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1.
Industrial minerals of a high degree of fineness such as kaolinite, calcite and barite are used to an increasing extent in the chemical industries as filling material in the manu-facturing of paper, paints and plastics or as ingredients of ceramic products. Grains smaller than 5 μm can be produced by dry grinding in a jet mill or by wet grinding in drum mills. To avoid impurities due to wear, these mills are lined with rubber or plastic and ceramic balls are used as grinding bodies.Our investigations in a jet mill show that the fineness of the ground product depends on the feed rate and on the air volume. The grain sizes received in the drum mill are influenced by feed rate, pulp density, speed of rotation and by the grinding bodies (density, size).REM-photographs of mill discharge in the grain-size ranges 10-5 μm and below 5 μm indicate that in both the grains mainly show crystal planes as boundaries. After dry grinding the grains show smooth and clean faces; thus is traced back to the impact effect of the air streams. In wet grinding the fine grains are very prone to form agglomerates.  相似文献   

2.
The performance of the secondary ball mill at the New Broken Hill Consolidated Ltd. concentrator is analysed using the perfect mixing model and an ore-specific breakage distribution function. This function was determined from single-particle breakage tests using a computer-monitored twin pendulum apparatus.The ratio of the breakage rate to the normalized discharge rate, r/d*, determined for the ball mill using the ore-specific breakage distribution function for a range of grinding conditions is related to the mill power consumption. The mill power consumption is related to the percentage of mill volume occupied by the ball charge and to the percentage of solids in the mill feed.  相似文献   

3.
A worldwide survey on grinding mill circuits in the mineral processing industry was conducted. The aims of this survey are to determine how milling circuits are currently controlled, and to find out how key process variables are linked to economic benefits. The survey involves background information on the circuits, the choice of controlled and manipulated variables, the economic impact of the controlled variables, adopted control technologies and assessment of control performance. Sixty-eight responses were received. Survey results are contrasted to the milling control literature.  相似文献   

4.
This study deals with the effect of mechanical treatment, using vibrating mill, on the mineralogy and structure of apatite and associated gangue minerals (dolomite, calcite, quartz, pyrite and gypsum) in Abu-Tartour phosphate ore, Egypt. The evolution of mineralogy, crystallinity and deformation mechanism were evaluated with different techniques (XRD, DTA, TGA and FT-IR). Data obtained using these techniques give a good picture about the mechanochemical behavior of the different components in the ore. X-ray diffraction (XRD) indicated that the mineralogy has been changed quantitatively at short time grinding (30 min). After 45 min of grinding, the sample contained mainly carbonate apatite, quartz and pyrite. On the other hand, dolomite mineral disappeared, while calcite was partially transformed into aragonite. This transformation increased with increasing grinding time. Both Fourier Transform Infrared (FT-IR) and differential thermal analysis (DTA) analyses revealed that remarkable changes in the structural groups have occurred after 45 min of grinding. After 75 min of grinding, the carbonate in the apatite mineral partially decomposed and tricalcium phosphate formed instead. The formation of that simple form (tricalcium phosphate) may be another reason, besides surface area, for increasing the reactivity of phosphate ore by grinding. Scanning electron micrographs (SEM) revealed some idea about the grinding mechanisms of Abu-Tartour phosphate using vibrating mill. They indicate that the different minerals are ground differently. The apatite minerals are ground mostly by abrasion mechanism, while the carbonate minerals are ground mostly by compression. Also, these minerals are ground with different rates, where dolomite is ground faster than calcite, which are referred to the crystal lattice.  相似文献   

5.
A centrifugal mill is a high-power intensity media mill that can be used for ultra-fine grinding, employing centrifugal forces generated by gyration of the axis of the mill tube in a circle. The mill charge motion is quite different depending on the ratio of the gyration diameter to the mill diameter (G / D ratio), varying from a motion similar to that of a conventional tumbling media mill to that of a vibration mill. In this study, a centrifugal mill was constructed with an arrangement where the gyration diameter could be readily adjusted. The batch grinding characteristics of three different minerals (limestone, talc and illite) in water with dispersing agent were investigated at various G / D ratios. It was found that the optimum G / D ratio in terms of the specific energy consumption to give a desired fineness of product was different for the three minerals. This was due to their different reactions to the breakage mechanisms provided by the mill charge motion at varying G / D ratios. The size distributions became progressively narrower at increased grinding times, and particles finer than about 0.1 μm were not detected even for prolonged grinding times. Measurement of specific surface areas indicated that this was not due to an artifact of the size measurements by laser diffractometry. This implies that there is a limitation in which particles finer than 0.1 μm are not produced under the conditions tested in this type of mill, but further investigation is needed for experimental verification of this limit of comminution.  相似文献   

6.
This paper presents a three dimensional Computational Fluid Dynamics (CFD) model to investigate the flow dynamics of solid–gas phases during fine grinding in an air jet mill. Alpine 100AFG fluidized bed air jet mill is considered for the study and the jet milling model is simulated using FLUENT 6.3.2 using a standard k-ε model. The model is developed in GAMBIT 2.3.16 and meshed by tet/hybrid (T-Grid) and Triangular (Pave) meshes. The effects of operating parameters such as solid feed rate, grinding air pressure and internal classifier speed on the performance of the jet mill are analyzed. The CFD simulation results are presented in the forms of dual phase vector plot, volume fraction of phases and particle trajectories during fine grinding process. The mass of ground feed entering and leaving the cyclone (underflow) is also computed by simulation. The proposed model gives realistic predictions of the flow dynamics within the jet mill. Experiments are conducted on the Alpine 100AFG jet mill to study the particle size, morphology and mass of the ground product. The numerical results are found in good agreement with the experimental results.  相似文献   

7.
In this study, a naturally available crab shell chitosan of low molecular weight (20?kDa) has been used as adsorbent to evaluate the pollution load in vegetable oil mill effluent. A series of batch experiment was conducted by varying chitosan dosage (100?C400?mg), pH (2?C9), stirring time (15?C90)?min and agitation speed (25?C150?rpm) to study their effects on adsorption and flocculation processes. The parameters considered for adsorption study are chemical oxygen demand, total suspended solids, electrical conductivity and turbidity. The maximum reduction in chemical oxygen demand, total suspended solids, electrical conductivity and turbidity is 74, 70, 56 and 92?% , respectively. The observed experimental result showed that crab shell chitosan could able to reduce significantly the chemical oxygen demand, turbidity, electrical conductivity and suspended matter. The optimum conditions were estimated as 400?mg/l chitosan, pH 4 and 45?min of mixing time with mixing speed of 50?rpm. Chitosan showed very good pollution removal efficiency and can be used for the effective treatment of vegetable oil mill effluent.  相似文献   

8.
Recent papers on the role of grinding aids in wet ball mills indicate that certain polymeric aids favorably act by altering pulp rheology, leading to improved production rates at high pulp densities. Analysis of recent data indicates that there can be an improvement in terms of the production of fine particles per unit time, but on the other hand, the production per unit of expended energy remains the same. Our experiments indicate that there is a critical pulp viscosity above which the grinding media tend to centrifuge because the balls cannot be detached from the mill wall during the time of rotation. Under these conditions the mill power draft decreases and a smaller amount of fines is generated. The polymeric additives are able to reduce the pulp viscosity to a value less than the critical value so that the balls no longer centrifuge and the mill draws full power. From an analysis of the force field acting on a ball inside the mill, this critical viscosity can be estimated and the results are in agreement with experiment.  相似文献   

9.
高转速钻进时金刚石钻头磨损的试验研究进展   总被引:4,自引:2,他引:2  
讨论了金刚石钻进中提高机械钻速和降低钻探磨损问题 ;探讨了这两个技术指标与钻压、转速的关系 ;提出了表示机械钻速和钻头胎体磨损关系的钻探效果指标 ,并根据后者确定出了规程参数最优值  相似文献   

10.
Ball milling is an energy-intensive unit operation and usually consumes a major proportion of the power drawn by a typical mineral processing plant. Hence, substantial economic benefits can be achieved by optimal design and by operating ball milling circuits under optimum process conditions. This requires an accurate ball mill modelling technique.In the multi-segment ball mill model, the size-dependent material transport within the mill varies systematically with the amount of coarse particles present in each segment. The ore-specific breakage distribution function can be determined from single particle breakage tests conducted using a computer-monitored twin pendulum apparatus. When the ore-specific breakage distribution function is used in the multi-segment, a constant relationship between the breakage rate parameters and mill diameter is observed. Thus, the performance of an industrial ball mill can be adequately described using the ore-specific breakage distribution function together with the systematic variation of the material transport and the breakage rate functions with process conditions and mill diameter, respectively.This ball mill modelling technique is illustrated using a case study on the design of a ball milling circuit for a particular grinding requirement and another case study on modelling the performance of an industrial ball milling circuit.  相似文献   

11.
The Florida Bay ecosystem has changed substantially in the past decade, and alterations in the seagrass communities have been particularly conspicuous. In 1987 large areas ofThalassia testudinum (turtlegrass) began dying rapidly in western Florida Bay. Although the rate has slowed considerably, die-off continues in many parts of the bay. Since 1991, seagrasses in Florida Bay have been subjected to decreased light availability due to widespread, persistent microalgal blooms and resuspended sediments. In light of these recent impacts, we determined the current status of Florida Bay seagrass communities. During the summer of 1994, seagrass species composition, shoot density, shoot morphometrics, and standing crop were measured at 107 stations. Seagrasses had been quantified at these same stations 10 yr earlier by Zieman et al. (1989).T. testudinum was the most widespread and abundant seagrass species in Florida Bay in both 1984 and 1994, and turtlegrass distribution changed little over the decade. On a baywide basis,T. testudinum density and biomass declined significantly between surveys; mean short-shoot density ofT. testudinum dropped by 22% and standing crop by 28% over the decade.T. testudinum decline was not homogeneous throughout Florida Bay; largest reductions in shoot density and biomass were located principally in the central and western bay. Percent loss ofT. testudinum standing crop in western Florida Bay in 1994 was considerably greater at the stations with the highest levels of standing crop in 1984 (126–215 g dry wt m−2) than at the stations with lower levels of biomass. While turtlegrass distribution remained consistent over time, both the distribution and abundance of two other seagrasses,Halodule wrightii andSyringodium filiforme, declined substantially between 1984 and 1994. Baywide,H. wrightii shoot density and standing crop declined by 92%, andS. filiforme density and standing crop declined by 93% and 88%, respectively, between surveys. Patterns of seagrass loss in Florida Bay between 1984 and 1994 suggest die-off and chronic light reductions were the most likely causes for decline. If die-off and persistent water-column turbidity continue in Florida Bay, the long-term future of seagrasses in the bay is uncertain.  相似文献   

12.
A method of parameter estimation is outlined for a two-component grinding-liberation model. The large number of model variables is reduced by using functional forms. The parameters for the functional forms are estimated using a modified Gauss-Newton algorithm. The technique is applied to both synthetic and real experimental data. Parameters estimated from wet grinding batch tests of Illinois No. 6 coal were used to predict mill output for a larger pilot-plant mill. The predictions were found to match the actual mill output within the limits of experimental error.  相似文献   

13.
This paper presents the experimental results of the mechanical production of silica and carbonate colloidal particles below 100 nm using two types of stirred bead mills (i.e., DCP Superflow 12 and PML H/V). It is shown that the stirred bead mill with very small beads can be used as an efficient equipment for the production of the colloidal particles in nanoscale from the feed materials of several microns in sizes at high energy consumptions. The DCP Superflow mill with high power densities is superior for the effective size reduction and production rate, compared to the conventional PML H/V mill with lower power densities. The smaller particles could be produced by the DCP Superflow mill at the same level of high energy inputs as from the PML H/V mill. The “grinding limit” for the processes in the mills has been discussed.  相似文献   

14.
The flotation response of gersdorffite has been determined in a series of batch flotation tests in which a sulphide sample containing about 76% gersdorffite was floated from mixtures with quartz.Using xanthate as collector, the arsenide floated strongly at pH 9, irrespective of whether lime, sodium hydroxide or sodium carbonate was used as pH modifier. When the pH was raised further to 10 or more using lime, the flotability decreased sharply.Changing the pulp potential at pH 9 also strongly affected the flotation response. Above about − 230 mV SHE, the mineral floated strongly, but below this potential it was essentially non-flotable. As far as it was tested (up to + 400 mV SHE), no upper limiting potential was found.Adding cyanide to the grinding mill brought about only a weak depressant effect on subsequent gersdorffite flotation at both pH 9 and 10. However, adding the same amount of cyanide to the flotation cell produced a strong depressant effect at the same pH values. At both pH 9 and pH 10, a threshold cyanide addition existed below which gersdorffite floated strongly, and above which it did not. For the conditions used in this study, this addition equates to about 100 g/t at pH 9 and about 80 g/t at pH 10. A hypothesis for the depression effect is presented which is consistent with both the available flotation data and a series of diagnostic analyses of grinding and flotation pulps completed during the test work.  相似文献   

15.
A size-continuous breakage-kinetics model is postulated and supported with industrial grinding-mill data. It is shown that the kinetics parameters include the effects of possible classification at the mill discharge. The estimated parameters were then used in the kinetics model to simulate the behavior of a grinding mill in open- and closed-circuit operation. While material transport and kinetics are equally important in open-circuit operation, heavy recycle in a closed circuit makes a detailed material-transport model for grinding unnecessary. In effect, the mill can be considered as backmixed. This suggests that more emphasis should be placed on modelling the classifier than the development of detailed material-transport models for the grinding mill.  相似文献   

16.
In this paper, the photocatalytic decontamination of hexavalent chromium and tri-ethyl phosphate, two important wastewater contaminants, are studied by the ultraviolet / nano-titanium dioxide process. The pH value and synergic effect between the oxidation of tri-ethyl phosphate and the reduction of hexavalent chromium were investigated in different concentrations of tri-ethyl phosphate and hexavalent chromium. Furthermore, the effects of ultraviolet and nano-titanium dioxide were investigated in a solution which contained tri-ethyl phosphate and hexavalent chromium. Results of adsorptions showed that hexavalent chromium was adsorbed better in acidic pH while the better adsorption for tri-ethyl phosphate was occurred in alkalinity pH. The reduction rate of hexavalent chromium was higher in acidic solutions while it was obtained at natural pH for tri-ethyl phosphate. In co-adsorption of hexavalent chromium and triethyl phosphate pollutants, tri-ethyl phosphate slightly increased adsorption of hexavalent chromium, but hexavalent chromium had no influence on the adsorption of tri-ethyl phosphate on nano-titanium dioxide particles. In contrast, triethyl phosphate has an improving effect on the reduction reaction rate of hexavalent chromium which increases with the interaction of the concentration of tri-ethyl phosphate in mixture. The same is true for the oxidation rate of tri-ethyl phosphate.  相似文献   

17.
A central composite face-centered design was used to study and to optimize lead biosorption from aqueous solution on Aspergillus terreus biomass. Four factors such as stirring speed, temperature, solution pH and biomass dose at different levels were studied.The hierarchical quadratic model were established by adding replicates at the central point and axial points to the initial full factorial design (24). The percentage removal of lead was affected by biomass dose, pH, and interactions between pH and biomass dose, pH and stirring speed, pH and temperature. The hierarchical quadratic model described adequately the response surface based on the adjusted determination coefficient (R2 Adj= 0.97) and the adequate precision ratio (42.21). According to this model, the optimal conditions to remove lead completely from aqueous solutions (at initial lead concentration of 50 mg/L and solutions of 100 mL) with Aspergillus terreus were at pH 5.2, 50 °C, stirring speed of 102/min and a biomass dose of 139 mg.The response surface methodology can be used to determine the optimal conditions for metal adsorption on several adsorbents. In addition, results reported in this research demonstrated the feasibility of employing A. terreus as biosorbent for lead removal.  相似文献   

18.
Dimensionless selection functions for the grinding of material in continuous gratedischarge mills can be scaled in terms of normalized quantities of feed rate, geometric mean size of the particles and the mill length-to-diameter ratio. Simulations using the scale-up criteria together with the lumped-parameter grinding model yield results for mills of different lengths and operating at different feed rates that are in excellent agreement with the observed values.  相似文献   

19.
This study investigates the wear performance of diamond circular saw blades in cutting of granitic rocks. An alternative wear measuring method is developed to measure the reduced blade radius without taking the blade off the machine. The effect on and contribution to the specific wear rate (SWR) of each operating variable are determined, and the SWR is correlated with rock properties. Morphologies of wearing surfaces of segments and rocks are also evaluated using scanning electron microscopy (SEM). Depending on both operating variables and rock properties, prediction models are developed for estimation of the SWR. Results show that the SWR increases with an increase in the peripheral speed and the traverse speed, while it decreases with an increase in the cutting depth and the flow rate of the cooling fluid. The peripheral speed, and the microhardness and proportions of minerals such as quartz, plagioclase, and feldspar are statistically determined as the significant variables affecting the SWR. Finally, it is disclosed that models developed for estimation of SWR have great potential for practical applications.  相似文献   

20.
Batch wet grinding of zeolite was studied with emphasis on a kinetic study in a laboratory size steel ball mill of 200 mm diameter. The breakage parameters were determined by using the single sized feed fractions of − 850 + 600 µm, − 600 + 425 µm and − 425 + 300 µm for the zeolite samples. The Si (specific rate of breakage) and Bi,j (primary breakage distribution) values were obtained for those feed size fractions in order to predict the product size distributions by simulation for comparison to the experimental data. The specific rates of breakage values for wet grinding in the first-order breakage region were higher than the dry values reported previously by a factor 1.7 at the same experimental conditions, but the primary breakage distribution (Bi,j) values were approximately the same. The simulations of the product size distributions of zeolite were in good agreement with the experimental data using a standard ball mill simulation program. The wet grinding of zeolite was subjected to slowing-down effect in the mill at 2 min of grinding, corresponding to an 80% passing size of about 400 µm. On the other hand, the slowing down effect in the dry grinding of zeolite was also seen at 4 min of grinding. In addition, effects of some operational parameters on dry and wet grinding of zeolite were determined by simulation using the breakage parameters obtained experimentally.  相似文献   

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