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1.
《Applied Geochemistry》2005,20(7):1391-1408
Surface water samples from the St. Lawrence River were collected in order to study the processes controlling minor and trace elements concentrations (Al, Fe, Mn, Cd, Co, Cu, Ni and Zn), and to construct mass balances allowing estimates of the relative importance of their natural and anthropogenic sources. The two major water inputs, the upper St. Lawrence River, which drains waters originating from the Lake Ontario, and the Ottawa River were collected fortnightly over 18 months. In addition, other tributaries were sampled during the spring floods. The output was monitored near Quebec City at the river mouth weekly between 1995 and 1999. Dissolved metal concentrations in the upper St. Lawrence River carbonated waters were lower than in the acidic waters of the tributaries draining the crystalline rocks of the Canadian shield and the forest cover. Biogeochemical and hydrodynamic processes occurring in Lake Ontario drive the seasonal variations observed in the upper St. Lawrence River. Biogeochemical processes relate to biological uptake, regeneration of organic matter (for Cd and Zn) and oxyhydroxide formation (for Mn and Fe), while hydrodynamic processes mainly concern the seasonal change in vertical stratification (for Cd, Mn, and Zn). In the Ottawa River, the main tributary, oxyhydroxide formation in summer governs seasonal patterns of Al, Fe, Mn, Cd, Co and Zn. The downstream section of the St. Lawrence River is a transit zone in which seasonal variations are mainly driven by the mixing of the different water masses and the large input of suspended particulate matter from erosion. The budget of all dissolved elements, except Fe and Zn, was balanced, as the budget of particulate elements (except Cd and Zn). The main sources of metals to the St. Lawrence River are erosion and inputs from tributaries and Lake Ontario. Direct anthropogenic discharges into the river accounted for less than 5% of the load, except for Cd (10%) and Zn (21%). The fluxes in transfer of dissolved Cd, Co, Cu and Zn species from the river to the lower St. Lawrence estuary were equal to corresponding fluxes calculated for Quebec City since the distributions of dissolved concentrations of these metals versus salinity were conservative. For Fe, the curvature of the dilution line obtained suggests that dissolved species were removed during early mixing.  相似文献   

2.
Questions persist concerning the earthquake potential of the populous and industrial Lake Ontario (Canada–USA) area. Pertinent to those questions is whether the major fault zone that extends along the St. Lawrence River valley, herein named the St. Lawrence fault zone, continues upstream along the St. Lawrence River valley at least as far as Lake Ontario or terminates near Cornwall (Ontario, Canada)–Massena (NY, USA). New geological studies uncovered paleotectonic bedrock faults that are parallel to, and lie within, the projection of that northeast-oriented fault zone between Cornwall and northeastern Lake Ontario, suggesting that the fault zone continues into Lake Ontario. The aforementioned bedrock faults range from meters to tens of kilometers in length and display kinematically incompatible displacements, implying that the fault zone was periodically reactivated in the study area. Beneath Lake Ontario the Hamilton–Presqu'ile fault lines up with the St. Lawrence fault zone and projects to the southwest where it coincides with the Dundas Valley (Ontario, Canada). The Dundas Valley extends landward from beneath the western end of the lake and is marked by a vertical stratigraphic displacement across its width. The alignment of the Hamilton–Presqu'ile fault with the St. Lawrence fault zone strongly suggests that the latter crosses the entire length of Lake Ontario and continues along the Dundas Valley.The Rochester Basin, an east–northeast-trending linear trough in the southeastern corner of Lake Ontario, lies along the southern part of the St. Lawrence fault zone. Submarine dives in May 1997 revealed inclined layers of glaciolacustrine clay along two different scarps within the basin. The inclined layers strike parallel to the long dimension of the basin, and dip about 20° to the north–northwest suggesting that they are the result of rigid-body rotation consequent upon post-glacial faulting. Those post-glacial faults are growth faults as demonstrated by the consistently greater thickness, unit-by-unit, of unconsolidated sediments on the downthrown (northwest) side of the faults relative to their counterparts on the upthrown (southeast) side. Underneath the western part of Lake Ontario is a monoclinal warp that displaces the glacial and post-glacial sediments, and the underlying bedrock–sediment interface. Because of the post-glacial growth faults and the monoclinal warp the St. Lawrence fault zone is inferred to be tectonically active beneath Lake Ontario. Furthermore, within the lake it crosses at least five major faults and fault zones and coexists with other neotectonic structures. Those attributes, combined with the large earthquakes associated with the St. Lawrence fault zone well to the northeast of Lake Ontario, suggest that the seismic risk in the area surrounding and including Lake Ontario is likely much greater than previously believed.  相似文献   

3.
The concentration of selected contaminant trace metals and organic contaminants, namely polycyclic aromatic hydrocarbons (PAHs), normal-alkanes, total polychlorinated biphenyls (PCBs), and other organochlorines, was studied in cores from shallow-water fine-grain sediments from both sides of the maximum turbidity zone (MTZ) in the upper estuary of the St. Lawrence. Average trace metal concentrations in the cores were generally lower in downstream sediments, except for Hg and Pb. Hg levels in the cores were very high, exceeding 0.7 μg g?1 in core C168 (south shore) and 0.19 μg g?1 in core LE (north shore). Trace metal concentrations in all the cores were highly variable with depth, but after normalization with reference to iron, the trend was remarkably uniform, thus confirming an important inverse relationship with grain size. A similar lack of a well-defined trend was noted in the profiles of the organic components in the modern sediments. Average PAH values for modern sediments at core sites C168 and LO were 1.05 μg g?1 and 0.44 μg g?1, respectively (i.e., less than or equal to those in Lake Ontario and upstream in the river). PCB values far exceeded those in upstream sediments (average: 347 ng g?1 in core LE and 158 ng g?1 in C168), but were less than in Lake Ontario. Concentrations of chlordane, heachlorobenzene, and mirex were relatively low and uniform in the modern sections of the cores. The vertical uniformity of both the contaminant profiles and those for Cs-137 (C168) suggests that the sediments are relatively young (i.e., definitely less than 35 yr at C168, and probably even less at LE and LO). Therefore no long-term or historical trend is evident.  相似文献   

4.
The vertical structure of the water column and the spatial distribution and semidiurnal variability of bacteria were investigated at six stations in the upper St. Lawrence estuary. The σ1 profiles indicate that the upper St. Lawrence is a partially mixed estuary. Stratification results from buoyancy input from the freshwater outflow of the St. Lawrence River, and its variability is controlled by tidal and, to a lesser extent, wind mixing. Calculations show that tidal mixing largely exceeds mixing caused by wind. Free and attached bacteria presented different patterns of spatial distribution and temporal variability. Free bacteria exhibited highest mean concentrations at the freshwater station (3.5–4.4 106ml?1) and lowest concentrations at the downstream stations (0.3–0.5 106ml?1); their numbers declined exponentially relative to salinity. Attached bacteria had highest mean concentrations (3.2–5.5 106ml?1) at salinities between 0.5 and 5 and were virtually absent at downseam stations (<0.05 106ml?1). The importance of semidiurnal variability was demonstrated Over the idal cycle, variability of attached bacteria was always greater than that of free bacteria. The analysis of causal models between salinity and free and attached bacteria, showed that the two types of bacteria are uncoupled and that both types have a strong relationship with salimity. Physical processes are thus important controlling factors of the distribution and variability of bacteria. Results suggest that large-scale processes, such as freshwater outflow and residual circulation, largely control free bacteria, whereas short-term and more local processes (e.g., sediment resuspension caused by wind) may also be important in the control of attached bacteria.  相似文献   

5.
Concentrations of rare earth elements (REE) and yttrium (Y), and major metals (Al, Fe and Mn) were measured in suspended particulate matter (SPM) and bottom sediments of the Kali estuary, western India, for their distribution and fractionation. The contents of SPM and metals in it were more uniform along the longitudinal transect during the monsoon. During the post- and pre-monsoons, low SPM in the upper/middle estuary coincided with high Fe and Mn and total REE (∑REE). But in the lower estuary SPM and its ∑REE content increased seaward, while Fe and Mn decreased. The Y/Ho ratios decreased seaward during the monsoon but increased during the post-monsoon. Sm/Nd ratios were more uniform along the transect during monsoon but decreased marginally seaward in other seasons. The Post-Archean Average Australian Shale (PAAS)-normalized REE patterns exhibited middle REE and heavy REE enrichment with positive Ce (\({\text{Ce}}/{\text{Ce}}^{*}\)), Eu (\({\text{Eu}}/{\text{Eu}}^{*}\)) and Y anomalies. The \({\text{Ce}}/{\text{Ce}}^{*}\) increased but \({\text{Eu}}/{\text{Eu}}^{*}\) decreased marginally seaward. The fine-grained sediments showed higher ∑REE and lower Y/Ho ratios than in coarse-grained sediments. The PAAS-normalized REE patterns of sediment were similar to that of SPM. The results revealed two processes, colloidal flocculation and coagulation of metals in the low-salinity zone and an estuarine turbidity maximum in the high salinity zone. Rare earths and yttrium (REY) in SPM and sediments primarily reflected the source rock composition than that of chemical weathering. Apart from physico-chemical processes, the mineralogy and grain size of sediments controlled the distribution and fractionation of REY in the estuary.  相似文献   

6.
珠江河口沉积物粒度特征及其对底层水动力环境的指示   总被引：17，自引：3，他引：14  
珠江口伶仃洋及邻近海域沉积物粒级变化大。频率分布曲线形态的变化揭示了珠江河口不同区域泥沙来源的差异。在平面分布上,粗粒级含量从西北部和北部向东南部迅速降低,而细粒级含量高值往往出现在河口中部。表层沉积物平均粒径梯度变化方向与珠江口悬浮物的运移方向大致吻合。反演获得的底层海流不同区域的优势速度与实测资料相符。两者较好地指示了沉积物多年平均优势海流速度和方向,表明利用沉积物粒度数据比较成功地反演出了珠江口沉积物推积前的搬运水动力环境。  相似文献   

7.
为阐明强潮河口最大浑浊带的形成机制及其运动规律,通过瓯江和椒（灵）江实测资料分析,系统分析了强潮河口最大浑浊带形成的影响因素及其与河口地貌的响应关系。考虑黏性细颗粒泥沙运动特性和盐度的影响,开发了强潮河口最大浑浊带数学模型,对椒（灵）江枯季大潮最大浑浊带运移过程进行了模拟。结果表明:①强潮河口最大浑浊带是潮波变形、咸淡水混合、泥沙再悬浮等复杂因素在一定河口边界和泥沙条件下相互作用的产物,潮波变形和泥沙供给是影响最大浑浊带形成的关键因素。②强潮河口最大浑浊带模拟必须充分考虑潮流、盐淡水混合、泥沙周期性起动、絮凝和沉积密实等因素,所建立的数学模型可用于强潮河口最大浑浊带研究。  相似文献   

8.
Trace element distributions, partitioning, and speciation were examined at 15 sites in the Patuxent River watershed from May 1995 through October 1997 to determine possible sources of trace elements to the river and estuary, to examine the relationship of the trace element discharges to freshwater discharges as well as to land use and geographic region, to validate previous estimates of loadings to the river, and to provide baseline data for trace elements in the Patuxent River watershed and estuary. Six freshwater sites were examined, representing different basins and geographic provinces, and nine sites along the estuarine salinity gradient. Subregions within the watershed varied considerably in concentrations and areal yields for some elements. Concentrations of As, Cd, Ni, Pb, and Zn were elevated in the Coastal Plain sites compared to the Piedmont sites, while Cu and Hg were more evenly distributed. Cadmium, Cu, Hg, Ni, Pb, and Zn showed overall positive correlations with river flow while As and methylHg (meHg) showed negative correlations with river flow. Concentrations of trace elements in the estuarine portion of the river were generally low, and consistent with mixing between Patuxent River water with elevated concentrations and the lower concentrations of the Chesapeake Bay. Interesting features included a local Cd maximum in the low salinity region of the estuary, probably caused by desorption from suspended sediments, and a significant input of water containing high As concentrations from the Chesapeake Bay and from As being released from bottom sediments in summer. Comparisons between the estimated annual flux of trace elements and the estimates of suspected source terms (atmospheric deposition, urban runoff, and known point sources) suggest that, except for Hg, direct atmospheric deposition is small compared to fluvial loads. Current estimates of trace element inputs from point sources or from urban runoff are inadequate for comparison with other sources, because of inappropriate techniques and/or unacceptably high detection limits. A complete examination of trace element dynamics in the Patuxent River (and in other coastal systems) will require better data for these potential sources.  相似文献   

9.
The St. Lawrence rift system from the Laurentian craton core to the offshore St. Lawrence River system is a seismically active zone in which fault reactivation is believed to occur along late Proterozoic to early Paleozoic normal faults related to the opening of the Iapetus ocean. The rift-related faults fringe the contact between the Grenvillian basement to the NW and Cambrian–Ordovician rocks of the St. Lawrence Lowlands to the SE and occur also within the Grenvillian basement. The St. Lawrence rift system trends NE–SW and represents a SE-dipping half-graben that links the NW–SE-trending Ottawa–Bonnechère and Saguenay River grabens, both interpreted as Iapetan failed arms. Coastal sections of the St. Lawrence River that expose fault rocks related to the St. Lawrence rift system have been studied between Québec city and the Saguenay River. Brittle faults marking the St. Lawrence rift system consist of NE- and NW-trending structures that show mutual crosscutting relationships. Fault rocks consist of fault breccias, cataclasites and pseudotachylytes. Field relationships suggest that the various types of fault rocks are associated with the same tectonic event. High-resolution marine seismic reflection data acquired in the St. Lawrence River estuary, between Rimouski, the Saguenay River and Forestville, identify submarine topographic relief attributed to the St. Lawrence rift system. Northeast-trending seismic reflection profiles show a basement geometry that agrees with onshore structural features. Northwest-trending seismic profiles suggest that normal faults fringing the St. Lawrence River are associated with a major topographic depression in the estuary, the Laurentian Channel trough, with up to 700 m of basement relief. A two-way travel-time to bedrock map, based on seismic data from the St. Lawrence estuary, and comparison with the onshore rift segment suggest that the Laurentian Channel trough varies from a half-graben to a graben structure from SW to NE. It is speculated that natural gas occurrences within both the onshore and offshore sequences of unconsolidated Quaternary deposits are possibly related to degassing processes of basement rocks, and that hydrocarbons were drained upward by the rift faults.  相似文献   

10.
《Applied Geochemistry》2000,15(5):567-581
The Pearl River estuary is created by the inflow of freshwater from the largest river system that drains into the South China Sea. In recent years, massive economic growth and development in the region has led to excessive release of waste into the environment. The accumulation of contaminants in sediments is likely to pose serious environmental problems in surrounding areas. The study of sediment profiles can provide much information on the metal contamination history and long term potential environmental impacts. In this project, 21 core samples (up to 3.65 m deep) were collected in the Pearl River estuary. About 15 subsamples from each core were analysed for moisture content, total organic matter (L.O.I.), particle size and heavy metal and major element concentrations. The results show that Pb and Zn contents are elevated in the sediments at most of the sampling sites. Compared with historical monitoring results, the sediment metal contents have increased over the last 20 a, particularly for Pb. The west side of the Pearl River estuary tends to be more contaminated than the east side due to the contaminants inputs from the major tributaries and different sedimentation conditions. There are close associations between Fe, Co, Ni and Cu concentrations in the sediments. Zinc and Pb contents in the sediment profiles reflect a combination of the natural geochemical background, anthropogenic influences and the mixing effects within the estuary. The distribution of Pb in the sediments shows strong influences of atmospheric inputs, probably from the coal burning activities in the region.  相似文献   

11.
北部湾东部海域表层沉积物稀土元素组成及物源指示意义   总被引：8，自引：0，他引：8  
窦衍光  李军  李炎 《地球化学》2012,(2):147-157
对北部湾东部海域70个表层沉积物样品的稀土元素(REE)分析结果表明,研究区沉积物 REE 呈现轻稀土元素(LREE)富集、重稀土元素(HREE)平坦以及中等程度的 Eu 异常等特征.REE 组成受沉积物粒度和生物碳酸盐含量的制约,具有典型风化上陆壳 REE 特征,其源岩以上陆壳的长英质岩石为主.根据研究区沉积物 REE 分布规律,研究区可划分为4个地球化学分区,各区域上陆壳标准化曲线明显的不同.物源判别显示研究区的西部、海南岛西南侧(Ⅰ区)呈多源沉积特征,来自以下几个物源区:(1)海南岛西南侧河流沉积物和沿岸侵蚀物;(2)由南向北输入的外海沉积物(冬季);(3)夏季或冬季由北部湾西北部和西部搬运来的沉积物.研究区中部粗粒沉积区(Ⅱ区)与北部湾西部沉积物来源是相同的,主要来源于红河输砂.东北部砂质区(Ⅲ区)沉积物可能来源于雷州半岛西北部近岸基岩侵蚀.研究区东北部(Ⅳ区)沉积物主要来自北部湾北部沿岸侵蚀、琼州海峡和雷州半岛西部的沿岸侵蚀.此外,部分沉积物还可能来自珠江流域以及南海北部陆架区和北部湾西北部  相似文献   

12.
The species composition and relative abundance of ichthyoplankton were investigated during summer 1986 at four stations along the salinity gradient in the Manicouagan River estuary, a tributary of the lower St. Lawrence estuary. Physical characteristics of water masses indicated the presence of a strong saline front (>10‰ per km) delineating the freshwater and marine section of the Manicouagan estuary. The estuary supports a depauperate ichthyoplankton community, including four species of pelagic fish eggs and eight species of fish larvae. Species richness increased with salinity. The ichthyoplankton fauna can be divided into two distinct groups: freshwater and marine. These two groups result initially from spawning preferences exhibited by the different species abundance of freshwater larvae was maximal at the head of the estuary and marine larvae were most abundant at the most saline station. The length frequency distribution suggests that marine larvae are not effectively retained within the estuary. The Manicouagan estuary cannot be considered as a major spawning site nor an important nursery zone for any fish found in this area.  相似文献   

13.
We tested the hypothesis that the distribution and retention of larval smelt (Osmerus mordax) in the middle estuary of the St. Lawrence River is related to the maintenance of other planktonic organisms in the maximum turbidity zone (MTZ). We documented the horizontal and vertical distribution of larval smelt, macrozooplankton, and suspended particulate matter over four tidal cycles at each of three stations located along the major axis of the turbid upstream portion of the middle estuary. During summer, the turbid, warm, and low salinity waters of the two upstream stations were characterized byNeomysis americana, Gammarus sp. (principallyG. tigrinus), larval smelt,Mysis stenolepsis, andCrangon septemspinosus. The more stratified and less turbid waters of the downstream station were characterized by a coastal marine macrozooplanktonic community and the almost total absence of smelt larvae. Within the MTZ, the distribution ofN. americana coincided with the zone of longest average advective replacement times (null zone). Smelt larvae were distributed further upstream within the MTZ thanN. americana. Overall, larger larvae were distributed further upstream than smaller larvae. The relationship between turbidity and larval density at a specific time was weak (due to resuspension of sediments but not larvae), but the mechanism responsible for producing higher residence times for both sediment and larvae on a longer term basis appears the same. The daily movement and skewed nature of the null zone (due to the general cyclonic circulation of the middle estuary) defines a geographic zone over which the larval smelt population oscillates and remains despite the mean downstream velocities over the water column.  相似文献   

14.
Sixty-eight samples of sediment collected on a variably-spaced grid pattern from Pamlico River Estuary of North Carolina were analyzed for As, Cd, Co, Cr, Cu, F, Ni, Pb, U, Zn, clay, and organic matter. The major objectives of the study were to determine background and anomalous levels of trace elements in the sediments, and the effects of human activities on concentration and distribution of trace elements in the sediments. Clay and organic matter are more concentrated near the center of the estuary. This causes the highest concentration of trace elements in the sediments to be located there also owing to their preferential uptake of these elements. Highest trace element concentrations were observed in clay and organic matter near industrial sites, housing developments, and tributary mouths that drain areas of human activity. The apparent increase in trace element contents of fine sediments in Pamlico River Estuary owing to human activities is 4 to 1,750 times normal background levels.  相似文献   

15.
Based on high spatial resolution monitoring, the first spatial distribution maps for the eight trace elements identified as priority contaminants in aquatic systems (i.e. As, Cd, Cr, Cu, Hg, Ni, Pb and Zn) in surface sediments of the Gironde Estuary (SW France) are presented. This large European fluvial–estuarine system is known for important historical multi-element (mainly Cd, Zn, Cu and Pb) pollution by former mining and mineral processing activation in the Riou-Mort watershed located 350 km upstream the estuary. As a consequence, oyster production in the estuary is prohibited, and Cd concentrations in oysters from the Marennes-Oléron area are close to consumption thresholds. Surface sediment samples were analysed for grain size, particulate organic C and trace element concentrations. Determination of trace elements was carried out by ICP-MS for As, Cd, Cr, Cu, Ni, Pb, Th and Zn, and by CV-AAS for Hg. Total and potentially released trace element stocks in the surface sediment were evaluated by using concentrations in the estuary and in selected sediment core. Assuming that sediment resuspension affects mainly the uppermost sediment layer, the total trace element stocks in the studied 0–10 cm depth range may represent the equivalent of one (Cd) to eight (As, Cr) times the annual fluvial trace element inputs into the estuary. Comparing total trace element concentrations in surface sediment with: (i) data on the regional geochemical baseline to evaluate the potentially remobilised fraction and (ii) the potentially bioavailable fraction aimed at establishing a first spatially resolved risk assessment of the trace element “cocktail” present in these sediments at the estuary scale. After correction for grain size effects by Th normalisation, potentially highly toxic metals such as Cd and Hg showed the highest enrichment factors. From ecotoxicological indices, areas were identified and quantified where trace element levels and mobility may bear a risk to benthic organisms. The GIS-based spatial distribution of ecotoxicological indices for the trace element “cocktail” suggests that ∼95% of the surface sediment are ‘Low–Medium’-priority zones, highlighting the need for further impact studies. The produced maps of trace element distributions and associated risk potentials are likely to be a useful tool to authorities in charge of sustainable estuarine management, e.g. for the optimisation of dredging activities or development of the estuarine infrastructure.  相似文献   

16.
基于潮间带和浅海12个柱状样粒度、地球化学元素、210Pb同位素实测数据,结合河流年代特征、岸线历史变化等资料,参照前人关于沉积相和沉积速率研究成果,对现代黄河三角洲南部潮间带及莱州湾西部海域沉积特征进行了分析。根据剩余210Pb比活度信息,综合运用历史地理学方法、沉积环境判别公式和粒度曲线变化特征,初步认识了现代黄河三角洲南部潮间带地区具体沉积年代。对柱状样的数据进行分析后,运用相关特征值定量区分了沉积物的物源。结果表明:在潮间带这样不稳定的沉积环境下,210Pbex比活度阶段性倒置的分布模式虽然无法对年代进行连续标定,但可以在很大程度上指示沉积环境变化。现代黄河三角洲南部潮间带沉积物形成时间要远早于莱州湾西部,210Pb结合沉积环境判别函数、历史地理资料以及粒度特征可以将深度102 cm、80 cm、32 cm分别标定为1929年、1934年和1947年。广利河水系在深度20 cm范围内影响沉积环境。地球化学元素相关特征值分析显示:现代黄河三角洲南部潮间带沉积物风化程度介于黄河和莱州湾南岸之间,个别微量元素富集程度与莱州湾沉积物差异明显,就沉积环境而言,与现代黄河沉积物已有所不同。  相似文献   

17.
The distribution of Mn was examined in the bottom sediments and water column (suspended paniculate matter) of the Laurentian Trough. Gulf of St. Lawrence. A characteristic profile of Mn with depth in the sediment consisted of a Mn-enriched surface oxidized zone, less than 20 mm thick, and a Mn-depleted subsurface reducing zone. A subsurface Mn maximum occurred within the oxidized zone. Below this maximum the concentration dropped sharply to nearly constant residual levels in the reducing zone. The accumulating estuarine sediments are deficient in Mn compared to the river input of suspended matter and are definitely not the ultimate sink for manganese. Manganese escapes from the sediment by diffusion and resuspension, forming Mn-enriched, fine-grained particles which are flushed out in the estuarine circulation. 5.0 × 109gyr?1 of Mn, or 50% more than the river input of dissolved Mn. are exported to the open ocean. In spite of the efficient mobilization and export of Mn, the quantity exported is a small fraction (0.2%) of the total flux to the deep-sea sediments. This is related to the low levels of paniculate matter transported by the St. Lawrence River. The export phénomenon, however, is probably true of many coastal regions of muddy sediments and thus has interesting implications for the oceanic budget of Mn.  相似文献   

18.
Eighteen sediment samples and six water-column samples were collected in a small (6 km2), coastal embayment (Port Jefferson Harbor, New York) to define a high-resolution spatial distribution of metals and to elucidate sources of contaminants to the harbor. Sediment metal (Ag, Cu, Fe, Ni, Pb, V, and Zn) concentrations varied widely, reflecting differences in sediment grain size, with higher metal concentrations located in the fine-grained inner harbor sediments. Calculated enrichment factors for these sediments show that Ag, Pb, Cu, and Zn are elevated relative to both crustal abundances and their respective abundances in sediments in central Long Island Sound. Metal concentrations were 1.2 to 10 fold greater in water from the inner harbor compared to water from Long Island Sound collected outside the mouth of the harbor. Spatial variations in trace metals in surface waters within the bay parallel the spatial variations of trace metals in sediments within the harbor. Elevated water-column metal concentrations appear to be partially derived from a combination of diagenetic remobilization from contaminated sediments (e.g., Ag) and anthropogenic sources (e.g., Cu and Zn) within the southern portions of the harbor. Although the National Status and Trends Program had reported previously that sediment metal concentrations in Port Jefferson Harbor were low, the results of this study show sediment metals have high spatial variability and are enriched in the inner harbor sediments at levels comparable to more urbanized western north shore Long Island harbors.  相似文献   

19.
The effects of nutrients, trace elements, and trophic complexity on benthic photosynthesis and respriation were studied in the Paxtuxent River estuary near St. Leonard, Maryland. Experiments were conducted over three years (1995–1997) in mesocosms containing riverine sediment and water. The experimental design was 2×2×3 factorial with two levels of nutrients (ambient and + nutrients), two of trace elements (ambient and + trace elements) and three of trophic complexity (plankton, plankton + fish, and plankton + fish + benthos). Trace elements included arsenic (As), copper (Cu), and cadmium (Cd). The experiment was conducted three times in 1995 and 1997 and four times in 1996. In 1995 and 1996, sediments were muddy, while in the final year sediments were sandy. In mesocoms with sandy sediments, nutrient additions increased benthic photosynthesis overall, while trace element additions increased benthic photosynthesis in two of three experimental runs. Benthic photosynthesis in these mesocosms appeared to be related to nitrogen loading. Benthic respiration increased in nutrient and trace element amended mesocosms with sandy sediments, apparently in response to higher benthic photosynthesis. Increasing trophic complexity, particularly the presence of benthic organisms, also increased benthic respiration in mesocosms with sandy sediments. There were no effects of nutrient or trace element additions on benthic photosynthesis and respiration when the sediments were muddy. The lack of consistent responses to nutrient additions was surprising given that benthic respiration rates (and presumably nutrient regeneration) were similar in all three years, regardless of sediment type. Muddy, sediments did not mask, the effects of nutrient addition by supplying more nutrients to benthic microalgae than sandy sediments. In 1996, the presence of filter feeding bivalves increased the relative heterotrophy of sediments, measured as production: respiration. Consistent with increased heterotrophy, effluxes of ammonium and soluble reactive phosphorus from sediments were greater in mesocosms containing benthic organisms. Anthropogenically-induced changes in estuaries, such as loading of nutrients and trace elements or reduced trophic complexity, can have important effects on benthic processes and potentially pelagic processes through feedback mechanisms.  相似文献   

20.
辽河双台子河口淤泥质沉积物来源探析   总被引：3，自引：0，他引：3  
采用化学质量平衡法,分析双台子河口淤泥质沉积物的常量元素特征,并对沉积物来源进行了初步探析。结果表明: 常量元素在沿拦海大坝由北至南方向上变化较为复杂,在向海离岸方向上Al2O3、CaO、TFe2O3、MgO 等表现为岸边含量较高,向海方向上含量较低,SiO2的沉积分布与其相反。上述5 种元素具有很好的相关关系,表明了河口沉积物以陆源沉积为主。河口沉积物主要来源于西拉木伦河上游上侏罗统地层区( Ⅱ区) ,该区贡献率达76. 08%,其次为辽河下游第四系沉积物区( Ⅳ 区) ,贡献率达17. 10%。  相似文献   

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