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1.
A. S. Goudie 《地球表面变化过程与地形》1986,11(3):275-285
‘The wick effect’ is the upward migration of saline solutions into rocks and their subsequent crystallization. Lower Carboniferous sandstone blocks of rectangular shape have been subjected to this process in the laboratory using a range of salt types, a range of salt concentrations, and various mixtures of salts. Some treatments produced severe disintegration, notably sodium carbonate and a mixture of sodium carbonate with magnesium sulphate, whereas other salts (including sodium chloride and gypsum) were much less effective. The debris produced by this experimental salt weathering included appreciable quantities of silt-sized material, which were analysed with a laser granulometer. Such material could provide a source for desert loess. 相似文献
2.
J. P. McGreevy 《地球表面变化过程与地形》1982,7(5):475-488
A laboratory experiment has been conducted to examine the effects of ‘frost and salt’ weathering (i.e. physical breakdown by the freezing of salt solutions) on a limestone. Results show that the presence of certain salts in solution can inhibit frost damage. These findings are in direct conflict with those presented by Goudie (1974) and, more recently, Williams and Robinson (1981). Comparison of the experimental methods used in each of these three studies suggests that opposing results can be explained in terms of the different experimental procedures which were employed. If salt supply is frequent and plentiful then it seems likely that rock breakdown will be enhanced-this is the case represented by the experiment of Williams and Robinson. Conversely if the salt supply is limited and the amounts of salt remain more or less constant then rock breakdown will be inhibited-the case of the present experimental study. Caution is therefore advocated when attempting to extrapolate laboratory-derived results to infer on the behaviour of rocks under natural conditions. Several environmental situations in which ‘frost and salt’ weathering may be a possibility are dsiscussed, but it is concluded that further field data, especially concerning temperature regimes and salt availability at and below rock surfaces in cold regions, would be necessary before more definite statements could be made about the efficacy of this process. 相似文献
3.
Cavernous weathering (tafoni development) occurs on coastal slopes in greenschist bedrock at elevations up to 40 m above sea level. The freshly weathered surfaces of the cavern interiors are irregular in morphology, discordant to major rock structure, formed by substantially weakened rock and associated with granular weathering debris. The weathering debris contains soluble elements in proportions similar to those present in seawater, and the penetration of elements associated with sea salts into the weathering surface to estimated depths of at least 0·1–0·2 m is indicated by the presence of chlorine. Scanning electron microscopy and microprobe analyses suggest that rock breakdown occurs principally through limited chemical weathering at grain boundaries. The mechanism for the emplacement of marine salts within sheltered rock surfaces in the tafoni is postulated to be a combination of dry deposition under turbulent atmospheric conditions and wetting by coastal fog. 相似文献
4.
George E. Mustoe 《地球表面变化过程与地形》2010,35(4):424-434
Honeycomb weathering occurs in two environments in Late Cretaceous and Eocene sandstone outcrops along the coastlines of south‐west Oregon and north‐west Washington, USA, and south‐west British Columbia, Canada. At these sites honeycomb weathering is found on subhorizontal rock surfaces in the intertidal zone, and on steep faces in the salt spray zone above the mean high tide level. In both environments, cavity development is initiated by salt weathering. In the intertidal zone, cavity shapes and sizes are primarily controlled by wetting/drying cycles, and the rate of development greatly diminishes when cavities reach a critical size where the amount of seawater left by receding tides is so great that evaporation no longer produces saturated solutions. Encrustations of algae or barnacles may also inhibit cavity enlargement. In the supratidal spray zone, honeycomb weathering results from a dynamic balance between the corrosive action of salt and the protective effects of endolithic microbes. Subtle environmental shifts may cause honeycomb cavity patterns to continue to develop, to become stable, or to coalesce to produce a barren surface. Cavity patterns produced by complex interactions between inorganic processes and biologic activity provide a geological model of ‘self‐organization’. Surface hardening is not a factor in honeycomb formation at these study sites. Salt weathering in coastal environments is an intermittently active process that requires particular wind and tidal conditions to provide a supply of salt water, and temperature and humidity conditions that cause evaporation. Under these conditions, salt residues may be detectable in honeycomb‐weathered rock, but absent at other times. Honeycomb weathering can form in only a few decades, but erosion rates are retarded in areas of the rock that contain cavity patterns relative to adjacent non‐honeycombed surfaces. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
5.
Cavernous tafoni‐type weathering is a common and conspicuous global feature, creating artistic sculptures, which may be relevant for geochemical budgets. Weathering processes and rates are still a matter of discussion. Field evidence in the type locality Corsica revealed no trend of size variability from the coast to subalpine elevations and the aspect of tafoni seems to be governed primarily by the directions of local fault systems and cleavage, and only subordinately by wind directions or the aspect of insulation. REM analysis of fresh tafone chips confirmed mechanical weathering by the crystallization of salts, as conchoidal fracturing of quartz is observed. The salts are only subordinately provided by sea spray, as calcium and sodium sulfates rather than halite dominate even close to the coast. Characteristic element ratios compare well with aerosols from mixed African and European air masses. Sulfates are largely derived from Sahara dust, indicated by their sulfur isotopic composition. Salt crystals form by capillary rise within the rock and subsequent crystallization in micro‐cracks and at grain boundaries inside rain‐protected overhangs. Siderophile bacteria identified by raster electron microscopy (REM) analysis of tafone debris contribute to accelerated weathering of biotite and tiny sulfide ore minerals. By applying 10Be‐exposure dating, weathering rates of large mature tafone structures were found to be about an order of magnitude higher than those on the exposed top of the affected granite blocks. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
6.
Kevin Hall 《地球表面变化过程与地形》1987,12(2):137-149
As part of a study on freeze-thaw weathering in the maritime Antarctic an investigation was made of the physical properties of the local rock. Tests were made of point-load compressive strength, Schmidt hammer in situ rock strength, moisture content, indentor resistance and the size range of weathering products. The resulting data were used to consider the form of freeze-thaw weathering operative in the field and its relationship to laboratory simulations. A distinct difference between ‘massive rock’ and ‘intact rock’ is observed in the field. It is suggested that future studies should generate a greater database pertaining to rock properties as it is an invaluable aid in the study of mechanical weathering. 相似文献
7.
This research characterizes the weathering of natural building stone using an unsteady‐state portable probe permeameter. Variations between the permeability properties of fresh rock and the same rocks after the early stages of a salt weathering simulation are used to examine the effects of salt accumulation on spatial variations in surface rock permeability properties in two limestones from Spain. The Fraga and Tudela limestones are from the Ebro basin and are of Miocene age. Both stone types figure largely in the architectural heritage of Spain and, in common with many other building limestones, they are prone to physical damage from salt crystallization in pore spaces. To examine feedbacks associated with salt accumulation during the early stages of this weathering process, samples of the two stone types were subjected to simulated salt weathering under laboratory conditions using magnesium sulphate and sodium chloride at concentrations of 5% and 15%. Permeability mapping and statistical analysis (aspatial statistics and spatial prediction) before and after salt accumulation are used to assess changes in the spatial variability of permeability and to correlate these changes with salt movement, porosity change, potential rock deterioration and textural characteristics. Statistical analyses of small‐scale permeability measurements are used to evaluate the drivers for decay and hence aid the prediction of the weathering behaviour of the two limestones. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
8.
Two types of cavernous‐weathering features are exposed in the Oligocene Macigno Sandstone along 5 km of the Tuscan coast south of Livorno, Italy. Honeycomb cells (type 1 features) are typical closely spaced, more or less circular pits of centimetre scale that have been eroded 2 to 6 cm below the general surface of bedding planes or joints. ‘Aberrant honeycomb’ cells (type 2 features) are highly elongate, polygonal, or irregular ?at depressions of decimetre scale surrounded by walls rarely higher than 2 cm, some of which pass into long, free‐standing walls or tendrils. Thus, not all type 2 ‘honeycomb’ cells are fully enclosed. We measured the geometry of 551 honeycomb cells and examined various rock properties (microscopic texture and fabric, mineralogy, porosity, permeability, and chemical composition) to isolate factors that control the size, shape, distribution, and pattern of the honeycombs. Our goal was to narrow potential origins of the features and to understand their formation. The ubiquitous occurrence of sea salt in the honeycombs and scanning electron microscope evidence of physical weathering of silicates, especially micas, favours an origin for the honeycombs chie?y by salt weathering. Honeycombs do not form in siltstone, iron‐oxide‐impregnated sandstone, calcite‐cemented concretions, or in case‐hardened joints. Thus, salt weathering of type 1 and 2 honeycombs is not effective in very low permeability rocks. We propose for type 1 honeycombs that seawater is drawn into micropores of the sandstone and evolves into self‐organized diffusion cells (Turing patterns). Selective evaporation at the stationary nodes of diffusion cells, which form at the same site over time, leads to the precipitation of salt, then grains spall off, and pits are formed. The deepest pits (>40 mm) formed where Turing patterns consistently formed at the same sites. Although the walls are more porous and weathered than the host sandstone, they become selectively case hardened by an unidenti?ed component of low abundance. Initial honeycomb cell shape and gravity locally in?uenced type 1 honeycomb shapes. We suggest that type 2 honeycombs develop where diffusion‐controlled Turing patterns lead to case‐hardening along linear trends; gravity and rock fabric are important locally in in?uencing the orientation of the walls. Only type 2 cells are forming today, suggesting recent environmental changes. Gravity is not a fundamental control on honeycomb shape; in places it is a contributing factor. Pre‐existing depressions (quarry tool marks) have strongly in?uenced honeycomb shape locally. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
9.
J. P. McGreevy 《地球表面变化过程与地形》1985,10(5):509-518
Honeycomb weathering has been observed in a Carboniferous sandstone at a coastal location near Ballycastle on the north coast of Northern Ireland. Specimens of this sandstone have been analysed by X-ray diffraction, scanning electron microscopy, and energy dispersive spectrometry. Results reveal that calcium sulphate (gypsum) is the only salt present and is found only at and immediately below the rock surface. SEM observations suggest that crystallization of salts in pores could easily dislodge quartz grains to promote granular disintegration, whilst etching of quartz grain surfaces attests to chemical weathering activity within the rock However, the reason for the development of the honeycomb pattern is not known. 相似文献
10.
A. S. Goudie 《地球表面变化过程与地形》1993,18(4):369-376
Samples of concrete were subjected in an environmental cabinet to six different diurnal cycles of temperature and humidity change representative of desert surface conditions in the presence of a range of saturated salt solutions. The samples were not subjected to repeated immersion or continuous partial immersion as has been the case in most previous experiments. Breakdown did occur nonetheless. The two most effective cycles were one from Egypt (with a very high daytime maximum) and one from the Negev (with high nocturnal humidity conditions). Cycles with relatively modest temperature and humidity cycles were ineffective in causing debris liberation. 相似文献
11.
A laboratory salt weathering experiment was performed using five salts to attack eight types of rocks to determine the relative significance of rock durability and salt aggressivity to salt crystallization damage. The influence of individual rock properties on the salt susceptibility of the rocks was also evaluated. To study the relation between pore characteristics, salt uptake, and damage, the pre‐ and post‐experiment pore size distributions of the rocks were also examined. It is observed that both salt type and rock properties influenced the damage pattern. The durability ranking of the rocks became significantly altered with the salt type while the variation in salt efficacy ranking with rock type was less pronounced. Of the five salts used, sodium chloride and aluminium sulfate were invariably ineffective with all rock types while sodium carbonate, sodium sulfate, and magnesium sulfate, were markedly more effective in damaging most types of rock used. Of the rock properties investigated, the microporosity (of pores smaller than 0·05 or 0·1 µm) showed the most significant influence on deterioration of the rocks associated with salt crystallization, whereas microporosity of pores smaller than 5 µm played a more important role in salt uptake. Pore size distribution was thus the key factor controlling salt uptake and damage. Rocks with a large number of pores (<5 µm) and a high proportion of pores (<0·05 or 0·1 µm) were particularly susceptible to salt crystallization damage. However, anomalies arose that could not be explained in terms of rock properties or salt efficacy alone. Overall, the relative influences of salt type/efficacy and rock type/properties on salt damage propensity were not clear enough to draw a reasonable conclusion. Salt crystallization damage appears to be influenced by the individual interactions between salts and rocks, which could explain the anomalous results. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
12.
A laboratory study has been used to investigate relationships between salts and contour scaling—a weathering feature commonly observed on rock surfaces in salt-rich environments. Surface disaggregation and essentially surface-parallel cracks were produced in sandstone blocks using 10 per cent solutions of sodium sulphate and magnesium sulphate applied daily to single exposed surfaces for sixty days. A control block soaked once in saturated magnesium sulphate and subsequently wetted daily with distilled water showed extensive surface disaggregation, but no cracking. Both surface disaggregation and subsurface cracking were associated with relative concentrations of microcrystalline salt. A tentative model of contour scaling is proposed, which involves linking together potential cracks by salt-induced fracturing of intervening, crack-stopping grains. Further control blocks treated respectively with 10 per cent and saturated sodium chloride showed no evidence of subsurface cracking and only limited surface disaggregation of the ‘saturated’ block. 相似文献
13.
The results of a series of experiments are reported in this paper which were designed to differentiate between the forces of crystal growth and hydration in salt weathering, using a single salt-hydrate system (sodium sulphate), five contrasting rock types, and several diurnal temperature-relative humidity cycles which permitted or inhibited these processes and simulated ground surface climates in hot, arid environments. It was shown that hydration of sodium sulphate is an effective mechanism of rock disintegration but that it is significantly less destructive than crystal growth pressure. Crystallization of thenardite (Na2SO4) is, in turn, more effective in rock weathering than the crystal growth of mirabilite (Na2SO4.10H2O). In general, rates of disintegration were most rapid where the diurnal temperature range was extreme and relative humidity lowest. 相似文献
14.
Two groups of fresh crushed Brazilian quartz grains (0.4–0.6 mm) were placed in 10 ml of various saturated salt solutions (sodium sulphate, sodium chloride, magnesium sulphate, sodium carbonate, and sodium carbonate and soil). One group was placed in an environmental cabinet programmed to simulate summer diurnal temperature and relative humidity values recorded in Wheeler Valley, a dry valley in southern Victoria Land, Antarctica. The other group was allowed to remain at normal laboratory conditions. Quartz grains from both groups were removed at pre-selected intervals for examination using the scanning electron microscope. After 50 hours chemical surface textures were formed on the quartz grains in all but the sodium sulphate solution. At the 140 hour interval all the salt solutions used were producing chemical surface textures on the quartz grains. This paper demonstrates that chemical surface textures can be produced on quartz grain surfaces by saturated salt solutions in a short period of time and may prove to be representative of chemical surface textures produced in a saturated saline environment. 相似文献
15.
Preliminary results from a continuing series of laboratory experiments designed to examine the combined effects of salt and frost weathering indicate that some salts greatly enhance the breakdown of rocks by frost. Samples of Ardingly Sandstone from southeast England were soaked in saturated solutions of sodium chloride or sodium sulphate and subjected to alternating cycles of freezing and thawing. Rapid disintegration of the sandstone occurred within twenty cycles, in each of the salt solutions. In contrast, samples subjected to freezing and thawing in deionized water suffered very little damage unless they were saturated under vacuum. When samples were subjected to twenty cycles of wetting and drying at temperatures above 0°C, those soaked in deionised water or sodium chloride suffered no appreciable damage but those soaked in sodium sulphate rapidly disintegrated. Tentative explanations of these results are offered. The enhancement of frost weathering by salt appears to have been overlooked by many writers yet it is likely to be an important geomorphological process in those areas of mid and high latitudes where rocks are saturated with sodium salts. 相似文献
16.
C. Cardell T. Rivas M.J. Mosquera J.M. Birginie A. Moropoulou B. Prieto B. Silva R. Van Grieken 《地球表面变化过程与地形》2003,28(1):1-14
A saline‐spray artificial ageing test was used to simulate the effects produced in granites and sedimentary rocks (calcarenites, micrites and breccia) under conditions in coastal environments. Three main points were addressed in this study: the durability of the different kinds of rock to salt decay, the resulting weathering forms and the rock properties involved in the weathering processes. For this, mineralogical and textural characterization of each of the different rocks was carried out before and after the test. The soluble salt content at different depths from the exposed surfaces was also determined. Two different weathering mechanisms were observed in the granite and calcareous rocks. Physical processes were involved in the weathering of granite samples, whereas dissolution of calcite was also involved in the deterioration of the calcareous rocks. We also showed that microstructural characteristics (e.g. pore size distribution), play a key role in salt damage, because of their influence on saline solution transport and on the pressures developed within rocks during crystallization. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
17.
Kevin Hall 《地球表面变化过程与地形》2004,29(1):43-57
Discussions regarding weathering in cold environments generally centre on mechanical processes and on the freeze–thaw mechanism in particular. Despite the almost ubiquitous assumption of freeze–thaw weathering, unequivocal proof of interstitial rock water actually freezing and thawing is singularly lacking. Equally, many studies have used the crossing of 0 °C, or values close to that, as the basis for determining the number of ‘freeze–thaw events’. In order to assess the weathering regime at a site in northern Canada, temperatures were collected at the surface, 1 cm and 3 cm depth for sets of paving bricks, with exposures both vertical and at 45°, orientated to the four cardinal directions. Temperature data were collected at 1 min intervals for 1 year. These data provide unequivocal proof for the occurrence of the freezing and thawing of water on and within the rock (freeze–thaw events). The freeze event is evidenced by the exotherm associated with the release of latent heat as the water actually freezes. This is thought to be the ?rst record of such events from a ?eld situation. More signi?cantly, it was found that the temperature at which freezing occurred varied signi?cantly through the year and that on occasion the 1 cm depth froze prior to the rock surface. The change in freeze temperature is thought to be due to the chemical weathering of the material (coupled with on‐going salt inputs via the melting of snowfall), which, it is shown, could occur throughout the winter despite air temperatures down to ?30 °C. This ?nding regarding chemical weathering is also considered to be highly signi?cant. A number of thermal stress events were also recorded, suggesting that rock weathering in cold regions is a synergistic combination of various chemical and mechanical weathering mechanisms. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
18.
Alan Paul Davison 《地球表面变化过程与地形》1986,11(3):335-341
An investigation using laboratory simulation has been made using air temperature data for Tunisia, Antarctica, and southwest England. An experiment with a 50 cycle run produced results which showed significantly greater debris production in the Antarctica and Tunisian simulations than in the southwest England simulation. Using X-ray analysts to determine salt penetration, an inverse relationship between salt penetration and debris production was seen to exist. This could be the result of evaporation in the Tunisian simulation and rapid freezing in the Antarctic simulation, concentrating salts in the upper layers of the rock samples. In the southwest England simulation, no freezing, and relatively high humidities allowed greater penetration, thus distributing an equal input of salt over a greater area. The author tentatively suggests the possible existence of a parabolic relationship between salt weathering and temperature. 相似文献
19.
Experiments are described in which chalk cubes were soaked in solutions of either sodium chloride, sodium sulphate, or magnesium sulphate at concentrations of 5·5 per cent and 12·5 per cent, or in a mixed solution of sodium chloride and sodium sulphate or in distilled water. After removal of excess liquid, the cubes were subjected to six freeze–thaw cycles with temperatures ranging from either +15 to ?10°C or +15 to ?30°C. The results confirm that frost weathering can be enhanced by the presence of certain salts, but the extent of weathering was much less than that previously reported for samples frozen totally immersed in the same liquids. Evidence is presented which suggests that salt crystallization is the major weathering process operative when non–immersed samples are frozen but a combination of frost and salt weathering operates when fully immersed samples are frozen. 相似文献
20.
Recent developments in long term landform evolution modelling have created a new demand for quantitative salt weathering data, and in particular data describing the size distribution of the weathered rock fragments. To enable future development of rock breakdown models for use in landscape evolution and soil production models, laboratory work was undertaken to extend existing schist/salt weathering fragmentation studies to include an examination of the breakdown of sub‐millimetre quartz chlorite schist particles in a seasonally wet tropical climate. Laser particle sizing was used to assess the impact of different experimental procedures on the resulting particle size distribution. The results reveal that salt weathering under a range of realistic simulated tropical wet season conditions produces a significant degree of schist particle breakdown. The fragmentation of the schist is characterized by splitting of the larger fragments into mid‐sized product with finer material produced, possibly from the breakdown of mid‐sized fragments when weathering is more advanced. Salinity, the salt addition method and temperature were all found to affect weathering rates. Subtle differences in mineralogy also produce variations in weathering patterns and rates. It is also shown that an increase in drying temperature leads to accelerated weathering rates, however, the geometry of the fracture process is not significantly affected. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献