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1.
Sodic pyroxene (jadeite content X jd=0.1–0.3) occurs locally as small inclusions within, albite porphyroblasts and in the matrix of hematite-bearing quartz schists in the Sanbagawa (Sambagawa) metamorphic belt, central Shikoku, Japan. The sodic, pyroxene-bearing samples are characteristically free from chlorite and their typical mineral assemblage is sodic pyroxene+subcalcic (or sodic) amphibole+phengitic mica+albite+quartz+hematite+titanite±epidote. Spessartine-rich garnet occurs in Mn-rich samples. Sodic pyroxene in epidote-bearing samples tends to be poorer in acmite content (average X Acm=0.26–0.50) than that in the epidote-free samples (X Acm=0.45–0.47). X Jd shows no systematic relationship to metamorphic grade, and is different among the three sampling regions [Saruta-gawa, Asemi-gawa and Bessi (Besshi)]. The average X Jd of the Saruta-gawa samples (0.21–0.29) is higher than that of the Asemi-gawa (0.13–0.17) and Bessi (0.14–0.23). The P-T conditions of the Asemi-gawa and Bessi regions are estimated at 5.5–6.5 kbar, >360°C in the chlorite zone, 7–8.5 kbar, 440±15°C in the garnet zone and 8–9.5 kbar, 520±25°C in the albite-biotite zone. Metamorphic pressure of the Saruta-gawa region is systematically 1–1.5 kbar higher than that of the Asemi-gawa and Bessi regions, and materials of the Saruta-gawa region have been subducted to a level 3–5 km deeper than materials that underwent metamorphism at equivalent temperatures and are now exposed in the Asemi-gawa and Bessi regions. Pressure slightly increases toward the north (structurally high levels) through the Sanbagawa belt of central shikoku. Two types of zonal structure were observed in relatively coarse-grained sodic pyroxenes in the matrix. One type is characterized by increasing X Jd from core to rim, the other type by decreasing X Jd from core to rim. Both types of zoned pyroxenes show an increase in X Fe 2+[=Fe2+/(Fe2++Mg)] from core to rim. The first type of zoning was observed in a sample from the chlorite zone of lowest grade, whereas the latter occurs in the garnet and albite-biotite zones of higher grade. The contrast in zonal structure implies that dP/dT during prograde metamorphism decreased with increasing metamorphic grade and may have been negative in some samples from the higher-grade zones. The estimated dP/dT of the prograde stage of the chlorite zone is 3.2 kbar/100°C, and that of the garnet and albite-biotite zones is -1.8 to 0.9 kbar/100°C. The variation of dP/dT at shallow and deep levels of a subduction system probably reflects the difference of heating duration and/or change in thermal gradient of the subduction zone by continuous cooling of the surrounding mantle.  相似文献   

2.
The macroscopically-zoned grandite from the garnetite skarn of Meka Presedla (Kopaonik Mountain, Serbia) was studied with optical microscopy, electron microprobe analysis (EMPA), Fourier transform infra-red (FT–IR), and Raman methods. The EMPA results indicate that the main core–rim compositional variations (Ca2.93–2.97Mn0.05–0.06Mg0.00–0.01Al1.14–1.26Fe3+0.72–0.83Ti0.00–0.02Si2.97–3.02O12) slightly differ along the zones, showing evidence for a quasi-cyclic alternation of the oscillatory zoning nature. Among this, considerable variation is observed only by the Al–Fe3+ substitutions in the octahedral site. The EMPA also indicate that the grandite zones compositionally vary, mostly within ±1 and ±2 mol% of the homogeneity level range, that is, Grs64±1Adr36±1Sps2 (A), Grs62±1Adr38±1Sps2 (B), Grs59±2Adr40±2Sps2 (C), Grs58±2Adr41±2Sps2 (D), and Grs58±1Adr41±1Sps2 (E). Therefore, the investigated garnet can be considered as relatively highly homogeneous. The majority of compositions lie within the narrow miscibility region of 0.58±2相似文献   

3.
Eclogites from the Onodani area in the Sambagawa metamorphic belt of central Shikoku occur as layers or lenticular bodies within basic schists. These eclogites experienced three different metamorphic episodes during multiple burial and exhumation cycles. The early prograde stage of the first metamorphic event is recorded by relict eclogite facies inclusions within garnet cores (XSps 0.80–0.24, XAlm 0–0.47). These inclusions consist of relatively almandine‐rich garnet (XSps 0.13–0.24, XAlm 0.36–0.45), aegirine‐augite/omphacite (XJd 0.08–0.28), epidote, amphiboles (e.g. actinolite, winchite, barroisite and taramite), albite, phengite, chlorite, calcite, titanite, hematite and quartz. The garnet cores also contain polyphase inclusions consisting of almandine‐rich garnet, omphacite (XJd 0.27–0.28), amphiboles (e.g. actinolite, winchite, barroisite, taramite and katophorite) and phengite. The peak P–T conditions of the first eclogite facies metamorphism are estimated to be 530–590 °C and 19–21 kbar succeeded by retrogression into greenschist facies. The second prograde metamorphism began at greenschist facies conditions. The peak metamorphic conditions are defined by schistosity‐forming omphacites (XJd ≤ 49) and garnet rims containing inclusions of barroisitic amphibole, phengite, rutile and quartz. The estimated peak metamorphic conditions are 630–680 °C and 20–22 kbar followed by a clockwise retrograde P–T path with nearly isothermal decompression to 8–12 kbar. In veins cross‐cutting the eclogite schistosity, resorbed barroisite/Mg‐katophorite occurs as inclusions in glaucophane which is zoned to barroisite, suggesting a prograde metamorphism of the third metamorphic event. The peak P–T conditions of this metamorphic event are estimated to be 540–600 °C and 6.5–8 kbar. These metamorphic conditions are correlated with those of the surrounding non‐eclogitic Sambagawa schists. The Onodani eclogites were formed by subduction of an oceanic plate, and metamorphism occurred beneath an accretionary prism. These high‐P/T type metamorphic events took place in a very short time span between 100 and 90 Ma. Plate reconstructions indicate highly oblique subduction of the Izanagi plate beneath the Eurasian continent at a high spreading rate. This probably resulted in multiple burial and exhumation movements of eclogite bodies, causing plural metamorphic events. The eclogite body was juxtaposed with non‐eclogitic Sambagawa schists at glaucophane stability field conditions. The amalgamated metamorphic sequence including the Onodani eclogites were exhumed to shallow crustal/surface levels in early Eocene times (c. 50 Ma).  相似文献   

4.
Quantitative thermobarometry of inclusions in zoned garnet from a Franciscan eclogite block record a counter-clockwise P–T path from blueschist to eclogite and back. Garnet retains prograde zoning from inclusion-rich Alm52Grs30Pyp6Sps12 cores to inclusion-poor Alm62Grs25Pyp12Sps1 mantles, with overgrowths of highly variable composition. Barometry using the Waters–Martin version of the garnet–phengite–omphacite thermobarometer yields conditions of 7–15 kbar, 400–500°C (garnet cores), 18–22 kbar, ∼550°C (mantles), and 10–14 kbar, 350–450°C (overgrowths), in agreement with clinozoisite–sphene–rutile–garnet–quartz barometry. These pressures are ∼10–15 kbar less than those obtained using more recent, fully thermodynamic calibrations of the phengite–omphacite–garnet thermobarometer. Low early temperatures suggest that the block was subducted in a thermally mature subduction zone and not at the inception of subduction when prograde temperature is expected to be higher. Franciscan high-grade blocks likely represent crust subducted throughout the history of this convergent margin, rather than only at the inception of the subduction zone.  相似文献   

5.
The Motuo area is located in the east of the Eastern Himalayan Syntaxis. There outcrops a sequence of high-grade metamorphic rocks, such as metapelites. Petrology and mineralogy data suggest that these rocks have experienced three stages of metamorphism. The prograde metamorphic mineral assemblages(M1) are mineral inclusions(biotite + plagioclase + quartz ± sillimanite ± Fe-Ti oxides) preserved in garnet porphyroblasts, and the peak metamorphic assemblages(M2) are represented by garnet with the lowest XSps values and the lowest XFe# ratios and the matrix minerals(plagioclase + quartz ± Kfeldspar + biotite + muscovite + kyanite ± sillimanite), whereas the retrograde assemblages(M3) are composed of biotite + plagioclase + quartz symplectites rimming the garnet porphyroblasts. Thermobarometric computation shows that the metamorphic conditions are 562–714°C at 7.3–7.4 kbar for the M1 stage, 661–800°C at 9.4–11.6 kbar for the M2 stage, and 579–713°C at 5.5–6.6 kbar for the M3 stage. These rocks are deciphered to have undergone metamorphism characterized by clockwise P-T paths involving nearly isothermal decompression(ITD) segments, which is inferred to be related to the collision of the India and Eurasia plates.  相似文献   

6.
A regional petrographic reconnaissance of psammitic and pelitic rocks in the Otago Schist, New Zealand, has revealed the presence of garnet (“grossalspite” with typical rim composition almandine41, spessartine25, grossular33, pyrope1) and biotite in 37 new samples, more than doubling the previously known number. A new garnet–biotite–albite zone can now be defined in the greenschist facies Otago Schist that is distinct from the better-known biotite, garnet and oligoclase zones in the along-strike Alpine Schist. The garnet–biotite–albite zone is in part metamorphically discontinuous with adjacent schists and does not support models of simple, continuous, progressive Jurassic regional metamorphism in Otago. The structurally higher (lower grade) boundary of the zone coincides in at least three places with previously mapped regional shear zones. The structurally lower (expected higher grade) boundary of the zone appears to be obliterated by a chlorite zone overprint which can be spatially related to Alpine Schist recrystallisation of ?Cretaceous age. The Otago situation serves as an example of the subtle metamorphic discontinuities that probably pervade many orogenic belts.  相似文献   

7.
Pan‐African high‐pressure granulites occur as boudins and layers in the Lurio Belt in north‐eastern Mozambique, eastern Africa. Mafic granulites contain the mineral assemblage garnet + clinopyroxene + plagioclase + quartz ± magnesiohastingsite. Garnet porphyroblasts are zoned with increasing almandine and spessartine contents and decreasing grossular and pyrope contents from core (Alm46Prp32Grs21Sps2) to rim (Alm52Prp26Grs19Sps3). This pattern is interpreted as a retrograde diffusion zoning with the preserved core chemistry representing the peak metamorphic composition. Mineral reaction textures occur in the form of monomineralic and composite plagioclase ± orthopyroxene ± amphibole ± biotite ± magnetite coronas around garnet porphyroblasts. Thermobarometry indicates peak metamorphic conditions of up to 1.57 ± 0.14 GPa and 949 ± 92 °C (stage I), corresponding to crustal depths of ～55 km. Zircon yielded an U–Pb age of 557 ± 16 Ma, inferred to date crystallization of zircon during peak or immediately post‐peak metamorphism. Formation of plagioclase + orthopyroxene‐bearing coronas surrounding garnet indicates a near‐isothermal decompression of the high‐pressure granulites to lower pressure granulite facies conditions (stage II). Development of plagioclase + amphibole‐coronas enclosing the same garnet porphyroblasts shows subsequent cooling into amphibolite facies conditions (stage III). Symplectitic textures of the corona assemblages indicate rapid decompression. The high‐pressure granulite facies metamorphism of the Lurio Belt, followed by near‐isothermal decompression and subsequent cooling, is in accordance with a long‐lived tectonic history accompanied by high magmatic activity in the Lurio Belt during the late Neoproterozoic–early Palaeozoic East‐African–Antarctic orogeny.  相似文献   

8.
This paper presents the first report on the occurrence of eclogite from the Kumon range of the Western province in Myanmar, which is in the southeastern extension of the Himalayan orogenic belt. The eclogite is mainly composed of omphacite, garnet, hornblende/edenite/katophorite/taramite, biotite, quartz, and rutile. The garnet grains in the eclogite usually show textures of barrier reef, atoll, and table reef types, and have a wide compositional range of Alm58–70Sps1–2Prp9–16Grs14–31. Omphacite grains that occur as garnet inclusions and as isolated crystals in the matrix have similar compositions of Jd34–45 and Jd37–44, respectively. Lesser amounts of jadeitic clinopyroxene (Jd21–38), phengite, biotite, albite, and quartz occur in the lagoon of barrier reef and atoll garnet grains. The matrix omphacite is partly replaced by symplectite of sodic clinopyroxene of Jd20–29 and albite. The lower limits of the pressure/temperature during the eclogite stage, which are defined by the assemblage of garnet, omphacite (Jd40–45), and quartz, are 1.2–1.3 GPa/530–615 °C. The finding of eclogite from Myanmar suggests the possibility of a wide occurrence of high-pressure metamorphic rocks in the ophiolite zone along the southeastern extension of the Indus-Yarlung Zangbo suture in Myanmar and Indochina.  相似文献   

9.
Mafic garnet-bearing granulites from Sostrene Island, 150 km southwest of Davis Station on the coast of Prydz Bay, East Antarctica, exhibit two-stage symplectic coronas on garnet, formed after peak metamorphic conditions (M1). An outer corona of Opx (Mg66) + Pl (An94–97) + minor Hbl mantles a finer-grained inner corona of Opx (Mg67) + Pl (An95–96) + Spl (Mg36). Both symplectites contain minor ilmenite–magnetite intergrowths. The finer-grained symplectite also occurs along a fracture cleavage in the garnet. The outer corona originated during a second metamorphic event (M2) via the reaction Grt + Cpx (Hbl) + SiO2= Opx + Pl (1), whereas the inner corona formed later in response to decompression and minor deformation, resulting in the fracture cleavage in the garnet, according to the reaction Grt = Opx + Pl + Spl (2). The grossular content of the garent (XGrs= 0.168) is almost exactly that which is required for the stoichiometric breakdown by reaction (2) (calculated XGrs= 0.167). The mafic rocks are silica undersaturated, and the SiO2 for reaction (1) was most probably derived externally from the surrounding felsic gneisses. Preferred P–T estimates for M1 based on garnet core (Prp40Alm42Grs17Sps1)–matrix Opx–Cpx–Hbl pairs are c. 10 kbar at 980°C. The fine-grained symplectite formed post-peak M2 at c. 7 kbar and 850°C. The enclosing felsic gneisses yield pressure estimates of between 5 and 7 kbar, which compare with conditions of c. 6 kbar and 775°C in the nearby Bolingen Islands. These lower P–T estimates are considered to be representative of the widespread 1100-Ma metamorphic event recognized in outcrops along the Prydz Bay coast. The high-P, high-T estimates derived from the garnet relics provide evidence for an earlier, possibly Archaean, high-grade metamorphic event.  相似文献   

10.
Metapelitic residual enclaves in the Neogene Volcanic Province of SE Spain are residues left after melt extraction. Glass (quenched melt) of granitic composition occurs as inclusions in most minerals and as intergranular pockets. The most common enclave types show one stage of garnet growth that is interpreted to have occurred at the same time as glass production. Some of these show a well‐developed foliation outlined by fibrolite, biotite, graphite and glass, which wraps around elongate garnet crystals that have aspect ratios up to 10:1. Based on microstructures and chemistry, the garnet within these rocks shows clear core and mantle structure. The core has an average composition of Alm76–Prp08–Sps14–Grs03 and contains primary inclusions of biotite and melt, trapped during garnet growth. A thin (c. 100 μm), irregular mantle overgrows the garnet core, enclosing oriented fibrolite inclusions in strain caps, and biotite in strain shadows. In places, the overgrowths form skeletal elongated arms, which extend parallel to the foliation. The garnet mantle contains less Mn and higher XMg, but both core and mantle display flat Mn profiles, the contact being a sharp break. Ternary feldspar and Grt–Bt thermometry yield temperatures in the range 800–900 °C, with no systematic differences among the different microstructural domains of elliptical garnet. Based on the observed intracrystalline microstructures, the high amount of melt extraction in the rock by flattening component strain and the chemical zoning of garnet, the formation of elliptical garnet is modelled by a multistage sequence. This involves pressure solution and reprecipitation of the core, followed by post‐kinematic, partly mimetic growth of the garnet mantle.  相似文献   

11.
The eclogite facies assemblage K-feldspar–jadeite–quartz in metagranites and metapelites from the Sesia-Lanzo Zone (Western Alps, Italy) records the equilibration pressure by dilution of the reaction jadeite+quartz=albite. The metapelites show partial transformation from a pre-Alpine assemblage of garnet (Alm63Prp26Grs10)–K-feldspar–plagioclase–biotite±sillimanite to the Eo-Alpine high-pressure assemblage garnet (Alm50Prp14Grs35)–jadeite (Jd80–97Di0–4Hd0–8Acm0–7)–zoisite–phengite. Plagioclase is replaced by jadeite–zoisite–kyanite–K-feldspar–quartz, and biotite is replaced by garnet–phengite or omphacite–kyanite–phengite. Equilibrium was attained only in local domains in the metapelites and therefore the K-feldspar–jadeite–quartz (KJQ) barometer was applied only to the plagioclase pseudomorphs and K-feldspar domains. The albite content of K-feldspar ranges from 4 to 11 mol% in less equilibrated assemblages from Val Savenca and from 4 to 7 mol% in the partially equilibrated samples from Monte Mucrone and the equilibrated samples from Montestrutto and Tavagnasco. Thermodynamic calculations on the stability of the assemblage K-feldspar–jadeite–quartz using available mixing data for K-feldspar and pyroxene indicate pressures of 15–21 kbar (±1.6–1.9 kbar) at 550±50 °C. This barometer yields direct pressure estimates in high-pressure rocks where pressures are seldom otherwise fixed, although it is sensitive to analytical precision and the choice of thermodynamic mixing model for K-feldspar. Moreover, the KJQ barometer is independent of the ratio PH2O/PT. The inferred limiting a(H2O) for the assemblage jadeite–kyanite in the metapelites from Val Savenca is low and varies from 0.2 to 0.6.  相似文献   

12.
The Ordovician Kellerjochgneiss (Schwaz Augengneiss) is a polymetamorphic orthogneiss-bearing unit and is part of the Austroalpine basement nappes north of the Tauern Window. Within the Kellerjochgneiss a small, strongly deformed metapegmatite dike occurs. The pegmatite crosscuts the gneiss discordantly and contains the mineral assemblage muscovite 1,2+plagioclase+K-feldspar+chlorite+quartz+garnet 1 (Alm67–76Andr0.9–2Sps17–28Prp0.4–5)+garnet 2 (Grs36–46Alm24–32Andr8–21Sps15–17Prp0–1)±stilpnomelane±biotite±clinozoisite. The magmatic protolith assemblage is comprised of relict K-feldspar, quartz and garnet 1. Textural observations indicate that biotite and muscovite cores (muscovite 1) are either part of the magmatic- or an earlier (Variscan?) metamorphic assemblage. Geothermobarometry of the metapegmatite was done on the latest-stage (Eo-Alpine) mineral assemblage garnet 2+muscovite 2+chlorite+stilpnomelane+plagioclase+quartz. Calculations of H2O-absent intersections in the system [KCNFMAS] with the multi-equilibrium program THERMOCALC v.3.1 yielded P–T estimates of 4.4 to 6.7 kbar and 321°C to 376°C. Calculations of the P–T conditions by using the assemblage muscovite 2+chlorite+stilpnomelane+quartz yielded slightly higher pressures of 6.4 to 7.2 kbar at temperatures of 310–325°C. Correlating these P–T data with geochronological data from the neighbouring lithologies (Kellerjochgneiss, Innsbruck Quartzphyllite, Wildschönau Schists) and with structural investigations from these units indicate that the P–T estimates obtained in this investigation represent the Eo-Alpine metamorphic overprint. Hence, these unusual rocks provide important information on the Eo-Alpine P–T conditions since most samples studied from the investigated Austroalpine basement nappes north of the Tauern Window rarely contain mineral assemblages suitable for geothermobarometry.  相似文献   

13.
Garnet-biotite gneisses, some of which contain sillimanite or hornblende, are widespread within the Otter Lake terrain, a portion of the Grenville Province of the Canadian Shield. The metamorphic grade is upper amphibolite to, locally, lower granulite facies. The atomic ratio Fe2+/(Fe2++ Fe3+) in biotite ranges from 0.79 to 0.89 (ferrous iron determinations in 10 highly pure separates), with a mean of 0.86. Mg and Fe2+ atoms occupy 67–78% of the octahedral sites, the remainder are occupied by Fe3+, Ti, and Al, and some are vacant. Mg/(Mg + Fe2+), denoted X, in the analysed samples ranges from 0.32 to 0.65. Garnet contains 1–24% grossular, 1–12% spessartine and X ranges from 0.07 to 0.34. Compositional variation in biotite and garnet is examined in relation to three mineral equilibria: (I) biotite + sillimanite + quartz = garnet + K-feldspar + H2O; (II) pyrope + annite = almandine + phlogopite; (III) anorthite = grossular + sillimanite + quartz. Measurements of X (biotite) and X (garnet) are used to construct an illustrative model for equilibrium (I) which relates the observed variation in X to a temperature range of 70°C or a range in H2O activity of 0.6; the latter interpretation is preferred. In sillimanite-free gneisses, the distribution of Mg and Fe2+ between garnet (low in Ca and Mn) and biotite is adequately described by a distribution coefficient (KD) of 4.1 (equilibrium II). The observed increase in the distribution coefficient with increasing Ca in garnet is ln KD= 1.3 + 2.5 × 10?2 [Ca] where [Ca] = 100 Ca/(Mg + Fe2++ Mn + Ca). The distribution coefficient is apparently unaffected by the presence of up to 12% spessartine in garnet. In several specimens of garnet-sillimanite-plagioclase gneiss, the Ca contents of garnet and of plagioclase increase in unison, as required by equilibrium (III). The mean pressure calculated from these data (n= 17) is 5.9 kbar, and the 95% confidence limits are ±0.5 kbar.  相似文献   

14.
Petrology of high-pressure granulites from the eastern Himalayan syntaxis   总被引：36，自引：0，他引：36  
The eastern Himalayan syntaxis, situated at the eastern terminus of the Himalayas, is the least-known segment of the Himalayas. Recent research in this area has revealed that the syntaxis consists of the Gangdise, the Yarlung Zangbo, and the Himalayan units, each of which is bounded by faults. The Himalayan unit, the northernmost exposed part of the Indian plate, mainly contains amphibolite facies rocks, marked by the assemblages staurolite+kyanite+plagioclase+biotite+muscovite±sillimanite and garnet+amphibole+plagioclase, in the south; to the north, low- to medium-pressure granulite grade pelitic gneisses and marbles are present and are characterized by the assemblages garnet+sillimanite+K-feldspar+plagioclase or antiperthite+biotite+quartz±spinel±cordierite±orthopyroxene in gneisses, and anorthite+diopside±wollastonite and plagioclase+diopside+quartz+phlogopite+calcite in marbles. Within this unit, the Namula thrust system is a series of moderately north-dipping structures that displaced the granulite facies rocks southwards over the amphibolite facies rocks. High-pressure granulites occur as relics within these granulite facies rocks and contain garnet–kyanite granulite and garnet clinopyroxenite. The peak assemblage of the garnet–kyanite granulite includes garnet (core part)+kyanite+ternary feldspar+quartz+rutile. Sillimanite+garnet (rim part)+K-feldspar+ oligoclase+ilmenite+biotite and spinel+albite+biotite or spinel+cordierite±orthopyroxene, which are coronas around sillimanite and garnet, are retrograde products of this peak assemblage. Another peak assemblage includes very-high-Ca garnet (CaO 32–34 wt%, Alm10±Grs>80) and diopside (CaO 22–24 wt%), scapolite, meionite, quartz, and accessory Al-bearing titanite (Al2O3 4–4.5 wt%). The diopside has kink bands. Partial or complete breakdown of Ca-rich garnet during post-peak metamorphism produced pseudomorphs and coronas consisting of fine-grained symplectic intergrowths of hedenbergite and anorthite. Thermobarometric estimates in combination with reaction textures, mineral compositions, and recent experimental studies indicate that these peak assemblages were formed at P=c. 1.7–1.8 GPa, T =c. 890 °C, and the retrograde assemblages experienced near-isothermal decompression to P=0.5±0.1 GPa, T =850±50 °C. The whole-rock compositions indicate that marble and pelite are plausible candidates for the protoliths. These facts suggest the following (1) sedimentary rocks were transported to upper-mantle depths and equilibrated at those conditions to form these high-pressure granulites, which were then emplaced into the crust quickly. During the rapid exhumation of these rocks, the earlier high-pressure assemblages were overprinted by the later low- to medium-pressure assemblages, that is, the high-pressure granulite belt formed in the syntaxis. (2) The Namula thrust system is an important tectonic boundary in the syntaxis, or even in the Higher Himalaya more generally.  相似文献   

15.
The frequency of occurrence of minerals in 1876 samples of Sanbagawa pelitic schist in central Shikoku is summarized on the basis of microscopic observation accompanied, in part, by use of an electron microprobe. All samples contain quartz, plagioclase, phengite, chlorite and graphite. More than 90% of samples contain clinozoisite, titanite and apatite. Garnet is present in 95% of samples from the garnet zone, and biotite is present in 64% of samples from the albite‐biotite zone. Calcite is found in about 40% of samples of the pelitic schist collected from outcrop, but occurs in 95% of the pelitic schist from drill cores. Calcite was apparently ubiquitous in the pelitic schist during the Sanbagawa metamorphism, but must have been dissolved recently by the action of surface or ground water. The mineral assemblages of the Sanbagawa pelitic schist have to be analyzed in the system with excess calcite, quartz, albite (or oligoclase), clinozoisite, graphite and fluid that is composed mainly of H2O, CO2 and CH4. In the presence of calcite, reactions that produce garnet, rutile, oligoclase, biotite and hornblende, some of which define isograds of the metamorphic belt, should be written as mixed volatile equilibria that tend to take place at lower temperature than the dehydration reactions that have been proposed. The presence of calcite in pelitic schist suggests that fluid composition is a variable as important in determining mineral assemblages as pressure and temperature. Thus Ca‐bearing phases must be taken into account to analyze the phase relations of calcite‐bearing pelitic schist, even if CaO content of Sanbagawa pelitic schist is low. As calcite is a common phase, the mineral assemblages of the biotite zone pelitic schist may contravene the mineralogical phase rule and warrant further study.  相似文献   

16.
The garnet-cordierite zone, the highest-grade zone of the Ryoke metamorphic rocks in the Yanai district, SW Japan, is defined by the coexistence of garnet and cordierite in pelitic rocks. Three assemblages in this zone are studied in detail, i.e. spinel + cordierite + biotite, garnet + cordierite + biotite and garnet + biotite, all of which contain quartz, K-feldspar and plagioclase. The Mg/(Fe + Mg) in the coexisting minerals decreases in the following order: cordierite, biotite, garnet and spinel. Two facts described below are inconsistent with the paragenetic relation in the K2OFeOMgOAl2O3SiO2H2O (KFMASH) system in terms of an isophysical variation. First, garnet and biotite in the last assemblage have Mg/(Fe + Mg) higher than those in the second. Second, the first two assemblages are described by the reaction,
while they occur in a single outcrop. The addition of MnO, ZnO and TiO2 to the system can resolve the inconsistencies as follows. The assemblage garnet + biotite can consist of garnet and biotite higher in Mg/(Fe + Mg) than those in garnet + cordierite + biotite as long as they are enriched in spessartine and depleted in Al, respectively. The assemblage garnet + cordierite + biotite becomes stable relative to spinel + cordierite + biotite with increasing spessartine content or decreasing gahnite content and the Ti content of biotite. The constituent minerals of the assemblages, spinel + cordierite + biotite and garnet + cordierite + biotite, preserve several reaction microstructures indicative of prograde reactions,
and
together with retrograde reactions,
and
This suggests that the pressure-temperature path of the rocks includes an isobaric heating and an isobaric or decompressional cooling. The high-grade areas consisting of the K-feldspar-cordierite zone, sillimanite-K-feldspar zone and garnet-cordierite zone have prograde paths involving isobaric heating and show a southwards increase in pressure with a thermal maximum in the middle. These high-grade zones are closely associated with the gneissose granitic rocks, suggesting that the Ryoke metamorphism, one of the typical low-pressure type, is caused by the heat supply from the syn-tectonic granitic rocks that emplaced at the middle level of the crust. Received: 22 August 1997 / Accepted: 11 May 1998  相似文献   

17.
Glaucophane‐bearing ultrahigh pressure (UHP) eclogites from the western Dabieshan terrane consist of garnet, omphacite, glaucophane, kyanite, epidote, phengite, quartz/coesite and rutile with or without talc and paragonite. Some garnet porphyroblasts exhibit a core–mantle zoning profile with slight increase in pyrope content and minor or slight decrease in grossular and a mantle–rim zoning profile characterized by a pronounced increase in pyrope and rapid decrease in grossular. Omphacite is usually zoned with a core–rim decrease in j(o) [=Na/(Ca + Na)]. Glaucophane occurs as porphyroblasts in some samples and contains inclusions of garnet, omphacite and epidote. Pseudosections calculated in the NCKMnFMASHO system for five representative samples, combined with petrographic observations suggest that the UHP eclogites record four stages of metamorphism. (i) The prograde stage, on the basis of modelling of garnet zoning and inclusions in garnet, involves P–T vectors dominated by heating with a slight increase in pressure, suggesting an early slow subduction process, and P–T vectors dominated by a pronounced increase in pressure and slight heating, pointing to a late fast subduction process. The prograde metamorphism is predominated by dehydration of glaucophane and, to a lesser extent, chlorite, epidote and paragonite, releasing ～27 wt% water that was bound in the hydrous minerals. (ii) The peak stage is represented by garnet rim compositions with maximum pyrope and minimum grossular contents, and P–T conditions of 28.2–31.8 kbar and 605–613 °C, with the modelled peak‐stage mineral assemblage mostly involving garnet + omphacite + lawsonite + talc + phengite + coesite ± glaucophane ± kyanite. (iii) The early decompression stage is characterized by dehydration of lawsonite, releasing ～70–90 wt% water bound in the peak mineral assemblages, which results in the growth of glaucophane, j(o) decrease in omphacite and formation of epidote. And, (iv) The late retrograde stage is characterized by the mineral assemblage of hornblendic amphibole + epidote + albite/oligoclase + quartz developed in the margins or strongly foliated domains of eclogite blocks due to fluid infiltration at P–T conditions of 5–10 kbar and 500–580 °C. The proposed metamorphic stages for the UHP eclogites are consistent with the petrological observations, but considerably different from those presented in the previous studies.  相似文献   

18.
Garnet-bearing mineral assemblages are commonly observed in pelitic schists regionally metamorphosed to upper greenschist and amphibolite facies conditions. Modelling of thermodynamic data for minerals in the system Na2O–K2O–FeO–MgO–Al2O3–SiO2–H2O, however, predicts that garnet should be observed only in rocks of a narrow range of very high Fe/Mg bulk compositions. Traditionally, the nearly ubiquitous presence of garnet in medium- to high-grade pelitic schists is attributed qualitatively to the stabilizing effect of MnO, based on the observed strong partitioning of MnO into garnet relative to other minerals. In order to quantify the dependence of garnet stability on whole-rock MnO content, we have calculated mineral stabilities for pelitic rocks in the system MnO–Na2O–K2O–FeO–MgO–Al2O3–SiO2–H2O for a moderate range of MnO contents from a set of non-linear equations that specify mass balance and chemical equilibrium among minerals and fluid. The model pelitic system includes quartz, muscovite. albite, pyrophyllite, chlorite, chloritoid, biotite, garnet, staurolite, cordierite, andalusite, kyanite. sillimanite, K-feldspar and H2O fluid. In the MnO-free system, garnet is restricted to high Fe/Mg bulk compositions, and commonly observed mineral assemblages such as garnet–chlorite and garnet–kyanite are not predicted at any pressure and temperature. In bulk compositions with XMn= Mn/(Fe + Mg + Mn) > 0.01, however, the predicted garnet-bearing mineral assemblages are the same as the sequence of prograde mineral assemblages typically observed in regional metamorphic terranes. Temperatures predicted for the first appearance of garnet in model pelitic schist are also strongly dependent on whole-rock MnO content. The small MnO contents of normal pelitic schists (XMn= 0.01–0.04) are both sufficient and necessary to account for the observed stability of garnet.  相似文献   

19.
The present study from the Sausar Mobile Belt (SMB) in the southern part of the Central Indian Tectonic zone (CITZ) demonstrates how microdomainal compositional variation of a single garnet porphyroblast in a metapelite granulite sample records the different segments of a near complete P-T path of metamorphic evolution. The microdomainal variation is ascribed to the preservation of growth zoning and heterogeneous distribution of diverse inclusion mineral assemblages. Subsequent mineral reactions under changing P/T conditions were controlled by this compositional heterogeneity. Four stages of metamorphic evolution have been deciphered. An early prograde stage (Mo) is implied by the rare presence of staurolite-biotite-quartz and in places of kyanite inclusion assemblages in other metapelite samples, together with the growth zoning preserved in garnet. The peak metamorphism (M1) at ~9.5 kbar, ~850 °C is consistent with the biotite dehydration melting that produced garnet-K-feldspar and granitic leucosomes. This was followed by near isothermal decompression (M2) at ~6 kbar, ~825 °C, during which different garnet segments behaved as separate microscale bulk compositions and decomposed both internally and externally to produce different retrograde mineral assemblages. In the quartz-bearing domain of almandine-rich and grossular-rich garnet core, grossular components in garnet reacted with included sillimanite and quartz to produce coronal plagioclase (XAn=0.90). By contrast, grossular-rich garnet in quartz-absent domain reacted with included sillimanite to produce layered spinelss {XMg (Mg/Mg+Fe2+) = 0.23–0.26}, XAl (Al/Al+Fe3+)=0.71–0.81}-plagioclase (XAn=0.91)-cordierite {XMg (Mg/Mg+Fe2+) = 0.80–0.83} coronas both in the core and inner rim region of garnet. During post-decompression cooling, reactions occurred at about 600 °C (M3), whereby quartz-bearing, sillimanite-absent microdomains of pyrope-rich, grossular-poor garnet outer rim decomposed to form relatively magnesian assemblages of cordierite-anthophyllite and cordierite-biotite-quartz. M2 spinelss decomposed to polyphase domains of spinel-magnetite±högbomite at this stage. Collating the textural and geothermobarometric results, a clockwise P-T path has been deduced. The deduced P-T loop is consistent with a model of crustal thickening due to continental collision, followed by rapid vertical thinning, which appears to be the general feature of the Sausar Mobile Belt. Using model calculations of the preserved growth and diffusion zoning in garnet, we demonstrate rather short-lived nature of this collision orogeny (in the order of 40–60 Ma).Editorial responsibility: W. Schreyer  相似文献   

20.
Mineralogical and mineral chemical evidence for prograde metamorphism is rarely preserved in rocks that have reached ultrahigh‐temperature (UHT) conditions (>900 °C) because high diffusion and reaction rates erase evidence for earlier assemblages. The UHT, high‐pressure (HP) metasedimentary rocks of the Leverburgh belt of South Harris, Scotland, are unusual in that evidence for the prograde history is preserved, despite having reached temperatures of ～955 °C or more. Two lithologies from the belt are investigated here and quantitatively modelled in the system NaO–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O: a garnet‐kyanite‐K‐feldspar‐quartz gneiss (XMg = 37, A/AFM = 0.41), and an orthopyroxene‐garnet‐kyanite‐K‐feldspar quartzite (XMg = 89 A/AFM = 0.68). The garnet‐kyanite gneiss contains garnet porphyroblasts that grew on the prograde path, and captured inclusion assemblages of biotite, sillimanite, plagioclase and quartz (<790 °C, <9.5 kbar). These porphyroblasts preserve spectacular calcium zonation features with an early growth pattern overgrown by high‐Ca rims formed during high‐P metamorphism in the kyanite stability field. In contrast, Fe‐Mg zonation in the same garnet porphyroblasts reflects retrograde re‐equilibration, as a result of the relatively faster diffusivity of these ions. Peak P–T are constrained by the occurrence of coexisting orthopyroxene and aluminosilicate in the quartzite. Orthopyroxene porphyroblasts [y(opx) = 0.17–0.22] contain sillimanite inclusions, indicative of maximum conditions of 955 ± 45 °C at 10.0 ± 1.5 kbar. Subsequently, orthopyroxene, kyanite, K‐feldspar and quartz developed in equilibrated textures, constraining the maximum pressure conditions to 12.5 ± 0.8 kbar at 905 ± 25 °C. P–T–X modelling reveals that the mineral assemblage orthopyroxene‐kyanite‐quartz is compositionally restricted to rocks of XMg > 84, consistent with its very rare occurrence in nature. The preservation of unusual high P–T mineral assemblages and chemical disequilibrium features in these UHT HP rocks is attributed to a rapid tectonometamorphic cycle involving arc subduction and terminating in exhumation.  相似文献   

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