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晋蒙交界孔兹岩系熔体参与变质反应的结构特征及其动力学意义 总被引：2，自引：2，他引：0
晋蒙交界孔兹岩系变质反应结构与矿物相转变机制研究结果表明,在麻粒岩相变质及其与之相伴随的重熔作用过程中,存在一类特殊的有熔体参与的变质反应,即未熔矿物与熔体之间的反应。结合天然块状岩石高温高压实验,确定研究区孔兹岩系熔体参与变质反应如下：①２Ｇｔ＋（９ＳｉＯ２＋４Ａｌ２Ｏ３）熔体＝３Ｃｒｄ;②Ｇｔ＋（２ＳｉＯ２＋２Ａｌ２Ｏ３）熔体＝Ｓｐ＋Ｃｒｄ;③２Ｇｔ＋（３ＳｉＯ２）熔体＝２Ｏｐｘ＋Ｃｒｄ;④１４Ｇｔ＋（２５ＳｉＯ２＋４Ｈ２Ｏ）熔体＝４Ｃｕｍ＋７Ｃｒｄ。这类熔体参与变质反应不仅受控于温压条件,而且与寄主岩石脱水熔融、长英质矿物部分熔融存在密切成因关系。该项理论与实验研究对于深化变质反应理论、探讨孔兹岩系矿物相转变成因机制及其动力学过程有着重要的意义。 相似文献
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地幔岩包体中斜方辉石的GOD化现象 总被引：2，自引：2，他引：2
对我国东部四个地点碱性玄武岩中地幔岩样品的研究分析表明，地幔岩包体被带上来的过程中，斜方辉石比单斜辉石更易发生部分熔融，而形成熔体玻璃（Ｇｌａｓｓ）、橄榄石（Ｏｌｉｖｉｎｅ）和铬透辉石（ＣｈｒｏｍｅＤｉｐｓｉｄｅ）集合体，此作用可称为ＧＯＤ化。ＧＯＤ化沿包体边部最发育，向内逐渐减弱，以至消失。当玻璃极富Ｋ２Ｏ时，出现强烈ＧＯＤ化。在强烈ＧＯＤ化外面的寄主岩石中，还形成销沸石和／或方沸石聚集体。斜方辉石的ＧＯＤ化不仅是由于升温降压而导致的不一致熔融所致，而且还伴有物质的交换（带入ＣａＯ＋Ｎａ２Ｏ＋Ｋ２Ｏ，带出ＳｉＯ２＋ＭｇＯ）。 相似文献
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一种计算NaAlSi3O8熔体粘度的理论方法 总被引：2，自引：0，他引：2
硅酸岩熔体的结构特征是制约熔体粘度的主要因素，熔体结构的变异是其中粘流作用发生的原因，化学成分对熔体粘度的控制是通过改变熔体结构而实现的。ＳｉＯ２熔体中仅存在Ｓｉ－Ｏ键，而ＮａＡｌ－Ｓｉ３Ｏ８熔体中存在Ｓｉ－Ｏ键，Ａｌ－Ｏ键和Ｎａ－Ｏ键，Ｎａ－Ｏ键在熔体结构中通过Ｏ与Ｓｉ－Ｏ键相联结，并且使与之相联的Ｓｉ－Ｏ键的键强变弱。因此，熔体结构单元中与Ｎａ－Ｏ键相联结的Ｓｉ－Ｏ键最易断开，并因此导致流变作用的发生。文中计算了不同温度条件下ＮａＡｌＳｉ３Ｏ８熔体中Ｓｉ－Ｏ键的键强，以ＳｉＯ２熔体中的Ｓｉ－Ｏ键的键强和ＳｉＯ２熔体的粘度为标准，建立了计算了ＮａＡｌＳｉ３Ｏ８熔体粘度的理论模型，依此理论模型求得的熔体粘度在合理的地质温度范围内与实验结果完全吻合 相似文献
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以岩石粉末试样的熔融实验为基础的 Ｑ Ａｂ Ｏｒ Ａｎ Ｈ２ Ｏ 体系的相关系表明,地壳岩石的熔融作用遵循矿物相消失所制约的固 液相平衡规律。然而,地壳岩石块状样品开放体系的熔融作用,其熔融机制、矿物相转变、初熔液相成分、残余固相等方面,均与地壳岩石封闭体系的熔融作用有很大差别。石英闪长岩开放体系的熔融实验表明,岩石的熔融首先从含水矿物的脱水熔融开始,从而熔体成分由基性逐渐转变为中酸性,残余固相趋于超酸性。这一实验结果对大陆地区岩浆起源和深部地壳物质组成的研究可能有新的启示。 相似文献
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大别山金鸡寨花岗岩体岩石化学特征及侵位机制初步探讨 总被引：2，自引：0，他引：2
】大别山金鸡寨花岗岩体位于大别山碰撞造山带东端,紧邻郯庐断裂,是由碱长石英正长岩和碱长花岗岩组成。这两种岩石的组成矿物均为碱性长石、石英、斜长石、角闪石、黑云母、磁铁矿及副矿物榍石、磷灰石,但矿物含量不同。它们的岩石化学特征也不相同：（１）碱长石英正长岩中常量元素的平均含量（ｗｔ％）ＳｉＯ２为６７．１１％,Ａｌ２Ｏ３为１７％,Ｎａ２Ｏ＋Ｋ２Ｏ为１０．９７％,其中Ｋ２Ｏ＞Ｎａ２Ｏ,微量、稀土元素均较富集,但高场强元素、轻稀土含量及ＬＲＥＥ／ＨＲＥＥ均大于碱长花岗岩中的相应数值。（２）碱长花岗岩中常量元素的平均含量（ｗｔ％）ＳｉＯ２为７５．１３％,Ａｌ２Ｏ３为１３％,Ｎａ２Ｏ＋Ｋ２Ｏ为８．２３％,其中Ｋ２Ｏ＞Ｎａ２Ｏ,微量、稀土元素含量较高,但大离子亲石元素、重稀土元素含量则大于碱长石英正长岩中的含量。根据野外调查、岩石学特征及常量、微量、稀土元素研究表明,这两种岩石是同一岩浆不同演化阶段的产物,是于造山后形成的Ａ型花岗岩,其形成经历了部分熔融和结晶分异两个阶段,源岩可能来自于北大别变质杂岩。金鸡寨岩体的侵位是以“半汽球”膨胀机制进行的,并与龙井关断裂密切相关。 相似文献
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同位素年代学研究表明，长乐－南澳变形变质带存在元古宙的古陆块，随后至少经历了加里东，印支，燕山，喜马拉雅等４期构造热事件，岩石化学特征显示，加里东基底岩石为正变质岩；印支，燕山期盖层石有正变质岩，也有负变质岩。从加里东→印支，燕山期，ＳｉＯ２含量从低到高，ＦｅＯ＋ＭｇＯ＋ＣａＯ＋ＴｉＯ２含量由高到低呈现规律性变化，稀土地球化学研究表明，加里东斯基底岩石稀土总量较低，轻重稀土轻度分异，Ｅｕ正异常，为 相似文献
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辽宁阜新地区晚太古宙花岗质岩石在中地壳糜棱岩化过程中的体积亏损 … 总被引：1，自引：0，他引：1
对辽西阜新地区晚太古宙韧性剪切变形变质岩石岩石学,常量、微量和稀土元素地球化学和矿物学的研究表明,在中地壳环境下的韧性剪切变形变质进程中,岩石中的元素都发生了不同程度的变异,主要表现为随变形强度的增加ＳｉＯ２,Ｎａ２Ｏ,Ｚｒ等组分规律性减少,而Ａｌ２Ｏ３,ＣａＯ,ＦｅＯ,ＭｇＯ等常量元素、稀土元素以及Ｂａ,Ｃｒ,Ｓｒ,Ｎｉ,Ｒｂ等微量元素规律性增加,本文认为剪切变形变质岩石的成分变异不仅仅是流体作 相似文献
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含水大陆下地壳的部分熔融：大别山C型埃达克岩成因探讨 总被引：4，自引：0，他引：4
根据大陆下地壳的成分、含水基性岩体系部分熔融的基本原理和实验岩石学资料,本文对大陆下地壳的熔融机制展
开了讨论,并在此基础上对比实验熔体与大别山C 型埃达克岩的成分,进而探讨约束源岩成分、熔融的温压条件和部分熔
融程度。研究结果表明,大陆下地壳总体上是中- 基性（SiO2 50%~60% ）和含少量水的,在缺乏流体相条件下伴随含水
矿物脱水的部分熔融是下地壳产生含水长英质熔体和无水残留体的主要机制。角闪岩在中等压力下（1.0~1.2 GPa,相当于
35~40 km）理论上能够产生石榴石含量超过~20% 的熔融残余,从而使得与之平衡的长英质熔体具有低Y,高Sr/Y 和La/Yb
比值等埃达克岩特征。基于水活度模型和变质基性岩p -t 相图的估算显示,含有40%~60% 角闪石的源岩（含水0.8%~1.2%）
在~950 ℃能够得到最大为15%~20% 的熔体,该熔体分数满足熔体分离的要求。大别山C型埃达克岩主要为高钾钙碱性系
列（K2O 3.5%~5%）,与实验熔体成分的对比可知,其无法由低钾源岩在合理的部分熔融程度形成。根据钾在角闪岩部分熔
融过程过表现为强不相容元素的原理,利用合理假设的残余体组合得到的分配系数,估算K2O 含量为~1% 的源岩在熔融程
度为15%~20% 的情况下能够得到类似大别山C 型埃达克岩成分的熔体。 相似文献
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对秦岭造山带和邻区块状岩石样品进行了高温（1 100~1 300 ℃）和高压（1.2~1.8 GPa）脱水熔融实验。通过对实验产物综合分析发现许多样品中出现了熔融玻璃和雏晶。玻璃代表的熔体成分为基性和中性,部分接近于超基性范围,熔体与原来岩石全岩成分比较,更偏基性。熔体出现的空间和成分都显示了局部熔融体系的特征,即含水矿物（角闪石或黑云母）和浅色矿物（石英或斜长石）控制了熔融的发生并且决定了熔体的成分。脱水熔融产生了比原岩更偏基性的熔体,这意味着熔融后残留部分将愈偏酸性。如果这种机制存在于大陆中-下地壳,将对探讨大陆地壳的结构和物质组成,解释某些地区的长英质中下地壳的成因等具有重要的意义。 相似文献
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深熔过程中熔体成分与锆石行为模拟计算 总被引：3，自引：2，他引：1
发生深熔作用是高级变质作用的一个重要特征。深熔过程中产生的熔体可为淡色花岗岩提供潜在的源区;深熔过程中锆石的行为直接影响对变质锆石记年地质意义的理解。在含Zr体系下的相平衡模拟显示泥质成分深熔过程中产生熔体的成分在P-T空间中规律变化。温度升高时熔体Zr/Si值、Zr、FeO、MgO以及CaO等含量明显增加,压力较高时K2O含量也随温度升高而明显增加。Na2O含量随温度升高而降低,但随压力升高而增加。压力升高时Al/Si值显著升高。温度较高时Na/(Na+K)等值线较陡,减压熔融过程不会显著改变熔体Na/(Na+K)值,而升温减压过程以及近等压升温过程都会明显降低熔体Na/(Na+K)值。中压时随温度升高熔体Fe/(Fe+Mg)值缓慢升高,而石榴石的生长发育会迅速降低熔体Fe/(Fe+Mg)值。不同温压条件下对应的固相线熔融、白云母脱水熔融以及黑云母脱水熔融形成的熔体成分具有明显差异。对比模拟熔体成分在P-T空间的演化,喜马拉雅地区电气石淡色花岗岩对应熔体的形成温压条件应低于二云母淡色花岗岩,同类型淡色花岗岩之间在形成条件上也可能存在一定差异,并经历了差异性演化过程。含Zr体系下的相平衡关系显示进变过程是消耗锆石的过程,因而在进变过程中变质锆石难以生长,发生深熔作用的岩石中的变质锆石主要在退变过程中形成并记录退变质年龄。熔体丢失相关模拟显示不同温度阶段发生熔体丢失对锆石稳定性的影响不同。温度较低时Zr含量较少的熔体丢失会扩大持续进变过程中锆石的稳定范围,而温度较高时富Zr熔体的丢失会降低持续进变过程中锆石的稳定温度。类似于分离熔融作用的过程最利于残留相中剩余锆石在持续进变过程中的保存。 相似文献
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Melt glasses for seven types of rock ranging from acid to basic were prepared under 1.0 GPa on a multi-anvil pressure apparatus, YJ-3000 ton press. Densities and elastic properties of the melt glasses were compared with those described in previous studies. It was found that the glasses melted under 1.0 GPa were consistent in density with both naturally-occurring glassy rocks and artificially prepared glasses melted at ambient pressure. The densities of glasses are negatively correlated with the SiO2 contents and positively correlated with the （MgO＋FeO） contents. The compressive velocity （Vp） of glass tends to increase with decreasing SiO2 contents and increasing （MgO＋FeO） contents. The shear velocity （Vs） of glass tends to increase slightly with increasing SiO2 contents, which has little connection with the （MgO＋FeO） contents. It was calculated from densities and velocities that the elastic moduli of glasses are negatively correlated with the SiO2 contents and positively correlated with the （MgO＋FeO） contents. 相似文献
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Experimental Study of Partial Melting of Mantle Peridotite--A Discussion about the Genesis of Silica-rich Fluids (Melts) 总被引：1，自引：0，他引：1
LI Jianping 《《地质学报》英文版》1999,73(4):395-403
Experiments on partial melting of mantle lherzolite have been realized at 0.6 and 1.0 GPa and the chemical compositional variations of melts during different melting stages have been first discussed. The results show that the trends of variations in SiO2, CaO, Al2O3, Na2O and TiO2 are different at different melting stages. The melts produced at lower pressure are richer in SiO2 than those at higher pressure. The mantle-derived silica-rich fluids (silicate melts) are polygenetic, but the basic and intermediate-acid silicate melts in mantle peridotite xenoliths from the same host rocks, which have equivalent contents of volatile and alkali components and different contents of other components, should result from in-situ (low-degree) partial melting of mantle peridotite under different conditions (e.g. at different depths, with introduction of C-O-H fluids or in the presence of metasomatic minerals). The intermediate-acid melts may be the result of partial melting (at lower pressure) Opx + Sp + K-Na-rich fluid±(Amphi)±(Phlog)= Ol+melt.But the intermediate-acid magmas cannot be produced from the partial melting of normal mantle peridotite unless the crustal materials are introduced to some extent. 相似文献
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内容提要:江南造山带是我国重要的稀有金属成矿带,已发现多处与锂相关的花岗伟晶岩型稀有金属矿床。锂等稀有金属元素在源区基底岩石中的富集是花岗伟晶岩型锂稀有金属矿床成矿的物质基础,但是江南造山带基底岩石中锂的分布及其富集机制仍不清楚。本文详细调查研究了江南造山带东段新元古代冷家溪群、双桥山群、溪口岩群和板溪群变质沉积岩和星子杂岩。这些基底变质岩的岩石类型包括变质砂岩、泥质板岩、千枚岩和云母片岩以及少量片麻岩。地球化学分析结果显示,冷家溪群、双桥山群和溪口岩群变质沉积岩具有相似的成分,变质砂岩和云母片岩-片麻岩整体上比泥质板岩和千枚岩具有较高的Si O2含量,较低的Ti O2、Al2O3、K2O、Mg O和TFe2O3含量。泥质板岩和千枚岩含有更高的稀有金属元素含量,其中锂含量达到61.8×10-6,而变质砂岩的锂丰度为44.9×10-6。板溪群具有最低的稀有金属元素含量(Li=30.8×10 相似文献
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Partial melting of ultrahigh-pressure metamorphic rocks at convergent continental margins: Evidences,melt compositions and physical effects 总被引：2，自引：0，他引：2
Ultrahigh-pressure(UHP) metamorphic rocks are distinctive products of crustal deep subduction,and are mainly exposed in continental subduction-collision terranes. UHP slices of continental crust are usually involved in multistage exhumation and partial melting, which has obvious influence on the rheological features of the rocks, and thus significantly affect the dynamic behavior of subducted slices. Moreover,partial melting of UHP rocks have significant influence on element mobility and related isotope behavior within continental subduction zones, which is in turn crucial to chemical differentiation of the continental crust and to crust-mantle interaction.Partial melting can occur before, during or after the peak metamorphism of UHP rocks. Post-peak decompression melting has been better constrained by remelting experiments; however, because of multiple stages of decompression, retrogression and deformation, evidence of former melts in UHP rocks is often erased. Field evidence is among the most reliable criteria to infer partial melting. Glass and nanogranitoid inclusions are generally considered conclusive petrographic evidence. The residual assemblages after melt extraction are also significant to indicate partial melting in some cases. Besides field and petrographic evidence, bulk-rock and zircon trace-element geochemical features are also effective tools for recognizing partial melting of UHP rocks. Phase equilibrium modeling is an important petrological tool that is becoming more and more popular in P-T estimation of the evolution of metamorphic rocks; by taking into account the activity model of silicate melt, it can predict when partial melting occurred if the P-T path of a given rock is provided.UHP silicate melt is commonly leucogranitic and peraluminous in composition with high SiO_2,low MgO, FeO, MnO, TiO_2 and CaO, and variable K_2 O and Na_2 O contents. Mineralogy of nanogranites found in UHP rocks mainly consists of plagioclase + K-feldspar + quartz, plagioclase being commonly albite-rich.Trace element pattern of the melt is characterized by significant enrichment of large ion lithophile elements(LILE), depletion of heavy rare earth elements(HREE) and high field strength elements(HFSE),indicating garnet and rutile stability in the residual assemblage. In eclogites, significant Mg-isotope fractionation occurs between garnet and phengite; therefore, Mg isotopes may become an effective indicator for partial melting of eclogites. 相似文献
18.
Partitioning coefficients between olivine and silicate melts 总被引：3，自引：0，他引：3
J.H. Bdard 《Lithos》2005,83(3-4):394-419
Variation of Nernst partition coefficients (D) between olivine and silicate melts cannot be neglected when modeling partial melting and fractional crystallization. Published natural and experimental olivine/liquidD data were examined for covariation with pressure, temperature, olivine forsterite content, and melt SiO2, H2O, MgO and MgO/MgO + FeOtotal. Values of olivine/liquidD generally increase with decreasing temperature and melt MgO content, and with increasing melt SiO2 content, but generally show poor correlations with other variables. Multi-element olivine/liquidD profiles calculated from regressions of D REE–Sc–Y vs. melt MgO content are compared to results of the Lattice Strain Model to link melt MgO and: D0 (the strain compensated partition coefficient), EM3+ (Young's Modulus), and r0 (the size of the M site). Ln D0 varies linearly with Ln MgO in the melt; EM3+ varies linearly with melt MgO, with a dog-leg at ca. 1.5% MgO; and r0 remains constant at 0.807 Å. These equations are then used to calculate olivine/liquidD for these elements using the Lattice Strain Model. These empirical parameterizations of olivine/liquidD variations yield results comparable to experimental or natural partitioning data, and can easily be integrated into existing trace element modeling algorithms. The olivine/liquidD data suggest that basaltic melts in equilibrium with pure olivine may acquire small negative Ta–Hf–Zr–Ti anomalies, but that negative Nb anomalies are unlikely to develop. Misfits between results of the Lattice Strain Model and most light rare earth and large ion lithophile partitioning data suggest that kinetic effects may limit the lower value of D for extremely incompatible elements in natural situations characterized by high cooling/crystallization rates. 相似文献
19.
在1.5GPa,950℃,恒温101h条件下对华北北缘太古宙地体中的斜长角闪岩块状样品进行了脱水部分熔融实验,实验产物组合为Hb+Cpx+Gt+Gl,获得的熔体为花岗闪长质成分。利用LA-ICP-MS测试了矿物和熔体的微量元素,获得该体系内各矿物/熔体的微量元素分配系数。角闪石、单斜辉石和石榴石的分配系数与前人在类似条件下的实验结果基本一致。这说明无论实验的初始物质是粉末状还是块状,对元素的分配没有太大的影响。各矿物的REE分配系数对离子半径的拟合曲线很好地符合晶格应变弹性模型。整体特征上,角闪石、单斜辉石和石榴石的LILE,LREE分配系数较低,而HREE的分配系数较高,石榴石具有强烈富集HREE的特征。由此,造成实验熔体表现出LILE、LREE富集而HREE亏损的特征。残留相中无金红石,使得熔体中没有明显的Nb、Ta负异常。熔体的主-微量元素特征符合华北北缘中生代埃达克质岩石的基本特征,进一步支持了该类岩石"可能起源于古老下地壳的部分熔融"的成因模式。 相似文献
20.
Low-Ca pyroxenes play an important role in mantle melting, melt-rock reaction, and magma differentiation processes. In order to better understand REE fractionation during adiabatic mantle melting and pyroxenite-derived melt and peridotite interaction, we developed a parameterized model for REE partitioning between low-Ca pyroxene and basaltic melts. Our parameterization is based on the lattice strain model and a compilation of published experimental data, supplemented by a new set of trace element partitioning experiments for low-Ca pyroxenes produced by pyroxenite-derived melt and peridotite interaction. To test the validity of the assumptions and simplifications used in the model development, we compared model-derived partition coefficients with measured partition coefficients for REE between orthopyroxene and clinopyroxene in well-equilibrated peridotite xenoliths. REE partition coefficients in low-Ca pyroxene correlate negatively with temperature and positively with both calcium content on the M2 site and aluminum content on the tetrahedral site of pyroxene. The strong competing effect between temperature and major element compositions of low-Ca pyroxene results in very small variations in REE partition coefficients in orthopyroxene during adiabatic mantle melting when diopside is in the residue. REE partition coefficients in orthopyroxene can be treated as constants at a given mantle potential temperature during decompression melting of lherzolite and diopside-bearing harzburgite. In the absence of diopside, partition coefficients of light REE in orthopyroxene vary significantly, and such variations should be taken into consideration in geochemical modeling of REE fractionation in clinopyroxene-free harzburgite. Application of the parameterized model to low-Ca pyroxenes produced by reaction between pyroxenite-derived melt and peridotite revealed large variations in the calculated REE partition coefficients in the low-Ca pyroxenes. Temperature and composition of starting pyroxenite must be considered when selecting REE partition coefficients for pyroxenite-derived melt and peridotite interaction. 相似文献