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1.
Martin Okrusch 《Contributions to Mineralogy and Petrology》1971,32(1):1-23
Three garnet-biotite pairs and eleven garnet-cordierite-biotite triplets from the Steinach aureole (Oberpfalz, North-East Bavaria) were analyzed using an electron probe microanalyzer.The regional metamorphic muscovite-biotite schists contain garnets strongly zoned with Mn-Ca-rich centers and Fe-rich edges, the average composition being almandine 67 — spessartine 4 — pyrope 4 — grossular (+andradite) 25.The first contact garnet that is formed in mica schists of the outermost part of the aureole is small, virtually unzoned, and has an average composition of almandine 52 — spessartine 37 — pyrope 8 — grossular (+andradite) 3. With increasing metamorphic grade, there is a consistent trend to form garnets richer in Fe ending up with a composition almandine 84.5 — spessartine 5.5 — pyrope 7.5 — grossular (+andradite) 2.5. This trend is accompanied by a general increase in grain size and modal amount of garnet. Associated cordierites and biotites also become richer in Fe with increasing grade. While the garnets in the highest grade sillimanite hornfelses are poorly zoned, the transitional andalusite-sillimanite hornfelses contain garnets with distinct but variable zonation profiles.These facts can possibly be explained by the time-temperature relationships in the thermal aureole. In a phase diagram such as the Al-Fe-Mg-Mn tetrahedron, the limiting mineral compositions of a four-phase volume or a three-phase triangle are fixed by T and P (the latter remaining effectively constant within a thermal aureole). Thus, in garnet-cordierite-biotite assemblages, garnet zonation should be controlled by temperature variation rather than by a non-equilibrium depletion process. Taking into account the experimental data of Dahl (1968), a zoned garnet from a transitional andalusite-sillimanite hornfels would reflect a temperature increase of about 40° C during its growth. A hypothetical P-X diagram is proposed to show semi-quantitatively the compositional variation of garnet-cordierite pairs with varying pressures (T constant). 相似文献
2.
湖北省宜昌市彭家河石榴石矿床地质特征及成因分析 总被引：1，自引：1，他引：0
运用矿物学、岩石学的方法对宜昌黄陵地区彭家河石榴石矿床中含矿层的矿物组合、化学成分、变质相及原岩特征进行分析与研究,结果表明彭家河石榴石矿床的含矿层位为水月寺群的周家河组,石榴石主要赋存于含(石墨)矽线石榴黑云斜长片麻岩及石榴黑云斜长片麻岩中,前者石榴石含量较高10%～50%,后者含量稍低12%～36%,X衍射及电子探针分析矿床中石榴石以铁铝榴石为主,其次是镁铝榴石,少量钙铝榴石.运用变质反应平衡温压方程计算出成矿温压条件为:P=600 MPa～800 MPa,T=650℃～750℃;变质相为高角闪岩相,高角闪岩相的富铁铝质沉积变质岩系--孔兹岩系是寻找此类石榴石矿床的重要找矿标志. 相似文献
3.
TUCCILLO M. E.; MEZGER K.; ESSENE E. J.; VAN DER PLUIJM B. A. 《Journal of Petrology》1992,33(6):1225-1259
Textural evidence, thermobarometry, and geochronology were usedto constrain the pressure-temperature-time (P—T—t)history of the southern portion of the Britt domain in the CentralGneiss Belt, Ontario Grenville Province. Typical metapeliticassemblages are quartz+plagioclase+ biotite + garnet + kyanite alkali feldspar sillimanite rutile ilmenite staurolite gahnite muscovite. Metatonalitic assemblages have quartz+ plagioclase + garnet biotite + hornblende + rutile + ilmenite.Metagabbroic rocks contain plagioclase + garnet + clinopyroxene+ biotite + ilmenite hornblende rutile quartz. Notabletextural features include overgrowths of sillimanite on kyaniteand of spinel on staurolite. The spinel overgrowths can be modeledby the breakdown of staurolite via the reaction Fe-staurolite= hercynite +kyanite + quartz + H2O. The decomposition of stauroliteto her-cynite has a steep dP/dT slope and constrains the lateprograde path of a staurolite metapelite. Garnet—Al2SiO5—plagioclase—quartz(GASP) barometry applied to metapelitic garnets that preservecalcium zoning reveals a pressure decrease from 11 to 6 kbat an assumed temperature of 700 C. Garnet—plagioclase—ilmenite—rutile—quartzand garnet—clinopyroxene—plagioclase—quartzbarometry is in good agreement with pressures obtained withthe GASP barometer. Geochronologic data from garnet, allanite,and monazite in metapelitic rocks give ages that fall into twogroups, 1–4 Ga and 1.1 Ga, suggesting the presence ofat least two metamorphic events in the area. It is most reasonableto assign the 1.4 Ga age to the high-pressure data and the 1.1Ga age to the lower-pressure data. Collectively the P—T—tdata indicate a complex and protracted history rather than asingle cycle of burial and uplift for this part of the GrenvilleProvince. 相似文献
4.
Garnet porphyroblasts in sillimanite‐bearing pelitic schists contain complex textural and compositional zoning, with considerable variation both within and between adjacent samples. The sillimanite‐bearing schists locally occur in regional Barrovian garnet zone assemblages and are indicative of a persistent lack of equilibrium during prograde metamorphism. Garnet in these Dalradian rocks from the Scottish Highlands preserves evidence of a range of metamorphic responses including initial growth and patchy coupled dissolution–reprecipitation followed by partial dissolution. Individual porphyroblasts each have a unique and variable response to prograde metamorphism and garnet with mainly flat compositional profiles co‐exists with those containing largely unmodified characteristic bell‐shaped Mn profiles. This highlights the need for caution in applying traditional interpretations of effective volume diffusion eliminating compositional variation. Cloudy garnet with abundant fluid inclusions is produced during incomplete modification of the initial porphyroblasts and these porous garnet are then particularly prone to partial replacement in sillimanite‐producing reactions. The modification of garnet via a dissolution–reprecipitation process releases Ca into the effective whole‐rock composition, displacing the pressure–temperature positions of subsequent isograd reactions. This represents the first report of internal metasomatism controlling reaction pathways. The behaviour of garnet highlights the importance of kinetic factors, especially deformation and fluids, in controlling reaction progress and how the resulting variability influences subsequent prograde history. The lack of a consistent metamorphic response, within and between adjacent schists, suggests that on both local and regional scales these rocks have largely not equilibrated at peak metamorphic conditions. 相似文献
5.
Bulk chemical and mineral analyses were carried out on a progressiveseries of low-pressure metamorphic pelites and psammites ofthe Bavarian Forest. The variation of rock compositions in thelower grade (=sillimanite-K-feldspar) zone with coexisting biotite+sillimanite(+K-feldspar+quartz) is essentially the same as that in thehigher grade (=cordierite-K-feldspar) zone with coexisting biotite+cordierite±sillimanite(+K-feldspar+quartz), so that nearly isochemical conditionscan be assumed for the metamorphic processes. The two metamorphiczones are related to each other through the multivariant reaction: biotite+sillimanite+quartz = cordierite+K-feldspar+H2O, but analyses of coexisting biotites and cordierites indicatethat metamorphism continues to increase even within the cordierite-K-feldsparzone. This increase is signalized through a continuous shiftof the 3-phase AFM field cordierite-biotite-sillimanite fromMg-rich to more Fe-rich compositions according to the abovereaction. At the highest grade detected the coexistence of biotite+sillimanitein the presence of quartz+K-feldspar is discontinued in favourof cordierite+garnet. Comparison with other metamorphic areas exhibiting the sameAFM assemblages leads to the tenative conclusion that the shiftdetected here is mainly due to increasing temperatures of metamorphism,whereas increasing pressures would shift the 3-phase AFM fieldin the opposite direction, that is towards more Mg-rich compositions.Thus the position of the biotite-sillimanite-cordierite fieldwithin the AFM plot can be used as indicator of metamorphicconditions in seemingly similar cordierite-sillimanite-biotite-quartz-K-feldspargneisses of variable provenance. Assuming water pressure toequal total pressure the conditions that lead to the cordierite-potashfeldspar zone studied here are estimated as 2-3 kb, 650-700°C. 相似文献
6.
石榴夕线片麻岩是中、下地壳主要组成岩石之一,岩石内石榴石和夕线石的结晶学优选方位会显著影响地壳深部流变性质,因此探讨特征变质矿物的变形机制和主要受控因素对构造带深部演化过程有深远意义。本文选取红河-哀牢山韧性剪切带内石榴夕线片麻岩为研究对象,通过定向切片内显微构造、电子探针、X-ray成分扫描、电子背散射衍射(EBSD)和相平衡模拟综合研究,揭示出石榴石在溶解沉淀反应过程中具有明显的粒度敏感性,不同粒径石榴石表现出截然不同的长宽比、成分环带、包裹体排列方式和压力影发育情况。石榴石表面流体活动明显截切早期生长环带。EBSD分析揭示石榴石破碎颗粒以绕〈112〉轴机械旋转为主,溶解过程主要集中于颗粒表面和裂隙内高曲率位置。夕线石的EBSD结果表明基质内夕线石以绕〈010〉轴旋转为主,而流体作用明显区域夕线石则以(100)[001]滑移为主。岩石相平衡模拟限定岩石变质峰期P-T条件达高压麻粒岩相,退变过程中同剪切变形导致大量流体渗入而形成降温降压退变轨迹,由~9.5kbar、760℃演化至~6.0kbar、500~600℃,并在粗粒石榴石内保存早期进变质环带,剪切抬升过程中石榴石内普遍发育垂直剪切方向的裂隙,并在流体作用下进一步改造其形态。此研究揭示红河-哀牢山剪切带内除前人报道的石榴石高温韧性变形外,还存在大量中-上地壳层次同变质反应下的溶解-沉淀蠕变作用。因此,石榴石变质-变形的综合研究有助于揭示变质杂岩带挤压-剪切-伸展多阶段构造演化过程。 相似文献
7.
The broad objective of this work is to develop models of reactionthat can be used to understand dynamic processes. The kineticsof reactions can be significant factors affecting heat and masstransfer, and the kinetic inhibition of equilibration enablesus to trace the history of natural samples. Samples were selectedfrom a metamorphic aureole for study because they show measurabledisequilibrium, and the approximate P—T path and timeof metamorphism are known. Detailed analysis of compositional variations of crystals andreaction textures suggests that biotite was being produced bythe breakdown of garnet at a faster rate than it was consumedby reaction with sillimanite. Some of the compositional variationsof biotite and cordierite can be explained by the process ofintergranular diffusion; however, the co-existence of metastablebiotite and sillimanite and the widespread distribution of Fe-richbiotite in the sample argue for a partial equilibrium modelfor which reaction rate was controlled by surface kinetic processes. Quantitative modelling was accomplished by breaking the overallreaction into three component reactions. The rate of one ofthese component reactions through time can be estimated fromgarnet zoning profiles, and the relative abundance of productphases is used then to estimate the absolute rates of the othercomponent reactions. A plausible interpretation of the datais that rate of dissolution of sillimanite was the rate-controllingprocess, and took place at a rate of 10–7 to 10–8cm/year in this sample. Analysis of this sample illustrates possible significant effectsof the kinetics of reaction in dry rocks in the deep crust.Even though biotite would have been unstable at final equilibriumand the overall reaction did not involve significant gain orloss of water, the particular kinetic path under taken resultedin production of biotite and consumption of water at the stageof reaction preserved in this sample. 相似文献
8.
An analysis is presented of equilibrium in six specimens ofgarnet—biotite—sillimanite—plagioclase—potashfeldspar—quartz ... gneiss from a metamorphic terrainin south-western Quebec. A nearly uniform Ti content of biotite may be accounted forby an equilibrium (a) involving biotite, sillimanite, quartz,garnet, potash feldspar, and H2O. The nature of the distributionof Fe and Mg between garnet and biotite may be accounted forby another equilibrium (b) involving the same mineral suite,or by a simple exchange equilibrium (c) involving only garnetand biotite. The distribution of Mn between garnet and biotiteis accounted for by an exchange equilibrium (d). A nearly uniformvalue of the ratio Ca content of plagioclase/Ca content of garnetmay be accounted for by an equilibrium (e) involving plagioclase,garnet, sillimanite, and quartz. A proposed equilibrium (f)involving biotite, quartz, ilmenite, potash feldspar, sillimanite,and H2O conflicts with equilibrium (a) and was evidently notestablished in the gneisses. The factors governing the Ca contentof biotite remain largely unknown. Some of these equilibria form potential indicators of relativegeologic temperature, pressure, and chemical potential of H2O. 相似文献
9.
高温变泥质岩石中石榴石-黑云母地质温度计的应用——以胶北荆山群富铝岩石为例 总被引：6，自引：0，他引：6
在对胶北荆山群麻粒岩相富铝岩石中石榴石、黑云母的成分环带进行深入研究基础上,选取不同粒径、与不同矿物相邻的石榴石、黑云母各微区点成分,利用石榴石-黑云母温度计分别进行了温度估算。确定在黑云母含量较高的岩石(V_(Grt)/V_(Bt)≤1)中,利用大颗粒石榴石(d≥1500μm)晶体核部(或靠近长英质矿物一侧的晶体幔部)成分与基质中远离石榴石等镁铁矿物处于长英质矿物之间的黑云母核部成分配合。通过石榴石-黑云母温度计可以获得相当可信的变质峰期温度。但是对于黑云母含量极低的岩石(V_(Grt)/V_(Bt)≥6),由于黑云母的成分普遍遭到了强烈改造。使得温度估算结果异常偏低,因此不适合采用石榴石-黑云母温度计估算峰期温度。同一岩石中,采用不同的相邻石榴石-黑云母矿物对晶体边缘成分获得的温度值差异较大,反映它们在峰期后发生Fe-Mg交换反应并达到封闭温度平衡状态的程度不同,因此利用石榴石-黑云母温度计难以获得准确的封闭温度。通过热力学计算,建立了一个新的石榴石-黑云母温度计公式。确定胶北荆山群所经历的变质峰期温度为720～770℃,峰期后最低相对封闭温度为480～500℃。 相似文献
10.
Garnet evolution in pre-Variscan pelitic rocks from the Lake Emosson area, Aiguilles Rouges Massif, Western Alps 总被引：1，自引：0，他引：1
Abstract The chemical evolution of garnets from pelitic rocks of probable Palaeozoic age corresponds to a complex metamorphic evolution of the host rocks.
Among the almandine-rich garnets (Alm60–80 ), two main types of evolution can be distinguished. Early Mn-rich garnets coexisting with kyanite may be replaced by plagioclase and then, during a late stage, by biotite and/or sillimanite. The second type of evolution corresponds to an overgrowth of Mn-poor late-stage garnet on older Mn-rich garnets which corresponds to a thermal peak with sillimanite-type of metamorphism. This new garnet may appear either as an overgrowth with a strong discontinuity, or as small, new euhedral garnet or as skeletal garnet.
This chemical evolution of garnet corresponds to an early collisional stage of metamorphism (of high pressure type with high Mn values) of probable Ordovician age followed by uplift and a thermal peak (low Mn values) in Devonian times. 相似文献
Among the almandine-rich garnets (Alm
This chemical evolution of garnet corresponds to an early collisional stage of metamorphism (of high pressure type with high Mn values) of probable Ordovician age followed by uplift and a thermal peak (low Mn values) in Devonian times. 相似文献
11.
点苍山变质杂岩新生代变质-变形演化及其区域构造内涵 总被引：3，自引：2，他引：1
点苍山变质杂岩体是哀牢山-红河韧性剪切带四个变质杂岩体之一,遭受了多期多阶段变质-变形作用改造。本文重点针对点苍山杂岩的新生代变质-变形作用,尤其是以富铝质高级变质岩即夕线石榴黑云片麻岩和侵位于其中的糜棱岩化细晶花岗质岩石开展了深入研究。对夕线石榴黑云片麻岩的显微构造分析与矿物共生组合研究,确定了高角闪岩相和低角闪岩相变质矿物共生组合,分别为:石榴石(Grt)+夕线石(Sil)+钾长石(Kfs)+黑云母(Bi)+斜长石(Pl)±石英(Q)和夕线石(Sil)+白云母(Ms)+黑云母(Bi)+石英(Q)。对其中的变质锆石进行SHRIMP U-Pb测试,获得了新生代三个阶段的变质作用年龄,即54.2±1.7Ma、31.5±1.5Ma和27.5±1.2Ma.本文还深入研究了侵位于高级变质岩中的一个花岗岩质糜棱岩的宏观与显微构造特点,其LA-ICP-MS年龄为24.4±0.89Ma,代表着同剪切就位花岗质岩浆侵位和结晶年龄。夕线石榴黑云片麻岩中变质锆石从2150～27Ma多期多阶段表观年龄的发育,表明点苍山变质杂岩体具有复杂的构造演化史。点苍山杂岩的多阶段新生代构造-热演化归咎于印度-欧亚板块会聚与碰撞作用(约54Ma)、造山后伸展作用(大约40～30Ma)和沿着哀牢山-红河剪切带大规模左行走滑变形作用(约27～21Ma)。 相似文献
12.
In a prograde amphibolite-granulite transition zone in the Namaqualand Metamorphic Complex, metapelites show an interbanding of the amphibolite facies association biotite+sillimanite+quartz with the granulite facies association garnet+cordierite+K-feldspar. Relict graded bedding shows that compositional banding is of sedimentary origin. The garnet-cordierite-K-feldspar gneisses contain quartzofeldspathic segregations surrounding garnets, and have more Fe-rich bulk compositions than the biotite-sillimanite schists.The contrasting asemblages could have formed at the same pressure and temperature provided that a(H2O) was systematically lower in the garnet-cordierite-K-feldspar layers. The a(H2O) reduction resulted from the production of silicate melt by a vapour-absent continuous Fe-Mg reaction such as biotite+sillimanite+quartz=garnet+K-feldspar+liquid which affects Fe-rich compositions before vapour-absent melting occurs in more Mg-rich rocks. The segregations represent the solid and liquid products of the reaction.Such processes imply local control of a(H2O), and indicate that this granulite transition did not result from a regional influx of metasomatising fluids. 相似文献
13.
Almandine in Thermal Aureoles 总被引：1，自引：0，他引：1
The concept that almandine-rich garnet is an anomalous phasein thermal metamorphic assemblages is based partly upon therarity of almandine in hornfelses, and partly upon evidenceof breakdown of ‘regionally’ formed garnets whentheir host-rocks have been thermally metamorphosed. Where amphibolitefacies regional gneisses have been re-metamorphosed within thepyroxene-hornfels facies conditions of the late Caledonian Lochnagaraureole, garnet of composition Alm80Py11p6 (Gr+And)4 has reactedwith biotite, sillimanite, and muscovite to give cordierite-richpseudomorphs; where armoured from reaction by immersion in quartzor feldspar, no signs of dissolution are seen. In some totallyreconstituted hornfelses, almandine garnet of composition AIm80P13Sp4(Gr+And)3 appears to have coexisted stably with cordierite andorthoclase. It is concluded that the ‘unstable’garnet was breaking down not because its P/T stability fieldhad been exceeded, but because the alman-dine-bearing rock-compositionfield in the thermal (pyroxene-hornfels) facies was more restrictedthan that in the regional (amphibolite) facies. Chemical datafrom the hornfelses suggest that this restriction was mainlydue to the stability of cordierite—the plane spinel-cordierite-quartzrestricts garnet to those rocks with effective mol. (FeO+MgO-t-MnO)A12O3>1, while within that range cordierite-biotite tie-linesrestrict garnet to rocks of high (FeO+MnO)/MgO ratio (Fig. 4b). Recorded instances of garnet ‘instability’ in thermalaureoles show similar features to the Lochnagar aureole—garnetbreaks down by reaction; unequivocal instances of isochemicalbreakdown are rare. This, combined with the widespread occurrenceof almandine in volcanic and plutonic igneous rocks, suggeststhat almandine is a physically stable phase not only in thehornblende-hornfels facies, but also in the pyroxene-hornfelsfacies and possibly in portion of the sanidinite facies as well.The rarity of almandine in thermal aureoles is the result ofits very narrow rock composition field under the P/T conditionsof such environments. Comparison of thermal and granulite facies garnet-cordieriteassemblages suggests that P and T modify the almandine-bearingrock composition field mainly by modifying the limiting Mg/Feratio of garnet and the limiting Fe/Mg ratio of cordierite (Fig.10). The wide rock-composition field of almandine in the amphibolitefacies may be contingent upon the inhibition of cordierite byhydrous minerals under relatively high partial pressures ofwater. 相似文献
14.
Summary Garnet occurs as a significant mineral constituent of felsic garnet-biotite granite in the southern edge of the Třebíč pluton.
Two textural groups of garnet were recognized on the basis of their shape and relationship to biotite. Group I garnets are
1.5–2.5 mm, euhedral grains which have no reaction relationship with biotite. They are zoned having high XMn at the rims and are considered as magmatic. Group II garnets form grain aggregates up to 2.5 cm in size, with anhedral shape
of individual grains. The individual garnet II grains are usually rimmed by biotite and have no compositional zoning. The
core of group I garnets and group II garnets contains 67–80 mol% of almandine, 5–19 mol% of pyrope, 7–17 mol% of spessartine
and 2–4 mol% of grossular. Biotite occurs in two generations; both are magnesian siderophyllites with Fe/(Fe + Mg) = 0.50–0.69.
The matrix biotite in granites (biotite I) has high Ti content (0.09–0.31 apfu) and Fe/(Fe + Mg) ratio between 0.50 and 0.59.
Biotite II forms reaction rims around garnet, is poor in Ti (0.00–0.06 apfu) and has a Fe/(Fe + Mg) ratio between 0.61 and
0.69. The textural relationship between biotite and garnet indicates that garnet reacted with granitic melt to form Ti-poor
biotite and a new granitic melt, depleted in Ti and Mg and enriched in Fe and Al. In contrast to the host durbachites (hornblende-biotite
melagranites), which originated by mixing of crustal melts and upper mantle melts, the origin of garnet-bearing granites is
related to partial melting of the aluminium-rich metamorphic series of the Moldanubian Zone. 相似文献
15.
David M. Hirsch 《Contributions to Mineralogy and Petrology》2008,155(4):401-415
Garnet-bearing schists from the Waterville Formation of south-central Maine provide an opportunity to examine the factors
governing porphyroblast size over a range of metamorphic grade. Three-dimensional sizes and locations for all garnet porphyroblasts
were determined for three samples along the metamorphic field gradient spanning lowest garnet through sillimanite grade, using
high-resolution X-ray computed tomography. Comparison of crystal size distributions to previous data sets obtained by stereological
methods for the same samples reveals significant differences in mode, mean, and shape of the distributions. Quantitative textural
analysis shows that the garnets in each rock crystallized in a diffusion-controlled nucleation and growth regime. In contrast
to the typical observation of a correlation between porphyroblast size and position along a metamorphic field gradient, porphyroblast
size of the lowest-grade specimen is intermediate between the high- and middle-grade specimens’ sizes. Mean porphyroblast
size does not correlate with peak temperatures from garnet-biotite Fe-Mg exchange thermometry, nor is post-crystallization
annealing (Ostwald Ripening) required to produce the observed textures, as was previously proposed for these rocks. Robust
pseudosection calculations fail to reproduce the observed garnet core compositions for two specimens, suggesting that these
calc-pelites experienced metasomatism. For each of these two specimens, Monte Carlo calculations suggest potential pre-metasomatism
bulk compositions that replicate garnet core compositions. Pseudosection analyses allow the estimation of the critical temperatures
for garnet growth: ∼481, ∼477, and ∼485°C for the lowest-garnet-zone, middle-garnet-zone, and sillimanite-zone specimens,
respectively. Porphyroblast size appears to be determined in this case by a combination of the heating rate during garnet
crystallization, the critical temperature for the garnet-forming reaction and the kinetics of nucleation. Numerical simulations
of thermally accelerated, diffusion-controlled nucleation, and growth for the three samples closely match measured crystal
size distributions. These observations and simulations suggest that previous hypotheses linking the garnet size primarily
to the temperature at the onset of porphyroblast nucleation can only partially explain the observed textures. Also important
in determining porphyroblast size are the heating rate and the distribution of favorable nucleation sites. 相似文献
16.
17.
Electron-probe microanalysis of a series of garnets in metapelitic rocks of the chloritoid staurolite, kyanite and sillimanite metamorphic zones, eastern area of the Sierra de Guadarrama, Sistema Central, Spain, manifest the well-known cryptozonation commonly observed in these minerals, with MgO and FeO increasing and MnO and CaO decreasing from the center to the outer rim of the crystals.The differences in composition of the garnets, from one metamorphic zone to another, is mainly a result of small differences in composition of the host-rock, since: (1) the amounts of MnO in the garnet are controlled by the amounts of SiO2, Al2O3 and FeO present in the host-rock; and (2) the percentages of MnO and MgO of the parent-rock influence in some way the concentration of CaO in the garnet, and those of MnO, Al2O3 and CaO influence the concentration of FeO. Nevertheless, the amount of FeO in the garnet is finally controlled, due to the diadochy, by the concentration of MnO + CaO in this mineral. 相似文献
18.
Mineral assemblages in pegmatite samples from Kolsva, Swedenand Marikov, Czechoslovakia show that chrysoberyl is alwaysaccompanied by quartz, and is a breakdown product of primarypegmatitic beryl. Textures and the mineral-forming process forthe Kolsva pegmatite are explained by the reactions beryl +K-feldspar + H+ = chrysoberyl + quartz + SiO2, aq + K+ + H2Oor alternatively beryl —K—feldspar + H2O = chrysoberyl+ quartz + melt. Mineral assemblages from mica-rich parts ofthe pegmatite include sillimanite—K—feldspar, muscovite—K—feldspar—sillimanite,and annite—magnetite—spinel—sillimanite—garnet.Details about the composition and the textural relationshipsof these minerals are given; they indicate a post-pegmatiticmetamorphic event at P—T conditions near to the anatecticregime. The samples from Marikov show textures, which are explainedby the reactions beryl + albite + H+ = chrysoberyl + quartz+ Na+ + H2O or alternatively beryl + albite + H2O = chrysoberyl+ quartz + melt. Breakdown of muscovite produces sillimaniteaccording to the reactions beryl + albite + muscovite + H+ =chrysoberyl + quartz + sillimanite + Na+ + K+ + H2O or alternativelyberyl + albite + muscovite + H2O = chrysoberyl + quartz + sillimanite+ melt. Similar reaction textures and mineral assemblages were foundin other chrysoberyl-bearing pegmatites (Maroankora, Madagascar;Helsinki, Finland; Haddam, Greenfield, Greenwood, U.S.A.). Hydrothermal experiments located the reaction beryl + alkalifeldspar + H2O = chrysoberyl + phenakite + melt at P—Tconditions between the K—feldspar—quartz—H2Osolidus and the K—feldspar—albite—quartz-H2Osolidus. It is concluded that the formation of Al-rich minerals likechrysoberyl and sillimanite in pegmatites is due to a post-pegmatiticevent at high P—T conditions. The question as to whichof the alternative set of reactions is more likely, the ionicequilibria or the anatectic chrysoberyl formation, must be leftopen. The previous hypothesis of a desilification of a pegmatitewhich intruded into SiO2-poor country rocks, or of the assimilationof Al2O3-rich country rocks, cannot explain the mineral assemblagesof the two pegmatites. 相似文献
19.
D. L. WHITNEY T. A. MECHUM S. M. KUEHNER & Y. R. DILEK 《Journal of Metamorphic Geology》1996,14(2):163-181
A complete Barrovian sequence ranging from unmetamorphosed shales to sillimanite–K-feldspar zone metapelitic gneisses crops out in a region extending from the Hudson River in south-eastern New York state, USA, to the high-grade core of the Taconic range in western Connecticut. NNE-trending subparallel biotite, garnet, staurolite, kyanite, sillimanite and sillimanite–K-feldspar isograds have been identified, although the assignment of Barrovian zones in the high-grade rocks is complicated by the appearance of fibrolitic sillimanite at the kyanite isograd. Thermobarometric results and reaction textures are used to characterize the metamorphic history of the sequence. Pressure–temperature estimates indicate maximum metamorphic conditions of 475 °C, c. 3–4 kbar in the garnet zone to >720 °C, c. 5–6 kbar in the highest grade rocks exposed. Some samples in the kyanite zone record anomalous (low) peak conditions because garnet composition has been modified by fluid-assisted reactions. There is abundant petrographic and mineral chemical information indicating that the sequence (with the possible exception of the granulite facies zone) was infiltrated by a water-rich fluid after garnet growth was nearly completed. The truncation of fluid inclusion trails in garnet by rim growth or recrystallization, however, indicates that metamorphic reactions involving garnet continued subsequent to initial infiltration. The presence of these textures in some zones of a well-constrained Barrovian sequence allows determination of the timing of fluid infiltration relative to the P–T paths. Thermobarometric results obtained using garnet compositions at the boundary between fluid–inclusion-rich and inclusion-free regions of the garnet are interpreted to represent peak metamorphic conditions, whereas rim compositions record slightly lower pressures and temperatures. Assuming that garnet grew during a single metamorphic event, infiltration must have occurred at or slightly after the peak of metamorphism, i.e. 4–5 kbar and a temperature of c. 525–550 °C for staurolite and kyanite zone rocks. 相似文献
20.
《International Geology Review》2012,54(3):207-223
Kinetic theory allows the calculation of a time scale for metamorphic events using the extent of relaxation of garnet growth zoning along a particular P-T trajectory. Eclogitic garnets from the Kokchetav Massif (Kazakhstan), the Great Caucasus (Russia), and the Yukon-Tanana terrane (Canada) experienced different metamorphic P-T histories and display different types of zoning patterns, which allowed testing of a variety of geospeedometric procedures. In all cases, the preservation of sharp compositional gradients and hence the limited degree of diffusive modification of garnet compositions can be explained if associated tectono-metamorphic processes were of very short duration. Results of diffusion modeling indicate rates of temperature and pressure change on the burial and/or the exhumation path on the order of several hundreds of °C/m.y. and several cm/yr, respectively. These extreme exhumation and cooling rates apply for rocks buried to a depth greater than, for example, 20 km, thus arguing for the existence of contrasted velocity fields for eclogitic block exhumation from deep versus shallow levels of the lithosphere. 相似文献