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1.
The experiment was conducted to ascertain net production and consumption rates of 15NH4 + and 15NO3 ? for water and sediment in a wetland. This was done using 15N isotope pool dilution methodology under ambient and elevated atmospheric CO2 concentrations in experimental riparian wetlands to obtain the gross N transformation rates. The 15N budget for sediment was also estimated. The results suggested that the differences in high proportion of 15N concentration in the overlying water body under elevated CO2 could be attributed to the low production and high consumption rates of 15NH4 + in sediment. The elevated CO2 effect on production and consumption of NH4 + decreased by 144 % (P = 0.014) and increased by 153 % (P = 0.009), respectively. Thereby, 15NH4 + production rates are negatively related with 15NO3 ? consumption rates and this accounted for the decreases in net 15NO3 ? consumption under CO2 enrichment in the wetland sediment by 11 % (P = 0.528). Therefore, 15NO3 ? production and consumption rates may strongly depend on NH4 + production. Inorganic 15N and total 15N exported from sediment to overlying water body by the effect of CO2 were 41 % (P = 0.071) and 18 % (P = 0.000), respectively. Therefore, low net 15NH4 + production and high 15NH4 + consumption rates under elevated CO2 may partly explain the significant reduction of N from the sediment.  相似文献   

2.
The aim of this study was to evaluate the relative performance of three nitrification inhibitors (NIs) viz. calcium carbide (CaC2), and plant derivatives of Pongamia glabra Vent. (karanj) and Melia azedarach (dharek) in regulating N transformations, inhibiting nitrification and improving N recovery in soil–plant systems. In the first experiment under laboratory incubation, soil was amended with N fertilizer diammonium phosphate [(NH4)2HPO4] at a rate of 200 mg N kg?1, N + CaC2, N + karanjin, and N + M. azedarach and incubated at 22 °C for 56 days period. Changes in total mineral N (TMN), NH4 +–N and NO3 ?–N were examined during the study. A second experiment was conducted in a glasshouse using pots to evaluate the response of wheat to these amendments. Results indicated that more than 92 % of the NH4 + initially present had disappeared from the mineral N pool by the end of incubation. Application of NIs i.e., CaC2, karanjin, and M. azedarach resulted in a significant reduction in the extent of NH4 + disappearance by 49, 32, and 13 %, respectively. Accumulation of NO3 ?–N was much higher in N amended soil 57 % compared to 11 % in N + CaC2, 13 % in N + karanjin, and 18 % in N + M. azedarach. Application of NIs significantly increased growth, yield, and N uptake of wheat. The apparent N recovery in N-treated plants was 20 % that was significantly increased to 38, 34, and 37 % with N + CaC2, N + karanjin, and N + M. azedarach, respectively. Among the three NIs tested, CaC2 and karanjin proved highly effective in inhibiting nitrification and retaining NH4 +–N in the mineral pool for a longer period.  相似文献   

3.
In the present study, we explored the use of various optical parameters to detect differences in the composition of the dissolved organic matter (DOM) in a set of lakes that are all located on the Canadian Precambrian Shield, but within which Cu and Ni speciation predictions were previously shown to diverge from measured values in some lakes but not in others. Water samples were collected with in situ diffusion samplers in 2007 (N = 18 lakes) and 2008 (N = 8 lakes). Significant differences in DOM quality were identified between the sampling regions (Rouyn-Noranda, Québec and Sudbury, Ontario) and among lakes, based on dissolved organic carbon concentrations ([DOC]), specific UV absorbance (SUVA254), fluorescence indices (FI), and excitation–emission matrix (EEM) fluorescence measurements. Parallel factor analysis (PARAFAC) of the EEM spectra revealed four components, two of which (C3, oxidized quinone fluorophore of allochthonous origin, and C4, tryptophan-like protein fluorescence of autochthonous origin) showed the greatest inter-regional variation. The inter-lake differences in DOM quality were consistent with the regional watershed characteristics as determined from satellite imagery (e.g., watershed-to-lake surface area ratios and relative percentages of surface water, rock outcrops vegetative cover and urban development). Source apportionment plots, built upon PARAFAC components ratios calculated for our lakes, were used to discriminate among DOM sources and to compare them to sources identified in the literature. These results have implications for other areas of research, such as quantifying lake-to-lake variations in the influence of organic matter on the speciation of trace elements in natural aquatic environments.  相似文献   

4.
Meiliang Bay and Gonghu Bay, in the north of Taihu Lake, are important water sources for the city of Wuxi, and increased eutrophication now threatens the safety of drinking water. The distribution of nitrogen (N) speciation and source of N in the surface waters in the north of Taihu Lake is studied, which was an important first step in controlling N pollution. The result shows that the average concentration of ammonia (NH4 +) and nitrate (NO3 ?) of surface water in Meiliang Bay was 0.32 and 0.35 mg/L, while 0.21 and 0.74 mg/L of Gonghu Bay, in which both bays had serious nitrate pollution. The concentrations of NH4 + and NO3 ? in the surface water of the two bays had a trend of gradual decrease from north to south. The maximum concentrations of NH4 + and NO3 ? of two bays were observed near the inflowing rivers, and the maximum concentrations of NH4 + in surface water of two bays were 0.49 and 0.61, and 0.77 and 1.38 mg/L of NO3 ?. The concentration of NH4 + in the interstitial water of the two bays had a trend of gradual decrease from west to east, but NO3 ? had the opposite tendency. The maximum concentrations of NH4 + in the interstitial water of the two bays were 5.88 and 4.64, and 3.58 and 7.18 mg/L of NO3 ?. The exchangeable NH4 + content in the sediment of Meiliang Bay had a trend of gradual decrease from north to south, but Gonghu Bay showed the reverse. The exchangeable NO3 ? content in the sediment of Meiliang Bay had a trend of gradual decrease from east to west, but a decreasing trend from north to south was observed in Gonghu Bay. The maximum concentrations of exchangeable NH4 + were determined, and the values were 96.25 and 74.90 mg/kg, as well as NO3 ? with the values of 12.06 and 7.08 mg/kg. Chemical fertilizer and domestic sewage were the major sources of nitrate in surface water of Gonghu Bay, contributing 39.16 and 47.79%, respectively. Domestic sewage was the major source of nitrate in Meiliang Bay, contributing 84.79%. The denitrification process in Gonghu Bay was more apparent than in Meiliang Bay. Mixing and dilution processes had important effects on changing the concentration of nitrate transportation in the two bays.  相似文献   

5.
Atmospheric dust is considered to be the major cause of poor air quality due to its contribution to high particulate levels, but their interaction with the acidic gases helps in controlling the level of SO2 and NO2 through ambient neutralization reactions. In the present study, the interaction of acidic gases such as SO2 and NO2 with alkaline dust was investigated during October, 2013–July, 2014 at a site named as Babarpur located at the Trans-Yamuna region of Delhi. The concentration of SO2 ranged from 10 to 170 μg/m3 with an average of 36 μg/m3 while that of NO2 ranged from 15 to 54 μg/m3 with an average of 26?±?8 μg/m3. The results were observed to be well within the National Ambient Air Quality Standard (NAAQS) limits prescribed by the Central Pollution Control Board (CPCB). The average concentrations of SO2 during day and night time were recorded as 31?±?18 and 43?±?53 μg/m3 respectively while the mean concentrations of NO2 during day and night time were recorded as 26?±?7 and 27?±?12 μg/m3 respectively. A positive correlation between SO42? and NO3? was also observed indicating their secondary aerosol formation. In aerosol phase, average concentrations of SO42? during day and night time were 3.9?±?0.3 and 6.5?±?2.3 μg/m3 respectively while that of NO3? were 9.5?±?1.5 and 7.3?±?0.5 μg/m3 respectively. Molar ratios of Ca2+/SO42?, NH4+/SO42?, and NH4+/NO3? were observed as 8, 5, and 1.7 during daytime and 1.5, 0.4, and 0.8 during nighttime respectively. Such molar ratios confirmed high concentrations of sulphate (SO4)2? and low concentrations of nitrate (NO3?) during night time, thereby indicating different pathway of aerosol formation during day and night time. Surface morphology and elemental composition of aerosol samples showed various oval, globular, and platy shapes where the diameter varied from few nm to ~5 μm depending on their precursors. There were certain shapes like grossularite, irregular aggregate, grape-like, triangular, and flattened which indicate the crustal origin of aerosols and their possible role in SO2 and NO2 adsorption.  相似文献   

6.
Rainwater plays an important role in scavenging of aerosols and gases from atmosphere, and its chemistry helps to understand the relative contributions of atmospheric pollution sources. The present work is aimed to understand and explain the sources, seasonal patterns and the processes thereof affecting rainwater chemistry in an urban environment of Delhi, India. Rainwater samples (n = 111) collected throughout the year in New Delhi showed alkalinity in general. Eight rainwater samples, collected in late monsoon and winter season, had pH less than 5.6 indicating that Delhi continues to face the prospects of acid rain despite the introduction of compressed natural gas as the clean fuel in city transport. Organic acids could be the possible contributors of acidity in rainwater samples having the fractional acidity (FA) value of 0.174, which is greater than the annual average FA (0.011) and the (Ca2+ + Mg2+ + NH4 +)/(SO4 2? + NO3 ?) ration of more than one. Average acid neutralization factors of cations decrease in the order Ca2+ (1.01) > NH4 + (0.77) > Mg2+ (0.10). However, neutralization by Ca2+ dominates only in summer season as cation-rich dust is transported from the Great Indian Thar Desert to this region by strong summer S–SW winds, while NH4 + dominates in rainwater of other three sampling seasons. Identified dominant sources for soluble ions in rainwater are (1) non-silicate crustal source for carbonates and sulfates of Ca and Mg, (2) emissions from catalytic convertor-fitted vehicles and agriculture fields for NH3 and (3) mixed anthropogenic sources for SO4 2?, NO3 ? and Cl?. Rainwater chemistry showed significant seasonal variations. This could be due to the changes in relative proportions of natural and anthropogenic sources of soluble ions to rainwater. Dominance of anthropogenic sources over crustal sources can result in acidic rains, which can adversely affect the environment and human health in this region.  相似文献   

7.
This study was carried out to determine the flux of nutrients and heavy metals from the Melai sub-catchment into Lake Chini through the process of erosion. Melai River is one of the seven feeder rivers that contributed to the present water level of Lake Chini. Three properties of soils, such as particle size, organic matter content, and soil hydraulic conductivity and three chemical soil properties, such as available nutrients, dissolved nutrients, and heavy metals, were analyzed and interpreted. Potential soil loss was estimated using the revised universal soil loss equation model. The results show that the soil textures in the study area consist of clay, silty clay, clay loam, and sandy silt loam. The organic matter content ranges from 3.40 to 9.92 %, while the hydraulic conductivity ranges from 5.2 to 25.3 cm/h. Mean values of available P, K, and Mg amount was 8.5 ± 3.7 μg/g, 24.5 ± 3.4 μg/g, and 20.7 ± 18.6 μg/g, respectively. The highest concentration of soluble nutrients was SO 4 ?2 (815.8 ± 624.1 μg/g), followed by NO3 ?-N (295.5 ± 372.7 μg/g), NH4 +-N (24.5 ± 22.1 μg/g) and PO4 3? (2.0 ± 0.8 μg/g). The rainfall erosivity value was 1658.7 MJ mm/ha/h/year. The soil erodibility and slope factor ranges from 0.06 to 0.26 ton h/MJ/mm and 7.63 to 18.33, respectively. The rate of soil loss from the Melai sub-catchment in the present condition is very low (0.0028 ton/ha/year) to low (18.93 ton/ha/year), and low level flow of nutrients and heavy metals, indicating that the Melai River was not the contaminant source of sediments, nutrients, and heavy metals to the lake.  相似文献   

8.
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9.
Human activities contribute different pollutants to receiving waters, often with significant variations in time and space. Therefore, integrating multiple parameters of water quality and their spatiotemporal variations is necessary to identify the pollution characteristics. Based on the water quality monitoring data with 12 parameters for 2 years at 22 sampling sites in the Cao-E River system, eastern China, the projection pursuit method was used to project all parameters and their temporal variations into a one-dimensional vector through two projections. Accordingly, we could easily assess the comprehensive water quality in different sampling sites and then classify their water pollution features. Factor analysis was then used to identify the pollution characteristics and potential sources. Results showed that all sampling sites for the river system could be classified into four groups: headwater sites (HS), agricultural nonpoint sources pollution sites (ANPS), point sources pollution sites (PSPS), and mixed sources pollution sites. Water quality in HS was good, containing only a few nutrients from the woodland runoff and soil erosion. For ANPS, the main pollutants were dissolved phosphorus, total P, and nitrate nitrogen (NO3 ?-N), mainly from farming land. For PSPS, ammonium nitrogen (NH4 +-N) and organic pollutants originated from industrial and municipal sewage. In HS and ANPS, NO3 ?-N was the main form of nitrogen, and a high ratio of NO3 ?-N/NH4 +-N was a remarkable characteristic, whereas NH4 +-N was the main form of nitrogen in PSPS. Except in HS, water quality in the other groups could not meet the local water quality control standard. Finally, suggestions were proposed for water pollution control for the different groups.  相似文献   

10.
This paper aims to reveal the reciprocal influence of Kürtün Dam and wastewaters from the settlements on the water quality in the stream Har?it, NE Turkey. Several key water-quality indicators were measured: water temperature (T), pH, dissolved oxygen (DO), electrical conductivity, water hardness, chemical oxygen demand (COD), ammonium nitrogen (NH4 +–N), nitrite nitrogen (NO2 ?–N), nitrate nitrogen (NO3 ?–N), total Kjeldahl nitrogen (TKN), total nitrogen (TN), orthophosphate phosphorus (PO4 3?–P), and methylene blue active substances (MBAS). The monitoring and sampling studies were conducted every 15 days from March 2009 to February 2010 at two stations selected in the upstream and downstream of the Kürtün Dam. It was concluded that the Kürtün Dam Lake had a high-quality water in terms of T, pH, DO, COD, NH4 +–N, NO2 ?–N and NO3 ?–N values, but slightly polluted water with respect to TKN, PO4 3?–P, and MBAS according to the Turkish Water Pollution Control Regulation. The dam improved the stream water quality by increasing the DO concentration, and decreasing the NO2 ?–N and PO4 3?–P concentrations thanks to its hydraulic residence time despite the wastewater discharge by the nearby settlements. However, the wastewater discharge deteriorated the stream water quality increasing the COD, NH4 +–N, NO3 ––N, and TN concentrations.  相似文献   

11.
Nowadays, natural resources are under increasing stress which fosters wastewater reuse planning and emphasizes on the decentralized wastewater treatment. Vermifiltration has been described as a viable alternative to treat domestic and urban wastewater, but few studies have focused on the impact of different filter packings on vermifiltration performance. This study evaluates the effect of vermicompost and sawdust in a single-stage vermifilter (VF) for urban wastewater treatment. After an acclimation period of 45 days, urban wastewater from a combined sewage collection system was applied continuously for 24 h. Earthworm stock density was of 20 g L?1, HRT of 6 h, HLR of 0.89 m3 m?2 day?1 and OLR of 7.38 g BOD5 day?1. System performance was assessed by the removal efficiencies of BOD5, COD, TSS, NH4 +, TN and TP, and fecal coliforms and helminth eggs elimination. Vermicompost (VE) and sawdust (SE) were tested, using an earthworm abundance of 20 g L?1. Treatment efficiencies were 91.3% for BOD5, 87.6% for COD, 98.4% for TSS and 76.5% for NH4 + in VE, and 90.5% for BOD5, 79.7% for COD, 98.4% for TSS and 63.4% for NH4 + in SE. Earthworms contributed to reduce NH4 + and TN removal and to increase NO3 ? concentration. No treatment was able to eliminate fecal coliforms down to guidelines values for wastewater irrigation as helminth eggs were completely eliminated. Single-stage vermifiltration system using both filter packings is inconsistent and cannot meet EU guideline values for discharge in sensitive water bodies and WHO guidelines for irrigation with treated wastewater.  相似文献   

12.
Assessment of groundwater quality in and around Vedaraniyam,South India   总被引：1，自引：1，他引：0  
Groundwater from 47 wells were analyzed on the basis of hydrochemical parameters like pH, electric conductivity, total dissolved solids, Ca2+, Mg2+, Na+, K+, Cl?, CO3 2?, HCO3 ?, NO3 ?, PO4 3? and F? in the Cauvery delta of Vedaraniyam coast. Further, water quality index (WQI), sodium percentage (Na %), sodium absorption ratio, residual sodium carbonate, permeability index and Kelley’s ratio were evaluated to understand the suitability of water for drinking and irrigation purposes. The result shows significant difference in the quality of water along the coastal stretch. The order of dominance of major ions is as follows: Na+ ≥ Mg2+ ≥ Ca2+ ≥ K+ and Cl? ≥ HCO3 ? ≥ CO3 2? ≥ PO4 3? ≥ F?. Na/Cl, Cl/HCO3 ratio and Revelle index confirmed that 60–70 % of the samples were affected by saline water intrusion. WQI showed that 36 % of the samples were good for drinking and the remaining were poor and unsuitable for drinking purpose. The degradation of groundwater quality was found to be mainly due to over-exploitation, brackish aquaculture practice, fertilizer input from agriculture and also due to domestic sewage.  相似文献   

13.
Sediment-water exchanges of ammonium (NH4 +), nitrate + nitrite (NOx ?), filterable reactive phosphorus (FRP, primarily ortho-phosphate), and oxygen (O2) under aphotic (heterotrophic) conditions were determined at 2–5 stations in the Neuse River Estuary, from 1987 to 1989. Shallow (1 m), sandy stations were sampled along the salinity gradient. Fluxes from deep (>2 m) sites were compared to the shallow sites in two salinity zones. Grain size became finer and organic content increased with depth in the oligohaline zone but not in the mesohaline zone. Net release of NH4 + and FRP occurred at all sites. Fluxes varied from slight uptake to releases of 200–500 μmol m?2 h?1 (NH4 +) and 150–900 μmol m?2 h?1 (FRP). Net NOx ? exchange was near zero, but were ±100 μmol m?2 h?1 over the year. Release of NH4 + and FRP from the shallow sandy stations decreased with distance down the estuary, but O2 uptake did not change. The deeper oligohaline site had twofold higher rates of NH4 + and FRP release and O2 uptake than the shallow site, but no differences occurred between depths in the mesohaline zone. Temperature and organic content were important controls for all fluxes, but water column NOx ? concentration was also important in regulating NOx ? exchanges. Ratios of oxygen consumption to NH4 + release were near the predicted ratio (Redfield model) at oligohaline sites but increased down estuary at mesohaline sites. This may be due to greater nitrification rates promoted by autotrophy in the sediments.  相似文献   

14.
Dissolved organic carbon (DOC) concentration and dissolved organic matter (DOM) optical properties were analyzed along two estuarine river transects during the wet and dry seasons to better understand DOM dynamics and quantify mangrove inputs. A tidal study was performed to assess the impacts of tidal pumping on DOM transport. DOM in the estuaries showed non-conservative mixing indicative of mangrove-derived inputs. Similarly, fluorescence data suggest that some terrestrial humic-like components showed non-conservative behavior. An Everglades freshwater-derived fluorescent component, which is associated with soil inputs from the Northern Everglades, behaved conservatively. During the dry season, a protein-like component behaved conservatively until the mid-salinity range when non-conservative behavior due to degradation and/or loss was observed. The tidal study data suggests mangrove porewater inputs to the rivers following low tide. The differences in quantity of DOM exported by the Shark and Harney Rivers imply that geomorphology and tidal hydrology may be a dominant factor controlling the amount of DOM exported from the mangrove ecotone, where up to 21 % of the DOC is mangrove-derived. Additionally, nutrient concentrations and other temporal factors may control DOM export from the mangroves, particularly for the microbially derived fluorescent components, contributing to the seasonal differences. The wet and dry season fluxes of mangrove DOM from the Shark River is estimated as 0.27?×?109 mg C d?1 and 0.075?×?109 mg C d?1, respectively, and the Harney River is estimated as 1.9?×?109 mg C d?1 and 0.20?×?109 mg C d?1.  相似文献   

15.
Tidal marshes act as a buffer system for nutrients in the pore water and play important roles in controlling the budget of nutrients and pollutants that reach the sea. Spatial and seasonal dynamics of pore water nutrients were surveyed in three tidal marshes (Chongming Island, Hengsha Island, and Fengxian tidal flat) near the Yangtze Estuary and Hangzhou Bay from August 2007 to May 2008. Nutrient variations in pore water closely followed seawater quality in the estuaries, while the average concentration of NH4 +–N, the main form of inorganic nitrogen in pore water, was over two orders of magnitude higher than that in seawater which was dominated by nitrate. NH4 +–N export (13.81 μmol m?2 h?1) was lower than the import of (NO3 ?+NO2 ?)–N (?24.17 μmol m?2 h?1) into sediment over the 1-year period, hence reducing N-eutrophication in coastal waters. The export of SiO3 2?–Si and PO4 3?–P from tidal marshes regulated nutrient level and composition and lifted the ratio beyond potentidal element limitation in the coastal system. Moreover, macrophyte plants (Spartina alterniflora and Phragmites australis) played significant roles in controlling nutrient concentration in pore water and its exchange between marshes and estuaries. Fengxian marsh was characterized by higher nutrient concentrations and fluxes than other marshes in response to the more serious eutrophication in Hangzhou Bay than in the Yangtze Estuary.  相似文献   

16.
A combined ABR–MBR process consisting of an anaerobic baffled reactor (ABR) combined with an aerobic membrane bioreactor (MBR) treating municipal wastewater was investigated at controlled pH range 6.5–8.5 and at constant temperature 25 ± 1 °C. Total nitrogen (TN), ammonia (NH4 +–N), total phosphorus (TP), and chemical oxygen demand (COD) removal performances were evaluated by analyzing the mechanism for efficient nutrient removal. The results showed that the average removal rates of COD, NH4 +–N, TN, and TP reached 93, 99, 79, and 92 %, respectively, corresponding with the COD, NH4 +–N, TN, and TP effluent of 24 (18–31), 0.4 (0–0.8), 10.6 (8.8–12.9), and 0.31 (0.1–0.5) mg/L under the operational condition of hydraulic retention time (HRT) 7.5 h, recycle ratio 200 %, and dissolved oxygen 3 mg/L. The MBR enhanced NH4 +–N, TN, and TP removal rates of 13, 10, and 18 %, respectively, and the membrane retention reduced TP 0.17 mg/L. The process was able to maintain a stable performance with high-quality effluent. Analysis of the results by fluorescence in situ hybridization showed that the abundance of ammonia-oxidizing bacteria, nitrite-oxidizing bacteria, and phosphorus accumulating organisms as percentages of all bacteria in each compartment was stable. The enriched microorganisms in the system appear to be the main drivers of the process efficient for nutrient removal.  相似文献   

17.
Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at a long-term observation well. Estimated rates of DOC loss were rapid and ranged from 0.093 to 0.21 micromoles per liter per day (μM d?1), and rate constants for DOC removal ranged from 0.0021 to 0.011 per day (d?1). Applying these removal rate constants to an advective-dispersion model illustrates substantial depletion of DOC over flow-path distances of 200 m or less and in timeframes of 2 years or less. These results explain the low to moderate DOC concentrations (20–75 μM; 0.26–1 mg L?1) and ultraviolet absorption coefficient values (a 254?<?5 m?1) observed in groundwater produced from 59 wells tapping eight different aquifer systems of the United States. The nearly uniform optical clarity of groundwater, therefore, results from similarly rapid DOM-removal kinetics exhibited by geologically and hydrologically dissimilar aquifers.  相似文献   

18.
This study investigated the effect of cations and anions on the sorption and desorption of iron (Fe) and manganese (Mn) in six surface calcareous soil samples from Western Iran. Six 10 mM electrolyte background solutions were used in the study, i.e., KCl, KNO3, KH2PO4, Ca(NO3)2, NaNO3, and NH4NO3. NH4NO3 and NaNO3 increased the soil retention of Fe and Mn, whereas Ca(NO3)2 decreased the soil retention of Fe and Mn. Iron and Mn sorption was decreased by NO3 ? compared with H2PO4 ? or Cl?. The Freundlich equation adequately described Fe and Mn adsorption, with all background electrolytes. The Freundlich distribution coefficient (K F) decreased in the order H2PO4 ? > Cl? > NO3 ? for Mn and H2PO4 ? > NO3 ? > Cl? for Fe. The highest sorption reversibility was for Fe and Mn in competition with a Ca2+ background, indicating the high mobility of these two cations. A MINTEQ speciation solubility model showed that Fe and Mn speciation was considerably affected by the electrolyte background used. Saturation indices indicated that all ion background solutions were saturated with respect to siderite and vivianite at low and high Fe concentrations. All ion background solutions were saturated with respect to MnCO3(am), MnHPO4, and rhodochrosite at low and high Mn concentrations. The hysteresis indices (HI) obtained for the different ion backgrounds were regressed on soil properties indicating that silt, clay, sand, and electrical conductivity (EC) were the most important soil properties influencing Fe adsorption, while cation exchange capacity (CEC), organic matter (OM), and Mn-DTPA affected Mn adsorption in these soils.  相似文献   

19.
Hydrogeochemical controlling factors for high rate of groundwater contamination in stressed aquifer of fractured, consolidated rocks belonging to semi-arid watershed are examined. The groundwater in mid-eastern part of Prakasam district confining to Musi-Gundlakamma sub-basins is heavily contaminated with nitrate and fluoride. Distinct water chemistry is noticed among each group of samples segregated based on concentration of these contaminants. The nitrate is as high as 594 mg/l and 57 % of the samples have it in toxic level as per BIS drinking water standards, so also the fluoride which has reached a maximum of 8.96 mq/l and 43 % of samples are not fit for human consumption. Nitrate contamination is high in shallow aquifers and granitic terrains, whereas fluoride is in excess concentration in deeper zones and meta-sediments among the tested wells, and 25 % of samples suffer from both NO3 ? and F? contamination. Na+ among cations and HCO3 ? among anions are the dominant species followed by Mg2+ and Cl?. The NO3 ?-rich groundwater is of Ca2+–Mg2+–HCO3 ?, Ca2+–Mg2+–Cl? and Na+–HCO3 ? type. The F?-rich groundwater is dominantly of Na+–HCO3 ? type and few are of Na+–SO4 2? type, whereas the safe waters (without any contaminants) are of Ca2+–Mg2+–HCO3 ?– and Na+–HCO3 ? types. High molecular percentage of Na+, Cl?, SO4 2? and K? in NO3 ? rich groundwater indicates simultaneous contribution of many elements through domestic sewerage and agriculture activity. It is further confirmed by analogous ratios of commonly associated ions viz NO3 ?:Cl?:SO4 2? and NO3 ?:K+:Cl? which are 22:56:22 and 42:10:48, respectively. The F? rich groundwater is unique by having higher content of Na+ (183 %) and HCO3 ? (28 %) than safe waters. The K+:F?:Ca2+ ratio of 10:5:85 and K+:F?: SO4 2? of 16:7:77 support lithological origin of F? facilitated by precipitation of CaCO3 which removes Ca2+ from solution. The high concentrations of Na+, CO3 ? and HCO3 ? in these waters act as catalyst allowing more fluorite to dissolve into the groundwater. The indices, ratios and scatter plots indicate that the NO3 ? rich groundwater has evolved through silicate weathering-anthropogenic activity-evapotranspiration processes, whereas F? rich groundwater attained its unique chemistry from mineral dissolution-water–rock interaction-ion exchange. Both the waters are subjected to external infusion of certain elements such as Na+, Cl?, NO3 ? which are further aggravated by evaporation processes leading to heavy accumulation of contaminants by raising the water density. Presence of NO3 ? rich samples within F? rich groundwater Group and vice versa authenticates the proposed evolution processes.  相似文献   

20.
A “snap shot” survey of the Mississippi estuary was made during a period of low river discharge, when the estuarine mixing zone was within the deltaic channels. Concentrations of H+, Ca2+, inorganic phosphorus and inorganic carbon suggest that the waters of the river and the low salinity (<5‰) portion of the estuary are near saturation with respect to calcite and sedimentary calcium phosphate. An input of oxidized nitrogen species and N2O was observed in the estuary between 0 and 4‰ salinity. The concentrations of dissolved NH4 + and O2, over most of the estuary, appeared to be influenced by decomposition of terrestrial organic matter in bottom sediments. The estuarine bottom also appears to be a source of CH4 which has been suggested to originate from petroleum shipping and refining operations. Estuarine mixing with offshore Gulf waters was the dominant influence on distributions of dissolved species over most of the estuary (i.e., from salinities >5‰). The phytoplankton abundance (measured as chlorophylla) increased as the depth of the mixed layer decreased in a manner consistent with that expected for a light-limited ecosystem. Fluxes of NO3 ?+NO2 ? and soluble inorganic phosphorus to the Gulf of Mexico were estimated to be 3.4±0.2×103 g N s?1 and 1.9±0.2 g P s?1 respectively, at the time of this study.  相似文献   

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