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1.
The Duocaima carbonate-hosted Pb-Zn deposit is a newly found large deposit in the southern area of Qinghai Province.In this paper, the characteristics, genesis, significance to Pb-Zn mineralization of the widely developed breccias, and the ore-forming process have been carefully studied based on geological documentation of drilling holes, microscopic observations of petrography and microstructure and some stable isotope measurements.Based on the compositions of the clast and matrix, the breccias can be classified into three types: limestone clasts cemented by marl; limestone clasts with fine-grained calcareous materials; and limestone clasts cemented by hydrothermal calcite.The mineralization in the first type of breccia is weak, whereas it is strong in the latter two types of breccias.According to the locations of occurrence and structural characteristics of the breccias along with the relationship between the breccias and mineralization, part of the limestone clasts that are cemented by marl and outcrop in the contact zone between the Wudaoliang Formation(Nw) and the underlying Jiushidaoban Formation(Pj) are attributed to synsedimentary fault-genetic breccia, whereas the last of the limestone clasts that are cemented by marl and developed in the Jiushidaoban Formation(Pj) are attributed to the breccia generated by karst cave collapse; the limestone clasts with fine-grained calcareous materials and the limestone clasts cemented by hydrothermal calcite are attributed to breccia formed by hydrothermal dissolution.The breccia formed by karst collapse had consistently evolved for a long period of time, while the breccias with other origins were formed around the period of mineralization(i.e., about or slightly later than 20–16 Ma).The breccia generated by karst cave collapse and hydrothermal dissolution are somewhat related; the formation of the breccia from karst cave collapse provided open space for the later mineralization and reaction between hydrothermal fluids and host rocks, and the subsequent strong dissolution by hydrothermal fluids transformed some of the breccia formed earlier by karst cave collapse.Meanwhile, carbonate host rocks with breccias and brecciaed mineralization can be a potential sign of Mississippi Valley Type(MVT) deposits and important indicators for regional mineral exploration.The δ13CV-PDB, δ18OVSMOW, and 87Sr/86 Sr values of hydrothermal calcite in the Duocaima deposit range from 4.3‰ to 7.1‰, 14.9‰ to 20.1‰, and 0.707494 to 0.708185, respectively; the δ13CV-PDB, δ18OV-SMOW, and 87Sr/86 Sr values of the host limestones of the Jiushidaoban Formation range from 3.6‰ to 5.3‰, 18.0‰ to 20.5‰, and 0.707372 to 0.707945, respectively.The δ13CV-PDB and 87Sr/86 Sr values of hydrothermal calcite and limestone are similar, indicating single sources of C and Sr in this deposit, with the likely source being the limestone of the Jiushidaoban Formation.The minor scattering of the δ18OV-SMOW values suggests that different O isotope fluids underwent the isotope exchange reaction.The C-O-Sr isotope characteristics indicate that the host limestones experienced a dissolution and precipitation process during mineralization, which is beneficial to improving the porosity of host rocks and promoting the precipitation of metal sulfides.The δ34SV-CDT value of the breccia-type mineralization sulfides ranges from-30.4‰ to-0.3‰; that is, the δ34SV-CDT value is negative with considerable variation, illustrating that during the breccia-type mineralization process, the bacteriogenic reduction of sulfates provided the vast majority of sulfur, whereas the thermochemical reduction of sulfates was relatively unimportant.The brecciation that occurred as a result of karst cave collapse was mainly generated by the dissolution of groundwater; however, the brecciation related to hydrothermal dissolution and mineralization processes were caused by mixing of different fluids. 相似文献
2.
The Polaris deposit, located on Little Cornwallis Island in the Canadian Arctic, was a Mississippi Valley-type Zn–Pb deposit hosted by brecciated carbonate rocks of the Upper Ordovician Thumb Mountain Formation. Mapping indicates that strike-slip faults on the east side of the Polaris deposit were active during the last stage of the Late Devonian Ellesmerian Orogeny. Polaris is on a jog in the north-oriented, Early Devonian Boothia fault system and was the site of localized extension during south-directed Late Devonian Ellesmerian compression. This structural setting elsewhere in the district may be prospective for Zn–Pb mineralisation.Ore fluids rising in the Late Devonian interacted with the host rock causing dissolution, brecciation and collapse. Carbonate beds are thinned, indicating widespread removal of carbonate material. Five breccia types (crackle, pseudo, cobble, mega and collapse) are present in the vicinity of the deposit. Crackle breccia is preserved around the periphery of the deposit and is indicative of structural dilation or the early stages of mineralisation. Dolomite and pseudobreccias are also preserved around, and extend beyond, the periphery of the deposit. These are considered an early stage of alteration directly related to the mineralising fluids and could act as a vector to the centre of the mineralising system where collapse, mega and cobble breccias occur intimately with massive mineralisation. 相似文献
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Petrography and geochemistry of the Belle Roche breccia (lower Visean, Belgium): evidence for brecciation by evaporite dissolution 总被引：1，自引：0，他引：1
The lower Visean Belle Roche breccia (east Belgium) displays a number of features that indicate brecciation by evaporite dissolution collapse: the sharp lower contact of the breccia, the gradual transition into the overlying strata, the presence of semi-continuous beds within the breccia giving it a crude ‘stratification’, and the existence of several types of (calcite, dolomite and silica) evaporite pseudomorphs. Furthermore, the majority of the breccia fragments indicates hypersaline to lagoonal sedimentation conditions. Most of these fragments display an interlocking fabric. The interpretation is also supported by the existence of continuous evaporite beds replaced by carbonates (calcite and dolomite) both under and overlying the breccia. The brecciation history is characterized by gradual subsidence. Multiple brecciation episodes are recognized, and are best seen in the lower breccia which underwent at least two major brecciation episodes. Here, brecciated and veined breccia fragments occur within a microsparite (neomorphosed mud) matrix. Brecciation of these strata was due to the dissolution of interlayered evaporites. The second brecciation event relates to infiltration of meteoric water and to the dissolution of the remaining evaporites. This infiltration was probably triggered by the orogenic event at the end of the Visean (Sudetic orogenic phase). The whole breccia was finally cemented by a blocky calcite. The different lithologies and cements were characterized by their trace element (Mg, Sr, Na, Fe, Mn, K), insoluble residue and organic matter content. Carbon/oxygen isotope data of the cements and replaced evaporite layers helped to place the multiple collapse episodes within a general diagenetic model. Solution-reprecipitation processes within the original aragonite-dominated mud fragments, as well as in the early diagenetic dolomite fragments, have been recognized. The geochemical data show that these transformation processes occurred in equilibrium with the same fluid. These processes may have occurred within a freshwater lens very early in the diagenetic evolution or under shallow burial conditions. Cementation of blocky calcite occurred in a meteoric realm under burial conditions. 相似文献
5.
Dolomite formation in breccias at the Musandam Platform border, Northern Oman Mountains, United Arab Emirates 总被引：3，自引：0，他引：3
The presence of dolomite breccia patches along Wadi Batha Mahani suggests large-scale fluid flow causing dolomite formation. The controls on dolomitization have been studied, using petrography and geochemistry. Dolomitization was mainly controlled by brecciation and the nearby Hagab thrust. Breccias formed as subaerial scree deposits, with clay infill from dissolved platform limestones, during Early Cretaceous emergence. Cathodoluminescence of the dolostones indicates dolomitization took place in two phases. First, fine-crystalline planar-s dolomite replaced the breccias. Later, these dolomites were recrystallized by larger non-planar dolomites. The stable isotope trend towards depleted values (δ18O: − 2.7‰ to − 10.2‰ VPDB and δ13C: − 0.6‰ to − 8.9‰ VPDB), caused by mixing dolomite types during sampling, indicates type 2 dolomites were formed by hot fluids. Microthermometry of quartz cements and karst veins, post-dating dolomites, also yielded high temperatures. Hot formation waters which ascended along the Hagab thrust are invoked to explain type 2 dolomitization, silicification and hydrothermal karstification. 相似文献
6.
Silicification of sulphate evaporites and their carbonate replacements in Eocene marine sediments, Tunisia: two diagenetic trends 总被引：1，自引：0，他引：1
Samples of chert nodules, diagenetic carbonates and evaporites (gypsum/anhydrite) collected from the gypsiferous limestones of the Kef Eddour Member (Ypressian‐Priabonian) near Metlaoui and Sehib (Tunisia) show selective silicification with great variety in the silicified by‐products. Based on δ13C values, which support an organic origin for the carbon, carbonates replaced evaporites microbially through bacterial sulphate reduction. Observations and results suggest two scenarios for chert formation that are related to the rate and timing of diagenetic carbonate replacement of the evaporites (anhydrite/gypsum). In the absence of early diagenetic carbonate phases, silica with δ18O values from +25 to +28·6‰ [standard mean ocean water (SMOW)] replaced the outer parts of anhydrite nodules at pH < 9. In contrast, pore‐fluid pH values > 9 in the innermost parts of the anhydrite nodules prevented silica precipitation. The record of this chemical barrier is preserved in the microquartz rims and geode features that formed in the inner parts of the nodules after dissolution of the anhydrite nucleus. The microbial diagenetic replacement of evaporites (bacterial sulphate reduction) by carbonates (calcite, aragonite and dolomite) favoured silica replacement of carbonates rather than evaporites. Silica, with δ18O signature of +21 to +26‰ (SMOW), replaced carbonates on a volume‐for‐volume basis, yielding a more siliceous groundmass, and accounting for 90–95% of the nodules. The relatively higher δ18O values of quartz replacing anhydrite can be explained by a diagenetic fluid in equilibrium with mixed (meteoric/marine) to marine water. The lower δ18O values of the quartz that replaced the diagenetic carbonates are ascribed to flushing by meteoric water in a later diagenetic stage. The silica supply for chert formation could be derived from the reworked bio‐siliceous deposits (diatomites) to the west of the basin [vestiges of an opal‐CT precursor undetectable by X‐ray diffraction (XRD) were revealed by δ29Si magic‐angle‐spinning nuclear magnetic resonance investigations], diagenesis of the extraformational and overlying clay‐rich beds (the host limestones are clay‐poor as shown by XRD measurements), and minor volcanogenic and hydrothermal contributions during early diagenetic stages. 相似文献
7.
The Trypali carbonate unit (Upper Triassic), which crops out mainly in central‐western Crete, occurs between the parautochthonous series (Plattenkalk or Talea Ori‐Ida series, e.g. metamorphic Ionian series) and the Tripolis nappe (comprising the Tripolis carbonate series and including a basal Phyllite–Quartzite unit). It consists of interbedded dolomitic layers, represented principally by algally laminated peloidal mudstones, foraminiferal, peloidal and ooidal grainstones, as well as by fine‐grained detrital carbonate layers, in which coarse baroque dolomite crystals and dolomite nodules are dispersed. Baroque dolomite is present as pseudomorphs after evaporite crystals (nodules and rosettes), which grew penecontemporaneously by displacement and/or replacement of the host sediments (sabkha diagenesis). However, portions of the evaporites show evidence of resedimentation. Pre‐existing evaporites predominantly consisted of skeletal halite crystals that formed from fragmentation of pyramidal‐shaped hoppers, as well as of anhydrite nodules and rosettes (salt crusts). All microfacies are characteristic of peritidal depositional environments, such as sabkhas, tidal flats, shallow hypersaline lagoons, tidal bars and/or tidal channels. Along most horizons, the Trypali unit is strongly brecciated. These breccias are of solution‐collapse origin, forming after the removal of evaporite beds. Evaporite‐related diagenetic fabrics show that there was extensive dissolution and replacement of pre‐existing evaporites, which resulted in solution‐collapse of the carbonate beds. Evaporite replacement fabrics, including calcitized and silicified evaporite crystals, are present in cements in the carbonate breccias. Brecciation was a multistage process; it started in the Triassic, but was most active in the Tertiary, in association with uplift and ground‐water flow (telogenetic alteration). During late diagenesis, in zones of intense evaporite leaching and brecciation, solution‐collapse breccias were transformed to rauhwackes. The Trypali carbonate breccias (Trypali unit) are lithologically and texturally similar to the Triassic solution‐collapse breccias of the Ionian zone (continental Greece). The evaporites probably represent a major diapiric injection along the base of the parautochthonous series (metamorphic Ionian series) and also along the overthrust surface separating the parautochthonous series from the Tripolis nappe (Phyllite–Quartzite and Tripolis series). The injected evaporites were subsequently transformed into solution‐collapse breccias. 相似文献
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湖南常宁县康家湾铅锌金矿硅化角砾岩岩石地球化学特征 总被引：8，自引：0，他引：8
湖南常宁县康家湾铅锌金矿床硅化角砾岩带由未硅化角砾岩—极弱硅化角砾岩—硅化角砾岩—强硅化角砾岩(似硅质岩)组成,产于侏罗系与下伏二叠系间的不整合面附近,角砾成份复杂,充填物和胶结物类型多样。随着硅化程度的加强,硅化角砾岩带SiO2含量变化大,最高可达95.34%,而Al2O3、MgO、FeO、K2O、Na2O、CaO、CO2和P2O5含量特别是MgO、CaO、CO2和P2O5含量明显降低,且K2O>Na2O,TiO2的含量显著偏低。硅化角砾岩带LREE/HREE比值为1.95～4.93,Ce(δCe=0.44～0.81)和Eu(δEu=0.58～0.89)均为弱负异常,属轻稀土富集型,但随硅化程度增高稀土元素含量显著减少:未硅化和弱硅化角砾岩稀土元素总量较高,为(176.82～318.93)×10-10,与当冲组泥质岩配分曲线相似;硅化强烈的角砾岩稀土元素总量低,为(7.71～65.95)×10-10,与下伏栖霞组灰岩稀土元素配分曲线极为相似。结合微量元素F、Ba、Cl、Cr、Ni、Sr、V研究结果及硅化角砾岩带自底部至顶部特有的下粗上细的韵律性层理构造,认为康家湾铅锌金矿床硅化角砾岩带是在地台体制向地洼体制转变期的大地构造环境下,由于地壳快速隆升,二叠纪灰岩、泥质岩、石英砂岩等岩石剥蚀,在古河流环境下搬运、沉积形成的。此 相似文献
10.
The Eifelian sedimentary record in the epeiric Baltic Basin contains an extensive brecciated interval known as the Narva Breccia. During recent decades, the origin of this breccia has been attributed to (1) palaeoseismicity, (2) extraterrestrial impact event or (3) diagenetic collapse. Our studies show the presence of two different breccia types that form 11 stratigraphic horizons and contain several laterally and stratigraphically unrelated breccias. The occurrence of Type‐1 and Type‐2 breccias, together with carbonate sabkha and carbonate inter‐ to supratidal tidal flat deposits on the basin margins, indicates synsedimentary brecciation formed in a sabkha environment. Type‐2 breccia could also originate from wave‐cycling loading. 相似文献
11.
J. W. Granath 《Australian Journal of Earth Sciences》2013,60(1-2):115-118
Field and petrographic studies on granitic, hematitic and chloritic breccias in the central portion of the Mount Painter Inlier, South Australia, indicate that: (i) breccias and brecciated basement extend to depths exceeding 400 m and have gradational contacts; (ii) clasts are mainly autochthonous and contain fine‐scale hematite, chlorite or quartz veinlets and fractures; (iii) K‐metasomatism preceded hematitisation and chloritisation; (iv) hematitic breccia intrudes a pegmatite dyke correlated with the Ordovician Arkaroola Pegmatite; and (v) U, F and REE‐containing minerals are present in the Proterozoic basement rocks, and concentrated in the breccias. With a single exception, δ34S values for pyrite from the breccias and brecciated granites fall in the narrow range —2.9% to +3.5%, implying formation from magmatic emanations or reducing fluids that leached sulphide minerals of magmatic derivation. δ34S values for three barite samples are all close to +16%o, and firm conclusions cannot be drawn from these data. Calcites from the same rock‐types as the pyrite have δ13C values of — 22.3%o to —4.2%o and δ18O values of —4.0%o to +23.1%., with an inverse δ13C/δ18O relationship. The more 13C‐depleted calcites probably incorporated CO2 from organic C, and their δ18O values are compatible with precipitation from magmatic or metamorphic fluids; mixing of such fluids with meteoric waters is implied by the calcites with variably lower δ18O values. The above features indicate that the major processes leading to brecciation and associated metasomatism were hydraulic fracturing and hydrothermal activity resulting from ascent of granitic magmas to shallow crustal levels during late stages (late Ordovician‐?Silurian) of the Delamerian Orogeny. Tectonic and sedimentary processes appear to have played relatively minor roles in breccia formation. 相似文献
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The Upper Ordovician rocks of Hadeland, Norway, form a sequence of thin bedded nodular limestones (wackestones) and shales, hosting five distinctive sedimentary breccia complexes. These breccias contain blocks of varying sizes and shapes in a wackestone and grainstone matrix. Blocks differ in lithology, and in their included biotas and cement sequences. The thin bedded limestones are interpreted as turbidites, deposited against a background of hemipelagic calcareous shales. The breccias occupy channels cut into this sequence. The lithologies and biotas of blocks in the breccias record deposition in differing sedimentary environments, whereas their cements are the results of contrasting diagenetic histories. Blocks were eroded from a diverse and mature carbonate platform, close to sea level, which probably lay 5–10 km east of Hadeland. The breccias are interpreted as debris flow deposits, transported as channellized flows. Following channel cutting events, perhaps triggered by sea level change, channels were characterized by deposition rather than erosion. Wackestones and grainstones associated with the breccias also reflect resedimentation, their less diverse biota suggesting local derivation on the slope. The reworking of calcarenaceous muds locally produced clean washed calcarenites (now grainstones). A fall in sea level resulted in emergence of the upper slope and erosion of the debris flow complex to form caverns and fissures. As sea level rose again crinoidal calcarenites, now grainstones, were deposited within these cavities. Cement sequences in blocks record early marine and burial conditions on the shelf, and also precipitation of new marine cements following downslope transport. Those cements in lithologies formed in situ document later shallowing, culminating in emergence. The localized dissolution of cements in both blocks and associated grainstones reflects the infiltration of ‘aggressive’meteoric waters through permeable channel deposits. A subsequent rise in sea level is recorded in the generation of an additional marine cement with final burial reflected in the deposition of blocky calcite. The debris flow deposits therefore maintained their distinctive character from deposition through diagenesis. 相似文献
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A. Aranburu P. A. Fernández-Mendiola† M. A. López-Horgue†‡ J. García-Mondéjar† 《Sedimentology》2002,49(4):875-890
ABSTRACT A calcite mass more than 1·5 km long and 20 m wide crops outs along the faulted margin of the Albian carbonate platform of Jorrios in northern Spain. The mass contains abundant dissolution cavities up to 7 m long and 1 m high, filled with cross‐stratified quartz sandstone and alternating sandstone–calcite laminae. Similar cavities are also present in a 50‐m‐wide zone of platform limestones adjacent to the calcite mass that are filled with limestone breccias and sandstone. The calcite mass has mean δ18O values of 19·6‰ (SMOW), whereas platform limestones have mean δ18O values of 24·4‰ (SMOW). Synsedimentary faulting of the carbonate margin and circulation of heated fault‐related waters resulted in replacement of a band of limestone by calcite. Soon after this replacement, dissolution by undersaturated fluids affected both the calcite mass and the adjacent limestones. Percolating marine quartz sand filled all dissolution cavities, sometimes alternating with precipitating calcite. The resulting cavities and fills, which recall products of meteoric diagenesis, are attributed to a hydrothermal origin based on their geometry, occurrence along the profile and synsedimentary tectonic relationships. The early faulting and diagenesis are related to local extensional tectonism in a large‐scale strike‐slip setting. Movements occurred during the early dispar/appenninica zone of the Late Albian. 相似文献
14.
Limestones containing radiaxial fibrous cements were sampled along the southern slope of the late Anisian (Middle Triassic) Latemar carbonate platform in the Dolomites, northern Italy. The Latemar upper slopes comprise massive microbial boundstone, whereas lower slopes are made of clinostratified grainstone, rudstone and breccia. Samples are representative of a seawater column from near sea‐level to an aphotic zone at about 500 m water depth. Radiaxial fibrous cements were analyzed for carbon (δ13C) and oxygen (δ18O) stable isotopic composition, as well as major and trace element content, to shed light on the origin of the slope facies zonation. The δ13C vary between 1·7‰ and 2·3‰ (Vienna Pee‐Dee Belemnite), with lowest values at palaeo‐water depths between 70 m and 300 m. Radiaxial fibrous cements yielded seawater‐like rare earth element patterns with light rare earth element depletion (NdSN/YbSN ≈ 0·4), superchondritic yttrium/holmium ratios (≈55) and negative cerium anomalies. Cadmium reaches maximum values of ca 0·5 to 0·7 μg/g at palaeo‐water depths between 70 m and 300 m; barium contents (0·8 to 1·8 μg/g) increase linearly with depth. The downslope patterns of δ13C and cadmium suggest increased nutrient and organic matter contents at depths between ca 70 m and 300 m and point to an active biological pump. The peak in cadmium and the minimum of δ13C mark a zone of maximum organic matter respiration and high nutrient and organic matter availability. The base of this zone at ca 300 m depth corresponds with the transition from massive microbial boundstone to clinostratified grainstone, rudstone and breccia. The microbial boundstone facies apparently formed only in seawater enriched in organic matter, possibly because this organic matter sustained benthic microbial communities at Latemar. The base of slope microbialites on high‐relief microbial carbonate platforms may be a proxy for the depth to maximum respiration zones of Palaeozoic and Mesozoic periplatform basins. 相似文献
15.
Isolated, high relief carbonate platforms developed in the intracratonic basin of east-central Mexico during Albian-Cenomanian time. Relief on the platforms was of the order of 1000 m and slopes were as steep as 20–43°. Basin-margin debris aprons adjacent to the platforms comprise the Tamabra Formation. In the Sierra Madre Oriental, at the eastern margin of the Valles-San Luis Potosi Platform, an exceptionally thick (1380m) progradational basin to platform sequence of the Tamabra Formation can be divided into six lithological units. Basinal carbonate deposition that preceded deposition of the Tamabra Formation was emphatically punctuated by an allochthonous reef block 1 km long by 0·5 km wide with a stratigraphic thickness of 95 m. It is encased in Tamabra Formation unit A, approximately 360 m of peloidal-skeletal wackestone and lithoclastic-skeletal packstone that includes some graded beds. Unit B is 73 m of massive dolomite with sparse skeletal fragments and intraclasts. Unit C, 114m thick, consists of structureless skeletal wackestone passing upward into graded skeletal packstone. Interlaminated lime mudstone and fine grained bioclastic packstone with prominent horizontal burrows are interspersed near the top. Unit D is 126 m of breccia with finely interbedded skeletal grainstone and burrowed or laminated mudstone. The breccias contain a spectrum of platform-derived lithoclasts and basinal intraclasts, up to 10 m in size. The breccias are typically grain supported (rudstone) with a matrix of lightly to completely dolomitized mudstone or skeletal debris. Beds are up to several metres thick. Unit E is 206 m of massive, sucrosic dolomite that replaced breccias. Unit F is approximately 500 m of thick bedded to massive skeletal packstone with abundant rudists and a few mudstone intraclasts. Metre scale laminated lime mudstone beds are interspersed. The section is capped by El Abra Formation platform margin limestone, consisting of massive beds of caprinid packstone and grainstone with many whole valves. Depositional processes within this sequence shift from basinal pelagic or peri-platform sedimentation to distal, platform-derived, muddy turbidity currents with a large slump block (Unit A); through more proximal (coarser and cleaner) turbidity currents (Unit B?, C); to debris flows incorporating platform margin and slope debris (Units D, E). Finally, a talus of coarse, reef-derived bioclasts (Unit F) accumulated as the platform margin prograded over the slope sequence. Interspersed basinal deposits evolved gradually from largely pelagic to include influxes of dilute turbidity currents. Units containing turbidites with platform-derived bioclasts reflect flooding of the adjacent platform. Breccia blocks and lithoclasts were probably generated by erosion and collapse of the platform during lowstands. Laminated, black, pelagic carbonates, locally cherty, are interbedded with both breccias and turbidites. At least those interbedded with turbidites may have been deposited within an expanded mid-water oxygen minimum zone during relative highstands of sea level. They are in part coeval with mid-Cretaceous black shales of the Atlantic Ocean. 相似文献
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Dolomitization by penesaline sea water in Early Jurassic peritidal platform carbonates, Gibraltar, western Mediterranean 总被引：6，自引：0，他引：6
Peritidal carbonates of the Lower Jurassic (Liassic) Gibraltar Limestone Formation, which form the main mass of the Rock of Gibraltar, are replaced by fine and medium crystalline dolomites. Replacement occurs as massive bedded or laminated dolomites in the lower 100 m of an ≈460‐m‐thick platform succession. The fine crystalline dolomite has δ18Ο values either similar to, or slightly higher than, those expected from Early Jurassic marine dolomite, and δ13C values together with 87Sr/86Sr ratios that overlap with sea‐water values for that time, indicating that the dolomitizing fluid was Early Jurassic sea water. Absence of massive evaporitic minerals and/or evaporite solution‐collapse breccias in these carbonate rocks indicates that the salinity of sea water during dolomitization was below that of gypsum precipitation. The occurrence of peritidal facies, a restricted microbiota and rare gypsum pseudomorphs are also consistent with penesaline conditions (salinity 72–199‰). The medium crystalline dolomite has some δ18Ο and δ13C values and 87Sr/86Sr ratios similar to those of Early Jurassic marine dolomites, which indicates that ambient sea water was again a likely dolomitizing fluid. However, the spread of δ18Ο, δ13C and 87Sr/86Sr values indicates that dolomitization occurred at slightly increased temperatures as a result of shallow (≈500 m) burial or that dolomitization was multistage. These data support the hypothesis that penesaline sea water can produce massive dolomitization in thick peritidal carbonates in the absence of evaporite precipitation. Taking earlier models into consideration, it appears that replacement dolomites can be produced by sea water or modified sea water with a wide range of salinities (normal, penesaline to hypersaline), provided that there is a driving mechanism for fluid migration. The Gibraltar dolomites confirm other reports of significant Early Jurassic dolomitization in the western Tethys carbonate platforms. 相似文献
17.
XI Kelai CAO Yingchang LIN Miruo LIU Keyu WU Songtao YUAN Guanghui YANG Tian 《《地质学报》英文版》2019,93(1):213-226
This article reviews the applications of light stable isotope, including carbon, oxygen and hydrogen, in thestudies on origin and formation temperature of authigenic carbonate, quartz and clay minerals. Theoretical knowledge andanalytical methods for major light stable isotopes are introduced in detail. Negative and positive δ13C values indicatesignificant differences on the origin of carbonate cements. The δ18O value is an effective palaeotemperature scale forauthigenic minerals formation. Various fractionation equations between δ18O and temperature are proposed for carbonatecements, quartz cements and clay minerals, whose merit and demerit, applicable conditions are clarified clearly. Clumpedisotope analysis can reconstruct the temperature of carbonate precipitation with no requirement on the δ18O of initial waters,which makes temperature calculation of carbonate cements formation more convenient and accurate. Hydrogen and oxygenisotopes mainly reflect the origin of diagenetic fluid for clay mineral formation, providing reliable evidence for diageneticenvironment analysis. This work aims at helping researchers for better understanding the applications of light stable isotopein sandstone diagenesis. 相似文献
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塔里木盆地西克尔露头区鹰山组古岩溶特征及其储层意义 总被引：2，自引：0，他引：2
鹰山组上段因主要发育岩溶型储层而成为塔里木盆地奥陶系的重要含油气层,但因钻井资料的局限储层特征难以精确揭示。塔里木盆地西缘西克尔地区经历了多期构造运动,发育了多期不整合之下的表生岩溶作用,出露的鹰山组发育丰富的古岩溶现象,为研究鹰山组岩溶储层特征和揭示岩溶储层成因规律提供了良好的条件。通过野外剖面和室内薄片观察和描述,识别出了大型溶洞及其充填物、小型溶孔以及构造裂缝和溶蚀缝等。强烈的表生岩溶作用形成的溶洞和角砾岩可直接形成溶洞型储层;小型溶孔广泛发育,常与溶蚀缝伴生形成孔洞型或缝洞型储层;多期构造裂缝叠加在岩溶储层之上,能显著提升储层的渗透性。结合岩相分析表明,颗粒灰岩中溶孔的发育密度要明显高于泥晶灰岩;同时溶蚀缝和构造裂缝也更易发生在颗粒含量高的灰岩中,从而形成裂缝型和孔洞缝复合型有利储层。 相似文献
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M.G Bjrnerud 《Tectonophysics》1998,290(3-4):259-269
Breccias from the central uplift at the Kentland, Indiana impact structure have outcrop and microscopic characteristics that give insight into events that may occur in a carbonate-dominated sedimentary sequence in the moments following hypervelocity impact. Three distinct types of brecciated rock bodies — fault breccias, breccia lenses, and breccia dikes — suggest multiple mechanisms of fragmentation. The fault breccias occur along steeply dipping faults that coincide with compositional discontinuities in the stratigraphic succession. The breccia lenses and dikes are less localized in occurrence and show no systematic spatial distribution or orientation. The fault breccias and breccia lenses show no consistent cross-cutting relationships, but both are transected by the breccia dikes. Textural analysis reveals significant differences in particle size distributions for the different breccias. The fault breccias are typically monomict, coarsest and least uniform in grain size, and yield the highest power-law exponent (fractal dimension) in plots of particle size vs. frequency. The polymict dike filling is finest and most uniform in grain size, has the lowest power-law exponent, and is locally laminated and size-sorted. SEM images of the dike-filling breccia show that fragmentation occurred to the scale of microns. Material within the breccia lenses has textural characteristics intermediate between the other two types, but the irregular morphology of these bodies suggests a mechanism of formation different from that of either of the other breccia categories. The breccia lenses and dikes both have sub-mm-scale spheroidal vugs that may have been formed by carbon dioxide bubbles released during sudden devolatilization of the carbonate country rock. Collectively, these observations shed light on the processes that occur during the excavation and modification phases of crater formation in carbonate strata — heterogeneous, polyphase, multiscale deformation accomplished over a time interval of seconds. 相似文献