首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 263 毫秒
1.
n-Alkane biomarker distributions in sediments from Swamp Lake (SL), in the central Sierra Nevada of California (USA), provide evidence for an increase in mean lake level ~ 3000 yr ago, in conjunction with widespread climatic change inferred from marine and continental records in the eastern North Pacific region. Length distributions of n-alkane chains in modern plants growing at SL were determined and compared to sedimentary distributions in a core spanning the last 13 ka. As a group, submerged and floating aquatic plants contained high proportions of short chain lengths (< nC25) compared to emergent, riparian and upland terrestrial species, for which chain lengths > nC27 were dominant. Changes in the sedimentary n-alkane distribution over time were driven by variable inputs from plant sources in response to changing lake level, sedimentation and plant community composition. A shift toward shorter chain lengths (nC21, nC23) occurred between 3.1 and 2.9 ka and is best explained by an increase in the abundance of aquatic plants and the availability of shallow-water habitat in response to rising lake level. The late Holocene expansion of SL following a dry mid-Holocene is consistent with previous evidence for increased effective moisture and the onset of wetter conditions in the Sierra Nevada between 4.0 and 3.0 ka.  相似文献   

2.
We investigated the molecular inventory of River Danube sediments and identified wax esters with 28–36 carbons, with C30, C31 and C32 homologs the most abundant. They consist of various combinations of n-, iso- and anteiso-aliphatic acid and alcohol moieties, with different isomer distributions for the esters with odd and even carbon numbers. The short chain length (C28–C36), high proportion of methyl moieties and presence of monounsaturated esters together suggest a bacterial origin for the wax esters. The concentration in surface sediments varied from 0 to 741 μg/kg, being significantly enriched at locations with high nutrient concentration and high primary productivity. Cluster analysis of denaturing gradient gel electrophoresis (DGGE) band patterns revealed different bacterial communities in surface sediments from the stream and surface sediments from the reservoir. The concentration in a 70 cm core of rapidly deposited sediments decreased significantly with depth, following first order kinetics, suggesting a loss of the esters within ca. 3 years following burial and hence a low probability for preservation in the geological record. Wax esters in rivers have rarely been investigated; our results suggest that they represent a bacterial response to enhanced primary production, triggered by higher nutrient supply.  相似文献   

3.
Oxygen and carbon isotope ratios of soil carbonate and carbon isotope ratios of soil organic matter (SOM) separated from three cores, Kalpi, IITK and Firozpur, of the Ganga Plain, India are used to reconstruct past rainfall variations and their effect on ambient vegetation. The δ18O values of soil carbonate (δ18OSC) analyzed from the cores range from ? 8.2 to ? 4.1‰. Using these variations in δ18OSC values we are able, for the first time, to show periodic change in rainfall amount between 100 and 18 ka with three peaks of higher monsoon at about 100, 40 and 25 ka. The estimation of rainfall variations using δ18O value of rainwater-amount effect suggests maximum decrease in rainfall intensity (~ 20%) during the last glacial maximum. The δ13C values of soil carbonate (δ13CSC) and SOM (δ13CSOM) range from ? 6.3 to + 1.6‰ and ? 28.9 to ? 19.4‰, respectively, implying varying proportions of C3 and C4 vegetations over the Ganga Plain during the last 100 ka. The comparison between monsoonal rainfall and atmospheric CO2 with vegetation for the time period 84 to 18 ka indicate that relative abundances of C3 and C4 vegetations were mainly driven by variations in monsoonal rainfall.  相似文献   

4.
The sedimentary record of the volcanic lake known as the Fuentillejo maar (central Spain) offers the opportunity to determine the palaeoenvironmental evolution of the central-southern part of the Iberian Peninsula during the Middle and Upper Pleistocene. A total of 439 samples from the upper 88 m of a ca. 142 m long core (spanning the last ca. 355 ka) were examined. The interval corresponds to the last 220 ka of the record. High n-alkane CPI values and the presence of sulfur revealed that little diagenetic signal attenuation or modification had occurred. A number of n-alkane-based indices (e.g. predominant n-alkane, ACL, Paq and TARHC ratios, and the proportion of C27, C29 and C31 n-alkanes with respect to the summed C27 + C29 + C31) alkanes, showed changing conditions in the organic matter input to the maar lake over time, with episodes involving a major input of terrestrial vegetation, alternating with others in which algae or a mixed input of terrestrial plants, aquatic macrophytes and algae occurred. The proportions of C27, C29 and C31 were useful for reconstructing the palaeoenvironmental evolution of the basin as they allowed assignment of several dry intervals during which grasses developed, while during humid phases trees expanded at the expense of grasses.In general, we found good correspondence between these episodes and the climatic cycles observed in δ18O records from ices cores in Greenland and Antarctica, as well as from marine cores. Thus, we conclude that global palaeoclimatological changes were recorded in the maar record. Likewise, Heinrich Events appeared to be reflected in the n-alkane indices. This was confirmed by single spectral analysis and cross spectral analysis with the insolation curve on 21 July at a latitude of 65°N. The approach revealed that the cycles interpreted in the Fuentillejo record (103, 41, 23 and 19 ka) showed evidence of orbital influence related to the astronomical cycles of the eccentricity variation in the Earth’s orbit, the Earth’s obliquity oscillation, and the precession variation (Milankovitch theory).  相似文献   

5.
Two deep cores (SSDP 102 and SSDP 105) from the southeastern inner shelves of Korea were examined in order to reconstruct the paleoenvironmental history of the Korea Strait during postglacial sea-level fluctuations. The results of the lithofaces, organic geochemical components, foraminiferal assemblages, and stable isotopes show that the Korea Strait was influenced in different ways by river discharges and open-ocean currents, according to their temporal and spatial variability.The results of core SSDP 105 indicate that the southeastern coast of Korea was probably a shallow coastal environment, such as a shoreface or beach, by about 17.5 cal ka. The area remained a coastal environment that was affected by high energy conditions and partly by freshwater input during the transgressive period of 17.5–8.1 cal ka. The area has changed to a modern-type shelf environment influenced by the inflow of the Tsushima Current and by the high supply of fine-grained sediments derived from the Nakdong River since 8.1 cal ka.Meanwhile, the results of core SSDP 102 taken from the Nakdong River mouth reveal that the river mouth area was most likely a terrestrial or fluvial environment at least before 13.9 cal ka. It then changed to the estuarine (deltaic) environment that was directly affected by the Nakdong River between 13.9 and 7.0 cal ka, and established a modern-type shelf (prodeltaic) environment, which is similar in many respects to the southeastern coast of Korea after temporarily undergoing erosion between 7.0 and 6.1 cal ka.  相似文献   

6.
The ReSaKo project undertook extended fieldwork across southern Cameroon to explore the palaeoenvironmental information recorded in the alluvial sediments of equatorial African rivers. 160 hand-corings reaching maximum depths of 550 cm were carried out on alluvial ridges and floodplains of major Cameroonian fluvial systems. These multilayered, sandy to clayey alluvia contain sedimentary form-units and palaeosurfaces, which provide excellent additional proxy data archives for the reconstruction of palaeoenvironmental conditions in western equatorial Africa. Coring transects and sedimentary profiles document grain-size shifts and distinguishable sedimentary units in the stratigraphic record, which evidence (fluvial-)morphological adjustments of the fluvial systems in response to external forcing and (river-) intrinsic variability. 76 14C-(AMS)-dated samples from organic sediment and macro-rests (fossil organic remains like wood, leafs, etc.) embedded in these sedimentary units indicate Late Pleistocene to recent ages (uncalibrated 14C-ages: 48–0.2 ka BP). The tentative interpretation of the alluvial record yields excellent additional information on the complex feedbacks between climate, ocean, fluvial as well as ecological systems and human activity in a little-studied region with high sensitive tropical ecosystems. δ13C-values (?35.5 to ?18.0‰) of the dated samples indicate the persistence of C3-dominated gallery forests across the rivers (‘fluvial rain forest refuges’) despite several climatic fluctuations (aridifications, e.g. Last Glacial Maximum around 20 ka BP, Younger Dryas 13–11 ka BP). This research complements earlier results from additional terrestrial and marine proxy data archives on the Late Quaternary history of monsoonal western equatorial Africa.  相似文献   

7.
Glycerol ether lipid distributions have been developed as proxies for reconstructing past environmental change or, in their intact polar form, for fingerprinting the viable microbial community composition. However, due to their structural complexity, full characterization of glycerol ether lipids requires separate protocols for the analysis of the polar head groups and the alkyl chain moieties in core ether lipids. As a consequence, the valuable relationship between core ether lipid composition and specific polar head groups is often lost; this limits understanding of the diversity of ether lipids and their utility as biogeochemical proxies. Here, we report a novel reversed phase liquid chromatography–electrospray ionization-mass spectrometry (RP-ESI-MS) protocol that enables the simultaneous analysis of polar head groups (e.g. phosphocholine, phosphoglycerol, phosphoinositol, hexose and dihexose) and alkyl moieties (e.g. alkyl moieties modified with different numbers of cycloalkyl moieties, hydroxyl and alkyl groups and double bonds) in crude lipid extracts without further preparation. The protocol greatly enhances detection of archaeal intact polar lipids (IPLs) and core lipids (CLs) with double bond- and hydroxyl group-bearing alkyl moieties. With these improvements, widely used ratios that describe relative distributions of the core lipids, such as TEX86 and ring index, can now be directly determined in specific intact polar lipids (IPL-specific TEX86 and ring index). Since IPLs are the putative precursors of the environmentally persistent core lipids, their detailed examination using this protocol can potentially provide new insights into diagenetic and biological mechanisms inherent to these proxies. In a series of 12 samples from diverse settings, core and IPL-specific TEX86 values followed the order: 2G-GDGTs > core GDGTs > 1G-GDGTs > 1G-GDGT-PI and the ring indices followed: 1G-GDGTs ≈ core GDGTs > 2G-GDGTs > 1G-GDGT-P1G > 2G-OH-GDGTs ≈ 1G-OH-GDGTs (1G, monoglycosyl; 2G, diglycosyl; P1G, phosphomonoglycosyl; GDGT, glycerol dialkyl glycerol tetraether).  相似文献   

8.
Proglacial lake sediments at Goting in the Higher Central Himalaya were analyzed to reconstruct the summer monsoon variability during the Last Glacial to early Holocene. Sedimentary structures, high resolution mineral magnetic and geochemical data suggest that the lacustrine environment experienced fluctuating monsoonal conditions. Optically stimulated luminescence (OSL) dating indicates that the lake sedimentation occurred before 25 ka and continued after 13 ka. During this period, Goting basin witnessed moderate to strengthened monsoon conditions around 25 ka, 23.5 ka–22.5 ka, 22 ka–18 ka, 17 ka–16.5 ka and after14.5–13 ka. The Last Glacial phase ended with the deposition of outwash gravel dated at ～11 ka indicating glacial retreat and the onset of Holocene condition. Additionally, centennial scale fluctuations between 16.5 ka and 12.7 ka in the magnetic and geochemical data are seen.A close correspondence at the millennial scale between our data and that of continental and marine records from the Indian sub-continent suggests that Goting basin responded to periods of strengthened monsoon during the Last Glacial to early Holocene. We attribute the millennial scale monsoon variability to climatic instability in higher northern latitudes. However, centennial scale abrupt changes are attributed to the result of albedo changes on the Himalaya and Tibetan plateau.  相似文献   

9.
A thick alluvial sequence in central New Mexico contains the Scholle wet meadow deposit that traces upstream to a paleospring. The wet meadow sediments contain an abundant fauna of twenty-one species of freshwater and terrestrial mollusks and ten species of ostracodes. The mollusks and ostracodes are indicative of a local high alluvial water table with spring-supported perennial flow but without standing water. Pollen analysis documents shrub grassland vegetation with sedges, willow, and alder in a riparian community. Stable carbon isotopes from the wet meadow sediments have δ13C values ranging from ? 22.8 to ? 23.3‰, indicating that 80% of the organic carbon in the sediment is derived from C3 species. The wet meadow deposit is AMS dated 10,400 to 9700 14C yr BP, corresponding to 12,300 to 11,100 cal yr BP and overlapping in time with the Younger Dryas event (YD). The wet meadow became active about 500 yr after the beginning of the YD and persisted 400 yr after the YD ended. The Scholle wet meadow is the only record of perennial flow and high water table conditions in the Abo Arroyo drainage basin during the past 13 ka.  相似文献   

10.
This study forms part of a wider investigation of late Quaternary environments in the Southern Hemisphere. We here review the terrestrial and near-shore proxy data from Australia, Indonesia, Papua New Guinea (PNG), New Zealand and surrounding oceans during 35–10 ka, an interval spanning the lead-up to the Last Glacial Maximum (LGM), the LGM proper (21 ± 2 ka), and the ensuing deglaciation. Sites selected for detailed discussion have a continuous or near continuous sedimentary record for this time interval, a stratigraphically consistent chronology, and one or more sources of proxy climatic data. Tropical Australia, Indonesia and PNG had LGM mean annual temperatures 3–7 °C below present values and summer precipitation reduced by at least 30%, consistent with a weaker summer monsoon and a northward displacement of the Intertropical Convergence Zone. The summer monsoon was re-established in northwest Australia by 14 ka. Precipitation in northeast Australia was reduced to less than 50% of present values until warmer and wetter conditions resumed at 17–16 ka, followed by a second warmer, wetter phase at 15–14 ka. LGM temperatures were up to 8 °C lower than today in mainland southeast Australia and up to 4 °C cooler in Tasmania. Winter rainfall was much reduced throughout much of southern Australia although periodic extreme flood events are evident in the fluvial record. Glacial advances in southeast Australia are dated to 32 ± 2.5, 19.1 ± 1.6 and 16.8 ± 1.4 ka, with periglacial activity concentrated towards 23–16 ka. Deglaciation was rapid in the Snowy Mountains, which were ice-free by 15.8 ka. Minimum effective precipitation in southern Australia was from 14 to 12 ka. In New Zealand the glacial advances date to ～28, 21.5 and 19 ka, with the onset of major cooling at ～28 ka, or well before the LGM. There is no convincing evidence for a Younger Dryas cooling event in or around New Zealand, but there are signs of the Antarctic Cold Reversal in and around New Zealand and off southern Australia. There remain unresolved discrepancies between the climates inferred from pollen and those inferred from the beetle and chironomid fauna at a number of New Zealand sites. One explanation may be that pollen provides a generalised regional climatic signal in contrast to the finer local resolution offered by beetles and chironomids. Sea surface temperatures (SSTs) were up to 5 °C cooler during the LGM with rapid warming after 20 ka to attain present values by 15 ka. The increase in summer monsoonal precipitation at or before 15 ka reflects higher insolation, warmer SSTs and steeper thermal gradients between land and sea. The postglacial increase in winter rainfall in southern Australia is probably related to the southward displacement of the westerlies as SSTs around Antarctica became warmer and the winter pack ice and Antarctic Convergence Zone retreated to the south.  相似文献   

11.
Detailed knowledge of the extent of post-genetic modifications affecting shallow submarine hydrocarbons fueled from the deep subsurface is fundamental for evaluating source and reservoir properties. We investigated gases from a submarine high-flux seepage site in the anoxic Eastern Black Sea in order to elucidate molecular and isotopic alterations of low-molecular-weight hydrocarbons (LMWHC) associated with upward migration through the sediment and precipitation of shallow gas hydrates. For this, near-surface sediment pressure cores and free gas venting from the seafloor were collected using autoclave technology at the Batumi seep area at 845 m water depth within the gas hydrate stability zone.Vent gas, gas from pressure core degassing, and from hydrate dissociation were strongly dominated by methane (> 99.85 mol.% of ∑[C1–C4, CO2]). Molecular ratios of LMWHC (C1/[C2 + C3] > 1000) and stable isotopic compositions of methane (δ13C = ? 53.5‰ V-PDB; D/H around ? 175‰ SMOW) indicated predominant microbial methane formation. C1/C2+ ratios and stable isotopic compositions of LMWHC distinguished three gas types prevailing in the seepage area. Vent gas discharged into bottom waters was depleted in methane by > 0.03 mol.% (∑[C1–C4, CO2]) relative to the other gas types and the virtual lack of 14C–CH4 indicated a negligible input of methane from degradation of fresh organic matter. Of all gas types analyzed, vent gas was least affected by molecular fractionation, thus, its origin from the deep subsurface rather than from decomposing hydrates in near-surface sediments is likely.As a result of the anaerobic oxidation of methane, LMWHC in pressure cores in top sediments included smaller methane fractions [0.03 mol.% ∑(C1–C4, CO2)] than gas released from pressure cores of more deeply buried sediments, where the fraction of methane was maximal due to its preferential incorporation in hydrate lattices. No indications for stable carbon isotopic fractionations of methane during hydrate crystallization from vent gas were found. Enrichments of 14C–CH4 (1.4 pMC) in short cores relative to lower abundances (max. 0.6 pMC) in gas from long cores and gas hydrates substantiates recent methanogenesis utilizing modern organic matter deposited in top sediments of this high-flux hydrocarbon seep area.  相似文献   

12.
《Applied Geochemistry》2006,21(11):1969-1985
Gossan Creek, a headwater stream in the SE Upsalquitch River watershed in New Brunswick, Canada, contains elevated concentrations of total Hg (HgT up to 60 μg/L). Aqueous geochemical investigations of the shallow groundwater at the headwaters of the creek confirm that the source of Hg is a contaminated groundwater plume (neutral pH with Hg and Cl concentrations up to 150 μg/L and 20 mg/L, respectively), originating from the Murray Brook mine tailings, that discharges at the headwaters of the creek. The discharge area of the contaminant plume was partially delineated based on elevated pH and Cl concentrations in the groundwater. The local groundwater outside of the plume contains much lower concentrations of Hg and Cl (<0.1 μg/L and 3.8 mg/L, respectively) and displays the chemical characteristics of an acid-sulfate weathering system, with low pH (4.1–5.5) and elevated concentrations of Cu, Zn, Pb and SO4 (up to 5400 μg Cu/L, 8700 μg Zn/L, 70 μg Pb/L and 330 mg SO4/L), derived from oxidation of sulfide minerals in the Murray Brook volcanogenic massive sulfide deposit and surrounding bedrock. The HgT mass loads measured at various hydrologic control points along the stream system indicate that 95–99% of the dissolved HgT is attenuated in the first 3–4 km from the source. Analyses of creek bed sediments for Au, Ag, Cu, Zn, Pb and Hg indicate that these metals have partitioned strongly to the sediments. Mineralogical investigations of the contaminated sediments using analytical scanning electron microscopy (SEM), transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM), reveal discrete particles (<1–2 μm) of metacinnabar (HgS), mixed Au–Ag–Hg amalgam, Cu sulfide and Ag sulfide.  相似文献   

13.
The stable carbon isotopic compositions of light hydrocarbon gases adsorbed in near-surface soil and sediments from the Saurashtra basin were characterized for their origin and maturity. Saurashtra is considered geologically prospective for oil and gas reserves; however, a major part of the basin is covered by the Deccan Traps, hindering the exploration of Mesozoic hydrocarbon targets. Surface geochemical prospecting, based on micro-seepage of hydrocarbons from subsurface accumulations, could be advantageous in such areas. In light of this, 150 soil samples were collected from the northwestern part of Saurashtra, around the Jamnagar area, where a thick sedimentary sequence of about 2–3 km exists under 1–1.5 km of Deccan basalt. The concentration of acid desorbed alkane gases from soil samples was found to vary (in ppb) as: methane (C1) = 3–518; ethane (C2) = 0–430; propane (C3) = 0–331; i-butane (iC4) = 0–297; n-butane (nC4) = 2–116; i-pentane (iC5) = 0–31 and n-pentane (nC5) = 0–23, respectively.Fifteen samples with high concentrations of alkane gases were measured for their δ13C1; δ13C2 and δ13C3 compositions using gas chromatography–combustion-isotope ratio mass spectrometry (GC–C-IRMS). The values for methane varied from ? 27 to ? 45.4‰, ethane from ? 20.9 to ? 27.6‰, and propane from ? 20.4 to ? 29.1‰ versus the Vienna PeeDee Belemnite (VPDB). The carbon isotope ratio distribution pattern represents isotopic characteristics pertaining to hydrocarbon gases derived from thermogenic sources. Comparisons of carbon isotopic signatures and compositional variations with the standard carbon isotopic models suggest that hydrocarbon gases found in the shallow depths of the study area are not of bacterial origin but are formed thermally from deeply buried organic matter, likely to be mainly a terrestrial source rock with a partial contribution from a marine source. These gases may have migrated to the near-surface environment, where they represent an admixture of thermally generated hydrocarbon gases from mixed sources and maturity. The maturity scale (δ13C versus Log Ro %) applied to the surface sediment samples of the Jamnagar area indicated the source material to be capable of generating oil and gas. The detection of thermogenic alkane gases in near-surface sediments offers the possibility of hydrocarbons at depth in Saurashtra.  相似文献   

14.
We employed X-ray diffraction methods to quantify clay mineral assemblages in the Indus Delta and flood plains since ~ 14 ka, spanning a period of strong climatic change. Assemblages are dominated by smectite and illite, with minor chlorite and kaolinite. Delta sediments integrate clays from across the basin and show increasing smectite input between 13 and 7.5 ka, indicating stronger chemical weathering as the summer monsoon intensified. Changes in clay mineralogy postdate changes in climate by 5–3 ka, reflecting the time needed for new clay minerals to form and be transported to the delta. Samples from the flood plains in Punjab show evidence for increased chemical weathering towards the top of the sections (6–< 4 ka), counter to the trend in the delta, at a time of monsoon weakening. Clay mineral assemblages within sandy flood-plain sediment have higher smectite/(illite + chlorite) values than interbedded mudstones, suggestive of either stronger weathering or more sediment reworking since the Mid Holocene. We show that marine records are not always good proxies for weathering across the entire flood plain. Nonetheless, the delta record likely represents the most reliable record of basin-wide weathering response to climate change.  相似文献   

15.
We determined biomarker concentrations and distributions for surface sediments from 54 sites in the Pearl River Estuary, China. We focus on a suite of four biomarker-based indicators for relative terrestrial to marine organic matter (OM) source: the branched-isoprenoid tetraether (BIT) index, the ratio of high/low molecular weight n-alcohols [(ΣC26–34/(ΣC16+18 + ΣC26–34)], an analogous ratio for n-fatty acids and the ΣC29-steroids/(ΣC29-steroids + brassicasterol) ratio. All four exhibit the same terrestrial to marine transition seen in previous bulk δ13C studies, but with an abrupt decrease in the relative terrestrial contribution across the delta front to pro-delta transition. Concentrations of terrestrially-derived biomarkers show no systematic decrease across the transition. Instead, the decrease in the proportion of terrestrial OM is due to a decrease in the sedimentation rate and associated terrestrial OM burial across the delta toe. This suggests that diagenetic controls on the fate of terrestrial OM, such as increased biodegradation where sedimentation rate is low, are subordinate to sedimentological processes. Biomarker-derived temperature values are cooler than expected for the lower Pearl River catchment, suggesting that the dominant component of the terrestrial OM is derived from the cooler upland regions of the catchment. The dominance of input from more distal terrain with greater topographic relief is evidence for the importance of geomorphological control on terrigenous OM transport. Collectively, the results demonstrate the importance of sedimentological processes in the supply, deposition and transport of terrestrial OM.  相似文献   

16.
Sedimentological, geomorphic, and ground penetrating radar (GPR) data are combined with optically stimulated luminescence data to define the Holocene evolution of a coastal system in peninsular Malaysia. The Setiu coastal region of northeast Malaysia comprises five geological and geomorphic units representing distinct evolutionary phases of this coastline. Estimated marine limiting point elevations indicate deposition of an early aggradational shoreline associated with a sea-level elevation of −0.1 to +1.7 m (MSLPMVGD datum) between ∼6.8 ka and 5.7 ka, in agreement with previous sea-level studies from the Malay–Thai peninsula. A hiatus occurs in the record between ∼5.7 ka and 3.0 ka, possibly due to a relative sea-level oscillation and shoreline erosion. Long-term relative sea-level fall and possible still-stands created strandplains that are interrupted by aggradational to transgressive paleo-barrier and estuary formation corresponding with brief episodes of RSL rise. Analyses of GPR facies and OSL ages suggest annual clinoform deposition, with geometries dictated by variations in ENSO. These data demonstrate the utility of high resolution studies of coastal facies as useful proxy indicators for paleoclimate studies at subdecadal to millennial time-scales.  相似文献   

17.
Ethane and propane are low molecular weight hydrocarbons observed widely at trace levels in cold marine sediments where thermogenic sources are considered insignificant, but their biological sources remain poorly constrained. In this study, several C2 and C3 compounds including alkenes, alcohols, thiols and carboxylic acids with a C2 or C3 skeleton were tested for their relative alkane-producing potential in an anoxic estuary sediment. Maximum conversion efficiency of substrates to ethane or propane was observed in the sediment supplemented with ethylene (up to 38%), followed by additions with ethanethiol (0.01%) and propanethiol (0.003%). Experiments with sterilized sediment, 2-bromoethanesulfonic acid or NaNO3 were negative for alkane production, suggesting that methanogens were involved in alkane generation. Detailed investigation on ethanogenesis from ethylene showed that this reaction required H2 but at reasonably low concentration (< 120 nmol dissolved H2 l−1 slurry) and caused a slight stable carbon isotope effect (εethane/ethylene = −8.6 ± 2.4‰). The high ethane-producing potential, reasonable H2 requirement and extensive occurrence of ethylene make ethylene reduction a plausible explanation for ethane in cold marine sediment. Phylogenetic analysis was first carried out with an ethane-producing enrichment with ethylene as the substrate and showed a dominance of homoacetogenic bacteria and the methanogenic genus Methanocalculus. Although we cannot rule out the possibility that other methanogens in the gene libraries are responsible for ethanogenesis from ethylene, the dominance of Methanocalculus, with its hydrogenotrophic cultured representatives, is in accord with our biogeochemical observation that H2 is required for this reaction.  相似文献   

18.
《Quaternary Science Reviews》2003,22(21-22):2303-2310
The present work revisits the chronology of the archaeologically controversial Pedra Furada Rock Shelter of Southeast Piauı́, Brazil, using an improved radiocarbon laboratory pre-treatment and measurements on charcoal samples. The procedure, known as ABOX-SC (acid–base–wet oxidation followed by stepped combustion), has previously been used to secure radiocarbon dates of >40 ka for the antiquity of human occupation of Australia and South Africa, and now has been applied to charcoal from the previously dated oldest occupation layer of the Pedra Furada site. Previous radiocarbon dating had obtained only lower limits of 40–45 ka BP for the Pedra Furada basal layer. Nine charcoal samples from well-structured hearths were subjected to the ABOX-SC procedure and their radiocarbon content determined by accelerator mass spectrometry. Measurements on five of the samples returned ages of greater than 56 ka BP, from graphites produced from ABOX pre-treated charcoal combusted at 910°C. Two other samples were greater than 50 ka BP. The remaining two samples were essentially completely combusted at 650°C, with no material surviving to make a 910°C CO2 fraction. Their ages were 41.3 and 47.2 ka BP. Ages obtained from graphites generated from the 650°C combusted fraction are considered minimum ages.  相似文献   

19.
《Quaternary Science Reviews》2004,23(16-17):1847-1865
High-resolution seismic data and sediment cores show that an up to 280 m thick sedimentary sequence has been deposited on the south Vøring margin, off mid-Norway, the last ca 250 ka. The sedimentary succession has been divided into six seismic units, dominated by hemipelagic sediments. Five wedge-shaped massive sequences, of marine isotope stages 8, 6 and 2, interfinger the hemipelagic deposits on the upper slope. The wedge-shaped sequences represent glacigenic debris flows that have been fed by till transported to the shelf edge by grounded ice sheets during maximum glaciations. The hemipelagic units show well-defined depocentres, of various thicknesses, on the upper continental slope. Seismic facies interpretation indicates that the sediment distribution locally has been controlled by currents. Commonly, the hemipelagic units are characterised by parallel and continuous reflectors. However, the second youngest unit identified, deposited between 15.7 and 15.0 14C ka BP, is acoustic transparent. We suggest that this unit has been sourced by along-slope transported meltwater plume deposits, released during the initial stage of the last deglaciation of the Norwegian Channel. The hemipelagic sedimentation rates have varied considerably throughout the studied time period. Until ca 21 14C ka BP the rates did not exceed 1.4 m/kyr, whereas during the Last Glacial Maximum the rates increased and reached values of about 36 m/kyr before decreasing again at ca 15 14C ka BP. Observation of iceberg scourings, of MIS 8 age, about 800 m below the present day sea level, suggest that the south Vøring margin has subsided by a rate of 1.2 m/kyr in the Late Quaternary.  相似文献   

20.
《Quaternary Science Reviews》2003,22(10-13):1207-1211
The time-integrated slip rate in fault zones can be determined if the deformed deposits are reliably dated. Here, we report optically stimulated luminescence (OSL) ages of Late Pleistocene fluvial deposits cut by the Wangsan fault, southeastern Korea, which displaces a hanging wall block of about 28 m. Five sandy samples of the deformed Quaternary deposits were dated by quartz OSL using the single aliquot regenerative-dose (SAR) protocol. Three samples taken from the footwall block show stratigraphically consistent OSL ages of 54±7, 76±5 and 90±6 ka, from top to bottom. Two samples collected from the same layer in the hanging wall block show reproducible OSL ages of 81±5 and 82±5 ka, which are also in good agreement with the stratigraphic relationships. Our OSL ages yield an average sedimentation rate of the Quaternary deposits as around 0.04 mm a−1, and a minimum value of time-integrated slip rate as 0.52 mm a−1. This minimum slip rate is considerably higher than those reported earlier for Quaternary faults in southeastern Korea. The youngest OSL age (54±7 ka) constrains the maximum value of the recurrence interval of the fault movement.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号