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1.
长坑矿田金,银矿床地球化学特征及形成差异分析   总被引:10,自引:0,他引:10  
梁华英 《地质论评》1998,44(2):194-199
长坑矿田金、银矿体主要产于下石炭统与上三叠统不整合面之下的硅质岩中,金、银矿体分离。金矿体主要为浸染状,富集As、Sb、Hg;银矿体主要为脉状,富集Cu、Pb、Zn。金矿体铅同位素组成与寒武纪—石炭纪地层及硅质岩的相同,银矿体铅同位素组成与金矿体的不同。金、银矿体的氢、氧、碳同位素组成也明显不同。银矿体Rb-Sr等时线年龄为70.4Ma。据上述特征,笔者认为长坑金、银矿床是不同成矿作用形成的,金矿主要是热水沉积形成,银矿主要是燕山期晚期改造形成。  相似文献   

2.
Mapping of the oxygen and carbon isotopic composition of hydrothermally altered wall rocks was conducted during blind ore prospecting for Pb---Zn skarn deposits in the Kamioka mining district, central Japan. The wall rocks consist of heterogeneous rock units. Oxygen and carbon isotope ratios were determined for 35 limestones and 33 silicate rocks from the area around the Mozumi deposit (3 km × 3 km) in the Kamioka mining district. The results (δ18Ospsmow of − 1.1 to + 17.3% and δ13Csppdb of − 5.0 to +4.8% for limestones, and δ18Ospsmow of −0.8 to + 12.5% for silicate rocks) show isotope zonations of the wall rocks, with lighter isotopic compositions toward the center of mineralization. The isotope zonations likely formed by interaction of thermal waters with the wall rocks during skarn mineralization. The isotopically light zone indicates a higher paleotemperature or higher water-to-rock ratios, and occurs in the footwall of the 7Gohi fault. This structure is spatially related to the distribution of orebodies, indicating that the fault was the main conduit of the ore-forming fluids. The oxygen and carbon isotopic compositions of limestones vary regularly across limestone bodies hosted by the silicate wall rocks, suggesting that the thermal waters were pervasive throughout the wall rocks at the time of mineralization.An isotopically light zone was also found in the southeastern corner of the study area, where significant mineralization had yet to be identified. This suggested an extension of the extinct hydrothermal system to this area, and the possibility of hidden orebodies underneath. Recent drilling in this area has intercepted a zone 45 m thick with a grade of 13.4% Zn, 0.03% Pb and 8 g per metric ton at about 380 m depth.  相似文献   

3.
利用碳氧同位素组成可以很好地判别其形成的沉积环境.以内蒙古大井矿床为例,对该矿床16个菱铁矿样品进行碳、氧同位素分析,δ13CPDB变化范围为-1.8‰~-6.6‰,δ18OVPDB变化范围为-23.1‰~-17.3‰.根据矿物δ13C与δ18O值投影到δ13C-δ18O图解中,样品数据在图中的投点落入热水沉积区,说明其形成过程中具有热水沉积作用的发生.古温度可以通过T=16.998-4.52(δ18cO-δ18wO)+0.03(δ18cO-δ18wO)2计算,其形成时的温度平均值为117℃,比海底和湖底的温度要高得多,主要原因在于热水流体参与成矿.碳酸盐的成矿环境可以通过公式Z=2.048(δ13C+50)+0.498(δ18O+50)计算:Z值大于120,表示成矿环境为海水;如果Z值小于120,表示成矿环境为淡水或湖水.内蒙古大井矿床菱铁矿的Z值为100~114,结合区域地质背景,大井矿床形成的古环境为深水湖泊环境.通过对碳氧同位素的分析,结合成矿地质背景、矿床地质特征以及微量元素组成,认为在大井矿床成矿的早期阶段曾经发生过热液沉积作用,本次研究不仅有利于全面理解和认识大井矿床成矿过程的全貌,而且有益于对古湖相环境热液事件的探索.  相似文献   

4.
老厂矿床是昌宁-孟连缝合带内唯一大型矿床,本文报道了老厂矿床Ag-Pb-Zn矿体中Ⅰ号矿体群下部块状矿体和上部网脉状矿体的方解石C-O同位素组成,以及Ⅰ、Ⅱ、Ⅳ三个矿体群内闪锌矿的Zn同位素组成。Ⅰ号矿体群下部块状矿体和上部网脉状矿体方解石δ13CPDB的范围分别为-6.17‰~2.71‰和-2.18‰~3.87‰,δ18OPDB的范围分别为-19.57‰~-17.23‰和-22.10‰~-16.21‰;计算获得对应成矿流体的δ13CCO2为-6.16‰~1.53‰和-2.39‰~6.43‰,δ18OH2O分别为1.62‰~7.62‰和4.36‰~16.92‰,通过与岩浆CO213C=-2‰~-8‰)和围岩灰岩(δ13C=-1.6‰~4.0‰)的δ13C值相比较,指示块状矿体成矿流体中的碳主要来自岩浆,网脉状矿体成矿流体中...  相似文献   

5.
Abstract: The origin of mineralizing fluids responsible for the Hishikari vein-type epithermal Au deposits was studied on the basis of the hydrogen isotopic ratio (δD) of the inclusion fluid from vein quartz and adularia. The origin of hydrothermal fluids was estimated by combination of the present δ values and the oxygen isotopic ratios (δ18O) previously reported by Shikazono and Nagayama (1993). The water in the fluid inclusions was extracted by means of decrepitation of quartz at 500°C. Hydrogen was obtained by reduction of the collected water with Zn shot at 450°C. The δD values were determined by mass spectrometer. The δD values of inclusion fluid obtained from quartz range from –61 to –114%. These are significantly lower than the δD value of the thermal water presently venting from the Hishikari deposits and that of local meteoric water. Hydrogen isotopic fractionation between water and amorphous silica, which might have initially precipitated from the hydrothermal fluids at least partly, is not a probable cause of this isotopic depletion, while some water might have been released from the initial hydrous amorphous silica during recrystallization to quartz observed presently. Thus, a part of ore fluids for the Hishikari deposits is supposed to have been originated from the water having anomalous δD values of lower than –100%. Such D depletion cannot be caused by simple oxygen-shift of meteoric water or by contribution of magmatic volatiles. The δD values of water released from the shale samples of the Shimanto–Supergroup, a major host to the Hishikari veins range from –132 to –148%. Therefore, the anomalous δD values of inclusion fluids from some vein quartz and adularia suggest that the water released from hydrous minerals of the sedimentary basement rocks by dehydration or the groundwater isotopically exchanged with sedimentary rocks at elevated temperatures during circulation, partly contributed to the hydrothermal fluids responsible for the Hishikari deposits.  相似文献   

6.
吐哈盆地西南缘砂岩型铀矿地质地球化学基本特征   总被引:10,自引:0,他引:10  
文章通过对含矿目的层及其渗透性的分析、与成矿作用有关的常量和微量元素及部分特征性地球化学指标如有机碳含量、全硫含量、三价铁和二价铁比值的分析,以及流体包裹体成分和物理化学参数的测试,配合铀、铅、碳、氧、硫同位素的分析等方法,综合分析研究区内砂岩型铀矿的地质地球化学基本特征,认为:吐哈盆地西南缘砂泥岩互层地层结构完整且延伸稳定,属弱渗透一渗透性地层,对砂岩型铀矿成矿比较有利。据常量和微量元素分析,认为铀成矿存在着明显的地球化学分带性,其中,氧化带以有机碳和全硫(∑s)含量低、Th/u和Fe2O3/FeO及Ra/U比值高为特征;过渡带(成矿带)以Th/U比值低、∑S、Mo、Re含量高为特征;还原带则以明显的低Fe2O3/FeO、Ra/U比值,高有机碳含量为其特征。其他微量元素如Cu、Pb、Zn、Cr、Co、Ni、zr等及稀土元素在成矿过程中并未得到明显富集。经对相关岩石的铀.镭平衡、气液包裹体及相关同位素的研究,认为铀成矿具有多期次、年代新且集中于第三纪的特点;含矿目的层煤成气提供了成矿所需的还原环境;成矿作用铀源主要来自于含矿目的层本身;铀成矿古流体属低温浅成热液且主要来源于大气降水。  相似文献   

7.
隗合明 《矿床地质》1991,10(4):300-312
秦岭凤太矿田的所有铅锌(铜)矿床中都含有大量的氧化硅,前人资料中往往以沉积或蚀变单一形成方式论其成因,非此即彼。本文提出氧化硅有三种产出类型,以同生沉积型为主,其次为成岩后生阶段交代灰岩者,第三类为造山期形成的脉体。三类氧化硅的产出特征有许多不同,但硅质来源一致,即均来自深部地层和岩石中循环的含矿热液。对矿床中氧化硅的研究不仅有助于深入探讨矿床的成因,而且对于该类矿床的勘查有较重要的意义。  相似文献   

8.
东北寨金矿床是我国迄今为止发现的规模最大的浅成热液形成的微细浸染型金矿床。对矿床的同位素组成的研究表明,成矿溶液主要来自大气降水,矿化和蚀变作用是在水/岩比值较低的体系中进行的;硫来自围岩中的还原硫;碳酸盐岩地层是提供金属组分的主源层。地下热液在环流过程中,从围岩中萃取金属矿质,并迁移到黑色岩系地层的破碎带中成矿。  相似文献   

9.
文章系统研究了老厂矿床的碳酸盐围岩和成矿方解石的碳、氧同位素组成.研究表明,相对于区域地层,矿区碳酸盐岩围岩普遍亏损18O;成矿方解石的碳氧同位素总体上具有明显的正相关性,这些特征表明成矿流体与围岩发生了大规模的水岩反应.文章初步建立了水岩反应的理想模式,根据该模式进一步将成矿方解石划分为矿体中心相和边缘相2组.水岩反应理论模拟表明:总体上成矿流体中的可溶性碳以H2CO3为主,中心相成矿流体的δ13C、δ18O值分别为-5.5‰和+4‰,具有典型深部岩浆流体的特征;边缘相成矿流体的δ13C、δ18O值分别为-1.5‰和+4‰,代表了深部岩浆流体与下渗天水共同交代碳酸盐岩围岩后的碳、氧同位素特征.  相似文献   

10.
内蒙古甲乌拉大型Pb-Zn-Ag矿床稳定同位素地球化学研究   总被引:2,自引:0,他引:2  
内蒙古甲乌拉银多金属矿床位于大兴安岭成矿带北段,为近年来发现的大型银铅锌多金属矿床。矿床矿体分布完全受到断裂构造的控制,金属矿物组成主要为方铅矿、闪锌矿、黄铜矿、黄铁矿、磁黄铁矿、毒砂、辉钼矿及磁铁矿等。文中重点分析了矿床的硫、氢、氧、碳和铅稳定同位素地球化学特征。研究结果表明:金属硫化物δ34S集中为1.37‰~4.10‰,平均为3.10‰(n=13),极差为2.73‰;石英和方解石δ18Owater的变化范围较大(-18.96‰~+1.08‰) (n=9),均值为-11.36‰;δDV SMOW的变化范围比较集中(-133.6‰~-103.4‰) (n=9);27件样品的铅同位素组成为:206Pb/204Pb=18.228 3~18.758 7、207Pb/204Pb=15.457~15.880和208Pb/204Pb=37.841~39.049,矿床的铅组成基本为正常的放射性成因铅;方解石δ13CV PDB变化范围为-5.2‰~-8.4‰,平均为-6.8‰(n=2)。矿石硫化物的硫同位素及方解石的碳同位素均指示成矿物质可能来源于深部的岩浆活动;石英和方解石的氢氧同位素组成表明成矿流体早期以岩浆流体为主,成矿晚期加入了大量加热补给的大气降水;铅同位素组成表明成矿流体中铅的来源主要为幔源,矿床形成过程中混入少量的壳源铅。矿床稳定同位素组成显示成矿流体主要来源于深部的岩浆热液,特别与燕山晚期的火山次火山热液有较为密切的联系,在流体演化过程中大气降水的加入对矿床成矿元素的聚集和沉淀也起到有利作用。成矿作用的发生是在一种总硫浓度比较低、中等氧化环境、相对开放的非平衡体系中进行的。矿床形成的地球动力学背景为一种岩石圈大规模快速减薄的过程。甲乌拉大型Pb Zn Ag矿床的成因类型属于火山次火山热液脉状银多金属矿床。  相似文献   

11.
湘中锡矿山锑矿床的Sr同位素地球化学   总被引:21,自引:3,他引:21  
对湘中锡矿山锑矿床围岩灰岩、硅化灰岩、煌斑岩和脉石矿物进行了系统的Sr同位素研究。结果表明,矿区围岩发生了隐性蚀变,灰岩中Sr亏损,而^87Sr/^86Sr高于同时代的海相碳酸盐,这种隐性蚀变很可能是水/岩反应所致。矿体附近的硅化灰岩中Sr更加亏损,而^87Sr/^86Sr明显增加。成矿期方解石的^87Sr/^86Sr较高,成矿体系中变化的W/R比造成了方解石中^87Sr/^86Sr值的明显波动。成矿流体为一富放射成因^87Sr的溶液。成矿流体来自或流经基底地层,流体中的Sr由基底碎屑岩提供,矿质Sb也可能主要来自富Sb的元古宇基底。水/岩反应的理论模拟显示,锡矿山成矿流体中的Sr约为3.0μg/g,^87Sr/^86Sr为0.717;蚀变-成矿体系为一开放体系,矿石的沉淀机制主要为水/岩反应,成矿体系中W/R 比较高。  相似文献   

12.
对栗木水溪庙矿区泥盆系上统融县组灰岩的碳氧同位素进行了研究,该地区灰岩的碳氧同位素组成可提供隐伏花岗岩隆起及其相关流体的重要信息。受隐伏花岗岩侵入驱动的流体与上覆融县组灰岩发生反应的温度在110℃左右,流体的初始同位素组成为δ18OSMOW=-3‰,δ13CPDB≤-7‰,反应的水岩比值(w/r)可能小于5。这种岩浆水与大气降水的混合流体与围岩之间的水岩反应使得地表灰岩的δ18O和δ13C值降低,产生负异常。研究表明,围岩的δ18O值降低受反应的水岩比值和温度控制;δ13C值降低主要与反应的水岩比值有关。反应的温度越高,w/r值越大,灰岩的碳氧同位素负异常越明显。因此,水溪庙矿区地表出露的碳酸盐地层中的碳氧同位素变化可在地球化学勘查中用于指示下伏花岗岩岩脊的隐伏位置。  相似文献   

13.
广东长排铀矿床成矿流体特征   总被引:1,自引:0,他引:1  
长排铀矿床位于广东长江铀矿田内,矿体主要赋存在北北西向硅化断裂带内及其两侧的蚀变花岗岩中。流体包裹体显微测温和激光拉曼光谱分析表明,成矿流体为中低温、中低盐度的含CO2、CH4和H2的流体。铀成矿期流体包裹体均一温度多集中于120~250 ℃,盐度为04%~102%。氢、氧同位素分析表明,成矿流体可能来源于深部,后期有大气降水的加入。成矿期方解石的δ13C值大多数集中于-91‰~-82‰,以深源碳为主。综合分析认为,长排铀矿床属于中低温热液脉型铀矿床。成矿流体经历了沸腾作用,使CO2等挥发分逃逸,这可能是长排铀矿床铀矿沉淀、富集的主要原因。  相似文献   

14.
Pyrometasomatic lead-zinc ore deposits of the Kamioka mine occur in the Hida metamorphic complex of central Japan. The pyrometasomatic ore deposition was followed by small scale hydrothermal ore deposition. Flaky graphite characteristically occurs in skarn, ores and in the surrounding crystalline limestone. 13C values of graphite in the skarn and the ores are close to those of graphites in the crystalline limestone. Graphite in the skarn and ores is considered to be remains of graphite in the crystalline limestone which was replaced by the skarn and the ores. At the pyrometasomatic stage, the oxygen fugacity of fluid would control the carbon isotopic composition of calcite precipitated. On the assumption that graphite played a role of oxygen buffer, the oxygen fugacity of the fluid was estimated to be from 10–31,4 to 10–301 bars at 350 °C and total pressure of 1,000 bars. The predominant carbon species in the fluid would be carbon dioxide. The 13C value of total carbon in fluid was estimated to be –3.6±1.7 (PDB) for the Tochibora and Maruyama deposits of the Kamioka mine, and the oxygen fugacity in the fluid was probably constant during the pyrometasomatic stage. It is likely that an important source of carbon was the carbon remained after the decarbonation of crystalline limestone. Oxygen isotopic studies on calcite of pyrometasomatic and hydrothermal stages revealed that meteoric water was an important source for most of the oxygen in fluid of both stages.  相似文献   

15.
保山镇康地块矽卡岩型铅锌矿床成因初探   总被引:4,自引:0,他引:4  
保山镇康地块是"三江"南段重要的铅锌多金属成矿区之一,地质构造复杂,铅锌成矿地质条件优越,其中核桃坪与芦子园是近年发现的两个大型铅锌矿床,矿床受近NE向断裂、背斜轴部和地层控制明显,上寒武统核桃坪组与沙河床组大理岩化灰岩为主要赋矿地层,近矿围岩矽卡岩化强烈,流体包裹体,Pb、S、H、O同位素和微量元素等地球化学对比研究表明:核桃坪和芦子园铅锌矿床均经历了中温、高温两个矿化阶段;核桃坪铅锌矿床矿石铅同位素较芦子园铅锌矿床有较高的比值和较大的变化范围,均以高μ值为特征,属于放射性成因铅,暗示其成矿物质以壳源铅为主;硫化物硫同位素均多为较低正值并呈塔式分布,具有岩浆硫特征,两者均无生物硫酸盐热化学还原作用的参与,其中硫同位素分馏已达平衡;与硫化物共生的石英δDH2O(-109‰~-91‰)和δ18OH2O(-4.3‰~2.3‰)同位素研究表明核桃坪矿床成矿流体主要来自深部岩浆水,并遭受后期大气降水或地层水的混合;核桃坪矿床与芦子园矿床的微量元素具有岩浆热液型矿床特征,不同于VMS型、MVT型铅锌矿床。因此,笔者认为两个矿床应属于与深部隐伏岩体有关的中-高温矽卡岩型铅锌矿床,矿区深部隐伏岩体的侵入产生岩浆热液并携带Pb、Zn等成矿物质与地层水或大气降水混合,在背斜轴部与NE向断裂的交汇处形成该类型矿床。  相似文献   

16.
兰坪盆地三类主要铜银多金属矿床的稳定同位素地球化学   总被引:6,自引:0,他引:6  
通过对兰坪盆地内三种主要成因类型(沉积-热液改造型、热水沉积-热液改造型和热液脉型)的铜银多金属矿床硫、碳、氢、氧同位素的研究,揭示了成矿作用过程的某些重要信息:矿石中的硫主要来自细菌还原的海水硫酸盐,但在沉积-热液改造型矿床中可能还有部分有机生物硫和深源火山硫的贡献;碳主要来自不同比值水/岩反应体系中碳酸盐岩地层的溶解结果,但在沉积-热液改造型矿床中还可能有深部地幔去气作用带来的CO2.成矿流体系以大气降水为主要补给源的盆地建造水,盆地建造水的运移成矿过程中可能伴有较为明显的蒸发作用.  相似文献   

17.
东天山康古尔金矿床成矿物源的同位素地球化学特征   总被引:5,自引:0,他引:5  
张连昌  姬金生 《现代地质》1998,12(3):380-387
康古尔金矿床属晚古生代火山岩区剪切带蚀变岩型金矿。同位素地球化学研究表明,矿石中铅为正常铅,热液系统硫同位素组成为陨石硫型,矿石中碳、钕同位素组成具深源特征,同时矿石与火山岩围岩中的Si、Sr、S、Pb等同位素组成相近,说明成矿物质主要来自矿体围岩———火山岩,晚期有少量来自矿区附近的侵入岩。铅、锶同位素组成反映成矿过程中也有少量壳源物质的加入。  相似文献   

18.
王允 《江苏地质》2020,44(3):265-270
荷花山大型铅锌矿位于长江中下游成矿带铜陵矿集区,是该矿集区内最新类型的典型矿床。矿区出露一套以砂页岩、硅质岩、灰岩为主的沉积岩地层,由F1断层、F2断层、褶皱和朱村断陷盆地以及热液共同作用,使早—中三叠世灰岩中发育构造溶解垮塌角砾岩,矿体赋存于其中。通过沉积成矿、热液成矿和岩浆作用等成矿规律的分析,认为荷花山地区具有良好的成矿地质前景,荷花山铅锌矿床受晚期岩浆热液的影响,铅锌进一步富集。荷花山铅锌矿床与沉积作用和热液作用关系较密切,岩体侵入对荷花山矿床进行了破坏和改造,并形成少量的闪锌矿和方铅矿。荷花山矿床位于铜陵矿集区内,其成矿规律与矿集区其他矿床的成矿规律相比既有共性又有特性,其独特的成矿规律丰富了铜陵矿集区的成矿理论。  相似文献   

19.
乌拉根铅锌矿床产出于塔里木盆地西北缘喀什凹陷中—新生界中,成矿地质条件优越,资源潜力可观,具有超大型矿床找矿远景,但其成因一直存在较大争议。本次对乌拉根铅锌矿进行了详细的S、Pb同位素研究,探讨了其成矿物质来源和矿床成因。测试分析结果表明,乌拉根铅锌矿床矿石δ34S值为-26.09‰~+15.0‰,具有较宽的分布范围,显示出轻硫与重硫同时富集的特征,指示乌拉根铅锌矿床S主要来自海相硫酸盐的还原。乌拉根铅锌矿的206Pb/204Pb值为17.771~18.6413,207Pb/204Pb值为15.402~15.6454,208Pb/204Pb值为37.92~38.7507,Pb同位素组成变化较小,且集中于造山带铅演化线附近,推测本矿区Pb可能来自区域内的古老地层。综合前人研究和本次S、Pb同位素分析结果,认为乌拉根铅锌矿床是在南天山和西昆仑山两大造山带相互逆冲推覆背景下,盆地流体大规模运移,在油气还原条件下形成的一类赋存于沉积岩中的铅锌矿床。  相似文献   

20.
The Dahutang tungsten polymetallic ore field is located north of the Nanling W-Sn polymetallic metallogenic belt and south of the Middle—Lower Yangtze River Valley Cu-Mo-Au-Fe porphyry-skarn belt.It is a newly discovered ore field,and probably represents the largest tungsten mineralization district in the world.The Shimensi deposit is one of the mineral deposits in the Dahutang ore field,and is associated with Yanshanian granites intruding into a Neoproterozoic granodiorite batholith.On the basis of geologic studies,this paper presents new petrographic,microthermometric,laser Raman spectroscopic and hydrogen and oxygen isotopic studies of fluid inclusions from the Shimensi deposit.The results show that there are three types of fluid inclusions in quartz from various mineralization stages:liquid-rich two-phase fluid inclusions,vapor-rich two-phase fluid inclusions,and three-phase fluid inclusions containing a solid crystal,with the vast majority being liquid-rich two-phase fluid inclusions.In addition,melt and melt-fluid inclusions were also found in quartz from pegmatoid bodies in the margin of the Yanshanian intrusion.The homogenization temperatures of liquid-rich two-phase fluid inclusions in quartz range from 162 to 363℃ and salinities are 0.5wt%-9.5wt%NaCI equivalent.From the early to late mineralization stages,with the decreasing of the homogenization temperature,the salinity also shows a decreasing trend.The ore-forming fluids can be approximated by a NaCl-H_2O fluid system,with small amounts of volatile components including CO_2,CH_4 and N_2,as suggested by Laser Raman spectroscopic analyses.The hydrogen and oxygen isotope data show that δ5D_(V-smow) values of bulk fluid inclusions in quartz from various mineralization stages vary from-63.8‰ to-108.4‰,and the δ~(18)O_(H2O) values calculated from the δ~(18)O_(V-)smow values of quartz vary from-2.28‰ to 7.21‰.These H-O isotopic data are interpreted to indicate that the ore-forming fluids are mainly composed of magmatic water in the early stage,and meteoric water was added and participated in mineralization in the late stage.Integrating the geological characteristics and analytical data,we propose that the ore-forming fluids of the Shimensi deposit were mainly derived from Yanshanian granitic magma,the evolution of which resulted in highly differentiated melt,as recorded by melt and melt-fluid inclusions in pegmatoid quartz,and high concentrations of metals in the fluids.Cooling of the ore-forming fluids and mixing with meteoric water may be the key factors that led to mineralization in the Dahutang tungsten polymetallic ore field.  相似文献   

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