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1.
La Soufrière (1467 m) is the active island arc volcano of Guadeloupe Island in the Lesser Antilles arc. Its historical eruptions are more or less violent phreatic outbursts the last of which, in 1976–1977, led to the evacuation of nearly 70 000 persons. The subsurface structure of the volcano consists of calderas, craters, and avalanche amphitheatres nested within the composite pile of eruptive products. Since the last magmatic eruption, dated ca. 1440 AD, the four phreatic eruptions have developed radial fractures on Soufrière dome favouring the development of a huge active hydrothermal system emphasized by a tropical environment. After the eruptions, the thermal state and the stable ground water flow are completely disorganised during several years during which the slow mineralization of rocks is becoming again preponderant. Sealing of fractures and decay of rocks permeability act as a cap for upward thermal transfers. Therefore Soufrière dome operates as a valve, resealing the hydrothermal system underlying the volcano thus providing over pressurization that could lead to the next phreatic eruption. In 1992 new small seismic swarms have appeared. Several of them are recorded every year while the emission of acid gas slowly increases.In order to recognise the superficial electrical resistive and conductive zones (less than 100 m depth) as well as the cavities on Soufrière volcano, we have made Very Low Frequency (VLF) surveys in 2000. Electrical conductive zones are clearly associated with major radial faults starting from the summit in which the hydrothermal activity takes place. In the continuation of these active hydrothermal fractures hot springs are located down slope. Conversely some of the resistive zones are associated with inactive clayed and sealed or opened faults. The distribution of the conductive zones allows detailing the state of the superficial part of the hydrothermal system of La Soufrière. The distribution of vertical clayed zones associated with major faults supposes Soufrière dome constituted of more or less consolidated blocks joined side by side and lying on the hydrothermally floor of crater Amic.  相似文献   

2.
La Soufrière of Guadeloupe is a dangerous volcano characterized over the last decade by moderate seismic and fumarolic unrest. In the last 15,000 years it has experienced phreatic and magmatic eruptions and unusually numerous flank collapse events sometimes associated with a magmatic eruption. We propose a new age of 1530 A.D. and a new eruptive scenario for the last magmatic eruption on the basis of a novel statistical analysis of radiocarbon age dates, and new field and geochemical data. This eruption is the only magmatic eruption likely to have occurred in Guadeloupe during the last 1400 years. The eruption mainly involved an andesitic magma which, in the first phase of the eruption, partially mixed with a slightly more differentiated magma stored in a small and shallow magma chamber. Ascent of magma to the surface generated a partial collapse of the hydrothermally altered edifice that increased the magma discharge and led to a sub-plinian phase with scoria fallout and column-collapse pyroclastic flows followed by near-vent pyroclastic scoria fountains. The eruption ended with growth of a lava dome. Our revised interpretation of the last magmatic eruption of La Soufrière constitutes the most likely key to a future magmatic eruption scenario for this volcano which displays strong evidence of unrest since 1992.  相似文献   

3.
White Island is an active andesitic-dacitic composite volcano surrounded by sea, yet isolated from sea water by chemically sealed zones that confine a long-lived acidic hydrothermal system, within a thick sequence of fine-grained volcaniclastic sediment and ash. The rise of at least 106 m3 of basic andesite magma to shallow levels and its interaction with the hydrothermal system resulted in the longest historical eruption sequence at White Island in 1976–1982. About 107 m3 of mixed lithic and juvenile ejecta was erupted, accompanied by collapse to form two coalescing maar-like craters. Vent position within the craters changed 5 times during the eruption, but the vents were repeatedly re-established along a line linking pre-1976 vents. The eruption sequence consisted of seven alternating phases of phreatomagmatic and Strombolian volcanism. Strombolian eruptions were preceded and followed by mildly explosive degassing and production of incandescent, blocky juvenile ash from the margins of the magma body. Phreatomagmatic phases contained two styles of activity: (a) near-continuous emission of gas and ash and (b) discrete explosions followed by prolonged quiescence. The near-continuous activity reculted from streaming of magmatic volatiles and phreatic steam through open conduits, frittering juvennile shards from the margins of the magma and eroding loose lithic particles from the unconsolidated wall rock. The larger discrete explosions produced ballistic block aprons, downwind lobes of fall tephra, and cohesive wet surge deposits confined to the main crater. The key features of the larger explosions were their shallow focus, random occurrence and lack of precursors, and the thermal heterogeneity of the ejecta. This White Island eruption was unusual because of the low discharge rate of magma over an extended time period and because of the influence of a unique physical and hydrological setting. The low rate of magma rise led to very effective separation of magmatic volatiles and high fluxes of magmatic gas even during phreatic phases of the eruption. While true Strombolian phases did occur, more frequently the decoupled magmatic gas rose to interact with the conduit walls and hydrothermal system, producing phreatomagmatic eruptions. The form of these wet explosions was governed by a delicate balance between erosion and collapse of the weak conduit walls. If the walls were relatively stable, fine ash was slowly eroded and erupted in weak, near-continous phreatomagmatic events. When the walls were unstable, wall collapse triggered larger discrete phreatomagmatic explosions.  相似文献   

4.
In January 1989 we observed submarine eruptions on the summit of Macdonald volcano during a French-German diving programme with the IFREMER submersible Cyana. Gas-streaming of large amounts of CH4, CO2 and SO2 from summit vents, inferred from water column anomalies and observed by submersible, was accompanied on the sea surface by steam bursts, turbulence, red-glowing gases, and black bubbles comprising volcanic ash, sulphur and sulphides. Chloride depletion of water sampled on the floor of an actively degassing summit crater suggests either boiling and phase separation or additions of magmatic water vapour. Submersible observations, in-situ sampling and shipboard geophysical and hydrographic measurements show that the hydrothermal system of this hotspot volcano is distinguished by the influence of magmatic gases released from its shallow summit.  相似文献   

5.
The 1902–1905 activity of Montagne Pelée represents a moderately large eruptive cycle typical of a subduction zone volcano. It followed a three-centuries-long repose interrupted only in 1792 by two small phreatic explosions and minor (phreatomagmatic?) eruptions in 1851–1852. The volcano decidedly awakened in early 1902 with increasing fumaroles at l'Etang Sec summit crater, light earthquakes and phreatic activity from 23 April onwards. On 2–3 May the eruption became phreatomagmatic and much more active. Destructive lahars culminated on 5 May and during the night of 7–8 May, causing 23 casualties at the Guérin factory and about 400 others at Le Prêcheur. On 8 May at 08:02 local time a climactic ‘nuée ardente’ destroyed the city of Saint-Pierre, 8 km south of the crater, and killed all its 27–28,000 inhabitants but one, or possibly two. Testimonies from eyewitnesses of this event, calculations made on its effects, and careful studies of its deposits support the interpretation of a powerful lateral blast (175−140 m/s) accompanied by a fast-moving pyroclastic flow which was directed N-S, i.e. toward the town itself. The temperature of the flow decreased from that of the acid andesite magma (about 900°C) at the crater to 400–200°C as it reached Saint-Pierre. Climactic ‘pelean’ eruptions, initiated by strong explosions, were renewed on 20 May and 30 August. This latter produced 1,000 additional victims at Morne Rouge, making a total of about 29,000 victims for the entire eruptive period. Less violent eruptions, without major explosions, took place on 26 May, 6 June, 9 July and from late 1902 to July 1905, generating slow-moving pyroclastic flows (50 m/s or less), linked to relatively quiet dome growth.The catastrophe of Saint-Pierre resulted from an insufficient knowledge of volcanic hazards at the time and particularly from the total ignorance of pyroclastic flow (nuée ardente) phenomena. Future hazards in Martinique include the renewal of pelean eruptions and widespread plinian activity, such as has occurred in the past 5,000 years, together with a less probable sector collapse triggering tsunami. As major magmatic eruptions of Montagne Pelée may be separated by repose periods of more than 500 years, a long-term instrumental surveillance of the volcano is needed, and adequate concepts in urban planning should be developed and sustained in the next centuries.  相似文献   

6.
The vent-hosted hydrothermal system of Ruapehu volcano is normally covered by a c. 10 million m3 acidic crater lake where volcanic gases accumulate. Through analysis of eruption observations, granulometry, mineralogy and chemistry of volcanic ash from the 1995–1996 Ruapehu eruptions we report on the varying influences on environmental hazards associated with the deposits. All measured parameters are more dependent on the eruptive style than on distance from the vent. Early phreatic and phreatomagmatic eruption phases from crater lakes similar to that on Ruapehu are likely to contain the greatest concentrations of environmentally significant elements, especially sulphur and fluoride. These elements are contained within altered xenolithic material extracted from the hydrothermal system by steam explosions, as well as in residue hydrothermal fluids adsorbed on to particle surfaces. In particular, total F in the ash may be enriched by a factor of 6 relative to original magmatic contents, although immediately soluble F does not show such dramatic increases. Highly soluble NaF and CaSiF6 phases, demonstrated to be the carriers of ‘available’ F in purely magmatic eruptive systems, are probably not dominant in the products of phreatomagmatic eruptions through hydrothermal systems. Instead, slowly soluble compounds such as CaF2, AlF3 and Ca5(PO4)3F dominate. Fluoride in these phases is released over longer periods, where only one third is leached in a single 24-h water extraction. This implies that estimation of soluble F in such ashes based on a single leach leads to underestimation of the F impact, especially of a potential longer-term environmental hazard. In addition, a large proportion of the total F in the ash is apparently soluble in the digestive system of grazing animals. In the Ruapehu case this led to several thousand sheep deaths from fluorosis.  相似文献   

7.
 Investigation of well-exposed volcaniclastic deposits of Shiveluch volcano indicates that large-scale failures have occurred at least eight times in its history: approximately 10,000, 5700, 3700, 2600, 1600, 1000, 600 14C BP and 1964 AD. The volcano was stable during the Late Pleistocene, when a large cone was formed (Old Shiveluch), and became unstable in the Holocene when repetitive collapses of a portion of the edifice (Young Shiveluch) generated debris avalanches. The transition in stability was connected with a change in composition of the erupting magma (increased SiO2 from ca. 55–56% to 60–62%) that resulted in an abrupt increase of viscosity and the production of lava domes. Each failure was triggered by a disturbance of the volcanic edifice related to the ascent of a new batch of viscous magma. The failures occurred before magma intruded into the upper part of the edifice, suggesting that the trigger mechanism was indirectly associated with magma and involved shaking by a moderate to large volcanic earthquake and/or enhancement of edifice pore pressure due to pressurised juvenile gas. The failures typically included: (a) a retrogressive landslide involving backward rotation of slide blocks; (b) fragmentation of the leading blocks and their transformation into a debris avalanche, while the trailing slide blocks decelerate and soon come to rest; and (c) long-distance runout of the avalanche as a transient wave of debris with yield strength that glides on a thin weak layer of mixed facies developed at the avalanche base. All the failures of Young Shiveluch were immediately followed by explosive eruptions that developed along a similar pattern. The slope failure was the first event, followed by a plinian eruption accompanied by partial fountain collapse and the emplacement of pumice flows. In several cases the slope failure depressurised the hydrothermal system to cause phreatic explosions that preceded the magmatic eruption. The collapse-induced plinian eruptions were moderate-sized and ordinary events in the history of the volcano. No evidence for directed blasts was found associated with any of the slope failures. Received: 28 June 1998 / Accepted: 28 March 1999  相似文献   

8.
The Soufrière volcano in Guadeloupe island delivered a phreatic eruption that commenced on July 8th, 1976 and lasted until March 1st, 1977. This eruption was similar to the 1797, 1798, 1809 and 1956 outbreaks. Phreatic activity ejected blocks derived from the fissure walls and fine pyroclasts produced by hydrothermal alteration of the old dome’s rocks. Field observations and measurements allowed the present authors to calculate the mass and energy transfer of steam and ashes: 107 tons of water (very low considering that on the mountain summit the annual precipitation is 10 tons m)2,106 m3 of ashes. The most important energy transfers was thermal: about 5 × 1020 ergs for each phreatic eruption. The total kinetic energy output was 2 × 1019 ergs for a total thermal energy output of 64 × 1020 ergs. The gases and fine pyroclasts did pollute the atmosphere, waters and soils and consequently affected the population living on the slopes of the volcano.  相似文献   

9.
Major slope failures are a significant degradational process at volcanoes. Slope failures and associated explosive eruptions have resulted in more than 20 000 fatalities in the past 400 years; the historic record provides evidence for at least six of these events in the past century. Several historic debris avalanches exceed 1 km3 in volume. Holocene avalanches an order of magnitude larger have traveled 50–100 km from the source volcano and affected areas of 500–1500 km2. Historic eruptions associated with major slope failures include those with a magmatic component (Bezymianny type) and those solely phreatic (Bandai type). The associated gravitational failures remove major segments of the volcanoes, creating massive horseshoe-shaped depressions commonly of caldera size. The paroxysmal phase of a Bezymianny-type eruption may include powerful lateral explosions and pumiceous pyroclastic flows; it is often followed by construction of lava dome or pyroclastic cone in the new crater. Bandai-type eruptions begin and end with the paroxysmal phase, during which slope failure removes a portion of the edifice. Massive volcanic landslides can also occur without related explosive eruptions, as at the Unzen volcano in 1792.The main potential hazards from these events derive from lateral blasts, the debris avalanche itself, and avalanche-induced tsunamis. Lateral blasts produced by sudden decompression of hydrothermal and/or magmatic systems can devastate areas in excess of 500km2 at velocities exceeding 100 m s–1. The ratio of area covered to distance traveled for the Mount St. Helens and Bezymianny lateral blasts exceeds that of many pyroclastic flows or surges of comparable volume. The potential for large-scale lateral blasts is likely related to the location of magma at the time of slope failure and appears highest when magma has intruded into the upper edifice, as at Mount St. Helens and Bezymianny.Debris avalanches can move faster than 100 ms–1 and travel tens of kilometers. When not confined by valley walls, avalanches can affect wide areas beyond the volcano's flanks. Tsunamis from debris avalanches at coastal volcanoes have caused more fatalities than have the landslides themselves or associated eruptions. The probable travel distance (L) of avalanches can be estimated by considering the potential vertical drop (H). Data from a catalog of around 200 debris avalanches indicates that the H/L rations for avalanches with volumes of 0.1–1 km3 average 0.13 and range 0.09–0.18; for avalanches exceeding 1 km3, H/L ratios average 0.09 and range 0.5–0.13.Large-scale deformation of the volcanic edefice and intense local seismicity precede many slope failures and can indicate the likely failure direction and orientation of potential lateral blasts. The nature and duration of precursory activity vary widely, and the timing of slope faliure greatly affects the type of associated eruption. Bandai-type eruptions are particularly difficult to anticipate because they typically climax suddenly without precursory eruptions and may be preceded by only short periods of seismicity.  相似文献   

10.
The edifice of Mount Rainier, an active stratovolcano, has episodically collapsed leading to major debris flows. The largest debris flows are related to argillically altered rock which leave areas of the edifice prone to failure. The argillic alteration results from the neutralization of acidic magmatic gases that condense in a meteoric water hydrothermal system fed by the melting of a thick mantle of glacial ice. Two craters atop a 2000-year-old cone on the summit of the volcano contain the world's largest volcanic ice-cave system. In the spring of 1997 two active fumaroles (T=62°C) in the caves were sampled for stable isotopic, gas, and geochemical studies.Stable isotope data on fumarole condensates show significant excess deuterium with calculated δD and δ18O values (−234 and −33.2‰, respectively) for the vapor that are consistent with an origin as secondary steam from a shallow water table which has been heated by underlying magmatic–hydrothermal steam. Between 1982 and 1997, δD of the fumarole vapor may have decreased by 30‰.The compositions of fumarole gases vary in time and space but typically consist of air components slightly modified by their solubilities in water and additions of CO2 and CH4. The elevated CO2 contents (δ13CCO2=−11.8±0.7‰), with spikes of over 10,000 ppm, require the episodic addition of magmatic components into the underlying hydrothermal system. Although only traces of H2S were detected in the fumaroles, most notably in a sample which had an air δ13CCO2 signature (−8.8‰), incrustations around a dormant vent containing small amounts of acid sulfate minerals (natroalunite, minamiite, and woodhouseite) indicate higher H2S (or possibly SO2) concentrations in past fumarolic gases.Condensate samples from fumaroles are very dilute, slightly acidic, and enriched in elements observed in the much higher temperature fumaroles at Mount St. Helens (K and Na up to the ppm level; metals such as Al, Pb, Zn Fe and Mn up to the ppb level and volatiles such as Cl, S, and F up to the ppb level).The data indicate that the hydrothermal system in the edifice at Mount Rainier consists of meteoric water reservoirs, which receive gas and steam from an underlying magmatic system. At present the magmatic system is largely flooded by the meteoric water system. However, magmatic components have episodically vented at the surface as witnessed by the mineralogy of incrustations around inactive vents and gas compositions in the active fumaroles. The composition of fumarole gases during magmatic degassing is distinct and, if sustained, could be lethal. The extent to which hydrothermal alteration is currently occurring at depth, and its possible influence on future edifice collapse, may be determined with the aid of on site analyses of fumarole gases and seismic monitoring in the ice caves.  相似文献   

11.
Superficial volcanic manifestations occurred at Soufriere de Guadeloupe in 1976–1977. Superficial phenomena started on July 8, and had been preceded the previous year by a seismovolcanic crisis of exceptional amplitude for the Caribbean region. The essentially phreatic manifestations were accompanied by an extraordinarily high number of recorded quiakes: 16,467 earthquakes in 21 months, 153 of which classified as clearly perceived. The epicentral area covered about 30 km2, and the seismic energy released reached a total of 1018 erg. Thirty-six volcanic tremors accompanied violent superficial manifestations, and 26 strong phreatic eruptions have been observed. The important role played by seismology as a crisis detector for this type of volcanoes has been clearly shown.  相似文献   

12.
This paper presents the first remote measurements of La Soufrière gas emissions since the fumarolic and seismic reactivation in 1992. The chemical composition of the plumes has been measured from May 2003 to September 2004 using an Open Path Fourier Transform InfraRed (OP-FTIR) spectrometer, up to 15 m downwind the South Crater. HCl is clearly detected (concentration between 2.4 and 12 ppmv) whereas SO2 and H2S generally remain below the detection limit of the OP-FTIR. Direct measurements of SO2 and H2S near the South Crater with a Lancom III analyzer show a fast decrease of their concentrations with the distance. Calculated Cl / S mass ratios are high: from 9.4 ± 1.7 at 15 m from the vent to 2.8 ± 0.6 at 140 m. The enrichment in HCl of the gas emitted at La Soufrière, observed since 1998, corresponds to the degassing of a magma enriched in Cl and depleted in S. This result agrees with isotopic measurements which suggest a magmatic origin of the gases. Readjustments inside the volcanic system may have taken place during the seismic activity beginning in 1992 and enhance the transfer of magmatic gases to the summit.  相似文献   

13.
Phreatic eruptions occurred at the Meakandake volcano in 1988, 1996, 1998, 2006, and 2008. We conducted geochemical surveillance that included measurements of temperature, SO2 emission rates, and volcanic gas composition from 2003 to 2008 at the Nakamachineshiri (NM), Northwest (NW), and Akanuma (AK) fumarolic areas, and the 96–1 vent, where historical eruptions had occurred. The elemental compositions of the gases discharged from the different areas are similar compared with the large variations observed in volcanic gases discharged from subduction zones. All the gases showed high apparent equilibrium temperatures, suggesting that all these gases originated from a common magmatic gas. The gases discharged from each area also exhibited different characteristics, which are probably the results of differences in the conditions of meteoric water mixing, quenching of chemical reactions, and vapor-liquid separation. The highest apparent equilibrium temperatures (about 500°C) were observed in the case of NW fumarolic gases, despite the low outlet temperature of about 100°C at these fumaroles. Since the NW fumaroles were formed as a result of the 2006 phreatic eruption, the high-temperature gas supply to the NW fumarole suggests that the phreatic eruption was caused by the ascent of high-temperature magmatic gases. The temperatures, compositions, and emission rates of the NM and 96–1 gases did not show any appreciable change after the 2006 eruption, indicating that each fumarolic system had a separate magmatic-hydrothermal system. The temperatures, compositions, and emission rates of the NM fumarolic gases were apparently constant, and these fumaroles are inferred to be formed by the evaporation of a hydrothermal system with a constant temperature of about 300°C. The 96–1 gas compositions showed large changes during continuous temperature decrease from 390° to 190°C occurred from 2003 to 2008, but the sulfur gas emission rates were almost constant at about four tons/day. At the 96–1 vent, the SO2/H2S ratio decreased, while the H2/H2O ratio remained almost constant; this was probably caused by the rock-buffer controlled chemical reaction during the temperature decrease.  相似文献   

14.
Local seismic activity consisting of sharp earthquakes accompanied by thunderous noise was reported starting in late December 1985 around Tacaná volcano (15.13°N, 92.10°W). Portable seismic stations were established in the area by late January 1986 and sampling of the only known thermal spring on the volcano flanks started at the same time. A marked increase in SO42− concentration in the spring water preceded by two months the occurrence of a seismic swarm crisis and a small phreatic explosion. A model involving a crystalline basement fractured by tectonic stresses is proposed to explain the chemical and seismic anomalies, and the consequences on risk of volcanic activity are briefly discussed in terms of the observed behaviour.  相似文献   

15.
Magmatic gas scrubbing: implications for volcano monitoring   总被引：1，自引：0，他引：1  
Despite the abundance of SO2(g) in magmatic gases, precursory increases in magmatic SO2(g) are not always observed prior to volcanic eruption, probably because many terrestrial volcanoes contain abundant groundwater or surface water that scrubs magmatic gases until a dry pathway to the atmosphere is established. To better understand scrubbing and its implications for volcano monitoring, we model thermochemically the reaction of magmatic gases with water. First, we inject a 915°C magmatic gas from Merapi volcano into 25°C air-saturated water (ASW) over a wide range of gas/water mass ratios from 0.0002 to 100 and at a total pressure of 0.1 MPa. Then we model closed-system cooling of the magmatic gas, magmatic gas-ASW mixing at 5.0 MPa, runs with varied temperature and composition of the ASW, a case with a wide range of magmatic–gas compositions, and a reaction of a magmatic gas–ASW mixture with rock. The modeling predicts gas and water compositions, and, in one case, alteration assemblages for a wide range of scrubbing conditions; these results can be compared directly with samples from degassing volcanoes. The modeling suggests that CO2(g) is the main species to monitor when scrubbing exists; another candidate is H2S(g), but it can be affected by reactions with aqueous ferrous iron. In contrast, scrubbing by water will prevent significant SO2(g) and most HCl(g) emissions until dry pathways are established, except for moderate HCl(g) degassing from pH<0.5 hydrothermal waters. Furthermore, it appears that scrubbing will prevent much, if any, SO2(g) degassing from long-resident boiling hydrothermal systems. Several processes can also decrease or increase H2(g) emissions during scrubbing making H2(g) a poor choice to detect changes in magma degassing.We applied the model results to interpret field observations and emission rate data from four eruptions: (1) Crater Peak on Mount Spurr (1992) where, except for a short post-eruptive period, scrubbing appears to have drastically diminished pre-, inter-, and post-eruptive SO2(g) emissions, but had much less impact on CO2(g) emissions. (2) Mount St. Helens where scrubbing of SO2(g) was important prior to and three weeks after the 18 May 1980 eruption. Scrubbing was also active during a period of unrest in the summer of 1998. (3) Mount Pinatubo where early drying out prevented SO2(g) scrubbing before the climactic 15 June 1991 eruption. (4) The ongoing eruption at Popocatépetl in an arid region of Mexico where there is little evidence of scrubbing.In most eruptive cycles, the impact of scrubbing will be greater during pre- and post-eruptive periods than during the main eruptive and intense passive degassing stages. Therefore, we recommend monitoring the following gases: CO2(g) and H2S(g) in precursory stages; CO2(g), H2S(g), SO2(g), HCl(g), and HF(g) in eruptive and intense passive degassing stages; and CO2(g) and H2S(g) again in the declining stages. CO2(g) is clearly the main candidate for early emission rate monitoring, although significant early increases in the intensity and geographic distribution of H2S(g) emissions should be taken as an important sign of volcanic unrest and a potential precursor. Owing to the difficulty of extracting SO2(g) from hydrothermal waters, the emergence of >100 t/d (tons per day) of SO2(g) in addition to CO2(g) and H2S(g) should be taken as a criterion of magma intrusion. Finally, the modeling suggests that the interpretation of gas-ratio data requires a case-by-case evaluation since ratio changes can often be produced by several mechanisms; nevertheless, several gas ratios may provide useful indices for monitoring the drying out of gas pathways.  相似文献   

16.
The densely populated metropolitan area of Quito is located on the slopes of the active Guagua Pichincha volcano at only 10 km from the crater. Recently, the Italian Ministry of Foreign Affairs sponsored a project for the mitigation of volcanic hazard in this area. The geochemical study carried out as part of this project was aimed at constructing a geochemical model of the zone for use in volcanic surveillance.According to this geochemical model, a hydrothermal aquifer (T = 200–240°C), fed both by meteoric waters and by fluids released by a magma body, lies at shallow levels beneath Guagua Pichincha crater. The crater fumaroles are essentially fed by steam boiled off from the hydrothermal aquifer. The high flow rate fumaroles located in the dome area show significant SO2 contents, which suggest a relatively high contribution of magmatic fluids in the zone of the aquifer feeding them. The absence of SO2 in the fumarolic discharges near the southern crater wall indicates instead that the magmatic fluids dissolve entirely into the aquifer here. The hot springs located at the western end of the crater represent the lateral discharge of the hydrothermal aquifer.On the basis of this model, it is likely that an increment in the flux of both the magmatic fluids and the heat from a magma body produces an increase, albeit small, of the pressure-temperature conditions of the hydrothermal system and consequent changes in flow rate and fluid chemistry of the fumarolic vents. In particular, total sulphur and possibly hydrochloric acid may increase in all the vents and sulphur dioxide may appear in other fumarolic discharges. The varying thermodynamic conditions in the hydrothermal aquifer can be evaluated on the basis of the equilibria among carbon species and hydrogen. Only minor delayed changes are expected in the physical-chemical characteristics of the springs located at the western end of the crater.  相似文献   

17.
Comparison of the chemical characteristics of spring and river water draining the flanks of Poa´s Volcano, Costa Rica indicates that acid chloride sulfate springs of the northwestern flank of the volcano are derived by leakage and mixing of acid brines formed in the summit hydrothermal system with dilute flank groundwater. Acid chloride sulfate waters of the Rio Agrio drainage basin on the northwestern flank are the only waters on Poa´s that are affected by leakage of acid brines from the summit hydrothermal system. Acid sulfate waters found on the northwestern flank are produced by the interaction of surface and shallow groundwater with dry and wet acid deposition of SO2 and H2SO4 aerosols, respectively. The acid deposition is caused by a plume of acid gases that is released by a shallow magma body located beneath the active crater of Poa´s.No evidence for a deep reservoir of neutral pH sodium chloride brine is found at Poa´s. The lack of discharge of sodium chloride waters at Poa´s is attributed to two factors: (1) the presence of a relatively volatile-rich magma body degassing at shallow depths (< 1 km) into a high level summit groundwater system; and (2) the hydrologic structure of the volcano in which high rates of recharge combine with rapid lateral flow of shallow groundwater to prevent deep-seated sodium chloride fluids from ascending to the surface. The shallow depth of the volatile-rich magma results in the degassing of large quantities of SO2 and HCl. These gases are readily hydrolyzed and quickly mix with meteoric water to form a reservoir of acid chloride-sulfate brine in the summit hydrothermal system. High recharge rates and steep hydraulic gradients associated with elevated topographic features of the summit region promote lateral flow of acid brines generated in the summit hydrothermal system. However, the same high recharge rates and steep hydraulic gradients prevent lateral flow of deep-seated fluids, thereby masking the presence of any sodium chloride brines that may exist in deeper parts of the volcanic edifice.Structural, stratigraphic, and topographic features of Poa´s Volcano are critical in restricting flow of acid brines to the northwestern flank of the volcano. A permeable lava-lahar sequence that outcrops in the Rio Agrio drainage basin forms a hydraulic conduit between the crater lake and acid chloride sulfate springs. Spring water residence times are estimated from tritium data and indicate that flow of acid brines from the active crater to the Rio Agrio source springs is relatively rapid (3 to 17 years). Hydraulic conductivity values of the lava-lahar sequence calculated from residence time estimates range from 10−5 to 10−7 m/s. These values are consistent with hydraulic conductivity values determined by aquifer tests of fractured and porous lava/pyroclastic sequences at the base of the northwestern flank of the volcano.Fluxes of dissolved rock-forming elements in Rio Agrio indicate that approximately 4300 and 1650 m3 of rock are removed annually from the northwest flank aquifer and the active crater hydrothermal system, respectively. Over the lifetime of the hydrothermal system (100's to 1000's of years), significant increases in aquifer porosity and permeability should occur, in marked contrast to the reduction in permeability that often accompanies hydrothermal alteration in less acidic systems. Average fluxes of fluoride, chloride and sulfur calculated from discharge and compositional data collected in the Rio Agrio drainage basin over the period 1988–1990 are approximately 2, 38 and 30 metric tons/day. These fluxes should be representative of minimum volatile release rates at Poa´s in the last 10 to 20 years.  相似文献   

18.
Santa Ana volcano in western El Salvador, Central America, had a phreatic eruption at 8:05 am (local time) on October 1, 2005, 101 years after its last eruption. However, during the last one hundred years this volcano has presented periods of quiet degassing with fumarolic activity and an acidic lake within its crater. This paper presents results of frequent measurements of SO2 degassing using the MiniDOAS (Differential Optical Absorption Spectroscopy) system and a comparison with the volcanic seismicity prior to the eruption, during, and after the eruption. Vehicle measurements of SO2 flux were taken every hour during the first nine days of the eruption and daily after that. The period of time reported here is from August to December, 2005. Three periods of degassing are distinguished: pre-eruptive, eruptive, and post-eruptive periods. The intense activity at Santa Ana volcano started in July 2005. During the pre-eruptive period up to 4306 and 5154 ton/day of SO2 flux were recorded on October 24 and September 9, 2005, respectively. These values were of the same order of magnitude as the recorded values just after the October 1st eruption (2925 ton/day at 10:01 am). Hourly measurements of SO2 flux taken during the first nine days after the main eruptive event indicate that explosions are preceded by an increase in SO2 flux and that this parameter reaches a peak after the explosion took place. This behavior suggests that increasing accumulation of exsolved magmatic gases occurs within the magmatic chamber before the explosions, increasing the pressure until the point of explosion. A correlation between SO2 fluxes and RSAM (Real Time Seismic Amplitude Measurements) is observed during the complete sampling period. Periodic fluctuations in the SO2 and RSAM values during the entire study period are observed. One possible mechanism explaining these fluctuations it that convective circulation within the magmatic chamber can bring fresh magma periodically to shallow levels, allowing increasing degasification and then decreasing degasification as the batch of magma lowers its gas content, becomes denser, and sinks to give space to a new magma pulse. These results illustrate that the measurements of SO2 flux can provide important warning signals for incoming explosive activity in active volcanoes.  相似文献   

19.
Ambae (also known as Aoba), is a 38 × 16 km2 lozenge-shaped island volcano with a coastal population of around 10 000. At the summit of the volcano is lake Voui — one of the largest active crater lakes worldwide, with 40 × 106 m3 of acidic water perched 1400 m a.s.l. After more than 300 years of dormancy, Ambae volcano reawakened with phreatic eruptions through Voui in 1995, and culminating in a series of surtseyan eruptions in 2005, followed by a rapid and spectacular colour change of the lake from light blue to red in 2006. Integrating lake water chemistry with new measurements of SO2 emissions from the volcano during the 2005–2006 eruptive period helps to explain the unusual and spectacular volcanic activity of Ambae — initially, a degassed magma approached the lake bed and triggered the surtseyan eruption. Depressurization of the conduit facilitated ascent of volatile-rich magma from the deeper plumbing system. The construction of a cone during eruption and the high degassing destabilised the equilibrium of lake stratification leading to a limnic event and subsequently the spectacular colour change.  相似文献   

20.
The eruptions of Nevado del Ruiz in 1985 were unusually rich in sulfur dioxide. These eruptions were observed with the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) which can quantitatively map volcanic sulfur dioxide plumes on a global scale. A small eruption, originally believed to be of phreatic origin, took place on September 11, 1985. However, substantial amounts of sulfur dioxide from this eruption were detected with TOMS on the following day. The total mass of SO2, approximately 9 ± 3 × 104 metric tons, was deposited in two clouds, one in the upper troposphere, the other possibly at 15 km near the stratosphere.The devastating November 13 eruptions were first observed with TOMS at 1150 EST on November 14. Large amounts of sulfur dioxide were found in an arc extending 1100 km from south of Ruiz northeastward to the Gulf of Venezuela and as an isolated cloud centered at 7°N on the Colombia-Venezuela border. On November 15 the plume extended over 2700 km from the Pacific Ocean off the Colombia coast to Barbados, while the isolated mass was located over the Brazil-Guyana border, approximately 1600 km due east of the volcano. Based on wind data from Panama, most of the sulfur dioxide was located at 10–16 km in the troposphere and a small amount was quite likely deposited in the stratosphere at an altitude above 24 km.The total mass of sulfur dioxide in the eruption clouds was approximately 6.6 ± 1.9 × 105 metric tons on November 14. When combined with quiescent sulfur dioxide emissions during this period, the ratio of sulfur dioxide to erupted magma from Ruiz was an order of magnitude greater than in the 1982 eruption of El Chichon or the 1980 eruption of Mount St. Helens.  相似文献   

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