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1.
Cores and surface samples of peats from the Everglades—Mangrove region of Southern Florida were analyzed for total sulfur and pyritic sulfur. These values were compared with the petrographic-botanical components of the peats as determined from point-counts of oriented microtome sections. Pyrite occurs as individual euhedral crystals, loosely packed framboids, and lenses or crusts of minute crystals. Framboids and minute crystals are often associated with organic matter and sometimes with bacteria and fungi. Pyrite tends to selectively occur in void spaces in or between peat tissues. In samples containing very small amounts of pyrite, framboidal pyrite is the prevalent form.Marine to brackish peats contain the highest pyrite and total sulfur contents, with brackish peats generally containing more pyrite than marine peats. Pyrite tends to be lower in all peats within 30 cm of the surface, whether marine or brackish.Burial of freshwater peats beneath marine or brackish peats tends to increase the total sulfur and pyritic sulfur in the underlying peats. Burial beneath brackish-water, clay-rich deposits (such as splays) tends to increase total sulfur and pyritic sulfur in the underlying deposits more than burial beneath less clay-rich deposits.  相似文献   

2.
Jurassic high-sulfur coals from the Maghara area in Egypt were analyzed for the abundance and isotopic composition of different forms of sulfur. Analyses indicated that the sulfur occurs in the form of organic, pyrite, and sulfate forms. Pyrite sulfur represents the major fraction, while sulfate sulfur is minor and could be formed during sample preparation for the analyses.The δ34S CDT values of the organic sulfur are positive ranging between 1.0‰ and 13.5‰ with an average of 9.1‰. Pyrite δ34S values are also positive ranging between 1.5‰ and 15.4‰ with an average of 6.6‰. The high δ34S values of the organic sulfur in the Maghara coals suggest a freshwater origin of the organic components of these coals. The lack of correlation between pyrite and organic sulfur isotopes implies different incorporation mechanisms of sulfur. The high-sulfur contents along with the positive and high δ34S values suggest a marine origin of pyrite sulfur and support the geological interpretation of marine invasion after the peat formation that was responsible for the incorporation of the pyrite sulfur.The occurrence of pyrite as euhedral crystals as well as the high and positive δ34S values of the pyrite sulfur indicates the formation of pyrite during diagenesis as a result of marine water invasion of the preexisting peat in a brackish coastal plain environment.  相似文献   

3.
The peat-forming systems of the Okefenokee Swamp are viewed as modern progenitors of coal. Taxodium and Nymphaea-derived peat-forming systems were characterized in terms of (1) organic fractions and (2) the distribution of organic/inorganic sulfur in each organic fraction (water soluble, benzene/methanol soluble, humin, humic acid, fulvic acid). The humin fraction is the largest organic fraction in both environments, approaching 70% of the total organic matter in the Nymphaea-derived environment. Humin origins are discussed in terms of a humic acid precursor, and undecomposed plant material. It is suggested that each depth of peat represents a diagenetic history of events which the authors believe occurred primarily when the currently buried peat was at the surface. The sulfur content of both peat-forming areas is low (0.23–0.27%); organic sulfur is the dominant sulfur form. Humin contains 50–80% of the total sulfur and of this, 80% is organic sulfur. Ester-sulfate appears to be especially prevalent in the fulvic acid fraction. The sulfur content of freshwater-derived peats is similar in quantity and distribution to that found in low sulfur coals.  相似文献   

4.
Although there is published information on the mechanism of sedimentary pyrite formation resulting from bacterial reduction of sulfate, little is known about the distribution of forms of sulfur, including organic, in peats. In order to increase understanding of the geochemistry of sulfur in coals, we have determined distributions of forms of sulfur in five cores of saline peat and one of brackish peat, all from areas near the Shark River and Whitewater Bay in the coastal swamps of south Florida. All concentrations vary widely with depth. Total sulfur concentrations range up to 6% of dry solids. Minor amounts of sulfur are present as H2S, S0, SO42−, and acid-soluble sulfide, but the principal forms are usually pyritic and organic. The ratio, organic/pyritic, is highly variable, but at a majority of levels in a profile is considerably greater than unity. It is inferred that topochemical factors are important in determining the distribution of sulfur forms in any element of volume.  相似文献   

5.
海南岛红树林泥炭中硫及其成因研究   总被引：4，自引：2，他引：4  
海南岛红树林泥炭普遍富硫。黄铁矿、硫酸盐和有机硫是泥炭中硫的三种主要赋存形态,其中,以黄铁矿硫高为特征。利用形态硫分析、硫同位素分析等手段结合硫的时空变化特征,研究了泥炭中硫的形成机理。泥炭中硫的富集与泥炭坪环境具紧密的成因联系,全硫和形态硫的时空变化受微环境的控制;潮坪水介质中的硫酸盐是泥炭中硫的最初来源;泥炭中硫的加入,主要发生于准同生价段,在加入过程中还原硫细菌起了决定性作用。定量沉积环境分析是查明古代富硫煤田硫分布的主要途径。  相似文献   

6.
The Middle Permian Collinsville Coal Measures of the northern Bowen Basin illustrate a range of cold to cold-temperate, coal-forming environments. Cold climate is indicated by Glossopteris flora in the coal measures, and by restricted marine fauna dominated by brachiopods and bryozoa in correlative marine sequences of the Back Creek Group which contains also abundant lonestones (dropstones). Sedimentation was characterised by an overall transgression, interrupted by local fluvial and coastal progradation in a shallow, epicontinental sea during a relatively quiescent tectonic period.Six sedimentary environments are represented: fluvial, fluvio-paralic, barrier-strandplain, back-barrier, tidal flat and open marine. The basal coal formed from peat of swamps of abandoned areas of gravelly braided streams, and is massive, dull, and with high ash (20%), low sulphur (1%) contents. Overlying coals developed from peats formed in fluvio-paralic and paralic environments, and thicker seams are generally brighter, with low to moderate ash (8–17%) and moderate to high total sulphur (1–6%) contents. Seams associated with fluvial influence show splits and high ash yield, while seams associated with coastal deposits show high sulphur levels (up to 21%).In contrast to reported models of coal-forming environments, no clearly defined deltaic or inter-distributary bay-fill sequences were identified in the area studied. Rather, vast freshwater wetlands backed low-gradient, progradational coasts locally having bars and barriers. The barriers were not prerequisites for substantial peat accumulation, although may have locally assisted peatland development by raising the profile of coastal equilibrium.  相似文献   

7.
The sulfur isotopic composition of the Herrin (No. 6) Coal from several localities in the Illinois Basin was measured. The sediments immediately overlying these coal beds range from marine shales and limestones to non-marine shales. Organic sulfur, disseminated pyrite, and massive pyrite were extracted from hand samples taken in vertical sections.The δ 34S values from low-sulfur coals (< 0.8% organic sulfur) underlying nonmarine shale were +3.4 to +7.3%0 for organic sulfur, +1.8 to +16.8%0 for massive pyrite, and +3.9 to +23.8%0 for disseminated pyrite. In contrast, the δ 34S values from high-sulfur coals (> 0.8% organic sulfur) underlying marine sediments were more variable: organic sulfur, ?7.7 to +0.5%0, pyrites, ?17.8 to +28.5%0. In both types of coal, organic sulfur is typically enriched in 34S relative to pyritic sulfur.In general, δ 34S values increased from the top to the base of the bed. Vertical and lateral variations in δ 34S are small for organic sulfur but are large for pyritic sulfur. The sulfur content is relatively constant throughout the bed, with organic sulfur content greater than disseminated pyrite content. The results indicate that most of the organic sulfur in high-sulfur coals is derived from post-depositional reactions with a 34S-depleted source. This source is probably related to bacterial reduction of dissolved sulfate in Carboniferous seawater during a marine transgression after peat deposition. The data suggest that sulfate reduction occurred in an open system initially, and then continued in a closed system as sea water penetrated the bed.Organic sulfur in the low-sulfur coals appears to reflect the original plant sulfur, although diagenetic changes in content and isotopic composition of this fraction cannot be ruled out. The wide variability of the δ 34S in pyrite fractions suggests a complex origin involving varying extents of microbial H2S production from sulfate reservoirs of different isotopic compositions. The precipitation of pyrite may have begun soon after deposition and continued throughout the coalification process.  相似文献   

8.
煤中硫是多种有害微量元素的重要载体。基于形态硫分析、电感耦合等离子质谱及X射线衍射等方法分析沁水盆地晚古生代煤中硫和有害微量元素的分布规律,探讨了煤中硫对有害微量元素富集的影响,运用带能谱的扫描电镜和光学显微镜划分煤中硫化物的微观赋存特征。结果表明,沁水盆地煤中硫整体上以有机硫为主,平均占全硫的78%,只有在太原组个别高硫煤中以黄铁矿硫为占优势。显微镜和扫描电镜下可识别出煤中黄铁矿的微观赋存状态包括莓球状、薄膜状、晶粒状、结核状、团窝状黄铁矿和细粒黄铁矿集合体,白铁矿的微观赋存特征包括聚片状、板状和矛头状白铁矿,部分白铁矿与黄铁矿共生。沁水盆地煤中有害微量元素含量整体较低,黄铁矿是有害微量元素As、Se和Hg的重要载体,而有机硫决定了煤中U的富集。研究认为,成煤时期海水对泥炭沼泽的影响导致太原组煤中全硫和黄铁矿硫较高,太原组煤中硫的来源具有多样性,煤中黄铁矿具有多阶段演化的特点。  相似文献   

9.
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10.
Occurrence and morphology of pyrite in Bulgarian coals   总被引：2，自引：0，他引：2  
Coals with different degrees of coalification (ranging from lignite to anthracite) from seven Bulgarian coal basins have been investigated. The forms of pyrite and their distribution have been established. The types found are: massive pyrite, represented by the homogeneous, cluster-like and microconcretionary varieties; framboidal pyrite, appearing in inorganic and bacterial forms; euhedral pyrite, which is either isolated or clustered; anhedral pyrite, in its infilling and replacement varieties; and infiltrational pyrite, as a replacement or infilling mineral.Most of the forms of the euhedral, framboidal and massive pyrite developed during peat deposition. The anhedral replacement pyrite formed in the peat bed during early diagenesis. Infiltrational pyrite filled fractures and cleats formed during the diagenesis, catagenesis and metagenesis.Both similarities and differences with respect to the distribution of the pyrite types have been determined between coals of different ranks from Bulgarian coal basins. These differences are due to: the presence of Fe and S in the rocks adjacent to ancient peat bogs; the activities of ground and surface waters which brought Fe and S into the peat bogs; the geochemical character (pH and Eh) of the peat bogs and the sulphur bacteria development; and the tectonic situation during diagenesis, catagenesis and metagenesis.  相似文献   

11.
方晶  胡克 《第四纪研究》2007,27(5):797-805
在辽东半岛东部的大孤山一带,面向海岸平原的沟谷埋藏泥炭十分发育。通过对11个沟谷进行钻孔调查,确认了在被切割的丘陵台地的沟谷中,埋藏泥炭广泛地发育在海拔\{2~\}10余米的不同高度; 并对钻孔样品做硅藻分析,明确了基底海拔高度在\{4~\}2m的泥炭层之下的沉积物为海生种硅藻占优势的海相层,因而取得了海水广泛侵入大洋河平原并直达沟谷深处的微体古生物方面的证据。进一步对3个代表性的小沟谷平原从沟头到沟口连续钻孔取样以及地质剖面分析,研究沟谷埋藏泥炭在横向上的分布特征表明:沟谷埋藏泥炭是全新世高海面期以后,随着海水的退却而形成的沼泽和湖沼等环境下的溺谷型泥炭; 位于沟谷中沟头位置的海拔4m左右的泥炭底部的标高,大致代表了该区全新世最高海面期海水(平均高潮线)曾达到的位置和高度,其泥炭在沟头开始形成的时期大致代表该区全新世最高海平面期; 研究区约\{6000~\}5500年前达到全新世最高海面,当时海面高度比现在约高出1.7m。  相似文献   

12.
Peat and organic rich sediments at coastal sites in extreme northwest Ireland have accumulated in a wide variety of environments, often strongly influenced by late Holocene changes in relative sea level and by geomorphic processes. A deep peat sequence on the coast of Aranmore Island accumulated initially in a lake and subsequently in a freshwater marsh environment. The long pollen record serves as a template for regional events. It extends over much of the Holocene and shows relatively high levels of Pinus pollen up to just before the disappearance of this taxon at c . 3600 BP. Coastal peat occurrences elsewhere are much thinner and have accumulated over shorter periods; they contain further evidence to show that coastal areas were well-wooded compared with today, and that Pinus was an important woodland component prior to c . 4000 BP. At sites in Gweebarra Bay intertidal peats record the closure of small estuaries by geomorphological events during the past 5000 years. Coastal sites at Ballyness, Clonmass, and Trawenagh display regressive stratigraphies ˜ minerogenic marine sediments are overlain by silty peats capped by highly organic freshwater peats. Basal radiocarbon dates range from 4500 to 3300 BP. The silty peats are interpreted as having formed in salt-marsh environments and contain distinctive pollen spectra, marked by high levels of Pinus and Compositae Liguliflorae pollen. The data suggest that relative sea level attained levels close to that of today by the mid-Holocene in this region. The pattern of relative sea-level change agrees well with that predicted by geophysical modelling.  相似文献   

13.
滨海红树林泥炭沉积物中硫的赋存特点及其控制因素   总被引：4，自引：0，他引：4  
海南和厦门两地滨海红树林沉积物和埋藏泥炭中硫的成分分析表明,滨海红树林沉积物和泥炭中的硫以硫化铁硫为主,有机硫次之,硫酸盐硫含量最低。泥炭沉积物中硫的赋存形式和特点与沉积环境密切相关。海南福田地区红树林泥炭沉积物主要形成于红树林潮上坪和泥炭坪,硫含量较高,平均为2.60%,且有机硫含量与有机碳含量呈正相关,而硫化铁硫含量与有机碳含量没有明显的相关性;厦门海沧镇红树林泥炭沉积物形成于红树林潮间坪以及潮道环境,硫含量较低,平均值仅为0.43%,形态硫和有机质的相关性与海南红树林泥炭地沉积物相反。红树林泥炭沉积物中铁的硫化物主要以黄铁矿形式产出,且以莓球状形态为主。研究表明,黄铁矿与次生有机硫的生成与微生物活动密切相关,造成红树林泥炭中硫含量差异最主要的原因不是硫源,而是有机质的供给与沉积微环境的影响。现代滨海红树林泥炭沼泽中硫的赋存特征将对煤中硫成因的研究提供重要的科学依据。  相似文献   

14.
Intermsoftheharmfulmattersincoalandcoalminingwastes,thefirstisabouthazardouselements ,theotherin cludessulfurandhazardousorganicmatter.Muchresearchontracetoxicelementsandtheirimpactsonenvironmenthasbeeninvestigatedinmanycountries (Goodarzi,1995 ;Finkelman ,1994 ;Chouetal.,1982 ) .Althoughthere searchconcerningthisaspectwasstartedmuchlaterinChi na ,manystudieshavebeenstrengthenedsince 1980 ,andmuchprogresshasbeenmade ,alargenumberofdatahavebeencollected ,andthecomparisonshavebeenmadeforthedata…  相似文献   

15.
The South Sumatra basin is among the most important coal producing basins in Indonesia. Results of an organic petrography study on coals from Tanjung Enim, South Sumatra Basin are reported. The studied low rank coals have a mean random huminite reflectance between 0.35% and 0.46% and are dominated by huminite (34.6–94.6 vol.%). Less abundant are liptinite (4.0–61.4 vol.%) and inertinite (0.2–43.9 vol.%). Minerals are found only in small amounts (0–2 vol.%); mostly as iron sulfide.Based on maceral assemblages, the coals can be grouped into five classes: (1) humotelinite-rich group, (2) humodetrinite-rich group, (3) humocollinite-rich group, (4) inertinite-rich group and (5) humodetrinite–liptinite-rich group. Comparing the distribution of maceral assemblages to the maceral or pre-maceral assemblages in modern tropical domed peat in Indonesia reveals many similarities. The basal section of the studied coal seams is represented typically by the humodetrinite–liptinite-rich group. This section might be derived from sapric or fine hemic peat often occurring at the base of modern peats. The middle section of the seams is characterized by humotelinite-rich and humocollinite-rich groups. The precursors of these groups were hemic and fine hemic peats. The top section of the coal seams is typically represented by the humodetrinite-rich or inertinite-rich group. These groups are the counterparts of fibric peat at the top of the modern peats. The sequence of maceral assemblages thus represents the change of topogenous to ombrogenous peat and the development of a raised peat bog.A comparison between the result of detailed maceral assemblage analysis and the paleodepositional environment as established from coal maceral ratio calculation indicates that the use of coal maceral ratio diagrams developed for other coal deposits fails to deduce paleo-peat development for these young tropical coals. In particular, mineral distribution and composition should not be neglected in coal facies interpretations.  相似文献   

16.
We present new original data on the geochemistry of scandium in the coals of Asian Russia, Mongolia, and Kazakhstan. In general, the studied coals are enriched in Sc as compared with the average coals worldwide. Coal deposits with abnormally high, up to commercial, Sc contents were detected in different parts of the study area. The factors for the accumulation of Sc in coals have been identified. The Sc contents of the coals depend on the petrologic composition of coal basins (composition of rocks in their framing) and the facies conditions of coal accumulation. We have established the redistribution and partial removal of Sc from a coal seam during coal metamorphism. The distribution of Sc in deposits and coal seams indicates the predominantly hydrogenic mechanism of its anomalous concentration in coals and peats. The accumulation of Sc in the coals and peats is attributed to its leaching out of the coal-bearing rocks and redeposition in a coal (peat) layer with groundwater and underground water enriched in organic acids. The enrichment of coals with Sc requires conditions for the formation of Sc-enriched coal-bearing rocks and conditions for its leaching and transport to the coal seam. Such conditions can be found in the present-day peatland systems of West Siberia and, probably, in ancient basins of peat (coal) accumulation.  相似文献   

17.
The stratigraphic and regional variation of petrographic and chemical properties within the coals of the Upper Carboniferous Tradewater Formation and surrounding rocks in the Western Kentucky coal field were analyzed with the intent of constructing a depositional model for the occurrence of these low sulfur coals. Cores were megascopically described, and coal samples were analyzed for maceral, ash, and sulfur contents. These data were then analyzed to determine regional variation within the study area, as well as vertical variation within single coal columns.Sedimentological data from core logs indicate that the majority of the Tradewater rocks consist of irregularly distributed, coarsening-upward, fine-grained detrital material that was deposited in shallow bodies of water. Fossiliferous shales and limestones indicate a marine influence. Less common coarse-grained, fining-upward sequences appear to represent deposits of meandering or braided channels.Like the detrital rocks, the coal seams are irregularly distributed and exhibit substantial variation in petrographic and chemical properties which reflect changes in the Eh and pH of the coal swamp waters. These individual swamps were relatively limited in extent and probably occupied a low-lying coastal area. The relatively high vitrinite content of most of the coals suggests a reasonable degree of preservation of decaying plant materials. The study of benched samples from surface mines suggests a distinct dichotomy between swamps that were in more or less continuous contact with sulfate-rich marine or brackish water and those in which peat accumulated in a dominantly fresh-water setting. Most of the latter show a pattern of upward increasing sulfur content and decreasing vitrinite content, indicating increasing influences of oxygenated water that would encourage microbial action and which would degrade the peat and increase the tendency for sulfide precipitation. The high sulfur coals do not display this variability. The high rates of lateral variability encountered in the data suggest that future study should concentrate on smaller areas where variation can be completely documented.  相似文献   

18.
Peat deposits on the recent lobe of the Fraser River delta, British Columbia, have accumulated in a variety of depositional settings. The study of the decomposition of the plant components associated with each depositional area has enabled prediction of the occurrence and distribution of the precursors of the loal macerals and microlithotypes.On inactive portions of the distal lower delta plain, thin sedge-grass peats ave developed. These peats were influenced by marine conditions near the base and freshwater conditions higher in the section. A high ratio of cellulose to lignin in marsh plants and limited exposure of these tissues to desiccation and oxidation prodcue primarily desmocollinite. Smaller amounts of cernite, cutinite, and alganite origginate from algal and sedge lipids. In the transition to freshwater peats, oxyfusinite, pyrofusinite and micrinite partially replace former exinite and vitrinite-group maceral precursors. Subsequent transgression by marine waters has further promoted decomposition of the peat. Laterally extensive but thin and discontinouus coal seams which would develop from such peat will contain vitrite bands near the base and grade upsection into interlamlaminated durite and vitrinertite.Peats deposited between the upper and lowerdelta plain originate from brackish water. As such, earliest peat horizons contain similar maceral compositions to thoce encountered in distal delta plain deposits. Crevasse and fire splays disrupt gradational changes in fabric upsection and along channel margins. Flooding by oxygenated, neutral pH waters, followed by extended periods of desicaation, result in increases of inertodetrinite, macrinite, sclerotinite, and oxyfusinite. Interlaminated durites and vitrinertites will form common microlithotypes. Interbedded bands of telinite, cutinite and cerinite are produced by later freshwater sedge-grass peat accumulations. In this biofacies, clarite replaces durite. After colonization by Sphagnum, lignin-rich tissues from ericaceous shrubs and Pinus contorta provide precurssors for subernnite, telocollinite, and telinite. Stumps of massive telinite interrupt these banded macerals. Coal seams originating from such peats would be thick, laterally extensive and characterized by vitrite with laminae of liptite and lenses of clarite in the upper part  相似文献   

19.
中国煤中硫的地球化学研究   总被引：16，自引：0，他引：16  
燃烧过程中,煤中硫会以硫氧化物等形式释放出来,污染大气以至形成酸雨,对环境造成极大的影响。本文在对中国煤中硫全面分析的基础上．总结并分析了中国煤中硫在不同地区、不同煤层和不同形成环境中的含量与分布规律,阐述煤中硫形成的地质成因和影响因素．以及育机硫、无机硫和元素硫的赋存状态．概述了煤利用过程中硫的转化机理及其对环境的影响．提出了对煤中硫的研究趋势和今后研究方向与热点问题。  相似文献   

20.
To better understand the formation mechanism of coal-hosted Ge ore deposits, this paper reports on the petrological, mineralogical, and geochemical compositions of the low-Ge coals in the Shengli Coalfield (Inner Mongolia, China), using optical microscopy, field emission-scanning electron microscopy, X-ray fluorescence, X-ray diffraction, and inductively coupled plasma mass spectrometry. The samples in the present study closely neighbor the previously-reported Wulantuga coal-hosted Ge ore deposit (both No. 6 Coal). In comparison with the Wulantuga Ge-rich coals, the low-Ge coals of the Shengli field display higher moisture (27.59% on average) and lower pyritic sulfur contents (0.53%). Both the low-Ge and Ge-rich coals are generally high in inertinite, and have varying but relatively low huminite contents. Preservation of fecal pellets as macrinite is notable in both the low-Ge and Ge-rich coals, and the position of the fecal pellets appears to be within tunnels or chambers within the wood. Quartz, kaolinite, pyrite, and gypsum are the major crystalline phases identified in most of the Ge-rich and low-Ge coals, but the low-Ge coals contain significantly less pyrite and are more abundant in non-mineral Ca and Mg. Ca-oxalate of authigenic origin is observed, generally occurring as cell-fillings in the low-Ge coals. Otherwise mineral-free organic matter in the low-Ge coals would be expected to have an inherent ash yield of around 6%, derived from the inorganic elements (mainly non-mineral Ca and Mg) that occur either in the organic matter or as dissolved ions in the pore water and form the sulfate species in low-temperature (oxygen-plasma) ash residues. The highly-elevated trace elements, including Be, Ge, As, Sb, W, Hg, and Tl, that occur in the Ge-rich coals of the Wulantuga deposit, are significantly depleted in the low-Ge coals. Lateral migration of Ge–W- and As–Hg–Sb–Tl-rich solutions through the original peat swamp for the Wulantuga Ge ore deposit has led to significant enrichment of Ge on the margin of the coal basin but decreasing Ge concentrations toward to the inner part of the basin. Such a migration direction is different to those in the previously-reported for the hydrothermal solutions in the Lincang (Yunnan of China) and Spetzugli (Russian Far East) Ge ore deposits, where the solutions migrated vertically from granite to peat along faults and led to a dome-shaped Ge distribution in the relevant coal seam.  相似文献   

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