首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 15 毫秒
1.
《Icarus》1987,72(3):604-622
The electrical conductivity and electrical charge on the aerosols in atmosphere of Titan are computed for altitudes from 0 to 400 km. Ionization due to both galactic cosmic rays and electron precipitation from the Saturnian magnetosphere is considered. This ionization results in free electrons and the primary ions N2+ and N+ which are then rapidly converted into secondary ions such as H2CN+ and NH4+ which in turn form ion clusters such as H2CN+(HCN)n and NH4+(NH3)m. In contrast to the atmospheres of Venus and Earth, we find no species in the Titan atmosphere that lead to the formation of appreciable concentrations of negative ions. Consequently, the predicted conductivity is quite different in that a substantial concentration of electrons exists all the way to the surface of Titan. The ubiquitous aerosols observed in the Titan atmosphere also play an important role in determining the charge distribution in the atmosphere. At altitudes above 100 km and for aerosol concentrations above approximately 10/cc, the recombination of electrons and positive ions is controlled by the recombination on the surface of the aerosols rather than by the gas-kinetic recombination rate. For small aerosol concentrations, the ratio of the number of charges per particle to the radius of the particle is approximately 30, for radii in microns. This value is similar to that obtained by previous investigators for terrestrial noctilucent clouds. Because the aerosol particles are highly charged, coagulation is inhibited, particle sizes are smaller, and their settling rates are reduced. As a consequence, the optical depth of the atmosphere is much higher than it would be if the particles were uncharged.  相似文献   

2.
Ionization of the atmosphere of Titan by galactic cosmic rays is a very significant process throughout the altitude range of 100 to 400 km. An approximate form of the Boltzmann equation for cosmic ray transport has been used to obtain local ionization rates. Models of both ion and neutral chemistry have been employed to compute electron and ion density profiles for three different values of the H2/CH4 abundance ratio. The peak electron density is of the order 103 cm?3. The most abundant positive ions are C2H9+ and C3H9+, while the predicted densities of the negative ions H? and CH3? are very small (<10?4 that of the positive ions). It is suggested that inclusion of the ion chemistry is important in the computation of the H and CH3 density profiles in the lower ionosphere.  相似文献   

3.
Discovery by Cassini's plasma instrument of heavy positive and negative ions within Titan's upper atmosphere and ionosphere has advanced our understanding of ion neutral chemistry within Titan's upper atmosphere, primarily composed of molecular nitrogen, with ~2.5% methane. The external energy flux transforms Titan's upper atmosphere and ionosphere into a medium rich in complex hydrocarbons, nitriles and haze particles extending from the surface to 1200 km altitudes. The energy sources are solar UV, solar X-rays, Saturn's magnetospheric ions and electrons, solar wind and shocked magnetosheath ions and electrons, galactic cosmic rays (GCR) and the ablation of incident meteoritic dust from Enceladus’ E-ring and interplanetary medium. Here it is proposed that the heavy atmospheric ions detected in situ by Cassini for heights >950 km, are the likely seed particles for aerosols detected by the Huygens probe for altitudes <100 km. These seed particles may be in the form of polycyclic aromatic hydrocarbons (PAH) containing both carbon and hydrogen atoms CnHx. There could also be hollow shells of carbon atoms, such as C60, called fullerenes which contain no hydrogen. The fullerenes may compose a significant fraction of the seed particles with PAHs contributing the rest. As shown by Cassini, the upper atmosphere is bombarded by magnetospheric plasma composed of protons, H2+ and water group ions. The latter provide keV oxygen, hydroxyl and water ions to Titan's upper atmosphere and can become trapped within the fullerene molecules and ions. Pickup keV N2+, N+ and CH4+ can also be implanted inside of fullerenes. Attachment of oxygen ions to PAH molecules is uncertain, but following thermalization O+ can interact with abundant CH4 contributing to the CO and CO2 observed in Titan's atmosphere. If an exogenic keV O+ ion is implanted into the haze particles, it could become free oxygen within those aerosols that eventually fall onto Titan's surface. The process of freeing oxygen within aerosols could be driven by cosmic ray interactions with aerosols at all heights. This process could drive pre-biotic chemistry within the descending aerosols. Cosmic ray interactions with grains at the surface, including water frost depositing on grains from cryovolcanism, would further add to abundance of trapped free oxygen. Pre-biotic chemistry could arise within surface microcosms of the composite organic-ice grains, in part driven by free oxygen in the presence of organics and any heat sources, thereby raising the astrobiological potential for microscopic equivalents of Darwin's “warm ponds” on Titan.  相似文献   

4.
Across the nightside of Venus, daily measurements from the PV Orbiter Ion Mass Spectrometer often indicate an ionosphere of relatively abundant concentration, with a composition characteristic of the dayside ionosphere. Such conditions are interspersed by other days on which the ionosphere appears to largely “disappear” down to about 200 km, with ion concentrations at lower heights also much reduced. These characteristics, coupled with observations of strong day to night flows of O+ in the upper ionosphere, support arguments that ion transport from the dayside is important for the maintenance of the nightside ionosphere. Also, U.S. and Soviet observations of nightside energetic electron fluxes have prompted consideration of impact ionization as an additional nightside ion source. The details of the ion and neutral composition at low altitudes on the nightside provide an important input for further analysis of the maintenance process. In the range 140–160 km, strong concentrations of O2+ and NO+ indicate that the ionization peak is at times composed of at least two prominent ion species. Nightside concentrations of O2+ and NO+ as large as 105 and 104/cm3, respectively, appear to require sources in addition to that provided by transport. The most probable sources are considered briefly, and no satisfactory explanation is yet found for the observed NO+ concentrations. Further analysis beyond the scope of this paper is required to resolve this issue.  相似文献   

5.
We have solved the coupled momentum and continuity equations for NO+, O2+, and O+ions in the E- and F-regions of the ionosphere. This theoretical model has enabled us to examine the relative importance of various processes that affect molecular ion densities. We find that transport processes are not important during the day; the molecular ions are in chemical equilibrium at all altitudes. At night, however, both diffusion and vertical drifts induced by winds or electric fields are important in determining molecular ion densities below about 200 km. Molecular ion densities are insensitive to the O+ density distribution and so are little affected by decay of the nocturnal F-region or by processes, such as a protonospheric flux, that retard this decay. The O+ density profile, on the other hand, is insensitive to molecular ion densities, although the O+ diffusion equation is formally coupled to molecular ion densities by the polarization electrostatic field. Nitric oxide plays an important role in determining the NO+ to O2+ ratio in the E-region, particularly at night. Nocturnal sources of ionization are required to maintain the E-region through the night. Vertical velocities induced by expansion and contraction of the neutral atmosphere are too small to affect ion densities at any altitude.  相似文献   

6.
We quantify the charge states of submicrometer aerosols and aromatic macromolecules in Titan's organic haze. The aerosol charge is balanced between the recombination of positive ions with the aerosol plus the ejection of electrons from the aerosol via the UV-driven photoelectric effect and the recombination of electrons with the aerosol. During the day, the dominant charge state for submicro-meter aerosols is positive. Macromolecules composed of fewer than 32 carbon atoms with low electron affinities (<1.0 eV) are neutral, while the rest are mainly neutral and negatively charged with a small fraction (∼10%) becoming positively charged at higher (≥300 km) altitudes. At night, Titan's aerosol population becomes uniformly neutral and negatively charged. The time taken for a nighttime aerosol to change from being negatively charged to its most probable daytime positive charge is on the order of a few seconds for the largest submicrometer aerosols, while macromolecules tend to persist in an anionic charge state for one to several Earth days. Charging strongly influences aerosol agglomeration via Coulomb attraction and may account for the seasonal variations in the albedo of the Titan haze at midrange (∼200-250 km) altitudes. Enhanced agglomeration may also efficiently produce a source of condensation nuclei for the daily rainout of methane. In addition, the difference in aerosol charge between Titan's day and night (or summer and winter) phases will produce dramatically different chemistries which must be accounted for in future photochemical models. Finally, if there are PAH-like macromolecules in the Titan haze, Cassini Huygens should be able to observe these charge differences, with neutral macromolecules emitting strongly at 3.3 and 11.2 μm, cationic macromolecules emitting between 6.2 and 8.6 μm, and anionic macromolecules emitting in both infrared spectral regions.  相似文献   

7.
The composition, energy and angular characteristics of upward flowing ionospheric ions at altitudes greater than ～ 20,000 km have been studied by means of the PROGNOZ-7 ion composition experiment. Very narrow beams, having widths corresponding to a mirroring altitude of the order a few thousand kilometers or less, may be found up to altitudes exceeding 30,000 km on the nightside. At much higher altitudes and in regions connected to the dayside/flank boundary layer and plasma mantle, the beams are much broader than expected from adiabatic particle motions from an ionospheric source/acceleration region, suggesting that pitch angle scattering or transverse acceleration processes are present there. Considerable mass dispersion effects have also been observed in some upward flowing ionospheric ion beams. The peak energy for the O+ ions may differ by several keV compared to that for the H+ ions in one and the same ion beam at altitudes above ～ 20,000 km. The O+ ions in these beams have gained considerably more energy than H+ in the acceleration process. Many examples with a much higher O+ than H+ content in the beam have been observed. Possible mechanisms giving rise to the observed effects are discussed, one being several kV of potential drop below the neutral H, O-crossover altitude (500–1500 km). At altitudes where the upflowing ionospheric ions are intermixed with magnetosheath ions, mass dispersion effects are also observed. This dispersion often appears to be the result of a velocity filtering effect caused by the dawn-dusk electric field (earthward convection).  相似文献   

8.
Orbiter ion mass spectrometer measurements, as available in the UADS data files are used to study the response of dayside Venus ions at various altitudes to solar wind dynamic pressure, P sw. Ion densities below about 200 km are not affected by changes in P sw. At altitudes above 200 km the ions get abruptly depleted with increase in P sw, and this abrupt depletion occurs at lower altitudes when P sw is high. At lower P sw, the depletion occurs at higher altitudes. The effect is similar for all ions. These results are also compared with the empirical relationship observed by Brace et al. (1980) between the ionopause altitude and P sw from electron density measurements on orbiter electron temperature probe.  相似文献   

9.
The Electron Spectrometer (ELS), one of the sensors making up the Cassini Plasma Spectrometer (CAPS) revealed the existence of numerous negative ions in Titan's upper atmosphere. The observations at closest approach (∼1000 km) show evidence for negatively charged ions up to ∼10,000 amu/q, as well as two distinct peaks at 22±4 and 44±8 amu/q, and maybe a third one at 82±14 amu/q. We present the first ionospheric model of Titan including negative ion chemistry. We find that dissociative electron attachment to neutral molecules (mostly HCN) initiates the formation of negative ions. The negative charge is then transferred to more acidic molecules such as HC3N, HC5N or C4H2. Loss occurs through associative detachment with radicals (H and CH3). We attribute the three low mass peaks observed by ELS to CN−, C3N−/C4H− and C5N−. These species are the first intermediates in the formation of the even larger negative ions observed by ELS, which are most likely the precursors to the aerosols observed at lower altitudes.  相似文献   

10.
Observations by several instruments onboard the Cassini spacecraft revealed the existence of heavy hydrocarbon and nitrile species with masses of several thousand atomic mass units in the ionosphere of Titan. These very large molecules are in fact aerosols. The goal of this paper is to compute the concentrations of the charged aerosols in the upper atmosphere (950-1200 km) of Titan. The charging of these aerosols has been studied using the charge balance equations, where positive ions, negative ions, electrons, neutral and charged aerosols are included. Number concentrations of charged aerosols are compared with those observed by the Cassini instruments. The present work estimates the aerosol mass density as 1-10 kg/m3, which is within the predicted range. The results show that the aerosols must be smaller than 10 nm in order to have reasonable agreement with observations by the Cassini Plasma Spectrometer.  相似文献   

11.
On the basis of observations in the dayside magnetosphere of the O+ and H+ ion densities as function of radial distance under fairly undisturbed and under storm conditions it is argued that acceleration of the hot magnetospheric ions of ionospheric origin cannot be limited to the outer parts of the field tubes. The extraction process seems to work below 1000 km altitude in storm conditions and to have a fairly small extension in altitude. The acceleration mechanism(s) do(es) not affect only one ion species. Variation in the altitude of the extraction of ionospheric ions is the most likely reason for the observed variations in the n(O+)/n(H+) ratio. Extraction of ionospheric ions into the magnetosphere does not seem to be a main cause of the storm time density decrease of the ionosphere.  相似文献   

12.
The descent imager/spectral radiometer (DISR) instrument aboard the Huygens probe into the atmosphere of Titan measured the brightness of sunlight using a complement of spectrometers, photometers, and cameras that covered the spectral range from 350 to 1600 nm, looked both upward and downward, and made measurements at altitudes from 150 km to the surface. Measurements from the upward-looking visible and infrared spectrometers are described in Tomasko et al. [2008a. Measurements of methane absorption by the descent imager/spectral radiometer (DISR) during its descent through Titan's atmosphere. Planet. Space Sci., this volume]. Here, we very briefly review the measurements by the violet photometers, the downward-looking visible and infrared spectrometers, and the upward-looking solar aureole (SA) camera. Taken together, the DISR measurements constrain the vertical distribution and wavelength dependence of opacity, single-scattering albedo, and phase function of the aerosols in Titan's atmosphere.Comparison of the inferred aerosol properties with computations of scattering from fractal aggregate particles indicates the size and shape of the aerosols. We find that the aggregates require monomers of radius 0.05 μm or smaller and that the number of monomers in the loose aggregates is roughly 3000 above 60 km. The single-scattering albedo of the aerosols above 140 km altitude is similar to that predicted for some tholins measured in laboratory experiments, although we find that the single-scattering albedo of the aerosols increases with depth into the atmosphere between 140 and 80 km altitude, possibly due to condensation of other gases on the haze particles. The number density of aerosols is about 5/cm3 at 80 km altitude, and decreases with a scale height of 65 km to higher altitudes. The aerosol opacity above 80 km varies as the wavelength to the −2.34 power between 350 and 1600 nm.Between 80 and 30 km the cumulative aerosol opacity increases linearly with increasing depth in the atmosphere. The total aerosol opacity in this altitude range varies as the wavelength to the −1.41 power. The single-scattering phase function of the aerosols in this region is also consistent with the fractal particles found above 60 km.In the lower 30 km of the atmosphere, the wavelength dependence of the aerosol opacity varies as the wavelength to the −0.97 power, much less than at higher altitudes. This suggests that the aerosols here grow to still larger sizes, possibly by incorporation of methane into the aerosols. Here the cumulative opacity also increases linearly with depth, but at some wavelengths the rate is slightly different than above 30 km altitude.For purely fractal particles in the lowest few km, the intensity looking upward opposite to the azimuth of the sun decreases with increasing zenith angle faster than the observations in red light if the single-scattering albedo is assumed constant with altitude at these low altitudes. This discrepancy can be decreased if the single-scattering albedo decreases with altitude in this region. A possible explanation is that the brightest aerosols near 30 km altitude contain significant amounts of methane, and that the decreasing albedo at lower altitudes may reflect the evaporation of some of the methane as the aerosols fall into dryer layers of the atmosphere. An alternative explanation is that there may be spherical particles in the bottom few kilometers of the atmosphere.  相似文献   

13.
It is argued that ozone measurements made by Weeks et al. (1972) can be interpreted in terms of the enhanced ionization present. The conversion of O2+ ions to oxonium, H3O+ · (H2O)n, ions plus the dissociative recombination of these ions provides for an increased OH and/or H formation rate. The resulting enhanced OH and HO2 concentrations reduce the ambient atomic oxygen and hence ozone populations. The net excess H + OH formation rate is found to lie between one and two times the ionization production rate at altitudes where oxonium ions are the dominant positive ion species.  相似文献   

14.
The total photoelectron and secondary electron fluxes are calculated at different times and altitudes along the trajectory of Mars Global Surveyor passing through the nightside and dayside martian ionosphere. These results are compared with the electron reflectometer experiment on board Mars Global Surveyor. The calculated electron spectra are in good agreement with this measurement. However, the combined fluxes of proton and hydrogen atom as calculated by E. Kallio and P. Janhunen (2001, J. Geophys. Res.106, 5617-5634) were found to be 1-2 orders of magnitude smaller than the measured spectra. We have also calculated ionization rates and ion and electron densities due to solar EUV, X-ray, and electron-proton-hydrogen atom impacting with atmospheric gases of Mars at solar zenith angles of 75°, 105°, and 127°. In the vicinity of the dayside ionization peak, it is found that the ion production rate caused by the precipitation of proton-hydrogen atom is larger than the X-ray impact ionization rate while at all altitudes, the photoionization rate is always greater than either of the two. Moreover, X-rays contribute greatly to the photoelectron impact ionization rate as compared to the photoion production rate. The calculated electron densities are compared with radio occultation measurements made by Mars Global Surveyor, Viking 1, and Mars 5 spacecraft at these solar zenith angles. The dayside ionosphere produced by proton-hydrogen atom is smaller by an order of magnitude than that produced by solar EUV radiation. X-rays play a significant role in the dayside ionosphere of Mars at the altitude range 100-120 km. Solar wind electrons and protons provide a substantial source for the nightside ionosphere. These calculations are carried out for a solar minimum period using solar wind electron flux, photon flux, neutral densities, and temperatures under nearly the same areophysical conditions as the measurements.  相似文献   

15.
S.A. Haider 《Icarus》2005,177(1):196-216
In this paper we have studied the chemistry of C, H, N, O, and S compounds corresponding to ions of masses ?40 amu in the inner coma of the Comet 1P/Halley. The production rates, loss rates, and ion mass densities are calculated using the Analytical Yield Spectrum approach and solving coupled continuity equation controlled by the steady state photochemical equilibrium condition. The primary ionization sources in the model are solar EUV photons, photoelectrons, and auroral electrons of the solar wind origin. The chemical model couples ion-neutral, electron-neutral, photon-neutral and electron-ion reactions among ions, neutrals, electrons, and photons through over 600 chemical reactions. Of the 46 ions considered in the model the chemistry of 24 important ions (viz., CH3OH+2, H3CO+, NH+4, H3S+, H2CN+, H2O+, NH+3, CO+, C3H+3, OH+, H3O+, CH3OH+, C3H+4, C2H+2, C2H+, HCO+, S+, CH+3, H2S+, O+, C+, CH+4, C+2, and O+2) are discussed in this paper. At radial distances <1000 km, the electron density is mainly controlled by 6 ions, viz., NH+4, H3O+, CH3OH+2, H3S+, H2CN+, and H2O+, in the decreasing order of their relative contribution. However, at distances >1000 km, the 6 major ions are H3O+, CH3OH+2, H2O+, H3CO+, C2H+2, and NH+4; along with ions CO+, OH+, and HCO+, whose importance increases with further increase in the radial distance. It is found that at radial distances greater than ∼1000 km (±500 km) the major chemical processes that govern the production and loss of several of the important ions in the inner coma are different from those that dominate at distances below this value. The importance of photoelectron impact ionization, and the relative contributions of solar EUV, and auroral and photoelectron ionization sources in the inner coma are clearly revealed by the present study. The calculated ion mass densities are compared with the Giotto Ion Mass Spectrometer (IMS) and Neutral Mass Spectrometer (NMS) data at radial distances 1500, 3500, and 6000 km. There is a reasonable agreement between the model calculation and the Giotto measurements. The nine major peaks in the IMS spectra between masses 10 and 40 amu are reproduced fairly well by the model within a factor of two inside the ionopause. We have presented simple formulae for calculating densities of the nine major ions, which contribute to the nine major peaks in the IMS spectra, throughout the inner coma that will be useful in estimating their densities without running the complex chemical models.  相似文献   

16.
In order to understand the cometary plasma environment it is important to track the closely linked chemical reactions that dominate ion evolution. We used a coupled MHD ion-chemistry model to analyze previously unpublished Giotto High Intensity Ion Mass Spectrometer (HIS-IMS) data. In this way we study the major species, but we also try to match some minor species like the CHx and the NHx groups. Crucial for this match is the model used for the electrons since they are important for ion-electron recombination. To further improve our results we included an enhanced density of supersonic electrons in the ion pile-up region which increases the local electron impact ionization. In this paper we discuss the results for the following important ions: C+, CH+, CH+2, CH+3, N+, NH+, NH+2, NH+3, NH+4, O+, OH+, H2O+, H3O+, CO+, HCO+, H3CO+, and CH3OH+2. We also address the inner shock which is very distinctive in our MHD model as well as in the IMS data. It is located just inside the contact surface at approximately 4550 km. Comparisons of the ion bulk flow directions and velocities from our MHD model with the data measured by the HIS-IMS give indication for a solar wind magnetic field direction different from the standard Parker angle at Halley's position. Our ion-chemical network model results are in a good agreement with the experimental data. In order to achieve the presented results we included an additional short lived inner source for the C+, CH+, and CH+2 ions. Furthermore we performed our simulations with two different production rates to better match the measurements which is an indication for a change and/or an asymmetric pattern (e.g. jets) in the production rate during Giotto's fly-by at Halley's comet.  相似文献   

17.
Topside ionospheric profiles are used to study the upward field-aligned flow of thermal O+ at high latitudes. On the majority of the field lines outside the plasmasphere, the mean flux is approximately equal to the mean polar wind measured by spacecraft at greater altitudes. This is consistent with the theory of thermal light ion escape supported, via charge exchange, by upward O+ flow at lower heights. Events of larger O+ flow are detected at auroral latitudes and their occurrence is found to agree with that of transversely accelerated ions within the topside ionosphere and the magnetosphere. The effects of low altitude heating of O+ by oxygen cyclotron waves, driven by downward field-aligned currents, are considered as a possible common cause of these two types of event.  相似文献   

18.
The coupled time-dependent O+ and H+ continuity and momentum equations and O+, H+ and electron heat balance equations are solved simultaneously within the L = 1.4 (Arecibo) magnetic flux tube between an altitude of 120 km and the equatorial plane. The results of the calculations are used in a study of the topside ionosphere above Arecibo at equinox during sunspot maximum. Magnetically quiet conditions are assumed.The results of the calculations show that the L = 1.4 magnetic flux tube becomes saturated from an arbitrary state within 2–3 days. During the day the ion content of the magnetic flux tube consists mainly of O+ whereas O+ and H+ are both important during the night. There is an altitude region in the topside ionosphere during the day where ion-counterstreaming occurs with H+ flowing downward and O+ flowing upward. The conditions causing this ion-counterstreaming are discussed. There is a net chemical gain of H+ at the higher altitudes. This H+ diffuses both upwards and downwards whilst O+ diffuses upwards from its solar e.u.v. production source which is most important at the lower altitudes. During the night the calculated O+ and H+ temperatures are very nearly equal whereas during the day there are occasions when the H+ temperature exceeds the O+ temperature by about 300 K.  相似文献   

19.
Photoionization of the upper atmosphere of Titan by sunlight is expected to produce a substantial ionospheric layer. We have solved one-dimensional forms of the mass, momentum, and energy conservation equations for ions and electrons and have obtained electron number densities of about 103 cm?3, using various model atmospheres. The significant ions in a CH4H2 atmosphere are H+, H3+, CH5+, CH5+, CH3+, and C2H5+. Electron temperatures may be as high as 1000°K, depending on the abundance of hydrogen in the high atmosphere. Interaction of the solar wind with the ionosphere is also discussed.  相似文献   

20.
The high electron temperatures existing within SAR-arcs can result in enhanced vibrational excitation of atmospheric N2 molecules and, as a consequence, increase the rate coefficient of the reaction, O+ + N2 → NO+ + N. This results in a change in the relative abundance of O+ and NO++ in the SAR-arc region compared with that in the undisturbed ionosphere. Theoretical ion density profiles were computed by a triple ion analysis solving the mass, momentum and energy equations for O+, NO+ and O+2 ions self-consistently. Although the electron temperature dependence of the recombination rate of NO+ is not well known, the results show that for a range of expected recombination rates NO+ still remains the dominant ion up to ca. 320 km at night within a bright SAR-arc. Studies were also made of the relative importance of a downward O+ flux and an upward ion drift in maintaining the F-region under SAR-arc conditions. It was found that the upward drift caused a marked increase in the NO+/O+ transition altitude as high as 460 km at night. However, for typical drift speeds up to 50 m sec?1 the peak electron density was lower than experimental observations. The effect of a large, short-duration perpendicular electric field on the SAR-arc ion and electron density profiles was found to be small. In all cases considered the magnitude of the enhanced NO+ density as a result of vibrationally excited N2 molecules was sufficient to prevent the electron density within the night-time SAR-arc from becoming vanishingly small.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号