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1.
We present an analysis of 19 μm spectra of Io’s SO2 atmosphere from the TEXES mid-infrared high spectral resolution spectrograph on NASA’s Infrared Telescope Facility, incorporating new data taken between January 2005 and June 2010 and a re-analysis of earlier data taken from November 2001 to January 2004. This is the longest set of contiguous observations of Io’s atmosphere using the same instrument and technique thus far. We have fitted all 16 detected blended absorption lines of the ν2 SO2 vibrational band to retrieve the subsolar values of SO2 column abundance and the gas kinetic temperature. By incorporating an existing model of Io’s surface temperatures and atmosphere, we retrieve sub-solar column densities from the disk-integrated data. Spectra from all years are best fit by atmospheric temperatures <150 K. Best-fit gas kinetic temperatures on the anti-Jupiter hemisphere, where SO2 gas abundance is highest, are low and stable, with a mean of 108 (±18) K. The sub-solar SO2 column density between longitudes of 90–220° varies from a low of 0.61 (±0.145) × 10?17 cm?2, near aphelion in 2004, to a high of 1.51 (±0.215) × 1017 cm?2 in 2010 when Jupiter was approaching its early 2011 perihelion. No correlation in the gas temperature was seen with the increasing SO2 column densities outside the errors.Assuming that any volcanic component of the atmosphere is constant with time, the correlation of increasing SO2 abundance with decreasing heliocentric distance provides good evidence that the atmosphere is at least partially supported by frost sublimation. The SO2 frost thermal inertias and albedos that fit the variation in atmospheric density best are between 150–1250 W m?2 s?1/2 K?1 and 0.613–0.425 respectively. Photometric evidence favors albedos near the upper end of this range, corresponding to thermal inertias near the lower end. This relatively low frost thermal inertia produces larger amplitude seasonal variations than are observed, which in turn implies a substantial additional volcanic atmospheric component to moderate the amplitude of the seasonal variations of the total atmosphere on the anti-Jupiter hemisphere. The seasonal thermal inertia we measure is unique both because it refers exclusively to the SO2 frost surface component, and also because it refers to relatively deep subsurface layers (few meters) due to the timescales of many years, while previous studies have determined thermal inertias at shallower levels (few centimeters), relevant for timescales of ～2 h (eclipse) or ～2 days (diurnal curves).  相似文献   

2.
The Visible and Infra-Red Thermal Imaging Spectrometer (VIRTIS) instrument on board the Venus Express spacecraft has measured the O2(a1Δ) nightglow distribution at 1.27 μm in the Venus mesosphere for more than two years. Nadir observations have been used to create a statistical map of the emission on Venus nightside. It appears that the statistical 1.6 MR maximum of the emission is located around the antisolar point. Limb observations provide information on the altitude and on the shape of the emission layer. We combine nadir observations essentially covering the southern hemisphere, corrected for the thermal emission of the lower atmosphere, with limb profiles of the northern hemisphere to generate a global map of the Venus nightside emission at 1.27 μm. Given all the O2(a1Δ) intensity profiles, O2(a1Δ) and O density profiles have been calculated and three-dimensional maps of metastable molecular and atomic oxygen densities have been generated. This global O density nightside distribution improves that available from the VTS3 model, which was based on measurements made above 145 km. The O2(a1Δ) hemispheric average density is 2.1 × 109 cm?3, with a maximum value of 6.5 × 109 cm?3 at 99.2 km. The O density profiles have been derived from the nightglow data using CO2 profiles from the empirical VTS3 model or from SPICAV stellar occultations. The O hemispheric average density is 1.9 × 1011 cm?3 in both cases, with a mean altitude of the peak located at 106.1 km and 103.4 km, respectively. These results tend to confirm the modeled values of 2.8 × 1011 cm?3 at 104 km and 2.0 × 1011 cm?3 at 110 km obtained by Brecht et al. [Brecht, A., Bougher, S.W., Gérard, J.-C., Parkinson, C.D., Rafkin, S., Foster, B., 2011a. J. Geophys. Res., in press] and Krasnopolsky [Krasnopolsky, V.A., 2010. Icarus 207, 17–27], respectively. Comparing the oxygen density map derived from the O2(a1Δ) nightglow observations, it appears that the morphology is very different and that the densities obtained in this study are about three times higher than those predicted by the VTS3 model.  相似文献   

3.
Hubble Space Telescope/Wide Field and Planetary Camera 2 (HST/WFPC2) images of Io obtained between 1995 and 2007 between 0.24 and 0.42 μm led to the detection of the Pele plume in reflected sunlight in 1995 and 1999; imaging of the Pele plume via absorption of jovian light in 1996 and 1999; detection of the Prometheus-type Pillan plume in reflected sunlight in 1997; and detection of the 2007 Pele-type Tvashtar plume eruption in reflected sunlight and via absorption of jovian light. Based on a detailed analysis of these observations we characterize and compare the gas and dust properties of each of the detected plumes. In each case, the brightness of the plumes in reflected sunlight is less at 0.26 μm than at 0.33 μm. Mie scattering analysis of the wavelength dependence of each plume’s reflectance signature suggests that range of particle sizes within the plumes is quite narrow. Assuming a normal distribution of particle sizes, the range of mean particle sizes is ～0.035–0.12 μm for the 1997 Pillan eruption, ～0.05–0.08 μm for the 1999 Pele and 2007 Tvasthar plumes, and ～0.05–0.11 μm for the 1995 Pele plume, and in each case the standard deviation in the particle size distribution is <15%. The Mie analysis also suggests that the 2007 Tvashtar eruption released ～109 g of sulfur dust, the 1999 Pele eruption released ～109 g of SO2 dust, the 1997 Pillan eruption released ～1010 g of SO2 dust, and the 1995 Pele plume may have released ～1010 g of SO2 dust. Analysis of the plume absorption signatures recorded in the F255W filter bandpass (0.24–0.28 μm) indicates that the opacity of the 2007 Tvashtar plume was 2× that of the 1996 and 1999 Pele plume eruptions. While the sulfur dust density estimated for the Tvashtar from the reflected sunlight data could have produced 61% of the observed plume opacity, <10% of the 1999 Pele F255W plume opacity could have resulted from the SO2 dust detected in the eruption. Accounting for the remaining F255W opacity level of the Pele and Tvasthar plumes based on SO2 and S2 gas absorption, the SO2 and S2 gas density inferred for each plume is almost equivalent corresponding to ～2–6 × 1016 cm?2 and 3–5 × 1015 cm?2, respectively, producing SO2 and S2 gas resurfacing rates ～0.04–0.2 cm yr?1 and 0.007–0.01 cm yr?1; and SO2 and S2 gas masses ～1–4 × 1010 g and ～2–3 × 109 g; for a total dust to gas ratio in the plumes ～10?1–10?2. The 2007 Tvashtar plume was detected by HST at ～380 ± 40 km in both reflected sunlight and absorbed jovian light; in 1999, the detected Pele plume altitude was 500 km in absorbed jovian light, but in reflected sunlight the detected height was ～2× lower. Thus, for the 1999 Pele plume, similar to the 1979 Voyager Pele plume observations, the most efficient dust reflections occurred in the region closest to the plume vent. The 0.33–0.42 μm brightness of the 1997 Pillan plume was 10–20× greater than the Pele or Tvashtar plumes, exceeding by a factor of 3 the average brightness levels observed within 200 km of 1979 Loki eruption vent. But, the 0.26 μm brightness of the 1997 Pillan plume in reflected sunlight was significantly lower than would be predicted by the dust scattering model. Presuming that the 0.26 μm brightness of the 1997 Pillan plume was attenuated by the eruption plume’s gas component, then an SO2 gas density ～3–6 × 1018 cm?2 is inferred from the data (for S2/SO2 ratios ?4%), comparable to the 0.3–2 × 1018 cm?2 SO2 density detected at Loki in 1979 (Pearl, J.C. et al. [1979]. Nature 280, 755; Lellouch et al., 1992), and producing an SO2 gas mass ～3–8 × 1011 g and an SO2 resurfacing rate ～8–23 cm yr?1. These results confirm the connection between high (?1017 cm?2) SO2 gas content and plumes that scatter strongly at nearly blue wavelengths, and it validates the occurrence of high density SO2 gas eruptions on Io. Noting that the SO2 gas content inferred from a spectrum of the 2003 Pillan plume was significantly lower ～2 × 1016 cm?2 (Jessup, K.L., Spencer, J., Yelle, R. [2007]. Icarus 192, 24–40); and that the Pillan caldera was flooded with fresh SO2 frost/slush just prior to the 1997 Pillan plume eruption (Geissler, P., McEwen, A., Phillips, C., Keszthelyi, L., Spencer, J. [2004a]. Icarus 169, 29–64; Phillips, C.B. [2000]. Voyager and Galileo SSI Views of Volcanic Resurfacing on Io and the Search for Geologic Activity at Europa. Ph.D. Thesis, Univ. of Ariz., Tucson); we propose that the density of SO2 gas released by this volcano is directly linked to the local SO2 frost abundance at the time of eruption.  相似文献   

4.
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5.
We present the photoionisation modelling of the intrinsic absorber in the bright quasar HS 1603 + 3820. We constructed the broad-band spectral energy distribution using the optical/UV/X-ray observations from different instruments as inputs for the photoionisation calculations. The spectra from the Keck telescope show extremely high Civ to Hi ratios, for the first absorber in system A, named A1. This value, together with high column density of Civ ion, place strong constraints on the photoionisation model. We used two photoionisation codes to derive the hydrogen number density at the cloud illuminated surface. By estimating bolometric luminosity of HS 1603 + 3820 using the typical formula for quasars, we calculated the distance to A1. We could find one photoionization solution, by assuming either a constant density cloud (which was modelled using cloudy), or a stratified cloud (which was modelled using titan), as well as the solar abundances. This model explained both the ionic column density of Civ and the high Civ to Hi ratio. The location of A1 is 0.1 pc, and it is situated even closer to the nucleus than the possible location of the Broad Line Region in this object. The upper limit of the distance is sensitive to the adopted covering factor and the carbon abundance. Photoionisation modelling always prefers dense clouds with the number density n0 = 1010 − 1012 cm−3, which explains intrinsic absorption in HS 1603 + 3820. This number density is of the same order as that in the disk atmosphere at the implied distance of A1. Therefore, our results show that the disk wind that escapes from the outermost accretion disk atmosphere can build up dense absorber in quasars.  相似文献   

6.
Jeffrey R. Johnson 《Icarus》2012,221(1):359-364
Andesine-rich (An36–46) anorthosite rocks experimentally shocked to high pressures (16–57 GPa) exhibit changes in spectral features with increasing pressure in laboratory thermal infrared emission spectra (250–1400 cm?1). These results are similar to previous studies of shocked bytownite- and albite-rich rocks, albeit with differences in absorption band centers characteristic of mineralogy and composition. Typical spectral absorptions result from Si–O antisymmetric stretch motions of the silica tetrahedral (1000–1250 cm?1) and weaker absorptions due to Si–O–Si octahedral bending vibrations (350–700 cm?1). Many of these features persist to higher pressures in the andesine spectra compared to similar features in measurements of shocked bytownite. This is consistent with previous thermal infrared absorption studies of shocked feldspars and likely is related to differences in density, hardness, and Al content. A transparency feature at ～832 cm?1 observed in powdered andesine spectra also degrades with increasing pressure, intermediate between the ～828 cm?1 and ～855 cm?1 transparency features in spectra of powders of shocked bytownite and albitite, respectively. These data can be incorporated into thermal infrared spectral analyses of cratered planetary surfaces (or laboratory spectra of shocked samples) to help constrain the occurrence and degree of shock in plagioclase feldspars.  相似文献   

7.
《New Astronomy》2007,12(6):435-440
A detailed analysis of emission lines of carbon-like silicon reveals that some ratios of n = 3 → 2 line intensities are sensitive to the electron density, ne. The ratio between two groups of 3d → 2p transition lines of 55.246 Å and 55.346 Å provides a good diagnostic of ne because of the combined characteristic of sensitivity to electron density and relative insensitivity to temperature. From this ratio, a lower limit of the electron density of 0.6 × 108 cm−3 was set for Procyon, which is consistent with the values constrained by C V and Si X emission lines. Significant discrepancies were found between theoretical predictions and observations for the 3s → 2p lines relative to 3d → 2p lines in Procyon, recently measured using the Chandra high-resolution transmission grating instrument. The difference of more than a factor of 3, cannot be explained by uncertainties of atomic data. Ness and co-workers also suggested that the effect of opacity appeared not to be a major factor for the discrepancy. For the 3s → 2p line at 61.611 Å, present work indicates that the large discrepancy may be from the contamination of a S VIII line at 61.645 Å. For lines at 61.702 and 61.846 Å, we suggest that the discrepancies may be attributed to contaminations by currently yet-unknown spectral lines.  相似文献   

8.
The ZrO molecule has been detected in sunspot umbrae through the identification of following laboratory molecular transitions: 1Σ+ ? X1Σ+ (0, 0), A3Φ2 ? X2Δ1 (0, 0), A3Φ3 ? X2Δ2 (0, 0), A3Φ4 ? X2Δ3 (0, 0), B3Π2 ? X3Δ3 (0, 0), B3Π1 ? X3Δ2 (0, 0) and B3Π0 ? X3Δ1 (0, 0) in red – infrared region using high resolution, visible range Fourier Transform Spectrum of sunspot umbra observed at the National Solar Observatory in Kitt Peak (NSO/KP). Much new identification has been made in the searched spectral wavenumber region from 16650 cm?1 to 18007 cm?1 of sunspot spectrum. Equivalent widths of well resolved lines, versus rotational quantum number J have been used to determine the effective rotational temperature for seven bands of the ZrO molecule. This result agrees well with the temperatures derived for other molecules’ presence in sunspot umbrae. It is evident that ZrO molecular lines are formed in higher layers of the atmosphere of relatively “cold” sunspots.  相似文献   

9.
We examine spectral properties of the SDSS quasar J093201.60 + 031858.7, in particular the presence of strong blue peaks in the Balmer emission lines offset from the narrow lines by approximately 4200 km s?1. Asymmetry in the broad central component of the Hβ line indicates the presence of a double-peaked emitter. However, the strength and sharpness of the blue Hβ and blue Hγ peaks make this quasar spectrum unique among double-peaked emitters identified from SDSS spectra. We fit a disk model to the Hβ line and compare this object with other unusual double-peaked quasar spectra, particularly candidate binary supermassive black holes (SMBHs). Under the binary SMBH scenario, we test the applicability of a model in which a second SMBH may produce the strong blue peak in the Balmer lines of a double-peaked emitter. If there were only one SMBH, a circular, Keplerian disk model fit would be insufficient, indicating some sort of asymmetry is required to produce the strength of the blue peak. In either case, understanding the nature of the complex line emission in this object will aid in further discrimination between a single SMBH with a complex accretion disk and the actual case of a binary SMBH.  相似文献   

10.
Building upon previous studies, we re-investigated the ethane spectrum between 1330 and 1610 cm?1 by combining unapodized spectra obtained at room temperature with a Bruker Fourier transform spectrometer (FTS) in Brussels and at 131 K with a Bruker FTS in Pasadena. The maximum optical path differences (MOPD) of the two datasets were 450 and 323.7 cm, corresponding to spectral resolutions of 0.0020 and 0.0028 cm?1, respectively. Of the 15,000 lines observed, over 4592 transitions were assigned to the ν6 (at 1379 cm?1), ν8 (at 1472 cm?1), ν4+ν12 (at 1481 cm?1) and 2ν4+ν9 (at 1388 cm?1) bands, and another 1044 transitions were located for the ν4+ν8?ν4 hot band (at 1472 cm?1). Our new analysis included an improved implementation of the Hamiltonian calculation needed to interpret the complex spectral structures caused by numerous interactions affecting these four modes of vibration. From these results, we created the first line-by-line database containing the molecular parameters for over 20,000 12C2H6 transitions at 7 μm.  相似文献   

11.
We report observations of Titan's high-altitude exosphere detected out to about 50,000 km altitude. The observations were made by the Ion Neutral Camera (INCA) on board the Cassini spacecraft. INCA detects energetic neutral atoms (ENA) that are formed when the ambient magnetospheric ions charge exchange with Titan's neutral atmosphere and exosphere. We find that Titan's exospheric H2 distribution follows closely a full Chamberlain distribution including ballistic, escaping and satellite distributions. As expected, neutral densities are dominated by a satellite distribution above about 10,000 km. The maximum detectable extent of the exosphere (～50,000 km) coincides with the radius of the Hill sphere of gravitational influence from Saturn. While we find no direct indications of a neutral Titan torus with densities greater than about 1000 cm?3, we observe interesting asymmetries in the distribution that warrants further investigation. Based on these findings we compute the average precipitating ENA flux to be about 5×106 keV/(cm2 s), or 8×10?3 erg/(cm2 s), which is directly comparable to that of precipitating energetic ions (Sittler, et al., 2009) and slightly higher than that of solar EUV (Tobiska, 2004). Thus, the energy deposited by precipitating ENAs must also be taken into consideration when studying the energy balance of Titan's thermosphere.  相似文献   

12.
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13.
We present the ensemble properties of 31 comets (27 resolved and 4 unresolved) observed by the Sloan Digital Sky Survey (SDSS). This sample of comets represents about 1 comet per 10 million SDSS photometric objects. Five-band (u, g, r, i, z) photometry is used to determine the comets’ colors, sizes, surface brightness profiles, and rates of dust production in terms of the Afρ formalism. We find that the cumulative luminosity function for the Jupiter Family Comets in our sample is well fit by a power law of the form N(<H) ∝ 10(0.49±0.05)H for H < 18, with evidence of a much shallower fit N(<H) ∝ 10(0.19±0.03)H for the faint (14.5 < H < 18) comets. The resolved comets show an extremely narrow distribution of colors (0.57 ± 0.05 in g ? r for example), which are statistically indistinguishable from that of the Jupiter Trojans. Further, there is no evidence of correlation between color and physical, dynamical, or observational parameters for the observed comets.  相似文献   

14.
Vertical distributions and spectral characteristics of Titan’s photochemical aerosol and stratospheric ices are determined between 20 and 560 cm?1 (500–18 μm) from the Cassini Composite Infrared Spectrometer (CIRS). Results are obtained for latitudes of 15°N, 15°S, and 58°S, where accurate temperature profiles can be independently determined.In addition, estimates of aerosol and ice abundances at 62°N relative to those at 15°S are derived. Aerosol abundances are comparable at the two latitudes, but stratospheric ices are ～3 times more abundant at 62°N than at 15°S. Generally, nitrile ice clouds (probably HCN and HC3N), as inferred from a composite emission feature at ～160 cm?1, appear to be located over a narrow altitude range in the stratosphere centered at ～90 km. Although most abundant at high northern latitudes, these nitrile ice clouds extend down through low latitudes and into mid southern latitudes, at least as far as 58°S.There is some evidence of a second ice cloud layer at ～60 km altitude at 58°S associated with an emission feature at ～80 cm?1. We speculate that the identify of this cloud may be due to C2H6 ice, which in the vapor phase is the most abundant hydrocarbon (next to CH4) in the stratosphere of Titan.Unlike the highly restricted range of altitudes (50–100 km) associated with organic condensate clouds, Titan’s photochemical aerosol appears to be well-mixed from the surface to the top of the stratosphere near an altitude of 300 km, and the spectral shape does not appear to change between 15°N and 58°S latitude. The ratio of aerosol-to-gas scale heights range from 1.3–2.4 at about 160 km to 1.1–1.4 at 300 km, although there is considerable variability with latitude. The aerosol exhibits a very broad emission feature peaking at ～140 cm?1. Due to its extreme breadth and low wavenumber, we speculate that this feature may be caused by low-energy vibrations of two-dimensional lattice structures of large molecules. Examples of such molecules include polycyclic aromatic hydrocarbons (PAHs) and nitrogenated aromatics.Finally, volume extinction coefficients NχE derived from 15°S CIRS data at a wavelength of λ = 62.5 μm are compared with those derived from the 10°S Huygens Descent Imager/Spectral Radiometer (DISR) data at 1.583 μm. This comparison yields volume extinction coefficient ratios NχE(1.583 μm)/NχE(62.5 μm) of roughly 70 and 20, respectively, for Titan’s aerosol and stratospheric ices. The inferred particle cross-section ratios χE(1.583 μm)/χE(62.5 μm) appear to be consistent with sub-micron size aerosol particles, and effective radii of only a few microns for stratospheric ice cloud particles.  相似文献   

15.
In the history of Mars exploration its atmosphere and planetary climatology aroused particular interest. In the study of the minor gases abundance in the Martian atmosphere, water vapour became especially important, both because it is the most variable trace gas, and because it is involved in several processes characterizing the planetary atmosphere. The water vapour photolysis regulates the Martian atmosphere photochemistry, and so it is strictly related to carbon monoxide. The CO study is very important for the so-called “atmosphere stability problem”, solved by the theoretical modelling involving photochemical reactions in which the H2O and the CO gases are main characters.The Planetary Fourier Spectrometer (PFS) on board the ESA Mars Express (MEX) mission can probe the Mars atmosphere in the infrared spectral range between 200 and 2000 cm?1 (5–50 μm) with the Long Wavelength Channel (LWC) and between 1700 and 8000 cm?1 (1.2–5.8 μm) with the Short Wavelength Channel (SWC). Although there are several H2O and CO absorption bands in the spectral range covered by PFS, we used the 3845 cm?1 (2.6 μm) and the 4235 cm?1 (2.36 μm) bands for the analysis of water vapour and carbon monoxide, respectively, because these ranges are less affected by instrumental problems than the other ones. The gaseous concentrations are retrieved by using an algorithm developed for this purpose.The PFS/SW dataset used in this work covers more than two and a half Martian years from Ls=62° of MY 27 (orbit 634) to Ls=203° of MY 29 (orbit 6537). We measured a mean column density of water vapour of about 9.6 pr. μm and a mean mixing ratio of carbon monoxide of about 990 ppm, but with strong seasonal variations at high latitudes. The seasonal water vapour map reproduces very well the known seasonal water cycle. In the northern summer, water vapour and CO show a good anticorrelation most of the time. This behaviour is due to the carbon dioxide and water sublimation from the north polar ice cap, which dilutes non-condensable species including carbon monoxide. An analogous process takes place during the winter polar cap, but in this case the condensation of carbon dioxide and water vapour causes an increase of the concentration of non-condensable species. Finally, the results show the seasonal variation of the carbon monoxide mixing ratio with the surface pressure.  相似文献   

16.
Determining the optical constants of Titan aerosol analogues, or tholins, has been a major concern for the last three decades because they are essential to constrain the numerical models used to analyze Titan’s observational data (albedo, radiative transfer, haze vertical profile, surface contribution, etc.). Here we present the optical constant characterization of tholins produced with an RF plasma discharge in a (95%N2–5%CH4) gas mixture simulating Titan’s main atmospheric composition, and deposited as a thin film on an Al–SiO2 substrate. The real and imaginary parts, n and k, of the tholin complex refractive index have been determined from 370 nm to 900 nm wavelength using spectroscopic ellipsometry. The values of n decrease from n = 1.64 (at 370 nm) to n = 1.57 (at 900 nm) as well as the values of k which feature two behaviors: an exponential decay from 370 nm to 500 nm, with k = 12.4 × e?0.018λ (where λ is expressed in nm), followed by a plateau, with k = (1.8 ± 0.2) × 10?3. The trends observed for the PAMPRE tholins optical constants are compared to those determined for other Titan tholins, as well as to the optical constants of Titan’s aerosols retrieved from observational data.  相似文献   

17.
We present observations of the O2(a1Δg) nightglow at 1.27 μm on Mars using the SPICAM IR spectrometer onboard of the Mars Express orbiter. In contrast to the O2(a1Δg) dayglow that results from the ozone photodissociation, the O2(a1Δg) nightglow is a product of the recombination of O atoms formed by CO2 photolysis on the dayside at altitudes higher than 80 km and transported downward above the winter pole by the Hadley circulation. The first detections of the O2(a1Δg) nightglow in 2010 indicate that it is about two order of magnitude less intense than the dayglow (Bertaux, J.-L., Gondet, B., Bibring, J.-P., Montmessin, F., Lefèvre, F. [2010]. Bull. Am. Astron. Soc. 42, 1040; Clancy et al. [2010]. Bull. Am. Astron. Soc. 42, 1041). SPICAM IR sounds the martian atmosphere in the near-IR range (1–1.7 μm) with the spectral resolution of 3.5 cm?1 in nadir, limb and solar occultation modes. In 2010 the vertical profiles of the O2(a1Δg) nightside emission have been obtained near the South Pole at latitudes of 82–83°S for two sequences of observations: Ls = 111–120° and Ls = 152–165°. The altitude of the emission maximum varied from 45 km on Ls = 111–120° to 38–49 km on Ls = 152–165°. Averaged vertically integrated intensity of the emission at these latitudes has shown an increase from 0.22 to 0.35 MR. Those values of total vertical emission rate are consistent with the OMEGA observations on Mars-Express in 2010. The estimated density of oxygen atoms at altitudes from 50 to 65 km varies from 1.5 × 1011 to 2.5 × 1011 cm?3. Comparison with the LMD general circulation model with photochemistry (Lefèvre, F., Lebonnois, S., Montmessin, F., Forget, F. [2004]. J. Geophys. Res. 109, E07004; Lefèvre et al. [2008]. Nature 454, 971–975) shows that the model reproduces fairly well the O2(a1Δg) emission layer observed by SPICAM when the large field of view (>20 km on the limb) of the instrument is taken into account.  相似文献   

18.
Vladimir Krasnopolsky 《Icarus》2012,219(1):244-249
To search for DCl in the Venus atmosphere, a spectrum near the D35Cl (1–0) R4 line at 2141.54 cm?1 was observed using the CSHELL spectrograph at NASA IRTF. Least square fitting to the spectrum by a synthetic spectrum results in a DCl mixing ratio of 17.8 ± 6.8 ppb. Comparing to the HCl abundance of 400 ± 30 ppb (Krasnopolsky [2010a] Icarus, 208, 314–322), the DCl/HCl ratio is equal to 280 ± 110 times the terrestrial D/H = 1.56 × 10?4. This ratio is similar to that of HDO/H2O = 240 ± 25 times the terrestrial HDO/H2O from the VEX/SOIR occultations at 70–110 km. Photochemistry in the Venus mesosphere converts H from HCl to that in H2O with a rate of 1.9 × 109 cm?2 s?1 (Krasnopolsky [2012] Icarus, 218, 230–246). The conversion involves photolysis of HCl; therefore, the photochemistry tends to enrich D/H in HCl and deplete in H2O. Formation of the sulfuric acid clouds may affect HDO/H2O as well. The enriched HCl moves down by mixing to the lower atmosphere where thermodynamic equilibriums for H2 and HCl near the surface correspond to D/H = 0.71 and 0.74 times that in H2O, respectively. Time to establish these equilibriums is estimated at ～3 years and comparable to the mixing time in the lower atmosphere. Therefore, the enriched HCl from the mesosphere gives D back to H2O near the surface. Comparison of chemical and mixing times favors a constant HDO/H2O up to ～100 km and DCl/HCl equal to D/H in H2O times 0.74.Ammonia is an abundant form of nitrogen in the reducing environments. Thermodynamic equilibriums with N2 and NO near the surface of Venus give its mixing ratio of 10?14 and 6 × 10?7, respectively. A spectrum of Venus near the NH3 line at 4481.11 cm?1 was observed at NASA IRTF and resulted in a two-sigma upper limit of 6 ppb for NH3 above the Venus clouds. This is an improvement of the previous upper limit by a factor of 5. If ammonia exists at the ppb level or less in the lower atmosphere, it quickly dissociates in the mesosphere and weakly affects its photochemistry.  相似文献   

19.
The exosphere of an atmosphereless icy moon is the result of different surface release processes and subsequent modification of the released particles. At Europa icy moon, water molecules are directly released, but photolysis and radiolysis due to solar UV and Jupiter’s magnetospheric plasma, respectively, can result in OH, H, O and (possibly) H2 production. These molecules can recombine to reform water and/or new chemical species. As a consequence, Europa’s neutral environment becomes a mixture of different molecules, among which, H2O dominates in the highest altitudes and O2, formed mainly by radiolysis of ice and subsequent release of the produced molecules, prevails at lower altitudes. In this work, starting from a previously developed Monte Carlo model for the generation of Europa’s exosphere, where the only considered species was water, we make a first attempt to simulate also the H2 and O2 components of the neutral environment around Europa, already observed by the Hubble Space Telescope and the Ultraviolet Imaging Spectrograph on board Cassini, during its flyby of Jupiter. Considering a specific configuration where the leading hemisphere coincides with the sunlit hemisphere, we estimate along the Europa–Sun line an O2 column density of about 1.5 × 1019 m?2 at the dayside and 3 × 1018 m?2 at the nightside. In this work we also improve our previous estimation of the sputtered H2O exosphere of this moon, taking into consideration the trailing–leading asymmetry in the magnetospheric ion bombardment and the energy and temperature dependences of the process yields. We find that a density of 1.5 × 1012 H2O/m3 is expected at altitudes ～0.1RE above the surface of the trailing hemisphere. Additionally, we calculate the escape of H2O, O2 and H2. The total number of neutral atoms in Europa’s neutral torus, is estimated to be in the range 7.8 × 1032–3.3 × 1033.  相似文献   

20.
To ascertain the importance of sputtering by solar wind ions on the formation of a sodium exosphere around Mercury and the Moon, we have irradiated with 4 keV He ions, the Na bearing tectosilicates: albite, labradorite, and anorthoclase, as well as adsorbed Na layers deposited on albite and on olivine (a neosilicate that does not contain Na). Sodium at the surface and near surface (<40 Å) was quantified with X-ray photoelectron spectroscopy before and after each irradiation to determine the depletion cross section. We measured a cross section for sputtering of Na adsorbed on mineral surfaces, σs ≈ 1 × 10?15 cm2 atom?1. In addition, mass spectrometric analyses of the sputtered flux show that a large fraction of the Na is sputtered as ions rather than as neutral atoms. These results have strong implications for modeling the sodium population within the mercurian and the lunar exospheres.  相似文献   

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