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1.
High As contents in groundwater were found in Rayen area and chosen for a detailed hydrogeochemical study. A total of 121 groundwater samples were collected from existing tube wells in the study areas in January 2012 and analyzed. Hydrogeochemical data of samples suggested that the groundwater is mostly Na–Cl type; also nearly 25.62 % of samples have arsenic concentrations above WHO permissible value (10 μg/l) for drinking waters with maximum concentration of aqueous arsenic up to 25,000 μg/l. The reducing conditions prevailing in the area and high arsenic concentration correlated with high bicarbonate and pH. Results show that arsenic is released into groundwater by two major phenomena: (1) through reduction of arsenic-bearing iron oxides/oxyhydroxides and Fe may be precipitated as iron sulfide when anoxic conditions prevail in the aquifer sediments and (2) transferring of As into the water system during water–acidic volcanic rock interactions.  相似文献   

2.
Arsenic occurrence in groundwater near the Cimino-Vico volcanoes (central Italy) was analysed considering the hydrostratigraphy and structural setting and the shallow and deep flows interacting within the Quaternary volcanics. Groundwater is the local source of drinking water. As documented in the past, arsenic in the groundwater has become a problem, and the European maximum allowable contaminant level was recently lowered to 10 μg/L. Chemical analyses of groundwater were conducted, sampled over an area of about 900 km2, from 65 wells and springs representative of the volcanic aquifer and thermal waters. Considering the type of aquifer, the nature of the aquifer formation and its substratum, the hydrochemical data highlight that the arsenic content of the groundwater is mainly connected with the hydrothermal processes in the volcanic area. Thermal waters (54–60°C) fed from deep-rising fluids show higher arsenic concentrations (176–371 μg/L). Cold waters sampled from the volcanic aquifer are characterized by a wide variability in their arsenic concentration (1.6–195 μg/L), and about 62% exceed the limit of 10 μg/L. Where the shallow volcanic aquifer is open to deep-rising thermal fluids, relatively high arsenic concentrations (20–100 μg/L) are found. This occurs close to areas of the more recent volcano-tectonic structures.  相似文献   

3.
High arsenic levels in groundwater of the aquifers, belonging to the Pliocene terrestrial layers and Quaternary alluvial sediments, have become a significant problem for the inhabitants living in Sarkisla (Turkey). The main objective of this study was to determine the origin and arsenic contamination mechanisms of the Sarkisla drinking water aquifer systems. The highest arsenic concentrations were found in Pliocene layers and alluvial sediments with concentrations ranging from 2.1 to 155 mg/kg. These rocks are the main aquifers in the study area, and most of the drinking groundwater demand is met by these aquifers. Groundwater from the Pliocene aquifer is mainly Ca-HCO3 and Ca-SO4 water type with high EC values reaching up to 3,270 μS/cm, which is due to the sulfate dissolution in some parts of the alluvial aquifer. Stable isotope values showed that the groundwater was of meteoric origin. Tritium values for the groundwater were between 8.31 and 14.06 TU, representing a fast circulation in the aquifer. Arsenic concentrations in the aquifers were between 0.5 and 345 μg/L. The highest arsenic concentrations detected in the Pliocene aquifer system reached up to 345 μg/L with an average value of 60.38 μg/L. The arsenic concentrations of the wells were high, while the springs had lower arsenic concentrations. These springs are located in the upper parts of the study area where the rocks are less weathered. The hydrogeochemical properties demonstrated that the water–rock interaction processes in sulfide-bearing rocks were responsible for the remarkably high groundwater arsenic contamination in the study area. In the study area, the arsenic levels determined in groundwater exceeded the levels recommended by the WHO. Therefore, it is suggested that this water should not be used for drinking purposes and new water sources should be investigated.  相似文献   

4.
Groundwater arsenic survey in Cachar and Karimganj districts of Barak Valley, Assam shows that people in these two districts are drinking arsenic-contaminated (max. 350 μg/l) groundwater. 66% of tubewells in these two districts have arsenic concentration above the WHO guideline value of 10 μg/l and 26% tubewells have arsenic above 50 μg/l, the Indian standards for arsenic in drinking water. 90% of installed tubewells in these two districts are shallow depth (14–40 m). Shallow tubewells were installed in Holocene Newer Alluvium aquifers are characterised by grey to black coloured fine grained organic rich argillaceous sediments and are mostly arsenic contamination in groundwater. Plio-Pleistocene Older Alluvium aquifers composed of shale, ferruginous sandstone, mottle clay, pebble and boulder beds, which at higher location or with thin cover of Newer Alluvium sediments are safe in arsenic contamination in groundwater. 91% of tubewell water samples show significantly higher concentrations of iron beyond its permissible limit of 1 mg/l. The iron content in these two districts varies from 0.5 to as much as 48 mg/l. Most of the arsenic contaminated villages of Cachar and Karimganj districts are located in entrenched channels and flood plains of Newer Alluvium sediments in Barak-Surma-Langai Rivers system. However, deeper tubewells (>60 m) in Plio-Pleistocene Older Alluvium aquifers would be a better option for arsenic-safe groundwater. The arsenic in groundwater is getting released from associated Holocene sediments which were likely deposited from the surrounding Tertiary Barail hill range.  相似文献   

5.
Groundwater arsenic contamination and its health effects in India   总被引：2，自引：0，他引：2  
During a 28-year field survey in India (1988–2016), groundwater arsenic contamination and its health effects were registered in the states of West Bengal, Jharkhand, Bihar and Uttar Pradesh in the Ganga River flood plain, and the states of Assam and Manipur in the flood plain of Brahamaputra and Imphal rivers. Groundwater of Rajnandgaon village in Chhattisgarh state, which is not in a flood plain, is also arsenic contaminated. More than 170,000 tubewell water samples from the affected states were analyzed and half of the samples had arsenic >10 μg/L (maximum concentration 3,700 μg/L). Chronic exposure to arsenic through drinking water causes various health problems, like dermal, neurological, reproductive and pregnancy effects, cardiovascular effects, diabetes mellitus, diseases of the respiratory and gastrointestinal systems, and cancers, typically involving the skin, lungs, liver, bladder, etc. About 4.5% of the 8,000 children from arsenic-affected villages of affected states were registered with mild to moderate arsenical skin lesions. In the preliminary survey, more than 10,000 patients were registered with different types of arsenic-related signs and symptoms, out of more than 100,000 people screened from affected states. Elevated levels of arsenic were also found in biological samples (urine, hair, nails) of the people living in affected states. The study reveals that the population who had severe arsenical skin lesions may suffer from multiple Bowens/cancers in the long term. Some unusual symptoms, such as burning sensation, skin itching and watering of eyes in the presence of sun light, were also noticed in arsenicosis patients.  相似文献   

6.
Arsenic contamination of well water is a serious issue in the Nawalparasi District of the Terai region in Nepal. A local investigation was carried out on 137 tube wells in 24 communities of the district in December 2011. The investigation revealed that the average arsenic concentration in the tube wells was 350 μg/L, and that nearly 98 % of the wells exceeded the WHO guideline arsenic level limit of 10 μg/L. Highly contaminated well water, with more than 400 μg/L of arsenic, was found within the limited depth ranges of 18–22 and 50–80 m. High arsenic levels exceeding 500 μg/L were detected in shallower wells at Patkhauli, Mahuawa, Thulokunwar, and Goini located between 27.517° and 27.543°N and between 83.648° and 83.748°E. Boring sampling at five communities of Kashiya, Goini, Sanokunwar, Thulokunwar, and Mahuawa revealed two aquifers located at the two depths around 14–22 and 41–50 m in each community. Dark gray or black-colored peaty clay layers rich in organic matter were distributed at depths of 18–21 m beside the upper aquifers with high arsenic concentration in each community. Positive correlations were shown between iron and arsenic in the sediments from the five communities. It can be inferred that these results were caused by dissolution of iron-oxyhydroxide molecules with arsenic from solid phases. Microbial metabolisms have a great potential to induce the dissolution and release arsenic attached on the solid phases into aqueous phases depending on the level of redox potential and pH.  相似文献   

7.
Groundwater pollution by arsenic is a major health threat in suburban areas of Hanoi, Vietnam. The present study evaluates the effect of the sedimentary environments of the Pleistocene and Holocene deposits, and the recharge systems, on the groundwater arsenic pollution in Hanoi suburbs distant from the Red River. At two study sites (Linh Dam and Tai Mo communes), undisturbed soil cores identified a Pleistocene confined aquifer (PCA) and Holocene unconfined aquifer (HUA) as major aquifers, and Holocene estuarine and deltaic sediments as an aquitard layer between the two aquifers. The Holocene estuarine sediments (approximately 25–40 m depth, 9.6–4.8 cal ka BP) contained notably high concentrations of arsenic and organic matter, both likely to have been accumulated by mangroves during the Holocene sea-level highstand. The pore waters in these particular sediments exhibited elevated levels of arsenic and dissolved organic carbon. Arsenic in groundwater was higher in the PCA (25–94 μg/L) than in the HUA (5.2–42 μg/L), in both the monitoring wells and neighboring household tubewells. Elevated arsenic concentration in the PCA groundwater was likely due to vertical infiltration through the arsenic-rich and organic-matter-rich overlying Holocene estuarine sediments, caused by massive groundwater abstraction from the PCA. Countermeasures to prevent arsenic pollution of the PCA groundwater may include seeking alternative water resources, reducing water consumption, and/or appropriate choice of aquifers for groundwater supply.  相似文献   

8.
Sedimentary rocks of Jurassic age (Ferozabad group) and igneous rocks (Bela Ophiolite) of Cretaceous age are widely exposed in the east of Winder Town, Balochistan. Representative 48 water and soil samples were collected and analyzed for Cd and other elements. The present study showed that water samples were contaminated by the Cd ion and most of the samples have higher concentration than prescribed WHO standards (3 μg/l) for drinking purpose. The concentration of Cd ions ranged between 1 and 30 with mean values of 10 μg/l and was found high in the vicinity of outcrops. The alkaline pH (av. 7.42) was mainly responsible for elevated Cd content in the water, having near equal molar proportions of Ca and HCO3 ions. Computed relative mobility values appeared as 0.23, indicating poor leaching from rocks and metal load in the groundwater is also measured low. The estimated values of mobility reflect fairly high mobility of Cd in the study area, decreases with distance from outcrops. The health hazard indices of drinking water was high (av. 1.33) with respect to safe average daily intake of Cd. The consumption of high Cd-bearing water may induce many disorders in the human health.  相似文献   

9.
Rock–water interaction along with mineral dissolution/ precipitation plays a profound role in the control of fluoride ion concentration within the alluvial groundwater in a part of semi-arid northern India. In the premonsoon season, the alluvial region experiences evaporative processes leading to increase in Na+ ions which through reverse ion exchange processes are adsorbed onto suitable sites within the aquifer matrix in exchange for Ca2+ ion in solution. Increase in Ca2+ ions in solution inhibits fluorite mineral dissolution, thereby controlling premonsoon fluoride ion concentration within alluvial groundwaters (1.40?±?0.5 mg/l). In the postmonsoon season, however, higher average fluoride ion concentration within the alluvial aquifer samples (2.33?±?0.80 mg/l) is observed mainly due to increase in silicate weathering of fluoride-bearing rocks and direct ion exchange processes enabling Ca2+ ion uptake from solution accompanied with the release of fluoride ions. Combined effect of these processes results in average fluoride ion concentration falling above the WHO drinking water permissible limit (1.5 mg/l). Alternatively, the hard rock aquifer samples within the study area have an average fluoride ion concentration falling below the permissible limit in both the seasons.  相似文献   

10.
The authors’ survey of the Ganga–Meghna–Brahmaputra (GMB) plain (area 569,749 km2; population >500 million) over the past 20 years and analysis of more than 220,000 hand tube-well water samples revealed groundwater arsenic contamination in the floodplains of the Ganga–Brahmaputra river (Uttar Pradesh, Bihar, Jharkhand, West Bengal, and Assam) in India and the Padma–Meghna–Brahmaputra river in Bangladesh. On average, 50 % of the water samples contain arsenic above the World Health Organization guideline value of 10 μg/L in India and Bangladesh. More than 100 million people in the GMB plain are potentially at risk. The authors’ medical team screened around 155,000 people from the affected villages and registered 16,000 patients with different types of arsenical skin lesions. Arsenic neuropathy and adverse pregnancy outcomes have been recorded. Infants and children drinking arsenic-contaminated water are believed to be at high risk. About 45,000 biological samples analyzed from arsenic-affected villages of the GMB plain revealed an elevated level of arsenic present in patients as well as non-patients, indicating that many are sub-clinically affected. In West Bengal and Bangladesh, there are huge surface water in rivers, wetlands, and flooded river basins. In the arsenic-affected GMB plain, the crisis is not over water scarcity but about managing the available water resources.  相似文献   

11.
Here we present the first systematic investigation of volatile geochemistry along the Southern Volcanic Zone (SVZ) of Chile. Holocene olivine-hosted melt inclusions in the most mafic tephras sampled from 16 volcanoes along the volcanic front of the SVZ between 33°S and 43°S were analysed for pre-eruptive sulphur, chlorine, and major element contents. These results are combined with trace element compositions of the host whole rocks. The highest fractionation-corrected gas contents occur in the least-degassed melt inclusions from small monogenetic cones of Los Hornitos, Cabeza de Vaca, and Apagado from both the transitional and the southern-central SVZ, reaching ~3,000 μg/g S and 1,400 μg/g Cl, while the lowest abundances of ~1,100 μg/g S and ~600 μg/g Cl were found in the central SVZ at Volcán Lonquimay, Volcán Llaima, and Volcán Villarrica. Chlorine co-varies with trace element indicators for the degree of melting and/or source enrichment, such that the lowest Cl contents are found in high-degree melts from the most depleted mantle sources. The size of the volcanic edifices correlates inversely with Cl abundances in the melt. This could reflect more extensive degassing during ascent through the complex magma plumbing systems beneath the stratovolcanoes or greater dilution during larger degrees of melting of more depleted sources, or a combination of these factors. Compared to other subduction zones, the SVZ melt inclusions exhibit Cl and S abundances in the same range as most of those from the Central American and those from the Marianas arcs.  相似文献   

12.
The sediment from an acid mine drainage affected reservoir of Guizhou province of China has the iron and arsenic concentration of about 400 and 2.6 g/kg, respectively. Sediment cores were collected, and were used to study the arsenic behavior in the seriously acidified reservoir from the viewpoint of chemical thermodynamics. The limestone neutralization and ferric iron hydrolysis regulated the porewater pH from about 2.9–5.8. The reductive dissolution of As–Fe-rich (hydr)oxides under the mild acidic conditions was the main mechanism for the release of absorbed arsenic into porewater. The maximum concentrations of iron, sulfate and arsenic reached to about 2,800, 9,000 and 1 mg/l, respectively. Arsenic speciation transformation and hydrous ferric oxide (HFO) crystallization enhanced the arsenic mobility in sediment. In addition, the iron sulfide minerals diagenesis could play a role in removing the dissolved arsenic from porewater. The actual distribution of arsenic concentration in porewater was well simulated using the model of surface complexation of arsenic to HFO. Although arsenic concentration in porewater could be above 100 times higher than that of reservoir water, it was not easy to release into the reservoir water through diffusion, because the shallow sediment had relatively strong arsenic adsorption capacity, and new HFO could be generated continuously at the sediment water interface.  相似文献   

13.
In order to address the problem of realistic assessment of groundwater potential and its sustainability, it is vital to study the recharge processes and mechanism of groundwater flow in fractured hard rocks, where inhomogeneties and discontinuities have a dominant role to play. Wide variations in chloride, δ18O and 14C concentrations of the studied groundwaters observed in space and time could only reflect the heterogeneous hydrogeological setting in the fractured granites of Hyderabad (India). This paper, based on the observed isotopic and environmental chloride variations of the groundwater system, puts forth two broad types of groundwaters involving various recharge processes and flow mechanisms in the studied granitic hard rock aquifers. Relatively high 14C ages (1300 to ～6000 yr B.P.), δ18O content (?3.2 to ?1.5‰) and chloride concentration (<100 mg/l) are the signatures that identified one broad set of groundwaters resulting from recharge through weathered zone and subsequent movement through extensive sheet joints. The second set of groundwaters possessed an age range Modern to ～1000 yr B.P., chloride in the range 100 to ～350 mg/l and δ18O from ?3.2 to +1.7‰. The δ18O enrichment and chloride concentration, further helped in the segregation of the second set of groundwaters into three sub-sets characterized by different recharge processes and sources. Based on these processes and mechanisms, a conceptual hydrogeologic model has evolved suggesting that the fracture network is connected either to a distant recharge source or to a surface reservoir (evaporating water bodies) apart from overlying weathered zone, explaining various resultant groundwaters having varying 14C ages, chloride and δ18O concentrations. The surface reservoir contribution to groundwater is evaluated to be significant (40 to 70%) in one subset of groundwaters. The conceptual hydrogeologic model, thus evolved, can aid in understanding the mechanism of groundwater flow as well as migration of contaminants to deep groundwater in other fractured granitic areas.  相似文献   

14.
A groundwater arsenic (As) survey in Mirzapur, Varanasi, Ghazipur, Ballia, Buxar, Ara, Patna, and Vaishali districts of UP and Bihar shows that people from these districts are drinking As-contaminated groundwater (max. 1,300 μg/l). About 66 % of tubewells from Buxar to Mirzapur areas and 89 % of tubewells from Patna to Ballia areas have As?>?10 μg/l (WHO guideline). Moreover, 36 % of tubewells from Buxar to Mirzapur areas and 50 % of tubewells from Patna to Ballia areas have As above 50 μg/l. Most of the As-affected villages are located close to abandoned or present meander channels of the Ganga River. In contrast, tubewells located in Mirzapur, Chunar, Varanasi, Saidpur, Ghazipur, Muhammadabad, Ballia, Buxar, Ara, Chhapra, Patna, and Hazipur towns are As-safe in groundwater because of their positions on the Pleistocene Older Alluvium upland surfaces. The iron (Fe) content in tubewell water samples varies from 0.1 to 12.93 mg/l. About 77 % As-contaminated tubewells are located within the depth of 21 to 40 m in the Holocene Newer Alluvium aquifers. The potential source of As in sediments carried through the rivers from the Himalayas. Maximum As concentrations in the Older and Newer Alluvium sediments are 13.73 and 30.91 mg/kg, respectively. The Himalayas rivers, i.e. Yamuna, Ganga, Gomati, Ghaghara, Gondak, Buri Gandak, and Kosi rivers carrying suspended sediments have high content of As (max. 10.59 mg/kg).  相似文献   

15.
The occurrence of minor toxic elements (arsenic, vanadium and fluoride among others) in the volcanic aquifers of central Italy, with concentrations often above the national standards for drinking waters, has been recognized since the 1970s. However, these groundwaters are still often used for human consumption. With the aim of providing insight into the water–rock interaction processes, as well as into the evolution of arsenic and other elements, water-sampling campaigns where undertaken within a 100 km2 area at the eastern margin of the Viterbo region, where volcanites overlie an alluvial aquifer complex. The samples were analysed and geochemical modelling was applied to characterize the thermodynamic state of the waters. The results indicate the existence of direct relations among arsenic, vanadium and fluoride concentrations and of their inverse relationship with calcium concentration. An evolution scheme of groundwater composition from the upstream volcanic aquifer to the downstream sedimentary aquifer is also discussed. Two hypotheses are proposed which justify the observed decrease of the cited minor element concentrations, i.e. dilution processes and/or precipitation of fluorapatite, which can include in its structure small amounts of these elements. The precipitation hypothesis is supported by modelling results.  相似文献   

16.
Mineralogical and geochemical studies were undertaken in the volcanic area of Biancavilla (Catania, Italy) with the aim of explaining the nature of the high As and F contents of the area’s rocks. As and F contents in soils and groundwater were also investigated. The metasomatised benmoreite lavas show fluorine and arsenic concentrations up to about 3,000 and 1,000 mg/kg, respectively. Mineralogical analyses show that fluorine occurs mostly in fluoro-edenite and apatite-(CaF) crystals, both abundantly present in the altered rocks, while As is exclusively attributed to the apatite-(CaF) crystals. Specifically, arsenic was observed only at the borders of these apatite crystals. Leaching tests and sequential extraction procedures were carried out to evaluate the potential remobilisation of As and F by the mineral phases and the eventual risks induced by their spreading. The results of the leaching tests suggest that As is almost totally associated with the ‘easily reducible’ fraction and that it is released by the preferential dissolution of the arsenic enriched rims of apatite-(CaF) crystals. In soils, As concentration is relatively low (about 15 mg/kg, on average), while F ranges from 236 to 683 mg/kg. The underground waters supplying the town of Biancavilla show As and F contents lower than the allowed limits for drinking water, (As:10 μg/L, F:1–1.5 mg/L). The limited distribution of these rocks and the relatively limited mobilisation by the minerals both contribute to maintain low As and F values, in soils and groundwaters, despite the high values in metasomatised lava samples.  相似文献   

17.
The dissolved ionic constitutents of groundwaters are,in part,a recored of the minerals and rocks in aquifers through which the water has flowed.The chemical composition and association of these major ions in groundwaters have been used to trace groundwater flow paths and sources,In general,the chemical compostion of water in carbonate-rock aquifers in dominated by calcium,magnesium,and bicarbonate,whereas sodium,chloride,and sulfate can be dominant ions in the water that comes from volcanic aquifers or clay minerals.Since the 1990‘s,we have dealt with the geochemistry of groundwaters from more than 100 springs and wells in southern Nevada and eastrn california ,USA for major solutes and trace elements.This paper compiles the hydrochemical data of major ions of these groundwaters.Based on major ion geochemistry,groundwaters from southern Nevada and eastern California can be classified as carbonate aquifer water,volcanic aquifer water,and mixing water (either mixing of cabonate and volcanic aquifer waters or mixing with local recharges),Piper and stiff diagrams of major ions have graphically shown the general chemical characteristics,classification,and mixing relationships of groundwaters from southern Nevada and eastern California.  相似文献   

18.
Concentrations of lead (Pb) in domestic water and blood plasma in the Olya and Al-Batha regions of Riyadh City, Saudi Arabia were correlated (r 2?=?0.03, p?<?0.0072 and r 2?=?0.37, p?<?0.00092, respectively). Greater concentrations of Pb in domestic water of Olya and Al-Batha (0.0119 and 0.03 mg/l, respectively) were greater than concentrations of Pb in bottled water and was also greater than the concentration of 0.01 mg Pb/l recommended by both the World Health Organization US Environmental Protection Agency (USEPA). In Al-Batha, 52.2 % of the population had concentrations of Pb in blood that exceeded 10 μg Pb/dl, which is the concentration used by USEPA to classify people as being at risk from effects of Pb. In Al-Batha, 17.5 and 22.5 % of the population exceeded 20–40 and >40 μg Pb/dl, respectively. In Olya, 37 and 10 % of the population had concentrations of Pb in blood that exceeded 10 and 20–40 μg Pb/dl, respectively, while none of the concentrations of PB exceeded 40 μg Pb/dl.  相似文献   

19.
Hydrogeochemistry of Roccamonfina volcano (Southern Italy)   总被引：1，自引：1，他引：0  
This is the first hydro-geochemical investigation carried out on the Roccamonfina Volcanic Complex groundwaters. The chemistry of Roccamonfina waters is defined by water–rock and water–rock–gas interactions. In fact, interactions between rocks of the first eruptive high-K formations and circulating groundwaters are recognized by high K concentrations. On the other hand, inverse concentration of calcium versus alkali metals is related to two different rock interactions occurring in different areas of the volcano: (a) within the caldera where groundwaters flow within latite and pyroclastic formations releasing calcium, and (b) similarly at the base of the volcano where groundwaters flowing from surrounding carbonates got strongly enriched in Ca. These geochemical processes are also associated with K (SE of caldera) and Mg/Ca (in sites located at the NE base of the volcano) decrease. Completely different dynamics occurs at Riardo groundwaters (SE). Here waters are the result of a mix between the Roccamonfina deep aquifer and the carbonate aquifer of the Riardo plain. Rich-CO2 emissions make these waters strongly mineralized. Minor elements show a similar geochemical behavior of major ions and are crucial defining interactions processes. The evolution of Roccamonfina groundwaters is also evident along the simultaneous enrichment of Ba, Sr, and Ca. Ba increase is the result of deep local carbonate alteration enhanced by CO2 emissions and, the lower Sr/Ca ratio, from 10 to 2 (ppb/ppm), is also due to the same process. In the light of our results the Roccamonfina aquifer can be schematically divided into two main reservoirs: (a) a superficial aquifer which basically follows the volcanic structure morphology and tectonics and (b) a deeper reservoir, originating within the oldest Roccamonfina volcano ultra potassic lavas and then flowing into the carbonate aquifers of the neighboring plain. Eventually, the chemistry of the Roccamonfina aquifer does not show any specific and visible pollution, contrary to what happens in the volcano surrounding plains. In fact, only 14% of the samples we collected (206) show a NO3 content >30 mg/l. These sites are all located at the base of the volcano, near the plain.  相似文献   

20.
Whole-rock chemistry and precise U – Pb zircon chronology have been used to determine the provenance of Archean greenschist-facies siliciclastic sedimentary rocks of the Diemals Formation in the Marda – Diemals area of the central Yilgarn Craton, Western Australia. Field evidence shows that these siliciclastic rocks are, at least in part, derived from uplift and erosion of underlying greenstones, and this is borne out by the similar La/Sc, Cr/Th and REE chemistry of Diemals Formation siltstones and some sandstones to mafic volcanic rocks of the underlying greenstones. The higher Cr/V and lower Y/Ni of some siltstones is consistent with input from ultramafic and mafic rocks. Diemals Formation sandstones and siltstones cannot be separated in terms of ratios such as Zr/La, and siliciclastic rock chemistry reflects provenance rather than the effects of transport and depositional processes, such as sorting. Chemistry does not support input to Diemals Formation sedimentary rocks from the Marda volcanic complex despite both units being close to each other, and having overlapping maximum depositional and crystallisation ages, respectively. Instead, it is likely that detritus for the two units was deposited in adjacent, physically discrete basins. Some Diemals Formation sandstones are geochemically similar to felsic rocks intruding the underlying greenstone succession, with higher La/Sc and lower Cr/Th, and LREE-enriched patterns with negative Eu anomalies. Support for a genetic relationship is shown by the overlap in the maximum depositional age of these sandstones with the crystallisation age of the geochemically identical Pigeon Rocks Monzogranite. Combined whole-rock chemistry and precise U – Pb zircon chronology indicates that Diemals Formation sedimentary rocks were in large part derived from the underlying mafic volcanic rocks, with progressive unroofing of this succession leading to erosion of felsic intrusive rocks, now represented by sandstones found at various levels in the Diemals Formation.  相似文献   

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