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Compositions, proportions, and equilibrium temperature of coexisting two-feldspar in crystalline rocks are of great importance to classification in petrography and interpretation of petrogenesis. Crystalline rocks are usually composed of 4-6 minerals (phases), depending on their independent chemical components and the equilibrium temperature of crystallizations. In general, number of mineral phases can be determined by the “Phase Rule”. According to the mass balance principle, bulk composition of coexisting two-feldspar could be evaluated from the bulk chemistry of a rock, provided that the compositions of the coexisting mafic mineral phases containing calcium, sodium, and potassium oxides are determined, e.g., by microprobe analysis. The compositions, proportions, and temperature of two-feldspar in equilibrium can thus be simultaneously resolved numerically from bulk composition of the rock, by incorporating the activity/composition relations of the ternary feldspars with the mass balance constraints. Upon the numerical approximation method presented in this paper, better-quality, internally consistent data on feldspar group could usually be obtained, which would be expected more realistic and accurate in consideration of thermodynamic equilibria in the system of crystalline rocks, as well as bulk chemistry of a rock and the composing minerals. 相似文献
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Mathematical simulation of non‐isothermal multiphase flow in deformable unsaturated porous media is a complicated issue because of the need to employ multiple partial differential equations, the need to take into account mass and energy transfer between phases and because of the non‐linear nature of the governing partial differential equations. In this paper, an analytical solution for analyzing a fully coupled problem is presented for the one‐dimensional case where the coefficients of the system of equations are assumed to be constant for the entire domain. A major issue is the non‐linearity of the governing equations, which is not considered in the analytical solution. In order to introduce the non‐linearity of the equations, an iterative discretized procedure is used. The domain of the problem is divided into identical time–space elements that cover the time–space domain. A separate system of equations is defined for each element in the local coordinate system, the initial and boundary conditions for each element are obtained from the adjacent elements and the coefficients of the system of equations are considered to be constant in each step. There are seven governing differential equations that should be solved simultaneously: the equilibrium of the solid skeleton, mass conservation of fluids (water, water vapor and gas) and energy conservation of phases (solid, liquid and gas). The water vapor is not in equilibrium with water and different phases do not have the same temperature. The governing equations that have been solved seem to be the most comprehensive in this field. Three examples are presented for analyzing heat and mass transfer in a semi‐infinite column of unsaturated soil. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
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G. Keller 《Australian Journal of Earth Sciences》2013,60(4-5):725-757
Large impacts are credited with the most devastating mass extinctions in Earth's history and the Cretaceous?–?Tertiary (K/T) boundary impact is the strongest and sole direct support for this view. A review of the five largest Phanerozoic mass extinctions provides no support that impacts with craters up to 180 km in diameter caused significant species extinctions. This includes the 170 km-diameter Chicxulub impact crater regarded as 0.3 million years older than the K/T mass extinction. A second, larger impact event may have been the ultimate cause of this mass extinction, as suggested by a global iridium anomaly at the K/T boundary, but no crater has been found to date. The current crater database suggests that multiple impacts, for example comet showers, were the norm, rather than the exception, during the Late Eocene, K/T transition, latest Triassic and the Devonian?–?Carboniferous transition, but did not cause significant species extinctions. Whether multiple impacts substantially contributed to greenhouse warming and associated environmental stresses is yet to be demonstrated. From the current database, it must be concluded that no known Phanerozoic impacts, including the Chicxulub impact (but excluding the K/T impact) caused mass extinctions or even significant species extinctions. The K/T mass extinction may have been caused by the coincidence of a very large impact (>?250 km) upon a highly stressed biotic environment as a result of volcanism. The consistent association of large magmatic provinces (large igneous provinces and continental flood-basalt provinces) with all but one (end-Ordovician) of the five major Phanerozoic mass extinctions suggests that volcanism played a major role. Faunal and geochemical evidence from the end-Permian, end-Devonian, end-Cretaceous and Triassic/Jurassic transition suggests that the biotic stress was due to a lethal combination of tectonically induced hydrothermal and volcanic processes, leading to eutrophication in the oceans, global warming, sea-level transgression and ocean anoxia. It must be concluded that major magmatic events and their long-term environmental consequences are major contributors, though not the sole causes of mass extinctions. Sudden mass extinctions, such as at the K/T boundary, may require the coincidence of major volcanism and a very large Impact. 相似文献
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计算流体地球化学研究的进展 总被引：3，自引：0，他引：3
成矿作用的化学机理可以通过实验和计算机模拟进行研究。随着计算机运算能力的不断增强 ,在地球化学中正在形成一门新兴学科———计算地球化学。其中热质输运模拟、化学质量迁移数值模拟和流体输运化学反应耦合动力学研究取得了显著进展。建立在Darcy定律和守恒方程基础上的多孔介质热质输运模拟通过流函数图、等温线图及速率矢量图等 ,从古水文学和流体地球化学方面高度动态研究成矿作用。根据化学和热力学原理进行的化学质量迁移数值模拟则通过矿物和流体中化学物种的热力学数据 ,预测多组分体系中发生的流体岩石相互作用 ,定量揭示经历了复杂化学反应进程的成矿作用的化学行为。将上述两方面结合的流体输运化学反应耦合动力学 ,可以从时间和空间上模拟真实成矿流体系统复杂的动力学行为 ,是计算流体地球化学的发展方向。 相似文献
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In this paper, the internal structure of shear band is investigated, and a model of the shear band with an echelon crack structure is developed. The model assumes the shear band to be composed of two conjugate sets of echelon cracks, such that the smaller echelon cracks are embedded in the space of the larger ones. The additional strain induced by the echelon cracks and the anisotropic development of the compliance tensor in the shear band zone are analyzed. The critical crack density at the onset of shear band is obtained by applying the bifurcation condition. Deviating from previous approaches, the new procedure evaluates the thickness of shear band based on the geometrical characteristics of echelon crack arrays and the failure probability of grain boundaries in the longitudinal direction at the onset of shear band. Parametric analysis shows that grain size, internal friction angle, dilation angle, and failure probability of grain boundaries are the dominant factors that account for the shear band thickness. The calculated results are consistent with the experimental data available in the literature. The model soundly explains that the measurements of the shear band thickness are generally scattered, ranging from 4 to 30 (or even more) times the grain size. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
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贵州黔西北地区煤矿资源丰富,因由于煤矿开采导致城市地下地质结构变化而引发安全问题。城市地下空间是城市未来发展的重要增长极,拟建城市规划区地下空间地质结构的识别及评价工作极为重要。文中提出基于电场理论、采空区氧化还原环境及煤区地质规律,综合电阻率、电流、自然电位等多个电参数对采煤区拟建城市区地质结构快速识别的方法,并对强风化层、老窑采空区、煤矿采空区等地质结构特征进行评价,取得成果与实地踏勘、已有工程一致,可为城区建设场地地质灾害危险性评价和地下空间开发利用提供重要依据。该方法具有无损、高效、绿色、低成本等优势,值得进一步研究推广。 相似文献
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基于岩体结构面分布分形维的岩体质量评价 总被引：4，自引：1，他引：3
尽管岩体结构面具有空间上的不规则性和结构网络上的复杂性,但由于它又具有自相似的特征,可以运用分形理论来对其进行研究。运用盒计维数法对某矿山巷道围岩体结构面分布的分维数进行计算,验证了岩体结构面分布的分形特征。通过对岩体结构面分布分形维值分布规律的分析发现,分形维数越大、结构面分布越密集,结构面迹线越长,岩体质量越差,表明可将岩体结构面分布的分形维作为岩体质量评价的指标。将计算所得的岩体结构面分布的分维数与按工程岩体分级标准对相应岩体分级所得的岩体质量等级进行对比,提出了一个以岩体结构面分布的分形维作为分级指标的岩体质量评价方案。 相似文献
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冀北地区是河北省矿产资源重要聚集地之一,成矿条件优越,其中中-酸性侵入岩体与银铅锌多金属矿床成矿密切相关。然而,大量的第四系覆盖压制了一些深部及隐伏弱异常成矿信息,使得常规化探方法在该覆盖区提取效果微弱。本文运用奇异性分析及主成分分析对冀北1：20万水系沉积物常量元素化探数据进行分析处理,提取区内成矿元素弱异常,并将其与未进行奇异性处理的结果进行对比。结合区域地质背景、物化探资料圈定覆盖区内与中-酸性侵入岩体有关的异常区,对成矿作用、成矿规律进行分析、讨论,以期揭示区内元素富集规律。结果显示,上述组合方法可以有效提取元素弱异常并进行成矿有利区圈定,并且圈定位置与已知岩体位置、区域构造条件相吻合,共圈出隐伏异常点7个,推测其为成矿远景区。 相似文献
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目前损伤力学已被认为是研究节理岩体力学行为的有效工具,但是在目前的节理岩体损伤变量定义中大多仅考虑节理几何特征而未考虑节理内摩擦角等力学参数,这显然不能很好地反映节理岩体的力学特征。为此,拟推导出一个能够综合考虑节理几何及力学参数的损伤变量（张量）,并由此建立单轴压缩荷载下岩体损伤本构模型。首先,基于断裂力学的由于单个节理存在引起的附加应变能增量与损伤力学的损伤应变能释放量相关联的观点,推导出了含非贯通节理岩体的损伤变量计算公式;其次,根据断裂力学理论对单轴压缩荷载下的单个节理尖端应力强度因子计算方法进行了研究,得出了应力强度因子KⅠ、KⅡ的计算公式;同时考虑多节理间的相互作用给出了单组单排及多排非贯通节理应力强度因子计算公式。最后,利用该模型对含单条非贯通节理的岩体在单轴压缩荷载作用下的峰值强度及损伤变量进行了分析计算。结果表明,当节理倾角小于其内摩擦角时,岩体强度与完整岩石相同,岩体损伤为零,而后随着节理倾角增加,岩体强度、损伤随节理倾角的变化分别呈开口向上及向下的抛物线,当节理倾角约为60°时,岩体损伤最大,强度最低。随着节理长度增加,岩体损伤增加,而随着节理内摩擦角的增加,岩体损伤则减小。 相似文献
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A Critical Approach to Probability Laws in Geochemistry 总被引：2，自引：0，他引：2
Probability laws in geochemistry have been a major issue of concern over the last decades. The lognormal on the positive real
line or the additive logistic normal on the simplex are two classical laws of probability to model geochemical data sets due
to their association with a relative measure of difference. This fact is not fully exploited in the classical approach when
viewing both the positive real line and the simplex as subsets of real space with the induced geometry. But it can be taken
into account considering them as real linear vector spaces with their own structure. This approach implies using a particular
geometry and a measure different from the usual ones. Therefore, we can work with the coordinates with respect to an orthonormal
basis. It could be shown that the two mentioned laws are associated with a normal distribution on the coordinates. In this
contribution both approaches are compared, and a real data set is used to illustrate similarities and differences. 相似文献
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利用地震几何属性和自组织神经网络进行地震相的自动识别 总被引：6，自引：0，他引：6
阐述了2类地震几何属性:①反映地震道空间变化量的属性;②反映地震属性空间相似程度及其衍生的各类参数.运用这些属性来判识地层或反射界面的空间连续性和倾向倾角等地质体的空间几何特征,采用自组织神经网络方法对这些属性进行自动分类来判别地震相.在山东东营凹陷永921井区的应用证明,该方法具有较好的应用效果. 相似文献
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针对目前节理岩体损伤变量定义中大多仅考虑节理长度、倾角等几何性质,而未考虑节理抗剪强度等力学性质的不足,基于断裂力学中的由于单个节理存在引起的附加应变能增量与损伤力学中的损伤应变能释放量相关联的观点,推导出了在双轴应力下含单条非贯通闭合节理岩体的损伤变量计算公式,并根据断裂力学理论对双轴压缩荷载下的单个节理尖端应力强度因子计算方法进行了研究,得出了应力强度因子KⅠ、KⅡ的计算公式;同时考虑多节理间的相互作用,给出了单组单排及单组多排非贯通节理尖端应力强度因子计算公式,由此建立了相应的节理岩体双轴压缩损伤本构模型,并利用该模型进行了相应的算例分析。结果表明：对含单条非贯通闭合节理的岩体而言,当节理倾角小于其内摩擦角时,岩体强度与完整岩石相同,岩体损伤为0,而后随着节理倾角增加,岩体强度、损伤随节理倾角的变化分别呈开口向上及向下的抛物线,当节理倾角约为60°时,岩体损伤最大,强度最低。随着节理长度增加,岩体损伤增加,而随着节理内摩擦角的增加,岩体损伤则减小;对含单组单排非贯通闭合节理的岩体而言,当节理总长度一定时,随着单条节理长度的减小及节理条数的增加,岩体损伤则逐渐减小,但其减小幅度与节理条数并不呈线性关系。 相似文献
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隧道围岩分类的层次类比系统方法 总被引：1，自引：0，他引：1
吕小平 《水文地质工程地质》1993,20(4):10-13
在本文中,把围岩分类的因素分为3种。第一种为大的地质环境,它主要包括地层、构造、地形等;第二种为围岩的小环境,它包括岩体结构、结构面的发育情况、地下水的分布等;第三种为围岩的物理、力学、水理以及埋深等具体参数。这3种因素从大到小形成一个层次递阶关系,下层元素是上层元素的具体表现,上层元素对下层元素产生影响。把用这种层次关系表征的典型工点集合,作为一个工程地质评价模型的基础。按典型工点的稳定性进行排序或进行聚类分析,再把新工点的稳定性权重与典型工点的稳定性权重序列或相似序列比较,找出新工点在典型工点序列中的相当位置,这样就可根据与新工点相近的典型工点围岩类别以及施工、支护等成功的设计参数或经验教训作为新工点的设计参数。 相似文献
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岩体结构研究中统计区间长度的确定 总被引：5，自引：0，他引：5
岩体结构研究日益得到工程地质界的重视,而岩体结构面现场测量数据是获得岩体结构特征的必需资料。在目前常用的2种结构面测量方法中对如何选择合理的统计区间长度缺乏充分的论证。利用我国西南某大型水电工程丰富的结构面测量资料,研究统计区间长度对岩体结构类型的影响,取得了一定的成果。即最小有效测线长度与结构面间距大小及概率密度分布形式有关,研究岩体结构特征时,必须根据工程实际情况选择满足要求的统计区间长度。 相似文献
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The model uses, in one-dimensional flow, the random-walk method on particles and integrates them into a discretized representation of space which eliminates the individual management of each particle. The method of computing allows a simulation of mass transfer in adsorbing media by dissociating the roles of convection, dispersion, and the exchange occurring between the mobile and immobile phases. This gives the parameters that have to be fitted, such as the dispersivity or the exchange rate, a meaning which is closer to their physical reality than that defined by global models (e.g., apparent dispersivity without considering exchange between phases). The model was tested first on analytical solutions and also on data from laboratory experiments on a double porosity chalk column and showed that, with the same limited set of parameters, it could fit concentration/time restitutions at different distances from the injection point. Because of its structure, the algorithm can easily be modified so as to simulate distributed injections and transfers in a regime of variable flow rates. 相似文献
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工程岩体完整性评价的实用方法研究 总被引：3，自引：1，他引：2
采用结构面统计与结构面结合特征识别相结合的方法,从结构面几何发育特征和结合特征两方面评价工程岩体完整性。用体积节理数评价结构面几何发育特征,并引入岩体几何完整性系数Ig来表征。根据结构面张开度和充填胶结特征将其结合程度分为5级,给出各级的定性特征描述,并引入结构面结合程度系数Ip对其量化。进而定义了岩体完整性指数将岩体完整性划分为完整、较完整、破碎、较破碎和极破碎5级,并给出对应的定性特征描述和Irm值区间。结合公路隧道工程实例,分别采用文中方法、声波测试法和体积节理数测量法对隧道围岩完整性进行了评价并对评价结果进行了比较。结果表明,文中方法得到的岩体完整性指数Irm与声波测试法得到的Kv基本一致,而体积节理数量测法的评价结果整体上大于声波测试方法。 相似文献
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The simplex with the Aitchison geometry is a natural sample space for compositional data, that is, observations carrying only
relative information (especially proportions, percentages, etc., often occurring in the geosciences). For this reason, standard
statistical methods that rely on Euclidean structure of the real space cannot be used directly for statistical analysis. At
first, compositional data need to be expressed in coordinates of an orthonormal basis on the simplex (with respect to the
Aitchison geometry). The mathematical interpretation of the orthonormal coordinates is derived from the procedure by which
they are constructed (called sequential binary partition), and they act as balances between groups of compositional parts.
The goal of this paper is to describe the covariance structure of coordinates and, consequently, to provide a complementary
interpretation based on log-ratios of parts of the original composition. It must be noted that, in a composition, the ratios
themselves contain all the relevant information. The possibilities as well as the limitations of this approach are demonstrated
through illustrative examples. 相似文献