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1.
B.P. Glass 《Earth and Planetary Science Letters》1986,77(3-4)
Fission-track and40Ar—39Ar dating of Australasian tektites indicates that the australites are older than the rest of the Australasian tektites. Some authors have suggested, therefore, that there should be two microtektite layers in the Australasian region: a younger layer approximately synchronous with the Brunhes/Matuyama geomagnetic reversal boundary (previously described in the literature) and an older layer of Australian microtektites (micro-australites) below the Brunhes/Matuyama reversal boundary and perhaps associated with the end of the Jaramillo event. Fifteen cores already known to contain a layer of Australasian microtektites at or slightly above the Brunhes/Matuyama reversal boundary were searched for an 0.8 to 0.9 m.y. old micro-australite layer. No evidence for this layer was found. Thus, the data do not support the conclusion that the Australasian tektites were produced by two impact events at different times. 相似文献
2.
B.P. Glass R.N. Baker D. Storzer G.A. Wagner 《Earth and Planetary Science Letters》1973,19(2):184-192
Over 6000 microscopic glass spherules between 125 μm and 1 mm in diameter were found in a sediment core (RC9-58) from the Caribbean Sea. These glassy objects are mostly confined to a zone ～ 40 cm thick at a depth of ～ 250 cm. We believe that the microscopic glass objects are microtektites belonging to the North American strewnfield, based on their geographical location, appearance, physical properties, stratigraphic age (middle Upper Eocene), fission track age (～34.6 my) and major element compositions. The occurrence of North American microtektites in the Caribbean Sea indicates that the North American strewnfield is two to three times larger than previously indicated. An estimate on the abundance of microtektites in core RC9-58 indicates that the North American strewnfield may contain greater than 1017 g of tektite material. 相似文献
3.
Variations in the major cation ratios in the (micro-) tektites of each of the different strewn fields were studied with the help of Niggli parameters. There is a high degree of variability in almost each individual strewn field which, however, is not random. Invariably, as SiO2 increases the proportion of alumina and the alkalies among the cations increases, that ofMgO + ΣFeO (total iron as FeO) and CaO decreases; simultaneouslyK2O/Na2O increases whileMgO/FeO decreases. This is entirely analogous to magmatic differentiations and is incompatible with an explanation by mechanical mixing of sedimentary parent rocks. The picture can best be explained by partial melting, in analogy to fulgurites and combustion ultrametamorphic glasses.In some strewn fields (e.g. javaites, georgiaites, bediasites), all tektites formed from the same set of parent rocks. In these fields each cation parameter, when plotted against silica, follow a linear slightly curved path with a very small scatter (simple type). In others (e.g. moldavites, philippinites, australites) some or all cation parameters show a strong scatter which sometimes almost obliterates the differentiation trends. These complex diagrams can be reduced to 2–5 diagrams (lineages) of the simple type, each reflecting a different combination of parent rocks. Most lineages again show the influence of partial melting differentiation.If the chemical variations of tektites are caused by partial melting, the silica-poor end of each variation diagram (case of total melting) and not the average composition corresponds to the parent rock combination involved. Thus, neglecting losses by evaporation (which are minor), the chemical compositions of 25 starting materials were established. All except one of these can very closely be matched by a combination, in appropriate proportions, of only two of the most common sedimentary rocks. The only group which cannot be duplicated by a combination of any two sedimentary rocks are the bottle-green microtektites. 相似文献
4.
Sm-Nd and Rb-Sr analyses of tektites and other impactites can be used to place constraints on the age and provenance of target materials which were impact melted to form these objects. Tektites have large negative εNd(0) values and are uniform within each tektite group while the εSr(0) are large positive values and show considerable variation within each group. Chemical, trace element, and isotopic compositions of tektites are consistent with production by melting of sediments derived from old terrestrial continental crust. Each tektite group is characterized by a uniform Nd model age,TCHURNd, interpreted as the time of formation of the crustal segment which weathered to form the parent sediment for the tektites: (1) ～1.15 AE for Australasian tektites; (2) ～1.91 AE for Ivory Coast tektites; (3) ～0.9 AE for moldavites; (4) ～0.65 AE for North American tektites, and (5) ～0.9 AE for high-Si irghizites. Sr model ages,TURSr, are variable within each group reflecting Rb-Sr fractionation and in the favorable limit of very high Rb/Sr ratios, approach the time of sedimentation of the parent material which melted to form the tektites. Australasian tektites are derived from ～0.25 AE sediments, moldavites from ～0.0 AE sediments, Ivory Coast tektites from ～0.95 AE sediments. Possible parent sediments of other tektite groups have poorly constrained ages. Our data on moldavites and Ivory Coast tektites are consistent with derivation from the Ries and Bosumtwi craters, respectively. Irghizites are isotopically distinct from Australasian tektites and are probably not related. Sanidine spherules from a Cretaceous-Tertiary boundary clay have initial εNd ～ +2; εSr ～ +5 and are not derived from old continental crust or meteoritic feldspar. They may represent a mixture of basaltic oceanic crust and sediments, implying an oceanic impact. These isotopic results are also consistent with a volcanic origin for the spherules. 相似文献
5.
6.
Ivory Coast microtektites have recently been found in three piston cores from the Atlantic Ocean. In two of these cores, the microtektites occur in a layer above the base of the Jaramillo geomagnetic event indicating that they fell approximately 0.95 m.y. ago. Major element compositions have been obtained for forty-one of the microtektites by electron microprobe and energy-dispersive X-ray analysis. The geographic location, stratigraphic age and major element compositions indicate that these microtektites are part of the Ivory Coast tektite strewnfield. Present data suggest that the Ivory Coast strewnfield may cover an area of about 4.5 million square kilometers and contain about 20 million metric tons of microtektites. 相似文献
7.
W. Gentner T. Kirsten D. Storzer G.A. Wagner 《Earth and Planetary Science Letters》1973,20(2):204-210
Darwin Glasses from the recently discovered Darwin Crater in Tasmania were dated by the K-Ar and the fission track methods. The ages by both methods agree and yield a combined age of 0.73 ± 0.04 my for the formation of Darwin Crater and Darwin Glass by an impact. Since an accidental coincidence of this age with the age of Australasian tektites is rather unlikely, we suppose that Darwin Crater is one of many — primary or secondary — impact structures caused by the collision of a meteorite or comet with the earth ～ 0.7 my ago in the region of South East Asia and Australia. 相似文献
8.
The concentrations of several diagnostic trace elements were determined in two comparatively large NiFe spherules extracted from tektites. The purpose of the study was to obtain some clues about the chemistry of the projectile that is presumed responsible for the formation of these tektites. However, the trace element pattern is distinctly terrestrial implying that the spherules are the result of in-situ reduction of the host rock and are not meteoritic in origin. 相似文献
9.
Frederic Moynier Pierre Beck Fred Jourdan Qing-Zhu Yin Uwe Reimold Christian Koeberl 《Earth and Planetary Science Letters》2009,277(3-4):482-489
Tektites are terrestrial natural glasses produced during a hypervelocity impact of an extraterrestrial projectile onto the Earth's surface. The similarity between the chemical and isotopic compositions of tektites and terrestrial upper continental crust implies that the tektites formed by fusion of such target rock. Tektites are among the driest rocks on Earth. Although volatilization at high temperature may have caused this extreme dryness, the exact mechanism of the water loss and the behavior of other volatile species during tektite formation are still debated. Volatilization can fractionate isotopes, therefore, comparing the isotope composition of volatile elements in tektites with that of their source rocks may help to understand the physical conditions during tektite formation.For this study, we have measured the Zn isotopic composition of 20 tektites from four different strewn fields. Almost all samples are enriched in heavy isotopes of Zn compared to the upper continental crust. On average, the different groups of tektites are isotopically distinct (listed from the isotopically lightest to the heaviest): Muong-Nong type indochinites (δ66/64Zn = 0.61 ± 0.30‰); North American bediasites (δ66/64Zn = 1.61 ± 0.49‰); Ivory Coast tektites (δ66/64Zn = 1.66 ± 0.18‰); the Australasian tektites (others than the Muong Nong-type indochinites) (δ66/64Zn = 1.84 ± 0.42‰); and Central European moldavites (δ66/64Zn = 2.04 ± 0.19‰). These results are contrasted with a narrow range of δ66/64Zn = 0–0.7‰ for a diverse spectrum of upper continental crust materials.The elemental abundance of Zn is negatively correlated with δ66/64Zn, which may reflect that isotopic fractionation occurred by evaporation during the heating event upon tektite formation. Simple Rayleigh distillation predicts isotopic fractionations much larger than what is actually observed, therefore, such a model cannot account for the observed Zn isotope fractionation in tektites. We have developed a more realistic model of evaporation of Zn from a molten sphere: during its hypervelocity trajectory, the molten surface of the tektite will be entrained by viscous coupling with air that will then induce a velocity field inside the molten sphere. This velocity field induces significant radial chemical mixing within the tektite that accelerates the evaporation process. Our model, albeit parameter dependent, shows that both the isotopic composition and the chemical abundances measured in tektites can be produced by evaporation in a diffusion-limited regime. 相似文献
10.
Characteristic geochemical features of the ophiolite suite from the Bay of Islands Complex have been determined by major and trace element analyses of 13 rocks. Based on elements, such as rare earth elements (REE), whose abundances are relatively immobile during alteration and metamorphism, we find that (1) the pillow lavas and diabases are relatively depleted in light REE similar to most tholeiites occurring along spreading oceanic ridges, in back-arc basins and comprising the early phases of volcanism in island arcs; (2) the gabbros, composed of cumulate plagioclase and olivine with poikilitic clinopyroxene, have REE contents consistent with formation as cumulates precipitated from magmas represented by the overlying pillow lavas and diabases; (3) as in most harzburgites from ophiolites, the Bay of Islands harzburgite and dunite have relative REE abundances inconsistent with a genetic relationship to the overlying basic rocks — this inconsistency may be primary or it may result from late-stage alteration, contamination and/or metamorphism; (4) some Bay of Islands lherzolites have major and trace element abundances expected in the mantle source of the overlying basic rocks. Overall, the geochemical features of this Bay of Islands ophiolite suite are similar to those from Troodos and Vourinos, but these data are not sufficient to distinguish between different tectonic environments such as deep ocean ridge, small ocean basin or young island arc. 相似文献
11.
Granodiorite and diorite plutons of the Rosetown complex, N.Y., which are associated with the nearby Cortlandt complex, have chemical and textural characteristics indicating that large-scale liquid immiscibility played a major role in their petrogenesis. Rare earth element, zirconium, niobium and phosphorus abundances are much greater in the diorite precluding the possibility that the Rosetown diorite and granodiorite are related by fractional crystallization. The trace element data also eliminate the possibility that the granodiorite represents: (1) a partial melt of crustal rocks including basalt; (2) a granitic cumulate; or (3) a residue from an aqueous fluid derived either from a silicate melt or crustal rocks. Liquid immiscibility appears to be viable model for the origin of the Rosetown granodiorite and iron-rich diorite. This model is supported by the following: (1) the major element compositions occur in a two-liquid field on a Greig diagram; (2) both bodies have similar Sr isotope compositions; (3) common phases in the two rock types have overlapping compositions; (4) the major and trace element data of the diorite and granodiorite are similar to the experimentally determined partition data of immiscible liquid pairs; and (5) possible ocelli of iron-rich diorite are found in the granodiorite. 相似文献
12.
S.N. Ehrenberg 《Earth and Planetary Science Letters》1982,57(1):191-210
Mineral and whole-rock REE abundances in garnet lherzolite and megacrystalline nodules from The Thumb display broad correlations with major element compositions. Lherzolites with > 12 modal % clinopyroxene plus garnet (“high-CaAl lherzolites”) have relatively flat chondrite-normalized whole-rock REE patterns. Lherzolites poor in clinopyroxene and garnet (“low-CaAl lherzolites”) have lower HREE in clinopyroxenes and garnets and higher whole-rock LREE/HREE. It is concluded that the low-CaAl lherzolites may have undergone LREE metasomatism after depletion of the major element compositions by partial melting and that much of the garnet now present was originally dissolved in aluminous orthopyroxene. The high-CaAl lherzolites may be interpreted either as primordial mantle samples or as products of equilibration with very LREE-enriched liquids. The “megacrystalline” nodules are medium- to ultracoarse-grained intergrowths and megacrysts with mineral compositions similar to discrete nodule suites in kimberlites. The REE abundances of the megacrystalline minerals are consistent with an origin as cumulates from magma with extremely fractionated REE, similar to minette or kimberlite.The patterns of correlation of REE and major elements in this inclusion suite are similar to the patterns observed in the garnet lherzolite and discrete nodule suites of southern African kimberlites. Both of the subcontinental mantle provinces represented by these suites contain three distinct petrogenetic components: refractory garnet lherzolite enriched in LREE and depleted in HREE, fertile garnet lherzolite with generally chondritic REE abundances, and a suite of ultracoarse minerals precipitated from magma with extremely fractionated REE generally similar to the host magmas. 相似文献
13.
Petrogenesis of basalts from the FAMOUS area: Mid-Atlantic Ridge 总被引：1，自引：0，他引：1
C.H. Langmuir J.F. Bender A.E. Bence G.N. Hanson S.R. Taylor 《Earth and Planetary Science Letters》1977,36(1):133-156
Fresh basalt glasses most of which have Mg/(Mg + Fe2+) of 0.66–0.72 from outcrops within 3 km of one other in the rift valley at the Project FAMOUS locality have been analyzed for major, minor and trace elements in order to determine their petrogenesis.Transition metal abundances of the FAMOUS samples are similar to a wide variety of continental and oceanic basalts with high MgO and Ni, all of which show remarkably little variation, with the exception of Cu, Zn and Ti, on a chondrite-normalized plot. Modelling of these data suggests that the mantle beneath both continents and oceans is systematically fractionated relative to chondrites. This fractionation provides a constraint for models of earth formation and subsequent evolution.The abundances of the rare earth and the incompatible elements, Ba, La, Th, U, and Nb, vary by more than a factor of three and the La/Yb and La/Sm ratios vary by factors of 3.1 and 1.6, respectively, in samples with similar, high Mg/(Mg + Fe2+). There is no correlation between the degree of light-REE enrichment and the heavy-REE abundance. Furthermore, the trace element variations do not appear correlated with respect to location in the rift valley or to time of eruption. These trace element features demonstrate that successive eruptions in one small area of the rift valley can show wide variations in trace element chemistry over a short span of time; they preclude the derivation of these basalt glasses from a single magma chamber.Despite the heterogeneities in REE and the variable trace element abundances, a homogeneous mantle source is suggested by the similarities among the samples in the incompatible element ratios of La/Ce, Ba/Th, Zr/Nb and K/Ba and the small range in87Sr/86Sr isotope ratios observed in other samples from the FAMOUS region (White and Bryan, 1977). Thus, trace element heterogeneities appear to be generated by processes in the mantle during melting. However, processes such as batch partial melting, fractional fusion, fractional crystallization, zone refining, or mixing of magmas or sources acting alone are incapable of explaining the lack of correlation between the light and heavy REE.It is suggested that the observed variations are a consequence of dynamic partial melting of a homogeneous mantle source region. This process includes varying degrees of partial melting of an uprising mantle source with continuous but incomplete removal of melt as melting proceeds, varying extents of batch partial melting, and zone refining. Dynamic melting can produce different melts from a homogeneous source which have different degrees of light-REE enrichment and crossing REE patterns. The variable trace element abundances which may be produced through dynamic melting may be the cause of the apparent decoupling of major and trace elements (Bryan et al., 1976) which previously has been suggested for the FAMOUS region (Bryan and Moore, 1977). 相似文献
14.
Major, minor and trace element abundances were determined in seven Angra dos Reis samples including whole rocks, fassaite (clinopyroxene), olivine and whitlockite separates via sequential instrumental neutron activation analysis. The chondritic normalized rare earth element (REE) abundance pattern for the Angra dos Reis clinopyroxene separates shows a concave downward shape with a small negative Eu anomaly. The strong fractionation between the light and the heavy REE in olivine separates could be attributed to the presence of islands of kirschsteinite in the olivines. The large-ion lithophile trace elements were highly enriched in the whitlockite separate as expected (e.g. La ≈ 370 ppm). The lower Hf and Sc abundances in whitlockite compared to that in the equilibrium “magma” could be the result of favorable partitioning of Hf and Sc in baddeleyite, which may have crystallized prior to or with whitlockite in the interstitial liquid. Comparison of whole rock with mineral separate data shows the presence of ～3% olivine, ～2.6% spinel and small amounts of metallic Ni-Fe and troilite in the whole rock.The trace element abundances in the derivative magma from which the Angra dos Reis clinopyroxene crystallized were estimated from the clinopyroxene data and the clinopyroxene mineral-liquid partition coefficients. From the derivative magma, the trace element abundances in the possible parent magmas were calculated by assuming that these parent magmas have undergone different degrees of clinopyroxene fractional crystallization to yield the Angra dos Reis derivative magma. Using the trace element abundances in these possible parent magmas, a two-stage crystal-liquid fractionation model with source material containing olivine, orthopyroxene and clinopyroxene is presented for the genesis of Angra dos Reis. Possible combinations of the degree of equilibrium non-modal partial melting, the source mineral composition and the initial element abundances required to generate possible Angra dos Reis parent magmas are calculated by the multilinear regression analysis method. Favorable solutions for this two-stage crystal-liquid fractionation model could be that Angra dos Reis crystallized at ～70% fractional crystallization of clinopyroxene from magmas generated by reasonable degrees of equilibrium partial melting (～7–10%) of deep-seated primitive source materials (olivine ～54–30%, orthopyroxene ～33–53%, and clinopyroxene ～13–17%) with trace element (Ba, Sr, REE and Sc) abundances ～3.5–4.7 × chondrites. These calculated REE abundances in the Angra dos Reis parent body are very similar to those suggested for the primordial moon (～3–5 × chondrites).Possible genetic relationships between Angra dos Reis and other achondrites, especially cumulate eucrites and nakhlites, are studied. Apparently, the unique Angra dos Reis could not be related to those achondrites by crystal-liquid fractionation of the same parent body. 相似文献
15.
Fission track ages of North American tektites from Texas, Georgia and Martha's vineyard range widely between 0.8 my and 34.2 my with the tektites from Georgia giving the lowest ages. Size studies of the fission track etch pits reveal the thermal history of each individual tektite resulting in the partial loss of tracks. Therefore, the measured fission track ages can be understood as thermally lowered.
Based on annealing experiments, correction factors for the thermally lowered fission track ages are found. The weighted mean of the corrected fission track ages is 34.9 my for the bediasites and the Martha's Vineyard tektite. On the other hand, the corrected fission track ages of the Georgia tektites are much lower resulting from a more complex thermal history.
It may now be stated that North American tektites and Libyan Desert glasses cannot have had a simultaneous origin. 相似文献
16.
C.M. Gray 《Earth and Planetary Science Letters》1984,70(1):47-60
A simple mixing process was a significant element in the genesis of many southeastern Australian granitic rocks: major and trace element abundances are near-linearly correlated, Nd and Sr initial isotopic compositions define a simple hyperbolic trend, and many initial 87Sr/86Sr ratios are a regular function of Rb/Sr ratios. Geological arguments and regression of geochemical variation diagrams place limits on the nature of the end members. The high-Si end member is meta-sedimentary-derived magma comparable in composition to the Cooma Granodiorite, the one pluton in the region surrounded by, and clearly derived from, regional metamorphic rocks. The low-Si end member is basaltic material with similarities to rare gabbros also found in the area. Isotope dilution calculations based upon initial Sr and Nd isotopic compositions deduced for the end members yield realistic hypothetical Sr and Nd concentrations for the end members in a demonstration of the internal consistency of the model. All of the granitic rocks, from hornblende tonalites to cordierite granodiorites, are a single broad family, products of variable mixing between distinct batches of basaltic material and a uniform partial melt of the regional basement. 相似文献
17.
This is a preliminary study on the microtektites that were found in large numbers from the interval between 7.80 and 8.10
m depth of core S095-17957-2 (10°53.9’N, 115°18.3’E, water depth 2 195 m), northern Nansha area of the South China Sea. The
microtektites vary in shape, with spherules predominating, and are commonly less than 1 mm in diameter, transparent or semitransparent,
brownish in color, with bubbles inside. Based on coarse fraction stratigraphy and foraminifera/nanofossil biostratigraphical
events the microtektite layer was assigned to nearly the Bm-hes/Matuyama magnetic reversal boundary (some 0.78 MaBP). Obviously,
the present microtektites, and those found from the middle Pleistocene of the Indian Ocean, Australia and loess of northern
China, were products of the same impact event and therefore, are useful as a reliable mark in Quaternary stratigraphy, as
well as in paleoclimatic studies.
Project supported by the National Natural Science Foundation of China (Grant Nos. 49676287, 49732060). 相似文献
18.
Stephen R. Winzer David F. Nava Shuford Schuhmann Charles W. Kouns R.K.L. Lum John A. Philpotts 《Earth and Planetary Science Letters》1974,23(3):439-444
Apollo 17 station 7 boulder consortia samples were analyzed for major and minor elements by a combined semimicro atomic absorption spectrophotometric and colorimetric procedure. Lithophile trace element abundances were determined by stable isotope dilution mass spectrometry. Three matrix types samples (77135, 77115, and 77075) were found to be KREEP-rich fragment-laden melts with analogues throughout the Apollo 17 landing site. Of the five clasts analyzed, at least one (77115,19, troctolite) is thought to be a cumulate; 77135, 77115, and 77075 are thought to have originated by impact fusion of material with similar composition. This original material may represent a partial melt of a parent material of the composition of an included, shocked norite breccia (77215). 相似文献
19.
Strontium isotope ratios and rare-earth element abundances have been measured in acid, intermediate and basic rocks from three late to postglacial volcanic complexes, and several other postglacial basalts in Iceland. Late and postglacial basalts in Iceland have been generated from a source region which is essentially homogeneous with respect to87Sr/86Sr. The mean87Sr/86Sr ratio for the basalts analysed is 0.70328 and the range is from 0.70317 ± 6to0.70334 ± 5 (2σ).Acid rocks from the Kerlinganfjöll and Namafjall volcanic complexes have87Sr/86Sr ratios which are indistinguishable from analysed basalts from the same complexes. However, intermediate and acid rocks from the Torfajökull complex have significantly higher87Sr/86Sr ratios and could not have been derived by fractional crystallization from basaltic magmas similar to those found in the same complex. These latter rocks have most probably been produced by remelting of Tertiary gabbroic rocks in Layer 3. Most of the basalts analysed have higher total rare-earth element abundances than typical dredged ocean-ridge tholeiites, and show less light rare-earth depletion. Intermediate and acid compositions show overall higher abundances and light rare-earth enrichments. The measured rare-earth abundances are compared with abundances generated by differential partial melting of various model source regions.It is shown that both the tholeiitic and alkali basalt compositions could be generated from the same source material by different degrees of partial melting. Variable partial melting of gabbroic material may account for the rare-earth element abundances of both the rhyolitic rocks (small degrees of melting) and the intermediate rocks (more extensive melting). 相似文献
20.
Paul Henderson Susan J. Fishlock J.C. Laul T.D. Cooper R.L. Conard W.V. Boynton R.A. Schmitt 《Earth and Planetary Science Letters》1976,30(1):37-49
Rare earth element (REE) abundances determined by activation analysis in rocks, plagioclase and mafic separates from the Fiskenaesset Complex are presented together with data on major and trace elements in the minerals. The REE data for the rocks and plagioclases are distinct from those of many other anorthositic complexes and the abundances are some of the lowest recorded for plagioclase from terrestrial anorthosites. The bulk and trace element compositions of the Fiskenaesset plagioclases show a number of similarities to those of lunar plagioclases. The plagioclases show a positive Eu anomaly of about 10 and a depletion in the heavy REE relative to the light ones. The mafic separates are enriched in the heavy REE relative to the light ones, and show no Eu anomaly except in one sample with a positive anomaly not attributable to plagioclase contamination. It is estimated, from experimental partition coefficient data, that the REE pattern in the magma at an early stage of fractionation was La (17×) to Lu (0.7× chondrites) with a possible positive Eu anomaly. This highly fractionated REE pattern may be attributed to partial melting of a garnet-bearing source. 相似文献