaminants and the distance to Antwerp (r between 0.812 and 0.901, p < 0.05), pointing to a higher degree of exposure further upstream. PCB and OCP exposures are highly correlated (r between 0.836 and 1.000, p < 0.05), which suggests that the pollution can be classified as historical. However, because urban and industrial centres may still be emitting these compounds, more recent point and non-point sources cannot be ruled out.  相似文献   

11.
Concentrations of polychlorinated biphenyls (PCBs) in beached resin pellets were examined to reveal variability between individual particles and differences among beaches. Fifty-five resin pellets from a beach in Tokyo were individually analyzed for PCBs, and showed concentrations ranging from <28 to 2,300 ng/g. This indicates that concentrations are highly variable between particles. Among several characters, discoloration (e.g., yellowing) had a positive relationship with PCB concentration: discolored pellets contained more PCBs than others on most of the beaches sampled. Given the color-selective ingestion of food by some organisms, this may be ecotoxicologically important. Measurements of samples from 47 beaches in Japan showed regional differences in PCB concentrations in resin pellets consistent with those in mussels. Sporadic high concentrations of PCBs were also found in pellets from remote islands, suggesting that resin pellets could be the dominant route of exposure to the contaminants at remote sites. The similarity of PCB concentrations between resin pellets and mussels suggests a potential use of resin pellets to monitor pollution in seawater.  相似文献   

12.
A diastereoisomer (alpha, beta, and gamma) specific analytical method for measuring hexabromocyclododecanes (HBCDs) was developed using liquid chromatography-tandem mass spectrometry (LC-MS-MS). The method developed was applied to analyze blubber of small cetaceans to divulge the distribution and temporal variation of HBCDs in the Asian marine environment. HBCDs were detected in all the blubber samples of finless porpoises (Neophocaena phocaenoides) and Indo-Pacific humpback dolphins (Sousa chinensis) collected from the South China Sea during 1990-2001. Concentrations of HBCDs were higher in humpback dolphins (31-380 ng/g lipid) than in finless porpoises (4.7-55 ng/g lipid), which can be attributed to habitat differences. Average concentrations of alpha-HBCD in finless porpoises increased from 9.5 ng/g lipid in 1990 to 35 ng/g lipid in 2000/01. alpha-HBCD was predominant among the three isomers with some exceptions in finless porpoises collected in 1990. This is the first report on HBCDs contamination in marine mammals from Southeast Asia.  相似文献   

13.
The distribution of polycyclic aromatic hydrocarbons (PAHs) has been investigated in the surface and core sediments from Masan Bay, Korea. Total PAHs in the surface sediments ranged from 207 to 2670 ng/g dry weight with a mean value of 680 ng/g. Qualitative similarity and quantitative difference between inner and outer bay indicate that the main sources of PAHs are located in the inner bay and outer bay is also affected by the same sources. Vertical distribution of PAHs revealed that three distinctive stages could be differentiated with the help of PCA analysis. The highest concentration (industrialization stage) appeared between late 1950s and 1980, which was 10 years later than other developed countries. A strong pyrolytic source fingerprint has been detected with slight influence of petrogenic sources, and diagenetic PAH, perylene also contributed. Total organic carbon normalized PAHs (sum of 13 PAHs, 8.85-88.0 microg/g OC) were under the threshold effects concentration (TEC, 290 microg/g OC).  相似文献   

14.
Surface water samples from marinas, commercial ports and open bay areas collected from Biscayne Bay and the Miami River, Florida, USA, were analyzed for the occurrence of IRGAROL 1051 by GC/MS. The anifouling boosting herbicide was found in 80% (46/57) of the samples collected between March 1999 and September 2000. Concentrations within the bay range between non-detected (<1 ppt) and 61 ppt (ng/L) and were generally low compared with levels reported in European or Japanese waters. Aside from the elevated concentrations observed along the Miami River South Fork (61 ppt), the highest concentrations observed in the bay corresponded to marinas with high density of pleasure craft and restricted water circulation. In contrast, occurrence of IRGAROL 1051 along the commercial port or the cruise line terminal was generally lower (<1-2.2 ppt). Concentrations around Coconut Grove Marina were consistently higher (5-12 ppt) than the rest of the bay waters during the whole period of time surveyed.  相似文献   

15.
Surface and core sediments collected from six mariculture farms in the Pearl River Delta (PRD) were analyzed to evaluate contamination levels of polychlorinated biphenyls (PCBs). The ∑PCBs (37 congeners) concentrations ranged from 5.10 to 11.0 ng g(-1) (mean 7.96 ng g(-1)) in surface and 3.19 to 22.1 ng g(-1) (mean 7.75 ng g(-1)) in core sediments, respectively. The concentrations were significantly higher than that measured in the sediments of their corresponding reference sites, whereby the average enrichment percentages were 62.0% and 42.7% in surface and core sediments, respectively. Significant correlations (R2=0.77, p<0.05) of PCB homologue group proportions between fish feeds and surface mariculture sediments suggested that fish feed input was probably the main source for the enrichment of PCBs. Due to the fact that PCBs could be transferred along food chains, PCB contamination in fish feeds and mariculture sediments should not be overlooked.  相似文献   

16.
Samples of Calanus hyperboreus, a herbivorous copepod, were collected (n = 20) between April and July 1998, and water samples (n = 6) were collected in May 1998, in the Northwater Polynya (NOW) to examine persistent organic pollutants (POPs) in a high Arctic marine zooplankton. Lipid content (dry weight) doubled, water content (r2 = 0.88) and delta15N (r2 = 0.54) significantly decreased, and delta13C significantly increased (r2 = 0.30) in the C. hyperboreus over the collection period allowing an examination of the role of these variables in POP dynamics in this small pelagic zooplankton. The rank and concentrations of POP groups in C. hyperboreus over the entire sampling was sum of PCB (30.1 +/- 4.03 ng/g, dry weight) > sum of HCH (11.8 +/- 3.23) > sum of DDT (4.74 +/- 0.74), sum of CHLOR (4.44 +/- 1.0) > sum of CIBz (2.42 +/- 0.18), although these rankings varied considerably over the summer. The alpha- and gamma-HCH and lower chlorinated PCB congeners were the most common POPs in C. hyperboreus. The relationship between bioconcentration factor (BCF) and octanol-water partition coefficient (Kow) observed for the C. hyperboreus was linear and near 1:1 (slope = 0.72) for POPs with a log Kow between 3 and 6 but curvilinear when hydrophobic POPs (log Kow > 6) were included. Concentrations of sum of HCH. Sum of CHLOR and sum of CIBz increased over the sampling period, but no change in sum of PCB or sum of DDT was observed. After removing the effects of time, the variables lipid content, water content, delta15N and delta13C did not describe POP concentrations in C. hyperboreus. These results suggest that hydrophobic POP (log Kow = 3.86.0) concentrations in zooplankton are likely to reflect water concentrations and that POPs do not biomagnify in C. hyperboreus or likely in other small, herbivorous zooplankton.  相似文献   

17.
As a part of Mussel Watch Program in Korea, the contamination levels and accumulation features of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) were assessed for 82 bivalve samples collected from 66 sites along the entire coast of Korea. The dry weight based ∑PCBs and ∑OCPs ranged from 4.4 ng g−1 to 422.0 ng g−1 (geometric MEAN=36.9 ng g−1) and from 9.95 ng g−1 to 131.37 (34.88) ng g−1, respectively. PCB was predominant in Korean coast, followed by DDTs, HCHs, and Chlordanes. From the observed log normal distribution of PCB and each OCP, low- and high-levels were defined as geometric mean ±1 S.D., respectively. The levels at the sites near urban and/or industrial areas often exceeded the high-levels and the spatial distributions of ∑DDTs and ∑CHLs were correlated with that of ∑PCBs, indicating terrestrial input pathways. Even distribution of ∑HCHs suggested a possibility of atmospheric input pathway of HCHs. The observed isomer ratios of DDTs, HCHs, and CHLs indicated that aging has occurred.  相似文献   

18.
An environmental survey on pesticide residues and polychlorobyphenyl compounds (PCBs), encompassing more than 70 polar and non-polar compounds quantifiable by the techniques used, was performed in the Mekong River delta based on analyses of water, sediment and bivalve mollusc samples. Few polar compounds, such as diazinon and fenotrothion, were detected in water but a high number of non-polar chlorinated compounds, such as DDT, HCH, endosulfan and PCBs, were detected in sediments and biota. The highest concentrations measured were of DDT with an average 6.3 ng g(-1) dry weight (range 0.32-67 ng g(-1)) in sediments and 38.6 ng g(-1) (range 5.5-123 ng g(-1)) in molluscs' soft tissues. Amongst chlorinated compounds, DDT concentrations were followed in decreasing order by those of PCB, endosulfan, hexachlorocyclohexane and chlordane. Residues of organochlorine compounds originate from local usage of agrochemicals although with a likely contribution also of atmospheric deposition of residues (not measured) originated elsewhere. Concentrations of PCB and pesticide residues in the aquatic environment of the Mekong River delta are lower than values reported for other regions of Vietnam and Asia. Nevertheless, current concerns about the effects of chlorinated compounds on public health advise improved control of chemical residue discharges in order to abate environmental contamination.  相似文献   

19.
Organochlorines in Hong Kong Fish   总被引：6，自引：0，他引：6  
Muscle samples from 15 species of fish (n=1) purchased from markets in Hong Kong and 10 liver samples of tilapia (Tilapia mossambica) collected from the Shing Mun River were analysed for organochlorines (polychlorinated biphenyls, ΣDDTs, hexachlorobenzene, hexachlorocyclohexanes, chlordanes, mirex and dieldrin). Polychlorinated biphenyls (PCBs) were detected in 15 market fish samples but the levels were very low (around 1 ng g−1). PCB levels in tilapia livers collected from Tai Wai (29.3–65.1 ng g−1) were higher than those from Fo Tan (3.5–23.2 ng g−1) suggesting that there may be some local point soucres. ΣDDTs were detected in all samples, ranging from 3.3 to 75.6 ng g−1 in the market fish and from 7.1 to 88.8 ng g−1 in tilapia. The DDE/DDT ratios in the market fish (0.12–0.75) showed higher variability than those of tilapia (0.30–0.46), suggesting that some of the market fish may have been collected from areas where DDT was recently used. Results of this preliminary study show that organochlorine levels in Hong Kong market fish are low and do not cause any concern for human consumption. An on-going monitoring program, however, is recommended.  相似文献   

20.
Hexabromocyclododecane (HBCD) and tetrabromobisphenol A (TBBPA) were measured in surface sediments in the Pearl River Delta, southern China. The concentrations ranged from 0.06 to 304 ng/g dry weight for TBBPA and from 0.03 to 31.6 ng/g for total HBCD. The correlations between the TBBPA and HBCD concentrations were significant in rivers (Dongjiang, Zhujiang, Beijiang, and Dayanhe Rivers) with local input sources but not significant in the Xijiang River and Pearl River Estuary without local sources. HBCD was dominated by γ-HBCD (averaged 52.5-75.0%), whereas α-HBCD contributions were relatively high in sediments from the urban areas. The enantiomeric fractions of γ-HBCD in the sediments (averaged from 0.431 ± 0.035 to 0.479 ± 0.010) differed significantly from that in HBCD technical product except for samples from the e-waste area (Dayanhe River, 0.488 ± 0.091). This suggests that enantioselective biotransformation of HBCD occurs in the aquatic environment in this region.  相似文献   

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