首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 527 毫秒
1.
The thermal expansion of stishovite has been determined by an X-ray camera technique in a temperature range of 18 – 600°C at an atmospheric pressure. The thermal-expansion coefficients along the crystallographic a- and c-axes at 300 K are αa = (6.0 ± 0.6) · 10?6K?1 and αc = (1.4 ± 0.5) · 10?6K?1, respectively. The volume coefficient at 300 K is αν = (13.5 ± 0.6) · 10?6K?1.  相似文献   

2.
The thermal conductivity of NaCl, MgO, coesite and stishovite have been measured as a function of pressures up to 40 kbar (4 Gpa) at room temperature. Polycrystalline coesite and stishovite were synthesized under high pressures and temperatures at our laboratory. An improved version of the comparative method suitable for the thermal conductivity measurement of small samples under high pressures was designed. The zero-pressure values are 0.0189 and 0.0412 cal. cm?1 s?1 °C?1 for coesite and stishovite, respectively. The thermal conductivities were found to increase linearly with pressure, and the increase rates relative to their zero-pressure values were 3.1, 0.68, 0.39 and 0.90% per kbar for NaCl, MgO, coesite and stishovite, respectively. On the thermal conductivity of coesite, the pressure dependence is small and the zero-pressure value is almost the same as that of polycrystalline quartz. On the other hand, the zero-pressure value of stishovite is 2.2 times as large as that of coesite.  相似文献   

3.
The thermal diffusivity of a naturally occurring polycrystalline olivine (Fo91Fa09) was measured by the Flash technique in the temperature range of 450–1500 K. At 450 K the thermal diffusivity was 10.7 × 10?7 m2/s and decreased as a function of reciprocal temperature to 7.0 × 10?7 m2/s at 800 K. From that temperature, the values gradually increased to a maximum of 7.8 × 10?7 m2/s at 1000 K, and then steadily decreased to 5.6 × 10?7 m2/s at 1500 K. The unusual decrease above 1000 K was caused by a reduction of the previously oxidized samples. The olivine's oxidation state plays a significant role in the value of thermal diffusivity at high temperatures.  相似文献   

4.
High temperature calorimetric measurements of the enthalpies of solution in molten if2 PbO · B2O3 of α- and γ-Fe2SiO4 and α-, β-, and γ-Co2SiO4 permit the calculation of phase relations at high pressure and temperature. The reported triple point involving α-, β-, and γ-Co2SiO4 is confirmed to represent stable equilibrium. The curvature in the α?β phase boundary in Co2SiO4 and of an α?γ boundary in Fe2SiO4 at high temperature is explained in part by the effects of compressibility and thermal expansion, but better agreement with the observed phase diagram is obtained when one considers the effect of small amounts of cation disorder in the spinel and/or modified spinel phases. The calculated ΔH0 and ΔS0 values for the α?β, α?γ, and β?γ transitions show that enthalpy and en changes both vary strongly in the series Mg, Fe, Co, and Ni, and are of equal importance in determining the stability relations. The disproportionation of Fe2SiO4 and Co2SiO4 spinel to rocksalt plus stishovite is calculated to occur in the 170–190 kbar region; cation disorder and/or changes in wüstite stoichiometry can affect the P?T slope. The calorimetric data for CoSiO3 and FeSiO3 are in good agreement with the observed phase boundary for pyroxene formation from olivine and quartz. The decomposition of pyroxene to spinel and stishovite at pressures near the coesite-stishovite transition is predicted in both iron and cobalt systems. The use of calorimetric data, obtained from small samples of high pressure phases, is very useful in predicting equilibrium phase diagrams in the 50–300 kbar range.  相似文献   

5.
High temperature solution calorimetry of synthetic quartz, coesite and stishovite provides enthalpies of transition. ΔH9750 for quartz-coesite and ΔH2980 for coesite-stishovite transition are 320 ± 70 and 11700 ± 410 cal mol?1, respectively. The present transformation enthalpy data represent a small but significant revision of those of Holm et al. Using the published phase equilibrium data, thermal expansivity, compressibility and heat capacity data, ΔS9750 for the quartz-coesite and ΔS2980 for the coesite-stishovite transition are ?1.2 ± 0.1 and ?1.0 ± 0.4 cal K?1 mol?1, respectively. These thermochemical data are used to calculate phase boundaries of the transitions. The calculated quartz-coesite transition boundary agrees well with the one determined experimentally by Bohlen and Boettcher. The calculated coesite-stishovite boundary is generally consistent with data by Yagi and Akimoto and by Suito.  相似文献   

6.
Thermal diffusivity (D) was measured using laser-flash analysis on pristine and remelted obsidian samples from Mono Craters, California. These high-silica rhyolites contain between 0.013 and 1.10?wt% H2O and 0 to 2?vol% crystallites. At room temperature, D glass varies from 0.63 to 0.68?mm2?s?1, with more crystalline samples having higher D. As T increases, D glass decreases, approaching a constant value of ??0.55?mm2?s?1 near 700?K. The glass data are fit with a simple model as an exponential function of temperature and a linear function of crystallinity. Dissolved water contents up to 1.1?wt% have no statistically significant effect on the thermal diffusivity of the glass. Upon crossing the glass transition, D decreases rapidly near ??1,000?K for the hydrous melts and ??1,200?K for anhydrous melts. Rhyolitic melts have a D melt of ??0.51?mm2?s?1. Thermal conductivity (k?=?D·??·C P) of rhyolitic glass and melt increases slightly with T because heat capacity (C P) increases with T more strongly than density (??) and D decrease. The thermal conductivity of rhyolitic melts is ??1.5?W?m?1?K?1, and should vary little over the likely range of magmatic temperatures and water contents. These values of D and k are similar to those of major crustal rock types and granitic protoliths at magmatic temperatures, suggesting that changes in thermal properties accompanying partial melting of the crust should be relatively minor. Numerical models of shallow rhyolite intrusions indicate that the key difference in thermal history between bodies that quench to obsidian, and those that crystallize, results from the release of latent heat of crystallization. Latent heat release enables bodies that crystallize to remain at high temperatures for much longer times and cool more slowly than glassy bodies. The time to solidification is similar in both cases, however, because solidification requires cooling through the glass transition in the first case, and cooling only to the solidus in the second.  相似文献   

7.
The lake without any outlet (11 ha, 55000 m3, zmax 2,25 m) has a weak thermal stratification with maximum surface temperatures of 32.5 °C. The annual variation of temperature and depth of visibility is unimodal, with the maxima or minima in August. Phytoplankton consists mainly of Cyanophyceae. The primary production determined by the light-dark bottle technique (oxygen method) varies in the annual variation between 0.3… 0.5 g m?2 d?1 C (winter) and 3.4… 4.6 g m?2 d?1 C (summer); as the annual means of 1975 and 1976 there were found 1.9 and 2.4 g m?2 d?1 C, resp., gross production at a utilization of 0.42… 2.85% of the radiation energy. The chemism is a well-buffered hydrogen-carbonate water (pH 8.1… 9.0) with 74… 90 mg/1 Na and 20.5… 31.5 mg/1 K and with a good nutrient supply (20… 40 μg/1 PO4—P and 100… 240 μg/1 NO3—N) at the same time.  相似文献   

8.
We apply a measurement technique that utilizes thermal video of vapor-dominated volcanic plumes to estimate the H2O gas flux at three degassing volcanoes. Results are compared with H2O flux measurements obtained using other methods to verify the thermal camera-derived values. Our estimation of the H2O emission rate is based on the mass and energy conservation equations. H2O flux is quantified by extracting the temperature and width of the gas plume from the thermal images, calculating the transit velocity of the gas plume from the thermal video, and combining these results with atmospheric parameters measured on-site. These data are then input into the equations for conservation of mass and energy. Selected volcanoes for this study were Villarrica in Chile, Stromboli in Italy, and Santa Ana in El Salvador. H2O fluxes estimated from the thermal imagery were 38–250?kg?s?1 at Villarrica, 4.5–14?kg?s?1 for Stromboli’s Central Crater, and 168–219?kg?s?1 at Santa Ana. These compare with H2O flux values estimated by other methods of 73–220, 3–70 and 266?kg?s?1, at the three volcanoes, respectively. The good agreement between thermal image-derived results and those estimated by other methods seem to validate this method.  相似文献   

9.
The high-pressure and temperature phase transformations of MgSiO3 have been investigated in a diamond-anvil cell coupled with laser heating from 150 to 300 kbar at 1000–1400°C. X-ray diffraction study of the quenched samples reveals that the sequence of phase transformations for this compound is clinoenstatite → β-Mg2SiO4 plus stishovite → Mg2SiO4(spinel) plus stishovite → ilmenite phase → perovskite phase with increasing pressure. The hexagonal form of MgSiO3 observed by Kawai et al. is demonstrated to have the ilmenite structure and the “hexagonal form” of MgSiO3 observed by Ming and Bassett is shown to be predominantly the orthorhombic perovskite phase plus the ilmenite phase. The mixture of oxides, periclase plus stishovite, reported by Ming and Bassett was not observed in this study. The very wide stability field for the ilmenite phase of MgSiO3 found in this study suggests that this phase is of importance in connection with the observed rapid increase of velocity in the transition zone of the earth's mantle. On the basis of the extremely dense-packed structure of the perovskite phase of MgSiO3, this phase should be the most important component for the lower mantle.  相似文献   

10.
We report the first detailed study of spatial variations on the diffuse emission of carbon dioxide (CO2) and hydrogen sulfide (H2S) from Hengill volcanic system, Iceland. Soil CO2 and H2S efflux measurements were performed at 752 sampling sites and ranged from nondetectable to 17,666 and 722?g?m?2?day?1, respectively. The soil temperature was measured at each sampling site and used to evaluate the heat flow. The chemical composition of soil gases sampled at selected sampling sites during this study shows they result from a mixing process between deep volcanic/hydrothermal component and air. Most of the diffuse CO2 degassing is observed close to areas where active thermal manifestations occur, northeast flank of the Hengill central volcano close to the Nesjavellir power plant, suggesting a diffuse degassing structure with a SSW?CNNE trend, overlapping main fissure zone and indicating a structural control of the degassing process. On the other hand, H2S efflux values are in general very low or negligible along the study area, except those observed at the northeast flank of the Hengill central volcano, where anomalously high CO2 efflux and soil temperatures were also measured. The total diffuse CO2 emission estimated for this volcanic system was about 1,526?±?160?t?day?1 of which 453?t?day?1 (29.7?%) are of volcanic/hydrothermal origin. To calculate the steam discharge associated with the volcanic/hydrothermal CO2 output, we used the average H2O/CO2 mass ratio from 12 fumarole samples equal to 88.6 (range, 9.4?C240.2) as a representative value of the H2O/CO2 mass ratios for Hengill fumarole steam. The resulting estimate of the steam flow associated with the gas flux is equal to 40,154?t?day?1. The condensation of this steam results in thermal energy release for Helgill volcanic system of 1.07?×?1014?J?day?1 or to a total heat flow of 1,237?MWt.  相似文献   

11.
The thermal diffusivity is the key parameter that controls near‐surface temperature where periodic temperature variation is progressively attenuated and delayed with depth. This article presents the results of apparent thermal diffusivity using temperatures recorded by a bedrock temperature measurement network in the fault zones of western Sichuan. High sensitivity temperature sensors (10?4 K) were installed at a maximum depth reaching 30 m. The apparent thermal diffusivities were deduced from both amplitude damping and phase shifting of annual temperature variations between two different depths. Under pure conduction, the thermal diffusivity determined through the phase method (αΦ) should be equivalent to that determined through the amplitude method (αA), whereas effects of the upward (downward) water flow are evidently reflected in the amplitude decay to make αΦ larger (lesser) than αA. The discrepancy between αΦ and αA can thus be a tracer of water movement or convective heat transfer. The calculated αΦ of the measurement stations varies from 1.22 × 10?6 to 3.00 × 10?6 m2/s, and the estimated αA ranges from 0.93 × 10?6 to 2.41 × 10?6 m2/s. Two regimes of heat transfer underground were suggested from the results. Conductive heat transport prevails over the nonconductive processes at five stations, which is characterized by αΦ coincident with αA for the same depth pair. On the contrary, the values of αΦ differ from αA at six stations in the intersection area of the Y‐shaped fault system, implying that convective heat transfer also plays a comparably important role. This finding is consistent with the hot springs distribution of the area. The results also indicate that water moves upward with an average Darcy velocity of approximately ?1 × 10?7 m/s in this region. Our research provides new evidence for the hydrothermal activity in the fault zones at the eastern margin of the Tibetan Plateau.  相似文献   

12.
  相似文献   

13.
The “anomalous” layer in the lowermost mantle, identified as D″ in the notation of K.E. Bullen, appears in the PREM Earth model as a 150 km-thick zone in which the gradient of incompressibility with pressure, dKdP, is almost 1.6, instead of 3.2 as in the overlying mantle. Since PREM shows no accompanying change in density or density gradient, we identify D″ as a thermal boundary layer and not as a chemically distinct zone. The anomaly in dKdP is related to the temperature gradient by the temperature dependence of Ks, for which we present a thermodynamic identity in terms of accessible quantities. This gives the numerical result (?Ks/?T)P=?1.6×107 Pa K?1 for D″ material. The corresponding temperature increment over the D″ range is 840 K. Such a layer cannot be a static feature, but must be maintained by a downward motion of the lower mantle toward the core-mantle boundary with a strong horizontal flow near the base of D″. Assuming a core heat flux of 1.6 × 1012 W, the downward speed is 0.07 mm y?1 and the temperature profile in D″, scaled to match PREM data, is approximately exponential with a scale height of 73 km. The inferred thermal conductivity is 1.2 W m?1 K?1. Using these values we develop a new analytical model of D″ which is dynamically and thermally consistent. In this model, the lower-mantle material is heated and softened as it moves down into D″ where the strong temperature dependence of viscosity concentrates the horizontal flow in a layer ～ 12 km thick and similarly ensures its removal via narrow plumes.  相似文献   

14.
A steady-state radial heat flux method is used to determine the apparent, lattice and radiative, thermal conductivity and its p, T-dependence up to 6 GPa and over a wide temperature range from 300 to 1600 K. The method employs a differential thermocouple to resolve small changes in temperature gradient due to a line source placed in a sample space subjected to well-defined uniform test temperatures. Measurements are made using an on-line computer. The method is shown to be eminently suitable for determining: (1) the p, T-dependence of the phonon conductivity of cubic single crystals and polycrystalline samples; (2) minima in the apparent thermal conductivity marking the onset of radiative contributions; (3) isolation of phonon and radiative components at high T; (4) conductivity variations caused by progressive polymorphic structure transformations; and (5) conductivity variations through high-pressure melting points into the liquid phase.Results for cubic structures such as MgO and NaCl give good agreement with existing standard values at low temperatures. The conductivity of MgO goes with the inverse of the temperature which is expected from 3-phonon processes. The conductivity of NaCl is of the form λαT?1.32 with the deviation most likely due to thermal expansion effects.At higher temperatures, a radiative contribution was observed in NaCl and CaCO3. Calculated values of the extinction coefficient of NaCl increase slightly with pressure.  相似文献   

15.
The pressure-induced high-spin—low-spin transition of the transition-metal ions in octahedral coordination is studied theoretically. The relation between the crossover point and the transition point is discussed and the formula to determine the transition point is given in terms of the crystal-field splitting Δ and the spin-pairing energy Π asΔ = αΠ. The numerical coefficient α is determined by the ratio of the change of the interatomic distances between the transition-metal ion and ligands. It is proved that α is generally less than 1 and takes a value of about 0.95-0.80 for the transition-metal oxides. Based on the discussions on the P–V relation of the low-spin oxides, transition pressures are estimated to be about 700–1300 kbar for MnO, CoO and Fe2O3, and about 250–400 kbar for FeO.The magnitude of the shifts of transition pressures due to entropy changes is roughly evaluated to be about 0.1 kbar K?1 for transition-metal oxides. It is discussed whether the transition at high temperature takes place continuously or not. For MnO, FeO and Fe2O3, the high-spin—low-spin transition will take place gradually at temperatures higher than about 2000 K. For CoO, the gradual transition will take place at above 300 K.  相似文献   

16.
Tracer diffusion coefficients for Li in glasses of albite, orthoclase, and obsidian composition have been determined by a method involving deposition of a thin source on polished glass wafers, anneal under controlled temperature conditions (300–900°C), and ion-microprobe determination of the concentration profile. All results conform to an Arrhenius-type relationship,D = D0exp(?Q/RT), whereQ is 23, 17, and 22 kcal mol?1;D0 is 0.2, 0.003, and 0.03 cm2s?1 for albite and orthoclase glasses, and obsidian respectively. Lithium is thus a fast diffusing ion and behaves similarly to sodium in the same glasses. A mechanism involving jumps of the diffusing ions through oxygen hexagonal rings is suggested by consideration of ionic radii ratio of alkali (H, Li, Na, K, Rb, and Cs) ions to the oxygen anions.  相似文献   

17.
Data in the literature and additional measurements on the thermal diffusivities of granites, granulites and ultrabasic rocks at temperatures up to 1000 K and pressures to 2 GPa, have been used to propose a new model for thermal diffusivity distribution in the crust and upper mantle.The laboratory measurements were made using a pulse method or the Angstroem method with cylindrical heat flow. After making particular assumptions about the pressure and temperature distribution within the top 60 km the pressure and temperature dependencies of diffusivity were transformed into a depth dependence.The model is characterised by a continuous decrease of diffusivity to a depth of ～30 km where there is a small but rapid increase to a nearly constant value of 7.3 × 10?3 cm2 s?1.  相似文献   

18.
This study shows the assessment of radiation hazard parameters due to terrestrial radionuclides in the soil around artisanal gold mining for addressing the issue of natural radioactivity in mining areas. Hence, the levels 238U, 232Th, 40K and 226Ra in soil (using gamma spectrometry), 222Rn in soil and 222Rn in air were determined. Radiation hazard parameters were then computed. These include absorbed dose D, annual effective dose E, radium equivalent activity Raeq, external hazard Hex, annual gonadal dose equivalent hazard index AGDE and excess lifetime cancer risk ELCR due to the inhalation of radon (222Rn) and consumption of radium (226Ra) in vegetation. Uranium (238U), thorium (232Th) and potassium (40K) averages were, respectively, 26, 36 and 685 Becquerel per kilogram (Bq kg?1). Soil radon (4671 Bq m?3) and radon in air (14.77 Bq m?3) were found to be less than worldwide data. Nevertheless, the average 40K concentration was 685 Bq kg?1. This is slightly higher than the United Nations Scientific Committee on the Effects of Atomic Radiation average value of 412 Bq kg?1. The obtained result indicates that some of the radiation hazard parameters seem unsavory. The mean value of absorbed dose rate (62.49 nGy h?1) was slightly higher than average value of 57 nGy h?1 (~?45% from 40K), and that of AGDE (444 μSv year?1) was higher than worldwide average reported value (300 μSv year?1). This study highlights the necessity to launch extensive nationwide radiation protection program in the mining areas for regulatory control.  相似文献   

19.
Samples of water from poor to very rich fens in the Schefferville region of subarctic Quebec revealed strong spatial and temporal variations in dissolved organic carbon (DOC), ranging from 2 to 40 mg 1?1. Concentrations of DOC tend to increase during the summer and decrease in the autumn, at most sites, which probably reflects increased plant tissue decomposition and higher rates of evapotranspiration. Principal components analysis revealed that DOC is strongly associated with Fe, NO?3-N and NO?2-N, but essentially independent of other chemical properties of the peat water, such as pH, Ca, Mg, K, P, and NH+4-N. Based on observed concentrations of DOC and estimates of summer runoff (June to September), export of DOC from four peatlands ranges from 1·1 to 4·9 gCm?2, with the lowest values for peatlands underlain by dolomite. Molecular weight fractionation of four samples revealed significant differences in the dissolved organic matter (DOM), with the largest fractions (GF/C to 10 000 nmw) being dominant in the more acid samples. The ratio of absorbance at 400 and 600 nm wavelengths (E4:E6) has been used as a simple indicator of differences in DOM type, ranging from 3 to 15. There is a strong seasonal pattern of increasing E4:E6 ratio during the summer at many sites, though this ratio is essentially independent of other chemical properties of peat waters.  相似文献   

20.
Some 300 measurements under a wide range of flow conditions were used to construct regression models to predict concentrations of six major ions in a moorland stream draining intermediate-basic lavas in Scotland. Ca, Mg, and HCO3 were very closely related to discharge in log-log regressions (r2 > 90 percent). Na and Cl required inclusion of seasonal functions for best prediction (r2 = 76 per cent in both cases). K concentrations were predicted from discharge, direction of stage change, and a seasonal function. Annual losses of Ca, Mg, and HCO3 were 252, 36, and 871 kg ha ?1, substantially larger than those for upland catchments on acid rocks. Losses of K, Na, and Cl were of a similar order to other upland sites.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号