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1.
分析了运移参数的变化对GCL中污染物运移的影响。从衬垫底部浓度比、对流和扩散通量、污染物累积运移量等方面,对污染物在GCL中的运移进行了计算。结果表明,减小渗透系数和扩散系数可以有效减缓衬垫底部浓度比的增加速度。渗透系数对对流通量的大小、扩散通量的变化速度的影响较大;扩散系数主要影响最大扩散通量。当渗透系数较大时,可以忽略扩散累积运移量,用对流累积运移量代替总累积运移量引起的误差很小。当渗透系数较小时,忽略扩散运移量可能产生较大的误差,尤其是在扩散系数也较大的情况下误差更加明显。 相似文献
2.
Vertical barrier walls are often constructed to prevent contamination of ground water and soils by landfill leachate. The
leachate water levels in landfills in southern China are generally high. Contaminants in such landfills may migrate through
the vertical barrier walls and give rise to environmental problems. Qizishan landfill in Suzhou, China was taken as an example
to investigate contaminant migration through the vertical barrier walls. Advection, diffusive and adsorption processes were
considered in the analysis. Influences of permeability and depth of the barrier wall on contaminant migration were analyzed.
The results show that it will be 13.5 years before breakthrough at 0.1% of the source concentration and 20.5 years before
breakthrough at 10% of the source concentration. By and large, the contaminant has not passed through the barrier wall at
present, and the contaminated zone is mainly located in the sandy clay layer near the earth dam, which is validated by testing
on sampled soils. Hydraulic conductivity and depth of the barrier wall are critical to contaminant migration. Special attention
need to be paid on them when building such a barrier wall. If bottom of the barrier wall is keyed into the aquitard and the
hydraulic conductivity reaches 10 −9 m/s, the time before breakthrough will be long enough to allow stabilization of the landfill. Pollution of the surroundings
will be avoided, and therefore the requirement for contaminant control will be attained. 相似文献
3.
A geographic information system (GIS) raster technique has been developed and used interactively with remediation designers to evaluate the optimum extent of excavating soil contaminated by chlorinated solvents. The technique and the results of its application are presented. The site was a former chemical storage plant for acids and solvents. Two distinct solvent plumes were detected within the ground using a photo-ionisation detector. The solvents were found to be dissolved in the groundwater and migrating in the general direction of groundwater flow. A remediation strategy was proposed involving the localised excavation of contamination ‘hot spots’ followed by the implementation of a groundwater remediation system. A number of excavation options were discussed and the GIS raster technique was developed to evaluate these options in terms of contaminant removed and excavation cost. The plumes were initially mapped using a triangular irregular network (TIN). These TIN models were rasterised to produce a regular grid of rectangular cells, each cell having a value relating to the concentration of contaminant at that spatial point. The proposed excavation zones were then overlaid on to the raster models as masks. The relationship between the value of contaminant concentration of cells within the mask (or excavation zone) and the total value of contaminant concentration of cells within the solvent plume was used to determine the efficiency of the excavation. The excavation options were compared taking into account the percentage of the contaminant plume removed, the excavation area (soil volumes) and related costs. Once the GIS raster technique had been developed, it proved very quick to rerun the analysis for the other excavation zones. The optimum excavation zone, based upon cost and contaminant recovery, was found for the site. The technique helped by targeting the worst area of contamination and provided the client with a cost-benefit analysis of the different remediation options. 相似文献
4.
作为一种垂直防渗墙体材料,水泥-膨润土泥浆已在欧美等一些国家被广泛应用于垃圾填埋场的垂直防渗系统中,而国内对此类墙体材料的研究和应用较少。通过对不同配合比的水泥-膨润土泥浆固结体进行渗透试验,研究了原材料对泥浆固结体渗透性能的影响以及渗透性随龄期变化的情况。试验结果表明,水泥和膨润土对固结体渗透系数的影响相互依赖,只有在水泥用量达到一定程度后,增加膨润土用量才能有效地降低固结体的渗透性能;随着龄期的增加,水泥-膨润土泥浆固结体的渗透系数明显降低。 相似文献
5.
为了控制垃圾渗滤液的侧向渗透,在城市垃圾卫生填埋场四周需设置垂直隔离墙。隔离墙采用现场开挖深槽,然后在槽内灌注水泥一膨润土一砂混合浆液的方法构筑。通过室内配比试验的方法,测定不同配比试件的无侧限抗压强度、渗透系数等参数,为隔离墙的施工提供合理的配比。 相似文献
6.
Soil-bentonite (SB) backfill is used extensively in cutoff walls at landfill sites; the walls are used as engineered geotechnical barriers for contaminant control. With increasing bentonite content, the coefficient of consolidation and hydraulic conductivity of the SB decrease. However, when the bentonite content is increased beyond a certain percentage, the hydraulic conductivity of the SB decreases very little. One of the aims of this paper is to introduce the concept of optimal bentonite content (OBC) for SB cutoff walls, in which the hydraulic conductivity ( kh) is expected to be lower than 1?×?10 ?9 m/s. Additionally, the paper introduces a new index consolidation stress ratio, cvσ′, which is used to obtain the OBC. For this study, the initial water contents of the SB backfill material are selected to be 0.8, 1.0, and 1.2 times their corresponding liquid limits. The clayey soils are amended with different bentonite contents, 0, 5, 8, and 10% (by dry weight basis) for the oedometer tests. Then, piezocone penetration test (CPTU) is applied in SB cutoff wall at a landfill site in Jingjiang city, China. The results of the laboratory and field studies show that the introduction of a new index, cvσ′, is very useful for calculating the OBC and for evaluating the coefficient of consolidation and hydraulic conductivity of SB backfill. The advantage of SB backfill with OBC is that it can achieve the design requirement of very low hydraulic conductivity and improve the safety reserves. 相似文献
7.
A number of major problems associated with the containment approach to landfill management are highlighted. The fundamental flaw in the strategy is that dry entombment of waste inhibits its degradation, so prolonging the activity of the waste and delaying, possibly for several decades, its stabilisation to an inert state. This, coupled with uncertainties as to the long-term durability of synthetic lining systems, increases the potential, for liner failure at some stage in the future whilst the waste is still active, leading to groundwater pollution by landfill leachate. Clay liners also pose problems as the smectite components of bentonite liners are subject to chemical interaction with landfill leachate, leading to a reduction in their swelling capacity and increase in hydraulic conductivity. Thus, their ability to perform a containment role diminishes with time. More critically, if diffusion rather than advection is the dominant contaminant migration mechanism, then no liner will be completely impermeable to pollutants and the containment strategy becomes untenable. There are other less obvious problems with the containment strategy. One is the tendency to place total reliance on artificial lining systems and pay little attention to local geological/hydrogeological conditions during selection of landfill sites. Based on the attitude that any site can be engineered for landfilling and that complete protection of groundwater can be effected by lining systems, negative geological characteristics of sites are being ignored. Furthermore, excessive costs in construction and operation of containment landfills necessitate that they are large scale operations (superdumps), with associated transfer facilities and transport costs, all of which add to overall waste management costs. Taken together with unpredictable post-closure maintenance and monitoring costs, possibly over several decades, the economics of the containment strategy becomes unsustainable. Such a high-cost, high-technology approach to landfill leachate management is generally beyond the financial and technological resources of the less wealthy nations, and places severe burdens on their economies. For instance, in third world countries with limited water resources, the need to preserve groundwater quality is paramount, so expensive containment strategies are adopted in the belief that they offer greatest protection to groundwater. A final indictment of the containment strategy is that in delaying degradation of waste, the present generations waste problems will be left for future generations to deal with. More cost-effective landfill management strategies take advantage of the natural hydrogeological characteristics and attenuation properties of the subsurface. The ‘dilute and disperse’ strategy employs the natural sorption and ion exchange properties of clay minerals, and it has been shown that in appropriate situations it is effective in attenuating landfill leachate and preventing pollution of water resources. Operated at sites with thick clay overburden sequences, using a permeable cap to maximise rainfall infiltration and a leachate collection system to control leachate migration, ‘dilute and disperse’ is a viable leachate management strategy. Hydraulic traps are relatively common hydrogeological situations where groundwater flow is towards the landfill, so effectively suppressing outwards advective flow of leachate. This approach is also best employed with a clay liner, taking advantage of the attenuation properties of clays to combat diffusive flow of contaminants. These strategies are likely to guarantee greater protection of groundwater in the long term. 相似文献
8.
Scale growth in alumina refineries occurs where supersaturated solutions are in contact with solid surfaces. Whilst some scale formations may prove beneficial in protecting equipment and pipe surfaces from chemical attack or abrasion, more commonly its deposition results in reduced equipment performance and plant productivity. Experiments have shown that the rate of scale growth is 60% higher in concentric reducers (contractions) than it is in adjacent straight pipes. One method of reducing the rate of gibbsite scale growth on the walls of precipitator tanks is to increase the flow velocity of the supersaturated slurry near the wall. For the supersaturated caustic–aluminate slurry encountered at Queensland Alumina Limited, (QAL), the results of this research suggests that a minimum slurry flow velocity of 2.9 m/s near the walls of the tank would reduce the rate of scale growth to zero on the tank walls. The energy required to develop this wall velocity would, however, be both uneconomic and impractical. 相似文献
9.
通过对栗木锡矿复杂地层的分析,采用绳索取芯技术,多级套管根管技术,优质泥浆护壁堵漏等钻进工艺,并对孔内事故的预防与处理提出了一系列措施,成功解决了该区深孔钻进的难题,取得了很好效果。 相似文献
10.
矿井斜井开拓安全通过新近系砂砾石含水层是一个普遍的难题,为给斜井地面预注浆或帷幕注浆法过砾石层提供依据,新矿集团在内蒙古自治区上海庙西矿区黑梁煤矿主副斜井附近对总厚20—30m的新近系砾石层（夹砂质粘土层）进行了专门注浆试验及抽水、取心等对比验证工作。结果表明。松散一半胶结砾石层虽然在超过1MPa的注浆压力“阀值”后具有一定的可注性,但浆液扩散范围小于2-3m,而且扩散方式不规则、不可控、形不成可靠的浆液扩散加固圈,对砾石层的含、导水性未发现有改善效果。通过本次试验,较好地掌握了松散一半胶结砾石层注浆性能,获得了有关注浆参数和经验,对类似地层的注浆改造和井巷工程的安全施工具有指导意义。 相似文献
11.
Contaminant transport through fractured rock mass is predominated by diffusion. This is due to the continuous interaction
of the mobile water present in the fracture network and relatively immobile pore water, which is adsorbed on the surface and
in the rock matrix itself. Even though the advective flow through the fracture network is high, besides sorption of rock mass,
the diffusive exchange into the rock mass leads to significant retardation of contaminant transport. Hence, for describing
contaminant transport in fractured rock mass, more precisely, the effect of retardation attributed to the matrix diffusion
must be taken in account. With this in view, a methodology, which can be employed for determination of the diffusion characteristics
of the rock mass, has been developed and its details are presented in this paper. Validation of the methodology has been demonstrated
with the help of Archie’s law. 相似文献
12.
基于印尼某电站场地的工程地质条件,根据基桩负摩阻力的产生机理,分析确定了中性点的位置,计算了负摩阻力产生的下拉荷载;并结合膨润土泥浆护壁的作用机理,计算了采取较大直径预钻孔和膨润土泥浆护壁的措施后负摩阻力产生的下拉荷载.计算结果表明,前者大于单桩承载力设计值,因此不能采用预应力混凝土管桩方案;后者较前者显著降低,约为单桩承载力设计值的50%,因此可以采用预应力混凝土管桩方案. 相似文献
13.
The migration of contaminants through a 2.9 m thick compacted clay liner (CCL) for a landfill leachate lagoon is examined 14 years after construction. The clay liner formed the lower portion of the composite liner system but the geomembrane (GM) was found to have defects that had allowed leachate to migrate between the GM and CCL. Chloride, sodium, potassium, calcium and magnesium pore water profiles through the CCL are examined. It is shown that chloride migrated approximately 1.7 m into the CCL during the 14 years of the lagoon operation, sodium approximately 1.2 m, and potassium 0.7 m. Diffusion and sorption data from laboratory diffusion testing are utilized in combination with a finite layer contaminant transport model to predict field contaminant migration profiles through the composite liner system and to establish the time of ‘failure’ of the geomembrane at sometime between 0 and 6 years after installation. Relatively high sorptive uptake of potassium by the CCL soil is observed from batch testing and diffusion testing with field data suggesting an even larger amount of sorption. It is hypothesized that organic sludge matter at the base of the lagoon is responsible for potassium uptake from the leachate. This field case highlights the importance of the compacted clay liner as part of the composite liner system in acting as a diffusion barrier during the lifetime of the lagoon as well as using relatively non-conservative contaminants such as chloride and sodium to estimate geomembrane ‘failure’ times 相似文献
14.
土?膨润土垂直防渗墙在美国已广泛应用于城市卫生填埋场中,我国的工程中则应用较少。由国产膨润土与原地层土混合在自重应力作用下固结形成的防渗墙,其渗透性、孔隙和压缩性如何受膨润土掺量的影响,针对该一问题,使用福建标准砂模拟原地层,以3种典型膨润土作为混合料,在各掺量下对砂?膨润土填筑土料开展改进柔性壁渗透试验固结试验,研究不同膨润土掺量对填筑料渗透系数k、孔隙率n与压缩系数av影响。结果表明,膨润土和砂形成防渗墙时存在一个对应最小n和av的最优掺量Copt,当膨润土掺量小于等于Copt时,随着掺量增加,填筑料k下降很快,av缓慢减小;当掺量大于Copt后,随掺量上升,k降低速度趋缓,av快速地升高。理论上,膨润土掺入较少时黏土颗粒仅填充砂粒间的孔隙而不影响砂粒堆积,掺量达到一定程度后膨润土使砂粒彼此分离,悬浮在其中,填筑料的孔隙率随掺量而增大,可能是宏观上造成最优掺量产生的主要原因。 相似文献
15.
针对河南省嵩县大王沟钼矿强烈蚀变、软硬不均、涌水漏失的复杂地层绳索取心钻进的难题,采用以套管为主、泥浆为辅的护壁措施,对钻探设备及工器具、金刚石钻头参数的选型进行了探讨,提出了腐植酸钾泥浆护壁和惰性材料堵漏的配方和配置方法,以及减小起下钻压力激动和抽吸对孔壁的破坏作用的措施,取得了较好的应用效果。 相似文献
16.
Granodiorite from the Gęsiniec Intrusion, Strzelin Crystalline Massif, SW Poland contains complexly zoned plagioclases. Five chemically and structurally distinct zones can be correlated among crystals: ‘cores’ (25–35% An), inner mantles (40–45% An), outer mantles (40–25% An), resorption zones (35–50% An) and rims (35–30% An). Good structural and chemical (major and trace elements) correlation of zones between crystals indicates that zonation was produced by changes in conditions of crystallization on a magma chamber scale. Plagioclase, being the liquidus phase, records a time span from the beginning of crystallization to emplacement and rapid cooling of granodiorite as thin dykes. Crystallization began with the formation of inner mantles. The paucity and different sizes of inner mantles suggests slow crystallization in high temperature magma. Normally zoned inner mantles were formed under increasing undercooling. Compositional trends in mantles suggest closed system crystallization. The major resorption zones were caused by injection of less evolved magma as indicated by the strontium increase in plagioclase. The injection triggered a rapid rise of magma and plagioclase crystals facilitating mixing but also inducing fast, kinetically controlled growth of complex multiple, oscillatory zonation within resorption zones. The ascent of magma caused decompression melting of plagioclase and produced melt inclusions within inner mantles—the ‘cores’. The decompression range is estimated at a minimum of 2 kbar. Emplacement of granodiorite as thin dykes allow rapid cooling and preservation of magmatic zonation in plagioclases. Melt inclusions crystallized completely during post-magmatic cooling. The zonation styles of plutonic plagioclase differ markedly from volcanic ones suggesting different magma evolution. Zones in plutonic plagioclase are well correlated indicating crystallization in quiescent magma where crystals accumulation and compositional magma stratification may occur. Crystals probably did not travel between different regimes. Resorption occurred but as single albeit complex episodes. Good correlation of zones in plutonic plagioclases allows a distinction between the main processes controlling zonation and superimposed kinetic effects. 相似文献
17.
We conducted laboratory true triaxial experiments in the nearly impermeable Pohang rhyolite to investigate failure mechanisms under ‘dry’ and ‘wet’ rock conditions. Under ‘dry’ conditions prismatic specimens were jacketed all around to prevent confining fluid penetration. Under ‘wet’ conditions one pair of the specimen faces was left unjacketed and in direct contact with the confining fluid (kerosene) applying the least principal stress in an attempt to simulate the case of an unlined borehole wall. In both testing setups the true triaxial compressive strength for a given least principal stress increases significantly as the intermediate principal stress rises. The unjacketed rhyolite strength is, however, only 60 to 85% of the strength under dry conditions, depending on the magnitude of the intermediate principal stress. In dry rhyolite the failure process begins upon dilatancy onset, followed by microcrack localization, and ending in a steeply dipping shear fracture. On the other hand, brittle fracture in wet specimens occurs almost immediately after the onset of dilatancy by the development of one or more through-going extensile fractures subparallel and adjacent to one of the unjacketed faces, resembling the extensile cracks leading to borehole breakouts in crystalline rocks. We infer that upon dilatancy the confining fluid intrudes and quickly propagates newly opened stress-induced microcracks subparallel to the unjacketed faces, leading to ‘early’ failure. 相似文献
18.
地下连续墙常采用泥浆护壁、水下灌注混凝土进行施工,槽壁稳定和槽段接头防渗一直是施工控制的难点。泥浆本身易于造成环境污染,而泥浆制备的水耗和废料处置也增加了工程造价。为解决这些问题,开发了一种新技术——双模管互导干作业地下连续墙技术。该技术采用钢模管护壁和双矩形模管导向沉管挤土或沉管干取土的成墙工艺（分别适用于墙厚300～500mm和600～1 000mm）,不需要泥浆和水下灌注墙混凝土,可以在同一平面内成墙、实现墙单元无缝连接。实践表明,该技术墙体防渗性能好,成墙效率高,连接质量可靠,不仅适用于深厚软粘土地层的基坑围护工程,也可应用于类似地质条件下水库工程的防渗加固。 相似文献
19.
Measurements on plutonium diffusivity in water-saturated compacted bentonite were carried out. Representative specimens of sodium bentonite were taken from the Tsukinuno and Kuroishi mines situated in northeast Japan. Tsukinuno bentonite was divided into three types: raw type, purified Na-type, and H-type which was prepared by treating Na-type bentonite with hydrochloric acid. Kuroishi bentonite contained chlorite as impurity. H-type bentonite was used as reference for the convenience of profile measurement in bentonite, since plutonium diffusivity in H-type bentonite was considered to be larger than that in Na-type bentonite because of low pH and low swelling pressure of H-type bentonite. Sampled bentonite was compacted into pellets of 20 mm in diameter and 20 mm in height. Bulk densities of these specimens were 1200–1800 kg/m3 for purified Na-type and H-type bentonite and 1600 kg/m3 for raw type bentonite. Plutonium profiles obtained in H-type bentonite can be explained by diffusion equation with constant concentration source. Diffusivity ranges from 10-13 to 1012 m2/s for H-type and Kuroishi impure sodium bentonite. Diffusivity in both raw type and purified Tsukinuno bentonite was was estimated to less than 10-14 M2/s. Diffusivity in H-type bentonite showed a tendency to decrease with increasing density. Influence of in bentonite was also studied. Quartz content up to 50% or hematite content up to 1% did not influence diffusivity significantly in H-type bentonite. The chemical species of plutonium in pore water of Na-type and H-type were estimated Pu(OH)3-; and PuO2- , respectively. 相似文献
20.
An approach is presented to quantify sensitivity of advective contaminant travel time to porosities of hydrogeologic units (HGUs) along the flowpaths when the porosities of different HGUs are correlated. The approach is an extension of the previous sensitivity analysis technique for independent input porosity cases. It is applicable in situations where a calibrated groundwater flow model exists, but a full contaminant transport model is not available. Three sensitivity indices are introduced based on the decomposition of covariance between the advective contaminant travel time and individual input porosities of HGUs. When the input HGU porosities are correlated, the three sensitivity indices quantify the total, intrinsic and correlated contributions from each individual HGU porosity, which should be considered in order to determine the relative importance to the uncertainty in advective contaminant travel time of the input HGU porosities contributing either independently or correlatedly. Two simple one-dimensional flow examples are presented to illustrate the applications of the approach to scenarios when each HGU has distinct porosity and situations of spatially variable porosity field. The approach is applicable to more complex multi-dimensional cases where advective contaminant travel time can be calculated based on simulated flow results from groundwater flow models. 相似文献
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