共查询到16条相似文献,搜索用时 78 毫秒
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异类矿物结构基元层间层矿物研究 总被引:1,自引:0,他引:1
异类矿物结构基元层间层矿物研究曹正民,秦善,王启明(北京大学地质学系,北京100871)关键词晶体化学、异类矿物结构基元层、墨铜矿矿物的间层现象是由J.W.Gruner在1934年发现的。其中属同一大类矿物基元层交互堆叠而形成的间层矿物已有大量的研究... 相似文献
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朱立军 《矿物岩石地球化学通报》1996,(3)
碳酸盐岩红土中1.4nm间层矿物及其环境意义朱立军(贵州工学院,贵阳550003)关键词红土,间层矿物,土壤环境1.4nm间层矿物是指由绿泥石晶层与2:1型含水膨胀层交互连生所构成的不规划间层粘土矿物,其中2:1型含水晶层可以是蒙脱石层,也可以是蛭石... 相似文献
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华北石炭二叠纪煤系中I/S间层矿物的研究 总被引:1,自引:1,他引:1
华北石炭二叠煤系中的I/S间层粘土岩夹矸或粘土岩层,在太行山以东较为发育。I/S间层矿物的类型有累托石、IS有序间层矿物、S/I无序间层矿物,它们是在近岸泥岩沼泽或沼泽环境中由同期降落的火山灰蚀变而成,在酸性介质的影响下,形成IS有序间层矿物,在偏碱性的介质条件下,形成S/I无序间层矿物;高压异常区则形成累托石。 相似文献
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层状硅酸盐矿物晶体结构的多体性组装模式与构筑原理 总被引:2,自引:0,他引:2
将层状硅酸盐矿物晶体结构中属性不同的二维结构单元体看成是不同的结晶学模块,研究了一般层状硅酸盐矿物和间层矿物的多体性组装模式和构筑原理。结果表明,不同二维结构单元体(包括硅氧四面体片、八面体片、层间域(物))的构筑基本符合球体紧密堆积原理,紧密堆积层平行{0001};四面体片与八面体片构筑TO和TOT结构层时采取多种机制消除二者在二维尺寸上的差异;两种模式的结构层与不同类型的层间物(域)组装形成六种组装模式的晶层;并通过二维结构单元体的组合规律的分析,计算出可能存在的28种TOT型间层结构,它们分属于6种间层结构多体性组装模式;间层结构中,结构层对于八面体片是不对称的,并在属性上表现出极性特征;间层矿物的晶层类型可用6种多体性组装模式加以表达。层状硅酸盐矿物结构的多体性分析与组装模式的研究,对于矿物晶体化学研究是非常重要的。 相似文献
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金云母—蛭石间层矿物分晶层晶体化学式的计算及意义 总被引:10,自引:0,他引:10
金云母-蛭石间层矿物由金云母晶层与蛭石晶层交叠排列而成,采用一般计算方法得出的晶体化学式不能充分揭示结构中金云母晶层与蛭石晶层各自的晶体化学特征。本文以化学成分分析与阳离子容量为基础,假定可交换性阳离子均为蛭石晶层层间阳离子,非交换性阳离子为金云母晶层层间阳离子,金云母晶层与蛭石晶层具有相同的八面体层等,计算出了结构中两种晶层的分晶层晶体化学式,确定了结构中两种晶层的比例和蛭石晶层的电荷数。并在此基础上讨论了新疆尉犁蛭石矿金云母-蛭石间层矿物的晶体化学特征。结果表明该方法设计合理,符合晶体化学原理,所计算的数据可靠。利用该方法计算出的两种晶层的比例为金云母-蛭石1:1规则间层矿物的确定提供了必要的依据。也为其它类似间层矿物的研究提供了一种计算分晶层晶体化学式的可行方法。 相似文献
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通过X射线衍射、红外光谱、热分析、理化性能测试和镜下观察等手段,确定了贵州大方猫场含黄铁矿粘土岩中主要粘土矿物为伊/蒙不规则间层矿物,其间层作用类型为R=1,即累托石型有序间层。 相似文献
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Interstratification—periodic or nonperiodic stacking of two different silicate layers along a c∗-axis—is common in phyllosilicates. Published evidence indicates that some interstratified minerals precipitate directly from aqueous solutions. In this paper, we have demonstrated, based on chaos theory, that both periodic and nonperiodic interstratification can autonomously arise from simple kinetics of mineral growth from a solution. Growth of a mixed-layer mineral is assumed to proceed layer by layer, and each layer starts with the formation of a base (Si, Al)-O tetrahedral sheet, whose structural configuration in a-b dimensions determines the type of new layer that forms. The sequence of layer stacking can be described by a one-dimensional map (i.e., a difference equation), which accounts for two competing factors: (1) the affinity of each end-member structural component for attaching to the surface of the preceding layer, and (2) the strain energy created by stacking next to each other two silicate layers with different structural configurations. Chaotic (or nonperiodic) interstratification emerges when the contacting solution becomes slightly supersaturated with respect to both structural components. The transition from one interstratification pattern to another reflects a change in chemical environment during mineral crystallization. Our model can successfully predict the occurrence of mixed-layer phyllosilicates and the associated layer stacking sequences observed in both hydrothermal alteration and sediment diagenesis. The model suggests that the diagenetic transition of smectite → nonperiodic illite/smectite → ordered illite/smectite → illite may reflect relative changes in the saturation degree of pore water with respect to two end-member phases as a result of increasing burial temperatures. 相似文献
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金云母-蛭石间层矿物的酸浸取物与酸蚀机理研究 总被引:1,自引:0,他引:1
对采自新疆尉犁蛭石矿的金云母蛭石间层矿物样品进行了酸处理实验研究。在样品化学成分和XRD分析的基础上,研究了样品酸处理后酸浸取物的化学组成、含量及结构变化特征;分析讨论了金云母蛭石间层矿物在酸处理过程中不同阳离子浸出率的变化规律和酸蚀机理。结果表明,层间可交换性阳离子的氧化物CaO和Na2O的酸浸取率最高,层间不可交换性阳离子的氧化物K2O次之,八面体中阳离子的氧化物MgO、Fe2O3和Al2O3具有较高的酸浸取率,而四面体阳离子的氧化物Si O2的酸浸取率最低;金云母蛭石间层矿物中蛭石晶层含量高的样品酸浸取率高,金云母蛭石间层矿物的耐酸蚀性能不如金云母。 相似文献
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Transmission electron microscopy (TEM) results show there is a series of periodically and nonperiodically interstratified
structures composed of berthierine and chlorite layers in low-temperature “chlorite” that is one of the alteration products
of granulite-facies Archean ironstone from the eastern border of the Beartooth Mountains, Montana. An antiphase domain structure
suggests that the interstratified structures are intermediate transformation products formed by reaction from berthierine
(serpentine structure) to chlorite. Periodically interstratified structures consisting of chlorite (C) and serpentine-like
(S) (or berthierine) layers include (CS), (CCS), (CCCS), (CCCCS), and (CCCCCCS). The layer sequences in interstratified chlorite-berthierine
are indicative of the reaction mechanisms that produce the interstratified structures (e.g., crystallization from solution
or solid-state transformation). The reaction from berthierine to chlorite is crystallographically much like a cell-preserved
phase transformation, even though it is highly reconstructive. Berthierine can be considered a polymorph of the Fe-rich chlorite
mineral chamosite, with berthierine as the los-temperature phase. Interstratification and integrowths in the chlorite-berthierine
series may be common phenomena in low-temperature layer silicates resembling chlorite. Although such relations are difficult
to recognize from chemical analyses or powder X-ray diffraction patterns, they can be observed readily with TEM method.
Received: 25 April 1995/Accepted 5 April 1996 相似文献
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粘土沉积物XRD定量分析方法 总被引:1,自引:0,他引:1
从理论上推导了无序混合层粘土矿物混层比f与XRD视面网间距d之间的近似函数关系,制定出I/S混层矿物的d-f换算表;通过对济阳拗陷泥质岩石的研究,从一种新的途径求出了粘土矿物的强度因子,提出混层矿物XRD强度因子与混层比的线性关系式。根据不同的制样方法,利用微机运算,可以对粘土沉积物中的6种或10种矿物进行大量快速的定量分析。 相似文献