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1.
Unlike the studies in small parcels by systematic measurements, the spatial variability of soil properties is expected to increase in those over relatively large areas or scales. Spatial variability of soil hydraulic conductivity (K h) is of significance for the environmental processes, such as soil erosion, plant growth, transport of the plant nutrients in a soil profile and ground water levels. However, its variability is not much and sufficiently known at basin scale. A study of testing the performance of cokriging of K h compared with that of kriging was conducted in the catchment area of Sarayköy II Irrigation Dam in Cank?r?, Turkey. A total of 300 soil surface samples (0–10 cm) were collected from the catchment with irregular intervals. Of the selected soil properties, because the water-stable aggregates (WSA) indicated the highest relationship with the hydraulic conductivity by the Pearson correlation analysis, it is used as an auxiliary variable to predict K h by the cokriging procedure. In addition, the sampling density was reduced randomly to n = 175, n = 150, n = 75 and n = 50 for K h to determine if the superiority of cokriging over kriging would exist. Statistically, the results showed that all reduced K h was as good as the complete K h when its auxiliary relations with WSA were used in cokriging. Particularly, the results of the “Relative Reduction in MSE” (RMSE) revealed that the reduced data set of n = 75 produced the most accurate map than the others. In this basin-scaled study, there was a clear superiority of the cokriging procedure by the reduction in data although a very undulating topography and topographically different aspects, two different land uses with non-uniform vegetation density, different parent materials and soil textures were present in the area. Hence, using the statistically significant auxiliary relationship between K h and WSA might bring about a very useful data set for watershed hydrological researches.  相似文献   

2.
This paper investigates, using the random field theory and Monte Carlo simulation, the effects of random field discretization on failure probability, p f, and failure mechanism of cohesive soil slope stability. The spatial sizes of the discretized elements in random field Δx, Δy in horizontal and vertical directions, respectively, are assigned a series of combinational values in order to model the discretization accuracy. The p f of deterministic critical slip surface (DCSS) and that of the slope system both are analyzed. The numerical simulation results have demonstrated that both the ratios of Δy/λ y (λ y  = scale of fluctuation in vertical direction) and Δx/λ x (λ x  = scale of fluctuation in horizontal direction) contribute in a similar manner to the accuracy of p f of DCSS. The effect of random field discretization on the p f can be negligible if both the ratios of Δx/λ x and Δy/λ y are no greater than 0.1. The normalized discrepancy tends to increase at a linear rate with Δy/λ y when Δx/λ x is larger than 0.1, and vice versa for p f of DCSS. The random field discretization tends to have more considerable influence on the p f of DCSS than on that of the slope system. The variation of p f versus λ x and λ y may exhibit opposite trends for the cases where the limit state functions of slope failure are defined on DCSS and on the slope system as well. Finally, the p f of slope system converges in a more rapid manner to that of DCSS than the failure mechanism does to DCSS as the spatial variability of soil property grows from significant to negligible.  相似文献   

3.
Mass movements in tropical Pacific small island developing states (SIDS) can be devastating although studies are relatively few and contributing environmental factors are not often investigated in detail. On 25 January 2012, following 3 days of heavy monsoonal rainfall (c. 550 mm) during a La Niña episode, more than 150 debris flows were triggered in the western part of the Ba river catchment of northwest Viti Levu island, Fiji. Reconnaissance field survey and geographical information system (GIS) analyses using high-resolution satellite imagery were carried out to investigate factors that may have led to the occurrence of the debris flows in the catchment. We evaluated the correlation between the density of mass movements (number of mass movements/km2) and several continuous variables using data measured within the GIS. There was a weak but significant positive correlation between mass movement density and elevation (r = 0.38, p value < 0.01), cyclonic precipitation (r = 0.37, p value < 0.01) and stream density (r = 0.31, p value < 0.01). Ninety-three percent of the mass movements occur within a plantation of Pinus caribaea (Caribbean pine) on slopes oriented mainly to the northeast and east on (trade) windward slopes and may be significant factors for their development. Although forests generally have a stabilizing effect on slopes, the plantation at Ba was a mature stand on its second plantation cycle and is a species that has a shallow rooting system making it more susceptible to failure.  相似文献   

4.
Because of economic and technical limitations, measuring solar energy received at ground level (R s ) isn’t possible in all parts of the country, and in only 12% of synoptic stations is this parameter measured and recorded. Thus, it should be estimated and modeled spatially based on other climatic variables using mathematical methods. In this research, many attempts have been made to introduce an air temperature-based model for Rs estimation, and then, based on the output of the mentioned models, several geostatistical methods have been tested, and finally an elegant spatial model is proposed for (Rs) zoning in Iran. In this regard, the relationships between the measured amounts of monthly solar radiation and other climatic parameters, such as a monthly average, maximum and minimum temperature, precipitation, relative humidity, and the number of sunny hours during the period 1970–2010, are examined and modeled. It was revealed that based on the linear relationship between the monthly average air temperatures and solar radiation values recorded in each of the stations, that the best-fit linear model, with R 2  = 0.822, MAE = 1.81, RMSE = 2.51%, and MAPE = 10.08, can be introduced for Rs estimation. Then, using the outputs of the proposed model, the amounts of (R s ) are estimated in another 171 meteorological stations (a total of 192 stations), and eight geostatistical methods (IDW, GPI, RBF, LPI, OK, SK, UK, and EBK) were investigated for zoning. Comparing the resulting variograms showed that in addition to proof of spatial correlation between solar radiation data, they can be applied for modeling changes in various directions. Analyzing the ratio of the nugget effect on the roof of the variograms showed that the Gaussian model with the lowest ratio (Co/Co + C = 0.883) and (R 2  = 0.972), could model the highest correlation between the data and, therefore, it was used for data interpolation. To select the best geostatistical model, R2, MAE, and RMSE were used. On this basis, it was found that the RBF method with R 2  = 0.904, MAE = 3.02, RMSE = 0.39% is the most effective. Also, the IDW method with R 2  = 0.90, MAE = 3.08, RMSE = 0.391%, compared to other methods is the most effective. In addition, for data validation, correlations between observed and estimated values of solar radiation were studied and found R 2  = 0.86.  相似文献   

5.
As soft rocks are likely to soften, slime and swell while contacting water, the existence of soft rocks is harmful for stability of surrounding rocks and supporting structures of tunnels. Through uniaxial and triaxial tests under dry condition and triaxial test with different moisture contents, the mechanical properties and failure modes of soft rocks were studied under conditions that the schistosity plane of the rock samples was vertical to, presented an oblique angle with, and paralleled to the loading direction. The results showed that peak strengths in natural and water-bearing states increased with increasing confining pressures, while those in water-bearing state were 40% lower than those in natural state. The samples were mainly subjected to ductile failure in both natural and water-bearing states while the samples in natural state exhibited a certain brittle failure characteristic in post-peak phase. With the increase of confining pressures, the post-peak curve gradually became gentle after certain brittle failure while the post-peak stresses had an insignificant change. In comparison, the samples in water-bearing state showed significant post-peak disparity, that is, exhibited strong ductile failure characteristic. Moreover, the fitting relationship between triaxial compressive strength and moisture of soft rocks can be expresses as σ 1 = Aω + B (A < 0, B > 0) while that between elasticity modulus and moisture can be expresses as E = Aω + B (A < 0, B > 0).  相似文献   

6.
Acacia nilotica was used for the adsorption of Reactive Black 5 (RB5) dye from an aqueous solution. Both the raw and activated (with H3PO4) carbon forms of Acacia nilotica (RAN and ANAC, respectively) were used for comparison. Various parameters (including dye concentration, contact time, temperature, and pH) were optimized to obtain the maximum adsorption capacity. RAN and ANAC were characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The maximum experimental adsorption capacities for RAN and ANAC were 34.79 and 41.01 mg g?1, respectively, which agreed with the maximum adsorption capacities predicted by the Langmuir, Freundlich, and Dubinin–Radushkevich equilibrium isotherm models. The adsorption data of ANAC showed a good fit to the isotherm models based on the coefficient of determination (R 2): Langmuir type II (R 2 = 0.99) > Freundlich (R 2 = 0.9853) > Dubinin–Radushkevich (R 2 = 0.9659). This result suggested monolayer adsorption of RB5 dye. The adsorption of RB5 dye followed pseudo-second-order kinetics. The RAN adsorbent reflected an exothermic reaction (enthalpy change, ΔH = ?0.006 kJ mol?1) and increased randomness (standard entropy change, ΔS = 0.038 kJ mol?1) at the solid–solution interface. In contrast, ANAC reflected both exothermic [?0.011 kJ mol?1 (303–313 K)] and endothermic [0.003 kJ mol?1 (313–323 K)] reactions. However, the ΔS value of ANAC was lower when the RB5 adsorption increased from 313 to 323 K. The negative values for the Gibbs free energy change at all temperatures indicated that the adsorption of RB5 dye onto RAN and ANAC was spontaneous in the forward direction.  相似文献   

7.
In many petroleum-producing regions, there are not adequate controls to prevent pipeline breaks and spills, and thus soil is frequently contaminated with petroleum hydrocarbons. Different petroleum oil compounds may produce negative impacts on soil fertility. In this study, four fresh crudes, a weathered petroleum, and oils from bioremediated and burned sites were investigated (specific gravities 0.83–1.27). Fourier transform infrared spectroscopy revealed three predominant polar functional groups to be more plentiful in the heavier crudes. The relative abundance of these groups was used to calculate an index that was directly correlated with specific gravity (R 2 = 0.9960) and the percent of asphaltene plus (polars + resins) fractions in the oil (R 2 = 0.9643). This index correlated exponentially to the water repellency caused by petroleum in an alluvial soil (R 2 = 0.9928). Furthermore, extra-heavy oil at a concentration of 10,000 ppm, the maximum allowable oil concentration in the soil that is within regulatory norms in many US states and other countries, and with a specific gravity >1.002, showed severe water repellency. This study presents an alternative for determining soil remediation criteria based on the API gravity of the oil rather than the C-range of the hydrocarbon mixtures, simplifying analytical methods and systematically studying the interaction between the kinds of petroleum mixtures and potential impacts to soil fertility.  相似文献   

8.
In this work, we estimated soil moisture (SM) by using dielectric constant properties of soil with radar backscattering coefficient (bc) from simulated annealing techniques of RISAT-1 (radar imaging satellite, based on synthetic aperture radar (SAR) technique) data. We examined the performance of simulated annealing in retrieving SM where the vegetation cover is not very high (NDVI ≈ 0.35 for wheat-dominated area on January 19, 2013).To overcome the land surface model limits on SM estimation accuracy, point measurement spatial coverage limits, and microwave remote sensing spatial-temporal sampling limits, we reduced uncertainties through a combination of these approaches. Near-surface SM measurements from the 5.35-GHz (C-band) channels of RISAT-1 were collocated against ground-truth data (collected during the flight time of RISAT-1 over the study area), to establish SAR-SM relationships for FRS-1(circular horizontal (RH) and circular vertical (RV)) data set of RISAT-1. Comparison with the limited ground-based point (total 24 points) measurements of SM content exhibited a net improvement when near-surface SM observations were assimilated. Comparison of the SM derived from the sigma naught (σ 0) (of RISAT-1 data set FRS-1) using the inversion algorithm with the observed measurements (using time domain reflectometry) of SM showed root mean square error of 0.24, nRMSE = 0.03, R-RMSE = 0.38, MAE = 0.63, NRMSE = 1.02, NSE = 1, d = 0.87, r 2 = 0.65, and RMSE% = 12.79 for RH polarized image while RV polarized image failed each statistical test for predicting good SM with respect to the observed SM. The ability to extract additional information comes at the expense of including more measurements, especially at frequencies lower than the L-band. This approach is therefore intended for future space-borne systems.  相似文献   

9.
Soil particle-size distribution (PSD) is an important index for soil classification because it has large influences on soil hydrological characteristics, salinity, fertility, erodibility, nutrient content, swelling/shrinking, and degradation. We present a case study of the fractal characteristics of soil PSD and its relationship with soil properties of gravel-mulched fields in an arid area of northwestern China using single-fractal calculation. Particle size was unimodally distributed within the narrow range of 20–100 μm, with silt as the most common component. Horizontally, silt content was the highest, followed by sand and clay contents. Vertically, clay content increased with depth, while there were no obvious change rules for both silt and sand contents. The volume fractal dimension (D) of PSD ranged from 2.4307 to 2.5260, increased with the content of fine particles but decreased with the content of coarse particles. D was correlated positively with soil-water content and salt content and negatively with bulk density. The saturated soil-water content was strongly correlated negatively with silt content (p < 0.01) and positively with sand content (p < 0.01). The results indicate that D can be a potential indicator of the physical and chemical properties of soil and can also provide a theoretical basis and technical guidance for the effective use and management of the region.  相似文献   

10.
The thermal evolution of 10-Å phase Mg3Si4O10(OH)2·H2O, a phyllosilicate which may have an important role in the storage/release of water in subducting slabs, was studied by X-ray single-crystal diffraction in the temperature range 116–293 K. The lattice parameters were measured at several intervals both on cooling and heating. The structural model was refined with intensity data collected at 116 K and compared to the model refined at room temperature. As expected for a layer silicate on cooling in this temperature range, the a and b lattice parameters undergo a small linear decrease, α a  = 1.7(4) 10?6 K?1 and α b  = 1.9(4) 10?6 K?1, where α is the linear thermal expansion coefficient. The greater variation is along the c axis and can be modeled with the second order polynomial c T  = c 293(1 + 6.7(4)10?5 K?1ΔT + 9.5(2.5)10?8 K?2(ΔT)2) where ΔT = T ? 293 K; the monoclinic angle β slightly increased. The cell volume thermal expansion can be modeled with the polynomial V T  = V 293 (1 + 8.0 10?5 K?1 ΔT + 1.4 10?7 K?2 (ΔT)2) where ΔT = T ? 293 is in K and V in Å3. These variations were similar to those expected for a pressure increase, indicating that T and P effects are approximately inverse. The least-squares refinement with intensity data measured at 116 K shows that the volume of the SiO4 tetrahedra does not change significantly, whereas the volume of the Mg octahedra slightly decreases. To adjust for the increased misfit between the tetrahedral and octahedral sheets, the tetrahedral rotation angle α changes from 0.58° to 1.38°, increasing the ditrigonalization of the silicate sheet. This deformation has implications on the H-bonds between the water molecule and the basal oxygen atoms. Furthermore, the highly anisotropic thermal ellipsoid of the H2O oxygen indicates positional disorder, similar to the disorder observed at room temperature. The low-temperature results support the hypothesis that the disorder is static. It can be modeled with a splitting of the interlayer oxygen site with a statistical distribution of the H2O molecules into two positions, 0.6 Å apart. The resulting shortest Obas–OW distances are 2.97 Å, with a significant shortening with respect to the value at room temperature. The low-temperature behavior of the H-bond system is consistent with that hypothesized at high pressure on the basis of the Raman spectra evolution with P.  相似文献   

11.
To evaluate the impact of invading seagrass on biogeochemical processes associated with sulfur cycles, we investigated the geochemical properties and sulfate reduction rates (SRRs) in sediments inhabited by invasive warm affinity Halophila nipponica and indigenous cold affinity Zostera marina. A more positive relationship between SRR and below-ground biomass (BGB) was observed at the H. nipponica bed (SRR = 0.6809 × BGB ? 4.3162, r 2 = 0.9878, p = 0.0006) than at the Z. marina bed (SRR = 0.3470 × BGB ? 4.0341, r 2 = 0.7082, p = 0.0357). These results suggested that SR was more stimulated by the dissolved organic carbon (DOC) exuded from the roots of H. nipponica than by the DOC released from the roots of Z. marina. Despite the enhanced SR in spring-summer, the relatively lower proportion (average, 20%) of acid-volatile sulfur (AVS) in total reduced sulfur and the strong correlation between total oxalate-extractable Fe (Fe(oxal)) and chromium-reducible sulfur (CRS = 0.2321 × total Fe(oxal) + 1.8180, r 2 = 0.3344, p = 0.0076) in the sediments suggested the rapid re-oxidation of sulfide and precipitation of sulfide with Fe. The turnover rate of the AVS at the H. nipponica bed (0.13 day?1) was 2.5 times lower than that at the Z. marina bed (0.33 day?1). Together with lower AVS turnover, the stronger correlation of SRR to BGB in the H. nipponica bed suggests that the extension of H. nipponica resulting from the warming of seawater might provoke more sulfide accumulation in coastal sediments.  相似文献   

12.
Understanding the changes in permeability of soil, when soil is subjected to high confining pressure and flow pressure, which may alter the textural and geomechanical characteristics of soil, is of great importance to many geo-engineering activities such as, construction of high-rise buildings near the coast or the water bodies, earthen dams, pavement subgrades, reservoir, and shallow repositories. It is now possible to evaluate the changes in permeability of soil samples under varying conditions of confining pressure and flow pressure using flexible wall permeameter (FWP). In the present study, investigation was carried out on a cylindrical sample of granular soil employing FWP under varied conditions of confining pressure (σ3)—50–300 kPa, which can simulate the stress conditions equivalent to depth of about 20 m under the earth’s crust, and a flow pressure (fp)—20–120 kPa, which is mainly present near the small earthen embankment dams, landfill liners, and slurry walls near the soft granular soil with high groundwater table. The obtained results indicate a linear relationship between hydraulic conductivity (k) with effective confining pressure (σeff.), k, decreasing linearly with an incremental change in σeff.. Further, k increases significantly with an increase in fp corresponding to each σeff., and q increases significantly with increase in the fp corresponding to each (σ3). It was also observed that corresponding to the low fp of 20 kPa, the reduction in k is nonlinear with σ3. The percentage reduction in k is observed to be 9, 13, and 27% corresponding to σ3 of 50–100, 100–200, and 200-300 kPa, respectively.  相似文献   

13.
Effective soil thermal conductivity (λ eff) describes the ability of a multiphase soil to transmit heat by conduction under unit temperature gradient. It is a critical parameter for environmental science, earth and planetary science, and engineering applications. Numerous models are available in the literature, but their applicability is generally restricted to certain soil types or water contents (θ). The objective of this study was to develop a new model in the similar form of the Johansen 1975 model to simulate the λ eff(θ) relationship of soils of various soil textures and water contents. An exponential type model with two parameters is developed and a new function for calculating dry soil thermal conductivity is presented. Performance of the new model and six other normalized models were evaluated with published datasets. The results show that the new model is able to well mimic λ eff(θ) relationship of soils from sand to silt loam and from oven dry to full saturation. In addition, it has the best performance among the seven models under test (with root-mean-square error of 0.059 W m?1 °C?1, average deviations of 0.0009 W m?1 °C?1, and Nash–Sutcliffe efficiency of 0.994). The new model has potential to improve the reliability of soil thermal conductivity estimation and be incorporated into numerical modeling for environmental, earth and engineering studies.  相似文献   

14.
The aim of this research was to evaluate the potential of six legumes: Medicago sativa L., Glycine max, Arachis hypogea, Lablab purpureus, Pheseolus vulgaris and Cajanus cajan to restore within a short period of time soil contaminated with 3% crude oil. The legumes in five replications were grown in crude oil-contaminated and crude oil-uncontaminated soil in a completely randomized design. Plants were assessed for seedling emergence, plant height and leaf number. GC–MS was used to analyze the residual crude oil from the rhizosphere of the legumes. Plant growth parameters were reduced significantly (P < 0.05) for legumes in contaminated soil compared to their controls. In the 4th week after planting (WAP), shoot height increased across the species up to the 8th WAP. However, in the 12 WAP no significant increase in the shoot of all species was observed. Two WAP legumes planted in contaminated soil had significantly (P < 0.05) higher leaf number than these planted in uncontaminated soil with the exception of M. sativa. In the 4th WAP, only A. hypogea and P. vulgaris had increased leaf number, while in the 6th WAP, only L. purpureus had increased leaf number and survived up to the 12th WAP while most of the legumes species died. Chromatographic profiles indicated 100% degradation of the oil fractions in C. cajan and L. purpureus after 90 days. For other legumes however, greater losses of crude oil fractions C1–C10 and C10–C20 were indicated in rhizosphere soil of P. vulgaris and G. max, respectively. The most effective removal (93.66%) of C21–C30 components was observed in G. max-planted soil even though vegetation was not established. The legumes especially C. cajan, L. purpureus and A. hypogea are promising candidates for phytoremediation of petroleum hydrocarbon-impacted soil.  相似文献   

15.
Rapid increases in the amounts of fullerene C60 nanoparticles (nC60) being produced and used will inevitably lead to increases in the amounts released into the aquatic environment. This will have implications for human and ecosystem health. Wastewater treatment plants are key barriers to nC60 being released into aquatic systems, but little information is available on how adsorption processes in wastewater treatment plants affect the fates of nC60. We investigated the effects of the surface properties of activated sludge on the adsorption of nC60 and related mechanisms by modeling the adsorption kinetics and equilibrium process and performing correlation analyses. The adsorption of nC60 closely followed the pseudo-second-order kinetic model (R > 0.983), the Freundlich isotherm model (R > 0.990), and the linear partitioning isotherm model (R > 0.966). Different adsorption coefficients, 1.070–4.623 for the Freundlich partitioning model and 1.788–6.148 for the linear partitioning model, were found for different types of activated sludge. The adsorption coefficients significantly positively correlated with the zeta (ζ) potential (R = 0.877) and hydrophobicity (R = 0.661) and negatively correlated with particle size (R = ?0.750). The results show that nC60 adsorption is strongly affected by the surface properties of activated sludge because changes in surface properties cause changes in the electrostatic and hydrophobic interactions that occur.  相似文献   

16.
Performances of conventional and improved soil moisture balance as well as locally calibrated empirical models were evaluated in simulating potential recharge (R) and soil moisture content for a semi-arid foothill region. Models comparison with observed values using lysimeter data during [(2011–2012), (2012–2013)] reveal poor performance of conventional soil moisture balance model, underestimating annual R values. Improved soil moisture balance model provided acceptable estimation of annual R for 2011–2012 by considering the wetting of the near surface soil storage. However, it produced the worst simulation for daily soil moisture content once rainy season was over. Sensitivity analysis revealed that the precision degree of initial soil moisture deficit value would strongly influence estimation of R by improved soil moisture balance model, which can be viewed as a limiting factor. Additionally, locally calibrated model produced the best estimation of annual R and daily soil moisture content, which is suggested for the study region.  相似文献   

17.
The improvement in the capabilities of Landsat-8 imagery to retrieve bathymetric information in shallow coastal waters was examined. Landsat-8 images have an additional band named coastal/aerosol, Band 1: 435–451 nm in comparison with former generation of Landsat imagery. The selected Landsat-8 operational land image (OLI) was of Chabahar Bay, located in the southern part of Iran (acquired on February 22, 2014 in calm weather and relatively low turbidity). Accurate and high resolution bathymetric data from the study area, produced by field surveys using a single beam echo-sounder, were selected for calibrating the models and validating the results. Three methods, including traditional linear and ratio transform techniques, as well as a novel proposed integrated method, were used to determine depth values. All possible combinations of the three bands [coastal/aerosol (CB), blue (B), and green (G)] have been considered (11 options) using the traditional linear and ratio transform techniques, together with five model options for the integrated method. The accuracy of each model was assessed by comparing the determined bathymetric information with field measured values. The standard error of the estimates, correlation coefficients (R 2 ) for both calibration and validation points, and root mean square errors (RMSE) were calculated for all cases. When compared with the ratio transform method, the method employing linear transformation with a combination of CB, B, and G bands yielded more accurate results (standard error = 1.712 m, R 2 calibration = 0.594, R 2 validation = 0.551, and RMSE =1.80 m). Adding the CB band to the ratio transform methodology also dramatically increased the accuracy of the estimated depths, whereas this increment was not statistically significant when using the linear transform methodology. The integrated transform method in form of Depth = b 0  + b 1 X CB  + b 2 X B  + b 5 ln(R CB )/ln(R G ) + b 6 ln(R B )/ln(R G ) yielded the highest accuracy (standard error = 1.634 m, R 2 calibration = 0.634, R 2 validation = 0.595, and RMSE = 1.71 m), where R i (i = CB, B, or G) refers to atmospherically corrected reflectance values in the i th band [X i  = ln(R i -R deep water)].  相似文献   

18.
The elastic and structural behaviour of the synthetic zeolite CsAlSi5O12 (a = 16.753(4), b = 13.797(3) and c = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V 0 = 1,155(4) Å3, K T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a 3, b 3, c 3) for the volume. The refined axial-EoS parameters are: a 0 = 16.701(44) Å, K T0a = 14(2) GPa (βa = 0.024(3) GPa?1), K′ a = 6.2(8) for the a-axis; b 0 = 13.778(20) Å, K T0b = 21(3) GPa (βb = 0.016(2) GPa?1), K′ b = 10(2) for the b-axis; c 0 = 5.018(7) Å, K T0c = 33(3) GPa (βc = 0.010(1) GPa?1), K′ c = 3.2(8) for the c-axis (K T0a:K T0b:K T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at P ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi5O12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi5O12 allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes.  相似文献   

19.
Debris flow density determined by grain composition   总被引：1，自引：1，他引：0  
Density is one of the most important parameters of debris flows. Because observing an active debris flow is very difficult, finding a method to estimate debris flow density is urgently needed for disaster mitigation engineering. This paper proposes an effective empirical equation in terms of grain size distribution (GSD) parameters based on observations in Jiangjia Gully, Yunnan Province, China. We found that the GSD follows P(D) = KD -μ exp(? D/Dc), with μ and Dc representing the fine and coarse grains, respectively. In particular, μ is associated with some characteristic porosity of soil in the natural state and increases with increased porosity. Dc characterizes the grain size range of the flow and increases with the grain concentration. Studies show that flow density is related to both parameters in power law. Here, we propose an empirical equation for estimating flow density: ρ = 1.26μ -0.132 + 0.049Dc0.443, which provides not only an estimation of the density for a flow, but also describes the variation in density with the GSD of material composition; this provides important information related to the design of debris flow engineering structures.  相似文献   

20.
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