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1.
Mechanism of the three-phase contact (TPC) formation and phenomena occurring during collisions of the ascending bubble with a solid and flat surface were studied. Three fluorite samples of different origins and surface roughness and smooth mica plates were investigated. It was found that the time-scale and the mode of air bubble/flat fluorite surface bouncing and attachment significantly depended on the surface roughness. For smooth fluorite surfaces the time of the TPC formation and the bubble attachment was over 150 ms while for rough surfaces it was 5 to 45 ms. It was also shown that the TPC formation at fluorite and mica surfaces was determined mainly by the electrical charge of the interacting interfaces. A small amount of cationic surfactant (n-octyltrimethylammonium bromide) was used to reverse the sign of electrical charge of the bubble surface. In n-octyltrimethylammonium bromide presence there was no TPC formation at the fluorite surface due to repulsions between positively charged interfaces, but the bubble attachment to negatively charged mica surface was observed due to attractive electrostatic interactions. It was also determined that there was no TPC formation at pHs when the signs of zeta potentials of the solution/gas and solution/fluorite interfaces were the same.  相似文献   

2.
Roughness and wear evolution of three different joint wall surfaces were characterized using surface roughness and surface wear parameters. Parameters were defined by considering the two components of morphology: waviness (“primary” roughness) and surface roughness (“secondary” roughness). Two surface roughness parameters are proposed: joint interface (or single wall) specific surface roughness coefficient SR s (0 ≤ SR s  ≤ 1) for quantifying the amount of “pure” roughness (or specific roughness), and degree of joint interface (or single wall) relative surface roughness DR r (0 ≤ DR r  ≤ 0.5). Two further parameters are also proposed in order to quantify the wear of wall surface: joint interface (or single wall) surface wear coefficient Λinterface, and the degree of joint interface (or single wall) surface wear D w(interface). The three test specimens were: man-made granite joints with hammered surfaces, man-made mortar joints with corrugated surfaces, and mortar joints prepared from natural rough and undulated schist joint replicas. Shearing under monotonic and cyclic shearing was performed using a computer-controlled bidirectional and biaxial shear apparatus. Joint surface data were measured using a noncontact laser sensor profilometer prior to and after each shear test. Calculation of specific surface roughness coefficient SR s , and degree of surface wear D w , indicated that the hammered joint interface with predominant interlocking wears much more (>90%) than the corrugated (27%) and the rough and undulated (23%) joint interfaces having localized interlocking points. The proposed method was also successfully linked to the classical wear theory.  相似文献   

3.
A particle–bubble attachment apparatus, similar to that used by Whelan and Brown [Bull. Inst. Min. Met. Trans. 65 (1956) 181] is developed to study free falling glass beads (dp=131 μm) with different surface treatment attaching to a stationary air bubble (db=3 mm). The entire process of the particle–bubble attachment is photographically recorded using a high framing-rate camera and analyzed frame by frame. It is found that the hydrophilic particle slides on the top half of the bubble, and then the particle leaves the bubble, as anticipated. The particle sliding velocity increases with increasing angular position on the bubble surface. For the hydrophobic particle, it was found that the particle slides over the entire bubble surface without detaching from the bubble. The sliding velocity, however, reaches a maximum at an angular position of 90–100°, and then slows down to zero. A smaller sliding velocity is obtained for the hydrophobic particle than that of the hydrophilic particle at a given angular position. The attachment efficiency for the hydrophobic particle reduces with increasing initial angular positions, suggesting that the hydrophobicity alone does not directly guarantee the attachment to a bubble. Adding surfactant (sodium dodecyl sulfate [SDS]) to the test solution makes the hydrophobic particle become less hydrophobic or even hydrophilic, thereby decreasing the attachment efficiency. A much longer induction time is obtained in our present work than that reported in the literature. A simplified particle sliding velocity and attachment model is developed, and a good agreement between the theoretical prediction and experimental measurement is obtained.  相似文献   

4.
Bubble–particle encounter during flotation is governed by liquid flow relative to the rising bubble, which is a function of the adsorbed frothers, collectors, and other surfactants and surface contaminants. Due to surface contamination, the bubble surface in flotation has been considered as immobile (rigid). However, surface contamination can be swept to the backside of the rising bubble due to the relative liquid flow, leaving the front surface of the rising bubble mobile with a non-zero tangential component of the liquid velocity. The bubble with a mobile surface was considered by Sutherland who applied the potential flow condition and analyzed the bubble–particle encounter using a simplified particle motion equation without inertia. The Sutherland model was found to over-predict the encounter efficiency and has been improved by incorporating inertial forces which are amplified at the mobile surface with a non-zero tangential velocity component of the liquid phase. An analytical solution was obtained for the encounter efficiency using approximate equations and is called the Generalized Sutherland Equation (GSE). In this paper, the bubble–particle encounter interaction with the potential flow condition has been analyzed by solving the full motion equation for the particle employing a numerical computational approach. The GSE model was compared with the exact numerical results for the encounter efficiency. The comparison only shows good agreement between the GSE prediction and the numerical data for ultrafine particles (< 10 μm in diameter), the inertial forces of which are vanishingly small. For non-ultrafine particles, a significant deviation of the GSE model from the numerical data has been observed. Details of the numerical methodology and solutions for the (collision) angle of tangency and encounter efficiency are described.  相似文献   

5.
Eight techniques to quantify the deposition of aeolian dust on horizontal surfaces were tested in a wind tunnel. The tests included three theoretical techniques and five measurement techniques. The theoretical techniques investigated were: the gradient technique, the inferential technique without grain-shape correction, and the inferential technique corrected for grain shape. The measuring techniques included the following surrogate surfaces: a water surface, a glass surface, a metal surface, a vertical array of metal plates, and an inverted frisbee filled with glass marbles. The efficiency of the techniques was investigated for the sediment as a whole (all grain sizes together) as well as for a large number of grain sizes extending from 1 to 104 μm. The surrogate surfaces showed more or less comparable catch efficiencies, although the water surface nearly always caught the highest quantities of dust and the marble-filled frisbee and the vertical array of metal plates the lowest quantities of dust. The dust fluxes calculated by theoretical methods were markedly different from those obtained by direct measurements. The fluxes calculated by the inferential technique approximated those of the direct measurements only for grain sizes between 30 and 40 μm. For smaller and coarser grains, deviations from the measured fluxes were high. The gradient method, in its turn, provided extremely low calculated fluxes for grains in all size classes investigated. The latter technique was not considered very reliable for the dust used in the tests.  相似文献   

6.
Two-dimensional Hurst Index of Joint Surfaces   总被引：2，自引：1，他引：2  
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7.
Development of deflation lag surfaces   总被引：3，自引：0，他引：3  
A series of wind tunnel tests were carried out to investigate the development of deflation lags in relation to the non-erodible roughness element concentration. Glass spheres (18 mm in diameter) were placed along the complete length of the wind tunnel working section in regular staggered arrays using three different spacings (d=18, 30 and 60 mm) and completely covered with a 0.27-mm erodible sand. A pre-selected free stream velocity above threshold (8m s?1) was established above the surface and the sediment transport measured at 2-s intervals using a wedge-shaped trap in which an electronic balance is incorporated. Throughout each test, the emerging lag surface was periodically photographed from above at two locations upwind of the trap. The photographs were electronically scanned and analysed to calculate the lag element coverage and location, as well as mean height and frontal area for each time period. Test results indicate that lag development has a profound effect on both the sediment flux and wind profile characteristics. Initially, there is an increase in sediment flux above that for a rippled sand bed because of increased erosion around and reduced kinetic energy loss in highly elastic collisions with the emerging roughness elements. With further emergence, a dynamic threshold is reached whereupon the sediment flux decreases rapidly, tending towards zero. At this point, the supply of grains to the air stream through fluid drag follows a reduction in aerodynamic roughness and, therefore, surface shearing stress. At least as important is the lesser potential for grain ejection at impact because of reduced momentum imparted from the air stream during saltation. Although recent shear stress partitioning models indicate when particle movement may commence on varying surfaces, our experimental results demonstrate that this partitioning has a further direct bearing upon the saltation flux ratio.  相似文献   

8.
Building stones manufactured from contact metamorphic slates (Fruchtschiefer slate) from Theuma (Sachsen, Germany) were investigated for mineralogical alterations as well as for changes in porosity and surface roughness due to weathering. After weathering periods of several years to decades, the originally dark gray-colored slates show pale spots of several centimeters in size at the surface of building stones. The dark-colored and light-colored sections of the slate show no differences in mineralogy. Surface weathering did not result in newly precipitated minerals. It was also found that the observed differences in color are not caused by variations in sedimentary organic carbon concentration or in sulfide/sulfate concentrations. Obtained results instead indicate that dark surface sections may show a thin cover of recent organic matter (OM), e.g., living OM, soot, dirt, etc. Microscopic investigations suggested that this cover was exfoliated at light-colored surface sections. The observed disaggregation of the upper 2 mm of the building block material results in an increase in porosity. Porosity of black (unweathered) slate is <2 vol.%. Due to weathering, the slate’s pores with diameters >1 μm show a significant increase in frequency compared to the original pore size distribution. Porosity of weathered rock volumes increased to approx. 8 vol.%. Discolored surface sections show a higher surface roughness (root-mean-square roughness, Rq ~ 1 μm) compared to dark-colored slate surfaces (Rq ~ 200 nm), both data are for cleavage planes. Preferentially, the discolored surface sections are located close to the edges of cut stones. This and the alteration in porosity, pore size, and surface roughness indicate that color changes of the slate are largely influenced by rock disaggregation proceeding from the edges into the center rather than by mineral dissolution/precipitation processes.  相似文献   

9.
Degree of rock surface weathering was measured on sites in Oldedalen and Brigsdalen, where dates of deglaciation have been estimated. and on an altitudinal transect on the slopes of Skåla. representing one of the highest supra-marine reliefs in western Norway. The Schmidt hammer is useful only for distinguishing sites deglaciated during the Little Ice Age from those deglaciated during the Lateglacial and early Holocene. Degree of roughness of granitic augen gneiss bedrock surfaces was quantified from profiles measured in situ using a micro-roughness-meter and profile gauge. There is a significant increase in surface roughness above a clear trimline at c. 1350 m a.s.I. but no significant increase above a higher trimline previously proposed as the vertical limit of the last ice sheet in this area (c. 1560 m a.s.I.). The roughness of boulder surfaces on the summit blockfield does not direr significantly from the roughness of bedrock surfaces downslope as far as the lower trimline. These unexpected results suggest that bedrock surfaces between the two trimlines were not glacially abraded during the Late Weichselian, so that the upper trimline is unlikely to represent the vertical limit of ice during either the Late Weichselian or a subsequent readvance. Preliminary results of 10Be dating of surface quartz samples from above the lower trimline support the proposal that the site was not abraded during the last glaciation. The results can be interpreted in two ways: (1) The upper trimline represents the vertical limit of a pre-Late Weichselian advance. During the Late Weichselian the mountains were completely covered but surfaces down to the lower trimline were protected by cold-based ice. (2) The lower trimline marks the vertical limit of the Late Weichselian ice and the upper limit an older and more extensive glaciation.  相似文献   

10.
Synchrotron X-ray reflectivity (SXR) was used to measure the thickness of the water film that adsorbs on a {} cleavage surface of calcite (CaCO3) in a sample chamber where relative humidity could be controlled within the range from <4% to 90%. Gases used to carry water vapour were initially either 100% N2 or 100% CO2. The product water film was remarkably constant in thickness at 15.5 Å (±1 Å) and independent of humidity. When N2 was used as the carrier gas, this film displayed a gap in its electron density at between 0.6 and 2 Å distance from the calcite surface, depending on humidity. This implies that a change in the arrangement of water molecules occurs in direct proximity to the surface. This electron density discontinuity was measurably further from the calcite surface, at 3.4 Å, when CO2 was used as the carrier gas. Except for this thin low density region proximate to the calcite surface, the density of the adsorbed water layer was 0.9 g cm−3, therefore suggesting a significant degree of ordering. Atomic force microscopy (AFM) images were completed in conjunction with the SXR measurements on similarly prepared calcite cleavage surfaces. AFM showed that terraces may be atomically flat over 1 μm or more. SXR corroborated this observation, with results showing that carefully cleaved surfaces had a starting root mean square (r.m.s.) roughness of ∼1.2 Å. Diffuse scatter measurements constrained the correlation lengths of these surfaces to be at least 18,000 Å. For comparison with the cleaved samples, a surface was also prepared by chemo-mechanical Syton polishing. This surface gave an r.m.s roughness by SXR that was an order of magnitude higher, equal to 12.1 Å. In this case, diffuse scatter resolved a correlation length of 950 Å, and revealed a fractal dimension that was higher than for the cleaved surface. On Syton polished samples, the water film determined by SXR was about twice as thick as for freshly cleaved surfaces, with a density of 1.0 g cm−3, equal to that of bulk water. However, surface roughness was too large to allow resolution of any gap in the electron density within the water layer proximate to the solid surface. Our AFM observations also confirm previous reports of calcite surface recrystallization. The electron density of the solid surface determined by SXR is indistinguishable from that of calcite, indicating that any material recrystallized within the adsorbed water film is compositionally indistinguishable from the calcite substrate.  相似文献   

11.
This study describes changes of surface roughness of semifusinite and fusinite as an indicator of structural alteration resulting from heat treatment at 400–1200 °C. Surface roughness has been investigated by atomic force microscopy of inertinite concentrates from coking coals (vitrinite reflectance Rr = 1.07%–1.41%) from the Upper Silesian Coal Basin of Poland (Namurian C — Westphalian A). Unheated fusinite has a higher surface roughness than semifusinite from the same coal. The average surface roughness of semifusinite decreases with the Swelling Index of the parent coal. Heating increases the surface roughness of semifusinite and fusinite. Increase in the average surface roughness is stronger for semifusinite than fusinite and correlates to increasing reflectance of these macerals. The surface roughness of semifusinite correlates to the relative mass loss of the inertinite concentrates during heating. After heating to 1200 °C fusinite has a lower average surface roughness than semifusinite from the same coal. Consequently, average surface roughness can be used as a measure of structural alteration of inertinite group macerals during heat treatment.  相似文献   

12.
We investigate the influence of small-scale asphericity of the surfaces of dust grains on the characteristics of the two deepest absorption bands observed in the spectra of protostellar objects and stars (the 3.1 μm water-ice and 9.7 μm silicate bands). The model used has composite particles in the form of radially inhomogeneous spheres with intermediate layers in which the index of refraction changes. The observed band widths and the ratios of the optical depths at the band centers can be explained if the grains are composed of small particles consisting of silicate cores with thin ice mantles and rough surfaces. The grain surface roughness considerably broadens the profile of the silicate band.  相似文献   

13.
《Applied Geochemistry》2006,21(2):305-317
There is significant random and systematic variability in As concentrations in numerous public water system wells in Minnesota. Arsenic concentrations fluctuate above and below the USA’s As drinking water Maximum Contaminant Level (MCL) of 10 μg/L. The average As concentration is commonly within one standard deviation of the MCL. Results of intensive sampling conducted over the course of approximately 1 year at 3 public water system wells is consistent with the analysis of historic As measurements. In some cases, significant As concentration variability was noted over a short period of time. In these wells, the As concentration was less than 10 μg/L shortly after pumping started, but the As concentration increased over time to a level exceeding 10 μg/L. In these wells, the As concentration decreased to below 10 μg/L again when pumping was briefly restarted after being stopped for 4 h. The As concentration variability is likely due to As adsorption reactions between Fe oxides in the well borehole and in the aquifer near the well borehole during periods when the pump is not in operation. When it is crucial to accurately determine true average As concentrations – for example, at one of the many wells that fluctuate above and below the regulatory As limit of 10 μg/L – it is worthwhile collecting samples frequently during pumping to more accurately determine the average As concentration. Determining a reliable average depends on the standard deviation (SD) of the measurements, with more measurements required if the SD is larger.  相似文献   

14.
Conventional and non-conventional flotation for mineral processing and for water (and wastewaters) treatment and reuse (or recycling) is rapidly broadening their applications in the mining field. Conventional flotation assisted with microbubbles (30–100 μm) finds application in the recovery of fine mineral particles (< 13 μm) and flotation with these fine bubbles is being used as a solid/liquid separation to remove pollutants. The injection of small bubbles to conventional coarse bubbles flotation cells usually leads to general improvements of the separation parameters, especially for the ultrafines (< 5 μm) ore particles. Results obtained are believed to occur by enhancing the capture of particles by bubbles, one of the main drawbacks in fine ore flotation. It is believed that by decreasing the bubble size distribution (through the injection of small bubbles), increases the bubble surface flux and the fines capture. DAF or dissolved air flotation with microbubbles, treating water, wastewater and domestic sewage is known for a number of years and is now gradually entering in the mining environmental area. This technology offers, in most cases, advantages over settling, filtration, precipitation, or adsorption onto natural and synthetic adsorbents. The targets are the removal of oils (emulsified or not), ions (heavy metals and anions) and the reuse or recirculation of the process waters. Advantages include better treated water quality, rapid start up, high rate operation, and a thicker sludge. New applications are found in the mining vehicles washing water treatment and reuse, AMD (acid mining drainage) neutralization and high rate solids/water separation by flotation with microbubbles. This work reviews some recent applications of the use of microbubbles to assist the recovery of very small mineral particles and for the removal of pollutants from mining wastewaters. Emphasis is given to the design features of innovative devices showing the potential of conventional and unconventional DAF flotation.  相似文献   

15.
Four dense Scandinavian limestones were analyzed to determine their mechanical properties. The generation of dust (? 10 μm) and fines (? 90 μm) during a closed circuit vertical roller mill comminution process was correlated with the calcite crystal size distributions of each limestone. Thin sections were analyzed and by means of stereology the calcite crystal size distributions for each limestone was measured. The dust generation of limestones is governed by a surface abrasive mechanism (R2 = 0.99) and the production of fines is governed by the mechanical strength of limestones (R2 = 0.99). The overall limestone degradation mechanism is predominantly controlled by the calcite cleavage planes which reduce the power consumption during the comminution process. This study is the first step in determining the influence of limestone texture on the wear rates in heterogenous raw mixes used in closed circuit comminution equipment.  相似文献   

16.
Estuarine systems are complex environments where seasonal and spatial variations occur in concentrations of suspended particulate matter, in primary constituents, and in organic matter content. This study investigated in the laboratory the flocculation potential of estuarine-suspended particulate matter throughout the year in order to better identify the controlling factors and their hierarchy. Kinetic experiments were performed in the lab with a “video in lab” device, based on a jar test technique, using suspended sediments sampled every 2 months over a 14-month period at three stations in the Seine estuary (France). These sampling stations are representative of (1) the upper estuary, dominated by freshwater, and (2) the middle estuary, characterized by a strong salinity gradient and the presence of an estuarine turbidity maximum. Experiments were performed at a constant low turbulent shear stress characteristic of slack water periods (i.e., a Kolmogorov microscale >1,000 μm). Flocculation processes were estimated using three parameters: flocculation efficiency, flocculation speed, and flocculation time. Results showed that the flocculation that occurred at the three stations was mainly influenced by the concentration of the suspended particulate matter: maximum floc size was observed for concentrations above 0.1 g l−1 while no flocculation was observed for concentrations below 0.004 g l−1. Diatom blooms strongly enhanced flocculation speed and, to a lesser extent, flocculation efficiency. During this period, the maximum flocculation speed of 6 μm min−1 corresponded to a flocculation time of less than 20 min. Salinity did not appear to automatically enhance flocculation, which depended on the constituents of suspended sediments and on the content and concentration of organic matter. Examination of the variability of 2D fractal dimension during flocculation experiments revealed restructuring of flocs during aggregation. This was observed as a rapid decrease in the floc fractal dimension from 2 to 1.4 during the first minutes of the flocculation stage, followed by a slight increase up to 1.8. Deflocculation experiments enabled determination of the influence of turbulent structures on flocculation processes and confirmed that turbulent intensity is one of the main determining factors of maximum floc size.  相似文献   

17.
Convergent margins, being the boundaries between colliding lithospheric plates, form the most disastrous areas in the world due to intensive, strong seismicity and volcanism. We review global geophysical data in order to illustrate the effects of the plate tectonic processes at convergent margins on the crustal and upper mantle structure, seismicity, and geometry of subducting slab. We present global maps of free-air and Bouguer gravity anomalies, heat flow, seismicity, seismic Vs anomalies in the upper mantle, and plate convergence rate, as well as 20 profiles across different convergent margins. A global analysis of these data for three types of convergent margins, formed by ocean–ocean, ocean–continent, and continent–continent collisions, allows us to recognize the following patterns. (1) Plate convergence rate depends on the type of convergent margins and it is significantly larger when, at least, one of the plates is oceanic. However, the oldest oceanic plate in the Pacific ocean has the smallest convergence rate. (2) The presence of an oceanic plate is, in general, required for generation of high-magnitude (M > 8.0) earthquakes and for generating intermediate and deep seismicity along the convergent margins. When oceanic slabs subduct beneath a continent, a gap in the seismogenic zone exists at depths between ca. 250 km and 500 km. Given that the seismogenic zone terminates at ca. 200 km depth in case of continent–continent collision, we propose oceanic origin of subducting slabs beneath the Zagros, the Pamir, and the Vrancea zone. (3) Dip angle of the subducting slab in continent–ocean collision does not correlate neither with the age of subducting oceanic slab, nor with the convergence rate. For ocean–ocean subduction, clear trends are recognized: steeply dipping slabs are characteristic of young subducting plates and of oceanic plates with high convergence rate, with slab rotation towards a near-vertical dip angle at depths below ca. 500 km at very high convergence rate. (4) Local isostasy is not satisfied at the convergent margins as evidenced by strong free air gravity anomalies of positive and negative signs. However, near-isostatic equilibrium may exist in broad zones of distributed deformation such as Tibet. (5) No systematic patterns are recognized in heat flow data due to strong heterogeneity of measured values which are strongly affected by hydrothermal circulation, magmatic activity, crustal faulting, horizontal heat transfer, and also due to low number of heat flow measurements across many margins. (6) Low upper mantle Vs seismic velocities beneath the convergent margins are restricted to the upper 150 km and may be related to mantle wedge melting which is confined to shallow mantle levels.  相似文献   

18.
Groundwater As concentrations >WHO limit (10 μg/L) are frequently found in the Po Plain (N. Italy). Although several hypotheses on As mobilization exist (i.e., reductive dissolution driven by peat degradation), the mechanisms of As release and subsequent attenuation acting in the multilayer aquifer in the Po Plain were poorly understood.The present work aims at implementing a reactive transport modeling of the aquifer system in Cremona, affected by As <183 μg/L, in order to quantify and test the feasibility of As release by the reductive dissolution of Fe-oxides driven by the degradation of peat contained in leaky aquitards and As attenuation downstream by the co-precipitation in iron sulfides.The model, based on a partial equilibrium approach, revealed that the observed As, Fe and Mn chemistry could be mostly explained by the simultaneous equilibrium between Fe-oxide and sulfate reduction and FeS precipitation and by the equilibrium of rhodochrosite precipitation/dissolution. Model results, together with litholog analysis, supported the assumption of peat as the likely source of organic matter driving As release. The model fitted to measured data showed that the peak in the organic carbon degradation rate at 20–40 m below surface (average of 0.67 mM/y), corresponding to the shallow peaty aquitard and the upper portion of the underlying semiconfined aquifer, is associated with the peak of net release of As (average of 0.32 μM/y) that is followed just downstream by a net precipitation in iron sulfides at 40–60 m below surface (average of 0.30 μM/y). These results support the assumptions of peaty aquifers as drivers of As release and iron sulfides as As traps. The model also outlined the following aspects that could have a broad applicability in other alluvial As affected aquifers worldwide: (a) shallow peaty aquitards may have a greater role in driving the As release since they likely have young and more reactive organic matter; (b) the occurrence of Fe-oxide reduction and FeS precipitation, that represent the As source and sink, together with sulfate reduction occurring simultaneously close to equilibrium may restrict the As mobility limiting the extent of contamination just downstream the source of organic matter that drives its release.  相似文献   

19.
The volcanic origin, primarily basaltic, of most of the surface material in Iceland influences its physical properties and appearance. Size distributions, shape analyses and melting experiments were made for surface material collected in high-erosion dust source areas and fresh volcanic ash deposits to determine whether they differ from one another and from dust from other major dust sources. The major differences found between Icelandic dust and dust from other major dust sources in the world, such as the Sahara, are in the particle shapes, lower density and darker colour. Icelandic dust particles greater than 20 μm retain volcanic morphological properties that are also found in fresh volcanic ash. Dust and fresh volcanic ash particles less than 20 μm are crystalline and blocky in nature, similar to the dust from other global source regions. The finer grained (<20 μm) Icelandic particles will have similar suspension and transport behaviours and be similarly hazardous to health and infrastructure as non-Icelandic dust. The coarser particles (>20 μm) will have different suspension and transport behaviours than other dusts due to the volcanic morphology. Icelandic surface material has between 5% and 30% glassy particles compared to fresh volcanic ash which has more than 50% glassy particles. Glassy particles were observed to melt at a lower temperature than the mineral grains; and, as a result, volcanic ash is found to be more threatening to aircraft engines than the typical dust from Iceland. Icelandic dust was observed to be blocky, or plate-like in the respirable size fraction, suggesting similar health hazards as dust from other regions.  相似文献   

20.
W.G. Ernst   《Gondwana Research》2007,11(1-2):38
In the early Earth, accretionary impact heating, including collision with a large, Mars-sized object, decay of short-lived radioisotopes, and (after an initial thermal run-up) continuous segregation of the liquid Fe–Ni core resulted in extensive the melting of the silicate mantle and in the formation of a near-surface magma mush ocean. Progressive, continuous degassing and chemical–gravitational differentiation of the crust–mantle system accompanied this Hadean stage, and has gradually lessened during the subsequent cooling of the planet. Mantle and core overturn was vigorous in the Hadean Earth, reflecting deep-seated chemical heterogeneities and concentrations of primordial heat. Hot, bottom-up mantle convection, including voluminous plume ascent, efficiently rid the planet of much thermal energy, but gradually decreased in importance with the passage of time. Formation of lithospheric scum began when planetary surface temperatures fell below those of basalt and peridotite solidi. Thickening and broadening of lithospheric plates are inferred from the post-Hadean rock record. Developmental stages of mantle circulation included: (a) 4.5–4.4 Ga, early, chaotic magma ocean circulation involving an incipient or pre-plate regime; (b) 4.4–2.7 Ga, growth of small micro-oceanic and microcontinental platelets, all returned to the mantle prior to 4.0 Ga, but increasing in size and progressively suturing sialic crust-capped lithospheric amalgams at and near the surface over time; (c) 2.7–1.0 Ga, assembly of cratons surmounting larger, supercontinental plates; and (d) 1.0 Ga–present, modern, laminar-flowing asthenospheric cells capped by gigantic, Wilson-cycle lithospheric plates. Restriction of komatiitic lavas to the Archean, and of ophiolite complexes ± alkaline igneous rocks, high-pressure and ultrahigh-pressure metamorphic terranes to progressively younger Proterozoic–Phanerozoic orogenic belts supports the idea that planetary thermal relaxation promoted the increasingly negative buoyancy of cooler oceanic lithosphere. The Thickening of oceanic plates enhanced the gravitational instability and the consequent overturn of the outer Earth as cold, top-down oceanic mantle convection. The scales and dynamics of deep-seated asthenospheric circulation, and of lithospheric foundering + shallow asthenospheric return flow evidently have evolved gradually over geologic time in response to the progressive cooling of the Earth.  相似文献   

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