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1.
The Melilla carbonate complex (NE Morocco) is the only area of the Paleo-Mediterranean Sea where volcanic activity was present throughout most of the Messinian. 40Ar/39Ar dating of volcanic tuffs interbedded within the upper Messinian sedimentary deposits, known as the Terminal Carbonate Complex (TCC), yields accurate ages of paleoenvironmental and sea-level changes related to the Messinian Salinity Crisis. The new chronologic data (1) provide an average of 5.95–5.99 Ma for the base of the TCC, thus being synchronous with the onset of the Messinian Salinity Crisis, (2) demonstrate for the first time that the basal unconformity of the TCC does not represent a hiatus of long duration, (3) define a precise time line at 5.87±0.02 Ma (2σ) corresponding to sedimentary rocks exhibiting a lateral transition between continental and marine deposits typical of the TCC and (4) yield evidence that emersion of the Melilla platform during deposition of the TCC is partly related to tectono-magmatic activity. An erosional surface, capping the TCC deposits in the Melilla basin, is related to the major Messinian Mediterranean drawdown. The duration of the hiatus, associated with this surface, is estimated to be at most 450 kyr, but is probably shorter.  相似文献   

2.
A review of geological and geophysical observations points towards a worldwide kinematic change at around 6 Ma. The synchronicity of many manifestations (tectonics, magmatism, kinematics, ecological events, among others) at ~6 Ma, similar to those recognized from time to time on the geological time‐scale, argues for a global geodynamic event that has led to many regional consequences on Earth's surface. In particular, we propose that this global event was the main trigger for the three fold increase in sediment deposits in the world ocean over the last ~5 Ma, but also for the onset of the Messinian Salinity Crisis in the Mediterranean area, one of the most severe ecological crises in the Earth's history. We suggest this Messinian revolution to be the last occurrence of cyclic successions of global events.  相似文献   

3.
The ongoing debate about the Messinian salinity crisis in the Mediternean is fuelled in part by the lack of an adequate time control. The most accurate and, at the same time, detailed constraints are nowadays provided by the astronomical dating technique. Here we present an astronomical age model for the cyclically bedded Tripoli diatomite Formation on Sicily (pre-evaporite Messinian, Italy) based on an integrated stratigraphic study of three key-sections, Falconara, Gibliscemi and Capodarso. Characteristic sedimentary cycle patterns allow (i) the sections to be cyclostratigraphically correlated, the 'bed-to-bed' correlations being confirmed by high-resolution planktonic foraminiferal biostratigraphy, and (ii) the Tripoli cycles to be calibrated to the astronomical record. Despite minor misfits the correctness of the tuning is evident from the match between precession-obliquity interference in the astronomical target and its reflection in the sedimentary cycle record. The tuning provides absolute astronomical ages for all sedimentary cycles and planktonic foraminiferal events. The base of the Tripoli is astronomically dated at 7.005 Ma, indicating that the onset of diatomite formation is diachronous in the Mediternean since it started 300 000 years earlier on Sicily than on Gavdos, south of Crete. The top of the Tripoli, and thus the onset of the salinity crisis proper on Sicily, arrives at 5.98 Ma.  相似文献   

4.
The Rio das Velhas greenstone belt is located in the Quadrilátero Ferrífero region, in the southern extremity of the São Francisco Craton, central-southern part of the State of Minas Gerais, SE Brazil. The metavolcano–sedimentary rocks of the Rio das Velhas Supergroup in this region are subdivided into the Nova Lima and Maquiné Groups. The former occurs at the base of the sequence, and contains the major Au deposits of the region. New geochronological data, along with a review of geochemical data for volcanic and sedimentary rocks, suggest at least two generations of greenstone belts, dated at 2900 and 2780 Ma. Seven lithofacies associations are identified, from bottom to top, encompassing (1) mafic–ultramafic volcanic; (2) volcano–chemical–sedimentary; (3) clastic–chemical–sedimentary, (4) volcaniclastic association with four lithofacies: monomictic and polymictic breccias, conglomerate–graywacke, graywacke–sandstone, graywacke–argillite; (5) resedimented association, including three sequences of graywacke–argillite, in the north and eastern, at greenschist facies and in the south, at amphibolite metamorphic facies; (6) coastal association with four lithofacies: sandstone with medium- to large-scale cross-bedding, sandstone with ripple marks, sandstone with herringbone cross-bedding, sandstone–siltstone; (7) non-marine association with the lithofacies: conglomerate–sandstone, coarse-grained sandstone, fine- to medium-grained sandstone. Four generations of structures are recognized: the first and second are Archean and compressional, driven from NNE to SSW; the third is extensional and attributed to the Paleoproterozoic Transamazonian Orogenic Cycle; and the fourth is compressional, driven from E to W, is related to the Neoproterozoic Brasiliano Orogenic Cycle. Gold deposits in the Rio das Velhas greenstone belt are structurally controlled and occur associated with hydrothermal alterations along Archean thrust shear zones of the second generation of structures.Sedimentation occurred during four episodes. Cycle 1 is interpreted to have occurred between 2800 and 2780 Ma, based on the ages of the mafic and felsic volcanism, and comprises predominantly chemical sedimentary rocks intercalated with mafic–ultramafic volcanic flows. It includes the volcano–chemical–sedimentary lithofacies association and part of the mafic–ultramafic volcanic association. The cycle is related to the initial extensional stage of the greenstone belt formation, with the deposition of sediments contemporaneous with volcanic flows that formed the submarine mafic plains. Cycle 2 encompasses the clastic–chemical–sedimentary association and distal turbidites of the resedimented association, in the eastern sector of the Quadrilátero Ferrífero. It was deposited in the initial stages of the felsic volcanism. Cycle 2 includes the coastal and resedimented associations in the southern sector, in advanced stages of subduction. In this southern sedimentary cycle it is also possible to recognize a stable shelf environment. Following the felsic volcanism, Cycle 3 comprises sedimentary rocks of the volcaniclastic and resedimented lithofacies associations, largely in the northern sector of the area. The characteristics of both associations indicate a submarine fan environment transitional to non-marine successions related to felsic volcanic edifices and related to the formation of island arcs. Cycle 4 is made up of clastic sedimentary rocks belonging to the non-marine lithofacies association. They are interpreted as braided plain and alluvial fan deposits in a retroarc foreland basin with the supply of debris from the previous cycles.  相似文献   

5.
Owing to its expanded stratigraphic sections, the Apennine thrust belt offers the opportunity to better understand the evaporitic and post-evaporitic Messinian events. A physical stratigraphic framework of Messinian deposits, based on facies analysis and basin-wide correlation of key surfaces and sedimentary cycles, is presented. It is shown that the Messinian Apennine foredeep had marginal basins with shallow-water primary evaporites and deeper basins where resedimented evaporites accumulated under relatively deep-water conditions. Like many other Mediterranean examples, primary shallow-water evaporites of Apenninic marginal basins show evidence for subaerial exposure and erosion. However, the development of such an erosional surface does not correspond to the deposition of primary evaporites in the deepest part of the basin(s); here, the unconformity can be traced towards the base of resedimented evaporites or to a level within them, implying that the deeper basins of the Apennine foredeep never underwent desiccation during the Messinian salinity crisis, but rather received the eroded marginal evaporites. This fact, usually overlooked, raises important questions about the deep desiccation model of the Mediterranean.  相似文献   

6.
How the Messinian Salinity Crisis (MSC) ended is still a matter of intense debate. The Terminal Carbonate Complex (TCC) is a late Messinian carbonate platform system that recorded western Mediterranean hydrological changes from the final stages of evaporite deposition till the advent of Lago-Mare fresh- to brackish water conditions at the very end of Messinian times. A multidisciplinary study has been carried out in three localities in south-eastern Spain to reconstruct the history of TCC platforms and elucidate their significance in the MSC. Overall, this study provides evidence that the TCC formed following a regional 4th order water level rise and fall concomitant with an opening-restriction trend. It can be subdivided into four 5th order depositional sequences (DS1 to DS4) recording two phases: (1) from DS1 to DS3, a tide-dominated ooidic to oobioclastic system with stenohaline faunas developed as a result of a 70 m water level rise. During this period, the TCC developed in a shallow sea with close to normal marine salinity; (2) in depositional sequence 4, a microbialite-dominated platform system developed. This is indicative of a significant environmental change and is attributed to a 30 to 40 m water level fall in the basins under study. These restricted conditions were coeval with intense evaporite deformation and brine recycling. The syn-sedimentary deformation of evaporites had a major impact on platform architecture and carbonate production, affecting the Messinian series throughout south-eastern Spain at the end of the TCC history. At that time, the TCC developed in a lake with fluctuating, brackish- to hypersaline water. These findings suggest a temporary restoration of marine conditions in the western Mediterranean marginal basins due to Atlantic water influxes prompted by a global sea level rise around 5.6 Ma. Whether marine conditions extended to the entire western Mediterranean still needs to be investigated.  相似文献   

7.
In this paper we show that the development of the sediment architecture at the leeward toe-of-slope of Great Bahama Bank (Ocean Drilling Project Leg 166, Bahama Transect) during the last 6 Ma is not only a response to sea-level fluctuations, but also to major paleo-oceanographic and climatic changes. A major sequence boundary close to the Miocene/Pliocene boundary (dated at 5.6-5.4 Ma) is interpreted to reflect a major sea-level drop that was followed by a sea-level rise, which led to the re-flooding of the Mediterranean Sea at the end of the Messinian and increasing sea-surface temperatures at Great Bahama Bank. Distinct erosional horizons occurred during the Pliocene (dated at 4.6 and 3.3-3.6 Ma) related to sea-level change and the intensification of the Gulf Stream when the emergence of the Isthmus of Panama reached a critical threshold. The Gulf Stream brings warm, saline and nutrient-poor waters to the Bahamas. Starting at the Early-Late Pliocene boundary at 3.6 Ma this paleo-oceanographic reorganization in combination with enhanced sea-level fluctuations associated with the Late Pliocene main intensification in Northern Hemisphere Glaciation (since 3.2 Ma) led to (1) a gradual change from a ramp-type to a flat-topped type morphology, and (2) a change from a skeletal to a non-skeletal-dominated sedimentary system (mainly peloidal). Increased sea-level fluctuations during the second half of the Pleistocene led to an intensified high stand-shedding depositional pattern within the surrounding basins.  相似文献   

8.
Establishing relative and absolute time frameworks for the sedimentary, magmatic, tectonic and gold mineralisation events in the Norseman-Wiluna Belt of the Archean Yilgarn Craton of Western Australia, has long been the main aim of research efforts. Recently published constraints on the timing of sedimentation and absolute granite ages have emphasized the shortcomings of the established rationale used for interpreting the timing of deformation events. In this paper the assumptions underlying this rationale are scrutinized, and it is shown that they are the source of significant misinterpretations. A revised time chart for the deformation events of the belt is established. The first shortening phase to affect the belt, D1, was preceded by an extensional event D1e and accompanied by a change from volcanic-dominated to plutonic-dominated magmatism at approximately 2685–2675 Ma. Later extension (D2e) controlled deposition of the ca 2655 Ma Kurrawang Sequence and was followed by D2, a major shortening event, which folded this sequence. D2 must therefore have started after 2655 Ma—at least 20 Ma later than previously thought and after the voluminous 2670–2655 Ma high-Ca granite intrusion. Younger transcurrent deformation, D3–D4, waned at around 2630 Ma, suggesting that the crustal shortening deformation cycle D2–D4 lasted approximately 20–30 Ma, contemporaneous with low-volume 2650–2630 Ma low-Ca granites and alkaline intrusions. Time constraints on gold deposits suggest a late mineralisation event between 2640–2630 Ma. Thus, D2–D4 deformation cycle and late felsic magmatism define a 20–30 Ma long tectonothermal event, which culminated with gold mineralisation. The finding that D2 folding took place after voluminous high-Ca granite intrusion led to research into the role of competent bodies during folding by means of numerical models. Results suggest that buoyancy-driven doming of pre-tectonic competent bodies trigger growth of antiforms, whereas non-buoyant, competent granite bodies trigger growth of synforms. The conspicuous presence of pre-folding granites in the cores of anticlines may be a result from active buoyancy doming during folding.  相似文献   

9.
The stratigraphy of the Black Sea western margin is revisited through seismic data acquired during two French-Romanian surveys. These data are calibrated by industrial and DSDP drillings; they display several major discontinuities regarded as Tertiary erosional surfaces. The major seismic discontinuity underlines the base of Miocene formations and corresponds to a composite surface including at least three erosional phases ranging from Oligocene to Pontian times. Moreover, a Messinian erosional surface is clearly identified. This is in agreement with the Hsü's proposition [Palaeogeogr. Palaeoclimatol. Palaeoecol. 29 (1979) 75–93] suggesting a Messinian sea-level drop of Black Sea related to the Messinian Salinity Crisis described in the Mediterranean Sea. To cite this article: H. Gillet et al., C. R. Geoscience 335 (2003).  相似文献   

10.
Spectral analysis of the Messinian Abad marls in the Cariatiz section (Sorbas Basin, south-eastern Spain) reveals three relevant orders of cyclicity. The most significant cycle is in the lowest frequency (average thickness of 365 cm, 4–5 cycles in the section). It is recorded in the composition of planktic foraminiferal assemblages indicative of surface-water temperature, planktic and benthic stable isotope signals, and carbonate proportions. The planktic assemblages, isotope values and carbonate proportions also record a middle-frequency cycle with an average of 177 cm (9–10 cycles in the section). The highest frequency cycle (average of 132 cm, 12–13 cycles in the section) is mainly reflected in siliciclastic and calcite proportions. Age constraints and cycle patterns suggest that the lowest frequency cycle was forced by orbital obliquity, whereas the two higher-frequency ones are related to precession. Obliquity seems to have controlled major changes in surface-water temperature in the Sorbas Basin during the early Messinian. Surface-water temperature was also affected by precession, with changes in weathering and run-off. Spectral analysis has also been applied to vertical shifts of reef facies throughout the progradation of the Cariatiz reef. This reef is coeval with the Cariatiz section. Vertical shifts of reef talus breccias point to the existence of 4–5 major cycles of sea-level change, whereas 7–9 higher-frequency cycles are reflected in the repeated occurrence of lowstand, non-reefal deposits. Correlation with the cycles observed at the Cariatiz section suggests that obliquity forced glacio-eustatic sea-level oscillations in the western Mediterranean during the Late Miocene.  相似文献   

11.
The Messinian sediments of northeastern Tunisia were deposited under an active tectonic setting. They are organized in sequences indicating a transitional deposit from margin – littoral to lacustrine – continental facies. These series unconformably overlie the Serravallian–Tortonian silty clays packages, and are overlain by the transgressive Early Pliocene marl (Zanclean). The presence of evaporitic strata points out to the Messinian Salinity Crisis described in the peripheral basins of the western Mediterranean. The Messinian sedimentation was found to have been closely controlled by transtensive tectonics and differential subsidence at a large spatio-temporal scale. It is organized in sequences typical of a depositional environment controlled by eustatism, tectonic and maybe by climate changes. Despite the existence of some local specific sedimentological characteristics, our results corroborate previous findings that pointed out to the Messinian times as a singular period all around the Mediterranean Basin. Field and subsurface seismic profile data helped reconstructing either the sedimentary or tectonic unconformities existing between the studied Messinian series and older Neogene successions.  相似文献   

12.
New U–Pb and Rb–Sr geochronology on syn- and post-orogenic granites provide constraints on the timing of major tectonic events in the Songpan–Garzê fold belt, west Sichuan, China. The Ma Nai granite was probably syn-kinematic with the main deformation and yields an age of 197±6 Ma that is interpreted as an upper age limit of the Indosinian event. Zircons and apatites from the post-kinematic Rilonguan granite also yield Jurassic ages (195±6 and 181±4 Ma). The post-orogenic Markam massif gives two ages of 188±1 and 153±3 Ma. Both granites are undeformed and cut structures in the Triassic sedimentary rocks. These results demonstrate that the major deformation and décollement tectonics in the Songpan–Garzê fold belt occurred prior to the Early Jurassic. The wide range of ages obtained for post-kinematic granites (from Early Jurassic to Late Jurassic) suggests that, locally, magmatic activity persisted for a long time (at least 50 Ma) after the Indosinian compressional tectonism. No Tertiary ages have been obtained, suggesting that these granites were not affected strongly by the India–Asia collision.  相似文献   

13.
川东北地区沉积波动特征与油气成藏   总被引：1，自引：1，他引：0  
川东北地区是上扬子板块北缘的中新生代含油气盆地,具有复杂的构造和成藏历史。采用沉积波动方法对其进行分析,研究了川东北地区沉积波动过程的主要周期,得出控制该区沉积波动的5个周期分别为760、220、100、35、20 Ma,以及存在2个周期为200 Ma的一级波动周期和4个周期为100 Ma的二级波动周期。通过分析二级波动周期与成藏旋回的关系,将该区分为3个成藏旋回。  相似文献   

14.
The Gran Sasso range is a striking salient formed by two roughly rectilinear E–W and N–S limbs. In the past 90° counterclockwise (CCW) rotations from the eastern Gran Sasso were reported [Tectonophysics 215 (1992) 335], suggesting west–east increase of rotation-related northward shortening along the E–W limb. In this paper, we report on paleomagnetic data from Meso-Cenozoic sedimentary dykes and strata cropping out at Corno Grande (central part of the E–W Gran Sasso limb), the highest summit of the Apennine belt. Predominant northwestward paleomagnetic declinations (in the normal polarity state) from both sedimentary dykes and strata are observed. When compared to the expected declination values for the Adriatic foreland, our data document no thrusting-related rotation at Corno Grande. The overall paleomagnetic data set coupled with the available geological information shows that the Gran Sasso arc is in fact a composite structure, formed by an unrotated-low shortening western (E–W trending) limb and a strongly CCW rotated eastern salient. Late Messinian and post-early Pliocene shortening episodes documented along the Gran Sasso front indicate that belt building and arc formation occurred during two distinct episodes. We suggest that the southern part of a late Messinian N–S front was reactivated during early–middle Pliocene time, forming a tight range salient due to CCW rotations and differential along-front shortening rates. The formation of a northward displacing bulge in an overall NW–SE chain is likely a consequence of the collision between the Latium-Abruzzi and Apulian carbonate platforms during northeastward propagation of the Apennine wedge, inducing lateral northward extrusion of Latium-Abruzzi carbonates towards ductile basinal sediment areas.  相似文献   

15.
We propose a revised age calibration of the Messinian salinity crisis onset in the Mediterranean at 5.971 Ma based on the recognition of an extra gypsum cycle in the transitional interval of the Perales section (Sorbas basin, Spain) and the revision of the magnetostratigraphy of the Monticino section (Vena del Gesso basin, Italy). This age re‐calibration allows to state more accurately that: (i) the interval encompassing the MSC‐onset is continuous, thus ruling out any erosional feature or stratigraphic hiatus related to a major sea‐level fall affecting the Mediterranean; (ii) the first gypsum was deposited during the summer insolation peak at 5.969 Ma associated with an eccentricity minimum and roughly coincident with glacial stage TG32; (iii) the MSC‐onset was preconditioned by the tectonically‐driven reduction of the hydrological exchanges with the Atlantic Ocean and finally triggered by glacial conditions in the northern hemisphere and by arid conditions in northern Africa.  相似文献   

16.
The age of spreading of the Liguro–Provençal Basin is still poorly constrained due to the lack of boreholes penetrating the whole sedimentary sequence above the oceanic crust and the lack of a clear magnetic anomaly pattern. In the past, a consensus developed over a fast (20.5–19 Ma) spreading event, relying on old paleomagnetic data from Oligo–Miocene Sardinian volcanics showing a drift-related 30° counterclockwise (CCW) rotation. Here we report new paleomagnetic data from a 10-m-thick lower–middle Miocene marine sedimentary sequence from southwestern Sardinia. Ar/Ar dating of two volcanoclastic levels in the lower part of the sequence yields ages of 18.94±0.13 and 19.20±0.12 Ma (lower–mid Burdigalian). Sedimentary strata below the upper volcanic level document a 23.3±4.6° CCW rotation with respect to Europe, while younger strata rapidly evolve to null rotation values. A recent magnetic overprint can be excluded by several lines of evidence, particularly by the significant difference between the in situ paleomagnetic and geocentric axial dipole (GAD) field directions. In both the rotated and unrotated part of the section, only normal polarity directions were obtained. As the global magnetic polarity time scale (MPTS) documents several geomagnetic reversals in the Burdigalian, a continuous sedimentary record would imply that (unrealistically) the whole documented rotation occurred in few thousands years only. We conclude that the section contains one (or more) hiatus(es), and that the minimum age of the unrotated sediments above the volcanic levels is unconstrained. Typical back-arc basin spreading rates translate to a duration ≥3 Ma for the opening of the Liguro–Provençal Basin. Thus, spreading and rotation of Corsica–Sardinia ended no earlier than 16 Ma (early Langhian). A 16–19 Ma, spreading is corroborated by other evidences, such as the age of the breakup unconformity in Sardinia, the age of igneous rocks dredged west of Corsica, the heat flow in the Liguro–Provençal Basin, and recent paleomagnetic data from Sardinian sediments and volcanics. Since Corsica was still rotating/drifting eastward at 16 Ma, it presumably induced significant shortening to the east, in the Apennine belt. Therefore, the lower Miocene extensional basins in the northern Tyrrhenian Sea and margins can be interpreted as synorogenic “intra-wedge” basins due to the thickening and collapse of the northern Apennine wedge.  相似文献   

17.
Jos  M. Martí  n  Juan C. Braga 《Sedimentary Geology》1994,90(3-4):257-268
The Messinian (Late Miocene) marine stratigraphic record of the Sorbas Basin (S.E. Spain) is well preserved and can be considered as being representative of the entire western Mediterranean. It exhibits a series of features relating to: (1) the composition, characteristics and evolution of coral reefs; (2) changes between temperate and subtropical climates; and (3) the extensive development of microbial carbonates (stromatolites and thrombolites) at the end of the Messinian. Each of these features has global significance.

Porites, which is the major and almost only coral component in reefs, is heavily encrusted with stromatolites. These reefs grew at the edge of the subtropical belt and were totally eliminated at the end of the Messinian because of global cooling.

Lowermost-Messinian carbonate sediments in the Sorbas Basin reflect a temperate climate, whereas those immediately above, which contain bioherms and coastal reefs, are subtropical. The shift from temperate to subtropical conditions during the early Messinian was accompanied by an important change in water circulation within the western Mediterranean. Temperate times were marked by cold surface Atlantic waters entering the Mediterranean, whereas subtropical times coincided with warm surface waters entering the western Mediterranean from the east. The subtropical waters were thermally stratified, which favoured the deposition of euxinic marls and diatomites at the centre of the basin. The upwelling of nutrient-rich water promoted stromatolite development within reefs and Halimeda growth on adjacent slopes.

Lastly, microbial carbonates (stromatolites and thrombolites) attained giant dimensions during the late Messinian, which can be regarded as a measure of their success in occupying a variety of ecological niches. This abundance of available habitats is believed to have resulted from the Messinian “salinity crisis”, which was followed by a re-colonization of the western Mediterranean. In this context stromatolite proliferation was due to opportunism of microbial communities in colonizing the new environments, rather than to a complete absence of other competitive biota. We do not believe that hypersaline conditions were a causal factor in stromatolite development because of the normal-marine biota associated with them.  相似文献   


18.
The Rei Bouba Group is a sedimentary and volcanic sequence (750–?650 Ma), regarded as a remnant of a Pan-African (back-arc?) orogenic basin that separated a remobilized Paleoproterozoic crust from an accretionary area (Poli Complex: 800-650 Ma). The latter was subjected to early deformation (D1) and intruded by calc-alkalic plutons (670 Ma). Transpressive tectonics and major thrusting, with emplacement of synkinematic granite, occurred at ca 630 Ma (D2-3) and a late compression (D4), with emplacement of calc-alkalic granite, occurred at ca 570 Ma. The Tcholliré Shear Zone is regarded as part of the major boundary between a recently accreted crust and the remobilized margin of the Congo Craton.  相似文献   

19.
Surface microlayer and subsurface water samples were collected at an oligotrophic Mediterranean site during a diel cycle. The composition of phospholipid ester-linked fatty acids (PLFA) was determined in size-fractionated particles (0.2–0.7 μm; 0.7–200 μm) in order to characterize the major contributors of organic matter to different size fractions. GF/F-retained particles (0.7–200 μm) from the surface microlayer were consistently enriched in PLFA relative to the underlying water. Molecular markers revealed a substantial difference in biological assemblages in both particle sizes. The larger particles were dominated by dinoflagellates, cyanobacteria, microzooplankton and attached bacteria, whereas particles filtered through GF/F and collected on 0.2 μm porosity Durapore filters (0.2–0.7 μm) were mostly bacteria and heterotrophic flagellates. Bacterial PLFA associated with 0.7–200 μm particles were more abundant than those in the 0.2–0.7 μm particles. Specific markers in the branched series appeared more representative of bacteria of smaller particle size.  相似文献   

20.
The Itacaiúnas Belt of the highly mineralised Carajás Mineral Province comprises ca. 2.75 Ga volcanic rocks overlain by sedimentary sequences of ca. 2.68 Ga age, that represent an intracratonic basin rather than a greenstone belt. Rocks are generally at low strain and low metamorphic grade, but are often highly deformed and at amphibolite facies grade adjacent to the Cinzento Strike Slip System. The Province has been long recognised for its giant enriched iron and manganese deposits, but over the past 20 years has been increasingly acknowledged as one of the most important Cu–Au and Au–PGE provinces globally, with deposits extending along an approximately 150 km long WNW-trending zone about 60 km wide centred on the Carajás Fault. The larger deposits (approx. 200–1000 Mt @ 0.95–1.4% Cu and 0.3–0.85 g/t Au) are classic Fe-oxide Cu–Au deposits that include Salobo, Igarapé Bahia–Alemão, Cristalino and Sossego. They are largely hosted in the lower volcanic sequences and basement gneisses as pipe- or ring-like mineralised, generally breccia bodies that are strongly Fe- and LREE-enriched, commonly with anomalous Co and U, and quartz- and sulfur-deficient. Iron oxides and Fe-rich carbonates and/or silicates are invariably present. Rhenium–Os dating of molybdenite at Salobo and SHRIMP Pb–Pb dating of hydrothermal monazite at Igarapé-Bahia indicate ages of ca. 2.57 Ga for mineralisation, indistinguishable from ages of poorly-exposed Archean alkalic and A-type intrusions in the Itacaiúnas Belt, strongly implicating a deep magmatic connection.A group of smaller, commonly supergene-enriched Cu–Au deposits (generally < 50 Mt @ < 2% Cu and < 1 g/t Au in hypogene ore), with enrichment in granitophile elements such as W, Sn and Bi, spatially overlap the Archean Fe-oxide Cu–Au deposits. These include the Breves, Águas Claras, Gameleira and Estrela deposits which are largely hosted by the upper sedimentary sequence as greisen-to ring-like or stockwork bodies. They generally lack abundant Fe-oxides, are quartz-bearing and contain more S-rich Cu–Fe sulfides than the Fe-oxide Cu–Au deposits, although Cento e Dezoito (118) appears to be a transitional type of deposit. Precise Pb–Pb in hydrothermal phosphate dating of the Breves and Cento e Dezoito deposits indicate ages of 1872 ± 7 Ma and 1868 ± 7 Ma, respectively, indistinguishable from Pb–Pb ages of zircons from adjacent A-type granites and associated dykes which range from 1874 ± 2 Ma to 1883 ± 2 Ma, with 1878 ± 8 Ma the age of intrusions at Breves. An unpublished Ar/Ar age for hydrothermal biotite at Estrela is indistinguishable, and a Sm–Nd isochron age for Gameleira is also similar, although somewhat younger. The geochronological data, combined with geological constraints and ore-element associations, strongly implicate a magmatic connection for these deposits.The highly anomalous, hydrothermal Serra Pelada Au–PGE deposit lies at the north-eastern edge of the Province within the same fault corridor as the Archean and Paleoproterozoic Cu–Au deposits, and like the Cu–Au deposits is LREE enriched. It appears to have formed from highly oxidising ore fluids that were neutralised by dolomites and reduced by carbonaceous shales in the upper sedimentary succession within the hinge of a reclined synform. The imprecise Pb–Pb in hydrothermal phosphate age of 1861 ± 45 Ma, combined with an Ar/Ar age of hydrothermal biotite of 1882 ± 3 Ma, are indistinguishable from a Pb–Pb in zircon age of 1883 ± 2 Ma for the adjacent Cigano A-type granite and indistinguishable from the age of the Paleoproterozoic Cu–Au deposits. Again a magmatic connection is indicated, particularly as there is no other credible heat or fluid source at that time.Finally, there is minor Au–(Cu) mineralisation associated with the Formiga Granite whose age is probably ca. 600 Ma, although there is little new zircon growth during crystallisation of the granite. This granite is probably related to the adjacent Neoproterozoic (900–600 Ma) Araguaia Fold Belt, formed as part of the Brasiliano Orogeny.Thus, there are two major and one minor period of Cu–Au mineralisation in the Carajás Mineral Province. The two major events display strong REE enrichment and strongly enhanced LREE. There is a trend from strongly Fe-rich, low-SiO2 and low-S deposits to quartz-bearing and more S-rich systems with time. There cannot be significant connate or basinal fluid (commonly invoked in the genesis of Fe-oxide Cu–Au deposits) involved as all host rocks were metamorphosed well before mineralisation: some host rocks are at mid- to high-amphibolite facies. The two major periods of mineralisation correspond to two periods of alkalic to A-type magmatism at ca. 2.57 Ga and ca. 1.88 Ga, and a magmatic association is compelling.The giant to world-class late Archean Fe-oxide Cu–Au deposits show the least obvious association with deep-seated alkaline bodies as shown at Palabora, South Africa, and implied at Olympic Dam, South Australia. The smaller Paleoproterozoic Cu–Au–W–Sn–Bi deposits and Au–PGE deposit show a more obvious relationship to more fractionated A-type granites, and the Neoproterozoic Au–(Cu) deposit to crustally-derived magmas. The available data suggest that magmas and ore fluids were derived from long-lived metasomatised lithosphere and lower crust beneath the eastern margin of the Amazon Craton in a tectonic setting similar to that of other large Precambrian Fe-oxide Cu–Au deposits.  相似文献   

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