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1.
在镜下对长春黄土状土的微观结构进行研究，发现第三层粉质粘土含水机制在于土中具有纵横交织的空洞和管道，地下水赋存于其中；第二层棕红色粉质粘土和粘土的崩解性在于该层土具有网状裂隙，卸荷后遇水崩解，在此基础上提出基坑降水的设计方案。 相似文献
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Claudio Territo Philippe Vieillard Dominique Righi Sabine Petit Riccardo Scalenghe 《Journal of Geochemical Exploration》2006,88(1-3):345
The aim of this study is to characterize the pedogenic clay minerals by using simple approach: mixing mineralogical and geochemical findings.The fine clay fractions (< 0.1 μm) of a Vertic Cambisol profile were studied by means of X-ray diffraction (XRD), infrared spectroscopy (FTIR) and cation exchange capacity (CEC).Qualitative and quantitative mineralogical compositions of the clay mixture were determined.Moreover, chemical equilibria and thermodynamic stabilities of minerals (calcite, gypsum, kaolinite, smectites and illites) were studied using results of ionic activities obtained from total concentration of various aqueous species in water extracts from soil-saturated pastes.XRD analysis shows a good homogeneity in the mineralogical composition of the soil material, with depth of soil profiles. The identified clay minerals are mainly illite–smectite mixed layers (I/S) and kaolinite. The chemical analysis of saturated paste extracts with clay minerals shows a slight undersaturation of the illitic phase while smectites and also calcite and gypsum reach the thermodynamic equilibrium along the soil profile. 相似文献
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In barrier design, familiarity of the structure and composition of the soil material at the micron scale is necessary for delineating the retention mechanisms of introduced metals, such as the formation of new mineral phases. In this study, the mineralogical and chemical makeup of the bentonite from a geosynthetic clay liner (GCL) was extensively characterized using a combination of conventional benchtop X-ray diffraction (XRD) and micro X-ray diffraction (μXRD) with synchrotron-generated micro X-ray fluorescence (μXRF) elemental mapping and μXRD (S-μXRD). These methods allow for the non-destructive, in situ investigation of a sample, with μm spatial resolution. Synchrotron-based hard X-ray microprobes are specifically advantageous to the study of trace metals due to higher spatial resolution (<10 μm) and higher analytical sensitivity (femtogram detection) than is possible using normal laboratory-based instruments. Minerals comprising less than 5% of the total bentonite sample such as gypsum, goethite and pyrite were identified that were not accessible by other conventional methods for the same GCL bentonite. Two dimensional General Area Diffraction Detector System (GADDS) images proved to be particularly advantageous in differentiating between the microcrystalline clay, which appeared as homogeneous Debye rings, and the ‘spotty’ or ‘grainy’ appearance of primary, more-coarsely-crystalline, accessory minerals. For S-μXRD, the tunability of the synchrotron X-rays allowed for efficient distinction of both clay minerals at low scattering angles and in identifying varying Fe oxide minerals at higher angles. GCL samples permeated with metal-bearing mining solutions were also examined in order to consider how mechanisms of metal attenuation may be identified using the same techniques. In addition to the cation exchange capacity from the montmorillonite clay, tests showed how minerals comprising only 1–2% of the bentonite such as goethite could potentially play a significant role in sequestering a range of metals, specifically Ni, Zn and Cu. 相似文献
4.
上海地区土体抗剪强度与静力触探比贯入阻力相关关系研究 总被引：2，自引：0，他引：2
基于上海地区19个工程共201组数据,通过黏土、粉质黏土和粉砂在上海地区土层中的分布,比贯入阻力Ps,室内固结快剪试验黏聚力cu和摩擦角?u,孔隙比e,塑性指数Ip沿土层深度的变化,分析得到3种土类的抗剪强度与比贯入阻力的相关关系,并总结了国内软土地区土体抗剪强度与静力触探比贯入阻力之间的相关关系。本文得到黏土的相关关系与以往的经验公式相近,同时给出了原位土层粉质黏土和粉砂的相关关系。区别不同土类使得相关关系可用性提高,在工程应用中更加合理。根据本文相关关系,通过静力触探比贯入阻力可以得到不同土层的抗剪强度值,进而应用于基坑稳定计算。本文研究的结果可以应用于海相沉积土的勘察和工程设计工作。 相似文献
5.
A 5.3m profile originally described as loess with a buried interglacial soil is reinterpreted from petrographic evidence and thermoluminescence dating as a Holocene colluvial accretionary soil. Mineralogical analyses of coarse silt (16–63 μm) fractions suggest that most of the silty colluvium was derived from weathered Thanet Beds upslope, though some loess was incorporated during the final depositional phase. Thin sections show that clay illuviation occurred penecontem-poraneously with deposition of colluvium. Thermoluminescence properties suggest partial optical bleaching of the grains during rapid deposition, which is consistent with a Holocene colluvial origin. 相似文献
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吸附离子对粉质粘土及改良土特性的影响 总被引：1，自引：0，他引：1
利用疏浚土有机质含量高、吸附能力强和低渗透性等特点,探讨将其作为填埋场黏土衬垫改性材料的可能性。针对粘土垫层所关心渗透性及强度两个基本问题,比较了粉质黏土、改良土（粉质黏土添加疏浚土）吸附离子前后的变化。吸附K+、Cu2+后粉质黏土、改良土的渗透系数随着土中离子含量的增加而增大,但对改良土渗透系数的影响要小于粉质黏土;吸附离子后,粉质黏土摩擦角增幅不大,黏聚力有较大增长,而改良土的黏聚力增长较少,摩擦角增长较快。总体而言,添加一定量的疏浚土能改善吸附离子对黏土垫层的影响。采用SEM电镜试验拍摄了离子吸附前后土体微观结构的变化,并从扩散双电层理论出发,解释了吸附离子对粉质黏土及改良土的影响。 相似文献
9.
Senapathi Venkatramanan Thirunavukkarasu Ramkumar Irudhayanathan Anithamary 《Arabian Journal of Geosciences》2013,6(5):1371-1380
The aim of this study is to understand the various sources and factors controlling the abundance and distribution of clay minerals, sand, silt, clay and organic matter of the surface sediments of Tirumalairajanar Estuary in two different seasons. The study was undertaken for two seasons, based on ten selected stations all along the estuary, mouth and freshwater zone. Furthermore, along the estuary region, clay and silt were observed and also at few stations in the upstream end. Organic matters in the sediments appeared to be the main mechanisms for the distribution of clay minerals in estuary indicated that the distributions of clay minerals were comparatively higher during postmonsoon than in premonsoon season. The clay mineral assemblage consists mainly of chlorite, kaolinite, montmorillonite, illite and very scarce gibbsite. The clay from the sediments has been separated and studied for mineral identification using X-ray diffraction analysis. The present study also reveals that sediment texture is one of the main controlling factors for the distribution of organic matter. 相似文献
10.
长江河口及其水下三角洲晚第四纪地层和环境变迁 总被引：5，自引：3，他引：5
笔者系统地研究了长江河口地区的晚第四纪地层。长江三角洲前缘区晚第四纪地层可划分为上更新统上段中部、全新统下部、全新统中部和全新统上部。上更新统顶部地层缺失。前三角洲区晚第四纪地层齐全，无缺失。武木冰期晚期，现今的长江河口和大陆架均出露成陆，古长江在大陆架外缘入海。１５０００ａＢ．Ｐ，海面上升，海水逐渐向大陆架上部侵入；１２０００—１００００ａＢ．Ｐ，海水沿谷地侵入；６０００ａＢ．Ｐ，长江人海口在扬州、镇江附近。随着人类活动的增强，长江流域水土流失加剧，人海河口不断外移，并以南岸边滩推展，北岸沙岛并岸的形式使河口不断束狭，逐渐形成现今长江口三级分汉四口入海的态势。 相似文献
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碎石土湿陷性试验研究 总被引：2，自引：0，他引：2
采用不同工况的载荷试验、室内常规土工试验和易溶盐试验,分析了碎石土的荷载-沉降曲线特征,探讨了碎石土的湿陷性与湿陷机理。结果表明：碎石土在200 kPa稳定后浸水,再加荷到400 kPa,载荷试验荷载-沉降曲线呈折线型,明显分为三个阶段：压缩变形阶段,湿陷变形阶段,复合变形阶段。场地中4 m厚碎石土具有湿陷性,且湿陷性不均匀。 碎石土湿陷的机理在于其结构是疏松的单粒架空结构。骨架颗粒间存在架空孔隙,且部分架空孔隙由砂质颗粒集合体充填;骨架颗粒间呈点与点接触,或者主要通过黏粒、黏土矿物、易溶盐组成的胶结物而联结在一起;在浸水加荷过程中,黏粒周围薄膜水增厚、粘土矿物自身产生膨胀、易溶盐溶解,导致胶结物的胶结强度丧失,结构失稳,发生湿陷。 相似文献
12.
Two complementary 3D techniques, neutron diffraction and synchrotron X-ray microtomography (SXR-μCT), were used to compare the Shape and Lattice Preferred Orientations of a mylonitised metagranite from the Monte Rosa unit (Western Alps, Italy). The goal of using these techniques was to obtain two different orientation distribution functions. Although the two functions describe relatively independent characteristics of the rock fabric, nonetheless they also exhibit close relationships to macroscopic fabrics and may be complementarily used to quantify rock fabrics and microstructures, thereby highlighting 3D features that cannot be obtained with either technique, if used independently. We describe an approach that can be potentially useful in various disciplines, e.g., structural geology, rock mechanics, tectonics and geophysics, when a complete data set of preferred orientations and size distribution is needed.Micas display a strong orthorhombic symmetry between mesoscopic lineation and microscopic SPO and LPO, whereas quartz and feldspars are characterised by a monoclinic symmetry between mesoscopic lineation and LPO. These observations suggest a rheological decoupling between the weak phase mica layers and the stronger quartz + feldspar layers. This mechanical decoupling occurred during the Alpine subduction-collision, when the Monte Rosa unit was part of the Insubric Line system and accommodated large vertical strain. 相似文献
13.
With optical microscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and synchrotron X-ray diffraction measurements, we analyzed clay microfabrics in ultracataclastic/gouge and cataclastic core samples obtained from the main bore hole of the San Andreas Fault observatory at depth (SAFOD). The analysis reveals a significant contrast between weak clay fabrics observed in the core samples with synchrotron X-ray fabric measurements and strong degree of preferred alignment for clay particles documented with the optical microscope. TEM and SEM observations also show distinct zones of locally aligned and randomly oriented clay minerals. The lack of a strong fabric may be attributed to randomly oriented matrix sheet silicates dominating the fault rocks. The presence of weak fabrics in intensely strained ultracataclasites/fault gouges is attributed to 1) newly formed clay minerals that grew in many orientations, 2) folded and kinked clay minerals, and 3) clay particles that are wrapped around grains. In addition, the locally aligned clay particles may act as barriers to fluid flow, which in turn decrease porosity, expel intergranular pore fluids, and consequently, may increase fluid pressure. 相似文献
14.
Batch and flow-through experiments were performed on quartz–feldspar granular aggregates at hydrothermal conditions (up to ≈150 °C, up to 5 MPa effective pressure, and near-neutral pH) for up to 141 days. The effect of dissolution–precipitation reactions on the surface morphology of the mineral grains was investigated. The starting materials as well as the solids and fluids resulting from the experiments were characterized using BET, energy dispersive X-ray spectroscopy, electron microprobe analysis, inductively coupled plasma-optical emission spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray powder diffraction, and X-ray fluorescence spectroscopy. The electrical conductivity of fluid samples was used as a proxy for the evolution of the fluid composition in the experiments. The chemical analyses of the fluids in combination with hydrogeochemical simulations with PHREEQC suggested the precipitation of Al–Si-bearing solid phases. Electron microscopy confirmed the formation of secondary amorphous Al–Si-bearing solid phases. The microscopic observations are consistent with a process of stoichiometric dissolution of the mineral grains, transport of dissolved ions in the fluid phase, and spatially coupled precipitation of sub-μm sized amorphous particles on mineral surfaces. These findings shed light onto early stages of diagenesis of quartz–feldspar sands and indicate that amorphous phases may be precursors for the formation of crystalline phases, for example, clay minerals. 相似文献
15.
Petrophysical experiments, using acoustic velocities to characterise anisotropies of mechanical behaviour of rocks are of essential relevance to understand the geomechanical behaviour of sandstone reservoirs under changing stress fields. Here, we present high-resolution X-ray microtomography (μ-CT) as a supplementary research tool to interpret anisotropic ultrasound velocities in sandstones with variation of isotopic stress.Specimens of two Lower Cretaceous sandstones (localities Bentheim and Obernkirchen, both Germany) have been used in petrophysical laboratory experiments under dry conditions to study ultrasonic sound velocities (frequency of signal input 1 MHz). Subsequently, oriented micro-plugs drilled from the sandstone samples were investigated using high-resolution X-ray microtomography. By means of image processing of the reconstructed scan images, geometric attributes such as mean structural thickness, orientation and tortuosity were evaluated from the μ-CT data for both pore space and grain skeleton. Our observations clearly indicate the different roles of pore space and grain skeleton in regard to the propagation of ultrasonic waves: because the pores do not transmit the waves, it was sufficient to investigate the average thickness of this fabric element. In contrast, as the ultrasonic waves traverse the rock via the adjacent grains, it was necessary to survey the actual travel lengths of seismic waves in the sandstone grain skeleton. 相似文献
16.
《Applied Geochemistry》2001,16(14):1611-1619
Biodegradation of polycyclic aromatic hydrocarbon (PAH) was investigated in the whole matrix and in the different aggregate size fractions of a sandy soil contaminated by a mixture of 8 PAHs and incubated at water holding capacity. The distribution of PAHs and of phenanthrene-degrading bacteria were determined in the bulk soil and in 4 size aggregate fractions corresponding to sand, coarse silt, fine silt and clay. The microbial communities able to degrade phenanthrene were detected at a similar level in the different aggregate fractions of the soil before contamination. After soil contamination and incubation, a significant growth of bacteria was observed and their distribution within aggregates was modified. Bacterial communities of phenanthrene-degraders were present in a higher density in the aggregates corresponding to sand (2000–50 μm) and clay (<2 μm). Chemical analysis show that remaining PAHs (low and high molecular weight) were much more concentrated in the fine soil fractions (fine silt and clay) and were present at a very low content in the larger aggregate size fractions. The interactions of well defined aggregates with PAHs and bacteria were also studied using phenanthrene as PAH model substrate and individual aggregates corresponding to sand and clay size fractions. Incubation of sand and clay aggregate fractions enriched with phenanthrene in the presence of a bacterial isolate NAH1 led to the simultaneous solubilization and biodegradation of phenanthrene. Differences in amounts of solubilized phenanthrene between sand and clay aggregate size fractions would be related to difference in adsorption capacities of phenanthrene by clay and sand aggregates. 相似文献
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We have examined microstructures, mineralogical composition, geochemical alteration, and texture of four selected fault rock samples from the Deep Geodynamical Laboratory (DGLab) Gulf of Corinth project using optical microscopy, cathodoluminescence microscopy (CL), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and synchrotron X-ray diffraction measurements. The fault core is composed of red and gray clayey gouge material and surrounded by a damage zone of brecciated limestones. Pressure solution features, calcite veins and calcite clasts in the breccia and gouge material attest the presence of paleo-fluids and fluid-driven mass transfer during deformation. Differences in CL-colors between the matrix and calcite vein cement and inside the vein cement suggest repeated infiltration of fluids with different composition from various sources (formation water and meteoric water). Twin lamellae densities estimated in calcite veins are used as paleo-piezometer. The deduced differential stress is ∼140 ± 70 MPa for the older vein generation and appears to be higher than stress for the youngest veins (45 ± 23 MPa). In spite of the relatively small clay content in both samples, newly formed clay minerals have been observed in gray as well as red clayey gouge material. Differences between gray and red clay gouge material are found in fault rock composition, porosity and clay fabric. The proportion of chlorite in the red gouge is significantly less than that in the gray gouge whereas the initial porosity is significantly higher than in the gray gouge material. The detection of a well-oriented clay fabric in red clay gouge samples is unique in comparison to other major fault zones. 相似文献
19.
Sand dunes as a major proximal dust source for late Pleistocene loess in the Negev Desert, Israel 总被引：3，自引：0，他引：3
Grain size analyses of three hilltop, primary eolian loess sequences in the Negev desert, southern Israel, show a bimodal grain-size distribution at 50-60 μm and 3-8 μm. Using analyses of mineralogy and OSL ages we demonstrate that the coarse mode is composed mostly of quartz grains and its relative magnitude increases regionally with time, suggesting an enhancement of a time-transgressive proximal dust source compared to a distal, Saharan fine-grain dust. The only proximal dust source for large amount of coarse silt quartz grains is the sands that advanced into Sinai and the Negev concurrently with the loess accretion during the late Pleistocene as a result of the exposure of the Mediterranean shelf. We therefore propose that the coarse silt quartz grains were formed through eolian abrasion within the margins of an advancing sand sea. This relationship between desert sand seas as a source for proximal coarse dust and desert margin loess deposits can be applicable to other worldwide deserts such as Northern Africa, China and Australia. 相似文献
20.
Surmounting luminescence age overestimation in Alaska-margin Arctic Ocean sediments by use of ‘micro-hole’ quartz dating 总被引：1，自引：0，他引：1
Glenn W. Berger 《Quaternary Science Reviews》2011,30(13-14):1750-1769
Because of several difficulties with the application of radiocarbon (14C) dating to Arctic Ocean sediments, numeric dating techniques are needed that can complement, supplant and reach beyond the 14C method. However, large age overestimates (often >7 kyr) for near-sediment-water-interface horizons from Arctic Ocean cores have been almost universal when luminescence dating has been applied to multigrain aliquots of fine silt (4–11 μm) quartz and feldspar grains. Here micro-hole quartz-grain photon-stimulated-luminescence (PSL) dating is applied to the 0.5–2.0 cm horizons of multicores from high-sedimentation-rate sites spanning depths from 87 m to 1140 m at the Alaska margin of the Arctic Ocean. Expected near zero ages (0–200 a) result when grains larger than ～11 μm are used, demonstrating that fine-silt age overestimations here and perhaps elsewhere in the Arctic Ocean are a function of grain and aliquot size. At the 87 m site, the micro-hole PSL approach revealed no significant gradient in age estimates over the 1–26 cm horizon range, implying that bioturbation reached to at least 26 cm. Micro-hole PSL dating of 25–62 μm quartz grains from trans-ocean sea-ice sediment also produced expected near zero ages, in contrast to earlier reported long-bleach multigrain PSL results from 4–11 μm fractions of the same samples. The micro-hole PSL approach thus surmounts the age overestimation problem associated with the use of multigrain silt fractions, and overcomes limitations of the 14C method in this region. Finally, results unexpectedly suggest the potential of micro-hole quartz PSL for use in provenance studies of Arctic Ocean sea-ice sediment. 相似文献