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1.
High temperature X-ray investigations of enstatite from Bamble shows that the proto (PE) to ortho (OE)/clino (CE) inversion is most probably triggered by preformed single stacking faults acting as nuclei and completed by a subsequent rapid growth process compatible with the martensitic nature of the transformation. New stacking faults are created during the transformation. From a detailed analysis of line profiles we deduce the formation of out-of-phase OE domains which are intergrown with well ordered CE sequences. Single layer faults and PE type faults can be ruled out. A transformation mechanism similar to that proposed by Sadanaga et al. (1969) fits well with our results. Inelastic neutron scattering experiments show that the origin of the transformation is not an elastic shear instability. A transient increase of the elastic constant c
55 is interpreted as a secondary effect caused by elastic strains in the progress of the transformation.Work was supported by the BMFT under 03-SC1LMU3 相似文献
2.
A high temperature single-crystal X-ray diffraction study of enstatite, Mg2Si2O6 was undertaken at 296, 900, 1200, 1360 and 1400 K. During the X-ray data collection at 1360 K (T0), orthoenstatite (Pbca) transformed to protoenstatite (Pbcn). The unit cell parameters measured at T0 are a=18.456(4), b=8.960(2) and c=5.270(1) Å for ortho and a=9.306(1), b=8.886(1) and c=5.360(1) Å for proto. The discontinuous increase in c and decrease in b due to the ortho to proto transformation are associated with the drastic unkinking of the silicate chains, whereas the abrupt increase in a results from the large expansion of the M2 — O distances along a coupled with the increase in the out-of-plane tilting of the silicate tetrahedra. Stacking faults form in ortho prior to the phase transition, as well as in proto between 1360 and 1400 K. With increasing temperature, the silicate B chain in ortho straightens faster than the A chain as the configurations of the SiA and SiB tetrahedra tend to become similar. At T0, the A and B chains with the O3-O3-O3 angles (O3 being the bridging oxygen atom) of 163.0° and 149.5° in ortho, respectively, attain an identical angle of 168.4° in proto. The configuration of the silicate chain in proto resembles that of the A chain in ortho. Rigid-body thermal vibration analysis suggests that between 1200 and 1400 K the largest, the second largest and the smallest thermal librational motions of the [SiO4] tetrahedra in both ortho and proto are approximately around a, c and b, respectively. Below 1200 K, the largest thermal librational amplitudes of the SiA and SiB tetrahedra in ortho are quite different, but become nearly equivalent at T0. In contrast to the results reported for all iron-bearing orthopyroxenes at high temperature, switching of the O3B atoms coordinated with the M2 cation occurs during the ortho to proto transformation, but not in ortho below T0. The ortho-proto transition does not affect the configuration of the M1 octahedron significantly, but results in a decrease of the mean M2 — O bond distance by 0.043 Å and a highly distorted M2 octahedron in proto. 相似文献
3.
以蒙脱石为初始材料,通过水热实验模拟在不同温度压力条件下蒙脱石的伊利石化过程。利用X射线粉末衍射及X射线荧光光谱、红外光谱和扫描电镜等方法对样品的矿物物相、化学成分、晶体结构与微观形貌等进行分析,其结果表明:(1)蒙脱石至伊利石的转化受温度和压力条件的控制;(2)随着温度和压力的增高,蒙脱石伊利石化沿着蒙脱石-无序伊蒙混层-有序伊蒙混层-伊利石的转化序列进行转化;(3)水热实验模拟表明蒙脱石至伊利石的转化以溶解重结晶机制为主。实验结果不仅有助于了解埋藏与低级变质作用中的蒙脱石伊利石化过程,同时为研究断层活动所致断层泥中黏土矿物的转化及反演断层形成时温度压力条件提供基本参数。 相似文献
4.
Reinhard Kaindl Daniel M. T?bbens Simon Penner Thomas Bielz Soipatta Soisuwan Bernhard Kl?tzer 《Physics and Chemistry of Minerals》2012,39(1):47-55
Heat-treatment and stepwise cooling of as-delivered, water-containing quartz-type GeO2 powder resulted in transformation into a water-free form. A rutile-type modification could be prepared by impregnation of
the quartz-type phase with RbOH solutions, drying and annealing. Raman- and FTIR-absorption spectra of quartz- and rutile-type
GeO2 were measured and compared to quantum-mechanical ab initio calculations based on a hybrid functional using the Perdew–Burke–Ernzerhof
correlation functional with 16.7% Hartree–Fock exchange density functional. Maximum and mean deviations between measured spectral
bands and assigned vibrational modes are 14 and ±8 cm−1 for the quartz-type and 30 and ±13 cm−1 for the rutile-type polymorphic form. Water is incorporated into GeO4 entities of quartz-type GeO2; a water-free and structurally stable form can be prepared by a heating up to 1,425 K, tempering at 1,323 K and stepwise
cooling. Spectral bands not explained by the calculations suggest defects and distortions in both quartz- and rutile-type
structures, in case of the quartz-type one by incomplete transformation into an ideal structure after removing the water,
whereas the rutile-type modification most probably incorporates Rb during its synthesis. 相似文献
5.
Jijin Yang Joseph I. Goldstein Edward R.D. Scott 《Geochimica et cosmochimica acta》2010,74(15):4471-4492
We have determined metallographic cooling rates below 975 K for eight main group (MG) pallasites from Ni profiles across taenite lamellae of known crystallographic orientation in metallic regions with Widmanstätten patterns. Comparison with profiles generated by modeling kamacite growth gave cooling rates ranging from 2.5 to 18 K/Myr. Relative cooling rates were also inferred from the sizes of cloudy zone particles in 28 MG pallasites (86-170 nm) and tetrataenite bandwidths in 20 MG pallasites (1050-2170 nm), as these parameters are positively correlated with each other and negatively correlated with the metallographic cooling rates. These three different techniques show that MG pallasites cooled below 975 K at significantly diverse rates. Since samples from the core-mantle boundary should have indistinguishable cooling rates, MG pallasites could not have cooled at this location. Group IIIAB irons, which were previously thought to be core samples from the MG pallasite body, have faster cooling rates (∼50-350 K/Myr) and smaller cloudy zone particle sizes and tetrataenite bandwidths. This shows that IIIAB irons cooled faster than MG pallasites and could not plausibly be from the same body. The absence of related iron meteorites and achondrites and our thermal constraints suggest that MG pallasites cooled at diverse depths in a pallasitic body consisting of well-mixed olivine and metallic Fe-Ni. Such a body may have formed during an impact on a differentiated asteroid or protoplanet that mixed olivine mantle fragments with residual Ir-poor molten metal from the outermost part of a core that chemically resembled the IIIAB core and was ∼80% fractionally crystallized. Separation of the solid core and most of the associated mantle may have resulted from a grazing hit-and-run impact with a larger protoplanet or asteroid. Thermal calculations suggest that the radius of the pallasitic body was 400 km but the likely presence of a regolith would reduce this estimate considerably. 相似文献
6.
Thermal Stability of Assemblages in the Cu--Fe--S System 总被引：1，自引：0，他引：1
The phase relations in the Cu-Fe-S system were determined from700 C to approximately 200 C in most portions of the systemand below 100 C in restricted areas. Approximate solid solutionlimits for bornite, chalcopyrite, and pyrrhotite were determinedat elevated temperatures. At low temperatures emphasis was placedon establishing the stable assemblages and less on determiningthe compositions of coexisting phases. At 700 C two extensiveternary solid solutions dominate the phase relations in thissystem. One of these solid solutions (bornite) includes thecompositions Cu2S, Cu18S, and Cu5FeS4and the other (chalcopyrite)lies with in the area bounded by the compositions CuFeS2 CuFe2S3,and CU3Fe4S4. The two fields are separated by approximately10 weight per cent copper at 700 C. The chalcopyrite volume,as seen in a trigonal prism representing temperature and composition,is intersected by a miscibility gap below approximately 600C.Below this temperature the two one-phase volumes are referredto as chalcopyrite and cubanite. Chalcopyrite is tetragonalat low temperature but isometric above approximately 550C.The temperature of the transformation is a function of composition.Cubanite is isometric above 252C, tetragonal from 252 to atleast 213C, and orthorhombic at lower temperature. The temperatureof the second transformation is unknown because the tetragonal-to-orthorhombictransformation has not been achieved in the laboratory. Borniteand pyrite become stable together at 568C and coexist downto 228C. Covellite appears with lowering temperature at 507C,and idaite at 501C. Idaite—pyrite and idaite—borniteare stable assemblages below 501 C. The composition of bornitecoexisting with idaite changes gradually towards digenite withdecreasing temperature, thus permitting the change from thebornite—pyrite tie-line to the digenite—chalcopyritetie-line at 228C. Other major tie-line changes are bornite—ironto pyrrhotite—copper below 475C and cubanite—pyriteto chalcopyrite—pyrrhotite below 334C. A new syntheticphase, x-bornite, which has a composition close to bornite (Cu5FeS4)but contains about 04 weight per cent more sulfur, forms whensulfur-rich bornite synthesized at high temperature is annealedbetween 62 and 140C. Optically this new phase is very similarto bornite, and their X-ray powder diffraction patterns aregiven for comparison. o The determined phase relations are applicable to numerous deposits.The tie-line changes involving bornitepyrite reacting to producedigenitechalcopyrite below 228 C and cubanite (isometric)pyritegoing to chalcopyritepyrrhotite below 334 C are of considerablegeological interest. The rates of these reactions are sufficientlyslow to allow the higher temperature assemblages to be observedin some ores. The cubic—tetragonal inversion in chalcopyriteis often deduced in ores by inversion twins. However, twinningis also commonly produced through deformation. Geological applicationof the inversion therefore depends on correct interpretationof the twinning. Because of the considerable solubility of copperin pyrrhotite the pyrrhotite—pyrite solvus of the pureFe—S system cannot be applied indiscriminately to oresthat also contain chalcopyrite or cubanite, or both. The newx-bornite phase was identified with the natural ‘anomalousbornites’, which when heated exsolve chalcopyrite and,depending on their composition, also digenite. The experimental results indicate that the mineral commonlyidentified as chalcopyrrhotite is in reality tetragonal or evenisometric cubanite. Experimental evidence could not be obtainedfor the existence of a phase of Cu2Fe4S7 or Cu2Fe4S7 composition,the older formulae given foor valleriite. The thermal breakdownof natural material supports the idea that valleriite is a low-temperaturepolymorph of chalcopyrite. The relatively uncommon occurrenceof idaite in comparison to covellite is attributed to the greaterdifficulty in nucleating idaite. The possibility of stable coexistenceof chalcocite and pyrite was investigated but was found to beprohibited by tie-lines between bornite and digenite even aslow as 100 C. 相似文献
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8.
A simple and efficient method for the solution of uncoupled transient thermoelastic problems using boundary integral techniques is presented. The method employs a Laplace transformation to remove temporarily the time dependence of the governing equations. Numerical analysis is then carried out in the transform space, and results in the time-position space are found by numerical inversion of the Laplace transform. The method has the advantage that it avoids time-stepping and the costly evaluation of domain integrals. Boundary element and analytic solutions are compared, and the effect of cooling on the stresses around a deep underground opening is examined. 相似文献
9.
E. L. Gromnitskaya O. F. Yagafarov A. G. Lyapin V. V. Brazhkin I. G. Wood M. G. Tucker A. D. Fortes 《Physics and Chemistry of Minerals》2013,40(3):271-285
We present an ultrasonic and neutron powder diffraction study of crystalline MgSO4·7H2O (synthetic epsomite) and MgSO4·7D2O under pressure up to ~3 GPa near room temperature and up to ~2 GPa at lower temperatures. Both methods provide complementary data on the phase transitions and elasticity of magnesium sulphate heptahydrate, where protonated and deuterated counterparts exhibit very similar behaviour and properties. Under compression in the declared pressure intervals, we observed three different sequences of phase transitions: between 280 and 295 K, phase transitions occurred at approximately 1.4, 1.6, and 2.5 GPa; between 240 and 280 K, only a single phase transition occurred; below 240 K, there were no phase transformations. Overall, we have identified four new phase fields at high pressure, in addition to that of the room-pressure orthorhombic structure. Of these, we present neutron powder diffraction data obtained in situ in the three phase fields observed near room temperature. We present evidence that these high-pressure phase fields correspond to regions where MgSO4·7H2O decomposes to a lower hydrate by exsolving water. Upon cooling to liquid nitrogen temperatures, the ratio of shear modulus G to bulk modulus B increases and we observe elastic softening of both moduli with pressure, which may be a precursor to pressure-induced amorphization. These observations may have important consequences for modelling the interiors of icy planetary bodies in which hydrated sulphates are important rock-forming minerals, such as the large icy moons of Jupiter, influencing their internal structure, dynamics, and potential for supporting life. 相似文献
10.
通过差热-热重分析、X射线粉末衍射（XRD）及磁化率分析等手段,对天然黄铁矿样品在氮气中受热发生的矿物相 变过程进行了综合研究。不同温度下黄铁矿煅烧产物的XRD物相分析结果显示,低于500℃时,黄铁矿无显著变化;随着 温度的升高（500~600℃）,黄铁矿开始转变为单斜磁黄铁矿,进而生成六方磁黄铁矿,磁化率显著升高;700℃~800℃的 煅烧产物主要为六方磁黄铁矿,磁化率明显下降,直至900℃进一步形成更稳定的陨硫铁（FeS）,磁化率接近于零。在黄 铁矿物相开始转变的温度（500~600℃）区间,黄铁矿生成单斜磁黄铁矿的速率大于单斜磁黄铁矿转化为六方磁黄铁矿的速 率;高温（700~900℃）时,黄铁矿转化为单斜磁黄铁矿的速率低于单斜磁黄铁矿转化为六方磁黄铁矿的速率,表现为黄铁 矿直接生成六方磁黄铁矿。 相似文献
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The dehydration process of the natural zeolite laumontite Ca4Si16Al8O48 · 18 H2O has been studied in situ by means of powder diffraction and X-ray synchrotron radiation. Powder diffraction profiles suitable for Rietveld refinements were accumulated in time intervals of 5 minutes using a position sensitive detector (CPS-120 by INEL), while the temperature increased in steps of about 5 K. The synchronization of accumulation time and temperature plateau allowed collection of 62 temperature-resolved powder patterns in the range 310–584 K, whose analysis produced a dynamic picture of the laumontite structure response to dehydration. The first zeolitic water molecules diffusing out of the channels are those not bonded to the Ca cations and located in the W(1) site, whose occupancy drops smoothly to 10% during heating to 349 K, while the sample in the capillary is still submerged in water. The remaining W(1) and 60% of W(5) water molecules are expelled rather sharply at about 370 K. At this temperature all remaining water submerging the powder crystallites is lost, the structure contains about 13 water molecules/cell, and the crystal structure is that of leonhardite. On continued heating 80% of the water molecules from the W(2) site are lost between 420 and 480 K, while a small amount of the diffusing water is reinserted in the W(5) site. The occupancy factor of the W(8) site decreases starting at 480 K, and reaches a maximum loss of 20% at 584 K. The combined occupancy of the Ca-coordinated W (2) and W (8) water sites never falls much below two, so that the Ca cations in the channels, which are bonded to four framework oxygen atoms, are nearly six-coordinated in the explored temperature range. The water loss is accompanied by large changes in the unit cell dimensions. Except at 367 K, where the excess surrounding water is leaving, all changes in cell dimensions are gradual. The loss of the hydrogen bonded W(1) and W(5) water molecules is related to most of the unit cell volume reduction below 370 K, as shown by the contraction of the a-, b- and c-axes and the increase in the monoclinic angle. Loss of the Ca-coordinated W(2) and W(8) water molecules has a small effect on the unit cell volume as the continued contraction of the a- and c-axes is counter-balanced by a large expansion in the b-axis and a decrease in the monoclinic β angle. 相似文献
14.
The 1986 lethal eruption of Lake Nyos (Cameroon) was caused by a sudden inversion between deep, CO2-loaded bottom lake waters and denser, gas-free surface waters. A deep CO2 source has been found in fluid inclusions which occur predominantly in clinopyroxenes from lherzolitic mantle xenoliths, brought to the surface by the last erupted alkali basalts. P–T conditions of CO2 trapping correspond to a gas density equal (or higher) than that of liquid water. It is suggested that this dense CO2, found in many ultrabasic mantle xenoliths worldwide, has accumulated at km depth, below a column of descending lake water. It may remain in a stable state for a long period, as long as the temperature is above the density inversion temperature for pure H2O/CO2 systems. At an estimated depth of about 3 km, cooling by descending waters (to about 30 °C) induces a density inversion for the upper part of the CO2 reservoir. This causes a constant, regular upstream of low-density CO2 which, in its turn, feeds the shallower lake density inversion. 相似文献
15.
松辽盆地十屋—德惠含气带反转构造分析 总被引：4，自引：0，他引：4
摘 要 松辽盆地十屋—德惠含气带自早白垩世以来经历了裂谷期末和坳陷期末两期构造正
反转形成了众多反转构造主要有6种构造样式和两种组合类型。分析认为本带反转构造
的形成演化机制有滑脱褶皱和断弯褶皱两种。文章分析了主要反转构造的反转强度探讨了
反转构造与油气的关系。 相似文献
16.
G. V. Novikov V. K. Egorov V. I. Popov L. V. Sipavina 《Physics and Chemistry of Minerals》1977,1(1):1-14
Iron-rich pyrrhotites proved to be metastable and to decompose at 70–140° C to troilite and pyrrhotite with less iron content as shown by nuclear gamma-resonance (Mössbauer) studies at high temperatures. Coherence of decomposition product lattices was established by studying powder samples textured in a magnetic field. Detailed X-ray powder diffraction and Mössbauer investigations revealed two different mechanisms of transformation in metastable associations. Kinetic phenomena are discussed in terms of a thermodynamic model of two-phase assemblage. 相似文献
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利用非线性共轭梯度反演方法,对采集到的近正交的两条音频大地电磁剖面数据构成的主阻抗数据集进行三维反演。结果显示,山西省河津市地下结构呈现较明显的三层构造特征,推测第一层高阻异常是侵入岩或变质片麻岩,第二层低阻异常是铁矿富存区,高阻的第三层异常反映研究区的花岗闪长岩基底。根据地球物理电性参数资料,铁矿体为低阻,电阻率<10Ω·m。因此,推测10Ω·m的电阻率等值面大致勾勒出大地电磁反演结果推测的铁矿的成矿有利区。在两条剖面正交位置下方,矿体规模较小;但在2号线60-100号点和3号线476-492号点的下方1 km深的位置附近发现了新矿体。结果表明,利用大地电磁法寻找类似热液型铁矿这类局部异常体,三维反演是获得可靠结果的必要技术手段;即使是剖面性观测数据,也可以进行三维反演,并取得良好效果。 相似文献
19.
Takumi Yoshida Tomoki Taguchi Hayato Ueda Kenji Horie M. Satish‐Kumar 《Journal of Metamorphic Geology》2021,39(1):77-100
We report two new eclogite localities (at Kanayamadani and Shinadani) in the high‐P (HP) metamorphic rocks of the Omi area in the western most region of Niigata Prefecture, Japan, which form part of the Hida Gaien Belt, and determine metamorphic conditions and pressure–temperature (P–T) paths. The metamorphic evolution of the eclogites is characterized by a tight hairpin‐shaped P–T path from prograde epidote–blueschist facies to peak eclogite facies and then retrograde blueschist facies. The prograde metamorphic stage is characterized by various amphibole (winchite, barroisite, glaucophane) inclusions in garnet, whereas the peak eclogite facies assemblage is characterized by omphacite, garnet, phengite and rutile. Peak P–T conditions of the eclogites were estimated to be ~600°C and up to 2.0 GPa by conventional cation‐exchange thermobarometry, Ti‐in‐zircon thermometry and quartz inclusion Raman barometry respectively. However, the Raman spectra of carbonaceous material thermometry of metapelites associated with the eclogites gave lower peak temperatures, possibly due to metamorphism at different conditions before being brought together during exhumation. The blueschist facies overprint following the peak of metamorphism is recognized by the abundance of glaucophane in the matrix. Zircon grains in blueschist facies metasedimentary samples from two localities adjacent to the eclogites have distinct oscillatory‐zoned cores and overgrowth rims. Laser ablation inductively coupled plasma mass spectrometry U–Pb ages of the detrital cores yield a wide range between 3,200 and 400 Ma, with a peak at 600–400 Ma. In the early Palaeozoic, proto‐Japan was located along the continental margin of the South China craton, providing the source of the older population of detrital zircon grains (3,200–600 Ma) deposited in the trench‐fill sediments. In addition, subduction‐related magmatism c. 500–400 Ma is recorded in the crust below proto‐Japan, which might have been the source for the younger detrital zircon grains. The peak metamorphic age was constrained by SHRIMP dating of the overgrowth rims, yielding Tournaisian ages of 347 ± 4 Ma, suggesting subduction in the early Carboniferous. Our results provide clear constraints on the initiation of subduction, accretion and the development of an arc‐trench system along the active continental margin of the South China craton and help to unravel the Palaeozoic tectonic history of proto‐Japan. 相似文献
20.
Antiphase domains (APD's) of pigeonite lamellae in natural and heated augite crystals from the Hakonetoge andesite have been examined by a transmission electron microscope (TEM). Antiphase boundaries (APB's) of the pigeonite lamellae in natural specimens have a sigmoidal shape cutting the c axis in (010) sections. APB's in specimens heated at temperatures above the high-low inversion and then quenched are nearly parallel to the c axis with almost straight boundaries. These observations indicate that the preferred orientation of APB's in (010) sections depends on cooling rate; at fast colling rates the APB's are nearly parallel to the c axis, whereas at slower cooling rates they are inclined to the c axis. The cooling rate of the natural augite specimen from Hakonetoge is estimated to be about 0.01 °C/h from the experimentally determined time-temperature-transformation (TTT) diagram for the APB orientations. APD sizes are large in specimens quenched from above the inversion temperature; they are at a minimum after cooling rates of around 1–0.1 °C/h, and then become larger with slower cooling rates. 相似文献