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1.
Relatively few data are available on geochemical and biogeochemical prospecting in arid deserts. Heterogeneities of results from wadi-sediment sampling indicate the necessity of relatively dense sample networks. An examination of the five relatively abundant plant types close to mineralization in southeastern Sinai, suggested the use of Fagonia mollis and Palicaria undulata for a more detailed study. Although the copper content in plant ash correlates well with that in the wadi sediment, this was not found for the other measured elements, nor was there significant enrichment of trace metals in ash vs trace metals in sediment. Biogeochemical methods were thus found to be of limited use.  相似文献   

2.
泛滥平原沉积物标准物质研制   总被引：6，自引：6，他引：0  
泛滥平原沉积物能代表流域内元素的平均分布规律并具有普遍的适用性,是地球化学填图工作的重要介质。目前国际上尚无泛滥平原沉积物标准物质,国外相似标准物质的研制注重于环境方面,定值成分较少;我国同类的土壤和水系沉积物标准物质受限于不同工作需要,研制目的各不相同,且多数标准物质不足。为满足需求,本文研制了长江流域、赣江流域、汉水流域、淮河流域、黄河流域、海河流域、黑龙江流域共7个泛滥平原沉积物国家一级标准物质(编号为GBW07385～GBW07391)。此系列标准物质采用X射线荧光光谱压片法测试了26种成分,主量成分的RSD小于1%,微量元素的RSD约为2%,所有成分的RSD均小于7%,方差检验的F值均小于临界值F0. 05(24,25)=1. 96,表明样品的均匀性良好。在23个月的考察期内,检验的24种成分未发现统计学意义的明显变化,证明样品的稳定性良好。由全国13家实验室采用不同原理的、可靠的多种分析方法共同完成了73种元素和化合物共511个特性成分的定值测试,除GBW07386和GBW07388的CO2未能赋值外,其余494个特性成分给出了认定值与不确定度,15个特性成分给出了参考值,是我国同类标准物质定值最为齐全的一个系列。该系列标准物质代表了各自流域元素的背景含量,适用于多目标地球化学调查、土地质量地球化学调查等样品的分析质量监控,亦可用作环境、农业等领域相关样品测试的量值和质量监控标准。  相似文献   

3.
在1:50000广顺幅区调过程中,首次发现广顺地区下二叠统粱山组有大量丰富的遗迹化石存在。本文特作以报道,并为该区早二叠世古环境分析提供了新的地质资料。一、广顺地区梁山组简介梁山组为早二叠世栖霞早期的沉积地层。它与下伏地层上石炭统马平组(主要由亮晶生物屑灰岩、团粒灰岩组成)呈不整合接触;与上覆下二叠统栖霞组(由泥—细晶生物屑灰岩夹钙质页岩、泥灰岩、燧石灰岩组成)呈整合接触。梁山组主要由石英砂岩、页岩和粘土岩组成,也见有生物屑硅质岩。有较多的腕足类和  相似文献   

4.
Cruziana及其相关的遗迹化石是由底栖三叶虫在沉积物表面停歇、爬行所留下的遗迹,一般认为产于潮下带至浅海陆棚环境,具有古水深指示意义。然而,本文通过对昆明民富二村下奥陶统红石崖组顶部含Cruziana rugosa遗迹化石群落层位的沉积环境分析却发现,Cruziana rugosa遗迹化石群落的沉积环境为潮上带—潮间带,说明三叶虫可以在短暂暴露环境中活动。三叶虫的这种适应性活动可能为节肢动物从海洋走向陆地做好了进化准备。  相似文献   

5.
This paper is intended to be a constructive discussion of Fiket et al. (2017, Geostandards and Geoanalytical Research , 41 , 123–135), who dealt with the determination of major, trace and rare earth elements in several sediment and soil certified reference materials. In the present author's view, the paper by Fiket et al. (2017) suffers from a lack of reference to several publications in which somewhat similar results had already been reported. The present contribution therefore provides a comparison of previously published results with those of Fiket et al. for the CRMs soil NCS DC 77302 (GBW 07410), stream sediment NCS DC 73309 (GBW 07311), marine sediments MESS‐3 and NCS DC 75301 (GBW 07314) and estuarine sediment IAEA‐405. It is argued that this fuller consideration (a) allows critical evaluation of the quality of the results presented by Fiket et al. and (b) highlights the advantages of their work. Finally, attention is drawn to the (possible or real) problems that can arise during simultaneous determination of multiple trace elements.  相似文献   

6.
Dongping Lake area, located in the lower reaches of Yellow River, is an ideal place to study the changes of modern river and lake sedimentary environment. The sediment samples of Dawen River, Yellow River, and Dongping Lake were collected, and the major elements, trace elements and organic matter geochemical composition of the samples were analyzed. Cluster analysis, characteristic element ratio method and graphic method were used to explore the geochemical characteristics of sediments and their environmental implication. The results show that the contents of SiO_2, Na_2O, TiO_2 and Zr in sediments of Dawen River and Yellow River are relatively high, and the contents of iron and manganese oxides, organic matter, CaO, P_2O_5 and Sr in lake sediments are relatively high. That reveals the differences of sedimentary environments between the rivers and the lake. The contents of Sr and Zr in Dawen River are affected by the rapid migration of clastic materials in the upstream carbonate source area during the flood season; the δCe,ΣREE and REE's ratios in the sediments of the Yellow River reflect the influence of the Loess source; and the distribution of elements changes along the flow direction during the flood season. The characteristics of p H, element composition and LREE HREE fractionation of the lake sediments indicate that the sediment source is complex, and the lake environment is affected by the flood season. The study shows that the geochemical content and its variation characteristics of sediments effectively reveal the sedimentary environment, material composition and characteristics of flood season of rivers and the lake in the study area.  相似文献   

7.
 Long sediment cores (>1 m) were collected from eight Precambrian Shield lakes in southern Ontario, Canada and analyzed for mercury (Hg), loss-on-ignition (LOI), and a suite of 36 other elements. Results indicated at least 100-fold variation in sediment Hg concentrations between lakes in close proximity (from 450 ppb), comparable to the variation reported for lakes across the whole of Canada. Strong areal correlations between Hg concentrations and LOI (r 2 =0.77), between Hg and other trace element concentrations (Pb, Zn, Cd, Sb, As, Br), and similarities in the vertical concentration profiles of Hg and LOI, all point to the importance of organic matter in the release, transport and redistribution of metals in watershed systems. The spatial pattern of Hg concentrations in deep, precolonial sediments (>20 cm) was found to mirror the pattern of Hg concentrations in modern surface sediments, an observation that was confirmed in a follow-up survey (r 2 =0.85;n=25 lakes), indicating that natural processes govern the unequal distribution of Hg among these lakes. Between-lake differences in surface sediment Hg concentrations normalized to organic carbon (Hg/C) were also reflected by Hg concentrations in smallmouth bass normalized to 35 cm length (R 2 =0.63;n=15 lakes). The latter relationship suggests that smallmouth bass and lake sediment indicators provide mutually supportive information regarding Hg loading to the lacustrine environment from geological sources in the watershed system. Received: 31 October 1996 · Accepted: 27 May 1997  相似文献   

8.

Background  

Seasonal changes in pore water and sediment redox geochemistry have been observed in many near-surface sediments. Such changes have the potential to strongly influence trace metal distribution and thus create seasonal fluctuations in metal mobility and bioavailability.  相似文献   

9.
The carbonate concretions occurring at the bottom of Talchir fissile shale facies preserved signatures of various trace fossils along with a cast of doubtful organisms and cyanobacterial mat structures. The host shale deposited under glacial melt water fed lacustrine condition. The concretions, formed in poorly oxygenated conditions, are either of syndepositional origin and/or deposited a little below the sediment water interface and were later exhumed to the depositional surface due to erosion of soft mud overlying them. The trace fossils are both megascopic and microscopic in nature. The megascopic trace fossils are identified on the basis of their morphology as Monocraterion and Rhizocorallium. Some of the megascopic structures described remain problematic at present. The microscopic trace fossils are formed due to the activity of marine meiofauna (possibly by nematodes), which, although produced morphologically show similar traces of known larger ichnogeneras but much smaller than them. The discovery of these trace fossils apparently indicate the influx of saline water into a lacustrine domain during the Talchir sedimentation at Giridih basin. Moreover, presence of the above two megascopic trace fossils in the marine lacustrine carbonate concretions may lead researchers to consider their much wider environmental significance than hitherto believed.  相似文献   

10.
Vegetated mid-channel islands play an important though poorly understood role in the sediment dynamics and morphology of tide-dominated deltas. Meinmahla Island is a mangrove-forest preserve at the mouth of the Bogale distributary channel, in the Ayeyarwady Delta, Myanmar. In this relatively unaltered mid-channel island, sediment dynamics can be directly connected to morphology. Field measurements from 2017 to 2019 provide insight into the pathways for sediment transport and resulting morphological evolution. Water depth, salinity and turbidity were monitored semi-continuously, and velocity profilers with turbidity and salinity sensors were deployed seasonally in single-entrance (dead-end/blind) and multi-entrance tidal channels of the island. The morphological evolution was evaluated using grain size, 210Pb geochronology, remote sensing and channel surveys. The data show that ebb-dominant, single-entrance channels along the island exterior import sediment year-round to the land surface. However, these exterior channels do not deliver enough sediment to maintain the observed ca 0.8 cm/yr accretion rate, and most of the sediment import occurs via interior, multi-entrance channels. Interior channels retain water masses that are physically distinct from the water in the Bogale distributary, and estuarine processes at the tidal-channel mouths import sediment into the island. Sediment is sourced to the island from upriver in the wet season and from the Gulf of Mottoma in the dry season, as the location of the estuary shifts seasonally within the Bogale distributary. The salinity and biogeochemistry of the distributary water are affected by interactions with sediment and groundwater in the island interior. The largest interior channels have remained remarkably stable while the island has aggraded and prograded over decadal timescales. However, the studied multi-entrance channel is responding to a drainage-network change by narrowing and shoaling. Overall, mid-channel islands trap sediment and associated nutrients at the river–ocean interface, and these resilient landscape features evolve in response to changes in drainage-network connectivity.  相似文献   

11.
The Upper Emsian to Frasnian Ia-Ib strata of the Marhouma area (or “km 30” outcrop), exposed in the Ougarta Range (SW Algeria) belong to the Chefar El Ahmar Formation. On the basis of distinct lithological and palaeontological features, this formation is subdivided into three members (Lower Marly Limestones Member, Middle Marly Limestones Member, and Upper Marly Limestones Member). The studied beds show low to moderate diversity of trace fossil assemblage which contains thirteen ichnotaxa: Chondrites intricatus, Chondrites isp., Chondrites cf. targionii, Circulichnis cf. montanus, Cochlichnus isp., Neonereites biserialis, Neonereites multiserialis, Nereites isp., Palaeophycus isp., Planolites isp., Thalassinoides isp., Zoophycos aff. cauda-galli, and Zoophycos isp. A. The two latter ichnotaxa are the most common trace fossils in the assemblage and occur at three different levels showing different bioturbation intensities. The first Zoophycos-bearing level (Zl 1) is characterised by an overall high bioturbation intensity reflecting a very high oxygenation rate and nutrient supply, allowing the development of large and dense Zoophycos specimens. The second Zoophycos-bearing level (Zl 2) has a considerable reduction of bioturbation intensity as compared to the previous level, with an abundance of Chondrites, which is probably due to radical palaeoecological changes that suggests dysoxic and stressful conditions. The third Zoophycos-bearing level (Zl 3) is characterised by an overall moderate bioturbation intensity. The distribution of trace fossils was influenced by lithology, sedimentation rate, energy level (storm events), bottom oxygenation, and nutrient supply. The lithofacies and trace fossils of the Chefar El Ahmar Formation both indicate a depositional environment fluctuating from the lower shoreface to lower offshore zone.  相似文献   

12.
Spatial distributions of trace elements in the coastal sea sediments and water of Maslinica Bay (Southern Adriatic), Croatia and possible changes in marine flora and foraminifera communities due to pollution were investigated. Macro, micro and trace elements’ distributions in five granulometric fractions were determined for each sediment sample. Bulk sediment samples were also subjected to leaching tests. Elemental concentrations in sediments, sediment extracts and seawater were measured by source excited energy dispersive X-ray fluorescence (EDXRF). Concentrations of the elements Cr, Cu, Zn, and Pb in bulk sediment samples taken in the Maslinica Bay were from 2.1 to over six times enriched when compared with the background level determined for coarse grained carbonate sediments. A low degree of trace elements leaching determined for bulk sediments pointed to strong bonding of trace elements to sediment mineral phases. The analyses of marine flora pointed to higher eutrophication, which disturbs the balance between communities and natural habitats.  相似文献   

13.
A temporary section in the Cuisian Bagshot Beds, which has been mapped in detail, displayed estuarine sediments with interlayered sands and muds, fine sands, channel-fill sands and intraformational (mainly mud clast) conglomerates. The facies show rapid lateral and vertical changes in grain size and bed form and a restricted suite of trace fossils including Ophiomorpha nodosa and Arenicolites sp. The sequence is shown to have been deposited in a subtidal channel where tidal, wave and fluvial processes were dominant at different times. The following points are considered to be characteristic of sedimentation in this environment: (i) correlation is difficult and facies predictability is low; (ii) there are frequent lateral facies changes from the channel to the subtidal bank environment; (iii) pene-contemporaneous erosion removes considerable amounts of sediment; (iv) load structures may be exposed, eroded, buried and reactivated; and (v) muddy layers and bioturbated horizons offer similar resistance to penecontemporaneous erosion.  相似文献   

14.
《Sedimentary Geology》2006,183(3-4):217-242
Geochemical and textural variations in frontal dune sediments along the western coast of Jutland, Denmark, have been investigated in order to identify possible sediment ‘provinces’ and transport pathways. An understanding of sediment sources and sinks is important for both for an understanding of the nature of sedimentary environments and for applied coastal engineering and management purposes. Four coastal sectors were identified on the basis of geochemical composition. One sector is compositionally different from the other three units, having higher concentrations of the trace elements Ni, Cr, V, Sc, Zn, Pb, Ba, Zr and many rare earth elements. Dune sediments on this section of coast also have higher Al2O3 to K2O ratios and lower Al2O3 to Fe2O3 ratios, reflecting a lower content of feldspar and higher content of heavy minerals. It is inferred that different, or additional, sediment source(s) have supplied sediment to this section of coast. Beach nourishment has contributed to the observed compositional differences, but previous data obtained from the Lodbjerg area indicate that aeolian sands on this section of coast naturally have a relatively high Si, Fe and Ti content, reflecting high quartz / feldspar ratio and relatively high content of heavy minerals, compared with those on other sections of the coast. Frontal dunes along the most northern section show high abundances of K2O, Rb and Ba, reflecting a relatively high K-feldspar content derived from local sources. Alongshore trends were also identified in the mean particle size and sorting of the frontal dunes, although there is no direct correspondence with the observed geochemical differences. Three coastal units can be identified on the basis of particle size. Frontal dune sediments in the middle section are relatively coarser and less well-sorted than those to the north and south, probably reflecting both the addition of beach nourishment material and greater exposure to strong westerly winds, which are a capable of transporting a wide range of particle sizes. The three units defined on this basis do not correlate directly with the units defined on the basis of geochemical composition.  相似文献   

15.
The chronology of near-surface sediments in Lake Illawarra has been investigated using radiocarbon dating and anthropogenically derived substances including trace metals, ash, and137Cs. Sediments at depths about 1 m below the water-sediment interface ranged in age from Modern to 786 calendar years bp on the basis of radiocarbon dating ofNotospisula trigonella valves. Multiple marker (for example ash-trace metals) depth-concentration sediment profiles yielded estimates of sedimentation rate ranging from 3 to 5 mm yr–1 at Griffins Bay to more than 16 mm yr–1 at Macquarie Rivulet. Sedimentation rates of approximately 10 mm yr–1 appeared to be typical of the western and southwestern portions of the lagoon. Rates of sediment accretion, prior to catchment clearing, urbanization, and industrialization have been estimated at less than 1 mm yr–1, thus indicating a general tenfold increase in sediment accumulation adjacent to the western foreshore caused by catchment development. Accelerated sedimentation in shallow coastal lagoons constitutes significant environmental impacts including shoaling, degradation of seagrass beds, and increased turbidity with consequent loss of aesthetic appeal. Management policy should be directed at attempts to reduce the amount of sediment input by the construction of strategically placed sediment retention ponds. Siltation within the shallow embayments of Lake Illawarra could be ameliorated by a carefully planned program of dredging.  相似文献   

16.
In the tidal creeks of the southeastern United States, the numerically and ecologically dominant macrobenthic organisms are typically oligochaetes. Due to their relatively small size and difficult taxonomy, little is known about the short-term and seasonal changes in the oligochaetes of tidal creeks. This study presents a report of the spatial and temporal changes of the oligochaete taxa within and between two tidal creeks in southern South Carolina, at monthly intervals over a 13-month period. These changes are framed within the reference of monthly changes in benthic chlorophylla, sediment composition, and porewater ammonia, as well as in the perspective of seasonal changes in the entire tidal creek macrobenthic community. The most abundant oligochaete found in this study was the tubificidMonopylephorus rubroniveus, followed by the naidParanais litoralis and the tubificidsTubificoides heterochaetus andT. brownae. All of the oligochaetes exhibited strong month-to-month and spatial changes, indicative of changes in water quality and sediment habitat characteristics (e.g., low dissolved oxygen, high benthic chlorophylla). There were significant correlations between the abundance of most species and either benthic chlorophylla concentration or the silt-clay fraction of the sediment. Looking at short-term changes in this rapidly changing component of the macrobenthic community provides insight not only into the ecology of the oligochaetes, but also into the changes in the tidal creek ecosystem and their potential effects on other biota.  相似文献   

17.
This study combines U–Pb age and Lu–Hf isotope data for magmatic and detrital zircons, with whole-rock geochemistry of the Browns Range Metamorphics (BRM), Western Australia. The BRM are medium- to coarse-grained metasandstones that consist of angular to sub-rounded detrital quartz and feldspars with minor granitic lithic fragments. The sequence has undergone partial to extensive quartz–muscovite alteration and rare-earth-element mineralisation and has been intruded by mafic/ultramafic, syenitic and pegmatitic intrusive rock units. Uranium–Pb and Lu–Hf isotopic data on detrital zircons from the metasandstones and intruding granitic rocks yield a well-defined age of ca 3.2 to ca 3.0 Ga for all samples, with relatively radiogenic ?Hf values (?Hf = –1.7 to 5.1) indicating derivation from Mesoarchean granite basement of juvenile origin. This is consistent with geochemical and petrological data that support deposition from a granitic source in a continental rift basin setting. The timing of sediment deposition is constrained between the ca 3.0 Ga age of the source rocks and ca 2.5 Ga age of the granitic intrusive bodies that cross-cut the metasedimentary rocks. The ca 2.5 Ga zircons from the intrusive rocks have ?Hf model ages of ca 3.4 to ca 3.1 Ga, which is consistent with formation via partial melting of the BRM, or the Mesoarchean granite basement. Zircons of the Gardiner Sandstone that unconformably overlies the BRM return detrital ages of ca 2.6 to ca 1.8 Ga with no trace of ca 3.1 Ga zircons, which discounts a significant contribution from the underlying BRM. The Mesoarchean age and isotopic signatures of the BRM zircons are shared by some zircon records from the Pine Creek Orogen, and the Pilbara, Yilgarn and Gawler cratons. Collectively, these records indicate that juvenile Mesoarchean crust is a more significant component of Australian cratons than is currently recognised. This work also further demonstrates that detrital minerals in Paleoproterozoic/Archean sedimentary rocks are archives to study the early crustal record of Earth.  相似文献   

18.
The bed and suspended (slime) sediment phases associated with effluent water that are produced from phosphate-ore-upgrading process at Al-Abyad mine in the southern part of Jordan were analyzed chemically and mineralogically. The results show that the effluent water is highly oxic and mildly alkaline in nature. The geochemical behavior of each phase was controlled by the effluent water physicochemical parameters, sediment particle size, mineralogical constituents of the studied phases, and the prevailing climatic nature of the area. Bed sediments have higher concentrations of many elements than slime. Accordingly, the bed sediments can be considered as a sink rather than a pool for many elements. The geochemical dissociation of major oxides and trace elements between bed and slime sediments was evident using t test, particularly between P2O5, SiO2, CaO, K2O, Mn, Sr, Y, and Co, and to lesser extent, V, U, Zn, and Cr. This might be attributed to effluent water characteristics, mineralogy, and the presence of fine-grained materials. The spatial distribution of major oxide and trace element concentrations along the stream drainage exhibited a slight increase with distance either in bed or slime sediment phases. However, they increased suddenly at the last three sampling sites, which might be due to the abundance of fine-grained materials that are mainly composed of clay minerals (montmorillonite) that would enhance the adsorption process. Moreover, the XRD results confirmed the existence of elemental geochemical dissociation as a function of mineral control.  相似文献   

19.
The mineralogy and bulk chemical compositions of 15 Kintampo (Late Stone Age) potsherds from the Birimi site on the Gambaga Escarpment and eight samples of local sediment were determined with the intent of characterizing these wares and identifying the material used in their manufacture. Sediment from clay pits still used by potters north of the escarpment contains iron‐rich laterite clasts (100 × XFeOt = 100 × FeOt/[FeOt + Al2O3 + SiO2] ≥10). Sedimentary clasts in stream sediments are relatively siliceous and iron‐poor (100 × XFeOt < 10). Bulk geochemical data together with the compositions of lithic clasts (laterite, siltstone/sandstone) link the pottery to sediment sources, including escarpment sediments not presently used by Ghanaian potters. Fresh granite clasts found in some of the sherds were not found in the analyzed sediment samples, although some of their distinctive mineralogical constituents (e.g., variably barian alkali feldspar) are present. The analytical data suggest that pots found at Birimi were made locally by mixing escarpment sediment with clay and stream sediment brought in from below the escarpment. This contrasts with present‐day practice, whereby the pots themselves are imported. The place where Birimi pottery was made and the outcrop source of aluminous sediment (mudstone with an “escarpment” trace element signature) used in these wares, however, remain unidentified. © 2013 Wiley Periodicals, Inc.  相似文献   

20.
The triterpenol geochemistry of the Santa Monica Basin from the Southern California Borderland, off the U.S.A., is described from the study of two sets of trap deployments, five box cores (≈30 cm) and a hydroplastic core (≈1 m). The biogenic sources and diagenetic stability of the triterpenols are discussed.The 17β(H), 21β(H)-hopanols (22R isomer) occur in the carbon number range from 30 to 32 and their abundance is nearly uniform in the shallow sediment sections. However, the three hopanols follow the order of abundance, C32 > C31 C30, in deeper sections. Their concentrations spans from trace levels to 156 μg/g organic carbon (<15 ng to 7 μg/g dry sediment). Tetrahymanol (gammaceran-3β-ol) has been identified in all the samples except in one set of trap particles collected at 100 m water depth, from trace level (<1 μg) to 215 μg/g organic carbon (<20 ng to 9 μg/g dry sediment). Diplopterol is also detected in trace amounts in some samples. The triterpenols in the trap material generally increase with the water column depth and decrease with the subbottom depth in the sediment cores.The extended hopanols are either degradation products of polyhydroxybacteriohopanes or are biosynthesized by bacteria. Tetrahymanol is probably the only suggested biological precursor of gammacerane (the reduced counterpart of tetrahymanol), which has been recognized in numerous crude oils and lithified sediments. Although it has been reported earlier from Green River Shale and from a residual Pleistocene lake sediment, tetrahymanol has so far been positively identified from recent marine sediments only in two recent studies. The decreasing content of tetrahymanol in sedimentary depth profiles in the Santa Monica Basin would favor an origin for this compound in the water column or at the sediment surface. The ubiquitous occurrence of this compound throughout the study area suggests that this triterpenol most probably originates from primitive organisms (protozoa, bacteria?), hitherto not identified or, more likely, not yet analyzed for their lipid composition.  相似文献   

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