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1.
Monitoring of municipal wells near the town of Sidney and domestic wells near Oshkosh in Nebraska's Panhandle indicated the nitrate-nitrogen (NO3-N) levels were increasing and exceeded the maximum contaminant level of 10 mg/l NO3-N in several wells. Both areas are located in narrow stream valleys that are characterized by well-drained soils, highly permeable intermediate vadose zones, shallow depths to groundwater, and intensive irrigated corn production. Both areas also have a large confined cattle feeding operation near the suspected contamination and potentially could be contaminated by more than on nitrate source.At Sidney NO3-N concentrations were measured in 13 monitoring wells installed along an east-west transect im the direction of groundwater flow, 26 private wells, and eight municipal wells. Nitrate-nitrogen concentrations were homogeneous beneath a 5 km by 1.2 km area and averaged 11.3 ± 1.8 mg/l NO3-N. The δ15N-NO3 values in the monitoring and municipal wells had a narrow range from +5.8 to +8.8%. The isotopic ratios are indicative of a mixed source of nitrate contamination, which originates from agronomic (commercial fertilizer N and mineralized N) N and animal waste. Both commercial fertilizer N and animal wastes are applied to the irrigated fields.Nitrate-nitrogen concentrations in two multilevel samplers installed downgradient from irrigated cornfields at the Oshkosh site averaged 20.1 ± 13.3 mg/l NO3-N and 37.3 ± 8.2 mg/l NO3-N. The δ15N-NO3 values spanned a narrow range from +3.5 to +5.9% and averaged +4.0 ± 0.5% and +5.0 ± 0.6%. These low values are indicative of leachates from commercial fertilizer applied to the irrigated fields.  相似文献   

2.
Impacts of land use changes and groundwater management actions on groundwater quality were evaluated at the island scale with spatiotemporal trends of NO3-N and Cl concentrations in groundwater of Jeju Island, Korea. The temporal trends from 1993 to 2012 in the concentrations of NO3-N and Cl from more than 3900 wells were estimated using the Mann–Kendall trend test and Sen’s slope analysis and compared with the land use change trend for the period 1995–2009. The results indicate that the upward trends in NO3-N were associated with the expansion of agricultural lands, whereas Cl trends were considered to be affected by other factors in addition to the land use changes. In the mid-mountainous region, the deterioration in the groundwater quality by the both NO3-N and Cl was expected due to the continuous expansion of agricultural lands. In the lowland area, the NO3-N and Cl components showed different trends depending on the regions. In the eastern area, increasing trends in NO3-N were observed due to the development of new agricultural areas, while the Cl concentration was observed to decrease as a result of the regulation on groundwater extraction to reduce seawater intrusion. Our study highlights that a comprehensive interpretation of trends in NO3-N and Cl and land use changes for long-term periods can provide useful insights to prepare for suitable groundwater management plans in the whole island perspective.  相似文献   

3.
High contents of nitrate in groundwater, ranging up to 1,500 mg/l, have been found. High concentrations are more common in village wells than in irrigation wells situated in the fields. The losses of nitrogen from the soil zone through deep leaching into the groundwater are small (260 kg N/km2); however, due to a small net infiltration (29 mm/year), the median content in groundwater still approaches the permissible limit of 50 mg/l NO 3 ? . In villages about 10–20% of the nitrogen from excreta are leached into the groundwater. Mineralization of soil nitrogen during a dry period, followed by heavy rains, caused extremely high contents of nitrate in groundwater.  相似文献   

4.
Geographical information system (GIS) technology was used to investigate NO3 − concentration of groundwater in the Zhangye Basin, Northwest China. Thematic information and NO3 − data of groundwater from the Zhangye Basin were analyzed in a GIS environment to study the extent and variation of NO3 − concentration and to establish spatial relationships with corresponding land use types. About 38.8% of groundwater samples showed NO3 − concentration above the human affected value (13 mg/l NO3 −), while more than 10.2% exceeded the maximum acceptable level (50 mg/l NO3 −) according to WHO regulations. The spatial distribution of NO3 − of groundwater in the Zhangye Basin showed an obvious character of zonation; the high NO3 − concentration was mainly located in the city seat areas, and Zhangye City was the high-value center. The probability of over 90% for NO3 − concentration exceeding 13 mg/l was found in urban seat areas. The spatial analyses indicated that groundwater contamination by NO3 − was closely related to one specific land use class, the urban. The NO3 − concentration of groundwater under urban was significantly higher than that under irrigation land or sand dune. Most of the unacceptable NO3 − levels were found in groundwater samples assigned to urban area, but a few were also found allotted to irrigation land class. Therefore, urban source was considered the principal source of NO3 − contamination of groundwater in the Zhangye Basin, while irrigation land source was still a possible source of NO3 − contamination.  相似文献   

5.
In order to assess the extent of groundwater contamination by nitrate (NO3 −–N) and to provide information about the deterioration of the groundwater quality in Zhangye Oasis, Northwest China, a study was conducted in this area. The mean value of NO3 −–N concentrations in groundwater samples was 10.66 ± 0.19 mg l−1. NO3 −–N concentrations exceeding 10 mg l−1 (the threshold for drinking water set by the World Health Organization) were found in 32.4% of 71 wells, and were 13, 33.3, 52.4 and 50.0% in the groundwater samples from drinking wells, irrigation wells, hand-pumping wells and groundwater table observation wells, respectively. The result showed that the groundwater samples that had NO3 −–N concentrations exceeding the threshold for drinking water were mostly collected from a depth of less than 20 m. Groundwater NO3 −–N concentrations in areas used for the cultivation of vegetables, seed maize and intercropped maize were significantly higher than those in urban or paddy areas. NO3 −–N contamination of groundwater in areas with sandy soil was more severe than in those with loam soil.  相似文献   

6.
High nitrate concentrations, above the WHO guideline of 50 mg l−1, were observed in samples of shallow wells reaching the Yeumbeul suburb (Senegal) area groundwater. This groundwater is exploited by 7000 houses and therefore there are health implications. Correlations between parameters such as nitrate content (NO3−) in the groundwater and soil water, the distance between shallow wells and family latrines, and soil water chloride (Cl−) and colon bacillus content led to two possible sources of groundwater pollution: first, contamination by non impervious and shallow latrines; and second, the leaching of soil NO3− from waste organic matter carried in groundwater.  相似文献   

7.
The Kingston Basin in Jamaica is an important hydrologic basin in terms of both domestic and industrial sector. The Kingston hydrologic basin covers an area of approximately 258 km2 of which 111 km2 underlain by an alluvium aquifer, 34 km2 by a limestone aquifer and the remainder underlain by low permeability rocks with insignificant groundwater resources. Rapid development in recent years has led to an increased demand for water, which is increasingly being fulfilled by groundwater abstraction. A detailed knowledge of the water quality can enhance understanding of the hydrochemical system, promoting sustainable development and effective management of groundwater resources. To achieve this, a hydrochemical investigation was carried out in the Kingston Basin. Results showed that the water is Na–Ca–Cl–HCO3 and Na–Ca–HCO3 type with higher concentrations of nitrate, sodium and chloride as the leading causes of contamination in most of the wells. High concentrations of nitrate correlate with wells from areas of high population density and could be attributed to anthropogenic causes, mainly involving improper sewage treatment methodologies or leaking sewer lines. Jamaica, owing to its island nature, has the continuous problem of saline water intrusion, and this is reflected in the higher levels of chloride, sodium and conductivity in the water samples collected from the wells. The wells studied show higher concentrations of chloride ranging from around 10.2 mg/l in wells located approximately (4931.45 m) from the coast to around 234 mg/l in the well located near to the coast. The conductivity values also closely correlate with the chloride levels found in the wells.  相似文献   

8.
The present work has been carried out in Moradabad, one of the important cities in the state of Uttar Pradesh. The main focus of the study is to estimate the extent of anthropogenic contamination in shallow groundwater of the area. For this purpose, total 188 groundwater samples collected from handpumps in pre- and post monsoon period of 2012 and 2013 (47 in each season) were analyzed for physico-chemical parameters such as pH, EC, TDS, major cations (Ca, Mg, Na, and K) and anions (Cl, HCO3, SO4, NO3 and F). The results of the analysis suggested that groundwater is slightly alkaline, hard to very hard in nature, average TDS values were found to be more than 1000 mg/l, which gives a clear evidence of anthropogenic influences. To estimate the extent of contamination, the information on relatively unpolluted groundwater systems occurring in different terrains including Ganga plain where the groundwater was relatively unaffected by anthropogenic activities is used. The estimated pristine chemical composition of groundwater of different terrains used in the present study was compared with the groundwater of Moradabad city. This comparison showed that Moradabad city with the highest Na, K, Cl, SO4 and NO3 values being 440 mg/l, 96 mg/l, 537 mg/l, 537 mg/ l and 244 mg/l, respectively, is one of the most polluted urban centres within the Ganga plain. It may be suggested that values of > 50 mg/l for Na, > 10 mg/l for K, > 25 mg/l for Cl, > 50 mg/l for SO4 and > 10 mg/l for NO3 have their respective sources in anthropogenic activities such as agricultural in the peripheral region, human and animal wastes, leakages from drains and septic tanks, landfill leachates and industrial effluents.  相似文献   

9.
A diagnosis of the groundwater quality of 70 wells sampled during two climatic regimes (dry and raining seasons) from a semiarid area in Rajasthan, India, had been carried out using standard methods. Analysis of the results for various hydrochemical parameters wherein the geological units are alluvium, quartzite and granite gneisses showed that all the parameters did not fall within the World Health Organisation’s acceptable limits for irrigation and drinking water purposes. The order of major cations and anions obtained during the dry and raining seasons are Na+ ? Mg2+ ? Ca2+ ? K+ and Cl?? HCO3 ? ? SO4 2?? CO3 ?> F? ? NO3 ?, respectively. A maximum value of nitrate of 491.6 mg/l has been examined and its contamination is due to discriminated highly impacted groundwater samples by agricultural activity and small-scale urbanization. Fluoride (F?) concentration is 6.50 mg/l as a maximum value, whereas values in about 26 % of the samples are more than the permissible limit (1.5 mg/l) for drinking water. The cumulative probability distributions of the selected ions show two individual intersection points with three diverse segments, considered as regional threshold values and highly impacted threshold values for differentiating the samples with the effects of geogenic, anthropogenic and saline water mixing. The first threshold values indicate the background hydrochemical constituents in the study area. The second threshold value of 732 mg/l for bicarbonate indicates that sandy aquifer is being dissolved during wet period, whereas NO3 ? concentration of more than the initial threshold value (=75 mg/l) indicates discriminated highly impacted groundwater samples by agricultural activity and urbanization in dry season. Various parameters such as soluble sodium percentage (SSP), salinity (electrical conductivity (EC)), sodium adsorption ratio (SAR), residual sodium carbonate (RSC), Kelley’s ratio (KR), permeability index (PI), residual sodium bicarbonate (RSB) and magnesium absorption ratio (MAR) for the well samples show that, overall, 46 % of groundwater samples are not suitable for irrigation. Further, chloro-alkaline indices (CAIs) were used for distinguishing regional recharge and discharge zones whereas corrosivity ratio (CR) utilized for demarcating areas to use metallic pipes for groundwater supply. In general, groundwater quality is mainly controlled by the chemical weathering of rock-forming minerals. The information obtained represents a base for future work that will help to assess the groundwater condition for periodical monitoring and managing the groundwater from further degradation.  相似文献   

10.
The concentrations of fluorine in groundwater of North Jordan range from 0.009 to 0.055 mg/l. Other chemical parameters, e.g. pH, EC, TDS, Cl, TH, HCO3, PO4, SO4, NO3, NH4, K, Ca, Mg, and NO3 have been studied and showed higher concentrations in HCO3− and NO3− of 307 and 51 mg/l, respectively. Thermodynamic considerations show that almost all the analyzed samples are undersaturated with respect to calcite and fluorite. This undersaturation is probably due to their low availability in the locations. Fluoride concentration shows a positive relation to pH and HCO3, whereas Cl, Mg, Ca, and Na initially increase and then decrease with increasing fluoride in the water. Saturation indexes of fluorite and calcite are estimated. The chemistry of the groundwater is controlled by the fluorite and calcite solubility. The topography of the area has exerted control on the aerial extent of fluoride concentration.  相似文献   

11.
Agricultural activities impact on groundwater nitrate pollution   总被引：1，自引：4，他引：1  
Concern over agricultural diffuse pollution sources in integrated water quality management has been growing recently. High nitrogen fertilizers application rates may increase the potential groundwater pollution. These effects were investigated in Andimeshk and Susa plains that cover an area of 1100 km2 between the Dez and Karkhe rivers in north of Khozestan-Iran. This region divided to 4 sub-regions A, B, C, and D. Additionally 168 groundwater samples were collected from 42 water wells during the months April, May, August, and September of 2004. The Hackspectrophotometer nitrate test was used to measure the NO3 ? concentration in water samples. Information about further nitrate data was obtained. A questionnaire procedure was used for collection N-fertilizers application rate data in studied area. The results demonstrated that all of the groundwater samples have NO3 t- concentration below the EPA MCL (44.27 mg/l) and WHO guideline (50 mg/l). The mean nitrate concentrations are 16.1, 19.5, 13.3, and 7.9 mg/l in sub-regions A, B, C, and D respectively. There are different amount of N-fertilizers applied in sub-regions A, B, C, and D. Correlation between NO3t- concentrations and N-fertilizers rate suggests a inverse correlation between Nfertilizers application rate and ground waters nitrate concentrations in studied area (r=?0.69).  相似文献   

12.
The paper describes the degradation of the groundwater resources in the Cecina area, where seawater intrusion, B contamination and NO3 pollution are all affecting the heavily exploited Pleistocene aquifer. Over-pumping has brought water levels to about 0 m.a.s.l. as far as about 7 km from the shore line, thereby promoting the seawater intrusion. The intrusion, which is characterized by cation exchange phenomena and Ca–Cl type waters, enters the plain mostly through the shallower horizons. The saline front, which advanced from 0.5 to 1 km in 4 a, has by now reached the foot of the hills to the east of the town, where it is also affecting wells of the local aqueduct. Boron contamination, linked to past discharge of industrial waste transported downstream by the river, reached concentrations as high as 3.5 mg/L in the mid-1980s. Although a decreasing trend is now under way, B content is still close to 1 mg/L. The presence of high NO3, which, together with the seawater intrusion, represents a major issue for groundwater management in the area, is linked to the widespread utilization of fertilizers. Nitrate concentration, which reaches a maximum of about 300 mg/L in the shallow aquifer horizons and then decreases rather regularly with depth, is strongly influenced by precipitation. However, irrigation also contributes significantly to transporting the NO3 contamination to depth, as clearly shown by δ18O data. The severe decline in the quality of the groundwater resource in the Cecina area is further compounded by an overall decrease in water availability in the region of Tuscany, as evidenced by long-term monitoring of precipitation and fluvial discharge.  相似文献   

13.
Irrigation in semi-arid agricultural regions can have profound effects on recharge rates and the quality of shallow groundwater. This study coupled stable isotopes (2??, 18O), age-tracers (3H, CFCs, 14C), 87Sr/86Sr ratios, and elemental chemistry to determine the sources, residence times, and flowpaths of groundwater and agricultural contaminants (e.g. NO 3 ?C ) in the Saddle Mountains Basalt Aquifer in central Washington, USA, where over 80% of the population depend on groundwater for domestic use. Results demonstrate the presence of two distinct types of water: contaminated irrigation water and pristine regional groundwater. Contaminated irrigation water has high NO 3 ?C concentrations (11?C116? mg/l), 87Sr/86Sr ratios (0.70659?C0.71078) within range of nitrogen-based fertilizers, detectable tritium (2.8?C13.4 TU), CFC ages 20?C40?years, high ??18O values (?16.9 to ?13.5??), and ??100 percent modern 14C. Pristine regional groundwater has low NO 3 ?C concentrations (1?C5? mg/l), no detectable tritium (??0.8 TU), low ??18O values (?18.9 to ?17.3??) and 14C ages from ??15 to 33?ky BP. Nitrogen and oxygen isotopes of NO 3 ?C , combined with high dissolved oxygen values, show that denitrification is not an important process in the organic-poor basalt aquifers resulting in transport of high NO 3 ?C irrigation water to depths greater than 40?m in less than 30? years.  相似文献   

14.
Moisture samples obtained from unsaturated-zone profiles in sands from northern Nigeria were used to obtain recharge estimates using the chloride (Cl) mass-balance method and to produce records of past recharge and climatic events. Recharge rates range from 14–49 mm/year, on the basis of unsaturated-zone Cl values and rainfall chemistry measured over eight years at three local stations. The unsaturated-zone results also provide a record of the changing recharge and climatic events of the past 80 years; this record compares quite well with modelling results using precipitation data from Maiduguri, especially for the late 20th-century period of drought. The best fit for the model is made, however, by using a lower mean rainfall Cl (0.65 mg/l) than that obtained from the mean of the field results (1.77 mg/l Cl). This result implies that the measured rainfall Cl probably overestimates the depositional flux of Cl, although the lower value is comparable to the minimum of the measured rainfall Cl values (0.6 mg/l Cl). Recharge estimates made using these lower Cl values range from 16–30 mm/year. The spatial variability was then determined using results from 360 regional shallow wells over 18,000 km2. Using the revised rainfall estimate, the Cl balance indicates a value of 43 mm for the regional recharge, suggesting that either additional preferential flow is taking place over and above that from the vadose one, or that the regional recharge represents inputs from earlier wetter periods. These recharge estimates compare favourably with those from hydraulic modelling in the same area and suggest that the recharge rates are much higher than values previously published for this area. High nitrate (NO3) concentrations (NO3-N>Cl) preserved under aerobic conditions in the vadose zone reflect secondary enrichment from N-fixing vegetation, as occurs elsewhere in the Sahel. Electronic Publication  相似文献   

15.
High water demand for domestic use in Douala with over 3 million inhabitants is met mainly by shallow groundwater. Field measurements and water sampling in January 2015 were carried out to examine the major controls on the groundwater composition and spatial view of ions in the water, timing of recharge and link between the recharge process and quality of the water. Fifty-two water samples were analysed for major ions and stable hydrogen and oxygen isotopes. Low pH values (3.61–6.92) in the groundwater indicated an acidic aquifer; thus, prone to acidification. The dominant water type was Na–Cl. Nitrate, which exceeded the WHO guide value of 50 mg/l in 22% of the groundwater, poses a health problem. Mass ratios of Cl?/Br? in the water ranged from 54 to 3249 and scattered mostly along the mixing lines between dilute waters, septic-tank effluent and domestic sewage. A majority of the samples, especially the high NO3 ? shallow wells, clustered around the septic-tank effluent-end-member indicating high contamination by seepage from pit latrines; hence, vulnerable to pollution. Stable isotopes in the groundwater indicated its meteoric origin and rapid infiltration after rainfall. The δ18O values showed narrow ranges and overlaps in rivers, springs, open wells and boreholes. These observations depict hydraulic connectivity, good water mixing and a homogeneous aquifer system mainly receiving local direct uniform areal recharge from rainfall. The rapid and diffused recharge favours the leaching of effluent from the pit toilets into the aquifer; hence, the high NO3 ? and Cl? in shallow wells. Silicate weathering, ion exchange and leaching of waste from pit toilets are the dominant controls on the groundwater chemistry. Drilling of deep boreholes is highly recommended for good-quality water supply. However, due the hydraulic connection to the shallow aquifer, geochemical modelling of future effects of such an exploitation of the deeper aquifer should support groundwater management and be ahead of the field actions.  相似文献   

16.
The Silurian bedrock aquifer constitutes a major aquifer system for groundwater supply across the Ontario province in Canada. The application of natural and industrial fertilizers near urban centers has led to groundwater NO3−-N concentrations that sometimes have exceeded the drinking water limit, posing a threat to the usage of groundwater for the human consumption. Therefore, there is a growing interest and concern about how nitrate is being leached, transported and potentially attenuated in bedrock aquifers. This study assesses the local distribution of groundwater NO3− in the up-gradient area of two historically impacted municipal wells, called Carter Wells, in the City of Guelph, Canada, in order to evaluate the potential nitrate attenuation mechanisms, using both groundwater geochemical and isotopic analysis (3H, δ15N-NO3, δ18O-NO3, δ18O-SO4, δ34S-SO4) and a detailed vertical hydrogeological and geochemical bedrock characterization. The results indicate that probably the main source of nitrate to the Carter Wells is the up-gradient Arkell Research Station (ARS), an agricultural research facility where manure has been historically applied. The overburden and bedrock groundwater with high NO3 concentrations at the ARS exhibits a manure-related δ15N and δ18O signature, isotopically similar to the high nitrate in the down-gradient groundwater from domestic wells and from the Carter Wells. The nitrate spatial distribution appears to be influenced and controlled by the geology, in which more permeable rock is found in the Guelph Formation which in turn is related to most of the high NO3− groundwater. The presence of an underlying low permeability Eramosa Formation favors the development of oxygen-depleted conditions, a key factor for the occurrence of denitrification. Groundwater with low NO3−-N concentrations associated with more oxygen-limited conditions and coincident with high SO42− concentrations are related to more enriched δ15N and δ18O values in NO3− and to more depleted δ34S and δ18O values in SO42−, suggesting that denitrification coupled with pyrite oxidation is taking place. The presence of macro crystalized and disseminated pyrite especially in the Eramosa Formation, can support the occurrence of this attenuation process. Moreover, based on tritium analysis, some denitrification can occur in shallow bedrock and within relatively short residence times, associated with less permeable conditions in depth which facilitates oxygen consumption through sulfide oxidation. The role of denitrification mediated by organic carbon cannot be discarded at the study site. This study suggests that the geological configuration and particularly the presence of low permeability Eramosa Formation can play an important role on nitrate natural attenuation, which may serve as a decision factor on defining the bedrock water supply system for both domestic and municipal purposes.  相似文献   

17.
One of the important indicators to show the quality of water for drinking and irrigation is nitrate values in water and soil. Nitrate enters surface water and groundwater through degradation and decomposition of human and animal wastes, industrial productions, and agricultural runoff. The present paper focuses on the concentration of nitrite (NO2 ?1) and nitrate (NO3 ?1) of the groundwater in Taft region, Central Iran. Sixty-one samples of the region’s aqueducts, wells, and springs were collected in September 2008 and May 2009 and analyzed by ICP-MS method. However, distribution maps of nitrate and nitrite and their frequency diagram in the pertinent samples have been generated. Then, they were compared to the US Environmental Protection Agency (EPA) and WHO international standards. The mean of nitrate content measured in the samples was 18.52 mg/l, maximum was 115 mg/l which is higher than the EPA standard (i.e., 10 mg/l), and the mean of nitrite content was about 0.06 mg/l. According to the distribution maps, concentration of these anions is high in the downstream of settlements and farmlands of Taft region. With respect to the penetration of agricultural wastes, flooding irrigation, thin layer of alluvium, sandy texture, and the amount of fertilizer consumed in the region, and also absence of any natural source for these anions and absence of the major industrial activities in the region to produce sewage, it seems that nitrate and nitrite originated from the agricultural sewage and human waste. As the content of nitrate in drinking water in the region is higher than WHO and EPA standards, so there is the risk of methemoglobinemia disease in infants. In addition, nitrate content within the stomach and lungs interacts with amine and nitrosamines are made up which are potentially the initial cause of all cancers in human.  相似文献   

18.
Impacts of irrigation with treated wastewater effluents on soils and groundwater aquifer in the vicinity of Sidi Abid Region (Tunisia) are evaluated. The groundwater aquifer was monitored by several piezometers, where monthly water levels were registered and groundwater salinity was evaluated. This resulted in characterizing the spatial and temporal evolution of the hydrochemical and hydrodynamic properties of the aquifer, showing thereby the impact of artificial recharge. Piezometric maps for pre-recharge and post-recharge situations were developed and a comparison study of both piezometric situations was considered. The piezometric evolution map showed a generalized rise of the piezometric level in the vicinity of the irrigation zone. The extent of recharge was shown to increase with time as the groundwater level increase, which was localized in the vicinity of the irrigation area, reached more extended zones. Several groundwater samples were withdrawn from wells and piezometers and analyzed. Examining the corresponding physical and chemical parameters showed an increase in the concentrations of nutrients (28 mg/l for NO3 and 3.97 mg/l for NH4) in the groundwater aquifer below the irrigation zone, which confirms again the infiltration of treated wastewater effluents. The evolution of soil salinity was examined through chemical analysis of soil samples. Electric conductivities of soils were generally shown to be less than 4 mS/cm while the irrigation water has an electric conductivity that may reach 6.63 mS/cm. This might be explained by the phenomenon of dilution and the capacity of soils to evacuate salts downward.  相似文献   

19.
Water samples from 72 wells tapping the Jilh aquifer were collected and analyzed for 10 different water quality parameters. Using these data, a regional irrigation water quality was assessed using three techniques: (i) United States Department of Agriculture method (USDA), (ii) Food and Agriculture Organization (FAO) guidelines for water quality assessment, and (iii) Water-Types approach. The USDA method revealed that the aquifer water salinity, as represented by electrical conductivity, ECw, ranges from high salinity (C3: ECw > 0.75–2.25 dS/m) to a very high salinity (C4: ECw > 2.25 dS/m). The sodium adsorption ratio (SAR) varied from low (S1) to very high (S4) sodicity. Therefore, the water of the Jilh aquifer is dominantly of the C4–S2 class representing 56% of the total wells followed by C4–S1, C4–S3, C3–S1 and C4–S4 classes at 19%, 14%, 8%, and 3% of the wells respectively. The FAO system indicated moderate to severe restriction on the use for irrigation and slight to moderate ion toxicities for Na+, Cl−, B+, NO3− and HCO3−. It is clear that, both USDA and FAO systems condemn the Jilh groundwater as hazardous for irrigation due to its high salt content, unless certain measures for salinity control are undertaken. The dominant salt constituents in the water are Mg–Cl2, Na–Cl and Ca–Cl2 as per the Water-Types method. However, due to the complexity in classifying the aquifer groundwater for irrigation, a simplified approach acknowledging three class groups (I-suitable water, II-conditionally suitable water and III-unsuitable water) adopted from the three methods, is suggested in this paper. The simplified approach combines C–S classes of the USDA method among these three groups according to the lowest ratings. The salinity of the FAO method has been split arbitrarily into slight and moderate subclasses with values of 0.7–2.25 and >2.25 dS/m, respectively; to match with the C3-class of the USDA system. The Water-Types were classified assuming that Ca–Cl2 is the least hazardous salt, followed by Mg–Cl2 and Na–Cl. Using this integrated hydrochemical method, the majority of the wells (92%) contain unsuitable water for irrigation (Group III) while the remaining wells (8%) are in Group II with water considered conditionally suitable for irrigation.  相似文献   

20.
A hydrogeochemical investigation was conducted in a coastal region of Cuddalore district to identify the influence of saltwater intrusion and suitability of groundwater for domestic and agricultural purposes. The geology of the study area comprises of sandstone, clay, alluvium, and laterite soils of Tertiary and Quaternary age. A total of 18 groundwater samples were analyzed for 14 different water quality parameters and the result indicates higher concentrations of ions like Cl (3,509 mg/l), Na (3,123 mg/l), and HCO3 (998 mg/l) when compared with WHO, BIS, and ISI standards. A positive correlation (r 2?=?0.82) was observed between Na and Cl, indicating its sources from salt water intrusion. Three factors were extracted with a total variance of 64% which indicates the sources of salinization, cation exchange, and anthropogenic impact to the groundwater. The Piper trilinear diagram indicates both Na–Cl and mixed Na–HCO3–Cl-type, indicating that groundwater was strongly affected by anthropogenic activities. The plot of (Ca?+?Mg)/(K?+?Na) indicates evidences of cation exchange and salt water intrusion. The (Ca–0.33*HCO3)/ SO4 plot indicates salt water intrusion for elevated SO4 levels rather than gypsum dissolution. The spatial distribution of total dissolved solid indicates the saline water encroachment along the SW part of the study area. As per sodium adsorption ratio (SAR), 50% of the samples with <10 SAR are suitable for irrigation and >10 SAR indicates that water is unsuitable for irrigation purposes. The residual sodium carbonate classification indicates that 50% of the samples fall in safe and 50% of the samples fall in bad zones and prolonged usage of this water will affect the crop yield. The Chloro Alkaline Index of water indicates disequilibrium due to a higher ratio of Cl?>?Na–K, indicating the influence of salt water intrusion. The Permeability Index of the groundwater indicates that the groundwater from the study area is moderate to good for irrigation purposes.  相似文献   

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