Biological Degradation of 2,4-Dinitrotoluene in a Continuous Bioreactor and Kinetic Studies Experimental results on the aerobic biological degradation with complete mineralization of 2,4-dinitrotoluene (2,4-DNT) are presented. A culture of Pseudomonas sp. DNT from Spain and Nishino was used. The degradation was examined with batch cultures for the determination of kinetic and stoichiometric coefficients. Further experiments were carried out with a continuous culture in a fixed-bed reactor with recirculation in order to obtain high degradation rates. The reactor was packed with ceramic Raschig rings (55 mL) and had a liquid reaction volume of 160 mL. The minimal salt media from Spanggord et al. with and without (NH4)2S)4 as nitrogen source was used as substrate. 2,4-DNT was the sole source of carbon and energy. From batch experiments a yield coefficient YB/S = (0.30 ± 0.05) g g?1 was calculated from a mass balance of the elements. This result was confirmed by calculations using literature data. Fitting the experimental data to the Monod equation, μmax = 0.1 h?1 and KS = 0.01…0.03 mmol L?1 were obtained. It was demonstrated by batch experiments that 2,4-DNT is not only used as the source of carbon and energy but also as the nitrogen source. In the fixed-bed reactor, a degradation of 92…97% was reached with a maximal 2,4-DNT load of 95 mg L?1 h?1. The rate of continuous degradation could be described by a pseudo-first-order reaction (k = 9.73 h?1). The complete mineralization of 2,4-DNT was verified by the measurement of DOC and the formed nitrite and nitrate. The formed nitrite was nitrified simultaneously. It was demonstrated by these experiments that large scale biological treatment of industrial effluent containing 2,4-DNT may be successful. 相似文献
Data for the diffusion of cations in pyroxenes are relevant to a variety of sub-solidus processes including order-disorder and exsolution. Similar data must also be available if the reliability of geobarometers and geothermometers involving pyroxenes is to be assessed. Two types of diffusion experiment have been performed to determine cation diffusion rates in pyroxenes: (1) interdiffusion between single crystals of diopside and polycrystalline sinters enriched in Al and Fe, and (2) interdiffusion between single crystals of diopside and a glass of the same composition which was isotopically enriched in26Mg and43Ca. Following high-temperature annealing for periods up to several hundred hours, analysis of the diffusion couples, using an electron microprobe and an ion microprobe respectively, failed to show any measurable diffusion profiles. From these “null result” experiments the diffusion coefficients (D) for Al and Fe in diopside are estimated to be less than4×10?14cm2s?1 at 1200°C, and values ofD for Ca and Mg in diopside are estimated to be less than7 × 10?14cm2s?1 at 1250°C. These rates are significantly slower than published tracer-type diffusion data for Ca and Al.A review of studies of order-disorder, microstructural coarsening, and diffusion in pyroxenes suggest that activation energies for cation exchange are typically in excess of 60 kcal mol?1. Transport rates will be assisted, and activation energies lowered by sample non-stoichiometry, inhomogeneities, high dislocation densities and the presence of water.The collective data for Al, Mg and Ca diffusion in diopside indicate diffusion coefficients? 10?15cm2s?1 at 1200°C. A comparison with data for diffusion in garnet, olivine and spinel suggests that pyroxenes may have the highest blocking temperatures. 相似文献
Summary The value of the electrical conductivity of the free atmosphere is inversely related to the concentration of nuclei. Measurements made with an airborne conductivity meter illustrates this effect. It was found that for these particular meteorological conditions a change of 47 nuclei/cm3 could be detected. It was also found that in one case nuclei from a smoke source were carried down wind for a distance of 400 miles. The concentration of nuclei varied from 14.6×103 nuclei/cm3 near the source to 1·3×103 at the distant location.This research was performed while the author was employed by USAF Cambridge Research Center, Bedford, Mass. 相似文献
The assumption of local equilibrium during partial melting is fundamental to the interpretation of isotope and trace element data for mantle-derived rocks. If disequilibrium melting is significant, the scale of the chemical and isotopic heterogeneity in the mantle indicated by the data could be as small as the grain size of the mantle rock, and the isotope data themselves are then of doubtful value to the understanding of mantle processes. To assess the scale of isotopic heterogeneity in a partially molten asthenosphere we review the Sr isotopic data of volcanic rocks from oceanic regions and the available experimental data on diffusion kinetics in minerals and melts similar to those existing in the mantle. Although diffusion data are scarce and afflicted with uncertainties, most of the diffusion coefficients for cations in mantle minerals at temperatures of 1000–1200°C appear to be greater than 10?13 cm2 s?1. Sr diffusion in liquid basalt is more rapid, with diffusion coefficients of D = 10?7 to 10?6cm2s?1 near 1300°C. Simple model calculations show that, with these D values, a fluid-free mantle can maintain a state of disequilibrium on a centimeter scale for periods of 108 to 109 years. The state of disequilibrium found in many mantle-derived xenoliths is thus easily explained. A partially molten mantle, on the other hand, will tend to equilibrate locally in less than 105 to 106 years. The analytical data on natural rocks likewise indicate that the inhomogeneities are both old (>FX1.5 b.y.) and regional in character and that the consistent isotopic difference between ocean island and ocean floor volcanics cannot be explained by small-scale heterogeneity of the source rock. 相似文献
Scattering by a slightly-rough core-mantle boundary (CMB) with small-scale radial variations of up to a few hundred metres, has been an attractive (though non-unique) interpretation of at least part of the precursors to PKIKP. Here it is shown that a slightly-rough CMB has an observable effect on PKKP as well, if the signal-to-noise ratio is sufficiently high. The effect may be observed as precursive arrivals and is due to back-scattering at CMB. This work was prompted by observations by Chang and Cleary at LASA of “PKKP” and precursors from the Novaya Zemlya explosions. NORSAR data from several source regions are presented here; small-scale radial variations of 100–200 metres are inferred from these data, although in some regions the CMB appears to be much smoother. On the other hand, the LASA data are anomalous and suggest much larger topography in the sampled region of the CMB. Both large- and small-scale topography must be dynamically produced, if current estimates of the viscosity of the lower mantle (～1022 Poise) are correct. 相似文献
Nitrogen contents range from a few parts per million in ordinary chondrites and achondrites to several hundred parts per million in enstatite chondrites and carbonaceous chondrites. Four major isotopic groups are recognized: (1) C1 and C2 carbonaceous chondrites have δ15N of+30to+50%.; (2) enstatite chondrites have δ15N of?30to?40‰; (3) C3 chondrites have low δ15N with large internal variations; (4) ordinary chondrites have δ15N of?10to+20‰. The major variations are primary, representing isotopic abundances established at the time of condensation and accretion. Secondary processes, such as spallation reactions, solar wind implantation and metamorphic loss may cause small but observable isotopic variations in particular cases. The large isotopic difference between enstatite chondrites and carbonaceous chondrites cannot be accounted for by equilibrium condensation from a homogeneous nebular gas, and requires either unusually large kinetic effects, or a temporal or spatial variation of isotopic composition of the nebula. Nitrogen isotopic heterogeneity in the nebula due to nuclear processes has not been firmly established, but may be required to account for the large variations found within the Allende and Leoville meteorites. The unique carbonaceous chondrite, Renazzo, has δ15N of+170%., which is well beyond the range of all other data, and also requires a special source. It is not yet possible, from the meteoritic data, to establish the mode of accretion of nitrogen onto the primitive Earth. 相似文献
A new methodology for probabilistic seismic hazard analysis is described. The approach combines the best features of the "deductive" (Cornell, 1968) and "historic" (Veneziano et al., 1984) procedures. It can be called a "parametric-historic" procedure. The maximum regional magnitude mmax is of paramount importance in this approach and Part I of the authors work (Kijko and Graham, 1998) was dedicated to developing efficient statistical procedures that can be used for the evaluation of this parameter. In Part II the approach of a probabilistic seismic hazard assessment at a given site is described. The approach permits the utilization of incomplete earthquake catalogues. It is assumed that a typical catalogue contains two types of information historical macroseismic events that occurred over a period of a few hundred years and recent, instrumental data. The historical part of the catalogue contains only the strongest events, whereas the complete part can be divided into several subcatalogues, each assumed complete above a specified threshold of magnitude. The authors approach also takes into account uncertainty in the determination of the earthquake magnitude. The technique has been developed specifically for the estimation of seismic hazard at individual sites, without the subjective judgment involved in the definition of seismic source zones, in which specific active faults have not been mapped and identified, and where the causes of seismicity are not well understood. As an example of the application of the new technique, the results of a typical hazard analysis for a hypothetical engineering structure located in the territory of South Africa are presented. It was assumed that the only reliable information in the assessment of the seismic hazard parameters in the vicinity of the selected site comes from a knowledge of past seismicity. The procedure was applied to seismic data that were divided into an incomplete part, containing only the largest events, and two complete parts, containing information obtained from instruments. The simulation experiments described in Part I of our study have shown that the Bayesian estimator K-S-B tends to perform very well, especially in the presence of inevitable deviations from the simple GutenbergRichter model. In the light of this fact value &gif1; = 6.66 - 0.44, which was obtained from the K-S-B technique, was regarded as the best choice. At an exceedance probability of 10х per annum, the median value of peak ground acceleration on rock at the site is 0.31g, and at an exceedance probability of 10ц per annum, the median peak ground acceleration at the site is 0.39g. The median value of the maximum possible acceleration at the site is 0.40g, which was calculated from attenuation formulae by assuming the occurrence of the strongest possible earthquake, e.g., with magnitude &gif1; = 6.66 at distance 10 km. 相似文献
Unique measurements by a solar submillimeter radio telescope (SST) have been carried out in the sub-THz radiation at 212 and 405 THz over the past decade. The spectrum of RF radiation in this region increased with frequency for the three flares of November 2 and 4, 2003, and December 6, 2006, and the flux value reached 5 × 103?2 × 104 sfu at 405 GHz (Kaufman et al., 2009). In this work, we consider a set of nonlinear equations for an accelerated electrons beam and the Langmuir wave energy density. The distribution functions of the accelerated electron beam and wave energy density are calculated taking into account Coulomb collisions, electron scattering by waves, and wave scattering by plasma ions. In addition, the source of accelerated particles and the heat level of the Langmuir turbulence are specified. The beam and plasma parameters are chosen based on the aims of a problem. The plasma concentration varies from n = 1013 to 1015 cm?3, the electron plasma frequency fp = (3 × 1010?3 × 1011) Hz in this case. The ratio of plasma and beam concentrations, sufficient to explain the value of the radio flux at a frequency of 300 GHz, is nb/n = 10?3. The Langmuir turbulence is excited due to the instability of the accelerated electron beam with an initial distribution function of the ??bump-in-tail?? type. Then, the parameters of radiowaves are calculated in the sub-THz range under the assumption of coalescence of two plasma waves. The calculation results show that a sub-THz radio flux can be obtained under the condition of injection of accelerated electrons. The fine time structure of radio flux observed is easily simulated based on this statement by the pulsed time structure of electron beams and their dynamics in overdense plasma. X-ray and gamma radiation was recorded during the events under study. Hard X-ray radiation is bremsstrahlung radiation from accelerated electron beams. 相似文献
Auroral precipitating electrons pass through an acceleration region before entering the atmosphere. Regardless of what produces it, a parallel electric field is assumed to cause the acceleration. It is well known that from kinetic theory an expression for the corresponding upward field-aligned current can be calculated, which under certain assumptions can be linearized to j = KV. The K constant, referred to as the Lyons-Evans-Lundin constant, depends on the source density and thermal energy of the magnetospheric electrons; it is an important parameter in magnetosphere-ionosphere coupling models. However, the K parameter is still rather unknown, and values are found in a wide range of 10–8–10–10Sim–2. In this study, we investigated how the type of auroral structure affects the K values. We look at onset and westwards-travelling surge (WTS) events and make comparisons with earlier results from observations of more stable auroral arcs. A new analysis technique for studying those magnetospheric parameters using ground-based measurements is introduced. Electron density measurements are taken with the EISCAT radar, and through an inversion technique the flux-energy spectra are calculated. Source densities, thermal energies and potential drops are estimated from fittings of accelerated Maxwellian distributions. With this radar technique we have the possibility to study the changes of the mentioned parameters during the development of onsets and the passage of surges over EISCAT. The study indicates that the linearization of the full Knight formulation holds even for the very high potential drops and thermal temperatures found in the dynamic onset and WTS events. The values of K are found to be very low, around 10–11Sm–2 in onset cases as well as WTS events. The results may establish a new technique where ionospheric measurements are used for studying the ionosphere-magnetosphere coupling processes. 相似文献
This paper introduces the conversion of Euler's equation from a Cartesian coordinate system to a radial coordinate system, and then demonstrates that for sources of the type 1/rN (where r is the distance to the source, and N is the structural index) it can be solved at each point in space without the need for inversion, for a known structural index. It is shown that although the distance to the source that is obtained from Euler's equation depends on the structural index used, the direction to the source does not. For some models, such as the gravity and magnetic response of a contact, calculation of the analytic signal amplitude of the data is necessary prior to the application of the method. Effective noise attenuation strategies, such as the use of moving windows of data points, are also discussed. The method is applied to gravity and magnetic data from South Africa, and yields plausible results. 相似文献
The effect of solid convection on the thermal evolution of the Moon is explored for a variety of viscosities, radioactive differentiation efficiencies and initial temperature profiles. Convective heat flux in the models is calculated using an empirical relation derived from the results of laboratory experiments and numerical solutions of the Navier-Stokes equations. The method retains the spherically symmetric approximation and, therefore, greatly facilitates numerical calculations.Results show that even though solid convection may determine the thermal state of the lunar interior, it does not necessarily produce a quasi-steady thermal balance between heat sources and surface loss. An imbalance persists, due to the cooling and growth of the nonconvecting lithosphere. The state of the lithosphere is sensitive to the efficiency of heat source redistribution, while that of the convecting interior depends primarily on rheology. Convecting models have viscosities of 1021–1022 cm2s?1 in their interiors; the central temperature must be above 1100°C. Convection occurring within the first billion years after formation could have led to mare flooding by magma produced in hot zones of convection cells. However, it cannot be shown from model calculations alone that solid convection must have dominated lunar thermal history. 相似文献
The Hsingtai, China earthquakes of March 1966 were a series of destructive earthquakes associated with the Shu-lu graben. Five strong shocks of Ms ≥ 6 occurred within a period of less than a month, the largest of which was Ms 7.2. Body and surface waves over the period range from several to 100 s have been modeled for the four largest events using synthetic seismograms in the time domain and spectral analysis in the frequency domain. Data from ground deformation, local geology, regional seismic network, and teleseismic joint epicenter determination have also been used to constrain the source model and the rupture process.The fault mechanism of the Hsingtai sequence was mainly strike-slip with a small component of normal dip-slip. The strikes of the four largest shocks range from ～ N26° to 30°E, approximately along strike of the major faults of the Shu-lu graben and the aftershock distribution. The source mechanisms can be explained with a NNW-SSE extensional stress and a NEE-SWW compressional stress acting in the area. The major shocks all had focal depths ～ 10 km.The four largest shocks in the sequence were characterized by a relatively simple and smooth dislocation time history. The durations of the far-field source time functions ranged from 3.5 to 5 s, while the rise times were all ～ 1 s. The seismic moments of the four largest earthquakes ranged from 1.43 × 1025 to 1.51 × 1026 dyne cm?1. The fault sizes of the four events were very close. Assuming circular faults, the diameters of the four events were determined to be between 10 and 14 km. Stress drops varied from ～ 52 to 194 bars. A trend of increasing stress drop with earthquake size was observed.A survey of stress drop determinations for 15 major intraplate earthquakes shows that on the average the magnitude of stress drop of oceanic intraplate earthquakes and passive continental margin events is higher (～ 200 to several hundred bars) than that of continental intraplate earthquakes (～ 100 bars or less). 相似文献
Approaches for estimating the influence of nonlinear effects on long-distance propagation of acoustic signals in an isothermal
atmosphere are developed. It has been indicated that nonlinear effects can be ignored on paths up to 3000 km at beam angles
smaller than 35° (nonlinear absorption). However, the spectrum will be pronouncedly distorted at these distances due to the
generation of new harmonics (for initial Mach numbers about 10−4). 相似文献
The Romanian earthquake of August 30, 1986 is the second largest intermediate depth event in this area since the worldwide deployment of digital instrumentation, and the first one since the installation of GEOSCOPE network. It offers the unique opportunity to document this well-known but poorly understood zone of deep continental seismicity using high quality teleseismic data in different frequency bands. The source is well constrained both from very-long period surface wave data observed on GEOSCOPE stations and, independently, from body wave modelling at various worldwide stations. The depth obtained is approximately 140 kilometers, the seismic moment, 0.8 1027 dyne-cm and the mechanism from both data sets is very similar to that of the previous 1940 and 1977 Vancrea events, indicating that these events, although having occurred at noticeably different depths, are expressions of the same tectonic process. However, from the detailed study of the source using broadband data, it can be inferred that the source presents much less complexity than the 1977 event. 相似文献
Compression wave velocityVp has been measured on 10 representative rock samples from the Early Mesozoic granulite and mafic-ultramafic cumulate xenoliths population from the Harqin area of the Inner Mongolia Autonomous Region (for short Inner Mongolia) as an aid to interpretingin-situ seismic velocity data and investigating velocity variation with depth in a mafic lower crust. The experiments have been carried out at constant confining pressures up to 1 000 MPa and temperatures ranging from 20 to around 1 300°C, using the ultrasonic transmission technique. After corrections for estimatedin situ crustal pressures and temperatures, elastic wave velocities range from 6.5 to 7.4 km·s?1, indicating that they are components of the Early Mesozoic crust-mantle transitional zone. Combining with previous experimental data, we have also reestablished the Early-Mesozoic continental compression velocity profile and compared it with those of the present and of the different tectonic environments in the world. The result shows that it is similar to the velocity pattern of the extensional tectonic area, providing new clues to the Mesozoic continental structure of the North China Craton. 相似文献
Summary A large number of experiments have been carried out with the object of determining the nature, properties and source of the condensation nuclei produced by the action of a beam of ultra-violet light within an expansion chamber. This paper is essentially a qualitative summary of the results which have been obtained. It is concluded that these experiments show that it is the rubber component of the chambers that has been responsible for the major part of the effect. It is by no means suggested that this is the only source of the nuclei, but it is implied that only apparatus free from rubber should be used in any study of the properties of the nuclei associated with a given gas or vapour.Work ofA. J. Barnard (now at University of Natal, Pietermaritzburg) andJ. R. Atkinson. 相似文献
Tholeiitic basalt glasses from the FAMOUS area of the Mid-Atlantic Ridge are among the most primitive basaltic liquids reported from the ocean basins. One of the more primitive of these[Mg/(Mg+Fe2+) = 0.68;Ni= 232ppm;TiO2 = 0.61] glasses (572-1-1) was selected for an experimental investigation. This study found olivine to be the liquidus phase from 1 atm to 10.5 kbar where it is replaced by clinopyroxene. The sequence of appearance of phases at 1 atm pressure is olivine (1268°C), plagioclase (1235°C) and clinopyroxene (1135°C). The sample is multiply saturated at 10.5 kbar with olivine (Fo88), clinopyroxene (Wo32En60Fs9), and orthopyroxene (Wo5En83Fs12). From the 1-atm data we have measured (FeO/MgO) olivine/(FeO*/MgO) liquid (K′D) for olivine-melt pairs equilibrated at 12 temperatures in the range 1268–1205°C.K′D varies from 0.30 at 1205°C to 0.27 at 1268°C. Analysis of high-pressure olivine melt pairs indicates a systematic increase inK′D with pressure.Evaluation of the 1-atm experiments reveals that fractionation of olivine followed by olivine + plagioclase can generate much of the variation in major element chemistry observed in the FAMOUS basalt glasses. However, it cannot account for the entire spectrum of glass compositions — particularly with respect to TiO2 and Na2O. The variations in these components are such as to require different primary liquids.Comparison of clinopyroxene microphenocrysts/xenocrysts found in oceanic tholeiites with experimental clinopyroxenes reveal that the majority of those in the tholeiites may have crystallized from the magma at pressures greater than ～ 10 kbar and are not accidental xenocrysts. Clinopyroxene fractionation at high pressures may be a viable mechanism for fractionating basaltic magmas.The major and minor element mineral/meltK′d's from our experiments have been used to model the source region residual mineralogy for given percentages of partial melting. These data suggest that ～20% partial melting of a lherzolite source containing 0–10% clinopyroxene can generate the major and minor element concentrations in the parental magmas of the Project FAMOUS basalt glasses. 相似文献
The reasons why53Mn (a cosmogenic radionuclide with a half-life of 3.7 × 106 y) appears as one of the best indicators of the presence of interplanetary dust are summarized. This paper reports the detection of53Mn in pre-1952 snow samples collected on the Eastern Antarctic Plateau in the vicinity of Plateau Station. The measurements were carried out by neutron activation and X-ray spectrometry on three samples weighing a few hundred kg and covering each the time interval 1935–1950. The specific activity of53Mn was found to be (0.82 ± 0.17) disint.min?1/103 tons of snow, corresponding to a deposition rate at Plateau Station of (2.2 ± 0.5) × 10?5 disint. min?1 m?2 y?1. The mean global deposition rate would be three times higher if53Mn were assumed to behave in the same way as stratospheric90Sr. By comparing this figure with existing data on the meteorite flux reaching the earth and with the galactic and solar production rates of53Mn, it is concluded that the bulk of the53Mn found at Plateau Station is associated with interplanetary dust in which it had been produced by the action of solar protons on iron. The deposition rate of extra-terrestrial dust-borne iron must be between 1.3 × 10?5 and 1.3 × 10?4 g m?2 y?1 at Plateau Station. These results support jointly with other studies the concept of an interplanetary zodiacal cloud of dust with a chemical composition and density not essentially different from chondritic meteorites, with a relatively ‘flat’ grain size distribution and a mass influx to the earth of the order of 105 tons/y. 相似文献
