首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
Numerous previous studies indicate that several different authigenic aluminosilicates form in the oceans. In this study we show, using dissolved Al distributions in sediments and waters from the nearshore regions of the East China Sea, that the process of aluminosilicate formation probably begins rapidly upon contact of detrital clays with seawater. Statistical analyses of dissolved Al-Si-H+ relations in surface sediments indicate that the minerals forming in East China Sea sediments low in dissolved Fe are dioctahedral chlorites with an average composition EX0.91Mg0.77Al5.0Si2.7O10(OH)8 (where EX = exchangeable + 1 cation). This composition is also consistent with dissolved Al and Si measurements as a function of salinity in turbid overlying waters. Results suggest a dissolution—reprecipitation mechanism for clay mineral reconstitution. This mechanism can help to explain why different authigenic clays are found in different areas of the oceans. In the East China Sea the total amount of authigenic clays present must constitute a very minor fraction of the bottom sediments. Thus, the formation of these minerals has a relatively small impact upon dissolved Si distributions. Clay mineral reconstitution in nearshore regions may provide a mechanism for buffering sediments and overlying waters with respect to pH, as the composition of minerals formed should be a direct function of the H+ activity in the surrounding environment.  相似文献   

2.
Problem of the distribution of clay minerals in water areas of the World Ocean and their relation to different (humid, arid, and volcanosedimentary) types of lithogenesis is considered. It is shown that layer silicates can be used as index minerals for distinguishing types of lithogenesis under conditions of marine sedimentation. Humid marine lithogenesis is represented by sediments of the White, Baltic, Black, and Mediterranean seas. Genetic link of marine clay formation with soil-climatic zones is clearly manifested in recent sediments of the World Ocean. Accumulation of statistic data on the mineral composition of clays allowed us to distinguish two modes of spatial-latitudinal distribution of clay minerals: maximal concentrations of illites and chlorites are confined to high latitudes, whereas kaolinite and smectite accumulate in the equatorial zone. In the arid lithogenesis, the dependence of clay formation on drainage areas is practically absent. The whole process is realized in surficial sediments and bottom waters: under conditions of intense evaporation, especially in closed water basins, the concentration of elements in the medium is enough for the synthesis of layer silicates, such as palygorskite and sepiolite. The processes were studied based on the Paleogene Fergana Bay and bottom sediments of the Sea of Aral, as well as DSDP core materials from the Atlantic (near the western coast of Africa) and Indian (the Arabian Peninsula area) oceans. The investigation of processes of volcanosedimentary lithogenesis was carried out within the East Pacific Rise (on the basis of core materials obtained during cruises of R/V Dmitry Mendeleev and Akademik Kurchatov). The results obtained made it possible to establish authigenic (primarily celadonite) K-Fe mineralization in the most active geothermal zones. The formation of clay minerals has specific features in each of the studied (humid, arid, and volcanosedimentary) types of lithogenesis. This should be taken into consideration during the lithological investigations and the study of clay mineralogy of past geological epochs. Clay minerals (particularly, unstable mixed-layered phases) are actively used as index minerals for paleogeographic and climatologic reconstructions.  相似文献   

3.
黏土矿物古气候意义研究的现状与展望   总被引：6，自引：1，他引：5  
系统地分析了利用海洋沉积物、古土壤、湖盆沉积物中黏土矿物进行古气候环境研究的现状、存在问题和发展趋势。海洋沉积物的物源范围广,影响因素复杂,其中的碎屑黏土矿物所指示的古气候参数只能用于解释母源区的气候变化,而只有自生黏土矿物才能指示沉积区的气候;古土壤形成于特定的地质背景条件下,尤其是发育于火山物质母岩之上的风化自生黏土矿物,可以准确地指示该区的古气候条件;湖盆沉积物的物源范围小,沉积物中的黏土矿物可以更有效地运用于古气候环境的分析。对于沉积物中黏土矿物来源的分析,可以借助晶体中cv空位和tv空位的精细结构特征进行判断;在风化改造的红土剖面研究中,因强烈的化学风化、淋滤和迁移,黏土矿物方法具有独特的优势。风化过程中形成的一些亚种或过渡性黏土矿物,以及同生沉积过程中形成的黏土矿物,对气候环境的变化更加敏感,应加强这方面的研究。此外,在造山带的气候环境演化研究中,自生黏土矿物稳定同位素可以更可靠地指示气候环境的变化。  相似文献   

4.
The fluvio-tidal transition of suspended sediment in terms of mineralogy and composition in the Loire River drainage basin, the largest French river basin, was investigated in the fluvial zone at Montjean and in the tidal zone at Mauves-Thouaré, for a complete seasonal cycle. At Montjean, where the river experiences unidirectional flow, the composition and mineralogy (especially clays and clay minerals) of river suspended material (RSM) are governed by the river discharge, upstream contributions, climatic conditions and microbiological activities. However, due to reversing tidal and river currents at Thouaré, in the zone of tidal dynamics, these relations are changed. In the downstream direction sand and clay content in the RSM decrease while the silt content increases. Among clay minerals, between these two observation stations, montmorillonite remains constant, kaolinite diminishes, and the other minerals increase downstream. Combustible material (organic) and nitrate (NO3) contents in the RSM increase whereas the phosphate (PO43-) and CaCO3 contents decline considerably during transport. At the head of the tidal zone, where the river flow encounters the tidal influence, there is a relatively stationary water mass (tidal slack) where sands, clays, phosphate, carbonate and silica are deposited by physical and chemical processes. Physical sedimentation takes place by simple gravitational deposition (sands), and by sorting and complicated differential settling (clays); chemical sedimentation takes place by precipitation (calcite-CaCO3; apatite-Ca5 (PO4)3 (OH,F,Cl); coagulation of dissolved silica-SiO2) in connection with seasonal algal bloom and eutrophic events.  相似文献   

5.
The Quaternary sequence of a boring from the island of Anholt, Denmark, comprises both marine and non-marine sediments spanning a time interval from the Holocene to at least as far back as the Saalian. The oldest Quaternary sediments consist of a till and a glaciofluvial sand sequence. These are overlain by marine silty clays of Saalian to Eemian age. An interstadial (Flakket Interstadial) and a stadial (Kattegat Stadial) are identified in the late Saalian. This climatic fluctuation has been compared to the Allerød and Younger Dryas events at the Weichselian–Holocene transition. The Eemian sediments are followed by sand and non-marine, varved clay overlain by 2 m of marine clay, which is correlated with the Middle Weichselian of the Skærumhede series. The marine clay is covered by silty clay and a thick sand sequence of non-marine origin. The uppermost 2 m sediments may represent the Holocene coastal accretion on Anholt.  相似文献   

6.
In the geochemical study of sedimentation, hydrogen and oxygen isotope data are useful for a discussionon formation conditions and material sources of sediments. Hydrogen and oxygen isotope analyses were madeon clays separated from the sea-floor surface sediments at 9 stations in the western sea region of the AntarcticPeninsula. On the basis of these isotopic data and the clay mineral components and by use of statistical dia-grams, it may be concluded that the clay fraction in this sea region is composed mainly of terrigenous detritus:i.e. it was formed by surface weathering or supergene alteration of the rocks from the terrigenous region in thepeninsular in the presence of meteoric water. However, at least a part of montmorillonite is a marine authigenicmineral formed by alteration of submarine eruptive materials or terrigenous pyroclasts in the presence of seawater. The above result is consistent with the idea derived from the study of clay mineralogy.  相似文献   

7.
The geochemical study of groundwaters and core sediments from the Old Brahmaputra plain of Bangladesh was conducted to investigate the distribution of arsenic and related trace elements. Groundwaters from tube wells are characterized by pH of 6.4–7.4, dissolved oxygen (DO) of 0.8–1.8 mg/l, Ca contents of 5–50 mg/l, and Fe contents of 0.2–12.9 mg/l. Arsenic concentrations ranged from 8 to 251 μg/l, with an average value of 63 μg/l. A strong positive correlation exists between As and Fe (r 2 = 0.802; p = 0.001) concentrations in groundwater. The stratigraphic sequences in the cores consist of yellowish silty clays at top, passing downward into grayish to yellowish clays and sands. The uppermost 3 m and lower parts (from 13 to 31 m) of the core sediments are oxidized (average oxidation reduction potential (ORP) +170 and +220 mV, respectively), and the ORP values gradually become negative from 3 to 13 m depths (−35 to −180 mV), indicating that anoxic conditions prevail in the shallow aquifers of the Brahmaputra plain. Age determinations suggest that clay horizons at ~10 m depth were deposited at around 2,000 and 5,000 years BP (14C ages) during the transgressive phase of sea-level change. Elevated concentrations of As, Pb, Zn, Cu, Ni, Cr, and V are present in the silts and clays, probably due to adsorption onto clay particles. Significant concentrations of As occur in black peat and peaty sediments at depths between 9 and 13 m. A strong positive correlation between As and Fe was found in the sediments, indicating As may be adsorbed onto Fe oxides in aquifer sediments.  相似文献   

8.
Measurements of the concentration and vertical distribution of dissolved aluminium and silica, and of pH. in interstitial waters of recent marine sediments from the North Sea and the Mediterranean Sea were performed to evaluate the behaviour of aluminium during early diagenesis. The results suggest that thermodynamic equilibria alone do not control the concentrations of dissolved species in the system Al-Si-O2-H2O during early diagenesis. Rather, these concentrations are governed by dynamic factors involving mineral dissolution-precipitation reactions and diffusion.  相似文献   

9.
The alkali and alkaline earth concentrations in the Toorongo Granodiorite weathering profile are controlled by two competing processes; leaching of cations from primary minerals during their degradation to clays; fixation, by exchange and adsorption, of the same cations onto the secondary clay minerals. Degradation and leaching dominate the early weathering stages whereas during the advanced stages, exchange and adsorption onto clays are of most influence.The alkali and alkaline earth compositional changes in the Toorongo Granodiorite weathering profile are typical of changes occurring during weathering of the continents, consequently the following generalizations apply to continental weathering. Ca, Sr and Na are most rapidly and most strongly removed (as dissolved species) during weathering of fresh continental rocks. Although large quantities of Mg are transported to the marine environment as dissolved species, appreciable amounts remain (fixed in secondary clay minerals) at the weathering site to be removed during mass wasting of continental weathering profiles. Large quantities of Rb, Cs and Ba, fixed in continental weathering profiles by exchange and adsorption onto secondary clays, are transported from the continents only during mass wasting of the continents.  相似文献   

10.
This paper considers the magnetic properties of a range of recent and contemporary sediments from the north eastern part of the Irish Sea. Principal component ordinations of the results show a close link between magnetic property variations and particle size. The magnetic properties of a subset of samples, particles sized by a combination of sieving and pipette analysis, confirm that variations in ferrimagnetic (‘magnetite’) grain size parallel those in particle size, despite the fact that the magnetic grains in the fine grades have diameters 1–2 orders of magnitude smaller than those of the particle size fraction in which they occur. This is best explained by postulating that the fine magnetic grains occur in the clay fraction but are present in declining concentrations in the coarser grades up to 4ø as an artefact of the pipette method. Most samples have a biomodal distribution of magnetic minerals, with a coarse mode associated with heavy minerals in the sands or coarse silts, and a fine mode in the clays. Magnetic susceptibility (x) and saturation isothermal remanent magnetization (SIRM) largely pick out the coarse mode where present; anhysteretic remanent magnetization (ARM) largely picks out the fine mode. The results open up the possibility of normalizing samples from these environments for particle size and, more specifically, clay content, by means of ARM or ARM/x values. The most likely source for the uniform and almost exclusive stable single domain magnetite, which dominates the magnetic properties of the clays, is thought to be bacterial magnetosomes. The measurements as a whole do not appear to hold much promise for discriminating sediment source types.  相似文献   

11.
Marine silty clay deposited during the Late-Wisconsinian postglacial marine transgression of eastern Québec (Goldthwait Sea) is ubiquitous in the sedimentary column of intertidal zones of the St-Lawrence Estuary. This mud is very compact and limits the penetration of organisms composing the modern Macoma balthica community. In order to describe the characteristics of intertidal sediments containing Goldthwait Sea mud, axial tomography (CT-Scan) is used. CT-Scan is a non-destructive method that can be used to describe sediment characteristics (grain size, mineralogy, primary and secondary sedimentary structures, fabric, shape and roundness, bedding contact), and to obtain high resolution, 3D representations of structures within sediment cores. Based on differences in the densities of analysed materials, the different lithologies, lithofacies, and organisms within the core can be discriminated, and a quantification of the volume occupied by the different components of the material can be made. Here, CT-Scan images provide information on the distribution, orientation and interweaving of thanatocœnosis shell beds that alternate with massive or faintly laminated postglacial marine mud beds, as well as on ichnofacies characteristics. In addition, we show 3D images of bioturbation structures within the recent sediment layer, which is distinguished from the underlying Goldthwait Sea mud. When coupled with conventional sedimentary (grain size statistics) and radiochronological (14C) analyses, these data provide information which is valuable for identifying depositional processes within sedimentary environments.  相似文献   

12.
蒋梅茵 《沉积学报》1985,3(3):95-104
第四纪红色粘土在我国南方分布很广,最典型的分布在华中岗地上,土层较厚,上部土质均匀,下部具有红白网纹并含砾石,大都是中更新世的洪积-冲积或残积-坡积物,笔者认为可能是间冰期比较暖热气候条件下的产物。熊毅早就指出:各地环境殊异,地形复杂,母岩不同,其理化特征将随之而异。第四纪红色粘土来自不同的堆积相,和经受不同的风化和成土过程,这将在矿物组成方面反映出来。土壤普查的结果表明,第四纪红色粘土按其分布的地形部位,成因和物质来源,可分成两类:一类是残积坡积相，为中更新世较早的暗红色沉积物，即Q2另一类是冲积相，为中更新世较晚的红化程度较轻的淡红色沉积物。它们都经历了中更新世至今的成土过程1)”。为了查明它们的差异，并有助于第四纪沉积物的研究，笔者用部分标本进行矿物分析，并对初步结果进行讨论。  相似文献   

13.
The separated clay fraction (material <μ) of surface and sub-surface sediment samples from the southwestern Barents Sea is described. The partitioning of the major and minor elements within the different grain-size fractions of the sediment and between detrital and non-detrital phases demonstrates that the clay chemistry of these oxic shelf sediments is terrigenous in origin.The clays are a variable mixture of micaceous debris and illite with chloritic material, minor expandable clay and occasional kaolinite. Carbonate debris and amphibole occur locally. The semi-quantitative analysis suggests the existence of a considerable variation in the relative content of the principal mineralogical components and this is confirmed by the investigation of the major and minor elements. The terrigenous chemistry provides a more sensitive index of clay variability and allows the recognition of three distinct petrographic provinces.  相似文献   

14.

Background  

Early diagenetic processes involved in natural organic matter (NOM) oxidation in marine sediments have been for the most part characterized after collecting sediment cores and extracting porewaters. These techniques have proven useful for deep-sea sediments where biogeochemical processes are limited to aerobic respiration, denitrification, and manganese reduction and span over several centimeters. In coastal marine sediments, however, the concentration of NOM is so high that the spatial resolution needed to characterize these processes cannot be achieved with conventional sampling techniques. In addition, coastal sediments are influenced by tidal forcing that likely affects the processes involved in carbon oxidation.  相似文献   

15.
《Geodinamica Acta》2013,26(5-6):259-272
The contents and the distribution of clay minerals in modern sediments of the Cadiz bay and the continental shelf have been studied aiming to establish the sedimentary exchange model and the pathways followed by the clay fraction between the bay and the adjoining continental shelf. The most abundant clay minerals in the muddy sediments consist mainly of illite, smectite, interstratified illite-smectite, kaolinite and chlorite. The application of factor analysis method (PCA) to clay minerals data are considered to be useful in the determination of sedimentary transport patterns. The data from clay mineral assemblages, and their distribution map, make possible to establish the fine sediments transport paths in the study area using clay mineral as natural tracers. This model of transport takes in consideration the facies distribution, the supplies sources and the way of fine sediments are incorporated to the marine environment.

Two flows paths have been established: the outflows coming from Cadiz bay and the littoral zones; and the inflows coming from external marine zones of the bay. These flows are controlled by tidal currents and the morphology of the coast. The action of surge and the marine currents, specially the Atlantic Surface Water flow, are also important in the transport of fine sediments coming from sources located to the north of the study zone.  相似文献   

16.
Torrance (1983) has recently reviewed factors producing high sensitivity in clayey sediments and proposed a general model for quick clay development. He suggested that the mineralogical requirement for quick clay behaviour to develop is that low activity minerals must predominate in the sediment. This is also the essential mineralogical requirement of the inactive-particle, short-range-bond hypothesis of high sensitivity (Smalley, 1971, 1972a, 1976; Cabrera & Smalley 1973; Smalley, Ross & Whitton, 1980). The predominance of low activity minerals causes most of the interparticle bonds to be of the short-range variety which allow/promote the'quick' behaviour—the transition from solid to liquid. In Canadian or Scandinavian quick clays the short-range bond requirement is largely met by the abundance of finegrained primary mineral particles. The very sensitive clays involved in the Tauranga landslide in New Zealand (Smalley et al ., 1980) owed their sensitivities to their content of inactive spheroidal halloysite particles. By many definitions the Tauranga material is a quick clay and its existence provides us with another window through which to view the quick clay problem. Torrance observed that for a quick clay to develop the sediment must have an open structure with a high void ratio. In a classic Canadian quick clay this structure is obtained by the slow sedimentation of fine particles in the salty Champlain Sea; in the Tauranga soil an open structure is obtained by air-fall sedimentation of the initial volcanic particles.  相似文献   

17.
A total of 402 coastal sea-sediment samples were collected from the continental shelf, slope, and basin off Tsushima Island in the western Sea of Japan, and were analyzed for 51 elements as part of a nationwide marine geochemical mapping project. The samples were compared to potentially related sample sets, and the results were considered from the viewpoint of the origin of marine surface sediments in the western Sea of Japan. The spatial distribution of elemental concentrations in the coastal sea sediments correspond to texture, grain size, the presence of shells and foraminifera, and the mud content of surface marine sediments. Most elemental concentrations increased with increasing mud content. Some samples located in littoral areas included sediment particles apparently supplied from nearby rivers, but their contribution was limited. Overall, the mean chemical compositions of clastic material in coastal sea sediments appear to differ from those of stream sediments in adjacent terrestrial areas. In addition, the geochemistry of the coastal sea sediments cannot be fully explained by the mixing of the material supplied from Korean and Chinese stream sediments, which are the most feasible sources. Coastal sea sediments in the study area are well mixed by transportation processes; therefore, elemental abundances in these marine sediments may be homogenized to such an extent that it is not possible to determine their origin. Alternatively, most of the clastics in the sediment may actually represent relict reworked material, originally formed in the Yellow Sea and Tsushima Strait during the last glacial stage and subsequent transgression.  相似文献   

18.
Clay mineralogy of Triassic sediments in southern Israel and Sinai   总被引：1，自引：0，他引：1  
The clay mineral composition of Triassic sediments in the Negev and Sinai depends upon the environment of deposition. Kaolinite predominates in continental and epicontinental sediments. The mineralogical composition of the marine clays resembles that of corresponding samples from North Africa and Europe, which comprise various mixtures and interstratifications of illite, montmorillonite, vermiculite and chlorite. Evaporitic sediments are poor in clay minerals and those present are largely detrital. The results presented suggest that chlorite was formed diagenetically by prolonged percolation of seawater through pervious layers overlying impervious ones (hard beds).  相似文献   

19.
《Applied Geochemistry》1999,14(5):559-568
Salt marshes are the major areas for net sedimentation in many estuaries such as the Delaware Bay, and their diagenetic chemistry is harsh and extreme with large seasonal excursions in chlorinity (1–50 ppt), pH (4–6), and Eh (−240+120). Such diagenesis is driven by organic matter decomposition using redox cycles of S and Fe materials imported primarily as tidal sea water SO4 and Fe silicates, respectively.Important and quantitative changes in clay mineralogy occur within a decade at the redox boundary in a high marsh sediment near Lewes, Delaware. The clay mineralogy consists initially of a micaceous illite and chlorite mixture accumulating at the salt marsh surface. It is comprised of relic glacial sediments deposited on the continental slope during their net tidal movement from the sea to land. Once buried, these detrital clays are transformed into a new assemblage containing an illite/smectitic mixed layer mineral of poor crystallinity. Using curve decomposition techniques on complex X-ray traces, it is estimated that this new phase constitutes 45–55% of the clay fraction.The redox boundary where the sharp transition occurs is only about 20 a old as determined by 210Pb and 137Cs geochronology, and, thus, the clay mineral transformation is rapid. The occurrence of the new, abundant clay mineral is very abrupt (less than 1 cm at 12 cm in depth) and, thus, may itself occur in as little as three years. Once formed, the new mixed layer phase remains stable during the subsequent 40 a of burial from the time of formation at the oxic/anoxic boundary.Slow transformations of unstable primary clay reactants such as illite and chlorite are a common process of soil formation. However such rapid clay reactions have rarely been documented in either subaerial or submerged soil settings. The formation of a smectite mineral product of high chemical reactivity for a significant portion of the clays in a soil is unusual. In fact, the abrupt change in clay mineralogy in the salt marsh occurs precisely at the sharp evolution in salt marsh geochemistry from oxidized to reducing conditions where there is extensive redox cycling of Fe and S phases. A large seasonal oscillation in interstitial pH and Eh probably contributes to the rapid clay transformation. Such clay transformations may have important implications for the retention of other trace elements entering the salt marsh by atmospheric fallout and tidal cycles, or the release of such metal inventories after burial.  相似文献   

20.
The specific mineralogy of clay grain coats controls the ability of the coat to inhibit quartz cementation in sandstones during prolonged burial and heating. How and why clay‐coat mineralogy varies across marginal marine systems is poorly understood, even though these eogenetic phenomena strongly influence subsequent mesodiagenesis and reservoir quality. The novel development of the ability to predict the distribution of clay‐coat mineralogy would represent an important development for sandstone reservoir quality prediction. In marginal marine sediments, clay minerals occur as grain‐coats, floccules, mud intraclasts, clay‐rich rock fragments or as dispersed material. However, the relationships between clay mineralogy, the amount of clay, and its distribution is poorly understood. This study focused on the Ravenglass Estuary, UK. The key aim was to develop and apply a novel methodology utilising scanning electron microscope – energy dispersive spectrometry, for the first time, on grain coats in modern sediments, to differentiate the clay‐coat mineral signature from that of the bulk sediment, and reveal the distribution of clay minerals across marginal marine sediments. The study showed that marginal marine sediments principally have their clay mineral assemblage present as clay‐coats on sand grains. These clay‐coats have a mixed clay mineralogy and are spatially heterogeneous across the range of marginal‐marine depositional environments. The study further showed that clay‐coat mineralogy is governed initially by the hydrologically‐controlled segregation of the clay minerals within inner estuarine depositional environments, and subsequently by the selective abrasive removal of specific clay mineral types during reworking and transport into the outer estuary and the marine environment. The highest relative abundance of grain‐coating chlorite was in sand‐flat and tidal‐bar depositional environments. The availability of an analogue data set, and an understanding of the controlling processes of clay‐coat mineralogy, offer crucial steps in building a predictive capability for clay‐coat derived elevated reservoir quality in deeply buried sandstones.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号