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1.
Mining dumps are major sources of pollutants within the mining area of Lausitz, especially sulphate and iron. Their existence in catchment areas comprising groundwater bodies or lakes often imposes negative effects on the water quality. The European Union Water Framework Directive [EU-WFD, 2000. Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 establishing a framework for Community action in the field of water policy. The European Parliament and Council, L327/1, p. 72] aims to achieve ‘good quality’ status for all water bodies across Europe by 2015. Consequently, predicting the development of ground and lake water quality is necessary and must be based on the geochemical composition of the mining dumps. Therefore, the dumps need to be quantified as pollutant sources.A method to calculate the amount of sulphate in mine dumps is presented. It is based on historic geological and geochemical data characterising the pre-mining situation. Additional information on the dump body, derived from the vertical extension of mining activities and the current Digital Elevation Model (DEM), allows the composition of the dump to be determined. This procedure is demonstrated for the Bärwalde site. An average total sulphur content of 0.62% (5.9 million tonnes) was calculated for the Bärwalde dump. About 40% of it is estimated to be pyrite sulphur. Applying an average pyrite oxidation rate for the whole dump body of 7% led to an additional water-soluble mass of 0.18 million tonnes of sulphate sulphur.Applying this technique to all mine dumps managed by the postmining administration company LMBV, will improve our knowledge of the catchment area for the different lakes of Lausitz and will form an essential basis for reactive transport calculations.  相似文献   

2.
Samples around a coal gangue dump of the Gequan Coal Mine were collected in April 2009. GC (gas chromatography) and GC/MS (gas chromatography/mass spectrometry) were employed to analyze the composition of organic matter in the samples. ICP-MS (inductively coupled plasma mass spectrometry) was used to determine the concentrations of heavy metals. The contents of organic extracts are within the range of 140-750 mg/kg. Alkand aro-ratios are relatively high. Compared to those of the background sample (GQ13 ), the contents of saturated hydrocarbon compounds in all the samples are relatively high. The contents of polycyclic aromatic hydrocarbons (PAHs) are relatively high with the distance getting closer to the coal gangue dump. These indicate that organic matter in the samples is from coal particles of the coal gangue dump. The distributions of heavy metals are very similar: the contents decrease with distance from the dump, which indicates that the harmful heavy metals from the coal gangue dump have polluted as thick as at least 500 m.  相似文献   

3.
Mine tailings present an important legacy of past and present ore-extraction activities in the Desert Southwest. Inactive mine tailings have no immediate economic role in current mining operations, yet from an environmental point of view it is important that such deposits are stabilized to prevent mass movement, wind or water erosion, leaching of chemicals such as acid mine drainage, and to reduce visual blight. In the presented study, we assess the potential for inferring textural properties of mine tailing deposits with electromagnetic induction (EMI) mapping as a means of informing efforts to establish vegetation at mine waste sites. EMI measurements of apparent electrical conductivity (ECa) and tailing samples were collected at a mine waste site in Southern Arizona, USA and used to test empirical and theoretical relationships between ECa and physical and mineralogical properties using linear and Gaussian process regression. Sensitivity analyses of a semi-theoretical and a regression model of ECa as a function of tailing properties indicated that volumetric clay fraction in the top 60 cm was a primary influence on bulk electrical conductivity along with water content, conductivity of the soil water and the presence of conductive minerals hematite and pyrite. At this site, latitude and longitude were better predictors of clay content than ECa, and while it was possible to obtain information about the spatial distribution of tailing texture using EMI, simple Kriging of texture data was a more powerful textural mapping technique. We conclude that EMI is a useful tool for mapping tailing texture at waste deposit sites, but due to physical and chemical heterogeneity of tailing deposits, it is necessary to collect more in situ samples than are needed for agricultural applications.  相似文献   

4.
Sediment from the sewage sludge dump site area in the New York Bight contains bacteria resistant to antibiotics and heavy metals. The purpose of this study was to determine if antibiotic resistance could be transferred from donor to recipient Escherichia coli strains inoculated into glass vessels containing sediment and seawater obtained near the dump site. Temperature was maintained at 10°C, the mean winter temperature of benthic water at the dump site. Transconjugants (recipients which inherit donor genes for tetracycline resistance) were isolated from the seawater and sediment within one hour after inoculation and were found in all subsequent sediment samples for one month. Donor and recipient E. coli remained viable in the sediment for at least one month. Our results indicate that sewage sludge polluted sediment may serve as an environment conducive to conjugal transfer of antibiotic resistance genes.  相似文献   

5.
The geochemistry of a dry dump of arsenic production wastes and a groundwater protection zone were studied with the use of macro- and microanalysis of aqueous and hydrochloric-acid extracts. The accumulation of water-soluble forms of the microcomplex is maximal in the surface layer of the cinder dump, in sulfate-acid zone. Here, aluminosilicates suffer acid destruction. The downward motion of sulfate-iron front at a decrease in medium acidity is accompanied by gypsum formation and the hydrolysis of sulfate salts with subsequent formation of Fe, Al, and Mn hydroxides. The technogenic geochemical sorption barriers, which form in this process, ensure self-conservation of pollution source. In the protection zone, carbonate-alkaline barrier completes the immobilization process. Over the 70 years of dump existence, only a small part of its immobilization potential have been utilized. The sulfate-acid process can be suppressed through the isolation of the dump from atmospheric moistening. The vulnerability of water objects is zero. The evacuation of the dump is not required, as local reclamation is enough.  相似文献   

6.
松原灌区建设对查干湖生态风险分析及对策   总被引：1，自引：1，他引：0  
松原灌区将对国家自然保护区查干湖周围的盐碱地实施大面积围垦,若大量高浓度碱性尾水直排入湖,将导致查干湖生态系统严重污染.对这一风险合理评估并防范,关系到湖区生态安全与灌区的可行.本文在对湖区生态环境及灌区尾水排放模式与含盐特性系统分析基础上,提出利用退化沼泽湿地(盐沼)构建湿地处理系统(生态缓冲区),而非直接入湖的构想.当灌区运行一定时期,尾水水质得到改善,再入湖发挥补水效应.同时在设计上采取盐碱地分批滚动开发,以控制年排盐总量,降低排盐强度;以及充分利用碱湖泡随机承泄,减轻对查干湖的压力,既可防止湖水污染,又可保证灌区建设可行.  相似文献   

7.
The aim of the present study was to evaluate the mixed function oxidase (MFO) system and the forms of supposed cytochrome P-450 in the liver of black-headed gulls (Larus ridibundus) feeding in a lagoon and on a garbage dump. Tissue levels of polychlorinated biphenyls (PCBs) were also determined. Ethoxyresorufin 10-deethylase (EROD) and aldrin epoxidase activities were higher in the dump gulls than in the lagoon gulls. A marked thickening of the proteins in the cytochrome P-450 area, particularly of P-450c and P-450d, was also found in the dump gulls. No relationship was found between MFO activity and tissue chlorinated hydrocarbon levels.  相似文献   

8.
Submarine ground water discharge (SGD) is now recognized as an important water pathway between land and sea. It is difficult to quantitatively predict SGD owing to its significant spatial and temporal variability. This study focuses on quantitative estimation of SGD caused by tidally induced sea water recirculation and a terrestrial hydraulic gradient. A two-dimensional hydrogeological model was developed to simulate SGD from a coastal unconfined aquifer in the northeastern Gulf of Mexico, where previous SGD studies were performed. A density-variable numerical code, SEAWAT2000, was applied to simulate SGD. To accurately predict discharge, various influencing factors such as heterogeneity in conductivity, uncertain boundary conditions, and tidal pumping were systematically assessed. The tidally influenced sea water recirculation zone and the fresh water–salt water mixing zone under various tidal patterns, tidal ranges, and water table heights were also investigated. The model was calibrated and validated from long-term, intensive measurements at the study site. The percentage of fresh SGD relative to total SGD ranged from 4% to 50% under normal conditions. Based on simulations of two field measurements in summer and spring, respectively, the fresh water ratios were 9% and 15%, respectively. These results support the hypothesis that the SGD induced by tidally driven sea water recirculation is much larger than terrestrial fresh ground water discharge at this site. The estimates of total and fresh SGD are at the low and high ends, respectively, of the estimation ranges obtained from geochemical tracers (e.g., 222Rn).  相似文献   

9.
Analytical Model for Contaminant Mass Removal by Air Sparging   总被引：2，自引：0，他引：2  
An analytical model was developed lo predict the removal of volatile organic compounds (VOCs) from ground water by air sparging (AS). The model treats the air sparging zone as a completely mixed reactor subject to the removal of dissolved contaminants by volatilization, advection, and first-order decay Nonequilibrium desorption is approximated as a first-order mass transfer process. The model reproduces the tailing and rebound behavior often observed at AS sites, and would normally require the estimation of three site-specific parameters. Dimensional analysis demonstrates that predicted tailing can be interpreted in terms of kinetic desorption or diffusion of aqueous phase contaminants into discrete air channels. Related work is ongoing to test the model against field data.  相似文献   

10.
In Bermuda, bulk waste such as scrap metal, cars, etc., and blocks of cement-stabilized incinerator ash (produced from burning garbage) are disposed of in a foreshore reclamation site, i.e., a seafill. Chemical analyses show that seawater leaching out of the dump regularly exceeds water quality guidelines for Zn and Cu, and that the surrounding sediments are enriched in multiple contaminant classes (metals, polycyclic aromatic hydrocarbons, petroleum hydrocarbons, dioxins and furans, polychlorinated biphenyls and an organochlorine pesticide), i.e., there is a halo of contamination. When compared against biological effects-based sediment quality guidelines (SQGs), numerous sediment samples exceeded the low-range values (where biological effects become possible), and for Hg and Zn exceeded the mid-range value (where they become probable). A few metres away from the edge of the 25 acre dump lies a small coral patch reef, proposed here as most contaminated coral reef in the world.  相似文献   

11.
This paper examines a variety of recirculation flow patterns that develop in the groyne fields on rivers. A comprehensive data set was obtained from flume experiments at Delft University of Technology and field measurements performed on the Elbe River in Germany. The analysis focuses on patterns of velocity, scour and deposition, and corresponding change of riverbed morphology. The results show that velocity patterns in the groyne fields depend mainly on the aspect ratio between groyne length and length of groyne field. When the aspect ratio is greater than 0·5, a one‐gyre pattern of recirculation develops, while at groyne fields with aspect ratios less than 0·5 a two‐gyre recirculation pattern emerges. The spatial distribution of fine‐sediment deposition between the groynes coincides with the locations of gyres. Moreover, the thickness of the fine‐sediment layer decreases toward the gyre margins where recirculation velocities are greatest. Although the total concentration of suspended sediment in the river does not change considerably as the flow moves through the groyne field, the biological and gravimetrical composition of the suspended material changes substantially within the groyne field. These changes are due to preferential deposition of coarse mineral particles and the replacement of those minerals with finer organic material. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

12.
A two-dimensional (2D) unsteady simulation model is applied to the problem of a submerged warm water discharge into a stratified lake or reservoir with an ice cover. Numerical simulations and analyses are conducted to gain insight into large-scale convective recirculation and flow processes in a cold waterbody induced by a buoyant jet. Jet behaviors under various discharge temperatures are captured by directly modeling flow and thermal fields. Flow structures and processes are described by the simulated spatial and temporal distributions of velocity and temperature in various regions: deflection, recirculation, attachment, and impingement. Some peculiar hydrothermal and dynamic features, e.g. reversal of buoyancy due to the dilution of a warm jet by entraining cold ambient water, are identified and examined. Simulation results show that buoyancy is the most important factor controlling jet behavior and mixing processes. The inflow boundary is treated as a liquid wall from which the jet is offset. Similarity and difference in effects of boundaries perpendicular and parallel to flow, and of buoyancy on jet attachment and impingement, are discussed. Symmetric flow configuration is used to de-emphasize the Coanda effect caused by offset.  相似文献   

13.
The Batu Hijau copper/gold mine in Sumbawa, Indonesia processes ore at approximately 130,000 tpd and discharges tailing via a submarine pipeline to depths below 3000 m at the base of a submarine canyon. The study investigated recolonisation of tailing by meiofauna and its dependence on subsequent accumulation of natural sediment. Microcosm and mesocosm scale experiments were carried out using two tailing and two control samples, the latter comprising defaunated and unaffected natural sediment. All test materials were similar in physical and chemical respects, except for the higher copper concentration in the tailing. The abundances of meiofauna colonising defaunated controls and both tailing samples increased from zero to levels statistically indistinguishable from natural unaffected controls after 97 and 203 days. Colonisation was well established in tailing from freshly mined ore after 40 days, and in oxidized tailing from stockpiled ore after 65 days, and was not dependent on settled natural material.  相似文献   

14.
Lozovitskii  P. S.  Bilai  V. A. 《Water Resources》2001,28(4):451-460
The presented results were obtained by studying the effect of the rates of application of phosphogypsum and sulphuric acid and their simultaneous introduction into the irrigation water on the concentrations of ions, alkalinity, chemical composition, TDS, and irrigation characteristics of the irrigation water as a function of the water initial composition and the time of saturation.  相似文献   

15.
The oceanic pathways connecting the Pacific Ocean to the Indian Ocean are described using a quantitative Lagrangian method applied to Eulerian fields from an ocean general circulation model simulation of the Indonesian seas. The main routes diagnosed are in good agreement with those inferred from observations. The secondary routes and the Pacific recirculation are also quantified. The model reproduces the observed salt penetration of subtropical waters from the South Pacific, the homohaline stratification in the southern Indonesian basins, and the cold fresh tongue which exits into the Indian Ocean. These particular water mass characteristics, close to those observed, are obtained when a tidal mixing parameterization is introduced into the model. Trajectories are obtained which link the water masses at the entrance and at the exit of the Indonesian throughflow (ITF), and the mixing along each trajectory is quantified. Both the ITF and the Pacific recirculation are transformed, suggesting that the Indonesian transformation affects both the Indian and Pacific stratification. A recipe to form Indonesian water masses is proposed. We present three major features of the circulation that revisit the classical picture of the ITF and its associated water mass transformation, while still being in agreement with observations. Firstly, the homohaline layer is not a result of pure isopycnal mixing of the North Pacific Intermediate Water and South Pacific Subtropical Water (SPSW) within the Banda Sea, as previously thought. Instead, the observed homohaline layer is reproduced by the model, but it is caused by both isopycnal mixing with the SPSW and a dominant vertical mixing before the Banda Sea with the NPSW. This new mechanism could be real since the model reproduces the SPSW penetration as observed. Secondly, the model explains why the Banda Sea thermocline water is so fresh compared to the SPSW. Until now, the only explanation was a recirculation of the freshwater from the western route. The model does not reproduce this recirculation but instead shows strong mixing of the SPSW within the Halmahera and Seram Seas, which erodes the salinity maximum so that its signature is not longer perceptible. Finally, this work highlights the key role of the Java Sea freshwater. Even though its annual net mass contribution is small, its fresh salinity contribution is highly significant and represents the main reason why the Pacific salinity maxima are eroded.  相似文献   

16.
In Carrara marble basins, the long and intensive quarrying activities (which began in the first century BC ) have produced extensive dump deposits, locally known as ravaneti. Ravaneti are of such large dimensions and diffusion as to make them a widespread landform of the Apuane Alps (Tuscany). In recent years these quarry dump deposits have been affected by frequent debris flows, more than 50 in 1996/97. This phenomenon is the most significant currently active geomorphological process in this landscape. The evolution of quarrying techniques produced a variety of sedimentological compositions of ravaneti. The debris flows analysed involve only the surface layers where debris is mixed with fine material with a lower permeability (active ravaneti) than the coarser underlying debris (older ravaneti). The presence of different permeability layers causes a wetting front to move downwards. Source area observations indicate a soil slip movement in the initial phases of the failure. The transformation of landslides into debris flow occurs by means of both soil contractive failure and an increase of granular temperature. The morphological and sedimentological analyses of depositional lobes resulted in a classification of three types of lobe, based on fabric–morphometry relationships allowing the identification of different flow dynamics: (1) type A lobe (platy form), matrix‐supported and well developed fabric with general tendency of ab clast plane strikes to lie generally parallel to flow direction as a consequence of laminar flow; (2) type B lobe (elongated form), clast‐supported and random fabric as a consequence of both turbulent flow and coarser composition of starting material; (3) type C lobe, intermediate type A–B morphometry, tendency for ab clast plane to lie in a semi‐circle around the main flow direction determined by the presence of secondary flow lines divergent from it in the stopping phase. In Carrara marble basins, the anomalous frequency with which debris flows tend to be triggered by medium‐intensity rainstorms (about 30 mm h−1 rainfall) is due to the recent increases in silt dump produced by modern quarrying techniques. This represents a significant example of debris flows as an environmental problem in major anthromorphized landscapes. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

17.
A microbiological study of an historically active dredge spoil disposal area in Long Island Sound showed no obvious long-term effects on the bacterial populations of water and sediment. Observations were made 4 years after the last deposition of dredge spoils. Determinations included total and faecal coliforms and numbers, hydrolytic types, and taxonomic groupings of ‘total’ heterotrophic bacteria. Comparisons with water and sediment from other areas of the sound indicated that the dump site was not bacteriologically unique.  相似文献   

18.
A biomarker study was undertaken using the Calico scallop Argopecten gibbus to assess the ecotoxicological effects of a semi-submerged municipal dump on the adjacent patch reef lagoon ecosystem (Castle harbour, Bermuda). Caged scallops were deployed in situ for 2 months at various distances from the dump (50 m, 900 m and 2.7 km) and at a reference site (14 km). A suite of biomarkers comprising metallothionein (MT), lipid peroxidation (LPO), vitellin-like proteins (Vn), glutathione S-transferase (GST), DNA strand breaks and condition factor (CF) were investigated in various tissues of the scallop (gill, digestive gland and gonad). Levels of heavy metals were also measured in the whole scallop soft tissue. While there was some variation in response between tissues, in general the results indicated that the dump was negatively impacting scallops deployed in the adjacent marine environment: elevated levels of MT, DNA strand breaks, Vn and GST and reduced condition factor were found for scallops deployed nearest to the dump and at the site 1.5 km from this point source of contamination (Tuckers town) in Castle harbour, with respect to the reference site, North Rock (although this exhibited some degree of metal contamination). The gills from scallops deployed at the dump site were the most responsive tissue, with the highest expression of MT, LPO and DNA damage. This study indicates the potential of the Calico scallop as a convenient bioindicator species in the marine tropical benthos.  相似文献   

19.
Right-side bias in both sea surface cooling and phytoplankton blooms is often observed in the wake of hurricanes in the Northern Hemisphere. This idealized hurricane modeling study uses a coupled biological-physical model to understand the underlying mechanisms behind hurricane-induced cooling and phytoplankton bloom asymmetry. Both a deep ocean case and a continental shelf sea case are considered and contrasted. Model analyses show that while right-side asymmetric mixing due to inertial oscillations and restratification from strong right-side recirculation cells contributes to bloom asymmetry in the open ocean, the well-mixed condition in the continental shelf sea inhibits formation of recirculation cells, and the convergence of water onto the shelf is a more important process for bloom asymmetry.  相似文献   

20.
Heat as a tracer in fractured porous aquifers is more sensitive to fracture-matrix processes than a solute tracer. Temperature evolution as a function of time can be used to differentiate fracture and matrix characteristics. Experimental hot (50 °C) and cold (10 °C) water injections were performed in a weathered and fractured granite aquifer where the natural background temperature is 30 °C. The tailing of the hot and cold breakthrough curves, observed under different hydraulic conditions, was characterized in a log–log plot of time vs. normalized temperature difference, also converted to a residence time distribution (normalized). Dimensionless tail slopes close to 1.5 were observed for hot and cold breakthrough curves, compared to solute tracer tests showing slopes between 2 and 3. This stronger thermal diffusive behavior is explained by heat conduction. Using a process-based numerical model, the impact of heat conduction toward and from the porous rock matrix on groundwater heat transport was explored. Fracture aperture was adjusted depending on the actual hydraulic conditions. Water density and viscosity were considered temperature dependent. The model simulated the increase or reduction of the energy level in the fracture-matrix system and satisfactorily reproduced breakthrough curves tail slopes. This study shows the feasibility and utility of cold water tracer tests in hot fractured aquifers to boost and characterize the thermal matrix diffusion from the matrix toward the flowing groundwater in the fractures. This can be used as complementary information to solute tracer tests that are largely influenced by strong advection in the fractures.  相似文献   

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