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1.
INTRODUCTIONBecause many P/ T boundary sections around the worldare stratigraphically unconformed,som e possible exceptionsdeveloped in Greenland,Iran,Russia and South China are ofcourse of international importance.Especially successive sedi-ments from the L ate Paleozoic to Early Mesozoic widely ap-peared in South China,for example,the Meishan Section inChangxing County,Zhejiang Province,and som e analogies inGuangyuan,Wulong and Shangsi counties,Sichuan Province.Some geologists…  相似文献   

2.
Trace fossils namely, Planolites, Planolites montanus, Thalassinoides and stuff burrows belonging to the Lameta Formation of Central India are reported for the first time from two new localities, i.e., Salbardi and Belkher area. Both the exposures are well represented by the typical marker lithounits as of Jabalpur, Nand-Dongargaon area of central India, i.e., greenish yellow sandstone, clays of various shades, chertified and brecciated limestones, etc. These successions are devoid of megaforal remains, therefore, these biogenic structures play a significant role in the interpretation of palaeoenvironment and palaeoecology during the deposition of the Lameta sediments. The trace fossils assemblage shows that the benthonic community was mainly polychaetes and crustaceans.  相似文献   

3.
Geochemical and isotopic analyses of the Cretaceous–Paleogene (K/Pg) boundary deposits were conducted at the Caravaca section (External Subbetic, southeast of Spain) in order to evaluate the recovery of the macrobenthic tracemaker community and the bioturbational disturbance. Samples from the infilling material of several lower Danian dark-colored trace fossils (Chondrites, Planolites, Thalassinoides and Zoophycos) located in the uppermost 8-cm of the light upper Maastrichtian strata, as well as samples from the host sedimentary rock of these trace fossils, were analyzed and compared with data from the lower Danian deposits. The values of element ratios indicative of extraterrestrial contamination (Cr/Al, Co/Al and Ni/Al) are higher in the infilling trace fossil material than in the upper Maastrichtian and lower Danian deposits, which suggests a contribution of the ejecta layer. Regarding the isotope composition, the δ13C values are lower in the infilling material than in the Maastrichtian host sedimentary rocks surrounding the traces, while the δ18O are higher in the infilling material. The geochemical and isotopic compositions of the infilling material evidence the unconsolidated character of the sediment, including the red boundary layer. Softground conditions confirm a relatively rapid recovery by the macrobenthic tracemaker community, starting a few millimeters above the K/Pg boundary layer. The mixture of the infilling material of the trace fossils moreover reveals a significant macrobenthic tracemaker activity affecting K–Pg boundary transition sediments that may have significantly altered original signatures.  相似文献   

4.
We have made oxygen and carbon isotope measurements on limestone samples of Albian to Eocene age recovered from the Bottaccione Gorge section in the Umbrian Apennines, central Italy. Additional measurements have been made on topmost Maastrichtian and Palaeocene sediments from the adjacent Contessa Highway section. Our data from the Bottaccione Gorge show 13C maxima at the Cenomanian/Turonian boundary and during the Palaeocene, as well as a pronounced 13C minimum 7 metres above the clay layer at the K/T boundary. Our data from the Contessa Highway show a 13C minimum 9 metres above the K/T boundary clay. These minima are probably diagenetic artifacts. In the Bottaccione Gorge there is evidence for a hiatus in the early Middle Eocene. The Palaeocene of the Bottaccione Gorge appears to have been affected by slumping or faulting (in addition to the diagenetic overprinting) giving a spurious δ13C recovery after the K/T boundary, the Contessa Highway section appears to be more complete. The Coniacian-Maastrictian is characterized by relatively stable 13C values. Our data indicate an increase in δ18O (and therefore possible cooling) across the Cretaceous/Tertiary boundary in both the Bottaccione and Contessa Highway sections.  相似文献   

5.
Chemical analysis of nine Deccan flow basalts at Anjar, Kutch, western India, indicates that all, except the uppermost flow F-9, are alkaline. In their major and trace element composition, the alkali basalts resemble Ocean island basalts (OIB). Similarities of many diagnostic trace element ratios (e.g. Sm/Nd, Ba/Nb,Y/Nb and Zr/Nb) are similar to those found in the Réunion Island basalts. The uppermost basalt is tholeiitic and chemically resembles the least contaminated Deccan basalt (Ambenali type). The Anjar basalts have iridium concentration ranging between 2 and 178 pg/g. Some of these values are higher by about an order of magnitude compared to the Ir concentration in other basalts of the Deccan. A synthesis of chemical, palaeomagnetic and geochronologic data enables us to construct a chemical and magnetic stratigraphy for these flows. The three flows below the iridium enriched intertrappean bed (IT III) show normal magnetic polarity whereas all except one of the upper basalts show reversed magnetic polarity. The sequence seems to have started in polarity zones 31N and probably continued up to 28R or 27R. The results presented here support the view that Deccan volcanism in Kutch occurred on a time span of a few million years.  相似文献   

6.
We report here for the first time the presence of the natural, toluene-soluble C60 and the toluene-insoluble high-pressure and temperature phase of fullerene C60 in the carbonaceous matter extracted from the iridium-rich layers of the intertrappean sediments of Anjar, India. The toluene-insoluble form of fullerene is formed at high-temperature and pressure (HPT) and is distinguished from normal fullerene by UV-visible and Fourier-transform infrared (FT-IR) spectroscopic techniques. The C60 fullerene has been identified by high-resolution electron-impact ionization mass spectrometric analysis, as well as by Fourier-transform infrared (FT-IR), UV-visible, and 13C-nuclear magnetic resonance (NMR) spectroscopy. In iridium-poor horizons of this section, fullerenes are absent, but complex hydrocarbons are sometimes present. The FT-IR spectroscopic studies on the insoluble fullerenes show strong absorption peaks at about 740 and 509 cm−1 and a number of weak peaks at 1380, 1300, 1205, 1120, 1000, 608, 554, and 441 cm−1, which are characteristic of a high-pressure and temperature C60 fullerene. The UV-visible spectra of the toluene-soluble fullerene, as well as the insoluble fullerene, show strong absorption bands at 270 and 348 nm, which are characteristic of pristine fullerene C60. The toluene-insoluble carbon-rich residue shows additional absorption bands at 710, 640, and 395 nm. These UV-visible bands independently confirm the presence of the high-pressure-temperature (HPT) phase of fullerene C60. Conditions of high-pressure and temperature required for formation of the HPT fullerene phase can be created by an energetic impact event. Therefore, the presence of HPT fullerene in the KT boundary layer at Anjar is linked to the impact event at the KT transition.  相似文献   

7.
In Jabalpur area about 18 m to 45 m thick Lameta Formation is stratigraphically divisible into five lithounits namely, Green Sandstone, Lower Limestone, Mottled Nodular Beds, Upper Limestone and Upper Sandstone. Having differentiated lithofacies constitution and here grouped as facies associations, these units are intensively burrowed and sparingly fossiliferous. Ichnogenera including Arenicolites, Calycraterion, Fucusopsis, Laevicyclus, Macanopsis, Ophiomorpha, Paleomeandron, Rhizocorallium, Stipsellus, Thalassinoides and Zoophycos are recovered from the Lower Limestone, Mottled Nodular Beds and Upper Limestone associations of the Lameta Formation of Jabalpur area.Among these, Arenicolites, Calycraterion, Laevicyclus, Ophiomorpha, Rhizocorallium, Stipsellus and Thalassinoides belong to mixed Skolithos and Cruziana ichnofacies and indicate sandy backshore to sublittoral condition of deposition. Additionally rhyzocretes, some times chertified, are also present in different parts of the Lameta Formation. Ichnofacies assemblage supported by sedimentological information suggests that the Lameta Formation of Jabalpur area was deposited in coastal marine settings where sediments were subaerially exposed intermittently.  相似文献   

8.
The mineral composition and U-Pb and Rb-Sr systematics of phosphorites from the Satka Formation of Lower Riphean carbonates, the Burzyan Group of Southern Urals, are studied. Phosphorites occurring as small lenses between stromatolite layers are composed largely of fluorapatite with admixture of detrital quartz, feldspars, illite, and chlorite. Phosphorite samples have been subjected to stepwise dissolution in 1 N (fraction L-1) and 2 N (fraction L-2) HCl. As is established, the maximum apatite content is characteristic of fraction L-1, while fraction L-2 is enriched in products of dolomite and sulfide dissolution and in elements leached from siliciclastic components. The Sr content in the Satka apatites (280–560 ppm) is substantially lower as compared with that in unaltered marine apatite. The 87Sr/86Sr “initial ratio in the phosphorites studied (0.71705–0.72484) and host dolomites from the lower part of the Satka Formation is significantly higher than in the Early Riphean seawater that indicates a reset of the Rb-Sr original systems in sediments. The Pb-Pb age of 1340 ± 30 Ma (MSWD = 6.4) estimated based on 7 data points characterizing fractions L-1 and L-2 is younger than the formation time of overlying Burzyan sediments, being consistent, within the error range, with date of the Mashak rifting event recorded at the Early-Middle Riphean boundary. The comparative U-Pb characteristics of two soluble fractions (L-1 and L-2) and silicate residue of phosphorites show that epigenetic redistribution of Pb and U was characteristic of the phosphorite horizon only. The initial Pb isotope composition and μ (238U/204Pb) estimated according to model by Stacey and Kramers for the early diagenetic fluids in carbonate and phosphate sediments of the Satka Formation suggest that they were in isotopic equilibrium with erosion products of the Taratash crystalline complex.  相似文献   

9.
Paleomagnetic records of declination and inclination from sediments recovered from the bed of Lake Kinneret (32.4°N, 35.7°E) have been dated by radiocarbon techniques. The sediments span the last 5000 yr. The changes in inclination down the sediment cores are more pronounced than the declination fluctuations and are repeatable between the three coring sites, which are several kilometers apart. Magnetic susceptibility logs display 13 maxima in the 5-m-long sequences, with a pronounced susceptibility minimum about 1000 yr B.P. Many of the susceptibility maxima and minima can be easily correlated between coring sites and are shown to be dominantly related to changes in sediment carbonate content. The natural remanent magnetization intensity follows a similar pattern to that of susceptibility, and the natural remanence of the Kinneret sediments is presumed to reside in detrital magnetite grains carried into the lake by the river Jordan from the basalt-rich bedrock of the rift floor and the Golan Heights. The 14C chronology is strongly supported by a pollen study in which pronounced changes in the proportion of olive pollen were interpreted as being due to extensive cultivation of olives around Galilee in the Hellenistic and Byzantine periods. The Kinneret paleosecular variation records, if accurately dated, point to a complex spatial pattern of Holocene secular variation with significant variations over distances as small as 1000–2000 km.  相似文献   

10.
The geochemistry of formation waters in the Molasse basin of Upper Austria has been investigated to ascertain the extent of meteoric water replacement of the connate interstitial fluids in these sediments. The chemistry, isotopic composition, and dissolved gas contents of the groundwaters and of oil and gas associated brines have been determined. The most superficial sediments of the basin, the Innviertel (Miocene), have been completely flushed by meteoric waters within the last 200 ka. The underlying Hall and Puchkirchen formations (Miocene/Oligocene) form gas reservoirs for biogenic methane, and the associated formation waters are chemically and isotopically modified connate brines of the original marine deposition. In the northeastern part of the basin, the connate brines of the deeper sediments (Cretaceous/Jurassic) have been partially or completely replaced by meteoric waters, whereas in the south of the basin these sediments contain high salinity fluids which are substantially of connate origin. These conclusions are supported by the stable isotope composition of the various brines. Oil-associated brines from the Eocene sediments contain large amounts of dissolved radiogenic40Ar, which suggests that the oils have migrated from high-temperature environments. This is in contrast with the Puchkirchen, for which the observed absence of radiogenic40Ar suggests that the biogenic methane has been formed in situ. The4He contents of these brines and of the Cretaceous/Jurassic groundwaters are, however, less than those in the overlying Puchkirchen formation and suggest that He has been removed from the deeper sediments as a result of flushing by meteoric water. The ratios of dissolved methane and nitrogen to argon increase with increasing ammonium content of the formation waters. All of these parameters may be used as indices for the maturation of the system. The heavy noble gases, Kr and Xe, are abnormally abundant in the dissolved gases, and this is attributed to geochemical concentration of these gases by adsorption onto shales in the sediment sequence. The overall geochemical situation confirms the existence of separate hydraulic systems with little interconnection in the several overlying geological horizons.  相似文献   

11.
He-Ar isotopic compositions of fluid inclusions trapped in pyrites from some representative PGE-polymetallic deposits in Lower Cambrian black rock series in South China were analyzed by using an inert gas isotopic mass spectrometer. The results show that the ore-forming fluids possess a low 3He/4He ratio, varying from 0.43×10-8 to 26.39×10-8, with corresponding R/Ra value of 0.003-0.189. The 40Ar/36Ar ratios are 258-287, close to those of air saturated water (ASW). He-Ar isotopic indicator studies show that the ore-forming fluids were mainly derived from the formation water or basinal hot brine and sea water, while the content of mantle-derived fluid or deep-derived magmatic water might be negligible. The PGE-polymetallic mineralization might be related to the evolution of the Caledonian miogeosynclines distributed along the southern margin of the Yangtze Craton. During the Early Cambrian, the formation water or basinal hot brine trapped in Caledonian basins which accumulated giant thick sediments was  相似文献   

12.
The water–sediment interface is a dynamic zone where the benthic and pelagic environments are linked through exchange and recycling of organic matter and nutrients. However, it is often difficult to measure rate processes in this zone. To that end, we designed an experimental apparatus for continuous and homogeneous perfusion of sediment porewater with dissolved conservative (SF6, Rhodamine WT dye) and isotopic (H13CO3− and 15NH4+) tracers to study nitrogen and carbon cycling by the sediment microbial community of shallow illuminated sediments. The perfusionator consists of a 60-cm ID × 60-cm high cylinder that includes a reservoir for porewater at the base of the sediment column. Porewater amended with conservative and stable isotopic tracers was pumped through a mixing reservoir and upward through the overlying sediments. We tested the perfusionator in a laboratory setting, as part of an outdoor mesocosm array, and buried in coastal sediments. Conservative and isotopic tracers demonstrated that the porewater tracers were distributed homogeneously through the sediment column in all settings. The perfusionator was designed to introduce dissolved stable isotope tracers but is capable of delivering any dissolved ionic, organic, or gaseous constituent. We see a potentially wide application of this technique in the aquatic and marine sciences in laboratory and field settings.  相似文献   

13.
四川茂县较场剖面厚101.1m,其中湖相沉积厚98.0m,为一套浅黄色-灰色的粉砂、粘土质粉砂和粉砂质粘土层。古地磁测试显示,除2个样品的磁偏角显示负极性外,其余样品的磁偏角全部为正,属布容正极性时,没有出现B/M界线。根据该套地层的岩性、岩相和所处的地貌部位,可以和云南金沙江谷地的龙街组对比,推测其开始沉积的时代为100~120 kaBP.另外,距顶4.0 m处光释光年龄为16.7±1.2 kaBP,推测其结束于10kaBP.湖相沉积历时约100kaBP,是岷江流域出露的末次(间)冰期以来厚度最大的剖面之一。   相似文献   

14.
This paper presents new SHRIMP zircon U–Pb chronology, major and trace element, and Sr–Nd–Hf isotopic data of two Early Paleozoic granitic plutons (Yierba and North Kudi) from the western Kunlun orogen, in attempt to further constrain the Proto-Tethys evolution. SHRIMP zircon U–Pb dating shows that the Yierba pluton was emplaced in the Middle Cambrian (513?±?7 Ma) and the North Kudi pluton was emplaced in the Late Silurian (420.6?±?6.3 Ma). The Yierba pluton consists of quartz monzodiorite, quartz monzonite and granodiorite. These granitoids are metaluminous and potassic, with initial 87Sr/86Sr ratios of 0.7072–0.7096, εNd (T) of ?0.2 to ?1.6 and εHf (T) (in-situ zircon) of ?1.2. Elemental and isotopic data suggest that they were formed by partial melting of subducted sediments, with subsequent melts interacting with the overlying mantle wedge in an oceanic island arc setting in response to the intra-oceanic subduction of Proto-Tethys. The North Kudi pluton consists of syenogranite and alkali-feldspar granite. These granites are metaluminous to weakly peraluminous and potassic. They show an affinity of A1 subtype granite, with initial 87Sr/86Sr ratios of 0.7077–0.7101, εNd (T) of ?3.5 to ?4.0 and εHf (T) (in-situ zircon) of ?3.9. Elemental and isotopic data suggest that they were formed by partial melting of the Precambrian metamorphic basement at a shallow depth (<30 km) during the post-orogenic regime caused by Proto-Tethyan oceanic slab break-off. Our new data suggest that the subduction of the Proto-Tethyan oceanic crust was as early as Middle Cambrian (～513 Ma) and the final closure of Proto-Tethys was not later than Late Silurian (～421 Ma), most probably in Middle Silurian.  相似文献   

15.
Oxygen and carbon stable isotopes and 25 elements were determined in the undisturbed K/T boundary profile of a flysch succession in the Soča Valley, Slovenia. The elemental enrichment and stable isotope anomalies are not confined strictly to the biostratigraphically defined K/T boundary. The relatively weak metal enrichment, which is probably due to the high sedimentation rate at the time of deposition of the K/T transition sequence, was found in a clayey layer and in the boundary clayey mar] 15 cm and 5 cm above the boundary, while the negative shift in δ18O and δ13C of carbonates was restricted to the basal part of the boundary clayey marl, approximately 5 cm below the boundary. It is postulated that elemental and isotopic anomalies are probably related to the supposed, so far poorly investigated impact of an extraterrestrial body in the Gorski Kotar area of Croatia.  相似文献   

16.
Reported here are the first 187Os/188Os ratios and abundances of Os and Re for Taklimakan Desert sands and glacial moraines from the Kunlun Mountains. Osmium isotopic data are also reported for river sediments around the Taklimakan Desert, river sediments from the Kunlun and Tianshan Mountains, Tibetan soils and loesses from the Loess Plateau, as well as Sr and Nd isotopic data for these samples. The Taklimakan Desert sands from various regions show surprisingly homogeneous Os isotopic ratios (187Os/188Os = 1.29 ± 0.08) and abundances (Os = 11 ppt), with some variations in Re abundances (Re = 130 to 260 ppt) and 187Re/188Os ratios (60 to 140). The 187Os/188Os ratios for the Taklimakan Desert sands are close to the average for Kunlun moraines, river sediments around the Taklimakan Desert sands, and the Tibetan soils, supporting the idea that the Taklimakan Desert sands are derived from moraines and river sediments around the desert or from Tibetan soils and are homogenized by aeolian activity in the desert. Furthermore, the Os isotopic data for the sediments studied here are compared with those (187Os/188Os = 1.04, Os = 32 ppt, Re = 206 ppt, 187Re/188Os = 35) of loesses from the Loess Plateau reported elsewhere, and it is concluded that the Re-Os data for the loess can be used as proxy for the upper continental crust.  相似文献   

17.
粤西阳春中生代钾玄质侵入岩及其构造意义：   总被引：28，自引：0，他引：28  
粤西阳春地区马山二长闪长岩强烈富集K、Sr和LREE，(87Sr／86Sr)；≈0.7046，εNd(t)≈+1；岗尾-轮水岩体较富集K、Rb、Th和LREE，(87Sr／86Sr)：≈0.7063，εNd(t)≈-2；石岩体较富集Sr，K、Rb、Th和LREE相对较低，(87Sr／86Sr);=0.7084～0.7089，εNd(t)≈-6。马山岩体来源于大离子亲石元素(ULE)和LREE富集的交代地幔；岗尾-轮水岩体来自于放射成因Sr、Nd同位素组成略高或交代时间略早的富集交代地幔，并且经历了明显的结晶分异作用；石岩体则很可能是前存下地壳底垫基性岩重熔形成的。从早侏罗世到早白垩世，南岭西部的岩浆成分和源区的规律性变化反映了区域软流圈地幔上涌和岩石圈伸展-拉张-减薄的演化过程。  相似文献   

18.
《Chemical Geology》2007,236(3-4):181-198
Variations in molybdenum isotopic composition, spanning the range of ∼ 2.3‰ in the terms of 97Mo/95Mo ratio, have been measured in sediment cores from three lakes in northern Sweden and north-western Russia. These variations have been produced by both isotopically variable input of Mo into the lakes due to Mo isotopic heterogeneity of bedrock in the drainage basins and fractionation in the lake systems due to temporal variations in limnological conditions. Mo isotope abundances of bedrock in the lake drainage basins have been documented by analysis of Mo isotope ratios of a suite of molybdenite occurrences collected in the studied area and of detrital fractions of the lake sediment cores. The median δ97Mo value of the investigated molybdenites is 0.26‰ with standard deviation of 0.43‰ (n = 19), whereas the median δ97Mo value of detrital sediment fractions from two lakes is − 0.40‰ with standard deviation of 0.36‰ (n = 15).The isotopic composition of Mo in the sediment cores has been found to be dependent on redox conditions of the water columns and the dominant type of scavenging phases. Hydrous Fe oxides have been shown to be an efficient scavenger of Mo from porewater under oxic conditions. Oxidative precipitation of Fe(II) in the sediments resulted in co-precipitation of Mo and significant authigenic enrichment at the redox boundary. In spite of a pronounced increase in Mo concentration associated with Fe oxides at the redox boundary the isotopic composition of Mo in this zone varies insignificantly, suggesting little or no isotope fractionation during scavenging of Mo by hydrous Fe oxides. In a lake with anoxic bottom water a chironomid-inferred reconstruction of O2 conditions in the bottom water through the Holocene indicates that increased O2 concentrations are generally associated with low δ97Mo/95Mo values of the sediments, whereas lowered O2 contents of the bottom water are accompanied by relatively high δ97Mo/95Mo values, thus confirming the potential of Mo isotope data to be a proxy for redox conditions of overlying waters. However, it is pointed out that other processes including input of isotopically heterogeneous Mo and Mn cycling in the redox-stratified water column can be a primary cause of variations in Mo isotopic compositions of lake sediments.  相似文献   

19.
The redox cycle of iron and manganese is a major geochemica process at the boundary layers of lake sediments.Lake Aha,which lies in the suburbs of Guiyang City,Guizhou Province,China,is a medium-sized artificial reservoir with seasonally anoxic hypolimnion,Long-term sedimentary accumulation of iron and manganese resulted in their enrichment in the upper sediments,In the anoxic season,Fe^2 and Mn^2 ,formed by diological oxidation,would diffuse up to overlying waters from sediments.However,the concentration of oxidation,would diffuse up to overlying waters from sediments,However,the concentration of Fe^2 increased later and decreased earlier than that of Mn^2 .Generally,sulfate reduction occurred at 6 cm below the sediment-water interface.Whereas,in the anoxic season.the reduction reached upper sediments,inhibiting the release of Fe^2 ,The Fe concentration of anoxic water is quickly decreased from high to low as a result of reduction of the suplhur system.  相似文献   

20.
Analyses of Lower Permian or older basalts and associated dykes of the Juchatengo sequence indicate that they are rift tholeiites that formed in a continental rift or back-arc tectonic setting. Age constraints include a Middle Permian fossil recovered from the tectonically overlying sediments and a cross-cutting, post-tectonic pluton dated by K/Ar on hornblende at 282±6 Ma. A location adjacent to the Oaxacan Complex or other old continental crust is suggested by (1) an Ndi isotopic value of −8.95 and a TDM age of 1487 Ma in the overlying sediments, which are similar to the Oaxacan Complex; (2) enrichment of incompatible elements in the lavas, suggesting old crustal contamination; and (3) the presence of Permian–Triassic calc-alkaline plutons that stitch the Juchatengo–Oaxaca boundary. The possible tectonic models depend on the age of the Juchatengo basalts, which requires future geochronological work. If the Juchatengo basalts are Permo-Carboniferous, they could have formed near the eastern edge of a back-arc basin: the contemporaneous arc would have rifted away to the west. Eastward migration of the arc magmatism indicated by the Permian–Triassic calc-alkaline plutonism may reflect shallowing of the dip of the subduction zone, which probably also produced the deformation of the Juchatengo sequence.  相似文献   

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