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1.
本文利用直接法和富利叶合成测定了产于我国四川省三叠系蒸发岩里的多钙钾石膏的晶体结构,结构参数经最小二乘法修正后,R=0.084。结构分析表明,多钙钾石膏属单斜晶系,空间群C2/c,a=17.462(8),b=6.828(2),c=18.219(9),β=113.45(4)°,V=1992(1)~3,Z=4,Dm=2.91,Dx=2.90(3)。三个硫酸根四面体各自的平均S—O键长为1.467、1.464和1.478。有三套Ca原子,其中Ca_1在二次对称轴上。Ca原子的配位数为9,各自的平均Ca—O键长为2.516、2.515和2.459。K原子的配位数为8。首次测定了矿物中氢原子的位置,证实矿物含1个结晶水,而不是含1.5个结晶水。晶体化学式为K_2Ca_5(SO_4)_6·H_2O。 相似文献
2.
撮科蛇绿混杂岩出露于元江县撮科大寨及周边地区,受到后期构造作用影响发生一定的变质和变形。蛇岩性较为复杂,岩块与基质之间为断层接触。基质以硅质岩、熔结凝灰岩和花岗质砾岩为主,岩块的类型主要有辉石岩、辉长岩、辉绿岩、闪长岩、玄武岩、斜长花岗岩等。其中,撮科蛇绿混杂岩中熔结凝灰岩的SHRIMP锆石U-Pb龄为(1 170±7) Ma(MSWD=0.54,n=12),花岗质砾岩基质具有单一的年龄,为(1 151±5) Ma(MSWD=1.3,n=17);辉长岩岩块的SHRIMP锆石U-Pb年龄为(1 168±8) Ma(MSWD=0.72,n=17),斜长花岗岩岩块的SHRIMP锆石U-Pb年龄为(1 163±9) Ma(MSWD=1.83,n=15),花岗斑岩岩块的SHRIMP锆石U-Pb年龄为(1 186±6) Ma(MSWD=0.92,n=17)。这些年龄指示该蛇绿混杂岩形成于中元古代晚期。撮科蛇绿混杂岩中辉长岩REE标准化曲线整体表现较为平坦的右倾趋势,具有与E-MORB相似的稀土元素特征。在MORB标准化图解中Nb、Ta没有出现明显的负异常,极低的Zr/Nb(8.65)、La/Nb(1.05)、Ba/Nb(10.72)、Th/Nb(0.10)、Th/La(0.09)、Ba/La(10.56)、Zr/Hf(43.4)平均值,且微量元素判别投点主要落入板内玄武岩范围,指示撮科蛇绿混杂岩应属于MORB型蛇绿岩,可能形成于板块伸展的构造环境。熔结凝灰岩锆石的εHf(t)值为-8.7 ~-4.7,平均值为-6.6,所有εHf(t)均为负,Hf同位素模式年龄(tDMC)为2 534~2 296 Ma,平均为2 408 Ma,指示熔结凝灰岩来自古元古代结晶基底的重熔。撮科蛇绿混杂岩的厘定,对重新认识原大红山群老厂河组的属性,研究扬子陆块西南缘中—新元古代岩浆和构造事件,划分扬子陆块基底大地构造单元具有重要意义。 相似文献
3.
粤北下庄矿田晚白垩世辉绿玢岩的地球化学特征及其构造意义 总被引：4，自引：0，他引：4
晚白垩世太平奄组辉绿玢岩位于粤北贵东复式岩体东部,呈NNE向展布。 它具有相对富硅(SiO2=5391% ~ 5603%)、富K(K2O=178 %~ 302%)、富集大离子亲石元素,Nb、Ta、Zr、Ti亏损明显,LREE富集(LREE/HREE=935 ~ 1024),基本无Eu异常(δEu=084 ~ 100), 低的εNd(91Ma)值(-58 ~ -98)、较高的［n(87Sr)/n(86Sr)］i值(070899 ~ 071525)和典型的Dupal异常铅等特征,这些明显的岛弧火山岩的地球化学特征与其所处的板内环境具有明显的不协调性。这种不协调性反映,在太平奄组辉绿玢岩形成之前的漫长时期内,由于古太平洋板块及其沉积物俯冲过程中产生的流体对上覆地幔楔的交代作用而形成具有岛弧火山岩特征的富集地幔源区。太平奄组辉绿玢岩正是在晚白垩世时期地壳伸展和岩石圈减薄的构造环境下,由这种具有EMⅠ和EMⅡ混合特征的富集地幔源区部分熔融形成的。 相似文献
4.
黑龙江四山林场金矿床是近年来在滨东地区发现的一座典型的硫化物石英脉型金矿。对其与成矿关系密切的闪长玢岩中锆石进行了详细研究的结果显示,该锆石的U--Pb 年龄可分为6 组: 1 057 ± 9 Ma、199 ± 2 Ma、144 ～ 148 Ma、115 ± 2. 7 Ma、111. 6 ± 1. 7 Ma ( n = 6,MSWD = 0. 55,probability = 0. 77) 和107. 3 ± 2. 8 Ma ( n = 3,MSWD = 0. 088,probability = 0. 92) 。结合区域岩浆热事件的发育状况,初步判定闪长玢岩的岩浆就位于115 ～ 107 Ma,岩浆演化过程受到中元古代及早侏罗世花岗质岩石的强烈混染; 成矿作用发生在早白垩世晚期向晚白垩世的转化阶段,其成岩成矿背景与太平洋板块俯冲作用下中酸性花岗岩岩浆作用密切相关。 相似文献
5.
通过1:250 000衢州区域地质调查,在武夷地块浙西南地区发现古元古代镁铁质-超镁铁质岩石。该套岩石在金华、龙游-带呈面状分布,金华张村出露最为完整,主要由辉石角闪石岩、角闪石岩、斜长阳起石岩、斜长辉石岩和斜长角闪岩等组成。对辉石角闪石岩与阳起石岩开展了LA-ICP-MS锆石U-Pb测年分析,分别获得其成岩年龄为1 834±14 Ma(MSWD=0.23,N=16)、1 839±17 Ma(MSWD=0.22,N=11),暗示这套镁铁质-超镁铁质岩石为古元古代岩浆活动的产物。这一发现表明,约1 830 Ma武夷地块处于板内伸展构造环境,同时该时期武夷地块已经具备足够的刚性,以致产生大规模的脆性破裂以及可能由地幔对流作用引发的基性岩浆活动,推测在约1.83 Ga武夷地块已经具有克拉通的性质。 相似文献
6.
华北太行岩墙群斜锆石生长世代和U-Pb年龄及其对岩浆演化的启示 总被引：4，自引：4，他引：0
斜锆石U-Pb定年是基性岩墙时代确定的有效方法。前人对太行岩墙群高分异组岩墙(Ti O2通常1%,Mg O一般6%)进行了较多的定年,但缺少对低分异组岩墙(Ti O2约为1%,Mg O6%)的高精度测年。两者年龄是否一致是讨论两组岩墙是否来源于同一岩浆的基本前提。本研究对华北太行岩墙群丰镇地区低、高分异组代表性岩墙进行了斜锆石离子探针207Pb/206Pb定年。结果表明,低分异组车道沟岩墙207Pb/206Pb平均年龄为1768±4Ma(n=9,MSWD=2.1);而高分异组酸刺湾岩墙斜锆石207Pb/206Pb年龄可以分为两组,加权平均值分别为1780±3Ma(n=8,MSWD=0.65)和1760±3Ma(n=5,MSWD=1.7)。斜锆石成分分析表明,酸刺湾岩墙两组年龄对应的矿物成分存在差异,如晚期斜锆石比早期更富Ti,Zr/Hf比值变化范围相对较小。据此认为,酸刺湾岩墙两组斜锆石可能结晶于岩浆不同阶段:早期(~1780Ma)的斜锆石可能结晶于成分更加原始的岩浆,很可能形成于岩浆房中;晚期(~1760Ma)的斜锆石可能结晶于成分更加演化的岩浆,可能是岩浆通道(岩墙)或岩浆房中。Zr/Hf值与单点年龄的负相关趋势可能记录了单斜辉石的结晶过程。已有的太行岩墙群U-Pb年代学结果集中于1785~1760Ma。我们的研究认为,太行岩墙群岩浆房存在了约20Myr,即岩浆房形成于~1785Ma,岩墙就位于1785~1760Ma。 相似文献
7.
邯邢侵入体中幔源超镁铁质岩包体的发现及其矿物地球化学特征 总被引：3，自引：3，他引：3
邯邢中基性侵入杂岩体中产有众多的岩石包体。作者在暗色闪长岩相中首次发现了超镁铁质岩包体,以方辉榄橄岩为主,由镁榄橄石(Fo=92±),顽火辉石(En=90±),铬透辉石和铬尖晶石组成,碎斑-平结构,发育扭折带。全岩SiO_2=41.02,MgO=42.24,∑EREE(3.95)甚低,稀土元素配分曲线显示特殊的向下凸的形状。δ~(18)O=6.5～7.0。辉石平衡温度约为1000℃,压力为20×10~8～22×10~8Pa。矿物-地球化学研究表明具上地幔岩特征,属A型包体,这在国内外文献中还未曾见过类似的报导。这个发现对探讨华北板块的地壳上地幔组成与演化,中生代构造岩浆活动的大地构造背景以及物质来源和邯邢式铁矿的成因将产生深远的影响。 相似文献
8.
九三沟金矿床是吉林省延边地区一座典型的浅成中高温热液金矿床.为了深入研究其成矿规律,首次对延边地区九三沟金矿床赋矿围岩蚀变闪长玢岩进行了锆石LA- ICP-MS年代学精细研究.实验获得单颗粒锆石U-Pb谐和年龄在103～ 116 Ma之间,其加权平均年龄为109.3±2.1 Ma(MSWD=7.0,n=18),代表闪长玢岩成岩年龄.谐和年龄可被细分为两段:112～116 Ma(平均值=113.1±1.1 Ma,n=9,MSWD=0.55,置信度为0.82)和103～110 Ma(平均值=105.8±1.8 Ma,n=9,MSWD=2.2,置信度为0.022).结合年龄数据、锆石晶形和CL图像特征,初步厘定前者应代表闪长玢岩主体结晶年龄,而后者则代表岩浆演化结束的时代.再结合区域成矿规律和之前取得的成果,限定九三沟金矿成矿作用应发生在106 Ma之后,成矿环境适值早白垩世晚期伊泽奈崎板块向古亚洲大陆边缘俯冲消亡、中国东部大陆边缘燕山造山期末的走滑、伸展构造转换过程. 相似文献
9.
峨眉地幔柱轴部的榴辉岩-地幔岩源区:主元素、痕量元素及Sr、Nd、Pb同位素证据 总被引：16，自引：2，他引：14
峨眉山大陆溢流玄武岩(ECFB)的西南部以丽江、大理和攀枝花三角区为中心的苦橄岩分布区,面积约5×10 4 km2 ,为峨眉地幔柱的轴部区。Sr、Nd、Pb同位素和痕量元素研究表明,大部分火山岩样品落在洋岛火山岩成分范围内,并存在类似FOZO、HIMU和EM - 的三个端元。这说明它们是在地幔柱轴部,由地幔岩和榴辉岩(古玄武质洋壳)组成的源区产生的岩浆形成的。岩浆源区再循环玄武质洋壳的存在可能是该区超大型钒钛磁铁矿床形成的根本原因。少部分分布在洋岛火山岩成分范围之外的样品,一部分属于地幔柱岩浆与地壳混染产物,另一部分低Ti岩石可能与岩石圈反应有关。地幔端元的地球化学特征如下:FOZO端元以白林山苦橄玄武岩(YB-0 1)为代表,低87Sr/86 Sr(0 .70 36 ) ,高1 43Nd/1 44 Nd(0 .5 12 7) ,中等2 0 6 Pb/2 0 7Pb(18.5 6 93) ;Nb/U =36 .6 7,Th/Nb =0 .0 82 ,L a/Nb=0 .91,Zr/Nb=6 .2 3。HIMU端元以丽江苦橄岩(JL - 2 9)为代表,高2 0 6 Pb/2 0 4 Pb(2 0 .6 4 12 )和2 0 7Pb/2 0 4 Pb(15 .74 89) ,低87Sr/86 Sr(0 .70 4 8)。EM - 端元包括两部分:1以二滩苦橄岩-玄武岩(R- 1、3、5、8)为代表,高87Sr/86 Sr(0 .70 73) ,低1 43Nd/1 44 Nd(0 .5 12 3) ,低2 0 6 Pb/2 0 4 Pb(17.996 8)和2 0 8Pb/2 0 4 Pb(37.94 5 0 ) 相似文献
10.
尚志中新世富碱的钾质系列玄武岩为白榴霞石岩、橄榄霞石岩、霞石碧玄岩和橄榄碧玄岩。岩石中似长石矿物大量出现,霞石和白榴石可以共存。稀土元素和大离子不相容元素的特征表明形成白榴霞石岩、橄榄霞石岩、霞石岩碧玄岩和橄榄碧玄岩的地幔熔融程度越来越高。主元素和微量元素的模拟计算表明,霞石岩岩浆为上地幔岩2～4％的熔融,碧玄岩为上地幔橄榄岩5～8％的部分熔融;这些岩浆形成时的温压条件为:霞石岩的T=1410～1430℃,P=22～23×10~8Pa;碧玄岩的T=1380～1430℃,P=20～23.5×10~8Pa。 相似文献
11.
Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
12.
Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
13.
The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引：4，自引：0，他引：4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
14.
Emmanuel Skourtsos Daniel Vachard Alexandra Zambetakis-Lekkas Rossana Martini Louisette Zaninetti 《Comptes Rendus Geoscience》2002,334(12):925-931
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931. 相似文献
15.
正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.) 相似文献
16.
正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.) 相似文献
17.
正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.) 相似文献
18.
正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus., 相似文献
19.
正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an 相似文献
20.
正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of 相似文献