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1.
Isotopic ratios of Nd and Sr have been measured in a suite of samples spanning most of the exposed stratigraphy of the Skaergaard intrusion in order to detect and quantify input (such as assimilated wallrock and fresh magma) into the magma chamber during crystallization. Unlike 18O and D, Nd and Sr isotope ratios do not appear to have been significantly affected by circulation of meteoric waters in the upper part of the intrusion. Variations in initial 87Sr/86Sr and Nd suggest that the Skaergaard magma chamber was affected during its crystallization by a small amount (2%–4%) of assimilation of Precambrian gneiss wallrock (high 87Sr/86Sr, low Nd) and possibly recharge of uncontaminated magma. Decreases in Nd and increases in 87Sr/86Sr during the early stages (0%–30%) of crystallization give way to approximately unchanging isotopic ratios through crystallization of the latest-deposited cumulates. Modelling of assimilation-fractional crystallization-recharge processes using these data as constraints shows that the assimilation rate must have been decreasing throughout crystallization. In addition, the isotope data allow replenishment by an amount of uncontaminated magma equal to 20%–30% of the total intrusion mass, occurring either continuously or in pulses over the first 75% of crystallization. Comparison of the recharge models with published Mg/(Mg+Fe2+) data from Skaergaard cumulates shows that the modelled replenishment rates are not inconsistent with available major element data, although significant recharge during the final 25% of crystallization can be ruled out. The isotope data show that the Skaergaard magma could have incorporated only a small amount of the gneiss that it displaced from the floor of the chamber; assimilation appears to have taken place primarily across a partially molten zone that formed at the roof from the wallrock that was dislodged during emplacement. In the latest stages of crystallization (>75% crystallized), the Skaergaard magma may have become stratified into two separately-convecting layers, effectively insulating Layered Series cumulates from further contamination.  相似文献   

2.
A comprehensive Sr–Nd–Pb–O isotopic study is reported for rhyolites from the Maroa Volcanic Centre in the Taupo Volcanic Zone (TVZ) of New Zealand. The Sr–Nd isotopic compositions of the rhyolites (87Sr/86Sr=0.705236 to 0.705660 and Nd = 2.0 to 0.2) are intermediate between those of primitive basalts (87Sr/86Sr=0.70387 and Nd = 5.3) and the Torlesse basement (87Sr/86Sr=0.709 and Nd = -4.5). The relatively low mantle-like oxygen isotopic compositions of 18 O = 7 ± 0.5 are consistent with the Nd-Sr isotopic constraints in that they can be accounted for by 15% to 25% crustal contamination of a basaltic parent by relatively 18 O-rich Torlesse metasediment. High precision Pb isotopic analyses of plagioclase separates from the Maroa rhyolites show that they have essentially the same compositions as the Torlesse metasedimentary terrane which is itself distinctive from the Western or Waipapa metasediments. Due to the high concentration of Pb in the Torlesse metasediments (>20 ppm) compared to the basalts (<2 ppm), the Pb isotopic composition of the volcanics may be controlled by relatively small amounts (>10%) of crustal contamination. All these results are shown to be consistent with derivation of the rhyolites by 15% to 25% contamination of relatively primitive basaltic magmas with Torlesse metasedimentary crust, followed by extensive, essentially closed system fractionation of the basalt to a magma of rhyolite composition. It is argued that the processes of assimilation and fractionation are separated in both space and time. The voluminous high silica rhyolites, which make up >97% of the exposed volcanism in the continental margin back-are basin environment of the TVZ, therefore appear to be a product of predominantly new additions to the crust with assimilation-recycling of pre-existing crust being of secondary importance.  相似文献   

3.
Nd, Sr and O isotopic data were obtained from silicic ash-flow tuffs and lavas at the Tertiary age (16–9 Ma) Timber (Mountain/Oasis Valley volcanic center (TMOV) in southern Nevada, to assess models for the origin and evolution of the large-volume silicic magma bodies generated in this region. The large-volume (>900 km3), chemically-zoned, Topopah Spring (TS) and Tiva Canyon (TC) members of the Paintbrush Tuff, and the Rainier Mesa (RM) and Ammonia Tanks (AT) members of the younger Timber Mountain Tuff all have internal Nd and Sr isotopic zonations. In each tuff, high-silica rhyolites have lower initial Nd values (1 Nd unit), higher87Sr/86Sr, and lower Nd and Sr contents, than cocrupted trachytes. The TS, TC, and RM members have similar Nd values for high-silica rhyolites (-11.7 to -11.2) and trachytes (-10.5 to -10.7), but the younger AT member has a higher Nd for both compositional types (-10.3 and -9.4). Oxygen isotope data confirm that the TC and AT members were derived from low Nd magmas. The internal Sr and Nd isotopic variations in each tuff are interpreted to be the result of the incorporation of 20–40% (by mass) wall-rock into magmas that were injected into the upper crust. The low Nd magmas most likely formed via the incorporation of low 18O, hydrothermally-altered, wall-rock. Small-volume rhyolite lavas and ash-flow tuffs have similar isotopic characteristics to the large-volume ash-flow tuffs, but lavas erupted from extracaldera vents may have interacted with higher 18O crustal rocks peripheral to the main magma chamber(s). Andesitic lavas from the 13–14 Ma Wahmonie/Salyer volcanic center southeast of the TMOV have low Nd (-13.2 to -13.8) and are considered on the basis of textural evidence to be mixtures of basaltic composition magmas and large proportions (70–80%) of anatectic crustal melts. A similar process may have occurred early in the magmatic history of the TMOV. The large-volume rhyolites may represent a mature stage of magmatism after repeated injection of basaltic magmas, crustal melting, and volcanism cleared sufficient space in the upper crust for large magma bodies to accumulate and differentiate. The TMOV rhyolites and 0–10 Ma old basalts that erupted in southern Nevada all have similar Nd and Sr isotopic compositions, which suggests that silicic and mafic magmatism at the TMOV were genetically related. The distinctive isotopic compositions of the AT member may reflect temporal changes in the isotopic compositions of basaltic magmas entering the upper crust, possibly as a result of increasing basification of a lower crustal magma source by repeated injection of mantle-derived mafic magmas.  相似文献   

4.
Thousands of cubic kilometers of dominantly intermediate composition, metaluminous magma erupted at approximately 35 Ma in eastern Nevada. Two stages of crustal contamination are inferred from detailed study of the earliest vocanic rocks. Fine-grained mafic rocks and rocks with mixed textures, ranging from basalt to rhyolite, were contaminated with a crustal component rich in Nd but poor in Sr. Overlying plagioclaserich andesites and dacites have greater Sr and 87Sr/86Sr, but less Nd and lower Nd and are interpreted to have been contaminated by a crustal component with the opposite elemental signature (i.e., poor in Nd but rich in Sr). The first contaminant represents a partial melt of the crust with plagioclase as a residual phase and the second contaminant is the residue of the partial melting event, or bulk crust. The net effect is bulk crustal assimilation, but in two bites. The separation of the crustal souree into two elementally distinct contaminants causes divergent trends with respect to the variation of 87Sr/ 86Sr versus Nd that could be misinterpreted to indicate the existence of isotopically distinct crustal reservoirs. Comparison of the calculated contaminants to melting relationships in pelites is consistent with the two contammants representing melt and residue at about 30% melting. The model age of the bulk crust is approximately 2.2 Ga, consistent with an early Proterozoic crustal province inferred by other workers.  相似文献   

5.
The Ascutney Mountain complex of eastern Vermont, USA, is a composite epizonal pluton of genetically related gabbro to granite intrusives. Nd isotopic data are reported for mafic rocks, granites, and nearby country rock. The parental mafic magma producing the complex 122 m.y. ago had 87Sr/86Sr=0.7039, 143Nd/144Nd=0.512678 ( Nd=+3.8) and 18O=6.1, indicating a mantle source with time-integrated lithophile element depletion. Uniform initial radiogenic isotope ratios for granites, which are undistinguishable from those for the most primitive gabbro, suggest that the granite magma evolved from the mafic magma without crustal contamination and that the increase in 18O, to about 7.8, is the result of fractional crystallization. Mafic rocks show a large range in initial 143Nd/144Nd ratio, from about 0.51267 to 0.51236 ( Nd= +3.7 to –2.5), which is correlated with elevated 87Sr/86Sr ratios and 18O. These data substantiate the production of mafic lithologies by fractional crystallization of the parental magma accompanied by assimilation of up to about 50% crust. The local country rocks include gneiss and schist and assimilation involved representatives of both rock types. The isotopic and chemical relationships preclude derivation from a single batch of magma undergoing contamination and indicate that a large magma body at depth evolved largely by fractionation with batches of melt issued from this chamber being variably contaminated at higher levels or at the level of emplacement.The Precambrian gneisses of the Chester dome and overlying lower Paleozoic schists have essentially identical Nd isotope systematics which suggest a crustal formation age of about 1.6. b.y. The parental sediments for the schists were apparently derived from a protolith similar to the gneissic basement without appreciable Sm/Nd fractionation.  相似文献   

6.
Two different contamination processes have been identified as having been operative in the genesis of a plutonic suite: initial contamination of a mantle source, and subsequent crustal contamination of uprising partial melts from the mantle. These processes are indicated by a detailed analyses of Nd, Sr, and oxygen isotopes together with major-and trace-elements of the 32–30 Ma calc-alkaline Bergell intrusion. This intrusion is located at the suture of the Alpine continental collision zone and contains rock types capable of discriminating between mantle and intracrustal processes. A range from basaltic-andesitic dykes in the surrounding country rocks, cumulitic hornblendites, gabbros, tonalite, granodiorite and lamprophyres, to pegmatites and aplites, is exposed in this single intrusion. The results of REE modelling and isotopic compositions of the basic members suggest that the cumulates were fractionated from a picrobasaltic liquid originating by partial melting of enriched subcontinental mantle (Nd=+4). Increases in 87Sr/86Sr (0.7055) and 18O(+6.7) in these samples relative to the mantle array and compositions of other Periadriatic intrusions are most likely the result of an initial contamination of the mantle source by dehydration or partial melting of altered subducted oceanic crust. Slight differentiation of such a picrobasaltic liquid produced the basaltic-andesitic dykes. Simultaneous fractional crystallization and contamination of the uprising magma by continental crust produced crustal isotopic signatures which increase with acidity to values of (Nd=-7.6), 87Sr/86Sr=0.716 and 18O=+10. The crustal imprint and LREE enrichment in the dominating tonalite increase with decreasing crystallization depth which indicates that the tonalites were emplaced in several distinct batches with different degrees of contamination. Shoshonitic lamprophyres, which intruded into the partly solidified granodiorite, were generated in a deep, strongly contaminated mantle source. The posttectonic 26 Ma Novate leucogranite is not cogenetic with the main Bergell body, but rather formed from a predominantly crustal source. If the described features are indeed due to mantle source contamination processes, which are well known for volcanic arcs, it must be concluded that these may also play a significant role in the genesis of calcalkaline plutonic suites.  相似文献   

7.
Strong compositional zonation of the 34 Ma Grizzly Peak Tuff in west-central Colorado is attended by non-monotonic trends in O, Sr, Nd, and Pb isotope ratios. Fiamme from the tuff cluster in chemical compositions and petrographic characteristics, indicating the magma chamber was not continuously zoned but consisted of at least seven compositional layers. The most mafic magma erupted (57 wt% SiO2, fiamme group 7) had 18O= +8.5, initial 87Sr/86Sr=0.7099, Nd, and 206Pb/204Pb=17.80, suggesting that the magma was produced by 50% fractional crystallization of basaltic magma that assimilated 20 to 40 wt% Proterozoic crust. Isotopic compositions of more evolved parts of the chamber (up to 77 wt% SiO2, fiamme group 1) depart from the mafic base-level composition of fiamme group 7, and reflect late-stage assimilation that occurred largely after compositional layering was established. 18O values decrease by as much as 1.5 from fiamme groups 7 through 4, indicating assimilation of hydrothermally altered roof rocks. 18O values abruptly inerease by up to 1.5 between fiamme groups 4 and 3. This discontinuity is interpreted to reflect evolution in an asymmetric chamber that had a split-level roof, allowing assimilation of wall rocks that varied vertically in degree of hydrothermal alteration. This chamber geometry is also supported by collapse structures in the caldera. Late-stage assimilation of heterogeneous wall rocks is also indicated by variations in Sr, Nd, and Pb isotope ratios. Large Sr isotope disequilibrium exists between some phenocrysts and whole-rock fiamme, and initial 87Sr/86Sr ratios in phenocrysts are as high as 0.7170. values regularly increase from-13.0 in fiamme group 7 to-11.3 in fiamme group 3, and then decrease to-12.2 in fiamme group 1. 206Pb/204Pb ratios generally increase from 17.80 to 17.94 for fiamme groups 7 through 1. The rhyolitic parts of the Grizzly Peak Tuff have isotopic compositions that could be attributed to a purely crustal melt. It is unlikely, however, that the mafic parts of the tuff were generated by crustal melting, and the compositional and isotopic variations across the entire zonation of the tuff are best explained by fractional crystallization of mantle-derived magmas, accompanied by extensive assimilation of Proterozoic crust.  相似文献   

8.
138Ce/142Ce isotope ratios in Cenozoic island arc volcanic rocks are reported for the first time, together with isotope ratios of Nd and Sr and abundances of REE, Ba and Sr. The island arc volcanics studies here are boninites from Chichijima, the Bonin Islands, and basalts and andesites from the Solomon Islands. REE patterns of the island arc volcanic rocks from the Solmon Islands and the Bonin Islands are confirmed to have negative Ce anomalies. It is also disclosed that the majority of these island arc volcanic rocks show mainly positive values for both Ce and Nd. It is shown that these Ce and Ce values can hardly be interpreted by simple mixing between MORB and oceanic or continental crustal rocks; the former have positive Nd and negative Ce and the latter have negative Ce and positive or negative Nd. Existence of sources having positive Ce and Nd values is strongly suggested. If the sources are assumed to have been fractionated from CHUR (chondritic uniform reservoir) at the early or middle Precambrian era, the sources from which the volcanics were derived are concluded to have kept concave REE patterns with larger (La/Ce)N and smaller (Nd/Sm)N ratios than chondritic values over a substantial period of time, until the time of Cenozoic magmatism forming island arc volcanic rocks in question. During the periods of the Cenozoic magmatic activities and their related events, Ce anomalies are considered to have been created. From Ce and Nd isotope ratios, however, it is difficult to determine which of the following processes was responsible for the Ce anomaly; the incorporation process of subducted oceanic crust into magma at the mantle or the slab dehydration and metasomatism process. Nevertheless, so far as Ce and Nd isotopic ratios are concerned, incorporation of oceanic sediments did not take place to any clearly detectable degree.  相似文献   

9.
Initial Nd isotope ratios are determined for components of 1.9-1.7 Ga age continental crust in the Ketilidian terrain of South Greenland. The Ketilidian has well-documented ages of migmatization/metamorphism (1.80 Ga) and post-tectonic granitoid intrusion (1.76-1.74 Ga) from U-Pb zircon studies. The Nd results show that: (1) metatholeiites with chondritic 147Sm/144Nd have Nd=+4 to +5 at 1.8 Ga; (2) migmatites, paragneisses and an early granitoid have Nd close to zero; (3) post-tectonic norites have Nd +1.5, while spatially associated more-abundant granitoids have Nd=0 to +1. The metatholeiites show that a normal depleted mantle (Nd=+4 to +5) was present beneath this 1.9-1.7 Ga orogenic zone, as is the case in such environments today. However, metatholeiites are an insignificant part of the Ketilidian crust, and the bulk initial ratio of the whole terrain lies close to Nd=0. Rather than invoking depleted and undepleted mantle sources whose products did not mix, we infer the Nd=0 value to be caused by mixing of a component derived from depleted mantle (Nd=+ 4 to +5) with Archean crustal material (Nd=-9 to -13). As there are no proven relics of Archean crust beyond the border zone of the Ketilidian, and the Nd= 0 value appears to be a wellhomogenized feature, we propose that the Archean material was added in the form of sediments transported to the orogenic zone on oceanic crust. The Archean component comprised between 5 and 17% of the Ketilidian, and the most reasonable estimate is 10%. Thus this 1.9-1.7 Ga terrain consisted of 90% new mantle-derived crust.  相似文献   

10.
Cretaceous-Paleogene granitoid rocks and contemporaneous volcanic rocks are widely distributed in the Inner Zone of Southwest Japan. This intense intermediate to felsic magmatism is considered to have taken place on the eastern margin of the Eurasian Continent, before the Southwest Japan Arc drifted away from the continent in the middle Miocene, resulting in the opening of the Japan Sea. The granitoid rocks show regional variations in terms of their radiometric age, petrography, Sr, Nd and O isotope ratios. Based on Sr and Nd isotope ratios, granitoid rocks can be divided into three zones (South, Transitional and North) between the Median Tectonic Line and the Japan Sea. Granitoid rocks and associated gabbros of the North Zone have low initial Sr isotope ratios (0.7048 to 0.7068) and high initial Nd values (+3 to-2.2), whereas granitoid rocks and gabbros from the South Zone have high initial Sr isotope ratios (0.7070 to 0.7088) and low initial Nd values (-3.0to-8.0). Most granitoid rocks from the Transitional Zone have Sr and Nd isotope ratios that lie between those of the North and South Zones, although there is some overlap. Contamination of magmas by upper crust cannot explain this geographical variation in Sr and Nd isotopes. Instead, the regional variation is attributed to compositionally different, magma sources (probably upper mantle and lower crust), beneath the North and South Zones. This is supported by the Sr and Nd isotopic ratios of upper mantle and lower crustal xenoliths included in Cenozoic volcanic rocks in the North and South Zones. These ratios are similar to those of the granitoid rocks in the respective zones. It is suggested that a micro-continent or island arc consisting of continental crust was underthrust beneath the South Zone before or during the Cretaceous, resulting in compositionally distinct sources for granitoid rocks of the North and South Zones. The large variation observed in Sr and Nd isotope ratios for Transitional Zone granitoid rocks is explained by variable proportions of the two different crustal and upper mantle components.  相似文献   

11.
A detailed isotopic study of minerals and whole rocks from the Cretaceous Oka complex, Quebec, Canada, shows a very small variation in initial Nd and Sr isotopic compositions. Assuming an age of 109 Ma for the complex, apatite, calcite, garnet, melilite, monticellite, olivine and pyroxene and whole rocks yield a range for initial 87Sr/86Sr of 0.70323–0.70333; and for initial 143Nd/144Nd of 0.51271–0.51284 ( SR(T)= –14.8 to –16.2; Nd(T)=+4.1 to +6.6). The negative SR and positive Nd indicate derivation of the Nd and Sr from a source with a time-integrated depletion in the large-ion lithophile (LIL) elements. This agrees with data from other Canadian carbonatites and confirms that a large part of the Canadian Shield is underlain by a source region depleted in the LIL elements. The new data from Oka suggest that the depleted source may have remained coupled to the continental crust until recent time.  相似文献   

12.
Initial Nd and Sr isotopic ratios have been measured for Cretaceous acidic and related intermediate rocks (24 volcanic and two plutonic rocks) from the Inner Zone of Southwest Japan (IZSWJ) to investigate the genesis of acidic magmas. The initial Nd and Sr isotopic ratios for these rocks show three interesting features: (1) Nd values for acidic rocks (+2 to –9) are negatively correlated with Sr values (+10 to +90) together with those for intermediate rocks ( Nd=+3 to -8; Sr=0 to +65). (2) The Nd values for silica rich rocks (>60% SiO2) correlate with the longitude of the sample locality, decreasing from west to east in a stepwise fashion: Four areas characterized by uniform Nd values are discriminated. (3) Low silica rocks (<60% SiO2) in a certain area have distinctly different Nd values from those of the high silica rocks in the same area.These results as well as those deduced from the additional samples collected, for comparison, from other provinces in Japan suggest that the acidic rocks can be formed neither by fractional crystallization processes from more basic magmas nor by crustal assimilation processes. The isotopic variations of the acidic rocks may reflect regional isotopic heterogeneity in the lower crust, and this heterogeneity may ultimately be attributed to the regional heterogeneity of the uppermost-mantle beneath the Japanese Islands.  相似文献   

13.
Meta-igneous granulite (MIG) xenoliths in lavas from Mount Ruapehu, Taupo Volcanic Zone, New Zealand, have variable but relatively high 18O (+8.2 to +11.7) and 87Sr/86Sr (0.70506 to 0.70872), and Nd ranging from +1.5 to +6.2. They show a strong positive correlation between 87Sr/86Sr and 18O, both of which are also broadly correlated with Mg number, but lack any correlation between 87Sr/86Sr and Nd. The xenoliths have been mineralogically re-equilibrated at lower-crustal temperatures (800–930°C) and pressures (7–10 kbar). Geochemical and isotopic evidence suggests they are fragments of oceanic crust that have been altered previously in an ocean floor hydrothermal system. Alternatively, they may be igneous rocks of unknown origin hydrothermally altered in the lower crust. Irrespective of this uncertainty, the xenoliths provide rare samples of the lower crustal basement beneath Taupo Volcanic Zone and represent a potential source rock for the voluminous rhyolites and ignimbrites that dominate the zone.  相似文献   

14.
Zusammenfassung Es wird ein kurzer Überblick über den komplexen Gesteinsbestand eines Gebietes im arabischen Grundgebirge des südlichen Hedjaz gegeben. Es zeigte sich, daß die tektonischen, stark überprägten und metamorphen Serien heute noch nicht in das Schema der in der Literatur genannten Serien eingebaut werden können. Diese scheinen sowohl hinsichtlich ihres stofflichen Bestandes wie auch des Zusammenhanges ihrer strukturellen und metamorphen Prägung noch zu wenig gekennzeichnet zu sein.Die im Grundgebirge weit verbreiteten Seitenverschiebungen werden kurz beschrieben und ihr Alter als wahrscheinlich spät-präkambrisch aufgefaßt.
The paper gives a general view of the different rock series occurring in a mapped area of the basement complex in the southern Hedjaz. The predominant masses of strongly tectonized and epimetamorphic series cannot be correlated with some series, which are named already in the literature of Arabia. These latter series seem defined not sufficiently in their composition and in the relation to their structural and metamorphic development.The wrench movements, wide spread in the Arabian basement, are briefly described and defined as being probably late-precambrian.
Résumé L'auteur donne un bref aperçu de la composition géologique complexe d'une région du soubassement arabe de l'Hedjaz du Sud. Il s'est avéré qu'à l'heure actuelle les séries fortement tectonisées et métamorphiques ne peuvent encore être intégrées au schéma des séries mentionnées par la littérature. Ces séries semblent être encore trop peu caractérisées en ce qui concerne leur composition ainsi que le rapport entre leurs caractéristiques structurelles et métamorphiques.Les failles horizontales de décrochement, qui sont très répandues dans le soubassement, sont décrites brièvement et définies comme datant probablement de la fin de l'antécambrien.
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15.
Quartz phenocrysts from 31 granitoid stocks in the Colorado Mineral Belt yield 18O values less than 10.4, with most values between 9.3 and 10.4. An average magmatic value of about 8.5 is suggested. The stocks resemble A-type granites; these data support magma genesis by partial melting of previously depleted, fluorine-enriched, lower crustal granulites, followed by extreme differentiation and volatile evolution in the upper crust.Subsolidus interaction of isotopically light water with stocks has reduced most feldspar and whole rock 18O values. Unaltered samples from Climax-type molybdenumbearing granites, however, show no greater isotopic disturbance than samples from unmineralized stocks. Although meteoric water certainly played a role in post-mineralization alteration, particularly in feldspars, it is not required during high-temperature mineralization processes. We suggest that slightly low 18O values in some vein and replacement minerals associated with molybdenum mineralization may have resulted from equilibration with isotopically light magmatic water and/or heavy isotope depletion of the ore fluid by precipitation of earlier phases.Accumulation of sufficient quantities of isotopically light magmatic water to produce measured depletions of 18O requires extreme chemical stratification in a large magma reservoir. Upward migration of a highly fractionated, volatile-rich magma into a small apical Climax-type diapir, including large scale transport of silica, alkalis, molybdenum, and other vapor soluble elements, may occur with depression of the solidus temperature and reduction of magma viscosity by fluorine. Climax-type granites may provide examples of 18O depletion in magmatic systems without meteoric water influx.  相似文献   

16.
The Dalma volcanic belt of the Singhbhum Precambrian terrain in eastern India is developed along the median zone of a linear basin flanked by Archaean cratonic basement to the south. The lavas, in a low grade metamorphic environment, preserve a strong compositional bimodality, with highly magnesian picritic volcanics developed at the base and low-K basalt flows above, constituting the bulk of the lava pile. The ultrabasic lavas have low concentrations of immobile incompatible elements, ratios of which are probably controlled by the source character. Dalma mafic flows are closely comparable in geochemical character to modern day mid-oceanic ridge basalts (MORB) with a dominance of light-REE-depleted basalts and ferrobasalts. However, in terms of certain element ratios (Th/Ta), deviation from MORB characteristics toward island arc tholeiites is apparent. In this respect the Dalma basalts appear to have a modified MORB composition and the closest chemical analogy may be basalts from back-arc basins, i. e. a supra-subduction zone environment. The bimodality of ultrabasic and mafic lavas is reminiscent of Archaean komatiitic provinces. The geochemical signature of the Dalma lavas, and the geological framework of the terrain, strongly point to a marginal basin domain developed in this crustal segment during the Proterozoic.
Zusammenfassung Der Vulkangürtel von Dalma liegt in der präkambrischen Region Singhbhum in Ostindien. Aufgeschlossen ist der Dalma-Gürtel im mittleren Bereich eines geradlinigen Bekkens, das im Süden durch Basement des Archaikums begrenzt wird. Die Laven befinden sich in einer geringmetamorphen Umgebung und weisen eine bimodale Zusammensetzung auf. An der Basis sind Magnesium-reiche und darüber Kalium-arme Basalte entwickelt, die repräsentativ für den Durchschnitt der Laven sind. Die ultrabasischen Laven enthalten niedrige Konzentrationen an immobilen nicht kompatiblen Elementen, deren Verhältnis wahrscheinlich von den Eigenschaften der Lavaquelle gesteuert wird. Der geochemische Charakter der mafischen Dalma-Vulkanite entspricht weitgehend den heutigen Basalten der ozeanischen Rücken (MORB). Dabei dominieren leicht abgereicherte REE-Basalte sowie eisenreiche Basalte. Vergleicht man allerdings Elementverhältnisse wie das von Th/Ta, wird eine Abweichung von dem typischen MORB-Charakter hin zu Inselbögen-Tholeiten deutlich. Berücksichtigt man diese Beobachtungen, scheinen die Dalma-Basalte eine modifizierte MORB-Zusammensetzung zu haben, die in ihrem Chemismus am ehesten den Basalten von Back-Arc-Becken, z. B. in einem Gebiet einer Supra-Subduktionszone, zu entsprechen. Die Bimodalität der ultrabasischen und mafischen Laven erinnert an archaische komatiitische Regionen. Die geochemische Zusammensetzung der Dalma-Laven sowie der geologische Rahmen des Gebietes deuten auf ein randliches Becken hin, das sich während des Proterozoikums entwickelt haben könnte.
Résumé La ceinture volcanique de Dalma, dans le Précambrien de Singhbhum (Inde Orientale) est située dans la partie médiane d'un bassin linéaire bordé au Sud par un socle cratonique archéen. Les laves se trouvent dans un environnement de faible degré de métamorphisme et présentent une composition nettement bimodale: volcanites picritiques très magnésiennes à la base, surmontées de coulées basaltiques pauvres en K, qui constituent l'essentiel de l'ensemble. Les laves ultrabasiques montrent de faibles concentrations en éléments immobiles incompatibles dont les rapports sont probablement déterminés par le caractère de la source. Les coulées basiques de Dalma sont très comparables, dans leurs propriétés géochimiques, aux basaltes récents des rides océaniques (MORB), avec une dominante de basaltes pauvres en terres rares légères et de ferro-basaltes. Toutefois, les rapport de certains éléments (Th/Ta) font apparaître, par rapport au MORB, une déviation vers les tholéiites d'arcs insulaires. A ce point de vue, les basaltes de Dalma montrent une composition de MORB modifée et une analogie avec les basaltes de bassins d'arrière-arc, c'est-à-dire en situation de supra-subduction. La bimodalité laves ultrabasiques/laves basiques est une réminiscence des provinces komatiitiques archéennes. Le signalement géochimiques des laves de Dalma et leur situation géologique plaident en faveur d'un domaine de bassin marginal développé dans ce segment central au cours du Protérozoïque.
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17.
The main result of a field survey is the presentation of a petrographical map, which for the first time gives details of the main structures of the Jebel Nefusa volcano. A second result of the mapping is that obviously the age relationship between two of the major rock types — phonolites and flood basalts — needs revision: the phonolites are the oldest ones. - Also are given some preliminary remarks regarding mineralogical composition: flood basalts are characterized by olivines corroded and partly oxidized before final crystallization, and all phonolites contain appreciable amounts of analcite.
Zusammenfassung Es wird eine petrographische Übersichtskarte vorgelegt, welche erstmals die beherrschenden Strukturen im Aufbau des Jebel-Nefusa-Vulkans (nördl. Tripolitanien, Libyen) erkennen läßt. Ein Ergebnis der Kartierung ist eine Neugliederung der Altersabfolge der drei Haupt-Gesteinsgruppen Phonolithe — Flutbasalte — Melabasalte. Die Phonolithe müssen offensichtlich älter als die Flutbasalte sein, und sind wahrscheinlich die ältesten Glieder der Abfolge. — Vorab mitgeteilte petrographische Details: die Flutbasalte werden durch Olivine charakterisiert, welche schon vor der Erstarrung der Schmelze korrodiert und teiloxidiert worden waren, und die Phonolithe führen sämtlich erhebliche Anteile an Analcim.
Résumé Le résultat principal de cette recherche sur le terrain est présentation d'une carte pétrographique qui, pour la première fois, montre les détails de la structure principale du volcan Jebel Nefusa. Ce travail montre avec évidence que les relations d'âge entre deux des principaux types de roches, les phonolites et les épanchements basaltiques, appellent une révision, car les phonolites sont les plus anciennes. Quelques remarques sont faites sur la composition minéralogique: les épanchements de basaltes sont caracterisés par des olivines corrodées et en partie oxydées avant la cristallisation finale; toutes les phonolites contiennent de l'analcime en proportions appréciables.
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18.
Résumé Les faunes de Mollusques découvertes pendant les dix dernières années, auxquelles s'ajoutent des arguments d'ordre paléoclimatique, tectonique et paléogéographique, prouvent que les dépÔts de ce bassin, que l'on attribuait à l'Oligocène et à tout le Miocène presque, appartiennent en réalité au Tortonien supérieur. La sédimentation a commencé pendant les derniers mouvements de la phase styrienne pour s'achever au début des mouvements de la phase moldave. à l'époque relativement calme qui sépare ces deux phases se sont formées les quelques 27 couches de charbon à épaisseurs, par endroit, remarquables.
So far the Petroeni Basin has been investigated only on a local scale without taking into account either the numerous and important advances related to the knowledge of some large areas belonging to Carpathian regions, or the evolution of the adjacent Neogene basins. The Oligocene and Aquitanian ages were assigned to these deposits by the first geologists without sufficient consideration of the palaeontological basis. These ages have been accepted for many years. The field work of the last years yielded the discovery of a rich Tortonian fauna. Palaeontological, palaeoclimatic and tectonical data suggest, for the time being, that the entire series of sediments in the basin represents a sole stage — the Tortonian. This stage cannot be considered complete but is represented only by its upper part. The assumption that all the deposits of the basin are Tortonian in age can be supported only with difficulty, but it is the only age which accounts for all geological observations. The large thickness of the deposits is considered the result of intense subsidence, during the Upper Styrian movements of ruptural character, which led to formation of a relatively small-sized graben. The exclusive presence of the Upper Tortonian tallies with the importance of the transgression which took place at the end of the Middle Miocene over large areas of the Carpathian regions.
Zusammenfassung Das Petroenier-Becken wurde bis heute nur in einem ganz engen Rahmen untersucht, ohne die zahlreichen und wichtigen Fortschritte über den Weidegang der Karpaten und der benachbarten neogenen Becken zu berücksichtigen. Das oligozäne und aquitanische Alter der Ablagerungen, das von den ersten Forschern postuliert wurde, ist von den meisten Geologen bis ins letzte Jahrzehnt angenommen worden. Es mangelte jedoch an einer vertieften paläontologischen Grundlage. Die reichhaltige Flora hat sich für die eindeutige Bestimmung des Alters als unzureichend erwiesen. Die fünf festgestellten lithologischen und biologischen Fazies wurden irrtümlicherweise als verschiedene Altersstufen des Oligozäns und des Miozäns betrachtet. Die Feldarbeiten im letzten Jahrzehnt haben jedoch eine reiche Molluskenfauna tortonischen Alters erbracht. Paläontologische, paläoklimatische und tektonische Ergebnisse bezeugen heute, daß die meisten Ablagerungen nur einer einzigen Stufe, nämlich dem Torton, angehören. Eine nähere Untersuchung lehrt weiter, daß auch das Torton unvollständig abgelagert wurde, da es nur durch sein letztes Drittel vertreten ist. Die letzten Ablagerungen gehören möglicherweise dem ältesten Sarmatikum an. Der Schluß über das spätmittelmiozäne Alter des ganzen Schichtkomplexes ist der einzige, welcher uns heute erlaubt, sämtliche geologischen Tatsachen zu verstehen. Die etwa 2000 m Mächtigkeit der Schichten ist die Folge einer intensiven Ablagerung in einem tiefen Einbruchsbecken während der mittelmiozänen Bewegungsphasen. Die Ablagerung der Kohlenflöze entspricht der Ruhezeit zwischen den steyerischen und den moldavischen Krustenbewegungen. Das mittelmiozäne Alter der Schichten des Beckens von Petroeni steht mit der weiten mittelmiozänen Meerestransgression in Mittelund Südosteuropa im Einklang.
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19.
The orthogneisses of the Spessart crystalline complex are derived from a granitic to granodioritic magma of S-type character which must have formed by anatexis of continental crust. It intruded into a relatively shallow crustal level, 410–420 Ma ago, at the Silurian. Trace element characteristics are consistent with a post-collision geotectonic environment testifying to extensional tectonics at the end of the Caledonian era.
Zusammenfassung Die Orthogneise des Spessartkristallins lassen sich von einem granitischen bis granodioritischen Magma von S-Typ-Charakter ableiten, das durch Anatexis kontinentaler Kruste entstanden sein mu\ und in ein relativ oberflächennahes Krustenniveau intrudierte. Die Platznahme erfolgte vor 410–420 Ma, d. h. im Silur. Die Spurenelement-Muster der Orthogneise entsprechen denen von Post-Kollisions-Granitoiden, was als Hinweis auf eine Phase der Dehnungstektonik am Ende der kaledonischen ära bewertet werden kann.
Résumé Les orthogneiss du Spessart sont dérivés d'un magma granitique à granodioritique de type S qui doit s'Être formé par anatexie de la croûte continentale. Ce magma a été intrudé dans un niveau peu profond de la croûte il y a 410–420 Ma c'est-à-dire au Silurien. La distribution des éléments en traces est en accord avec celle des granitoÏdes formés dans un contexte géodynamique de post-collision. Cette observation est en faveur d'une phase d'extension tectonique à la fin du cycle calédonien.
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20.
The volcano Savalan, located in Eastern Azerbaijan, is a big structure with andesitic to rhyodacitic products long considered to be Quaternary. Four K/Ar whole-rock age determinations on vulcanites point, however, to a long volcanic history, starting at least in the Upper Miocene. Three K/Ar absolute ages of volcanites erupted from other centers in the same province also provide evidence of calc-alkaline activity since Middle Miocene.Calc-alkaline activity of Miocene and later periods is well known in other parts of central-western Iran. It can be chronologically correlated with the rifting and oceanfloor spreading in the Red Sea, which began in the Miocene, and with attendant oceanic-crust subduction of the Arabian plate underneath the Iranian plate. The present-day halt in calc-alkaline magmatism may be explained by collision of the Arabian and Iranian continental masses, with limited underthrusting of Arabian continental crust. It is also suggested that the recent onset of alkali basalt volcanism in several districts of central and western Iran is related to the relaxation of compressional stresses following migration of deformation to the south-western part of the continental-crust prism below the Zagros belt facing the Persian Gulf and Mesopotamian trough edge.
Zusammenfassung Vier K/Ar Altersbestimmungen von Vulkaniten verschiedener Bildungen des Savalan Vulkans (Ost-Azerbaijan, Iran), der eine große Struktur mit andesitischen bis riodazitischen Produkten ist, und der für lange Zeit als Quaternär betrachtet worden ist, lassen auf eine lange vulkanische Geschichte schließen, die mindestens im oberen Miozän begann. K/Ar Altersbestimmungen von drei Vulkanit-Proben aus anderen Orten derselben Provinz weisen auch kalk-alkaline Aktivität ab Mittel-Miozän auf. Die Aktivität von diesem und späteren Alter, die in anderen Teilen Zentral- und WestIrans bekannt ist, kann kronologisch mit dem Rifting und Ocean-floor spreading im Roten Meer, die im Miozän begannen, und mit der zusammenhängenden ozeanischen Krust-Subduktion der Arabischen Platte unter die Iranische Platte, verbunden werden. Die Kollision der Arabischen und Iranischen Kontinentalmassen mit beschränkter Unterschiebung der Arabischen Kontinentalkruste kann die gegenwärtige Unterbrechung im kalk-alkalinen Magmatismus erklären. Es wird auch vorgeschlagen, daß der jüngste Ansatz vom alkali-basaltischen Vulkanismus in vielen Gebieten Zentral- und WestIrans auf die Entspannung von Stressen zurückzuführen ist, nach Verschiebung der Deformationen zum südwestlichen Teil des kontinentalen Krust-blocks unter die ZagrosKette gegenüber des Persischen Golfs und der Mesopotamischen Tiefebene.
Résumé Quatre échatillons de coulées laviques appartenant à différentes unités du cortège magmatique du volcan Savalan (Azerbaijan oriental, Iran) ont été daté par la méthode K/Ar sur roche totale. Ces nouvelles données radiochronologiques permettent de définir pour le Savalan (depuis longtemps estimé Quaternaire) une activité volcanique calealcaline qui a commencé au moins pendant le Miocène supérieur. Les âges (K/Ar) de trois échatillons de volcanites d'autres zones dans le même district montrent aussi la présence d'une activité cale-alcaline à partir du Miocène moyen. Ce volcanism, comme le suivant, remarqué dans les autres régions de l'Iran central et occidental, permet d'établir des relations chronologiques avec l'ouverture du rift de la Mer Rouge (qui l'on fait remonter au Miocène) et avec la subduction concomittante du fond océanique de la plaque arabique sous la plaque iranienne. La collision du bloc arabique avec le bloc iranien, suivie du sous-charriage, à un degré limité, de la croûte continentale arabique, pourrait expliquer l'actual arrêt du magmatisme cale-alcalin.De plus, le récent début du volcanisme basique alcalin dans beaucoup de zones centrales et occidentales de l'Iran, permettrait des corrélations avec le relâchement des forces de compression à la suite du déplacement de la déformation vers la partie sud-occidentale du prisme de croûte continentale sous la chaîne du Zagros qui donne sur les Golfe Persique et la dépression mésopotamienne.
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