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1.
Mercury concentrations in surface intertidal sediments from estuarine and coastal environments of the Northeastern Irish Sea are reported. This region has two inputs of mercury contaminated effluents from chlor-alkali factories, and localized mercury contamination of sediments fairly similar to that reported for the Rhine has been found in the Wyre estuary. The present results for the Mersey estuary agree well with others reported in the lierature. Coastal sediments are much less contaminated than the estuarine deposits, and in all the environments studied strong correlations between mercury concentration, total organic carbon and < 63 μm grainsize fraction contents have been found.  相似文献   

2.
The distribution of americium in surface intertidal sediments from a coastal environment near the Windscale nuclear fuel reprocessing plant has been investigated. The study includes data on the broadscale distribution of 241Am in Northwest England, but focuses on the sediments of the Ravenglass estuary 10 km south of Windscale. The results indicate that americium concentrations in the inner estuary sediments are up to seven times higher than those from the Irish Sea itself. Americium distribution on silt banks is rather constant on a small scale, but varies considerably between adjacent silt bank and salt marsh areas.  相似文献   

3.
The occurrence of some fission products from the Sellafield (formerly Windscale) nuclear fuel reprocessing facility has been determined for surface sediments from forty locations in the Ravenglass estuary, North-west England. The influence of the silt-sized fraction in the sediments on the geographic distribution of 137Cs is clearly important, and to a lesser extent also influences the distributions of 106Ru, 134Cs+95ZrNb and 144Ce. The data are compared with recently published results reported by the Ministry of Agriculture, Fisheries and Food for a monitoring site in this estuary.  相似文献   

4.
The distribution of 137Cs from the Sellafield (Windscale) nuclear fuel reprocessing plant has been examined in detail in the surface intertidal sediments of the inner Solway Firth by means of a hovercraft-borne radiometric survey. With the exception of a belt of relatively active sands to the south of Silloth, caesium distribution is generally consistent with that of fine-grained sediment such that the highest concentrations occur in mud flat and salt marsh sediments which are most extensive in sheltered coastal embayments. 137Cs activities in July 1980 were typically 2–30 pCi g?1 but locally exceeded 50 pCi g?1. These levels are considerably lower than those recorded in locations, such as the outer Solway and Ravenglass estuary, which are closer to the Sellafield outfall.  相似文献   

5.
《Marine pollution bulletin》2014,81(1-2):263-274
The current study aimed to examine the relationship between metals in sediments and metal bioaccumulation in oyster tissue in a highly-modified estuary (Sydney estuary, Australia). While extensive metal contamination was observed in surficial sediments, suspended particulate matter and oyster tissue, a significant relationship between these media could not be established. No relationship was determined between sediment quality guidelines and oyster size or weight, nor with human consumption levels for metals in oyster tissue. Moreover, oyster tissue metal concentrations varied greatly at a single locality over temporal scales of years. Oyster tissue at all 19 study sites exceeded consumptions levels for Cu. Bioaccumulation of metals in oyster tissue is a useful dynamic indicator of anthropogenic influence within estuaries, however oysters cannot be used in Sydney estuary as a valid biomonitor due to overriding internal regulation (homoestasis) by the animal, or by external natural (sediment resuspension) and anthropogenic (sewer/stormwater discharges) pressures, or both.  相似文献   

6.
The quantities of petroleum hydrocarbons being discharged to the Hudson Raritan estuary have been estimated, in tonnes day?1, from data in the literature as: sewage discharges (35), oil refinery discharges (1.3), non-oil refinery industrial discharges (17), oil spills (1.5), atmospheric deposition (0.002), urban and rural run-off (37). Losses have been estimated in a somewhat similar manner as: permanent deposition in sediments (11), dredging (5.8), advection (6.5), bed sedimentary transport (0.007), decomposition in water and sediments (42), evaporation (0.4), movement of surface slicks (0.4). The results are approximate but suggest that petroleum hydrocarbons originate principally from sewage as well as urban and rural run-off and only moderate proportions are discharged through the estuary mouth. However, this discharge combined with that due to dredging spoil disposal operations results in a considerable quantity of petroleum hydrocarbon entering the adjacent New York Bight.  相似文献   

7.
Radionuclides, released into the north-east Irish Sea from the British Nuclear Fuels plc uranium reprocessing plant at Sellafield, Cumbria, UK and which are present in sediments of the Esk estuary, Cumbria, are initially associated with large (i.e. >0.5 mm) rather than fine grained (i.e. <63 μm) particles. I call these macro particles organoliths. They consist of an agglomerate of sediment grains held together with an organic iron rich matrix; their surfaces are coated with a patina of iron and manganese oxides with which the radionuclides are associated. Concentration factors (Kd's) for plutonium, americium, and other radionuclides, together with various stable elements in the patina are orders of magnitude greater than those found in bulk sediments. Some implications concerning the radionuclide content of organoliths are discussed in relation to geochemical process, pollution studies and the requirements of radiological protection.  相似文献   

8.
Surface sediments samples were collected from 9 stations of the Cochin estuary during the monsoon, post-monsoon and pre-monsoon seasons and were analyzed for grain size, total organic carbon (OC), total nitrogen (TN) and stable isotopic ratios of carbon (δ13C) and nitrogen (δ15N) to identify major sources of organic matter in surface sediments. Sediment grain size is found to be the key factor influencing the organic matter accumulation in surface sediments. The δ13C values ranges from ?27.5‰ to ?21.7‰ in surface sediments with a gradual increase from inner part of the estuary to the seaward side that suggest an increasing contribution of marine autogenous organic matter towards the seaward side. The δ15N value varies between 3.1‰ and 6.7‰ and it exhibits complex spatial and seasonal distributions in the study area. It is found that the dynamic cycling of nitrogen through various biogeochemical and organic matter degradation processes modifies the OC/TN ratios and δ15N to a considerable degree. The fraction of terrestrial organic matter in the total organic matter pool ranges from 13% to 74% in the surface sediments as estimated by δ13C based two end member mixing model.  相似文献   

9.
The Fitzroy estuary (Queensland, Australia) receives large, but highly episodic, river flows from a catchment (144,000 km(2)) which has undergone major land clearing. Large quantities of suspended sediments, and particulate and dissolved organic carbon are delivered. At peak flows, delta(13)C (-21.7+/-0.8 per thousand) and C/N (14.8+/-1.3) of the suspended solids indicate that the particulate organic material entering the estuary is principally soil organic carbon. At the lower beginning flows the particulate organic matter comes from in-stream producers (delta(13)C=-26 per thousand). The DOC load is about 10 times the POC load. Using the inverse method, budgets for POC and DOC were constructed for high and low flows. Under high flows, only a small portion of the POC and DOC load is lost in the estuary. Under dry season (low flow) conditions the estuary is a sink for DOC, but remains a source of POC to the coastal waters.  相似文献   

10.
Radiocaesium, introduced into coastal waters in the effluent from the B.N.F.L. nuclear fuel reprocessing plant at Windscale, is present at significant levels throughout the Clyde Sea Area. Concentrations reached maximum in April, 1977, and have recently declined. Around 30% of Windscale radiocaesium output passes through the Clyde Sea Area but less than 0.3% remains in sediments. There appears to be no major radiological safety hazard. The radiocaesium is, however, an excellent tracer species for both waters and sediments. The Irish Sea-derived component comprises over 90% of Clyde seawater and may well introduce major inventories of pollutants. The average water residence time in the Clyde system is 4.5 months, although significantly longer entrainment is evident in northern sea lochs. Study of radiocaesium variations has enabled improved assessment of the Clyde's response to marine pollution.  相似文献   

11.
Lignin and pigment biomarkers were analyzed in surface sediments of the Louisiana Continental margin (LCM) to distinguish differences in the degradative state of sedimentary organic matter along and between two major depositional pathways (along shore and offshore to the Mississippi Canyon) from Southwest (SW) Pass in July 2003. Barataria Bay, an inter-distributary estuary, was also assessed as a potential source of terrestrial organic matter to the LCM. Sediment signatures taken along the same pathways after Hurricane Ivan (October 2004) were compared with the pre-Ivan signature to elucidate carbon dynamics after major hurricane events. Density fractions were investigated at key stages across the LCM. Mississippi Canyon sediments are a depocenter for labile and refractory organic matter derived from river and previously deposited shelf sediments. Barataria Bay material may be a contributing source of sedimentary organic matter in shallow shelf areas bordering the bay and is thus potentially important in carbon cycling in sediments of these shallow areas; however, our results show that organic matter inputs from the bay were likely rapidly decomposed and/or diluted. Hurricane Ivan mobilized sedimentary organic carbon (SOC) offshore and homogenized terrestrial sediment parameters and gradients. As observed through pigment concentrations sediments tended to equilibrate to a more steady-state condition within months of the disturbance. Insights from density fractions show that selective degradation and aggregation/flocculation processes were also very important processes during cross-shelf transport. Zooplankton grazing, largely on diatoms and other algae, was a shelf wide phenomenon, however, grazing products dominated the marine-derived SOC in margin sediments west of the birdsfoot delta indicated by the abundance of steryl chlorin esters (SCEs).  相似文献   

12.
Sediment is commonly considered as a source of phosphine, which is a highly toxic and reactive atmospheric trace gas. This study aims to investigate the seasonal and spatial distribution of matrix-bound phosphine (MBP) and its relationship with the environment in the Changjiang River Estuary. A total of 43 surface sediments were collected in four seasons of 2006, and concentrations of MBP and relative environmental factors were analyzed. MBP ranged from 1.93 to 94.86ngkg(-1) dry weight (dw) with an average concentration of 17.14ngkg(-1)dw. The concentrations of MBP in the upper estuary were higher than those in the lower estuary, which could be attributed to greater pollutant inputs in the upper estuary. The concentrations of MBP also varied with season, with November>August>May>February. Significant correlations existed between MBP and total phosphorus (TP), organic phosphorus (OP), inorganic phosphorus (IP), organic carbon (OC), total nitrogen (TN), the grain size, and redox potential (Eh), suggesting that these sedimentary environmental characteristics played an important role in controlling the MBP levels in the sediments. Notably, there were positive linear relationships between the concentrations of soluble reactive phosphorus (SRP), TP, and chlorophyll a (Chl a) in bottom water and MBP in sediments. These relationships might be very complicated and need further exploration. This work is the first comprehensive study of the seasonal and spatial distribution of MBP in sediments and its relationships with environmental factors in a typical estuary, and will lead to deeper understanding of the phosphorus (P) biogeochemical cycle.  相似文献   

13.
In a dispersive coastal area under multiple organic enrichment sources, stable isotopes were used to trace organic sources of carbon and nitrogen in sediments and benthic macrofauna. The Bivalve Abra alba and the Polychaetes Nephtys sp. and Pectinaria (Lagis) koreni were reliable indicators of the input of terrestrial-derived organic matter into this coastal area, either originated in outfall sewage discharges or estuarine outflow. An isotopic depletion was observed up to 250 m from the outfall branches, much stronger in the biota than in the sediments. An enrichment of 2‰ in the sediments, and 2-6‰ in the species was noticed in sites located farther than 1500 m from the outfall. Depositivores and carnivores/omnivores gave the best picture of the extension of the sewage dispersion and incorporation into the food web.  相似文献   

14.
Surface waters collected along the salinity gradient of the Hudson River estuary in four cruises between 1995 and 1997 were size-fractionated into particulate (>0.45 μm), ‘dissolved' (<0.45 μm), colloidal (10 kDa, 0.45 μm) and low molecular weight (<10 kDa) phases. Dissolved Cd concentrations (range: 0.11–1.19 nM) in surface waters of the estuary appear to have decreased fourfold (from an average of 2.36 to 0.61 nM) over a 23-year period, since the initial analysis of samples collected in the 1970s by Klinkhammer and Bender [Estuar. Coastal Shelf Sci. 12 (1981) 629–643]. This interannual decline reflects improvement in sewage treatment and the elimination of industrial Cd sources to the Hudson River estuary. In contrast, dissolved Mn levels (range: 0.033–1.46 μM) have remained relatively constant over the same period of time, suggesting that anthropogenic sources have very limited impact on Mn concentrations in the estuary. The concentrations of both Cd and Mn appeared to strongly depend on the season and/or river discharge. The highest concentrations were detected under low freshwater discharge, implying that limited hydraulic flushing allows a build-up of metals in the water column. Although the decline in Cd levels within the estuary reflects a reduction in the magnitude of anthropogenic inputs, mass balance estimates indicated that current sources of Cd to the estuary include sewage discharges (in the lower estuary around Manhattan) and diagenetic remobilization from industrial Cd deposited in sediments nearly 2 decades ago (in the upper estuary near Foundry Cove). Moreover, under low river discharge, the sources considered in our model (sewage, riverine input, atmospheric deposition, and benthic fluxes) could account for no more than 60% of the Cd exported from the lower estuary to the ocean. This suggests that undefined sources such as ground water and inputs from other watersheds (e.g., Long Island Sound and Newark Bay) may potentially influence the water quality of the New York Harbor. The size-fractionated metal concentrations indicated that most of the traditionally defined ‘dissolved' Cd and Mn consisted of <10 kDa molecular weight species. High molecular weight colloidal species of Mn accounted for about 50% of the dissolved fraction at the riverine end-member and <5% at intermediate and high salinities. Colloidal Cd accounted for <6% of the dissolved phase throughout the estuary. Unlike the non-conservative excess (relative to ideal dilution of river water and seawater) of dissolved Mn observed along the estuary, high molecular weight colloidal Mn appeared to be removed at the head of the estuary. The small contribution of colloidal Cd and Mn to the ‘dissolved' phase suggests that remobilization from suspended particulate phases and/or from sediments occurs through the formation of small molecular weight species.  相似文献   

15.
The Seine’s estuary (France) waters are the receptacle of effluents originating from wastewater treatment plants (WWTP). In this estuary, mudflats are deposition zones for sediments and their associated contaminants, and play an essential role in the mercury (Hg) biogeochemical cycle mainly due to indigenous microorganisms. Microcosms were used to assess the impact of WWTP-effluents on mercury methylation by monitoring Hg species (total dissolved Hg in porewater, methylmercury and total mercury) and on microbial communities in sediments. After effluent amendment, methylmercury (MeHg) concentrations increased in relation with the total Hg and organic matter content of the WWTP-effluents. A correlation was observed between MeHg and acid-volatile-sulfides concentrations. Quantification of sulfate-reducing microorganisms involved in Hg methylation showed no increase of their abundance but their activity was probably enhanced by the organic matter supplied with the effluents. WWTP-effluent spiking modified the bacterial community fingerprint, mainly influenced by Hg contamination and the organic matter amendment.  相似文献   

16.
In July 1978, total phosphorus and organic carbon were determined in the sediments of Tolo Harbour, a sewage-polluted estuary in north-east Hong Kong. Concentrations were correlated with % silt-clay in each of three areas. Phosphorus concentrations were highest in central Tolo Harbour, lower by about 1.5μg at. P g?1 in the outer estuary, Tolo Channel, and lowest in the polluted inner reaches near large coastal reclamations. The latter values, about 3.0 μg at. P g?1 lower than in central Tolo Harbour, might reflect a selective adsorption of phosphate by reclamation sediments. Organic carbon concentrations were high in the inner reaches and decreased towards the outer channel. Correlations between phosphorus and organic carbon were compared with a published correlation for the east coast of England: in Hong Kong, phosphorus concentrations showed a smaller increase as organic carbon increased, and reached only one-third of the English values as organic carbon approached 2.0%.  相似文献   

17.
The effect of discharges from two sewage treatment plants located on the northern shore of lake Geneva on surrounding sediments was investigated. Four forms of phosphorus were analyzed, together with extractable iron and organic carbon. Areal distribution of the parameters and correlation analysis show that the sewage treatment plant at Vidy discharges into the lake significant amounts of phospho-ferric precipitate. The influence of the other plant at Morges is more discrete, but its extent can be traced by the areal distribution of the ratios [Feextr.]/[non-apatite inorganic P] and [organic carbon]/[organic phosphorus].   相似文献   

18.
Mass spectrometric analyses of low levels of global fallout plutonium separated from Atlantic marine samples have differentiated fallout239Pu and240Pu in aquatic samples for the first time. The results show no single characteristic240Pu/239Pu ratio in marine samples; the observed range is from 0.11 to 0.24 on an atom basis. There are indications that differences exist in the chemical or physical form of plutonium from atmospheric fallout in Atlantic surface water and that selective concentration in surface organisms is occurring. No single240Pu/239Pu value is found in pelagic sediments collected from different depths and locations. Discounting sources other than fallout, our results show that the plutonium deposited at any given time since atmospheric testing began may have carried a unique240Pu/239Pu tag. This label may be extremely useful to trace fallout plutonium through biogeochemical cycles.  相似文献   

19.
Concentrations of dissolved226Ra in Winyah Bay, South Carolina, and in the adjacent Atlantic Ocean are augmented by the desorption of radium from sediments in the low-salinity area of the estuary and diffusion from bottom sediments. Desorption of226Ra is reflected by lower concentrations in suspended sediments from higher-salinity regions of the estuary. Bottom sediments from the high-salinity region have lower226Ra/230Th activity ratios than those from the low-salinity end.The shape of the dissolved226Ra vs. salinity profile is influenced by the river discharge. During average-discharge conditions, desorption of226Ra from suspended and bottom sediments increases the dissolved226Ra concentrations by a factor of 3.5 as the water passes through Winyah Bay. High river discharge produces an initial increase of dissolved226Ra by a factor of 2 to 3 and apparently reflects only desorption from suspended sediments. By driving the salt wedge down the estuary and reducing the zone of contact of salt water with bottom sediments, the high-flow conditions sharply reduce the flux of226Ra from bottom sediments.  相似文献   

20.
Anthropogenic mercury pollution was studied in Kastela Bay (Croatia), 10 years after chloralkaline plant (PVC) stopped production. The concentration of total mercury determined in sediments which are composed mainly of calcite and quartz, are in the range 14,280-30,400 ng/g. The values are higher than reported in the literature for Elbe and Seine estuaries and also above 25,000 ng/g used for criterion in remediation project in Minamata Bay. The concentration of methylmercury 6.05-36.74 ng/g are typical for slightly to highly contaminated estuarine sediments. The low ratio of methylmercury to total mercury found in sediments of Kastela Bay is in the range 0.04-0.18%. It can be explained that in this region predominate conditions which do not promote in-situ methylation. Sediments were found to be highly anoxic. Concentrations of total mercury in unfiltered surface waters are in the range 69-145 ng/l and in unfiltered bottom waters in the range 230-1,418 ngl(-1). High concentrations found in bottom waters suggest that either resuspension or partial dissolution of sediments takes place. An experiment performed on filtered and unfiltered waters showed that about 85% of total mercury in surface water and almost 100% in bottom water was retained on 45 microm filters. To demonstrate contrasts, two pristine estuaries from norths and south Europe were studied. Silicious sediments of Ore estuary (Sweden) and calcareous sediments of Krka estuary (Croatia) have total mercury concentrations close to accepted background level. The ratio of methylmercury to total mercury is < or = 1% in all samples with one exception. The highest observed ratio (2.70%) was in the surface sediment from E2 station in Krka estuary measured in March 2000. This location is suitable for studying methylmercury formation in pristine environment.  相似文献   

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