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1.
Distributions and magnitude of metals in water, sediment and soil collected from the watershed and estuarine areas of southern Bohai Sea, were investigated. The largest dissolved concentrations of As, Cu and Zn in water were 347.70, 2755.00, 2076.00 μg/L, respectively, much higher than corresponding drinking water guidelines. The greatest concentrations of Cu, Zn, Cr, Ni, Pb, As and Cd in sediments were 1462.2, 1602.17, 196.43, 67.15, 63.54, 73.86 and 1.41 mg/kg, dw, respectively. The mean concentrations of Cu, Ni, Cd, Zn, Cr, Pb and As in soils were 24.67, 24.73, 0.14, 64.75, 56.52, 25.12 and 9.34 mg/kg, dw, respectively. Land use was confirmed to be an important factor of influence on soil metal concentrations. Metal contents along the watershed of Jie River were significantly greater than in other locations. The detection of metals in relatively high concentrations from different environmental matrices in this region indicates the necessity of further studies.  相似文献   

2.
The use of reclaimed water and its impact on groundwater quality in the middle and southern parts of the Jordan Valley are investigated. The chemical analyses indicate that nitrate and bacteriological pollution is widespread, and thus, seriously affects groundwater use. During the study, 365 water samples were collected from wells and springs to determine the water chemistry and the extent of nitrate pollution. Three hydrochemical facies are identifed, i. e., (Ca–(Mg)–Na–HCO3), (Ca–Na–SO4–Cl) and (Ca–Na–Cl). The change of facies is accompanied by a gradual increase in the groundwater total dissolved solids (TDS), which is mainly controlled by evaporates and carbonates dissolution in the aquifer matrix. Water analyses indicate that the shallow aquifer in the study area is affected by non‐point pollution sources, primarily from natural (manure) and chemical nitrogen (N)‐fertilizers and treated wastewater used for agriculture. The concentration of nitrate in the groundwater ranges from 10 to 355 mg/L. Considerable seasonal fluctuations in groundwater quality are observed as a consequence of agricultural practices and other factors such as annual rainfall distribution and the Zarqa River flow. The noticeable levels of total coliform and Escherichia coli in the northern part of the study area may be attributed to contamination from the urban areas, intensive livestock production, and illegal dumping of sewage. Heavy metal concentrations in all samples were found to be significantly lower than the permissible limits for drinking water standards.  相似文献   

3.
Despite the regulatory mandate to maintain “natural water quality”, there are ?271 storm drain discharges that potentially threaten the 14 designated marine water quality protected areas in Southern California called Areas of Special Biological Significance (ASBS). After sampling 35 site-events, the geomean concentrations of total suspended solids, nutrients, total and dissolved trace metals, and polycyclic aromatic hydrocarbons in the ocean following storm events were similar between reference drainages and ASBS discharge sites. Concentrations of chlorinated hydrocarbons were nondetectable and no post-storm sample exhibited significant toxicity to the endemic purple sea urchin (Strongylocentrotus purpuratus) near ASBS discharge sites. A reference-based threshold was developed and, despite the similarities in average concentrations, there were some individual ASBS discharge sites that were greater than reference background. Cumulatively across all ASBS, the constituents that were most frequently greater than the reference-based threshold were nutrients and general constituents, followed by dissolved and total trace metals.  相似文献   

4.
In many smallholder farms in sub-Saharan Africa dambos are used for grazing and crop production especially horticultural crops. Increased use of dambos especially for crop production can result in ground and surface water pollution. Ground and surface water quality along a dambo transect in Chihota, Zimbabwe, was investigated between October 2013 and February 2014. The transect was divided into; upland (control), dambo gardens (mid-slope) and the river (valley bottom). Water samples for quality assessment were collected in October 2013 (peak of dry season) and February 2014 (peak of rainy season). The collected water samples were analysed for pH, faecal coliforms, total nitrogen, electrical conductivity, total dissolved solids (TDS), and some selected nutrients (P, K, Ca, Mg, Na, Zn, and Cu). Water pH was 7.0, 6.4 and 6.1 for river water, garden and upland wells respectively. During the wet season total nitrogen (TN) concentrations were 233 mg/L for uplands, 242 mg/L for gardens and 141 mg/L for the river. During the dry season, TN concentrations were all below 20 mg/L, and were not significantly different among sampling stations along the dambo transect. Dry season faecal coliform units (fcu) were significantly different and were 37.2, 30.0 and 5.0 for upland wells, garden wells and river respectively. Wet season faecal coliforms were also significantly different and were 428.5, 258.0 and 479.4 fcu for upland wells, garden wells and river respectively. The other measured physico-chemical parameters also varied with sampling position along the transect. It was concluded that TN and fcu in sampled water varied with season and that wet season concentrations were significantly higher than dry season concentrations. High concentrations of faecal coliforms and total N during the wet season was attributed to increased water movement. Water from upland wells, garden wells and river was not suitable for human consumption according to WHO standards during both the dry and wet seasons.  相似文献   

5.
The Odra river flood of 1997 was a rare hydrological as well as an interesting sedimentological event. At Hohenwutzen (Lower Odra River) we observed the suspended particulate matter transport and the temporal development of water and solidsπ pollution with heavy metals and As. While the suspended particulate matter concentration decreased the trace element concentrations increased during the flood by fractionation of particles and solution processes. Because of a successive flooding of differently contaminated sedimentary sources and polluted regions the contents of heavy metals developed irregularly. Their median particulate concentrations did not exceed the values of older samples taken under mean discharge conditions between 1989 and 1995. The dissolved amounts correspond to those of the Elbe river in 1990. During the flood the dissolved share of all analyzed total element contents increased. The total loads increased 4fold (Cr) to 17fold (Cd).  相似文献   

6.
The water quality of a marine embayment (Brown Bay) was monitored during the remediation of an abandoned waste disposal site at Casey Station, East Antarctica, using a combination of biomonitoring and chemical methods. The Antarctic amphipod Paramoera walkeri, in field mesocosms suspended in the water column, was deployed adjacent to the site and at two reference sites for periods of 14 days, repeated three times during the remediation period (December to February). Diffusive gradients in thin film (DGT) samplers were deployed for the same periods to provide estimates of dissolved metals. No difference in mortality of amphipods was observed between Brown Bay and reference sites. There were significant differences, however, in accumulated metal concentrations between amphipods from Brown Bay and reference sites, with greater concentrations of antimony, copper, cadmium, lead, iron and tin at Brown Bay. The melt water/runoff treatment strategy employed for the remediation was successful in preventing acute toxic effects, but water quality was reduced at Brown Bay, where increased metal bioavailability may have been high enough to induce chronic effects in some biota. DGT samplers were less sensitive than amphipods in detecting differences in metal concentrations between sites, indicating that metals bound to suspended particulates were a potentially significant source of contamination.  相似文献   

7.
The Batu Hijau copper–gold mine on the island of Sumbawa, Indonesia operates a deep-sea tailings placement (DSTP) facility to dispose of the tailings within the offshore Senunu Canyon. The concentrations of trace metals in tailings, waters, and sediments from locations in the vicinity of the DSTP were determined during surveys in 2004 and 2009. In coastal and deep seawater samples from Alas Strait and the South Coast of Sumbawa, the dissolved concentrations of Ag, As, Cd, Cr, Hg, Pb and Zn were in the sub μg/L range. Dissolved copper concentrations ranged from 0.05 to 0.65 μg/L for all depths at these sites. Dissolved copper concentrations were the highest in the bottom-water from within the tailings plume inside Senunu Canyon, with up to 6.5 μg Cu/L measured in close proximity to the tailings discharge. In general, the concentrations of dissolved and particulate metals were similar in 2004 and 2009.  相似文献   

8.
李传琼  王鹏  陈波  李燕 《湖泊科学》2018,30(1):139-149
于2015年1月和7月在赣江干流和主要支流37个采样点共采集74个水样,分析赣江水系15种溶解态金属元素(Be、Al、V、Mn、Fe、Co、Ni、Cu、As、Mo、Cd、Sb、Tl、Pb、U)的空间分布特征和污染来源的贡献率.结果表明:多数水样的溶解态金属元素浓度符合水质标准,主要的超标元素是Fe,样品超标率为21.60%,其次为As(8.10%)、Mn(4.05%)、Tl(4.05%)和Al(1.35%).Be、Al、V、Fe、Co、Ni、Cu、U浓度在枯水期显著高于丰水期,其他元素差异不显著.依据溶解态金属元素的空间分布特征,赣江流域可分为3个区域:湘水、章水和赣江赣州市段(C1),桃江、袁水和锦江(C2),其他区域(C3);溶解态金属元素水平大小排序为C1C2C3,其中Be、Al、Cu、Mo、Sb、As浓度在C1最高,V、Mn、Fe、Ni、Cd浓度在C2最高.采矿废水、矿渣和农田土壤降雨淋滤、钢铁冶炼废水是赣江溶解金属元素的主要来源;Be、Al、Cu、Pb、U的污染源超过40%来自采矿废水,Cu、As、Mo、Cd的污染源超过35%来自矿渣和农田土壤降雨淋滤,V、Mn、Co、Ni的污染源超过41%来自钢铁冶炼废水.  相似文献   

9.
Samples of raw water were collected in the St. Lawrence River during six sampling trips from August 1990 to April 1992. Water samples were analyzed for both dissolved and particulate phases for five trace metals. Partition coefficients (Kd) and metal fluxes were calculated in order to determine metal transport. A mass balance equation was used for the determination of the major metal sources to the St. Lawrence River and an estimation of metal loadings to the estuary was made. Average dissolved metal concentrations were found to be Cd 10 ng/L, Co 74 ng/L, Cu 64 ng/L, Fe 69 µg/L and Mn 700 ng/L. Particulate concentrations were (in µg/g) 1.68 for Cd, 31 for Co, 73 for Cu, 25 mg/g for Fe and 1.69 mg/g for Mn. Co, Fe and Mn were transported essentially in the particulate phase while Cd and Cu were predominantly found in the dissolved phase at 56% and 48% of the total metal concentration respectively. Log Kd values varied from 5.1 (for Cu) to 6.8 (for Mn). In the dissolved phase the major sources were found to be the Great Lakes and the Ottawa River whereas in the particulate phase Québec tributaries appear to be the most important. Industrial inputs are quite important in both the dissolved and the particulate phases for Cd, whereas other sources are very variable, especially for the dissolved phase.  相似文献   

10.
In this study, remediation results of trace metals in natural water and treated water using three functionalized nanofiber mats of cellulose and chitosan are reported. The nanofiber materials, packed in mini-columns, were employed for the remediation of five toxic trace metals (Cd, Pb, Cu, Cr and Ni) from natural water samples. Trace metals in real water samples were undetectable as the concentrations were lower than the instrument’s detection limits of 0.27 × 10−3 (Cd) and 4.2 × 10−2 (Pb) μg mL−1, respectively. However, after percolation through the functionalised biosorbents in cartridges, detectability of the metal ions was enhanced. The starting volume of the natural water sample was 100 mL, which was passed through a column containing the nanofibers sorbent and the retained metals eluted with 5 mL of 2.0 M nitric acid. The eluate was analyzed for metals concentrations. An enrichment factor of 20 for the metals was realized as a result of the pre-concentration procedure applied to handle the determination of the metals at trace levels. The order of remediation of the studied metals using the nanofibers was as follows: chitosan/PAM-g-furan-2,5-dione < cellulose-g-furan-2,5-dione < cellulose-g-oxolane-2,5-dione. The modified biopolymer nanofibers were able to adsorb trace metals from the river water and treated water, thereby confirming their capability of water purification. These materials are proposed as useful tools and innovative approach for improving the quality of drinking for those consumers in small scale households.  相似文献   

11.
The ability of seven hyperaccumulator macrophytes which grow naturally in the heavy metal contaminated channels of three different industries (Hindustan Aeronautical Ltd., Eveready Ltd., and Scooter India Ltd.) to accumulate heavy metals was recorded. All these industries use electroplating processes in their manufacturing and are located in the inner area of Lucknow City, U.P., India. Of the three industries monitored, effluent released from Eveready Ltd. contained the highest concentration of heavy metals. In general, accumulations of heavy metals depend upon the plant species and the metal concentration in the media. All plant samples showed heterogeneous metal accumulations, except for Fe or Cd. It was observed that some plant species accumulated high level of metals, e. g., Eichhornnia crassipes for Fe (4052.44 μg/g), Mn (788.42 μg/g), and Cu (315.50 μg/g), and Spirodela polyrhiza for Cd (12.75 μg/g), Pb (20.25 μg/g), and Cr (128.27 μg/g), even when the metal concentrations were not high in the effluent. In summary, these two plants were found to be the best accumulators at each contaminated site. The results will be helpful in the selection of plant species which can be used as bioaccumulators or bioindicators.  相似文献   

12.
Dissolved oxygen (D.O.) concentration has a significant effect upon ground water quality by regulating the valence state of trace metals and by constraining the bacterial metabolism of dissolved organic species. For these reasons, the measurement of dissolved oxygen concentration should be considered essential in most water quality investigations. D.O. measurements have been frequently neglected in ground water monitoring. This is because O2 has often been assumed absent below the water table; measurement of O2, concentrations is not mandated by drinking water standards; and the redox potential has previously been considered an adequate and encompassing electrochemical measurement. Redox potentials, however, cannot adequately predict dissolved oxygen concentrations nor can D.O. concentrations be used to calculate redox potentials.
D.O. concentrations can be measured precisely in the field by titration or electrode methods. The best methods of sample recovery are those that use positive pressure displacement devices. A fully adequate sampling procedure will isolate ground water from the atmosphere and will collect samples at restricted depth intervals at ambient temperature and pressure.  相似文献   

13.
Metal pollutants in water poses great threats to living beings and hence requires to be monitored regularly to avoid loss of lives. Various analytical methods are available to monitor these pollutants in water and can be improved with time. Modelling of metal pollutants in any water system helps chemists, engineers and environmentalists to greatly understand the various chemical processes in such systems. Water samples were collected from waste water treatment plant and river from highlands close to its source all the way to the ocean as it passing through areas with high anthropogenic activities. Pre-concentration of pollutants in the samples was done through acid digestion and metal pollutants were analysed using inductively coupled plasma-optical emission spectra (ICP-OES) to determine the concentration levels. Metal concentrations ranged between 0.1356–0.4658 mg/L for Al; 0.0031–0.0050 mg/L for Co, 0.0019–0.0956 mg/L for Cr; 0.0028–0.3484 mg/L for Cu; 0.0489–0.3474 mg/L for Fe; 0.0033–0.0285 mg/L for Mn; 0.0056–0.0222 mg/L for Ni; 0.0265–0.4753 mg/L for Pb and 0.0052–0.5594 mg/L for Zn. Modelling work was performed using PHREEQC couple with Geochemist’s workbench (GWB) to determine speciation dynamics and bioavailability of these pollutants. Modelling thus adds value to analytical methods and hence a better complementary tool to laboratory-based experimental studies.  相似文献   

14.
Plastic production pellets sampled from four beaches along a stretch of coastline (south Devon, SW England) and accompanying, loosely adhered and entrapped material removed ultrasonically have been analysed for major metals (Al, Fe, Mn) and trace metals (Cu, Zn, Pb, Ag, Cd, Co, Cr, Mo, Sb, Sn, U) following acid digestion. In most cases, metal concentrations in composite pellet samples from each site were less than but within an order of magnitude of corresponding concentrations in the pooled extraneous materials. However, normalisation of data with respect to Al revealed enrichment of Cd and Pb in plastic pellets at two sites. These observations are not wholly due to the association of pellets with fine material that is resistant to ultrasonication since new polyethylene pellets suspended in a harbour for 8 weeks accumulated metals from sea water through adsorption and precipitation. The environmental implications and potential applications of these findings are discussed.  相似文献   

15.
To compare water quality in rivers of developed and developing countries, a study based on physicochemical parameters and dissolved metals levels was conducted. Water samples were collected from selected sites in Dhaka, Bangladesh; Hokkaido and Osaka, Japan; Erdenet, Mongolia and West Java, Indonesia. Analysis of least significant differences revealed that most water quality parameters were within comparable low levels in both developed and developing countries. The dissolved metals concentrations were found to be similar and below those of water standards except for manganese and cadmium at every sampling point, and lead in Erdenet, Mongolia. Some metals showed high enrichment factors in the rivers of Osaka, Japan and Erdenet, Mongolia, indicating accumulation possibility of metals in the river‐bed sediments. High concentrations of dissolved organic carbon, Escherichia coli and dissolved metals suggested greater water pollution in some rivers of developing countries than in the rivers of Japan. Principal component analysis showed strong correlations between “dissolved organic carbon and chemical oxygen demand” and “conductivity and total dissolved solids” at each sampling point, and E. coli, nitrate (NO), nitrite (NO), and pH levels were found to be higher in the rivers of Dhaka and Erdenet. In addition, there were high levels of Al and Zn in West Java, Pb in Erdenet, and Mn, Fe, and Cr in the rivers of Dhaka and Japan. Based on pressures and impacts, it is evident that dissolved metal, organic, and fecal pollution in the rivers of developing countries are in somewhat dreadful condition in comparison with the rivers of developed country.  相似文献   

16.
The risk that benzene and toluene from spills of gasoline will impact drinking water wells is largely controlled by the natural anaerobic biodegradation of benzene and toluene. Benzene and toluene, as well as ethanol and other biofuels, are degraded under anaerobic conditions to the same pool of degradation products. Biodegradation of biofuels may produce concentrations of degradation products that make the thermodynamics for degradation of benzene and toluene infeasible under methanogenic conditions and produce larger plumes of benzene and toluene. This study evaluated the concentrations of fuel alcohols that are necessary to inhibit the anaerobic degradation of benzene and toluene under methanogenic conditions. At two ethanol spill sites, concentrations of ethanol greater ≥42 mg/L inhibited the anaerobic degradation of toluene. The pH and concentrations of acetate, dissolved inorganic carbon, and molecular hydrogen were used to calculate the Gibbs free energy for the biodegradation of toluene. In general, the anaerobic biodegradation of toluene was not thermodynamically feasible in water with ≥42 mg/L ethanol. In a microcosm study, when the concentrations of ethanol were ≥14 mg/L or the concentrations of n‐butanol were ≥16 mg/L, the biodegradation of the alcohols consistently produced concentrations of hydrogen, dissolved inorganic carbon, and acetate that would preclude natural anaerobic biodegradation of benzene and toluene by syntrophic organisms. In contrast, iso‐butanol and n‐propanol only occasionally produced conditions that would preclude the biodegradation of benzene and toluene.  相似文献   

17.
Trace metal retention in mangrove ecosystems in Guanabara Bay,SE Brazil   总被引：1，自引：0，他引：1  
Along contrasting environmental conditions (e.g., degree of trace metal contamination and mangrove forest structural development), sediments of Laguncularia racemosa-dominated mangrove stands in Guanabara Bay (SE Brazil) presented a trend of trace metal accumulation in forms with low potential of remobilization and biotic uptake. Concurrently, a relatively low transfer of sediment-bound metals to L. racemosa leaves was observed, which may moderate the metal export from the forests via leaf litter transport and the metal availability to enter in food chains based on leaf consumption.  相似文献   

18.
Hydrocarbon and nonhydrocarbon components dissolving in water from fresh diesel and field samples of highly weathered diesel (spilled up to 50 years ago) from two sites were investigated. The fresh and weathered diesels were equilibrated with water using a slow-stirring method, and the product and equilibrated aqueous water samples analyzed by a range of analytical procedures. The water phase equilibrated with weathered diesels had higher total dissolved organics concentrations (96 and 8.6 mg/L at the two sites) compared to the water phase equilibrated with fresh diesel (average of 3.4 mg/L). Compound class characterization of dissolved organics in water from the weathered diesel showed that polar components were a significant compound class (98% and 42% at the two sites) and appeared largely as an unresolved complex mixture (UCM) in the total ion chromatograms (TICs). Identification of 1-adamantanol in the polar fraction of both weathered diesel samples (3.6 and 0.3 μg/L at the two sites) suggested that at least some of the associated polar components are from a petroleum source. The analysis of total petroleum hydrocarbons (TPH) is aimed at measuring only dissolved carbon and hydrogen-containing compounds, and dissolved polar compounds present as a UCM are often assumed to be from natural organic matter (NOM) and removed. This may result in a gross underestimation of the total soluble organic material in water associated with weathered diesels. In addition, the risk posed by these fuel-derived polar compounds is unknown.  相似文献   

19.
The influence of large‐scale mining operations on groundwater quality was investigated in this study. Trace element concentrations in groundwater samples from the North Mara mining area of northern Tanzania were analyzed. Statistical analyses for relationships between elemental concentrations in the samples and distance of a sampling site from the mine tailings dam were also conducted. Eleven trace elements (Al, As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) were determined, and averages of Fe and Al concentrations were higher than levels accepted by the Tanzanian drinking water guideline. Levels of Pb in three samples were higher than the World Health Organization (WHO) and United States Environmental Protection Agency (USEPA) drinking water guidelines of 10 and 15 µg/L, respectively. One sample contained a higher As level than the WHO and USEPA guideline of 10 µg/L. The correlation between element concentrations and distance from the mine tailings dam was examined using the hierarchical agglomeration cluster analysis method. A significant difference in the elemental concentration existed depending on the distance from the mine tailings dam. Mann–Whitney U‐test post hoc analysis confirmed a relationship between element concentration and distance of a sampling site from the mine tailings dam. This relationship raises concerns about the increased risks of trace elements to people and ecosystem health. A metal pollution index also suggested a relationship between elemental concentrations in the groundwater and the sampling sites’ proximity from the mine tailings dam.  相似文献   

20.
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