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1.
This paper aims to identify the spatial distribution of exchangeable base cations in soils on an acid hillslope and to investigate possible cation release processes from slope soils to the stream. The basic assumption underlying this research is that the amount of exchangeable cations in soils reflects the nutrient stores and cation leaching processes across the slope where vegetation and parent materials are similar. The distribution of exchangeable Ca2+, Mg2+, K+ and Na+ has been investigated on a three-dimensional hillslope on the Quantock Hills, Somerset, UK. A two-way ANOVA shows that soil depth is predominant in explaining the total variance of exchangeable bases, despite the steep slope gradient and clear podzolic catena development. Major nutrient base cations, such as Ca2+, Mg2+ and K+, display homogeneous topsoil storage right across the slope. This spatial pattern may indicate that the spatial distribution of major nutrient cations is tightly controlled by the soil–vegetation system in nutrient-poor heathland environments. Na+ is an exception to this vegetation-controlled spatial distribution, because of its small involvement in the soil–vegetation and soil exchangeable systems. In subsurface soils, cations liberated from the soil–vegetation system are subject to redistribution over the slope according to the hydrological flowpaths operating on the slope, with some eventually released into the stream. The saturated wedge developed at the base of the slope plays a key role in the storage and release processes of base cations from slope soils to the stream. Ca2+, Mg2+ and Na+ carried by throughflow are stored in the saturated wedge and gradually released into the stream at times of high flow. K+, however, shows an apparently different spatial behaviour, being deficient in the saturated wedge. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

2.
Previous studies of the downslope movement of soil moisture have been largely confined to two-dimensional slope profiles—the influence of contour curvature (three-dimensional) on moisture movement has received little attention. An automatic tensiometer system has been used to monitor soil moisture status continuously in a single hollow and adjacent spurs. Maximum saturated hillslope flow is shown to coincide with the stream discharge ‘throughflow peak’. Relative to the hollow, little saturation is evident at the base of the spurs. This subcatchment model is applied to a major portion of the catchment, showing the general importance of topography in the control of stream discharge.  相似文献   

3.
Abstract

Throughflow has been measured from three soil horizons on a 12 slope with impermeable, bedrock. Storm flow comes from the 10–45 cm horizon and is controlled by the upslope extent of saturated conditions. Base flow comes from the 45–75 cm horizon and is supplied by slow unsaturated flow from the whole soil mass to a small constant zone of saturation.

Differences between input and output stream hydrographs over 270 metres of channel are attributed to throughflow and correlate well with measured values providing a basis for separating throughflow components from the stream hydrograph. Observed stream flows contain no overland flow or ground water flow components. The main basin flood peak is not generated within this control section of channel but is produced in the headwater zone (0.1 km2) by the faster runoff characteristics of the soils in that area and by topographic factors which lead to rapid channel extension.  相似文献   

4.
This paper considers the contributions of overland flow, throughflow and deep seepage to the generation of streamflow in a salt-affected, deeply weathered landscape. Runoff mechanisms on a small hillslope in south-western Australia were dependent on the extent and development of variable source areas. In winter, streamflow generation was controlled by returnflow, saturation overland flow and throughflow. In summer, post-ponding, infiltration-excess and saturation overland flow dominated. The extent of the variable source area and the magnitude of streamflow were due to antecedent soil moisture, rainfall and slope morphology. Concave hillslope sections accumulated soil moisture due to both saturated and unsaturated lateral flow processes. Throughflow provided the mechanism and vehicle for solute movement from the groundwater discharge area to the stream. However, discharge from the deep aquifer was the primary mechanism responsible for soil salinity and maintaining the core of the variable source area. Estimates of throughflow which only take account of soil-water movement and disregard returnflow, will underestimate the magnitude of throughflow.  相似文献   

5.
A small hillslope was chosen to investigate the role of throughflow as a mechanism responsible for the movement of soil water and solutes towards a saline seep and as a source of recharge to a permanent, regional aquifer at depth. The hydraulic properties, chemical characteristics and physical responses of both systems were studied on a deeply weathered, salt-affected hillslope. Additional data were also obtained from other sites in south-western Australia. Regional groundwater flow occurred in a variably textured, deeply weathered material in which the hydraulic conductivity varied from < 0·001 to 0·14m day?1. Perched groundwater flow (throughflow) occurred in the higher permeability (? 1·5 m day?1), near-surface soil materials. Throughflow occurred throughout winter, contributing approximately 530 m3 of fresh (? 160 mg l?1 Cl) water to a saline seep. By contrast, the deep aquifer discharged approximately 1100 m3 of waters with salt concentrations of 2000–6000 mg l?1 Cl. Recharge and discharge rates to and from the deep aquifer, were estimated to be of the order of 5–20 mm a?1 and 50–300 mm a?1 respectively. Saturated conditions existed throughout winter within the seep and the immediately adjacent non-saline area, with up to 60 per cent of the hillslope soils becoming saturated after major rainfall events ( > 20 mm day?1). In the mid-slopes, in particular along a central depression, saturation of the shallow soils caused macropore channel recharge to take place through the clay-textured subsoils. Water-level responses suggest that approximately 25–30 per cent of annual recharge occurred from one storm studied in September 1984. Recharge through macropore channels is a significant mechanism in the concave slope areas on the hillslope. Throughflow was found to be a major source of water, but not salt, contributing to the saline seep. In general, the contribution of throughflow was found to decrease further inland at other sites studied. However, at inland sites where perennial, perched aquifers have developed in deep sands, saline areas have been caused by throughflow and not by deep aquifer discharge.  相似文献   

6.
This study documented the spatial and temporal variability of outflow from a forested hillslope segment during snowmelt at a small mountain catchment in south coastal British Columbia, Canada. A pit 5 m wide was established just upslope from the stream channel. Outflow from the organic horizon was intercepted and measured by a single trough, and outflow from the mineral horizons was measured separately for three adjacent sections. Throughflow exhibited non‐steady‐state behaviour involving shifting allocations of flow amongst different sections of the outflow pit, as well as threshold effects and hysteresis in the relationship between pit outflow and water table elevation. Most of the pit outflow originated from the mineral horizons, indicating that throughflow was the dominant pathway by which water was delivered to the stream channel. Direct precipitation and snowmelt onto near‐stream saturated areas can account for less than 20% of the total outflow from the hillslope segment. Throughflow from the mineral sections consistently peaked either at the same time as or earlier than stream flow from the 150‐ha catchment during diurnal snowmelt cycles, indicating that throughflow appears to respond rapidly enough to contribute to snowmelt‐induced peak stream flow. Pit outflow cannot be extrapolated reliably to the catchment scale on the basis of simple length‐ or area‐based ratios. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

7.
The paper looks at the process of lateral translocation in a small valley basin from the Northaw Great Wood, Hertfordshire. The valley basin comprises four lithostratigraphic units (London Clay and Pebble Gravel, and the others a mixture of these two), which were initially established in the field by a rough assessment of texture. Particle size analysis validated the lithostratigraphic units as delineated in the field; it was found unnecessary to alter the boundaries of the units. Patterns of lateral translocation of silt and clay (measured by the hydrometer method) and the amorphous colloidal hydrous oxides and hydroxides of Al, Fe, Mn and Si (measured in oxalate solution by atomic absorption spectrophotometry) are inferred from balance sheets of the relative gains and losses of the materials. Materials from horizons formed in lithostratigraphic units derived from London Clay are balanced against a clay dilution factor; those from the lithostratigraphic unit of Pebble Gravel against the dilution of sand on a clay-free basis. The results lead to the following conclusions about the process of lateral translocation: it has been a significant contributor to soil development; larger amounts of material have moved down-slope towards the hollow than over the nose because there has, theoretically, been more throughflow in the hollow; for some materials there has been less down-slope transport in lower horizons owing to less throughflow in them.  相似文献   

8.
The distribution of soil 137Cs in relation to selected soil and landform properties was studied across a 16 ha hillslope hollow in the Hunter valley, New South Wales, Australia. The hillslope was used as grazing for cattle. Caesium-137 was not significantly related to the amount of sand, silt, or clay, the bulk density, the organic matter content, the slope angle or the relative distance downslope. However, 137Cs was significantly related to the thickness of the soil A horizon. Spatial variations in 137Cs were compared with topographic units and a six-element hillslope model, but there was little correspondence. It was thought that the effects of microtopography could have masked potential interrelationships between 137Cs and broader scale landform parameters.  相似文献   

9.
Measurements have been made of unsaturated and saturated lateral soil water flow on a convex hill-slope with a good soil cover and impermeable bedrock during natural rainstorms. The hydraulics of flow are examined in detail with particular reference to the role of breaks in vertical permeability, the change from saturated to unsaturated flow and the velocity of flow. In this instance, after rainfall slope flow is dominated by vertical unsaturated movement towards the profile base. Preceding upslope moisture gradients result in the growth of a zone of soil saturation upwards from the slope base. Slope discharge, through the B and B/C horizons, is related to the form of the saturation zone, within which flow is lateral, according to Darcy's law. The time required for vertical percolation and the low hydraulic conductivity of the lower soil horizons result in a hillslope hydrograph which is delayed and attenuated and cannot be regarded as stormflow. During drainage the saturation zone contracts and is replaced by a lateral unsaturated flow system at the profile base which supplies discharge from the B/C horizon for up to 42 days without further recharge. It is concluded that, in general, either distinct soil horizons or impermeable bedrock are essential for the initiation of lateral flow. Saturated flow is likely to dominate hillslope hydrographs through non-capillary pore spaces but these may be integrated to the point where Darcy's law still holds. Although lateral soil water flow must be a widespread phenomenon, it is unlikely to provide storm runoff to the stream unless saturated conditions are generated within the organic horizons for flow within the lower soil horizons is dominated by non-Darcian flow through non-capillary spaces in the soil.  相似文献   

10.
An integrated programme of hydrological monitoring at the 10 km2 Allt a' Mharcaidh catchment in north-east Scotland has been based on observations at plot, hillslope and catchment scale. The resonse of the principal soil types has been characterized from a combination of throughflow and three-dimensional tensiometer data at plot scale, and plot sequences have been used to investigate hillslope scale effects. Seep emergence is associated with downslope drainage and local topographic convergence; in parallel preferential pathways generate a highly dynamic throughflow response. Catchment and subcatchment hydrographs mirror the twin dynamic observed at hillslope scale, and a unified hypothesis of response is presented which is consistent with all scales of observations.  相似文献   

11.
Variation in solute concentrations of soil and stream water during throughflow events was studied at Bicknoller Combe, Somerset, England. The main hydrological process acting in the catchment involves a delayed throughflow discharge pulse a day or two after the rainfall event. During the period of storm runoff, coincident with the rainfall, the solutes in the stream are diluted, but their concentration in the throughflow remains unchanged. During the delayed throughflow pulse, concentrations of both soil and stream water increase. This is due to additional leaching from the soil in hollows where saturated moisture conditions prevail. The results suggest that two distinct erosional environments may exist: on the spurs, leaching seems to be related solely to infiltration processes, whilst in the hollows, saturated throughflow also contributes to the solute removal. This contrast in erosional processes may perhaps account for the difference in slope form and development between the hollow and spur zones.  相似文献   

12.
Concentrations of both aluminium (Al) and dissolved organic carbon (DOC) in stream waters are likely to be regulated by factors that influence water flowpaths and residence times, and by the nature of the soil horizons through which waters flow. In order to investigate landscape‐scale spatial patterns in streamwater Al and DOC, we sampled seven streams draining the Hubbard Brook valley in central New Hampshire. We observed considerable variation in stream chemistry both within and between headwater watersheds. Across the valley, concentrations of total monomeric aluminium (Alm) ranged from below detection limits (<0·7 µmol l−1) to 22·3 µmol l−1. In general, concentrations of Alm decreased as pH increased downslope. There was a strong relationship between organic monomeric aluminium (Alo) and DOC concentrations (R2 = 0·92). We observed the highest Alm concentrations in: (i) a watershed characterized by a steep narrow drainage basin and shallow soils and (ii) a watershed characterized by exceptionally deep forest floor soils and high concentrations of DOC. Forest floor depth and drainage area together explained much of the variation in ln Alm (R2 = 0·79; N = 45) and ln DOC (R2 = 0·87; N = 45). Linear regression models were moderately successful in predicting ln Alm and ln DOC in streams that were not included in model building. However, when back‐transformed, predicted DOC concentrations were as much as 72% adrift from observed DOC concentrations and Alm concentrations were up to 51% off. This geographic approach to modelling Al and DOC is useful for general prediction, but for more detailed predictions, process‐level biogeochemical models are required. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

13.
This study was designed to improve our understanding of, and mechanistically simulate, nitrate (NO3) dynamics in a steep 9.8 ha rural headwater catchment, including its production in soil and delivery to a stream via surface and subsurface processes. A two‐dimensional modelling approach was evaluated for (1) integrating these processes at a hillslope scale annually and within storms, (2) estimating denitrification, and (3) running virtual experiments to generate insights and hypotheses about using trees in streamside management zones (SMZs) to mitigate NO3 delivery to streams. Total flow was mathematically separated into quick‐ and slow‐flow components; the latter was routed through the HYDRUS software with a nitrogen module designed for constructed wetlands. Flow was monitored for two years. High surface‐soil NO3 concentrations started to be delivered to the stream via preferential subsurface flow within two days of the storm commencing. Groundwater NO3‐N concentrations decreased from 1.0 to less than 0.1 mg l?1 from up‐slope to down‐slope water tables, respectively, which was attributed to denitrification. Measurements were consistent with the flushing of NO3 mainly laterally from surface soil during and following each storm. The model accurately accounted for NO3 turnover, leading to the hypotheses that denitrification was a minor flux (<3 kg N ha?1) compared to uptake (98?127 kg N ha?1), and that SMZ trees would reduce denitrification if they lowered the water table. This research provides an example of the measurement and modelling of NO3 dynamics at a small‐catchment scale with high spatial and temporal resolution. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

14.
The transformation of snowmelt water chemical composition during melt, elution and runoff in an Arctic tundra basin is investigated. The chemistry of the water flowing along pathways from the surface of melting snow to the 95·5 ha basin outlet is related to relevant hydrological processes. In so doing, this paper offers physically based explanations for the transformation of major ion concentrations and loads of runoff water associated with snowmelt and rainfall along hydrological pathways to the stream outlet. Late‐lying snowdrifts were found to influence the ion chemistry in adjacent reaches of the stream channel greatly. As the initial pulse of ion‐rich melt water drained from the snowdrift and was conveyed through hillslope flowpaths, the concentrations of most ions increased, and the duration of the peak ionic pulse lengthened. Over the first 3 m of overland flow, the concentrations of all ions except for NO increased by one to two orders of magnitude, with the largest increase for K+, Ca2+ and Mg2+. This was roughly equivalent to the concentration increase that resulted from percolation of relatively dilute water through 0·25 m of unsaturated soil. The Na+ and Cl? were the dominant ions in snowmelt water, whereas Ca2+ and Mg2+ dominated the hillslope runoff. On slopes below a large melting snowdrift, ion concentrations of melt water flowing in the saturated layer of the soil were very similar to the relatively dilute concentrations found in surface runoff. However, once the snowdrift ablated, ion concentrations of subsurface flow increased above parent melt‐water concentrations. Three seasonally characteristic hydrochemical regimes were identified in a stream reach adjacent to late‐lying snowdrifts. In the first two stages, the water chemistry in the stream channel strongly resembled the hillslope drainage water. In the third stage, in‐stream geochemical processes, including the weathering/ion exchange of Ca2+ and Mg2+, were the main control of streamwater chemistry. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

15.
Jason A. Leach  Dan Moore 《水文研究》2017,31(18):3160-3177
Stream temperature controls a number of biological, chemical, and physical processes occurring in aquatic environments. Transient snow cover and advection associated with lateral throughflow inputs can have a dominant influence on stream thermal regimes for headwater catchments in the rain‐on‐snow zone. Most existing stream temperature models lack the ability to properly simulate these processes. We developed and evaluated a conceptual‐parametric catchment‐scale stream temperature model that includes the role of transient snow cover and lateral advection associated with throughflow. The model consists of routines for simulating canopy interception, snow accumulation and melt, hillslope throughflow runoff and temperature, and stream channel energy exchange processes. The model was used to predict discharge and stream temperature for a small forested headwater catchment near Vancouver, Canada, using long‐term (1963–2013) weather data to compute model forcing variables. The model was evaluated against 4 years of observed stream temperature. The model generally predicted daily mean stream temperature accurately (annual RMSE between 0.57 and 1.24 °C) although it overpredicted daily summer stream temperatures by up to 3 °C during extended low streamflow conditions. Model development and testing provided insights on the roles of advection associated with lateral throughflow, channel interception of snow, and surface–subsurface water interactions on stream thermal regimes. This study shows that a relatively simple but process‐based model can provide reasonable stream temperature predictions for forested headwater catchments located in the rain‐on‐snow zone.  相似文献   

16.
This study examined the spatial and temporal variability of throughflow in a shallow forest oil in terms of the controls exerted by topography, soil properties and the shape of the water table. Hillslope outflow was measured at nine troughs installed at a road cut, and hydraulic head was measured at 37 piezometers installed to the confining till surface at the base of the soil. At the lowest flows, the distribution of throughflow across the hillslope conformed reasonably to the distribution of upslope contributing area computed from the topography of the confining basal till layer. At higher flows, however, the distribution of throughflow shifted, partly as a result of changes in the orientation in flow tubes as the piezometric surface changed. At high flows, surface topography appeared to provide a reasonable proxy for the shape of the water table. Shunting of water through discrete macropores, however, can apparently overwhelm topographic controls on throughflow, at least for slope widths less than about 10 m. Effective hydraulic conductivities computed at the scale of the troughs varied over two orders of magnitude and displayed no consistent relationship with the thickness of the saturated layer. Estimates at the plot scale (c. 10 m hillslope width) were far less variable, and for higher flows displayed an approximately linear relationship with saturated zone thickness. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

17.
There is considerable interest in large‐scale spatial patterns of sediment transport in catchments, and this topic is often approached using terrain‐based modelling. In such models topography influences the discharge of overland flow and its sediment transport capacity. The sediment transport capacity of overland flow is commonly expressed as a power function of slope and discharge (i.e. qs=k1qβSγ). The relationship between discharge and contributing area can also be expressed as a power function. Several reviews reveal a limited range of values for the two exponents β and γ. In this paper we examine the sensitivity of catchment‐scale patterns of sediment delivery to valley floors to a range of sediment transport capacity and hillslope hydrology parameterizations, using two catchments on the southern tablelands of New South Wales. The results indicate that, over the limited range of β and γ identified within the literature, sediment deliveries to valley floors across the two catchments are similar for all but one of five sediment transport capacity relationships. The patterns are dominated by the trend in slope through each catchment. The sensitivity to hillslope hydrology of predicted sediment delivery patterns is strong in the catchment with systematic variation in unit hillslope area, and weak in the catchment for which there are no systematic trends in unit hillslope area. We believe there is less experimental evidence to restrict choice of hillslope hydrology parameters than there is for sediment transport capacity. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

18.
Simple, rapid, and sensitive spectrophotometric methods have been proposed for the determination of cationic surfactants (CS) as cetyltrimethylammonium bromide (CTAB), dodecyltrimethylammonium (DTAB), and cetylpyridinium bromide (CPB). The methods are based on the effects of CSs on the complexes of Al3+ and Be2+ with Chrome Azurol S (CAS). The optimum reaction conditions such as CAS concentration, metal ion concentration, and pH have been studied and found to be 2.0 × 10?4 mol L?1 CAS, 0.5 mg L?1 Al3+ or 0.4 mg L?1 Be2+ and pH 5.4. The analytical characteristics of the methods such as limit of detections, limit of quantifications, and linear ranges have been obtained. CTAB, CPB, and DTAB could be determined by the Al–CAS complex in the ranges of 0.50–40.00, 0.20–10.00, and 0.40–10.00 µmol L?1, and for the Be–CAS complex in the ranges of 0.08–5.00, 0.08–3.00, and 0.20–6.00 µmol L?1, respectively. The limit of the detections of the method for the determination of CTAB, CPB, and DTAB for the Be–CAS complex has been found as 0.025, 0.024, and 0.061 µmol L?1, respectively. The interfering effect of some anions and cations was also tested. The method was applied to the determination of CS CTAB in conditioner shampoo and water samples.  相似文献   

19.
The hydrochemical behaviour of catchments is often investigated by inferring stream chemistry through identification of source areas involved in hydrograph separation analysis, yet its dynamic evolution of hydrologic pathways has received little attention. Intensive hydrometric and hydrochemical measurements were performed during two different storms on March 29, 2001 and August 21–22, 2001 to define hydrochemical evolution under the dynamic of flow pathways in a 5·2 ha first‐order drainage of the Kawakami experimental basin (KEB), Central Japan, a forested headwater catchment with various soil depths (1·8 to 5 m) overlying late Neogene of volcanic bedrocks. The hydraulic potential distribution and flow lines data showed that the change in flow direction, which was controlled by rainfall amount and antecedent wetness of the soil profile, agreed well with the hydrochemical change across the slope segment during the storm. Hydrograph separation predicted by end‐member mixing analysis (EMMA) using Ca2+ and SiO2 showed that near surface riparian, hillslope soil water and deep riparian groundwater were important in stream flow generation. The evidence of decrease in solutes concentration at a depth of 1 m in the hillslope and 0·6 m in the near surface riparian during peak storm suggested a flushing of high solutes concentration. Most of the solutes accumulated in the deep riparian groundwater zone, which was due to prominent downward flow and agreed well with the residence time. The distinct flow pathways and chemistry between the near surface riparian and deep riparian groundwater zones and the linkage hillslope aquifer and near surface riparian reservoir, which controls rapid flow and solutes flushing during the storm event, are in conflict with the typical assumption that the whole riparian zone resets flow pathways and chemical signature of hillslope soil water, as has been reported in a previous study. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

20.
In order to improve the coagulation/flocculation efficiency of polyaluminum chloride (PAC), a composite flocculant of PAC and polydimethyldiallylammonium chloride (PDMDAAC), or PAC‐PDMDAAC, was prepared. The chemical species distribution of aluminum in PAC and PAC‐PDMDAAC, which has a close relationship with their coagulation/flocculation performance, was investigated by Al‐Ferron complexation timed spectrophotometry and 27Al‐NMR. The factors affecting the chemical species of aluminum in PAC‐PDMDAAC, such as the weight concentration of PDMDAAC (Wp), basicity (B) of PAC, and viscosity (η) of PDMDAAC, were studied. The flocculation efficiencies of PAC‐PDMDAAC, PAC and PDMDAAC were studied on a six‐spindle multiple stirrer unit. The results showed that the aluminum species distribution in PAC‐PDMDAAC depends on the Wp, B and η value. When the B value is 1.5 and η value is 1.22 dL/g, the composite flocculant with Wp = 15 % gives highest Alb and Al13 contents, and its flocculation efficiency is highest in the test flocculations.  相似文献   

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