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1.
Zircon U–Pb ages, geochemical and Sr–Nd isotopic data are presented for the late Carboniferous Baoligaomiao Formation (BG Fm.) and Delewula Formation (DW Fm.) volcanic rocks, widely distributed in northern Inner Mongolia, in the northern part of the Xing'an–Mongolia Orogenic Belt (XMOB). The BG Fm. rocks mainly consist of basaltic andesites and andesites while the DW Fm. rocks include dacites, trachytes, rhyolites, pyroclastic rocks and minor andesites. New LA-ICPMS zircon U–Pb analyses constrain their eruption to late Carboniferous (317–322 Ma and 300–310 Ma, respectively). The BG Fm. volcanic rocks are characterized by enriched large ion lithophile elements (LILE) and depleted high field strength elements (HFSE), with initial 87Sr/86Sr ratios of 0.70854–0.70869 and negative εNd(t) (− 2.1 to − 2.4) values. They have low La/Ba (0.03–0.05), high La/Nb (2.05–3.70) ratios and variable Ba/Th (59.5–211) ratios. Such features suggest that they are derived from melting of heterogeneous sources including a metasomatized mantle wedge and Precambrian crustal material. The DW Fm. volcanic rocks are more depleted in HFSE with significant Nb, Ta, P, Ti anomalies. They have high initial 87Sr/86Sr ratios (0.72037–0.72234) and strong negative εNd(t) (− 11 to − 11.6) values which indicate those igneous rocks were mainly derived from reworking of the Paleoproterozoic crust. The late Carboniferous volcanic rocks have geochemical characteristics similar to those of the continental arc rocks which indicate the northward subduction of the Paleo Asian Ocean may have continued to the late Carboniferous. The volcanic association of this study together with the early Permian post-collisional magmatic rocks suggests that a tectonic transition from subduction-related continental margin arc volcanism to post-collisional magmatism occurred in the northern XMOB between the late Carboniferous and the early Permian.  相似文献   

2.
Ore-forming porphyries and barren granitoids from porphyry Cu deposits differ in many ways, particularly with respect to their adakitic affinity and calc-alkaline characteristics. In this study, zircon U–Pb and molybdenite Re–Os dating, whole rock geochemistry, whole rock Sr–Nd–Pb and zircon O–Hf isotopic analyses were carried out on the ore-forming granitoids from the Kounrad, Borly and Sayak deposits, and also on pre-ore and post-ore granitoids in adjacent regions of Central Kazakhstan. Geochronology results indicate that pre-ore magmatism occurred in the Late Devonian to Early Carboniferous (361.3–339.4 Ma), followed by large scale Cu mineralization (325.0–327.3 Ma at Kounrad, 311.4–315.2 Ma at Borly and 309.5–311.4 Ma at Sayak), and finally, emplacement of the Late Carboniferous post-ore barren granitoids (305.0 Ma). The geochemistry of these rocks is consistent with calc-alkaline arc magmatism characterized by strong depletions in Nb, Ta and Ti and enrichments in light rare earth elements and large ion lithophile elements, suggesting a supra-subduction zone setting. However, the ore-forming rocks at Kounrad and Sayak show adakitic characteristics with high Sr (517.5–785.3 ppm), Sr/Y (50.60–79.26), (La/Yb)N (9.37–19.62) but low Y (6.94–11.54 ppm) and Yb (0.57–1.07 ppm), whereas ore-forming rocks at Borly and barren rocks from northwest of Borly and Sayak have normal arc magma geochemical features. The Sr–Nd–Hf–O isotopic compositions show three different signatures: (1) Sayak granitoids have very young juvenile lower crust-derived compositions ((87Sr/86Sr)i = 0.70384 to 0.70451, ɛNd (t) = + 4.9 to + 6.0; TDM2 (Nd) = 580 to 670 Ma, ɛHf (t) = + 11.3 to + 15.5; TDMC (Hf) = 330 to 600 Ma, δ18O = 6.0 to 8.1‰), and were probably generated from depleted mantle-derived magma with 5–15% sediment melt addition in the magma source; (2) the Kt-1 granite from northwest of Sayak shows extremely enriched Sr–Nd isotopic compositions ((87Sr/86Sr)i = 0.71050, ɛNd (t) = − 7.8, TDM2 (Nd) = 1700 Ma), likely derived from partial melting of ancient continental crust; (3) other granitoids have transitional Sr–Nd compositions between the Sayak and Kt-1 samples, indicating a juvenile lower crust source with the addition of 10–30% of ancient crustal material. The pre-ore magmatism was probably related to partial melting of juvenile lower crust due to northward subduction of the Junggar–Balkhash Ocean, whereas the ore-forming adakitic rocks at Aktogai, Kounrad and Sayak formed by partial melting of thickened lower crust which subsequently delaminated. The ore-forming rocks at Borly, and the later post-ore barren granites, formed by partial melting of juvenile lower crust with normal thickness. This tectonic setting supports the existence of an Andean-type magmatic arc in the Devonian to the Late Carboniferous, resulting from the subduction of the Junggar–Balkhash oceanic plate. The link between whole rock geochemistry and scale of mineralization suggests a higher metallogenic potential for adakitic rocks than for normal arc magmatism.  相似文献   

3.
Uranium–Pb (zircon) ages are linked with geochemical data for porphyry intrusions associated with giant porphyry Cu–Au systems at Oyu Tolgoi to place those rocks within the petrochemical framework of Devonian and Carboniferous rocks of southern Mongolia. In this part of the Gurvansayhan terrane within the Central Asian Orogenic Belt, the transition from Devonian tholeiitic marine rocks to unconformably overlying Carboniferous calc-alkaline subaerial to shallow marine volcanic rocks reflects volcanic arc thickening and maturation. Radiogenic Nd and Pb isotopic compositions (εNd(t) range from + 3.1 to + 7.5 and 206Pb/204Pb values for feldspars range from 17.97 to 18.72), as well as low high-field strength element (HFSE) contents of most rocks (mafic rocks typically have < 1.5% TiO2) are consistent with magma derivation from depleted mantle in an intra-oceanic volcanic arc. The Late Devonian and Carboniferous felsic rocks are dominantly medium- to high-K calc-alkaline and characterized by a decrease in Sr/Y ratios through time, with the Carboniferous rocks being more felsic than those of Devonian age. Porphyry Cu–Au related intrusions were emplaced in the Late Devonian during the transition from tholeiitic to calc-alkaline arc magmatism. Uranium–Pb (zircon) geochronology indicates that the Late Devonian pre- to syn-mineral quartz monzodiorite intrusions associated with the porphyry Cu–Au deposits are ~ 372 Ma, whereas granodiorite intrusions that post-date major shortening and are associated with less well-developed porphyry Cu–Au mineralization are ~ 366 Ma. Trace element geochemistry of zircons in the Late Devonian intrusions associated with the porphyry Cu–Au systems contain distinct Th/U and Yb/Gd ratios, as well as Hf and Y concentrations that reflect mixing of magma of distinct compositions. These characteristics are missing in the unmineralized Carboniferous intrusions. High Sr/Y and evidence for magma mixing in syn- to late-mineral intrusions distinguish the Late Devonian rocks associated with giant Cu–Au deposits from younger magmatic suites in the district.  相似文献   

4.
The Halasu porphyry copper belt situated in the East Junggar is one of the major porphyry copper belts in Xinjiang Uygur Autonomous Region, northwest China. Copper and molybdenum mineralization occurs as disseminated sulfides or veinlets mainly in granodiorite porphyry and diorite porphyry, with the intense development of zoned alteration from potassic, through sericitic to an outer zone of propylitic alteration.New LA–ICP-MS zircon U–Pb dating reveals that magmatism in the belt can be divided into three periods during the Middle Devonian and Early Carboniferous, namely the pre-mineralization stage of 390 Ma, syn-mineralization stage of 382–372 Ma, and post-mineralization stage of 350–320 Ma. The syn-mineralization intrusions are calc-alkaline, whereas pre- and post-mineralization intrusions are shoshonitic and high-K calc-alkaline. The syn-mineralization intrusions are enriched in highly incompatible trace elements but depleted in Nb, Ta, Hf and Ti relative to the pre- and post-mineralization intrusions.Zircon trace elements analyses demonstrate a negative correlation between Ti-in-zircon temperatures and oxygen fugacity. Ore-bearing syn-mineralization granitoids are characterized by higher water content, oxygen fugacity and low temperatures with higher mineralization potential than pre- and post-mineralization ones. These characteristics, together with the geochemical signature of the intrusions, suggest that the ore-bearing porphyries are derived from relative high ƒH2O magma reservoir. The remarkably homogeneous Hf isotopic compositions (εHf(t) = 8 to 13) from syn-mineralization intrusions span over 10 m.y., suggesting the existence of a long-lived reservoir beneath Halasu belt during the Middle Devonian. All the intrusions have low initial 87Sr/86Sr values (0.703935 to 0.707172), high εNd(t) values (4.7 to 5.5) and young crustal model ages (650 to 750 Ma). Combined with the mantle-derived Pb isotope characteristics, the Sr–Nd–Hf data suggest that the parental magma was probably derived from flat subduction triggered partial melting of juvenile crust generated during subduction–accretionary process with no significant input of old crust, whereas pre-mineralization and post-mineralization intrusions are supposed to emplaced in immature island arc setting and post-orogenic setting, respectively.  相似文献   

5.
Sr-Nd-Pb-Hf isotope mapping combined with U-Pb zircon SHRIMP ages of granitoids from four sampling profiles across terrane boundaries in Uzbekistan reveal distinct reservoir types (cratonic and accretionary), witnessed by the diverse nature and origin of the predominant Paleozoic granitic magmatism that provided hosts for major ore-bodies. The study region comprises four major terranes, including 1) the Sultan-Uvais terrane, 2) the Kyzylkum-Nurata Segment and 3) the Gissar Segment of the South Tien Shan and 4) the Chatkal-Kurama terrane of the Middle Tien Shan. Sr-Nd isotope analyses show a wide range of εNdt (− 5 to + 7) and (87Sr/86Sr)t of 0.704–0.707, indicating involvement of both mantle-derived material and older crustal sources. A wide range of Hf-isotope compositions found in zircons of Chatkal-Kurama granites, Middle Tien Shan (εHf mainly ~ − 5 to + 5), could be due to recycling of older crustal protolith(s); in particular, the earliest (Silurian) granites may be directly derived from 1.5 to 1.7 Ga lower crust. In the Southern Tien Shan, some involvement of subducted oceanic crust is evidenced by strongly juvenile εHft values of up to + 14 and + 16 (Sultan-Uvais, Teskuduk-Kyzylkum). Permo-Carboniferous granitoids, which occur across all terranes also exhibit a wide range of isotope signatures, corresponding to Mesoproterozoic–Neoproterozoic crustal protoliths with a westward increase in juvenile contributions. Pb isotopes (whole-rock) imply the dominance of a crustal component and crust-mantle mixing processes. New age data confirmed: 1) old age of the Turkestan Ocean (505 Ma in Sultan-Uvais), 2) fragments of Silurian island arcs in the accretionary complex of the Chatkal-Kurama terrane (granites of 429–416 Ma) and in the upper allochthon of the South Tien Shan (gabbro 438 Ma in Tamdytau), and 3) a significant volume of granitoid magmatism of subduction or early-collisional stages (around 320–310 Ma) in the Chatkal-Kurama Segment and especially in the Gissar Segment. The westernmost part of the Tien Shan is characterized by multiple subduction processes responsible for 300 million years of geodynamic evolution history (accretionary collage, crustal growth) with the pre-Mesozoic crust formation concluded by Permian post-collisional extensional magmatism.  相似文献   

6.
The Hongshan Cu-polymetallic deposit is located in the southern Yidun arc in southwestern China, where both subduction-related (Late Triassic) and post-collisional (Late Cretaceous) porphyry–skarn–epithermal mineralization systems have been previously recognized. In this study, two distinct magmatic events, represented by diorite porphyry and quartz monzonite porphyry, have been revealed in the Hongshan deposit, with zircon SHRIMP U–Pb ages of 214 ± 2 Ma and 73.4 ± 0.7 Ma, respectively. The 73 Ma age is comparable to the Re–Os ages of 77 to 80 Ma of ore minerals from the Hongshan deposit, indicating that the mineralization is related to the Late Cretaceous quartz monzonite porphyries rather than Late Triassic diorite porphyries. The Late Triassic diorite porphyries belong to the high-K calc-alkaline series and show arc magmatic geochemical characteristics such as enrichment in Rb, Ba, Th and U and depletion in HFSEs, indicating that they were formed during the westward subduction of the Garzê–Litang Ocean. In contrast, the Late Cretaceous quartz monzonite porphyries show shoshonitic I-type geochemical characteristics, with high SiO2, K2O, LILE, low HREE, Y and Yb contents, and high LREE/HREE and La/Yb ratios. These geochemical characteristics, together with the Sr–Nd–Pb isotopic compositions (average (87Sr/86Sr)i = 0.7085; εNd(t) = − 6.0; 206Pb/204Pb = 19.064, 207Pb/204Pb = 15.738, 208Pb/204Pb = 39.733) suggest that the quartz monzonite porphyries originated from the partial melting of the ancient lower crust in response to underplating of mafic magma from subduction metasomatized mantle lithosphere, possibly triggered by regional extension in the post-collisional tectonic stage. The S isotopic compositions (δ34SV-CDT = 3.81‰ to 5.80‰) and Pb isotopic compositions (206Pb/204Pb = 18.014 to 18.809, 207Pb/204Pb = 15.550 to 15.785, and 208Pb/204Pb = 38.057 to 39.468) of ore sulfides indicate that the sulfur and metals were derived from mixed mantle and crustal sources. It is proposed that although the Late Triassic magmatic event is not directly related to mineralization, it contributed to the Late Cretaceous mineralization system through the storage of large amounts of sulfur and metals as well as water in the cumulate zone in the mantle lithosphere through subduction metasomatism. Re-melting of the mantle lithosphere including the hydrous cumulate zone and ancient lower crust during the post-collisional stage produced fertile magmas, which ascended to shallow depths to form quartz monzonite porphyries. Hydrothermal fluids released from the intrusions resulted in porphyry-type Mo–Cu ores in and near the intrusions, skarn-type Cu–Mo ores in the country rocks above the intrusions, and hydrothermal Pb–Zn ores in the periphery.  相似文献   

7.
Many studies have examined the Japan Sea basalts recovered during Ocean Drilling Program (ODP) Leg127/128. Of these, the 40Ar–39Ar dating undertaken is important in constraining the timing of the formation of the Japan Sea; however, the implications of their results do not appear to be fully appreciated by the geological community. In this paper, I reassess the 40Ar–39Ar age data of the basalts with reference to Nd–Sr isotopic data. The 40Ar–39Ar dating was performed on basalts somewhat enriched in large-ion lithophile elements and recovered from ODP Sites 794, 795 and the lower part of 797, yielding the plateau ages of 21.2–17.7 Ma. These basalts show the Nd–Sr isotopic signature of a moderately depleted mantle source (εNd: 0.6–6.9). In contrast, the basalts from the upper part of Site 797 have yet to be dated due to their low K content, although their Nd isotopic compositions are similar to that of MORB (εNd: 8.4–10.4). By analogy to the secular Nd–Sr isotopic trends reported for Sikhote-Alin and northeast Japan, the age of the upper basalts at Site 797 may be inferred to be younger than the lower basalts, probably around 16 Ma. The Nd–Sr isotopic compositions of the Japan Sea basalts have been interpreted in terms of eastward asthenospheric flow, as have the lavas of the Sikhote-Alin and northeastern Japan. The timing of volcanic activity in the Japan Sea region (i.e., from 21.2 to 14.86 Ma) is consistent with the timing of rotational crustal movements inferred from paleomagnetic studies of the Japanese Islands (i.e., 14.8–4.2 Ma for southwest Japan and 16.5–14.4 Ma for northeast Japan).  相似文献   

8.
The newly discovered Fuxing porphyry Cu deposit is located in the Dananhu–Tousuquan arc, adjacent to the Tuwu–Yandong Cu deposits of Eastern Tianshan, in the southern Central Asian Orogenic Belt. The Fuxing deposit is hosted by volcanic rocks (basalt and dacite) in the Early Carboniferous Qi'eshan Group and Carboniferous felsic intrusions (plagiogranite porphyry, monzogranite, and quartz diorite). New SIMS zircon U–Pb dating indicates that the plagiogranite porphyry and monzogranite emplaced at 332.1 ± 2.2 Ma and 328.4 ± 3.4 Ma, respectively. The basalts are characterized by low SiO2 contents (47.47–54.90 wt.%), a lack of Eu anomalies, strong depletion of Na, Ta, and Ti elements but positive Sr, U, and Pb anomalies, high Y (20.8–28.2 ppm) and HREE concentrations (Yb = 2.23–3.06 ppm), and relatively low (La/Yb)N (2.20–3.92) values; the dacite samples have high SiO2 contents (66.13–76.93 wt.%), clearly negative Eu anomalies, high Mg# values (36–51), and high Y (41.8–54.9 ppm) and Yb (5.76–8.98 ppm) concentrations. The basalts and dacites exhibit similar signatures as normal arc rocks, and were considered to be derived from partial melting of mantle-wedge peridotite that was previously metasomatized by slab melts. In contrast, the plagiogranite porphyry, monzogranite, and quartz diorite show the same geochemical affinity with modern adakites, which are characterized by high SiO2 contents (67.55–79.00 wt.%), minor negative to positive Eu anomalies, strong depletion of heavy rare earth elements (Yb = 0.17–1.19 ppm) and Y (1.86–10.1 ppm), positive K, Rb, Sr, and Ba but negative Nb, Ta, Th, and Ti anomalies, and high (La/Yb)N ratios and Mg# values. Moreover, these adakitic felsic intrusions display relatively high positive zircon εHf(t) values (+ 11.4 to + 18.3), low 87Sr/86Sr (0.706080–0.711239), high 143Nd/144Nd (0.512692–0.512922) ratios, and consistent zircon δ18O values (4.41‰–5.48‰), suggesting that their parental magma were most likely derived from partial melting of the subducted oceanic crust followed by mantle peridotite interaction. Based on the whole-rock geochemical and Sr–Nd–Hf–O isotopic data, as well as detailed petrographic analyses, we further suggest that the Fuxing igneous rocks and associated porphyry Cu mineralization were generated by the northward subduction of the paleo-Tianshan oceanic plate beneath the Dananhu–Tousuquan island arc during the Early Carboniferous.  相似文献   

9.
The northeastern Gangdese Pb–Zn–Ag–Fe–Mo–W polymetallic belt (NGPB), characterized by skarn and porphyry deposits, is one of the most important metallogenic belts in the Himalaya–Tibetan continental orogenic system. This belt extends for nearly four hundred kilometers along the Luobadui–Milashan Fault in the central Lhasa subterrane, and contains more than 10 large ore deposits with high potential for development. Three major types of mineralization system have been identified: skarn Fe systems, skarn/breccia Pb–Zn–Ag systems, and porphyry/skarn Mo–Cu–W systems. In this study, we conducted a whole-rock geochemical, U–Pb zircon geochronological, and in situ zircon Hf isotopic study of ore-forming rocks in the NGPB, specifically the Jiangga, Jiaduopule, and Rema skarn Fe deposits, and the Yaguila Pb–Zn–Ag deposit. Although some of these deposits (porphyry Mo systems) formed during the post-collisional stage (21–14 Ma), the majority (these three systems) developed during the main (‘soft collision’) stage of the India–Asia continental collision (65–50 Ma). The skarn Fe deposits are commonly associated with granodiorites, monzogranites, and granites, and formed between 65 and 50 Ma. The ore-forming intrusions of the Pb–Zn–Ag deposits are characterized by granite, quartz porphyry, and granite porphyry, which developed in the interval of 65–55 Ma. The ore-forming porphyries in the Sharang Mo deposit, formed at 53 Ma. The rocks from Fe deposits are metaluminous, and have relatively lower SiO2, and higher CaO, MgO, FeO contents than the intrusions associated with Mo and Pb–Zn–Ag mineralization, while the Pb–Zn–Ag deposits are peraluminous, and have high SiO2 and high total alkali concentrations. They all exhibit moderately fractionated REE patterns characterized by lower contents of heavy REE relative to light REE, and they are enriched in large-ion lithophile elements and relatively depleted in high-field-strength elements. Ore-forming granites from Fe deposits display 87Sr/86Sr(i) = 0.7054–0.7074 and εNd(t) = − 4.7 to + 1.3, whereas rocks from the Yaguila Pb–Zn–Ag deposit have 87Sr/86Sr(i) = 0.7266–0.7281 and εNd(t) = − 13.5 to − 13.3. In situ Lu–Hf isotopic analyses of zircons from Fe deposits show that εHf(t) values range from − 7.3 to + 6.6, with TDM(Hf)C model ages of 712 to 1589 Ma, and Yaguila Pb–Zn–Ag deposit has εHf(t) values from − 13.9 to − 1.3 with TDM(Hf)C model ages of 1216 to 2016 Ma. Combined with existing data from the Sharang Mo deposit, we conclude that the ore-forming intrusions associated with the skarn Fe and porphyry Mo deposits were derived from partial melting of metasomatized lithospheric mantle and rejuvenated lower crust beneath the central Lhasa subterrane, respectively. Melting of the ancient continental material was critical for the development of the Pb–Zn–Ag system. Therefore, it is likely that the source rocks play an important role in determining the metal endowment of intrusions formed during the initial stage of the India–Asia continental collision.  相似文献   

10.
The closure of Paleo-Asian Ocean is considered to have occurred along the Solonker Suture in the southernmost segment of the Central Asian Orogenic Belt (CAOB), the largest Phanerozoic accretionary orogen on the globe. The suture branches to the east to form the northern Hegenshan–Heihe Suture and the southern Solonker–Changchun Suture. The Hegenshan–Heihe Suture is an ideal natural laboratory for studying the post-collisional geodynamic processes operating in a soft collision zone driven by divergent double-sided subduction. Here we report results from an integrated study of the petrology, geochronology, geochemistry, and Sr–Nd–Hf isotopic compositions of the Early Carboniferous–Early Permian magmatic suite in the Hailar Basin of the Xing’an–Erguna Block. The Early Carboniferous igneous rocks are represented by 356–349 Ma andesitic tuffs, exhibiting typical subduction-related features, such as enrichment in large-ion lithophile elements and depletion in high-field-strength elements. These features, together with the relatively depleted Sr–Nd–Hf isotopic compositions, constant Nb/Y values, but highly variable Rb/Y and Ba values indicate that these rocks were generated by partial melting of a depleted mantle wedge metasomatized by slab-derived fluids. The Late Carboniferous–Early Permian magmatic suite (317–295 Ma) is characterized by high Sr contents (313–1080 ppm) and low Y contents (5–13 ppm), and these can be subdivided into calc-alkaline adakitic rocks and high-K calc-alkaline adakitic rocks. The calc-alkaline adakitic rocks have higher values of Sr/Y, (Sm/Yb)source normalized, and Mg#, and lower values of Y, Ybsource normalized, and K2O/Na2O than the high-K calc-alkaline adakitic rocks, which suggests that the former was generated by partial melting of foundered lower continental crust and the latter by partial melting of normal lower continental crust. Based on our new data, in conjunction with those in previous studies, we conclude that the tectonic evolution of the Hegenshan–Heihe Suture involved Early Carboniferous double-sided subduction of the Nenjiang Ocean, latest Early Carboniferous soft collision between the Xing’an–Erguna and Songliao blocks, and Late Carboniferous–Early Permian post-collisional extension. We also propose a new geodynamic scenario in which removal of the lithospheric root might have occurred in a soft collision zone during the post-collision period via repeated and localized lithospheric dripping, which results from combined effects of hydration weakening of the lithosphere caused by pre-collision subduction and asthenospheric stirring triggered by slab break-off.  相似文献   

11.
The Central Anatolian Volcanic Province (CAVP), one of four major volcanic provinces in Turkey, plays a significant role in the interpretation of the tectonic evolution of Central Anatolia. The CAVP developed within a complex collisional system involving the African, Arabian and Eurasian plates during the Miocene. The volcanism exhibits complicated variations in mineralogical, petrological and geochemical compositions resulting from post-collisional lithospheric dynamics. The Incesu ignimbrite has 5–20 m thick and covers an area of ～7800 km2. It is composed of three stratigraphic levels. The lower level (LL) shows blackish brown and glassy welded structure. The middle level (ML) is a well-welded, reddish pink in color and has large amounts of fiamme. The upper level (UL) is grayish pink, weakly welded and has rock fragments of different compositions. The Incesu ignimbrite is composed of plagioclase (oligoclase, andesine) + pyroxene (augite, clinoenstatite) + opaque minerals and low amount of amphibole, biotite and quartz. Eutaxitic texture is dominant in ML and LL samples; these levels are more strongly and contain more flattened pumice fragments and volcanic glass shards than in the UL. A sharp color contrast defines the contact between LL and ML.Major, trace and rare earth element of the Incesu ignimbrite, characterized by their rhyolite, rhyodacite–dacite composition, medium–high K, calcalkaline and peraluminous nature, show fractional crystallization primarily controlled by plagioclase, clinopyroxene, magnetite, ilmenite and titanomagnetite. Sr and Nd isotopic ratios of Incesu ignimbrite display isotopic variations between the ignimbrite levels; they exhibit a limited range in 87Sr/86Sr (0.7043–0.7049) and 143Nd/144Nd (0.512716–0.512760). The Sr–Nd isotopic ratio of Incesu ignimbrite reveals an age of 3 Ma. The ignimbrite evolved through fractional crystallization and crystal contamination of the parent magma derived from Ocean Island Basalt (OIB) like magma. This suggestion is supported by the AFC modeling based on the trace elements and Sr isotope data.Variation of several major oxide concentrations (Fe2O3, TiO2, CaO and K2O), trace element concetrations (V, Sr, Cs and Rb) and trace element ratios (Ba/Rb, Sr/, K/Sr, K/Nb, Rb/Sr, Rb/Y and Rb/Nb) versus SiO2 concentration show the magma chamber that generated the Incesu ignimbrite was compositionally zoned. All geochemical and Sr–Nd isotpic datas can be interepreted to be the result of a subduction related source.  相似文献   

12.
The Beiya ore deposit is located in the northwestern Yangtze Block, to the southeast of the Tibetan Plateau, SW China. The deposit is hosted by a porphyritic monzogranitic stock that is cross-cut by a porphyritic granite and later lamprophyre dikes. The whole-rock geochemistry of the porphyritic monzogranite and granite intrusions is both potassic and adakite-like, as evidenced by high K2O/Na2O (2.2 to 24.8), Sr/Y (53.2 to 143.2), and (La/Yb)N (4.9 to 28.9) ratios. Both intrusions have comparable zircon U–Pb ages of ca. 36 Ma and εHf(t) values of − 6.8 to + 2.7. Zircons within these intrusions have Hf isotope crustal model ages with a prominent peak at ca. 840 Ma, and both of the intrusions have similar Sr–Nd–Pb isotopic compositions that are comparable to the compositions of amphibolite xenoliths hosted by potassic felsic intrusions in western Yunnan. The contemporaneous lamprophyre dikes show Nb–Ta depletion, enriched (87Sr/86Sr)i and εNd(t), and extremely low Nb/U ratios (1.6–3.6), suggesting that these dikes were formed from magmas generated by partial melting of a metasomatized subcontinental lithospheric mantle (SCLM). The geochemistry of the porphyritic intrusions and the lamprophyre dikes suggests that the Beiya porphyries formed as a result of partial melting of a thickened and K-rich region of the lower crust, triggered by melting of metasomatized SCLM. The ca. 840 Ma U–Pb ages and εHf(t) values (− 6.8 to + 2.7) of xenocrystic zircons within the porphyritic intrusions suggest that these zircons were produced in a continental arc setting at ca. 840 Ma. The peak Hf model age of the zircons crystallized from the intrusions and the U–Pb ages of the xenocrystic zircons within the intrusions suggest that these porphyritic intrusions formed from magmas sourced from a juvenile crust that formed at ca. 840 Ma. This juvenile crust is most likely the source for the metals within the porphyry–skarn deposits in the study area, as the SCLM-derived lamprophyre dikes in this area are barren.Massive Fe–Au orebodies (~ 99 million metric tons at an average grade of 2.61 g/t Au) within the study area are generally located within the skarn-altered boundary of the porphyritic monzogranite stock and along the faults in the surrounding Triassic carbonates. The Fe–Au orebodies are spatially and genetically associated with skarn comprising garnet and diopside. Petrographic observations show that the massive Fe–Au orebodies mainly consist of hematite and magnetite with disseminated pyrite that hosts native gold and electrum.The porphyritic granite contains porphyry-style mineralization in the form of disseminated and veinlet-hosted pyrite and chalcopyrite. Pyrite-hosted lattice-bound gold is present within both the massive Fe–Au and the porphyry-type mineralization in the study area, and is present at concentrations up to 10 ppm Au (as determined by in situ LA-ICP-MS analysis). Subsequent weathering altered the primary magnetite–hematite–sulfide assemblage in the Fe–Au orebody into a magnetite–limonite assemblage, and generated laterite-type mineralization in which gold is hosted by limonite.  相似文献   

13.
The Baoligaomiao Formation, within the Hegenshan ophiolite-arc-accretion complex is an important segment to understand the tectonic evolution of the Central Asian Orogenic Belt (CAOB), world's largest Phanerozoic orogenic belt. In this study, we present an integrated study of zircon U-Pb isotopic ages, whole rock major-trace elements, and Sr-Nd-Pb isotopic data from the volcanic succession in the Baoligaomiao Formation. The volcanic succession can be divided into the lower sequence with zircon U-Pb ages in the range of 326.3 Ma–307.4 Ma and the upper sequence of 305.3 Ma. The succession belongs to two suites: calc-alkaline volcanics and high-Si rhyolites. The calc-alkaline volcanic rocks include basaltic andesite through andesite and dacite to rhyolite and their pyroclastic equivalents. These rocks exhibit a well-defined compositional trend from basaltic to rhyolitic magma, reflecting continuous fractional crystallization. These rocks show obvious enrichment in LILEs and LREEs and relative depletion of HFSEs, typical of subduction-related magma. The calc-alkaline rocks have low initial 87Sr/86Sr (0.7023–0.7052), positive ɛNd(t) values (2.75–4.80), and their initial Pb isotopic compositions are 17.875–18.485 of 206Pb/204Pb, 15.481–15.520 of 207Pb/204Pb and 37.467–37.764 of 208Pb/204Pb, respectively. Geochemical and isotopic results suggest that the volcanic succession represents Carboniferous subduction-related, mature, continental arc volcanism. The outcrops of high-Si rhyolites are restricted to the northern edge of the continental arc, marking a transition zone between volcanic arc and back-arc basin, where they are interbedded with the calc-alkaline rocks in the lower sequence, and the upper sequence is composed only of high-Si rhyolites. The high-Si rhyolites have high SiO2 (71.12–81.76 wt%) and varied total alkali contents (K2O + Na2O = 5.46–10.58 wt%), low TiO2 (0.06–0.27 wt%), MgO (0.09–0.89 wt%) and CaO (0.08–0.72 wt%). Based on the presence of mafic alkali phenocrysts, such as arfvedsonite and siderophyllite, high Zr/Nb ratios (> 10) and peralkalinity index (PI) near unity, the high-Si rhyolites can be classified as peralkaline comendites. The high-Si rhyolites are characterized by unusually low Sr and Ba, and high abundance of Zr, Th, Nb, HREEs and Y. They show geochemical characteristics similar to those of typical A2-type granites including their high K2O + Na2O, Nb, Zr and Y, and high ratios of FeOT/MgO, Ga/Al and Y/Nb. Our study suggests that the high-Si rhyolites were derived from discrete trachytic parent magma with fractional crystallization within shallow magma reservoirs. Their Nd-Pb isotopic characteristics are similar to those of the calc-alkaline arc rocks and are compatible with partial melting of pre-existing juvenile continental arc crust. We observe that the widespread eruptions of A2-rhyolitic magmas (305.3 Ma–303.4 Ma) following a short period of magmatic quiescence was temporally and spatially associated with voluminous intrusion of the bimodal magmas (304.3 Ma–299.3 Ma) in the pre-existing arc volcanic-plutonic belt (329 Ma–307 Ma). We envisage northward subduction and slab breakoff process resulting in an obvious change of the regional stress field to extensional setting within the Carboniferous continental arc running E-W for thousands of kilometers. Therefore, we propose the existence of an east-west-trending Carboniferous continental arc in the Hegenshan ophiolite-arc-accretion complex, with the slab breakoff event suggesting that the age of the upper sequence (305.3 ± 5.5 Ma) likely indicates the maximum age for the cessation of the northward subduction of the Hegenshan oceanic lithosphere.  相似文献   

14.
This study provides 87Sr/86Sr, δ13C and δ18O data from the best-preserved limestone and dolomite of the Ediacaran carbonate-dominated Khorbusuonka Group of the Olenek Uplift, NE Siberian Craton, as well as detrital zircon geochronological data from both underlying and overlying sandstones. The Maastakh Formation is characterized by 87Sr/86Sr ratios of ca. 0.70822 and δ13C values between + 4.8 and + 6.0‰. 87Sr/86Sr ratios in limestones of the Khatyspyt Formation are fairly uniform, ranging from 0.70783 to 0.70806. The carbon isotopic composition slowly decreases from bottom (+ 3.7‰) to top (− 0.2‰) of section. The Sr isotopic composition of the Turkut Formation varies from 0.70824 to 0.70914, value of δ13C is about zero: − 0.7…+0.7 ‰. The youngest population of detrital zircons from Maastakh Formation indicates that these rocks were formed not later than 630 Ma. U–Pb detrital zircons data of Kessyusa Group has a single peak at about 543 Ma, which is almost identical to the earlier dating. Based on biostratigraphy and isotopic data, the Sr isotopic compositions from the Khatyspyt Formation (87Sr/86Sr = 0.70783–0.70806) represent the composition of seawater at 560–550 Ma. Such low values of 87Sr/86Sr ratio in Ediacaran water were probably caused by the quick opening of Iapetus Ocean.  相似文献   

15.
Major, trace element and isotopic (Sr, Nd, Pb) data and unspiked K–Ar ages are presented for Quaternary (0.90–0.95 Ma old) basalts from the Hayyabley volcano, Djibouti. These basalts are LREE-depleted (Lan/Smn = 0.76–0.83), with 87Sr/86Sr ratios ranging from 0.70369 to 0.70376, and rather homogeneous 143Nd/144Nd (εNd = + 5.9–+ 7.3) and Pb isotopic compositions (206Pb/204Pb = 18.47–18.55, 207Pb/204Pb = 15.52–15.57, 208Pb/204Pb = 38.62–38.77). They are very different from the underlying enriched Tadjoura Gulf basalts, and from the N-MORB erupted from the nascent oceanic ridges of the Red Sea and Gulf of Aden. Their compositions closely resemble those of (1) depleted Quaternary Manda Hararo basalts from the Afar depression in Ethiopia and (2) one Oligocene basalt from the Ethiopian Plateau trap series. Their trace element and Sr, Nd, Pb isotope systematics suggest the involvement of a discrete but minor LREE-depleted component, which is probably an intrinsic part of the Afar plume.  相似文献   

16.
Neoproterozoic igneous rocks are widely distributed in the Kuluketage block along the northern margin of the Tarim Craton. However, the published literature mainly focuses on the ca. 800 Ma adakitic granitoids in the area, with the granites that intrude the 735–760 Ma mafic–ultramafic rocks poorly studied. Here we report the ages, petrography and geochemistry of two granites in the Xingdi mafic–ultramafic rocks, in order to construct a new view of the non-adakitic younger granites. LA-ICP-MS zircon U–Pb dating provided weighted mean 206Pb/238U ages of 743.0 ± 2.5 Ma for the No.I granite (G1) and 739.0 ± 3.5 Ma for the No.II granite (G2). A clear core-rim texture of similar age and a high zircon saturation temperature of ca. 849 ± 14 °C were observed for the No.I granite; in contrast, G2 has no apparent core-rim texture but rather inherited older zircons and a lower zircon saturation temperature of ca. 763 ± 17 °C. Geochemical analysis revealed that G1 is an alkaline A-type granite and G2 is a high-K calc-alkaline I-type granite. Both granites share similar geochemical characteristics of arc-related magmatic rocks and enriched Sr–Nd–Hf isotopes, likely due to their enriched sources or mixing with enriched magma. Whereas G1 and its host mafic rocks form typical bimodal intrusions of the same age and similar Sr–Nd–Hf isotope compositions, G2 is younger than its host mafic rocks and its Sr–Nd–Hf isotope composition indicates a lower crust origin. Although they exhibit arc-related geochemical features, the two granites likely formed in a rift setting, as inferred from thier petrology, Sr–Nd–Hf isotopes and regional tectonic evolution.  相似文献   

17.
The Qinling Orogen is one of the main orogenic belts in Asia and is characterized by multi-stage orogenic processes and the development of voluminous magmatic intrusions. The results of zircon U–Pb dating indicate that granitoid magmatism in the Qinling Orogen mainly occurred in four distinct periods: the Neoproterozoic (979–711 Ma), Paleozoic (507–400 Ma), and Early (252–185 Ma) and Late (158–100 Ma) Mesozoic. The Neoproterozoic granitic magmatism in the Qinling Orogen is represented by strongly deformed S-type granites emplaced at 979–911 Ma, weakly deformed I-type granites at 894–815 Ma, and A-type granites at 759–711 Ma. They can be interpreted as the products of respectively syn-collisional, post-collisional and extensional setting, in response to the assembly and breakup of the Rodinia supercontinent. The Paleozoic magmatism can be temporally classified into three stages of 507–470 Ma, 460–422 Ma and ∼415–400 Ma. They were genetically related to the subduction of the Shangdan Ocean and subsequent collision of the southern North China Block and the South Qinling Belt. The 507–470 Ma magmatism is spatially and temporally related to ultrahigh-pressure metamorphism in the studied area. The 460–422 Ma magmatism with an extensive development in the North Qinling Belt is characterized by I-type granitoids and originated from the lower crust with the involvement of mantle-derived magma in a collisional setting. The magmatism with the formation age of ∼415–400 Ma only occurred in the middle part of the North Qinling Belt and is dominated by I-type granitoid intrusions, and probably formed in the late-stage of a collisional setting. Early Mesozoic magmatism in the study area occurred between 252 and 185 Ma, with the cluster in 225–200 Ma. It took place predominantly in the western part of the South Qinling Belt. The 250–240 Ma I-type granitoids are of small volume and show high Sr/Y ratios, and may have been formed in a continental arc setting related to subduction of the Mianlue Ocean between the South Qinling Belt and the South China Block. Voluminous late-stage (225–185 Ma) magmatism evolved from early I-type to later I-A-type granitoids associated with contemporaneous lamprophyres, representative of a transition from syn- to post-collisional setting in response to the collision between the North China and the South China blocks. Late Mesozoic (158–100 Ma) granitoids, located in the southern margin of the North China Block and the eastern part of the North Qinling Belt, are characterized by I-type, I- to A-type, and A-type granitoids that were emplaced in a post-orogenic or intraplate setting. The first three of the four periods of magmatism were associated with three important orogenic processes and the last one with intracontinental process. These suggest that the tectonic evolution of the Qinling Orogen is very complicated.  相似文献   

18.
The Solânea Complex (572 ± 8 Ma) comprises various intrusions that total 200 km2. It cuts Palaeoproterozoic migmatized orthogneisses of the Serrinha–Pedro Velho Complex, which is part of the São José do Campestre Massif, North Tectonic Domain of the Borborema Province, NE Brazil. It is a post-collisional intrusion constituted of coarse-grained biotite–amphibole monzogranites, fine-grained leucogranites and diorites. Major, trace and rare earth elements data, used to constrain the origin and nature of these rocks, indicate that the monzogranites display chemical features of weakly peraluminous ferro-potassic trans-alkaline granitoids, similar to coeval occurrences described in eastern Nigerian. Sm–Nd data together with the whole rock geochemical data suggest that: (I) the monzogranites were generated by partial melting of tonalitic gneiss from the lower crust, leaving behind a granulitic residue; (II) the diorites originated by partial melting of an enriched lithospheric mantle; (III) the evolution of the Solânea Complex involved magma mixing between the monzogranites and diorites. K-feldspar and amphibole fractionation appear to have occurred during the evolution of the monzogranites.Leucogranites constituting an elliptical shaped intrusion (80 km2), the Dona Inês Pluton, are intruded to the north of the Solânea Complex. They also occur as small intrusions cross-cutting the border of the Solânea Complex. Geochemical and isotopic data suggest that the leucogranites were generated by melting of crustal Palaeoproterozoic rocks. Rb–Sr data gave an age of 544 ± 16 Ma.Trans-alkaline magmatism is associated with ductile–brittle deformation in the Serrinha–Pedro Velho Complex of the São José do Campestre Massif. This event follows the peak of an extensional-related high-temperature metamorphism (upper amphibolite to granulite facies), with estimated age of 578 to 574 Ma. If a pre-Gondwana reconstruction is considered, this event is seen to extend to the African side of Gondwana in eastern Nigeria.  相似文献   

19.
We have investigated the petrography, geochemistry, and detrital zircon U–Pb LA-ICPMS dating of sandstone from the Gorkhi Formation of the Khangai–Khentei belt in the Ulaanbaatar area, central Mongolia. These data are used to constrain the provenance and source rock composition of the accretionary complex, which is linked to subduction of the Paleo-Asian Ocean within the Central Asian Orogenic Belt during the Middle Devonian to Early Carboniferous. Field and microscopic observations of the modal composition of sandstone and constituent mineral chemistry indicate that the sandstone of the Gorkhi Formation is feldspathic arenite, enriched in saussuritized plagioclase. Geochemical data show that most of the sandstone and shale were derived from a continental margin to continental island arc setting, with plutonic rocks being the source rocks. Detrital zircon 206Pb/238U ages of two sandstones yields age peaks of 322 ± 3 and 346 ± 3 Ma. The zircon 206Pb/238U age of a quartz–pumpellyite vein that cuts sandstone has a weighted mean age of 339 ± 3 Ma. Based on these zircon ages, we infer that the depositional age of sandstone within the Gorkhi Formation ranges from 320 to 340 Ma (i.e., Early Carboniferous). The provenance and depositional age of the Gorkhi Formation suggest that the evolution of the accretionary complex was influenced by the intrusion and erosion of plutonic rocks during the Early Carboniferous. We also suggest that spatial and temporal changes in the provenance of the accretionary complex in the Khangai–Khentei belt, which developed aound the southern continental margin of the Siberian Craton in relation to island arc activity, were influenced by northward subduction of the Paleo-Asian Ocean plate.  相似文献   

20.
Three plutons (Deh-Siahan, Bande-Bagh and Baghe-Khoshk Sharghi, collectively referred to as the DBB hereafter) in southwestern Kerman, in the southeastern part of the Urumieh–Dokhtar magmatic assemblage (UDMA) of the Zagros orogenic belt differ from the typical calc-alkaline metaluminous, I-type intrusions of the region. The DBB intrusions have a distinct lithological assemblage varying from diorite through monzogranite and monzonite to alkali feldspar syenite and alkali granite. The DBB granitoids are metaluminous to slightly peraluminous, alkaline to shoshonitic in composition and have high total alkali contents with K2O > Na2O, high FeOT/MgO values, and low CaO and MgO contents. They are enriched in some LILEs (such as Rb and Th) and HFSEs (such as Zr, Y and REEs except Eu) and depleted in Sr and Ba relative to primordial mantle, and have low concentrations of transitional metals. These features along with various geochemical discriminant diagrams suggest that the DBB granitoids are post-collisional A-type granitoids, which had not been recognized previously in the UDMA. The chondrite-normalized REE patterns of the DBB granitoids show slightly enriched light REEs [(La/Sm)N = 2.26–4.13], negative Eu anomalies [(Eu/Eu*)N = 0.19–0.74] and flat heavy REE patterns [(Gd/Yb)N = 0.80–1.87]. The negative Eu anomaly indicates an important role for plagioclase and/or K-feldspar during fractional crystallization. Whole-rock Rb–Sr isotope analysis yields an isochron age of 33 ± 1 Ma with an initial 87Sr/86Sr value of 0.7049 ± 0.0001. Whole-rock Sm–Nd isotope analysis gives εNdt values from + 2.56 to + 3.62 at 33 Ma. The positive εNdt and low ISr values of the DBB granitoids together with their TDM of 0.6–0.7 Ga suggest their formation from partial melting of a lithospheric mantle source, modified by fluids or melts from earlier subduction processes. Melting of lithospheric mantle occurred via a dehydration melting process at pressures below the garnet stability field, as a consequence of lithospheric mantle delamination or break-off of a subducted slab and melting of the lithospheric mantle by upwelling of hot asthenosphere. On the basis of Rb/Sr age dating and the post-collisional geochemical signatures of the DBB granitoids, along with extensive pre-collisional volcanic eruptions in Middle Eocene, we suggest Late Eocene for the time of collision between the Arabian and Central Iranian plates. This also implies that the calc-alkaline I-type intrusions in the southwestern Kerman and in other parts of the UDMA may have formed in a post-collisional context.  相似文献   

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