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1.
A study was conducted to investigate the performance of amaranth, a known hyperaccumulator of cesium, on the promotion of the dissipation of soil phenanthrene and pyrene, which are PAHs (polycyclic aromatic hydrocarbons). Amaranthus tricolor L. een choi was the cultivar used. The presence of Amaranthus tricolor L. evidently enhanced the dissipation of these PAHs in soils with initial phenanthrene concentrations of 7.450–456.5 mg/kg dw (dw, dry weight) and pyrene of 8.010–488.7 mg/kg dw. At the end of the experiment (45 days), the residual concentrations of phenanthrene and pyrene in spiked soils with plants were generally higher than those with no plants. The loss of phenanthrene and pyrene in vegetated soils was 87.85–94.03% and 46.89–76.57% of the soil with these chemicals, which was 2.55–13.66% and 11.12–56.55% larger than the loss in non-vegetated soils, respectively. The accumulation of phenanthrene and pyrene by the plant was evident. Root and shoot concentrations of these chemicals monotonically increased with increasing soil PAH concentrations. Bioconcentration factors (BCFs), defined as the ratio of chemical concentrations in plants and in the soils (on a dry weight basis), of phenanthrene and pyrene by roots were 0.136–0.776 and 0.603–1.425, while by shoots were 0.116–0.951 and 0.082–0.517, respectively. BCFs of phenanthrene and pyrene tended to decrease with the increasing concentrations of soil phenanthrene and pyrene. Plant accumulation only accounted for less than 0.32% (for phenanthrene) and 0.33% (for pyrene) of the total amount enhancement of the dissipated PAHs in vegetated vs. non-vegetated soils. In contrast, plant-promoted microbial biodegradation was the predominant contribution to the plant-enhanced dissipation of soil phenanthrene and pyrene. These results suggested the feasibility of the radionuclide hyperaccumulator in phytoremediating the soil PAH contaminants.  相似文献   

2.
A. M. A. Ismail 《GeoJournal》1991,23(3):233-237
This study is mainly about the relationship of the moisture holding and release capacity of soils with their texture, particularly the clay fraction. Soil samples collected from various sites in the Sudan Gezira were analysed for physical and chemical properties and moisture characteristics. Generally the soils were clayey except the recent alluvium which was loamy. The pH was alkaline and the electric conductivity < 1.0 dS m–1. The studied soils were calcareous and very poor in organic matter, their intermediate to high water holding capacity being due mainly to the presence of large quantities of clay. Matric potentials of –0.4 to –1.5 MPa reduced soil moisture for all types of soils but the effects were not necessarily quantitatively equal. Permanent wilting point — moisture content at – 1.5 MPa — varied widely (10.5 – 22.0%) amongst the different soils and this was mainly attributed to texture and mineralogy of the soil clays. Bulk density decreased with increase in clay content. Calcium carbonate content was found to have no apparent relationship with the moisture content of these soils. The amount of silt fraction seems to have an overriding effect on the relationship between soil moisture availability in the recent alluvium soil and its subsequent release to growing plants. The results are discussed in relation to the phenomenon of mid-day stress observed in all grown crops of the Sudan Gezira.  相似文献   

3.
Geochemical field and laboratory tests of soils and stream sediments in an area of weak surficial lead-zinc mineralization resulted in the delineation of two anomalous zones. Lead-zinc values are exceptionally high, but downslope and downstream mobility is low.The metals occur in base-exchangeable positions (5%), with iron oxides (45–60%), in clay lattice positions (15–30%), as resistant minerals (2–5%), and in organic matter (up to 20%).Intense dissolution and redeposition of metals occurred probably close to their point of origin in residual soils.  相似文献   

4.
The August 1985 crack has focussed attention on passive earth processes in parts of Bauchi State, Nigeria. These processes, encompassing groundwater solution and roof collapse, soil shrink-swell, and gullying, are widespread in the Akko, Gombe, and Bauchi Local Government Areas (LGAs) of the State. Soils in these areas are rich in montmorillonite clay minerals and possess appreciable shrink-swell capabilities. Surface heave ranges from 8.1 to 11 cm. Preliminary data on plasticity measurement show a plasticity index (PI) of 13.4 to 15%. Consequently, in response to seasonal changes, the soil usually splits, leaving gaping cracks. These cracks, once formed, constitute channels throug which meteoric water easily penetrates the bedrock. The water is chemically acid and the underlying bedrock contains layers of limestone and shale. Systematic solution of these chemically reactive rocks results in the formation of caverns, the roof of which may ultimately collapse leaving randomly distributed sink holes. These cracks and sink holes run through villages, destroying mud buildings, which often collapse overnight, and transforming most modern block buildings into death traps. They affect roads, bridges, and other foundations, and render farmlands waste, swallowing up livestock.The expansive soil processes, solution and roof collapse phenomena currently identified in these places, are passive phenomena and have been overlooked as geologic hazards. Preliminary results of investigations on the physical and chemical properties of the soils and underlying rocks indicate that these areas of Bauchi State of Nigeria need to be monitored closely to avert disaster.  相似文献   

5.
Occurrence of expansive soils in construction sites has serious implications on planning, design, construction, maintenance, and overall performance especially of lightweight engineering infrastructures. Such soils are particularly susceptible to large volume changes in response to moisture content fluctuations following seasonal climatic variations. This can lead to deformation of structures built up on them. For this study, soil samples were collected from the eastern part of Addis Ababa. Specific expansive soil engineering parameters namely; Atterberg limits (LL, PL and PI), free swell and cation exchange capacity were measured in a soil mechanics laboratory. Reflectance spectra of each soil sample were acquired in a remote sensing laboratory using ASD fieldspec full range spectrometer. A multivariate calibration method, partial least squares regression (PLSR) analysis, through simple wavelength approach, was used to construct empirical prediction models for estimating engineering parameters of expansive soils from their respective reflectance spectra. Correlation coefficients of 0.90, 0.87, 0.71, 0.81 and 0.71 for CEC, LL, PL, PI and FS respectively were obtained. The correlation coefficients showed that large portion of variations in engineering parameters of expansive soils could be accounted for by spectral parameters. Apart from these high correlation coefficients, small root mean square errors of calibration (RMSEC) and prediction (RMSEP), standard error of calibration (SEC) and prediction (SEP) and minimum bias were obtained. The results indicate potential of spectroscopy in deriving engineering parameters of expansive soils from their respective reflectance spectra and hence, its potential applicability in supporting geotechnical investigations of such soils.  相似文献   

6.
The Cr and Ni contents are high in the Eocene lignite of the Shenbei coalfield, which is a small intracontinental basin located in Liaoning Province, China. In this paper, we studied the distribution, origin and occurrence of Cr, Ni and other hazardous trace elements in the Shenbei lignite on the basis of coal petrology, and geochemistry of the lignite and combustion products. The following conclusions on the Shenbei lignite can be drawn: (1) The dominant maceral group in the Shenbei coal is huminite (humodetrinite), accounting for 96%–99% of the total maceral. Inertinite content is less than 1%. Liptinite content (sporinite and cutinite) is 0.2–1.6%. Common minerals in the Shenbei lignite include clay minerals (kaolinite), pyrite and quartz, and calcite and siderite. Chromite is not present in the lignite. (2) Potentially hazardous trace elements such as Co (22 μg/g), Cr (79 μg/g), Cu (63 μg/g), Zn (93 μg/g), V (88 μg/g) and Ni (75 μg/g) are strongly enriched in the Shenbei lignite compared with average concentration of trace elements in the Chinese coal and worldwide lignite. These elements are mainly associated with fulvic acid (FA) and/or coal organic macromolecular compounds in most of the studied lignite samples, indicating an organic association and enrichment of these elements in the Shenbei lignite. (3) Unusually high trace elements contents in the Shenbei lignite are derived mainly from the olivine basalt (country rock of coal basin) that consists of 52.7% plagioclase, 17.8% pyroxene, 14% olivine and 15.5% Ti–Fe oxide minerals. These olivine basalts have higher Cr, Ni, Pb and Zn contents than other types of rock and worldwide basalts do. (4) Fly ash of the Shenbei lignite, with 90% 1–50 μm amorphous particles and 8% 1–10 μm cenosphere, has high contents of Zn (23,707 μg/g), Be (12 μg/g), Sr (1574 μg/g), Pb (486 μg/g) and Cr (349 μg/g). In particular, the ferruginous micro-cenoshperes contain 1–12.79% Zn. Fine bottom ash (<0.031mm) of the Shenbei lignite has higher contents for most of the elements with the exception of Mo, Sn and Zn. Therefore, the potentially environmental and health impact of the fly ash and fine bottom ash should constitute a major concern.  相似文献   

7.
ABSTRACT

Expansive soil subgrades, which are subjected to dual swell-shrink problem consequent upon absorption and evaporation of water, need to be improved by chemical stabilization or compacted cushion or geosynthetic reinforcement in order that pavements constructed over them are even, stable and safe. This paper presents extensive experimental data on plasticity, free swell index (FSI) and compaction characteristics of a highly swelling expansive clay stabilized with varying silica fume contents. In another series of tests on a laterite soil to be used as a cushion over the expansive clay subgrade, plasticity properties, compaction characteristics and strength characteristics were determined at varied silica fume contents. Further, CBR of the expansive clay subgrade was determined in the laboratory stabilizing it with varied silica fume contents and providing a cushion of 50 mm thickness of silica fume-stabilized lateritic soil. Liquid limit (LL), plasticity index (PI) and free swell index (FSI) of the expansive clay decreased with increasing silica fume contents. The compaction and strength characteristics of both the soils improved with silica fume stabilization. The CBR of the expansive clay provided with silica fume-stabilized cushion improved significantly.  相似文献   

8.
The Langmuir and Freundlich adsorption isotherm equations were used to model Cs sorption in 6 Welsh soils. The pH (in water), of the soils ranged from 3.5 to 6.5, and the estimated organic matter (determined by loss-on-ignition) ranged from 4.8% to 46%. According to the Langmuir adsorption isotherm, highest sorption maxima,b, were displayed by the loams at 102–204 mg kg−1, compared with organic soils at 37–86 mg kg−1. Subsoil horizons (15–30 cm depth) did not always display higher sorption maxima than their topsoil (0–15 cm depth) counterparts. Where an improved fit to the Freundlich model was found over the Langmuir model, it was assumed that either concurrent desorption of other species, or bond-energy heterogeneity in the substrate, were significant for these soils.  相似文献   

9.
Soils from historical Pb mining and smelting areas in Derbyshire, England have been analysed by a 5-step sequential extraction procedure, with multielement determination on extraction solutions at each step by ICP-AES. Each of the chemical fractions is operationally defined as: (i) exchangeable; (ii) bound to carbonates or specifically adsorbed; (iii) bound to Fe–Mn oxides; (iv) bound to organic matter and sulphides; (v) residual. The precision was estimated to be about 5%, and the overall recovery rates were between 85 and 110%. The carbonate/specifically adsorbed and Fe–Mn oxide phases are the largest fractions for Pb in soils contaminated by both mining and smelting. Most of the Zn is associated with Fe–Mn oxide and the residual fractions. Cadmium is concentrated in the first 3 extraction steps, particularly in the exchangeable phase. The most marked difference found between soils from the mining and smelting sites is the much higher concentrations and proportions of metals in the exchangeable fraction at the latter sites. This indicates greater mobility and potential bioavailability of Pb, Zn and Cd in soils at the smelting sites than in those in the mining area. The most important fraction for Fe and Al is the residual phase, followed by the Fe–Mn oxide forms. In contrast, the Fe–Mn oxide fraction is the dominant phase for Mn in these soils. In the mining area, most of the Ca is in the carbonate fraction (CaCO3), while the exchangeable and residual phases are the main fractions for Ca at the smelting sites. Phosphorus is mainly in the residual and organic fractions in both areas. The exchangeable fractions of Pb, Zn and Cd in soils were found to be significantly related to the concentrations of these metals in pasture herbage.  相似文献   

10.
Water samples from 72 wells tapping the Jilh aquifer were collected and analyzed for 10 different water quality parameters. Using these data, a regional irrigation water quality was assessed using three techniques: (i) United States Department of Agriculture method (USDA), (ii) Food and Agriculture Organization (FAO) guidelines for water quality assessment, and (iii) Water-Types approach. The USDA method revealed that the aquifer water salinity, as represented by electrical conductivity, ECw, ranges from high salinity (C3: ECw > 0.75–2.25 dS/m) to a very high salinity (C4: ECw > 2.25 dS/m). The sodium adsorption ratio (SAR) varied from low (S1) to very high (S4) sodicity. Therefore, the water of the Jilh aquifer is dominantly of the C4–S2 class representing 56% of the total wells followed by C4–S1, C4–S3, C3–S1 and C4–S4 classes at 19%, 14%, 8%, and 3% of the wells respectively. The FAO system indicated moderate to severe restriction on the use for irrigation and slight to moderate ion toxicities for Na+, Cl−, B+, NO3− and HCO3−. It is clear that, both USDA and FAO systems condemn the Jilh groundwater as hazardous for irrigation due to its high salt content, unless certain measures for salinity control are undertaken. The dominant salt constituents in the water are Mg–Cl2, Na–Cl and Ca–Cl2 as per the Water-Types method. However, due to the complexity in classifying the aquifer groundwater for irrigation, a simplified approach acknowledging three class groups (I-suitable water, II-conditionally suitable water and III-unsuitable water) adopted from the three methods, is suggested in this paper. The simplified approach combines C–S classes of the USDA method among these three groups according to the lowest ratings. The salinity of the FAO method has been split arbitrarily into slight and moderate subclasses with values of 0.7–2.25 and >2.25 dS/m, respectively; to match with the C3-class of the USDA system. The Water-Types were classified assuming that Ca–Cl2 is the least hazardous salt, followed by Mg–Cl2 and Na–Cl. Using this integrated hydrochemical method, the majority of the wells (92%) contain unsuitable water for irrigation (Group III) while the remaining wells (8%) are in Group II with water considered conditionally suitable for irrigation.  相似文献   

11.
We present here the first available estimations of chemical weathering and associated atmospheric CO2 consumption rates as well as mechanical erosion rate for the Lesser Antilles. The chemical weathering (100–120 t/km2/year) and CO2 consumption (1.1–1.4 × 106 mol/km2/year) rates are calculated after subtraction of the atmospheric and hydrothermal inputs in the chemical composition of the river dissolved loads. These rates thus reflect only the low-temperature basalt weathering. Mechanical erosion rates (approx. 800–4000 t/km2/year) are estimated by a geochemical mass balance between the dissolved and solid loads and mean unaltered rock. The calculated chemical weathering rates and associated atmospheric CO2 consumption rates are among the highest values worldwide but are still lower than those of other tropical volcanic islands and do not fit with the HCO3− concentration vs. 1/T correlation proposed by Dessert et al. (2001). The thick soils and explosive volcanism context of the Lesser Antilles are the two possible keys to this different weathering behaviour; the development of thick soils limits the chemical weathering and the presence of very porous pyroclastic flows allows an important water infiltration and thus subsurface weathering mechanisms, which are less effective for atmospheric CO2 consumption.  相似文献   

12.
This study presents a combined geochemical and mineralogical survey of urban surface soils. Many studies on urban soils are restricted to purely chemical surveys in order to investigate soil pollution caused by anthropogenic activities such as traffic, heating, industrial processing, waste disposal and many more. In environmental studies, chemical elements are often distinguished as lithogenic and anthropogenic elements. As a novel contribution to those studies, the authors combined the analysis of a broad set of chemical elements with the analysis of the main mineralogical phases. The semi-quantification of mineralogical phases supported the assignment of groups of chemical elements to lithogenic or anthropogenic origin. Minerals are important sinks for toxic elements. Thus, knowledge about their distribution in soils is crucial for the assessment of the environmental hazards due to pollution of urban soils. In Pforzheim, surface soils (0–5 cm depth) from various land use types (forest, agriculture, urban green space, settlement areas of various site densities) overlying different geological units (clastic and chemical sediments) were investigated. Urban surface soils of Pforzheim reflect to a considerable degree the mineral and chemical composition of parent rocks. Irrespective of the parent rocks, elevated concentrations of heavy metals (Zn, Cu, Pb, Sn, Ag) were found in soils throughout the whole inner urban settlement area of Pforzheim indicating pollution. These pollutants will tend to accumulate in inner urban surface soils according to the available adsorption capacity, which is normally higher in soils overlying limestone than in soils overlying sandstone. However, inner urban surface soils overlying sandstone show elevated concentrations of carbonates, phyllo-silicates and Fe and elevated pH values compared with forest soils overlying sandstone. Thus, in comparison to forest soils overlying sandstones, inner urban soils overlying sandstone affected by pollution concurrently possess elevated concentrations of mineral phases typically providing relatively high adsorption capacities for heavy metals.  相似文献   

13.
The behaviour of trace elements (Al, As, Cd, Co, Cr,Cu, Fe, Mn, Ni, V, Zn) was studied in five humus-richstreams (dissolved organic carbon = 14–40 mg/L)impacted by acid sulphate soils developed in marinesulphide-bearing fine-grained sediments. During heavyrainfalls in autumn, on which the study focusses, themetals Al, Cd, Co, Cu, Mn, Ni and Zn are extensivelyleached from these acidic soils (pH = 2.5–4.5), whileAs, Cr, Fe and V are not leached more strongly fromthis soil type than from areas of till and peat. Aspeciation experiment, based on anion and cationexchange of the stream waters in the field, showedthat (1) the metals Al, Cd, Co, Mn, Ni and Zn aretransported in the streams mainly as inorganiccations, (2) Cu exists mainly in cationic form but isalso to a significant extent associated with dissolvedhumic substances, (3) Fe occurs mainly in the anionicfraction explained by organic coating on colloidal Feoxyhydoxides and (4) the hydrochemistry of As, Cr andV is complex as these elements may exist in severalunquantified anionic fractions and to a minor extentin cationic species/forms. Whereas the proportion ofacid sulphate soils in the catchments had a largeimpact on concentrations levels of several elements inthe stream waters, these soils did not have a largeaffect on the speciation of elements in water.  相似文献   

14.
The seismic ground motion hazard is mapped in the Sikkim Himalaya with local and regional site conditions incorporated through geographic information system. A strong motion network in Sikkim comprising of 9 digital accelerographs recorded more than 100 events during 1998–2002, of which 41 events are selected with signal-to-noise ratio 3 for the estimation of site response (SR), peak ground acceleration (PGA) and predominant frequency (PF) at all stations. With these and inputs from IRS-1C LISS III digital data, topo-sheets, geographical boundary of the State of Sikkim, surface geological maps, soil taxonomy map in 1:50,000 scale and seismic refraction profiles, the seismological and geological thematic maps, namely, SR, PGA, PF, lithology, soil class, %slope, drainage, and landslide layers are generated. The geological themes are united to form the basic site condition coverage of the region. The seismological themes are assigned normalized weights and feature ranks following a pair-wise comparison hierarchical approach and later integrated to evolve the seismic hazard map. When geological and seismological layers are integrated together through GIS, microzonation map is prepared. The overall site response, PGA and predominant frequency show an increasing trend in the NW–SE direction peaking at Singtam in the lesser Himalaya. As Main Boundary Thrust (MBT) is approached, the attribute value increases further. A quasi-probabilistic seismic hazard index has been proposed based on site response, peak ground acceleration and predominant frequency. Six seismic hazard zones are marked with percent probability <22%, 22–37%, 37–52%, 52–67%, 67–82%, >82% at 3 Hz and <20%, 20–34%, 34–48%, 48–61%, 61–75%, >75% at 9 Hz. In the microzonation vector layer of integrated seismological and geological themes also six major zones are mapped, with percent probability <15%, 15–31%, 31–47%, 47–63%, 63–78%, >78% at low frequency end. The maximum risk is attached to the probability greater than 78% in the Singtam and its adjoining area. These maps are generally better spatial representation of seismic hazard including site-specific analysis.  相似文献   

15.
A small watershed (160 km2) located in the Massif Central (France) has been chemically, isotopically and hydrologically studied through its dissolved load, bed sediments and soils. This watershed is underlain by basaltic bedrock and associated soils in which the vegetation is dominated mainly by meadows.Dissolved concentrations of major ions (Cl, SO4, NO3, HCO3, Ca, Na, Mg, K, Al and Si), trace elements (Rb and Sr) and strontium isotopes have been determined for two different hydrologic periods on the main stream of the Allanche river and its tributaries.The major objectives of this study were to characterize the chemical and isotopic signatures of each reservoir occurring in the watershed. Changes in chemical and isotopic signatures are interpreted in terms of fluctuations of the different components inputs: rainwater, weathering products, anthropogenic addition.Water quality may be influenced by natural inputs (rainwater, weathering processes) and anthropogenic additions (fertilizers, road salts, etc.). Precipitation serves as a major vehicle for dissolved chemical species in addition to the hydrosystem and, in order to constrain rain inputs, a systematic study of rainwaters is carried out over a one year period using an automatic collector. Corrections of rainwater addition using chloride as an atmospheric input reference were computed for selected elements and the Sr/Sr ratio. After such corrections, the geochemical budget of the watershed was determined and the role of anthropogenic additions evaluated through the relationship between strontium isotopes and major and trace element ratios. Thus, 10% of Ca and Na originate in rainwater input, 40 to 80% in fertilizer additions and 15 to 50% in rock weatheringThe cationic denudation rates for this watershed are around 0.3 g s–1 km2 during low water discharge and 0.6 g s–1 km2 in high water stage. This led to a chemical denudation rate of 5.3 mm/1000 years.For solid matter, the normalization of chemical species relative to parent rocks shows the depletion or enrichment in soils and sediments. The use of K and Ca as mobile reference illustrates the weathering state of soils and sediments relative to parent rocks. This weathering state for bed sediments range from 15 to 45% for the K normalization and from 2 to 50% for the Ca normalization. For the soils, the weathering state ranges from 15 to 57% for the K normalization and from 17 to 90% for the Ca normalization.  相似文献   

16.
Calayır  Yusuf  Sayın  Erkut  Yön  Burak 《Natural Hazards》2012,60(2):703-713
Numerous studies demonstrated the possibility of utilizing fly ash in the construction of embankments, road subgrades and stabilization of a wide range of soils. The present investigation aims at determining the optimum fly ash (OFA) for mechanical stabilization of expansive soils. Four different soils were tested for compaction characteristics and unconfined compressive strength with and without the addition of fly ash to determine the OFA. The liquid limit (LL) and the fraction coarser than 425 μ (CF) of these soils range from 50 to 120 and 25 to 70%, respectively. An experimental strategy called two-factor factorial design was adopted in the conducting experiments. LL and CF present in the soil are the two factors considered to influence the OFA content. Factorial experimentation enables relative quantification of the effect of each factor as well as their interaction with the OFA. The OFA was found to range from 5 to 40% depending upon the two factors. The LL and the CF were found to have dominating influence on OFA content in that order, whereas the interaction effect of these two factors was marginal to fair. A statistical regression model was developed for determination of the OFA in terms of the influencing factors. The validity of the model developed was verified by conducting laboratory tests on two more soils that were not used in the development of the model. Swell potential and swelling pressure of expansive soils were reduced to non-critical levels when treated with OFA.  相似文献   

17.
Stabilization of fuel oil contaminated soil—A case study   总被引：1，自引：0，他引：1  
Fuel oil contamination brings adverse effect on basic geotechnical properties of foundation soil. The present study pertains to one such case, from the petrochemical complex near Vadodara City in Gujarat State, India. Here, the fuel oil contaminated soil samples exhibit drastic changes in their geotechnical parameters. Noteworthy among such deleterious changes are: decrease in maximum dry density (–4%), cohesion (–66%), angle of internal friction (–23%) and unconfined compressive strength (UCS) (–35%) and increase in liquid limit (+11%). An attempt has been made to stabilize the contaminated soil using various additives viz., lime, fly ash and cement independently as well as an admixture of different combinations. It is apparent from the test results that the stabilization agents improved the geo-technical properties of the soil by way of cation exchange, agglomeration, and pozzuolanic actions. The best results were observed when a combination of 10% lime, 5% fly ash and 5% cement was added to the contaminated soil. The improvement in unconfined compressive strength (UCS), cohesion and angle of internal friction can be attributed to neo-formations such as Calcium Silicate Hydrates (CSH, CSH-1) that coats and binds the soil particles. Formation of stable complex between oil and metallic cations, results in reduction of leachableoil.  相似文献   

18.
To support the development of protocols for the proposed North American Soil Geochemical Landscapes project, whose objective is to establish baselines for the geochemistry of North American soils, two continental-scale transects across the United States and Canada were sampled in 2004. The sampling employed a spatially stratified random sampling design in order to estimate the variability between 40-km linear sampling units, within them, at sample sites, and due to sample preparation and analytical chemical procedures. The 40-km scale was chosen to be consistent with the density proposed for the continental-scale project. The two transects, north–south (N–S) from northern Manitoba to the USA–Mexico border near El Paso, Texas, and east–west (E–W) from the Virginia shore north of Washington, DC, to north of San Francisco, California, closely following the 38th parallel, have been studied individually. The purpose of this study was to determine if statistically significant systematic spatial variation occurred along the transects. Data for 38 major, minor and trace elements in A- and C-horizon soils where less than 5% of the data were below the detection limit were investigated by Analysis of Variance (ANOVA). A total of 15 elements (K, Na, As, Ba, Be, Ce, La, Mn, Nb, P, Rb, Sb, Th, Tl and W) demonstrated statistically significant (p < 0.05) variability at the between-40-km scale for both horizons along both transects. Only Cu failed to demonstrate significant variability at the between-40-km scale for both soil horizons along both transects.The patterns of relative variability differ by transect and horizon. The N–S transect A-horizon soils show significant between-40-km scale variability for 29 elements, with only 4 elements (Ca, Mg, Pb and Sr) showing in excess of 50% of their variability at the within-40-km and ‘at-site’ scales. In contrast, the C-horizon data demonstrate significant between-40-km scale variability for 26 elements, with 21 having in excess of 50% of their variability at the within-40-km and ‘at-site’ scales. In 36 instances, the ‘at-site’ variability is statistically significant in terms of the sample preparation and analysis variability. It is postulated that this contrast between the A- and C- horizons along the N–S transect, that is dominated by agricultural land uses, is due to the local homogenization of Ap-horizon soils by tillage reducing the ‘at-site’ variability. The spatial variability is distributed similarly between scales for the A- and C-horizon soils of the E–W transect. For all elements, there is significant variability at the within-40-km scale. Notwithstanding this, there is significant between-40-km variability for 28 and 20 of the elements in the A- and C-horizon data, respectively. The differences between the two transects are attributed to (1) geology, the N–S transect runs generally parallel to regional strikes, whereas the E–W transect runs across regional structures and lithologies; and (2) land use, with agricultural tillage dominating along the N–S transect. The spatial analysis of the transect data indicates that continental-scale maps demonstrating statistically significant patterns of geochemical variability may be prepared for many elements from data on soil samples collected on a 40 × 40 km grid or similar sampling designs resulting in a sample density of 1 site per 1600 km2.  相似文献   

19.
Environmental change in NW Iberia between 7000 and 500 cal BC   总被引：1，自引：0，他引：1  
We review research done on environmental changes in northwest (NW) Iberia spanning from the beginning to the late Holocene (7000–500 cal. BC). The type of archives (peat bogs, lake sediments, colluvium, soils, etc.) and proxies (pollen, element concentrations, isotopes, etc.) that were used to reconstruct changes on climate, soils, vegetation and atmospheric metal pollution are briefly described. Then we synthesize what the records suggest about the ecological history of NW Iberia. We identified four main phases: 7000–5000, 5000–3000, 3000–1500 and 1500-500 cal. BC. Each phase is determined by a set of environmental conditions, a combination of changes in climate, vegetation, soils and human impact. Human activities seem to have been involved in landscape changes in NW Iberia since at least 5000 cal. BC, with an increasing degree of anthropisation through time, which accelerated by 1500 cal. BC. The interaction between human activities and natural changes expressed as modifications in the vegetation cover, the elimination of the soil resources in many areas and its concentration in more localized, control-demanding sectors, as well as a progressive acidification and pollution of continental ecosystems. To a great extent, the present landscape in NW Iberia is the end product of these complex interactions, a cultural landscape.  相似文献   

20.
An area of a Tertiary and Cretaceous deposits, 100–310 m above sea level and on predominant 20–45°, highly dissected, concave slopes was investigated to assess its geotechnical characteristics and land use planning implications. Lithologies include turbidites, fluvial conglomerates, breccias, sandstones, mudrocks, carbonates, granodiorite, acid dykes, chloritized and epidotized volcanics, andesite and Holocene fluvial deposits. Bedrock is highly fractured and sheared, hydrothermally altered and highly weathered. Soils are quite variable, with a strong geological control on soil properties. Soils are generally sandy to gravely, with local silts and clays in mudrocks, within Holocene alluvium or in hydrothermally altered and sheared granodiorites. The soils are composed of 0.14–80.00% gravel; 5.36–62.50% sand, 2.33–50.55% silt, 0.17–51.50% clay, and total fine content between 2.50 and 94.50%, with natural moisture between 4 and 44% during the dry season, plastic limit between 6 and 35%, liquid limit between 19 and 83% and plasticity index between 1 and 59%. Sandy soils have residual friction angles between 19 and 39°, PI values less than 35% with cohesion between 1.00 and 5.27 KN/m2 for cohesive samples. ASTM classification of soils include soil groups GC, GM, GW, GP, SP, SM, SC, SM, SC, ML, CL and CH.

Based on the characteristics of the terrain, the geotechnical and land use planning problems include high landslide frequency and susceptibility, soil erosion, fluvial and reservoir sedimentation, high debris flow hazard, cut slope failures, potentially expansive clays and silts, seepage erosion and soil piping, differential settlement in interlayered competent and incompetent lithologies, high solution erosion and potential subsidence over limestones, waste water disposal problems and groundwater pollution and seismic induced settlement and ground failures. These phenomena suggest that systematic site investigations should be conducted prior to the utilization of these areas for construction and development in order to minimize the deleterious effects resulting from ground failure.  相似文献   


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